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Economic and environmental evaluations of extractable coal resources conducted by the U. S. Geological Survey

The Economic and Environmental Evaluations of Extractable Coal Resources (E4CR) project integrates economic analyses of extractable coal resources with environmental and coal quality considerations in order to better understand the contribution that coal resources can make to help meet the Nation’s future energy needs. The project utilizes coal resource information derived from the recent National Coal Resource Assessment (NCRA), National Oil and Gas Assessment (NOGA), and Coal Availability and Recoverability Studies (CARS) conducted by the U.S. Geological Survey and other State and Federal cooperating agencies. The E4CR evaluations are designed to augment economic models created by the U.S. Geological Survey CARS and NCRA projects and by the Department of Energy/Energy Information Administration (DOE/EIA). E4CR evaluations are conducted on potentially minable coal beds within selected coalfields in the United States. Emphasis is placed on coalfields containing Federally owned coal and within or adjacent to Federal lands, as shown in U.S. Geological Survey Fact Sheets 012-98, 145-99, and 011-00 (U.S. Geological Survey, 1998, 1999, 2000). Other considerations for the selection of study areas include coal quality, potential environmental impact of coal production activities and coal utilization, the potential for coalbed methane development from the coal, and projected potential for future mining. Completion dates for the E4CR studies loosely follow the schedule for analogous NOGA studies to allow for a comparison of different energy resources in similar geographic areas.

Fact Sheet↗

Heavy-Mineral Placer Potential Map of the U.S. Continental Shelf, Western and Northern Gulf of Mexico

The establishment of the Exclusive Economic Zone (EEZ) in 1983 by Presidential Proclamation opened for natural resource exploration a vast offshore frontier area contiguous to the United States and its territories. The EEZ extends from the seaward limit of state waters (3 nautical mi from shore) to 200 nautical mi offshore, and it includes the continental shelves. Within the context of the EEZ natural resource assessment effort, the purpose of this study is to delineate, on a regional basis, the potential for heavy-mineral placers on the U.S. Continental Shelf in the western and northern Gulf of Mexico from the United States-Mexico border to the Alabama-Florida state line. This map is intended to serve as a general guide for placer exploration. It shows favorable sea-floor areas for placer occurrence in water depths ranging from 0 to 100 fathoms (600 ft). The map can be used as a guide for focusing costly exploratory efforts, such as coring operations and geophysical surveys. The potential economic value of heavy-mineral placer concentrations on the U.S. Continental Shelf is a function of both geologic and economic variables. Geologic variables include the composition and concentration of the heavy-mineral assemblages and their environment of deposition. Economic variables include the current world market price of extracted metals, as well as the cost of mining, processing, and marketing the metals. These economic factors, in turn, are tempered by the nation1s socio-political climate, which determines its need for specific mineral resources at any given time.

Miscellaneous Field Studies Map↗

The zinc content of plants on the Freidensville zinc slime ponds in relation to biogeochemical prospecting

The zinc content of thirty different kinds of plants growing on slime ponds containing on the average 12.5 per cent zinc were determined by the dithizone method. The zinc content ranged from 39 p.p.m. in the fruit of the false solomon's seal (Smilacina racemosa) to 5,400 in the horsetail (Equiseteum arvense}. This latter plant varied considerably in zinc at different places on the slime ponds. The zinc contents of the aspen (Populus grandidentata}, ragweed {Ambrosia artemisiifolia), and horsetail grown on normal soils are compared to those on the slime ponds and it is recommended that the poplar and ragweed be studied further as indicators of zinc ore bodies.

Pennsylvania↗

Estimating usable resources from historical industry data

Historical production statistics are used to predict the quantity of remaining usable resources. The commodities considered are mercury, copper and its byproducts gold and silver, and petroleum; the production and discovery data are for the United States. The results of the study indicate that the cumulative return per unit of effort, herein measured as grade of metal ores and discovery rate of recoverable petroleum, is proportional to a negative power of total effort expended, herein measured as total ore mined and total exploratory wells or footage drilled. This power relationship can be extended to some limiting point (a lower ore grade or a maximum number of exploratory wells or footage), and the apparent quantity of available remaining resource at that limit can be calculated. For mercury ore of grades at and above 0.1 percent, the remaining usable resource in the United States is calculated to be 54 million kg (1,567,000 flasks). For copper ore of grades at and above 0.2 percent, the remaining usable copper resource is calculated to be 270 million metric tons (298 million short tons); remaining resources of its by-products gold and silver are calculated to be 3,656 metric tons (118 million troy ounces) and 64,676 metric tons (2,079 million troy ounces), respectively. The undiscovered recoverable crude oil resource in the conterminous United States, at 3 billion feet of additional exploratory drilling, is calculated to be nearly 37.6 billion barrels; the undiscovered recoverable petroleum resource in the Permian basin of western Texas and southeastern New Mexico, at 300 million feet of additional exploratory drilling or 50,000 additional exploratory wells, is calculated to be about 6.2 billion BOE (barrels of oil equivalent).

