SEARCH · USGS Science

Results for “Nature Water”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 307 records · Page 17Linked to original sources

USGS2015

Towards automating measurements and predictions of Escherichia coli concentrations in the Cuyahoga River, Cuyahoga Valley National Park, Ohio, 2012–14

Nowcasts are systems that can provide estimates of the current bacterial water-quality conditions based on predictive models using easily-measured, explanatory variables; nowcasts can provide the public with the information to make informed decisions on the risk associated with recreational activities in natural water bodies. Previous studies on the Cuyahoga River within Cuyahoga Valley National Park (CVNP) have found that predictive models can be used to provide accurate assessments of the recreational water quality. However, in order to run the previously developed nowcasts for CVNP, manual collection and processing of samples is required on a daily basis to acquire the required explanatory variable data (laboratory-measured turbidity). The U.S. Geological Survey and the National Park Service collaborated to develop a more automated approach to provide more timely results to park visitors regarding the recreational water quality of the river. In May 2012, an in-stream water-quality sensor was installed by the U.S. Geological Survey at Jaite, Ohio (a site centrally located in CVNP on the Cuyahoga River), to provide near-real-time measurements of turbidity and water temperature. To transition from methods used during previous studies at CVNP, a relation between laboratory- and in-stream measured turbidity was developed after the recreational season of 2012. During the recreational seasons of 2012 through 2014, discrete water samples were collected and processed to determine Escherichia coli ( E. coli ) concentrations at Jaite and one site upstream of Jaite (Lock 29) within CVNP. Predictive models, using in-stream turbidity measurements, were developed for the recreational seasons of 2013 and 2014 to estimate recreational water quality in regards to Ohio’s single-sample water-quality standard for primary-contact recreation. A computer program was developed to manage the nowcasts by running the predictive models and posting the results to a publicly accessible Web site daily by 9 a.m. The nowcasts were able to correctly predict E. coli concentrations above or below the water-quality standard at Jaite for 79 percent of the samples compared with the measured concentrations. In comparison, the persistence model (using the previous day’s sample concentration) correctly predicted concentrations above or below the water-quality standard in only 68 percent of the samples. To determine if the Jaite nowcast could be used for the stretch of the river between Lock 29 and Jaite, the model predictions for Jaite were compared with the measured concentrations at Lock 29. The Jaite nowcast provided correct responses for 77 percent of the Lock 29 samples, which was a greater percentage than the percentage of correct responses (58 percent) from the persistence model at Lock 29.

Ohio↗

USGS2015

Ground-survey and water-quality data for selected wetlands on or near the Lower Brule Indian Reservation in South Dakota, 2012-13

Numerous lakes, ponds, and wetlands are located within the Lower Brule Indian Reservation. Wetlands are an important resource providing aquatic habitat for plants and animals, and acting as a natural water filtration system. Several of the wetlands on or near the reservation are of particular interest, but information on the physical and biological integrity of these wetlands was needed to provide a base-line reference when planning for future water management needs. A reconnaissance-level study of selected wetlands on and near the Lower Brule Indian Reservation was completed in 2012–13 by the U.S. Geological Survey in cooperation with the Lower Brule Sioux Tribe using ground surveys and water-quality analyses. Ground surveys of six wetland areas (Dorman Slough, Little Bend Wetlands, Miller Pond, Potter Slough, an unnamed slough, and West Brule Community wetlands) were completed to map land, water, vegetation, and man-made features of the selected wetland areas using real-time kinematic global navigation satellite systems equipment. Water samples were collected from four of the selected wetlands. Two separate waterbodies were sampled at one of the wetlands for a total of five sampling locations. Water samples were analyzed for physical properties, selected inorganics, metals, nutrients, and suspended sediment. Concentrations of calcium, sodium, and sulfate were greater at the two wetland sites fed by ground water, compared to the wetland sites fed by surface runoff.

