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Tracking diagenetic alteration of magnetic susceptibility in thrust ridge and slope basin sediments of the Cascadia margin (ODP Sites 1249 and 1252; IODP Site U1325)

We investigated sediment core records from the Cascadia Margin (Ocean Drilling Program Sites 1249 and 1252 at Hydrate Ridge; Integrated Ocean Drilling Program Site U1325 offshore Vancouver Island) using a Zr/Rb heavy mineral proxy from X-ray fluorescence (XRF) core scanning to identify intervals of primary detrital magnetic susceptibility (κ) and predict intervals where diagenesis caused magnetite dissolution by hydrogen sulfide. We also measured total sulfur (TS) content, grain size distributions, total organic carbon (TOC) content, and the magnetic mineral assemblage to further constrain the role of diagenesis on κ. Understanding how κ can be used to better characterize the varied effects of detrital and diagenetic signals in marine settings is important for understanding biogeochemical cycling and records of paleoenvironmental change. The upper 100 m of slope basin Site 1252 contains multiple intervals (> 90 m total) of decreased κ correlated with elevated TS content, consistent with dissolution of magnetite and precipitation of pyrite, iron monosulfides, and/or elemental sulfur. Similarly at the other slope basin site, Site U1325, κ is lower and TS is elevated in the interval between 24 and 51 mbsf, due to sulfide formation. At both slope basin sites, these low κ intervals correspond with high TOC, suggesting the possibility that organoclastic sulfate reduction (OSR) is likely a major driver of diagenetic alteration of κ at these sites. High TS:TOC ratios at Site U1325 suggests anaerobic oxidation of methane (AOM) during sulfate-methane transition zone (SMTZ) migration may have contributed to alteration of κ. In contrast, within the upper 90 m of Site 1249, a methane seep site at the summit of Hydrate Ridge, κ is almost entirely altered by diagenetic processes, with much of the low κ explained by a high degree of iron sulfide formation, while some intervals are affected by precipitation of magnetic iron sulfides that maintain or even increase κ. The presence of abundant methane seepage and gas hydrate as well as chemosynthetic seafloor fauna at this site, suggests that sulfide is released to the water column and AOM, rather than OSR, drives diagenetic alteration of κ at this site. Overall, the slope basin sites show episodic variation of κ that is influenced by TOC content, likely driven by changes in marine primary productivity and sedimentation rate, while the seep site shows consistently altered κ with lower TS content and no correlation with TOC. Methane seep environments likely experience loss of hydrogen sulfide to the water column and oxidation of hydrogen sulfide by seafloor seep fauna, which limits the amount of solid phase sulfur (pyrite, iron monosulfides, elemental sulfur) that can be precipitated within the sediments. In contrast, the migration of a buried SMTZ at slope basin sites results in enhanced sulfur precipitation within the sediments. This integrated magnetic and geochemical approach reveals the diagenetic production pathway and residence time of sulfide with the sediment column ultimately controls the style and degree of diagenetic loss of κ in marine sediments. This approach works best in environments with unaltered reference intervals/sites, consistent magnetic mineralogy, and clay-to-silt grain sizes.

Cascadia margin, Pacific Ocean

A 481 m-high landslide-tsunami in a cruise ship-frequented Alaska fjord

Early in the morning of 10 August 2025, a >64 × 10 6 –cubic meter landslide struck Tracy Arm fjord in Alaska. The landslide was preconditioned by glacial retreat caused by climate change. The resulting 481-meter runup megatsunami followed an initial 100-meter-high breaking wave traveling at >70 meters per second. The landslide was preceded by several days of microseismicity, which increased in rate and magnitude until ~1 hour before failure. The landslide produced globally observed long-period seismic waves equivalent in size to a moment magnitude 5.4 earthquake. A long-period (~66 second) global seismic signal, produced by a landslide-induced seiche trapped within the fjord, persisted for up to 36 hours, the second time a days-long seiche had thus been observed. With fjord regions increasingly visited by cruise ships, and climate change making similar events more likely, this unanticipated, near-miss event highlights the growing risk from landslides and tsunamis in coastal environments.