Economic Geology↗

The Spar Lake strata-Bound Cu-Ag deposit formed across a mixing zone between trapped natural gas and metals-bearing brine

Ore formation at the Spar Lake red bed-associated strata-bound Cu deposit took place across a mixing and reaction zone between a hot oxidized metals-transporting brine and a reservoir of “sour” (H 2 S-bearing) natural gas trapped in the host sandstones. Fluid inclusion volatile analyses have very high CH 4 concentrations (≥1 mol % in most samples), and a sample from the fringe of the deposit has between 18 and 36 mol % CH 4 . The ratio of CH 4 /CO 2 in fluid inclusions appears to vary regularly across the deposit, with the lowest CH 4 /CO 2 ratios from high-grade chalcocite-bearing ore, and the highest from the chalcopyrite-bearing fringe. The helium R/R a isotope ratios (0.23–0.98) and concentrations define a mixture between crustal and atmospheric helium. The volatiles in fluid inclusions (CH 4 , CO 2 , H 2 S, SO 2 , H 2 , H 2 O, and other organic gases) and values of f O 2 and temperature calculated from the volatiles data all show gradations across the deposit that are completely consistent with such a mixing and reaction zone. Other volatiles from the fluid inclusions (HCl, HF, 3 He, Msup>4 He, N 2 , Ar) characterize the brine and give evidence for only shallow crustal fluids with no magmatic influences. The brine entered the gas reservoir from below and along the axis of the deposit and migrated out along bedding to the southwest, northeast, and northwest. Metals-transporting brines may have been fed into the host sandstones from the East Fault, but that remains uncertain. Abundant ore-stage Fe and Mn calcite cements from the reduced fringe have δ 13 C values as low as −18.4‰, and many values less than −10‰, which indicate that significant carbonate was generated by oxidation of organic carbon from the natural gas. The zone of calcite cements with very low δ 13 C values approximately envelopes chalcocite-bearing ore. Sulfur isotope data of Cu, Pb, and Fe sulfides and barite indicate derivation of roughly half of the orebody sulfide directly from sour gas H 2 S. That sour gas H 2 S had developed in steps known from other sedimentary basins, starting with (1) bacterial sulfate reduction (BSR) of seawater sulfate having δ 34 S of about 20‰ and sequestering of the sulfide in organic matter in source rocks stratigraphically below the deposit host rocks, followed by (2) maturation of the sulfide-bearing organic matter into liquid petroleum with relatively homogeneous sulfide having δ 34 S of 5 ± 5‰, then by (3) thermal cracking of the oil to CH 4 and H 2 S with relatively homogeneous sulfide having δ 34 S closely distributed, about 6‰. The CH 4 and H 2 S migrated and were trapped in sandstones of the upper member of the Revett Formation, where they were later met by the 200°C metals-transporting brine. There was additional contribution of sulfide to ore from later thermochemical sulfate reduction (TSR) operating on sulfate δ 34 S of 20 to 29‰ in both formation waters and metals-transporting solutions. A large range of δ 34 S in sulfides resulted as the 6‰ sour gas sulfide was supplemented with varying proportions of 20 to 29‰ sulfide from TSR.

Economic Geology↗

Economics and the national oil and gas assessment: The case of onshore northern Alaska

The National Oil and Gas Assessment of undiscovered recoverable conventional oil and gas resources assigned nearly 36% of the undiscovered U.S. onshore oil resources and 28% of the commercially developable undiscovered oil resources to onshore northern Alaska. Economic screening models were applied to the geologic play assessment to estimate the commercially developable resources. This paper presents the geologic and economic assessment methodology and results; it also focuses on the robustness of estimates of the commercially developable onshore resources to changes in economic assumptions. With the economic assumptions used in the national assessment, about 60% or 6.49 billion bbl of oil of the recoverable undiscovered resources of 10.76 billion bbl of oil assessed in fields larger than 1 million bbl of oil are estimated to be commercially developable. Changes in facilities costs induced the most significant cost-related response in the commercially developable resource estimates. Price increases or cost reductions that reduce the minimum commercially developable field size to 250 million bbl from the base case size of 380 million bbl added 1 billion bbl of oil to the commercially developable resources. If, through facilities sharing or satellite-field development, the minimum commercial field size is reduced to just below 100 million bbl, estimated developable oil woul increase to 9.17 billion bbl of oil or more than 85% of the assessed recoverable oil in onshore plays.