South Dakota↗

USGS1993

Crude oil in a shallow sand and gravel aquifer—I. Hydrogeology and inorganic geochemistry

Changes in the distribution of inorganic solutes in a shallow ground water contaminated by crude oil document a series of geochemical reactions initiated by biodegradation of the oil. Upgradient of an oil body floating on the water table, oxidation of oil to carbonic acid dissolves carbonate minerals in the aquifer matrix. In this oxidized zone pH is depressed &sim;1 pH unit, and the concentrations of Ca, Mg and HCO 3 − increase to more than twice that of the native ground water. In the anoxic zone beneath the oil body concentrations of dissolved SiO 2 , Sr, K, Fe and Mn increase significantly. Here, Fe is mobilized by microbial reduction, pH is buffered by the carbonate system, and silicates weather via hydrolysis and organic-acid-enhanced dissolution. Farther down-gradient the ground water is reoxygenated and Fe precipitates from solution, possibly as iron hydroxide or iron carbonates, while SiO 2 precipitates as amorphous silica. Other solutes, such as Mg, are transported more conservatively down-gradient where contaminated and native ground water mix. The observed changes in inorganic aqueous chemistry document changes in water-mineral interactions caused by the presence of an organic contaminant. These organic-initiated interactions are likely present in many contaminated aquifers and may be analogous to interactions occurring in other organic-rich natural waters.

Minnesota↗

USGS2023

Guidelines for field-measured water-quality properties

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.0, provides guidance and protocols for the measurement of field parameters on site, which include the selection of sites and methods for measurement in groundwater and surface water and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.0, version 2.0, by Franceska D. Wilde. Field parameters are routinely measured when water samples are collected, are often measured continually at USGS streamgages, and are regularly measured during laboratory and field experiments. The field methods for measuring field parameters described in this chapter are applicable to most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.er.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS1999

Quantification of aerobic biodegradation and volatilization rates of gasoline hydrocarbons near the water table under natural attenuation conditions

Aerobic biodegradation and volatilization near the water table constitute a coupled pathway that contributes significantly to the natural attenuation of hydrocarbons at gasoline spill sites. Rates of hydrocarbon biodegradation and volatilization were quantified by analyzing vapor transport in the unsaturated zone at a gasoline spill site in Beaufort, South Carolina. Aerobic biodgradation rates decreased with distance above the water table, ranging from 0.20 to 1.5 g m −3 d −1 for toluene, from 0.24 to 0.38 g m −3 d −1 for xylene, from 0.09 to 0.24 g m −3 d −1 for cyclohexene, from 0.05 to 0.22 g m −3 d −1 for ethylbenzene, and from 0.02 to 0.08 g m −3 d −1 for benzene. Rates were highest in the capillary zone, where 68% of the total hydrocarbon mass that volatilized from the water table was estimated to have been biodegraded. Hydrocarbons were nearly completely degraded within 1m above the water table. This large loss underscores the importance of aerobic biodradation in limiting the transport of hydrocarbon vapors in the unsaturated zone and implies that vapor‐plume migration to basements and other points of contact may only be significant if a source of free product is present. Furthermore, because transport of the hydrocarbon in the unsaturated zone can be limited relative to that of oxygen and carbon dioxide, soil‐gas surveys conducted at hydrocarbon‐spill sites would benefit by the inclusion of oxygen‐ and carbon‐dioxide‐gas concentration measurements. Aerobic degradation kinetics in the unsaturated zone were approximately first‐order. First‐order rate constants near the water table were highest for cyclohexene (0.21–0.65 d −1 ) and nearly equivalent for ethylbenzene (0.11–0.31 d −1 ), xylenes (0.10–0.31 d −1 ), toluene (0.09–0.30 d −1 ), and benzene (0.07–0.31 d −1 ). Hydrocarbon mass loss rates at the water table resulting from the coupled aerobic biodgradation and volatilization process were determined by extrapolating gas transport rates through the capillary zone. Mass loss rates from groundwater were highest for toluene (0.20–0.84 g m −2 d −1 ), followed by xylenes (0.12–0.69 g m −2 d −1 ), cyclohexene (0.05–0.15 g m −2 d −1 ), ethylbenzene (0.02–0.12 g m −2 d −1 ), and benzene (0.01–0.04 g m −2 d −1 ). These rates exceed predicted rates of solubilization to groundwater, demonstrating the effectiveness of aerobic biodgradation and volatilization as a combined natural attenuation pathway.