Alaska

Increasing artificial light at night enhances salmonid predator foraging efficiency in an urbanized lake

Artificial light at night (ALAN) poses a threat to ecosystems globally. It includes both direct and indirect light, or skyglow, which occurs when ALAN scatters in the atmosphere, extending beyond its original source. We analyzed ALAN trends in Lake Washington, WA, from 2014 to 2023 using Visible Infrared Imaging Radiometer Suite (VIIRS) nighttime light measurements, evaluated the relationship between in situ and satellite measurements, and modeled predator search volumes for a juvenile salmon predator, cutthroat trout ( Oncorhynchus clarki ), as a function of ambient light and turbidity conditions. Open water regions experienced significant increases in ALAN, while nearshore areas primarily showed no or negative trends, revealing the role of skyglow in shaping open water light environments. Using a visual foraging model for cutthroat trout, we found that juvenile salmon at the shallow southern pelagic site experienced light 28 times brighter, resulting in a 168% greater predation vulnerability than those at the northern site. In the Ship Canal, a narrow corridor for outmigrating salmon, predator search volumes were 249% higher than at the southern site. These contrasts in predation vulnerability demonstrate how local conditions influence predator–prey dynamics and provide critical insight for targeting mitigation of both nearshore and distant light sources.

Washington

Teach me how to pycap: A high-capacity well decision support tool using analytical solutions in Python

Regulatory agencies in humid temperate environments rely on timely evaluations of streamflow depletion and drawdown to protect aquatic ecosystems and existing water users. Numerical models offer detailed insights, but their complexity and time demands often preclude their practical use in rapid decision-making. We present pycap-dss, an open-source Python package that implements a suite of analytical solutions for estimating streamflow depletion and drawdown. The tool supports superposition of multiple wells and time-varying pumping, enabling cumulative impact assessments in situations with multiple wells and streams. The software is modular and extensible, allowing users to interchange solutions or add new analytical methods. A YAML-based configuration supports batch processing of multiple wells, and an optional AnalysisProject class facilitates integration with regulatory workflows. Rigorous unit and regression testing ensures computational reliability, and continuous integration supports ongoing development. We demonstrate deterministic examples of drawdown where multiple solutions are readily compared and streamflow depletion with multiple wells in the Central Sands region of Wisconsin. We also show the value of Monte Carlo analyses of streamflow depletion in the same Central Sands example, leveraging computational efficiency to evaluate the uncertainty of individual and cumulative streamflow depletion calculations from over 200 high-capacity wells.

Wisconsin

A soil velocity model for improved ground motion simulations in the U. S. Pacific Northwest

Near-surface seismic velocity structure may significantly impact the intensity, duration, and frequency content of ground shaking during an earthquake. In this study, we compile 649 shear wave velocity (Vs) profiles throughout the U.S. Pacific Northwest and southern British Columbia (PNW) and use these measured profiles to develop a representative soil velocity model for four major Holocene soil provinces: Puget Lowlands, Willamette Valley, fill and alluvium, and `other' soils. The resulting soil velocity model shows good agreement to measured data for a wide range of site conditions, with variability between different geologic domains reflecting fundamental differences in depositional environments. We then show that using this regional soil velocity model in simulations of the 2001 M6.8 Nisqually, Washington earthquake improves the fit to observed high-frequency (≥ 0.5 Hz) ground motions in the Puget Sound region compared to simulations that do not incorporate shallow (≤ 200 m) seismic velocity structure. Overall, this work shows that incorporating localized soil velocity profiles into seismic velocity models is important for accurately estimating high-frequency ground motion and regional seismic hazard in earthquake simulations. Future earthquake simulations and hazard studies in the PNW could incorporate these soil velocity profiles to capture the region's distinct site response characteristics.