Alaska↗

Manganese-bearing veins in southwestern Virginia

Veins carrying manganese silicates largely in the form of the manganese garnet, spessartite, occur in the crystalline schists and gneisses of Carroll and Grayson Counties, Virginia, in the southern parts of the Galax and Independence quadrangles just north of the North Carolina State line. This brief paper includes a discussion of these manganese-bearing veins which are described in a report on the Geology and Mineral resources of the Great Gossan Lead district prepared by G. W. Stose and the writer for publication by the Virginia Geological Survey

Virginia↗

A cotangent ruler for simplifying the graphic solution of problems in structural geology

The cotangent ruler is a device for measuring directly the dip of contoured surfaces, or, conversely, for constructing contours that represent planes of known dip. It greatly simplifies the graphic solution of problems in structural geology, and has several specialized applications to problems commonly encountered in mining geology and areal geologic mapping.

Economic Geology↗

Genesis of the Silsilah tin deposit, Kingdom of Saudi Arabia

The Silsilah tin deposit (lat 25 degrees 06' N, long 42 degrees 40' E) consists of a group of pervasively greisenized, flat-topped granite cupolas within a 12-km-diam ring complex. The greisens contain varying amounts of disseminated cassiterite and wolframite. Several types of quartz veins are peripheral to the greisens; some of these contain minor wolframite. The deposit is genetically associated with a highly differentiated, peraluminous alkali-feldspar granite (587 + or - 8 Ma) that is part of a mostly peralkaline, igneous ring complex intruded into Late Proterozoic, immature sandstones of the Murdama Group. We recognize four distinct phases of the peraluminous granite. Only the smallest, most highly differentiated cupolas contain significant tin greisen mineralization. Greisens developed beneath aplitic carapaces that overlie the granite and created impermeable barriers to rising volatiles. The geometry of a cupola correlates strongly with the intensity of alteration; cupolas with the smallest cross sectional areas and steepest marginal contacts have the most intensely greisenized apexes. The paragenetic sequence can be divided into five stages: pegmatite formation, locally pervasive albitization, locally pervasive greisenization and deposition of cassiterite, deposition of quartz-wolframite veins, and deposition of quartz veins with minor base metal sulfides. Pressure-corrected fluid inclusion filling temperatures indicate that the hydrothermal system generally cooled as it evolved and that the delta 18 O values of the hydrothermal quartz increased from 10.8 to 15.7 per mil. Calculated delta 18 O values of the hydrothermal fluid varied concomitantly from the pegmatite stage (delta 18 O fluid approximately 8.6ppm; T [asymp] 550 degrees C) to the greisen stage (5.4 and 5.6[ppm; T [asymp] 360 degrees C), the quartz-wolframite vein stage (6.3 and 7.5ppm; T [asymp] 390 degrees C), and the late vein stage (4.0 and 5.1ppm; T [asymp] 270 degrees C). This evolution probably reflects the admixture of generally increasing amounts of meteoric or formation water having a lower delta 18 O value into the cooling magmatic hydrothermal system. In delta 18 O -delta 18 O plots for mineral separates from fresh to altered samples of the peraluminous granite the values for quartz and feldspar conform to a steep, positive-sloped disequilibrium trend that indicates interaction with high 18 O hydrothermal fluid, mirrored by a negative-sloped disequilibrium trend for quartz and mica. These complementary trends suggest strongly that individual granite cupolas were essentially closed systems during alteration. To our knowledge, this is the first oxygen isotope demonstration of a closed-system, hydrothermal metal deposit. The sandstone country rock has whole-rock delta 18 O values of 12.4 + or - 2.0 per mil. The highest values (>13ppm) form a approximately 3-km-wide high delta 18 O annulus immediately peripheral to the ring complex. The data suggest that the country rocks were pervasively exchanged with an outward-migrating, high delta 18 O fluid moving down a temperature gradient. This fluid was probably formation water that flowed radially inward toward the pluton at a deeper level, forming a largely horizontal, unicellular flow system that had fluid-flow lines nearly vertical next to the intrusion, and directed upward and outward at higher levels. Low delta 18 O fluids that formed quartz associated with the tin-tungsten mineralization and later veins are inferred to be the result of a subsequent and distinct phase of the hydrothermal system. Almost all the geologic processes necessary for the formation of an economically viable tin deposit occurred at Silsilah, but the lack of a strong localizing mechanism for cassiterite mineralization resulted in an economically marginal deposit. If the greisenized cupolas had been vertically stacked, as are the intrusions and ore zones in Climax-type molybdenum deposits, or if the mineralizing fluids had been channeled into veins, as in the tin deposits in Cornwall, England, a higher grade deposit might have formed. The generally closed-system behavior of the hydrothermal system at Silsilah may have prevented additional scavenging of metals and the formation of a larger, richer deposit.