Water Resources Research↗

USGS1964

Water resources of the Green Bay area, Wisconsin

The Green Bay area comprises an area of about 525 square miles in eastern Wisconsin at the south end of Green Bay. It includes the western three-fourths of Brown County and the eastern one-ninth of Outagamie County. In 1960, the population of the area was estimated at 124,000. The most prominent topographic feature is the northwest-facing, southwestward trending Niagara escarpment. The area northwest of the escarpment drains into Green Bay via the Fox River, Suamico River, Duck Creek, and their tributaries. The area southeast of the escarpment is drained by streams that flow into Lake Michigan. The chief sources of surface water in the Green Bay area are the Fox River, Green Bay, and Lake Michigan. Smaller amounts of water are available from the East and Suamico Rivers and other streams. A sandstone aquifer is the principal source of the ground-water supply. The Niagara dolomite, although largely undeveloped, is potentially an important aquifer in the eastern part of the area. Small amounts of water are obtained also from the Platteville formation and from deposits of Pleistocene and Recent age. Water from the surfaceand ground-water sources is moderately hard to very hard. The Fox River, tributary to Lake Michigan at Green Bay, is a significant source of water for industrial use in the Green Bay area. The Menasha Dam, which controls release of water from the Lake Winnebago pool, is the major regulation on the Fox River, and it has considerable effect in reducing peak flows and supplementing low flows in the lower Fox River. The average discharge of the lower Fox River for the period 1898-1959, as measured at the gaging station at Rapide Croche Dam, was 2,687 mgd (million gallons per day). The longest consecutive period during which the discharge averaged less than 500 mgd was 80 days. The average discharge can be expected to fall below 700 mgd about once every 5 years for a 7-day period. In 1959, the average withdrawal of water from the Fox River was about 62 mgd. The water in the river is of the calcium magnesium bicarbonate type and is hard. The small streams in the area are utilized chiefly for stock watering; some of the water, however, is used for irrigation. The water in the small streams is more highly mineralized than the water in the Fox River and is very hard. Large quantities of water are available from Green Bay, but the disposal of industrial waste into the bay has restricted the use of the water. The major withdrawal is for condenser cooling, and, in 1959, it averaged about 415 mgd. The water from Green Bay is moderately hard but is of better chemical quality than the water from the Fox River and the small streams in the area. The only withdrawals of water from Lake Michigan for use in the Green Bay area are made by the city of Green Bay. In 1959, these withdrawals averaged 7.8 mgd. The lower Fox River is not subject to extremes of flow owing to the dampening effect of the Lake Winnebago pool and the regulation of flow at Menasha Dam. Cloudbursts over the lower Fox River valley below Menasha Dam, however, have occasionally caused extremely high water, as in 1922, when the discharge at the mouth of the Fox River was estimated to be about 50,000 mgd. Daily discharges greater than about 13,000 mgd occurred only 7 times in the period 1918-59. The 50-year flood of 15,500 mgd represents an average runoff of less than 2.6 mgd per square mile of drainage area, a relatively low runoff for a 50-year flood in Wisconsin. The sandstone aquifer is the principal source of ground water in the Green Bay area and furnishes water for public supply and industrial use. This aquifer includes rocks of Late Cambrian age, and the Prairie du Chien group and St. Peter sandstone of Ordovician age; it ranges in thickness from 550 to 640 feet. Ground water is found in openings along fractures and bedding planes and in the interstices between sand grains. The sandstone aquifer can support additional development of large supplies of ground water. Wells can be developed in most of the area that will yield 500 gpm (gallons per minute) or more, provided they are properly spaced and penetrate the entire thickness of the aquifer. It is estimated that the perennial yield of the sandstone in the Green Bay area could be at least 30 mgd if the aquifer is properly developed; only 5.4 mgd was withdrawn in 1959. The water from this sandstone aquifer is of the calcium magnesium bicarbonate type, is very hard, and, at a few places, contains objectionable amounts of iron. The Niagara dolomite, potentially a source of moderate to large quantities of water in the eastern part of the area, probably will yield 500 gpm or more to wells. In 1959, the average withdrawal of water for all uses was estimated at 495 mgd, of which 98.2 percent was from surface-water sources and 1.8 percent was from wells. About 485 mgd of water was withdrawn for industrial use, 6 mgd for public supply, and 4 mgd for rural use. The industrial use of water averaged 441 mgd for condenser cooling, 38 mgd fot processing by the paper industry, and 6 mgd for other industrial uses. The city of Green Bay used 7.8 mgd of water from Lake Michigan; other public supplies in the area used 2.6 mgd from wells. Of the withdrawals of water for rural use, about 75 percent was from wells and about 25 percent was from streams. The discharge of wastes into the lower Fox River and its tributary streams has altered the quality of the natural water. The wastes consist chiefly of treated municipal sewage and treated and untreated wastes from the paper industry, rendering plants, a sugar mill, and other industries. The industrial waste makes up about 90 percent of the oxygen-demand loading in the lower Fox River, and treated municipal sewage accounts for about 10 percent. The dissolved-oxygen concentration of water in the lower Fox River decreases rapidly in the vicinity of Green Bay during the summer when the river water is warm. If the periods when the river water is warmest, generally during July and early August, were to coincide with periods of lowest annual streamflow, generally in late August, the river would be unable to assimilate the loading of decomposable organic matter. In an emergency, industrial and public supply wells could supply at least 6 mgd for a sustained period and probably as much as 10 mgd for a period of several days. Six of the wells that formerly supplied the city of Green Bay are maintained in operating condition and could furnish about the same quantity of water as the industrial and other public supply wells. Small streams in the area would be supplemental sources of water, and the water in the Fox River and Green Bay is easily accessible.