Washington

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming

Geotechnical description of four Mississippi Delta soil borings

The submerged portion of the Mississippi Delta complex forms an ideal natural laboratory to study the effects of rapid deposition. One of the most obvious of these effects is the mass movements of sediments. Slump and slide signatures, mudflow characteristics, and evidence for creep are all found in abundance on the delta platform. These types of features have been studied by Colemen and Wright (1974) with regard to form and by Garrison (1974) with regard to their spatial distribution. Assembling these authors' findings, it is clear that the entire offshore zone contiguous with the Mississippi River is a myriad of geological action. This situation is indeed stimulating to the sedimentologist, yet it represents a nightmare to the foundation engineer. Emplacing offshore structures in such an environment is a most difficult task, particularly since the high degree of local variability dictates that each case must be handled separately. It is under these circumstances that a marriage between geology and engineering is most fruitful, for determining the relationships between the sedimentological processes and the engineering properties is satisfying to parties from both disciplines. This, then, is the underlying objective of the Mississippi Delta research project. By investigating the instability in a geologic sense, it is hoped that many of the engineering problems will become more soluble and that extrapolation and prediction will become more realistic.

Mississippi Delta

Streamflow, base-flow, and precipitation trends and simulated effects of groundwater withdrawals from the North Fork Red River aquifer on base flows upgradient from Lake Altus, western Oklahoma, 1980–2022

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used five scenarios created from a previously published numerical groundwater-flow model (1980–2013) and historical streamflow records (1980–2022) to investigate the relation between groundwater withdrawals from the North Fork Red River aquifer and inflows to Lake Altus from the North Fork Red River in western Oklahoma. The five scenarios were (1) a scaled-equal-proportionate-share (EPS) groundwater-withdrawal scenario, (2) a study-area-scaled-reported groundwater-withdrawal scenario, (3) a zonal-scaled-reported groundwater-withdrawal scenario, (4) a historical drought-threshold scenario, and (5) a base-flow and evapotranspiration depletion scenario. For the scaled-EPS groundwater-withdrawal scenario, EPS groundwater withdrawals were often much higher than reported groundwater withdrawals and greatly decreased base flows for most scale factors. For the study-area-scaled-reported groundwater-withdrawal scenario, base flows were reduced more but by smaller percentages during wet periods than during dry periods when scaling simulated reported groundwater withdrawals. For the zonal-scaled-reported groundwater-withdrawal scenario, scaling simulated reported groundwater withdrawals within selected zones with more groundwater withdrawals did not always affect base flows more than scaling reported groundwater withdrawals within zones with less groundwater withdrawals. For the historical drought-threshold scenario, curtailing groundwater withdrawals at the drought thresholds increased annual base flows to Lake Altus by about 1,169 to 3,665 acre-feet. For the base-flow and evapotranspiration depletion scenario, the distance between a groundwater well and a stream was a major factor affecting base flow to the North Fork Red River when increasing groundwater withdrawals; however, spatially variable hydrologic properties and saturated-zone evapotranspiration could also affect the relation between base flows and groundwater withdrawals.

Oklahoma

Satellite interferometry landslide detection and preliminary tsunamigenic plausibility assessment in Prince William Sound, southcentral Alaska

Regional mapping of actively deforming landslides, including measurements of landslide velocity, is integral for hazard assessments in paraglacial environments. These inventories are also critical for describing the potential impacts that the warming effects of climate change have on slope instability in mountainous and cryospheric terrain. The objective of this study is to identify slow-moving landslides in the Prince William Sound region, southcentral Alaska, United States, which has had rapid deglaciation since the mid-1800s, and assess their tsunamigenic plausibility. We use an automated time series persistent scatterer interferometric synthetic aperture radar processing method with 7 years of Sentinel-1 data (2016–22) to identify 43 slow-moving slopes with average velocities ranging from approximately 0.2 to 21 millimeters per year. Landslide presence is confirmed using aerial imagery and previous landslide inventory records. We assess the tsunamigenic plausibility of the landslides using empirically derived estimates of landslide mobility based on modeled landslide volumes. Of the identified landslides, our preliminary analysis suggests that 11 have tsunamigenic potential if they were to fail rapidly and catastrophically. Although our estimate of tsunamigenic plausibility is preliminary and can be refined with additional observations and analyses, it can be used to prioritize ongoing and future hazard assessment, surveillance, and research efforts.