Economic Geology↗

Geology of the Ivanhoe Hg-Au district, northern Nevada: Influence of Miocene volcanism, lakes, and active faulting on epithermal mineralization

The mercury-gold deposits of the Ivanhoe mining district in northern Nevada formed when middle Miocene rhyolitic volcanism and high-angle faulting disrupted a shallow lacustrine environment. Sinter and replacement mercury deposits formed at and near the paleosurface, and disseminated gold deposits and high-grade gold-silver veins formed beneath the hot spring deposits. The lacustrine environment provided abundant meteoric water; the rhyolites heated the water; and the faults, flow units, and lakebeds provided fluid pathways for the hydrothermal fluids. A shallow lake began to develop in the Ivanhoe area about 16.5 Ma. The lake progressively expanded and covered the entire area with fine-grained lacustrine sediments. Lacustrine sedimentation continued to at least 14.4 Ma, and periodic fluctuations in the size and extent of the lake may have been responses to both climate and nearby volcanism . The eruption of rhyolite and andesite flows and domes periodically disrupted the lacustrine environment and produced interfingered flows and lake sediments. The major pulse of rhyolitic volcanism took place between 15.16 ± 0.05 and 14.92 ± 0.05 Ma. High-angle faulting began in the basement about 15.2 Ma, penetrated to and disrupted the paleosurface after 15.10 ± 0.06 Ma, and largely ceased by 14.92 ± 0.05 Ma. Ground motion related to both faulting and volcanism created debris flows and soft-sediment deformation in the lakebeds. Mercury-gold mineralization was coeval with rhyolite volcanism and high-angle faulting , and it took place about 15.2 to 14.9 Ma. At and near the paleosurface, hydrothermal fluids migrated through tuffaceous sediments above relatively impermeable volcanic and Paleozoic units, creating chalcedonic, cinnabar-bearing replacement bodies and sinters. Disseminated gold was deposited in sedimentary and volcanic rocks beneath the mercury deposits, although the hydrologic path between the two ore types is unclear. Higher-grade gold-silver deposits formed in massive rhyolites and Paleozoic quartzites at deeper levels, and these mineralized zones possibly represent the feeder zones for the higher-level deposits. Fluctuations in the ground-water table locally produced hydrothermal oxidation of the near-surface mercury and disseminated gold deposits. The locus of mineralization shifted with time, moving south and east from its inception point in the west-central part of the district . Thus, although mineralization in the district took place during a span of 300,000 years, the duration of mineralization at any one place probably was much shorter. The low-sulfidation deposits of the Ivanhoe district formed at the same time and under similar conditions as those in the nearby Midas district , 15 km to the northwest, which includes the large, high-grade Ken Snyder gold-silver epithermal vein deposit. The exposures in the Ivanhoe district are interpreted to represent the near-surface example of the paleosurface that originally was present above the Midas mineralizing system. The resulting combined Ivanhoe -Midas model provides an exploration guide for epithermal deposits in similar geologic environments in northern Nevada .

Economic Geology↗

Geology and land use in the western part of the Gulf Coast coal-bearing region

This map series is a compilation of the outcrop geology in the U.S. Gulf Coast coal region. The maps show the regional geologic setting for primary coal occurrences and detailed geology and historic mining areas. The CD contains ESRI ArcView SHP files of cities, urban areas, historical mines (points and polygons), counties, current mines, 1:100,000 quadrangle outlines of the study area, fossil fuel powerplants, nuclear powerplants, political boundaries, federally managed lands, roads and railroads in the study area, hydrology in the study area (polygons and arcs), geology nomenclature breaks, geological features (faults), and geology. ArcExplorer is included on the CD.