Wisconsin↗

USGS2020

Chapter A6.2. Dissolved oxygen

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface water and groundwater resources. This chapter, NFM A6.2, provides guidance and protocols for the measurement of dissolved oxygen, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.2, version 3.0, by Stewart A, Rounds, Franceska D. Wilde, and George F. Ritz. Dissolved oxygen is routinely measured when water samples are collected, is often continually measured at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring dissolved oxygen described in this chapter is applicable to most natural waters. Before 2017, the USGS NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0—U.S. Geological Survey, 2018) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.er.usgs.gov . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS2019

Chapter A6.3. Specific Conductance

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.3, provides guidance and protocols for the measurement of specific conductance of a water sample, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.3, version 1.2, by D.B. Radtke, J.V. Davis, and F.D. Wilde. Specific conductance is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring specific conductance described in this chapter is applicable to most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.er.usgs.gov. Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS1999

Hydrogeology and water quality of the upper Floridan aquifer, western Albany area, Georgia

Geologic, hydrologic, and water-quality data were collected to refine the hydrogeologic framework conceptual model of the Upper Floridan aquifer, and to qualitatively evaluate the potential of human activities to impact water quality in the Upper Floridan aquifer in the western Albany area, Georgia. Ground-water age dating was conducted by using chlorofluorocarbons (CFC) and tritium concentrations in water from the Upper Floridan aquifer to determine if recharge and possible contaminant migration to the aquifer is recent or occurred prior to the introduction of CFCs and tritium in the early 1950's into the global natural water system. Data were collected from core holes and wells installed during this study and previously existing wells in the Albany area. Hydrogeologic data collected during this study compare well to the regional hydrogeologic conceptual model developed during previous studies. However, the greater data density available from this study shows the dynamic and local variability in the hydrologic character of the Upper Floridan aquifer in more detail. The occurrence of sediment sizes from clay to gravel in the overburden, the absence of overburden because of erosion or sinkhole collapse, and large areas lacking surface drainage west of the Flint River provide potential areas for recharge and contaminant migration from the surface to the Upper Floridan aquifer throughout the study area. Ground-water ages generally range from 9 to 34 years, indicating that recharge consisting of 'modern' water (post early-1950's) is present in the aquifer. Ground-water ages and hydraulic heads in the Upper Floridan aquifer have an irregular distribution, indicating that localized areas of recharge to the aquifer are present in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area. Generally, water in the Upper Floridan aquifer is calcium-bicarbonate rich, having low concentrations of magnesium, potassium, sodium, chloride, and sulfate. Water in the Upper Floridan aquifer is oxygenated, having dissolved-oxygen concentrations greater than 2 milligrams per liter. Nitrite-plus-nitrate as nitrogen, is present in the aquifer at concentrations ranging from less than 0.02 to 5.5 milligrams per liter. Areas of higher nitrate concentrations in the aquifer, coupled with widely distributed localized recharge to the aquifer indicates that suburban residential and agricultural land use in the western Albany area may affect water quality in the Upper Floridan aquifer. However, concentrations exceeding drinking water criteria were not detected in the study area.