Alaska

Aboveground carbon stocks across a hydrological gradient: Ghost forests to non-tidal freshwater forested wetlands

Upper estuarine forested wetlands (UEFWs) play an important role in the sequestration of atmospheric carbon (C), which is facilitated by their position at the boundary of terrestrial and maritime environments but threatened by sea level rise. This study assessed the change in aboveground C stocks along the estuarine–riverine hydrogeomorphic gradient spanning salt-impacted freshwater tidal forested wetlands to freshwater forested wetlands in seasonally tidal and nontidal landscape positions. Standing stocks of C in forested wetlands were measured along two major coastal river systems, the Winyah Bay in South Carolina and the Savannah River in Georgia (USA), replicating and expanding a previous study to allow the assessment of change over time. Aboveground C stocks on these systems averaged 172.9 Mg C ha −1 , comparable to those found in UEFWs across the globe and distinct from the terrestrial forested ecosystems they are often considered to be a part of during large-scale C inventory efforts. Groundwater salinity conditions as low as 1.3 ppt were observed in conjunction with losses of aboveground C. When viewed in context alongside expected sea level rise and corresponding saltwater intrusion estimates, these data suggest a marked decrease in aboveground C stocks in forested wetlands situated in and around tidal estuaries.

Georgia, South Carolina

Simulated effects of future water availability and protected species habitat in a perennial wetland, Santa Barbara County, California

This study evaluates the potential water availability in Barka Slough and the effects of changing hydrological conditions on the aquatic habitat of five protected species. Barka Slough is a historically perennial wetland at the downstream western end of the San Antonio Creek Valley watershed (SACVW). A previously published hydrologic model of the SACVW for 1948–2018 was extended to include 2019–2021 and then modified to simulate the future years of 2022–2051. Two models simulating the future years of 2022–2051 were constructed, each with different climate inputs: (1) a repeated historical climate and (2) a 2070-centered Drier Extreme Warming climate (2070 DEW). The model with the 2070 DEW climate had warmer temperatures and an increase in average annual precipitation driven by larger, albeit more infrequent, precipitation events than the model with the historical climate. Simulated groundwater pumpage resulted in cumulative groundwater storage depletion and groundwater-level decline in Barka Slough in both future models. The simulations indicate that Barka Slough may transition from a perennial to an ephemeral wetland. Streamflow, stream disconnection, and depth to groundwater are key habitat metrics for federally listed species in Barka Slough. Future seasonal conditions for each metric are more likely to affect federally listed species’ habitats under 2070 DEW climatic conditions. Future seasonal streamflow volume may negatively impact unarmored threespine stickleback ( Gasterosteus aculeatus williamsoni ) and tidewater goby ( Eucyclogobis newberryi) habitats. Future seasonal stream disconnection may negatively impact the unarmored threespine stickleback habitat. Future groundwater-level decline may negatively impact Gambel’s watercress ( Nasturtium gambelii ) and La Graciosa thistle ( Cirsium scariosum var. loncholepis ) habitats and could influence the ability to use Barka Slough as a restoration or reintroduction site for these species. Results from this study can be used to inform water management decisions to sustain future groundwater availability in the SACVW.

California

Compositional and structural mapping of Northwest Africa 15507 angrite

Angrite meteorites represent interesting sampling of planetary crustal environments. Quench-textured angrites with strong crystal zoning originated from the shallow surface region, with evidence of reducing conditions during solidification. Plutonic angrites have more coarse-grained igneous and metamorphic textures with comparatively less zoning and are interpreted as having equilibrated at greater depth. Plutonic angrites contain the minerals magnetite Fe 3 O 4 comprised of Fe 2+ and Fe 3+ , and rhönite, where Fe 3+ is required by inspection of mineral stoichiometry. NWA 15507 is a plutonic angrite with a microgabbroic texture (mean grainsize ∼1.4 mm) composed of zoned Al-Ti-augite, Ca-bearing olivine, anorthite, with accessory kirschsteinite, rhönite, hercynite, low-Ni kamacite, merrillite, Ti-free magnetite and troilite [ 1 ]. Rhönite analyzed by electron-probe microanalysis (EPMA) has the formula Ca 2.04 (Mg 0.32 Fe 2+ 4.25 Fe 3+ 0.47 Ti 0.33 Al 0.61 )(Si 3.74 Al 2.26 )O 20 , where Fe 3+ was estimated by stoichiometric analysis. During preliminary cathodoluminescence (CL) analysis, complex subgrain and oscillatory zoning was observed in the anorthite. In this study we use a combined approach of electron probe microanalysis (EPMA), cathodoluminescence (CL), electron-backscatter diffraction (EBSD), and laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to further investigate the anorthite and distribution of Fe 3+ in NWA 15507.