Bureau of Economic Geology (Texas), Miscellaneous ↗

The data of lead isotope geology related to problems of Ore Genesis

Searching questions about the origins of ore deposits have been asked for many years. Where do ore fluids originate-within the crust, or deeper? Can specific sources of ore metals be identified? When were ores deposited? How long did mineralization continue? What was the rate and paragenesis of deposition? Which deposits are cogenetic, and what metallogenetic provinces do they define? Isotope analyses of lead from rocks and ores provide a new tool for attacking such problems of ore genesis . About two thousand such analyses now available from more than 20 laboratories have been compiled and studied for this purpose. The data now available suggest partial answers to some questions and serve to define other, new problems , not previously recognized. Their greatest import, however, is to illustrate the potential future significance of lead - isotope studies. Ore - lead , as shown two decades ago, ranges widely in isotopic composition. Recent studies show that traces of lead in ordinary rocks of the earth's crust exhibit apparently similar variations. All these variations are attributable primarily to mixing of old lead with accumulations of new radiogenic lead from decay of radioactive uranium and thorium. Each sample of lead preserves in its isotopic composition a record of its own mixing history: a composite record of the time this lead was in different environments, its past associations with uranium and thorium, and the geochemical processes that moved it from place to place. Integrated study of all these variables will throw light on many difficult problems of ore genesis when adequate techniques are developed. Progress will be slow, however, until more accurate lead - isotope analyses can be made at lower cost and more objective criteria developed for interpreting measured isotopic compositions in terms of geologic history.

Economic Geology↗

Technique for the extraction and partial chemical analysis of fluid-filled inclusions from minerals

A method has been developed for the extraction and limited chemical analysis of the materials in solution in the fluid from the very minute fluid-filled inclusions such as commonly occur in whitish or milky quartz. The method may also be applied, with some reservations, to a variety of other minerals. As the amounts of substances in the fluid are small compared with possible contaminants, great care is needed in sample purification and cleaning; an electrolytic method has been found to be the only satisfactory final cleaning step. Following this, the inclusions are opened by ball milling of the cleaned sample, with deionized water, in an alumina ball mill using alumina grinding media. The ions present in the resultant slurry are separated from the ground quartz by electrodialysis and analyzed. Other methods, such as the decrepitation of a sample in an absorption train, are used to estimate the amount of H2O and CO2 in the inclusions. The most significant part of the analytical work has been to determine the ratios between the alkali metals. The materials in solution in the fluid-filled inclusions from 11 samples of quartz have been analyzed by the ball milling-electrodialysis method. Although there are large differences between samples, the average weights of the alkali metal ions found, for all samples, in milligrams per kilogram of quartz, are: Li+-0.92, Na+-99, K+-133, Rb+-0.45, Cs+-0.38 (atomic ratios, in the same sequence: 0.03/1.00/0.79/0.001/0.0007). In addition, 27 to 193 milligrams of CI", and 5 to 140 milligrams of SOr were found, per kilogram of quartz. H2O and COa were determined on only one sample. Six of the samples were from gold-quartz veins in the Grass Valley district, California. In these six the Na+/K+ ratios were all very similar, but the amounts of Li+, Rb+ and Cs+ found varied greatly. Although there are serious limitations to this and to all other techniques developed, it is felt that the results presented are sufficiently encouraging to warrant further study and possible application to specific geologic problems, such as the identification of epochs of quartz deposition

Economic Geology↗

Book review: New concepts and discoveries: the Geological Society of Nevada 2015 Symposium Proceedings

The Nevada Geological Society has a long history of convening meetings and workshops focused on the geology and metallogeny of the western United States relevant to the mineral exploration and mining community across the Great Basin. One outgrowth of the Geological Society of Nevada’s 2015 Symposium is a two-volume set, edited by W.M. Pennell and L.J. Garside, entitled New Concepts and Discoveries . The symposium was held in Sparks, Nevada, May 14–23, 2015, with more than 1,000 attendees, 59 talks in 10 thematic sessions, 7 field trips, and 10 short courses, all focused on serving the geologic, exploration, and mining community. The attractively produced, hardbound, two-volume set includes a CD-ROM containing all the manuscripts as well as numerous abstracts from presentations arranged by the thematic session in which they were presented. The papers range from detailed case study descriptions of individual deposits to important syntheses covering the geologic evolution and resulting metallogeny of the Great Basin and beyond.

Economic Geology↗