Georgia↗

USGS2004

Effects of changes in reservoir operations on water quality and trophic state indicators in Voyageurs National Park, northern Minnesota, 2001-03

Implementation of an order by the International Joint Commission in January 2000 has changed operating procedures for dams that regulate two large reservoirs in Voyageurs National Park in northern Minnesota. These new procedures were expected to restore a more natural water regime and affect water levels, water quality, and trophic status. Results of laboratory analyses and field measurements of chemical and physical properties from May 2001 through September 2003 were compared to similar data collected prior to the change in operating procedures. Rank sum tests showed significant decreases in chlorophyll-a concentrations and trophic state indices for Kabetogama Lake (p=0.021) and Black Bay (p=0.007). There were no significant decreases in total phosphorus concentration, however, perhaps due to internal cycling of phosphorus. No sites had significant trends in seasonal total phosphorus concentrations, with the exception of May samples from Sand Point Lake, which had a significant decreasing trend (tau=-0.056, probability=0.03). May chlorophyll-a concentrations for Kabetogama Lake showed a significant decreasing trend (tau=-0.42, probability=0.05). Based on mean chlorophyll trophic-state indices (2001-03), Sand Point, Namakan, and Rainy Lakes would be classified oligotrophic to mesotrophic, and Kabetogama Lake and Rainy Lake at Black Bay would be classified as mesotrophic. The classification of Sand Point, Namakan, and Rainy Lakes remain the same for data collected prior to the change in operating procedures. In contrast, the trophic classification of Kabetogama Lake and Rainy Lake at Black Bay has changed from eutrophic to mesotrophic.

Minnesota↗

USGS2017

Design- and model-based recommendations for detecting and quantifying an amphibian pathogen in environmental samples

Accurate pathogen detection is essential for developing management strategies to address emerging infectious diseases, an increasingly prominent threat to wildlife. Sampling for free-living pathogens outside of their hosts has benefits for inference and study efficiency, but is still uncommon. We used a laboratory experiment to evaluate the influences of pathogen concentration, water type, and qPCR inhibitors on the detection and quantification of Batrachochytrium dendrobatidis ( Bd ) using water filtration. We compared results pre- and post-inhibitor removal, and assessed inferential differences when single versus multiple samples were collected across space or time. We found that qPCR inhibition influenced both Bd detection and quantification in natural water samples, resulting in biased inferences about Bd occurrence and abundance. Biases in occurrence could be mitigated by collecting multiple samples in space or time, but biases in Bd quantification were persistent. Differences in Bd concentration resulted in variation in detection probability, indicating that occupancy modeling could be used to explore factors influencing heterogeneity in Bd abundance among samples, sites, or over time. Our work will influence the design of studies involving amphibian disease dynamics and studies utilizing environmental DNA (eDNA) to understand species distributions.

Ecolology and Evolution↗

USGS2021

Stability of inorganic and methylated arsenic species in laboratory standards, surface water and groundwater under three different preservation regimes

Geogenic arsenic (As) adversely affects drinking water quality in geologically diverse aquifers across the globe. Although the species of As significantly affects its fate, transport, toxicity, and As treatment technology efficacy, reported effectiveness of As species preservation methods varies widely with preservation methods and natural water geochemistry. Our study 1) evaluates the shelf life of As(III), As(V), dimethylarsinate (DMA), and monomethylarsonate (MMA) in standards prepared with ultrapure water; 2) establishes a hold time for these As species in low-iron (Fe) groundwater and surface water samples preserved with a concentration of EDTA that exceeded the sum of the molar concentrations of Al, Fe, Mn, Ca, Mg, and Sr (molar excess of EDTA); and 3) evaluates As(III) species stability in groundwater samples with detectable SO 4 and up to 6.5 mg/L Fe concentrations preserved in 3 ways: less than molar excess EDTA, molar excess EDTA, and Vacuette® tubes with an unknown (proprietary) amount of EDTA. Arsenic species standards prepared with 2.5 mM EDTA in ultrapure water and stored at 4 °C had a shelf life of at least 180 days. As(III) was stable for at least 15 days and DMA and MMA were stable for at least 90 days in environmental samples with Fe less than 1 mg/L that were preserved with a molar excess of EDTA and stored in opaque containers at 4 °C. As(III) species were not stable for any holding time in samples with Fe greater than 1 mg/L and detectable SO 4 when preserved with a molar excess of EDTA and stored in white high density polyethylene bottles at room temperature, or when preserved by storage in EDTA containing Vacuette® tubes at 4 °C. For geochemical or water quality studies where the distribution of As(III) and As(V) is a critical factor, an understanding of the sample chemistry, rapid As speciation analysis after sample collection, and collecting a field spike with the sample can be helpful for collecting accurate inorganic As species data.