Microscopy and Microanalysis

In-situ geochronology using LA-ICP-MS/MS: Application of the Lu-Hf system in carbonate, apatite and fluorite

Geochronology is a fundamental tool for reconstructing earth history and constraining the timing of ore deposit formation. Traditionally, U-rich minerals like zircon, titanite, monazite and apatite have been analysed to determine the timing of mineralization and alteration events. However, not all deposits or alteration assemblages contain these minerals, and the U-Pb system can be disturbed due to open system behaviour. We present a methodology for obtaining in-situ Lu-Hf dates from various minerals to demonstrate the potential for dating ore deposits that lack U-rich minerals. Carbonate, apatite and fluorite minerals from different tectonic settings and geological environments were analysed. We acquired Lu-Hf and REE (rare earth element) data from carbonate minerals from a carbonatite orebody and dike samples from the Mountain Pass REE carbonatite deposit in California, USA. We also tested a ‘double-dating’ method, where U-Th-Pb dates and Lu-Hf dates were obtained from the same analysis of apatite from rocks in the Michigan’s Great Lakes Tectonic Zone. Preliminary results for Lu-Hf dating of fluorite from carbonatite rocks in the Lemitar Mountains of New Mexico are also included. The analytical methodology shows promising results in each of these cases where there is sufficient parent Lu and U and measurable daughter Hf and Pb respectively.

Conference Paper

Groundwater tracing used to delineate recharge areas and map karst groundwater pathways for subterranean streams at Oregon Caves National Monument and Preserve

Oregon Caves National Monument and Preserve in southwestern Oregon is a 4,554-​acre area managed by the National Park Service that is home to several cave systems, including Oregon Caves, which is the longest cave in Oregon, with 3.03 miles of mapped passages. Because of the interconnected nature of karst hydrologic systems, it is critical to understand the areas that can influence water quality and quantity in karst environments. Toward this goal, dye tracing was conducted by the U.S. Geological Survey from 2021 to 2024 to better understand the pathways that karst groundwater follows at Oregon Caves National Monument and Preserve and to delineate recharge areas for two caves, Oregon Caves and Cave Next Door. During the project, eight dye injections were conducted, delineating a 0.51-​square-​mile recharge area for Oregon Caves and a 0.69-​square-​mile recharge area for Cave Next Door. Additionally, the study helped to identify three resurgences associated with Oregon Caves that were previously unknown and showed that the recharge areas for the two caves were distinct from one another. The dye traces also illuminated some unique recharge characteristics of the karst at Oregon Caves, including a high variance in karst groundwater velocities, retention within the karst aquifers, and a significant diffuse-​flow component.

Oregon

Morphodynamics of snow barchans at Concordia Station, Antarctica

Barchans are crescent-shaped dunes that form and migrate under unimodal wind regimes in areas of low sediment availability. While sand barchan morphodynamics has been extensively studied, snow barchans remain poorly documented. Here, using hourly time-series images taken near Concordia Station, Antarctica, we measure the sizes (lengths 0.3 m to 13 m, widths 0.4 m to 7.5 m) and migration rates (0.13 m h −1 to 3.5 m h −1 ) of 44 populations of snow barchans during 2017–2022. We compare this dataset with established height–velocity and length-width relationships for sand barchans in both air and water. Our results show that snow barchans follow the same scaling as sand barchans, allowing us to estimate a characteristic sintering (bonding of snow particles) time of about one day. This sintering process limits the size of snow barchans when active, reduces their aspect ratios, and, once wind falls below the transport threshold, explains their preservation over a few years. During wind events, migrating barchans are too small to maintain their shape and orientation, making them highly responsive to fluctuations in wind direction. Thus, studying snow barchans improves understanding of an elementary bedform encountered in multiple environments and also of the surface properties of snow on different timescales, offering insights into snow accumulation and wind-blown snow in ice cores.