Applied Geochemistry↗

USGS2024

Temperature

The “National Field Manual for the Collection of Water-Quality Data” (NFM) provides guidelines and procedures for U.S. Geological Survey (USGS) personnel who collect data used to assess the quality of the Nation’s surface-water and groundwater resources. This chapter, NFM A6.1, provides guidance and protocols for the measurement of temperature of air, of a surface-water body or in groundwater, which include the scientific basis of the measurement, selection and maintenance of equipment, calibration verification, troubleshooting, and procedures for measurement and reporting. It updates and supersedes USGS Techniques of Water-Resources Investigations, book 9, chapter A6.1, version 2.0, by Franceska D. Wilde. Temperature of air and water is routinely measured when water samples are collected, is often measured continually at USGS streamgages, and is a parameter regularly measured during laboratory and field experiments. The field method for measuring temperature described in this chapter is applicable to air and most natural waters. Before 2017, the NFM chapters were released in the USGS Techniques of Water-Resources Investigations series. Effective in 2018, new and revised NFM chapters are being released in the USGS Techniques and Methods series; this series change does not affect the content and format of the NFM. More information is in the general introduction to the NFM (USGS Techniques and Methods, book 9, chapter A0) at https://doi.org/10.3133/tm9A0 . The authoritative current versions of NFM chapters are available in the USGS Publications Warehouse at https://pubs.usgs.gov/ . Comments, questions, and suggestions related to the NFM can be addressed to nfm@usgs.gov .

Techniques and Methods↗

USGS1976

Geohydrology of the lowland lakes area, Anchorage, Alaska

Unconsolidated deposits, chiefly of glacial origin, make up the surficial geologic materials in the Anchorage lowland lakes area , the western part of the Anchorage glacial outwash plain. Postglacial accumulation of peat, commonly 5 to 10 feet thick, and the presence of ground water at or very near the surface combine to create the swamp-muskeg terrane of much of the area. Deeper, confined ground water is also present beneath thick silt and clay layers that underlie the surficial deposits. Domestic water supply for the lowland lakes area is provided largely by public-supply wells completed in the deep, confined aquifers. No large perennial streams traverse the area, thus streamflow is not a major parameter in the area 's natural water balance. The major uses of surface water are recreational, including fishing and boating at several of the larger lakes, and private and commercial aircraft operations at Hood-Spenard Lakes floatplane base. The hydrology and water balance of these lakes is complex. Water levels in some lakes appear to be closely related to adjacent ground-water levels. Other lakes are evidently perched above the local water table. The relation of lake level to adjacent ground-water level may vary along the shoreline of a single lake. The effect of residential development practices on lake basin water balance is not completely understood. At Sand Lake, the largest lake in this area of rapid urbanization, the water level has declined about 6 feet since the early 1960's. (Woodard-USGS)

Alaska↗

USGS2015

Carbon isotope analysis of dissolved organic carbon in fresh and saline (NaCl) water via continuous flow cavity ring-down spectroscopy following wet chemical oxidation

This work examines the performance and limitations of a wet chemical oxidation carbon analyser interfaced with a cavity ring-down spectrometer (WCO-CRDS) in a continuous flow (CF) configuration for measuring δ 13 C of dissolved organic carbon ( δ 13 C-DOC) in natural water samples. Low-chloride matrix (<5 g Cl/L) DOC solutions were analysed with as little as 2.5 mg C/L in a 9 mL aliquot with a precision of 0.5 &permil;. In high-chloride matrix (10–100 g Cl/L) DOC solutions, bias towards lighter δ 13 C-DOC was observed because of incomplete oxidation despite using high-concentration oxidant, extended reaction time, or post-wet chemical oxidation gas-phase combustion. However, through a combination of dilution, chloride removal, and increasing the oxidant:sample ratio, high-salinity samples with sufficient DOC (>22.5 µg C/aliquot) may be analysed. The WCO-CRDS approach requires more total carbon (µg C/aliquot) than conventional CF-isotope ratio mass spectrometer, but is nonetheless applicable to a wide range of DOC concentration and water types, including brackish water, produced water, and basinal brines.