Geomorphica

Framework for mapping liquefaction hazard–Targeted design ground motions

Liquefaction-induced ground failure poses substantial challenges to geotechnical earthquake engineering design. Current approaches for designing against liquefaction hazards, as specified in most seismic provisions, focus on estimating a liquefaction factor of safety ( 𝐹⁢𝑆𝐿 ) and typically characterize earthquake loading using design parameters based on probabilistic or deterministic ground motion levels. Because 𝐹⁢𝑆𝐿 is estimated deterministically, this basis of design neglects considerable uncertainties for estimating liquefaction triggering and its consequences and results in a lack of liquefaction-specific design criteria, particularly as structural design has advanced toward risk-targeted performance objectives. This study presents a framework for developing liquefaction-targeted design criteria based on a minimum acceptable return period of liquefaction, informed by probabilistic liquefaction hazard analysis (PLHA). PLHA quantifies annualized rates of liquefaction by considering contributions from (1) the full ground-motion probability space, and (2) uncertainties in liquefaction triggering using probabilistic models. PLHA is used in this study to characterize the current, effective return periods of 𝐹⁢𝑆𝐿 ( 𝑇𝑅,𝐹⁢𝑆 ) obtained from conventional liquefaction hazard analysis (CLHA) using uniform-hazard ground motions. 𝑇𝑅,𝐹⁢𝑆 is evaluated in a parametric study of nearly 100 sites throughout the conterminous United States. The results indicate large geographic variations in acceptable liquefaction hazard levels, with implied 𝑇𝑅,𝐹⁢𝑆 ranging between approximately 1,000 to 3,000 years. To address these inconsistencies without the computational demands of full PLHA, a framework is proposed for developing a liquefaction-targeted design peak ground acceleration, 𝑃⁢𝐺⁢𝐴𝐿 , for use in liquefaction models that result in consistent liquefaction design levels across all geographic locations. The mapped 𝑃⁢𝐺⁢𝐴𝐿 is shown to be somewhat sensitive to site-specific properties, and adjustment factors are developed and presented. The proposed 𝑃⁢𝐺⁢𝐴𝐿 mapping procedure produces 𝐹⁢𝑆𝐿 estimates that are consistent with those obtained from full PLHA at a target 𝑇𝑅,𝐹⁢𝑆 , providing a promising roadmap to incorporating PLHA concepts into current liquefaction design methods.

Journal of Geotechnical and Geoenvironmental Engin

Per- and polyfluoroalkyl substances in waters associated with oil and gas development in the Denver Basin

Use of per- and polyfluoroalkyl substances (PFAS) in the petroleum industry could be a cause for concern due to the large volumes of produced water (PW) generated during oil and gas extraction, the reuse of these wastes in water-stressed regions, and adverse health outcomes related to PFAS exposures. However, PW PFAS characterization is nearly absent in the literature, and hydraulic fracturing (HF) chemical disclosures often omit the identities of additives as proprietary. Here we evaluate PFAS in PW samples from three petroleum wells in the Denver Basin during their first year of production. Total concentrations of targeted PFAS (Σ 40 PFAS) were < 35 ng/L in PW samples, with short-chain PFAS like perfluorobutanoic acid persisting throughout the sampled duration. Analysis of freshwater inputs for hydraulic fracturing (Σ 40 PFAS ~ 113 ng/L) and mixed fracture fluid (Σ 40 PFAS ~ 69 ng/L) indicated much of the targeted PFAS content was derived from the input water, and not from HF additives, however samples subjected to oxidation indicated the presence of PFAS precursors that would not be detected by targeted analysis. This study highlights that while PFAS content is low in the studied PWs, the potential for redistribution of PFAS in the environment may be a consideration for reuse applications.

Colorado, Nebraska, Wyoming

An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York