Isotopes in Environmental and Health Studies↗

USGS2010

Comparison of photon correlation spectroscopy with photosedimentation analysis for the determination of aqueous colloid size distributions

Colloidal materials, dispersed phases with dimensions between 0.001 and 1 μm, are potential transport media for a variety of contaminants in surface and ground water. Characterization of these colloids, and identification of the parameters that control their movement, are necessary before transport simulations can be attempted. Two techniques that can be used to determine the particle-size distribution of colloidal materials suspended in natural waters are compared. Photon correlation Spectroscopy (PCS) utilizes the Doppler frequency shift of photons scattered off particles undergoing Brownian motion to determine the size of colloids suspended in water. Photosedimentation analysis (PSA) measures the time-dependent change in optical density of a suspension of colloidal particles undergoing centrifugation. A description of both techniques, important underlying assumptions, and limitations are given. Results for a series of river water samples show that the colloid-size distribution means are statistically identical as determined by both techniques. This also is true of the mass median diameter (MMD), even though MMD values determined by PSA are consistently smaller than those determined by PCS. Because of this small negative bias, the skew parameters for the distributions are generally smaller for the PCS-determined distributions than for the PSA-determined distributions. Smaller polydispersity indices for the distributions are also determined by PCS.

Water Resources Research↗

USGS2021

Optical properties of water for prediction of wastewater contamination, human-associated bacteria, and fecal indicator bacteria in surface water at three watershed scales

Relations between spectral absorbance and fluorescence properties of water and human-associated and fecal indicator bacteria were developed for facilitating field sensor applications to estimate wastewater contamination in waterways. Leaking wastewater conveyance infrastructure commonly contaminates receiving waters. Methods to quantify such contamination can be time consuming, expensive, and often nonspecific. Human-associated bacteria are wastewater specific but require discrete sampling and laboratory analyses, introducing latency. Human sewage has fluorescence and absorbance properties different than those of natural waters. To assist real-time field sensor development, this study investigated optical properties for use as surrogates for human-associated bacteria to estimate wastewater prevalence in environmental waters. Three spatial scales were studied: Eight watershed-scale sites, five subwatershed-scale sites, and 213 storm sewers and open channels within three small watersheds (small-scale sites) were sampled (996 total samples) for optical properties, human-associated bacteria, fecal indicator bacteria, and, for selected samples, human viruses. Regression analysis indicated that bacteria concentrations could be estimated by optical properties used in existing field sensors for watershed and subwatershed scales. Human virus occurrence increased with modeled human-associated bacteria concentration, providing confidence in these regressions as surrogates for wastewater contamination. Adequate regressions were not found for small-scale sites to reliably estimate bacteria concentrations likely due to inconsistent local sanitary sewer inputs.

Michigan, New York, Ohio, Wisconsin↗

USGS1983

Crassulacean acid metabolism in the seasonally submerged aquatic Isoetes howellii

Evidence to date is consistent with the hypothesis that the submerged aquatic Isoetes howellii Engelmann possesses crassulacean acid metabolism. Quantitative 14 C uptake studies indicate that CO 2 assimilation in both the light and dark are functions of pH and total inorganic carbon level. In both the light and dark, maximum uptake rates in 0.6 mM NaHCO 3 were double the rates in 0.3 mM NaHCO 3 . At both carbon levels there was a large drop in carbon assimilation rate between pH 6 and 8. In nature water pH and inorganic carbon level fluctuated diurnally thus complicating the determination of the contribution of light vs dark CO 2 uptake to the total carbon gain. On a sunny day between 0600 and 1200 h water chemistry changed markedly with ∼40% reduction in total carbon, ∼2 pH unit rise resulting from ∼100% depletion of free CO 2 . Under such conditions daytime deacidification in Isoetes leaves was 88% complete by noon. In contrast, on an overcast day, reduction of carbon in the water was much slower, deacidification was only 46% complete by noon and substantial malic acid levels remained in the leaves at the end of the day. Upon emergence crassulacean acid metabolism was largely lost in Isoetes leaves. Preliminary estimates suggest that under natural submerged conditions, early morning photosynthetic rates may be substantially higher than dark CO 2 uptake rates, though uptake rates throughout much of the day could be substantially lower than nightime CO 2 assimilation.

Oecologia↗