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Occurrence of selenium and mercury in surface water, Wind River Indian Reservation, Wyoming, 1995

Surface-water samples for chemical analyses were collected during May and August 1995 from 13 sites in an irrigated area of the Wind River Federal Irrigation Project, Wind River Indian Reservation, Wyoming. Sites included irrigation drains, ponds, and streams in an irrigated area partially underlain by seleniferous geologic materials described as having the potential to support vegetation that may be toxic to animals. Samples were analyzed for dissolved selenium, mercury, and other inorganic constituents. The study was done in cooperation with the Shoshone Tribe and the Northern Arapaho Tribe. Six samples analyzed from the May sampling period had dissolved selenium concentrations greater than the aquatic-life chronic criterion of 5 μg/L (micrograms per liter) established by the U.S. Environmental Protection Agency (USEPA). The largest dissolved selenium concentration (49 μg/L) exceeded the aquatic-life acute criterion of 20 μg/L established by the USEPA. Selenium concentrations in all 12 samples collected during the August sampling period were less than the laboratory minimum reporting level of 5 μg/L. The Goose Pond Drain site was dry in August. The dissolved solids concentrations were larger in samples collected in May than in August from all but two sites. The large dissolved selenium concentrations in the May samples, collected prior to the start of the irrigation season, were associated with large dissolved solids concentrations. Dissolved mercury concentrations were less than the minimum reporting level of 0.1 jig/L for 24 of the 25 samples collected during May and August. One sample collected in May had a concentration of 0.3 μg/L. This concentration was less than the aquatic-life acute criterion of 2.4 μg/L for mercury established by the USEPA.

Wyoming

Water-resources activities of the U.S. Geological Survey in Utah, October 1, 1993, to September 30, 1994

This report contains summaries of the progress of water-resources studies in Utah by the U.S. Geological Survey, Water Resources Division, Utah District, from October 1, 1993, to September 30, 1994. The water-resources program in Utah during this period consisted of 21 projects; a discussion of each project is presented in the main body of this report. The following sections outline the origin of the U.S. Geological Survey, the basic mission of the Water Resources Division, the organizational structure of the Utah District, office addresses of the Utah District, the distribution of District funding in terms of source of funds and type of activity funded, and the agencies with which the District cooperates. The last part of the introduction is a list of reports produced by the District from October 1993 to September 1994.

Open-File Report

Water-surface elevations for the high tide of December 15, 1977, in the Puget Sound region, Washington

An unusually high oceanic tide on December 15, 1977, caused flooding of lowlying, nearshore parts of western Washington, including several areas in the Puget Sound region. At Seattle, the December 15 high tide of 14.8 feet above MLLW (mean lower low water datum; 8.55 feet above the National Geodetic Vertical Daltum of 1929, or NGVD) was 0.1 foot higher than the 100-year high tide. At Neah Bay, near the western end of the Straits of Juan de Fuca, however, the high tide of 8.77 feet MLLW (4.55 feet NGVD) on that date was 3.2 feet lower than the 100-year high tide. This study has identified the observed December 15 high-tide elevations at many locations in the Puget Sound region. The observed high tide then was much higher than predicted in most of the Puget Sound region, primarily as the result of a very low barametric pressure. Little damage from wind waves was reported. Elevation profiles for the predicted and observed high tides on December 15 and for several other selected tide levels indicate an increase in the maximum height in the inland direction, except near Port Angeles, and show abrupt changes in tidal elevations at three constrictions - Admiralty Inlet, Tacoma Narrows, and Deception Pass. (USGS)

Water-Resources Investigations Report

Methods for estimating streamflow at mountain fronts in southern New Mexico

The infiltration of streamflow is potential recharge to alluvial-basin aquifers at or near mountain fronts in southern New Mexico. Data for 13 streamflow-gaging stations were used to determine a relation between mean annual stream- flow and basin and climatic conditions. Regression analysis was used to develop an equation that can be used to estimate mean annual streamflow on the basis of drainage areas and mean annual precipi- tation. The average standard error of estimate for this equation is 46 percent. Regression analysis also was used to develop an equation to estimate mean annual streamflow on the basis of active- channel width. Measurements of the width of active channels were determined for 6 of the 13 gaging stations. The average standard error of estimate for this relation is 29 percent. Stream- flow estimates made using a regression equation based on channel geometry are considered more reliable than estimates made from an equation based on regional relations of basin and climatic conditions. The sample size used to develop these relations was small, however, and the reported standard error of estimate may not represent that of the entire population. Active-channel-width measurements were made at 23 ungaged sites along the Rio Grande upstream from Elephant Butte Reservoir. Data for additional sites would be needed for a more comprehensive assessment of mean annual streamflow in southern New Mexico.

Water-Resources Investigations Report

Nationwide summary of US Geological Survey regional regression equations for estimating magnitude and frequency of floods for ungaged sites, 1993

For many years, the U.S. Geological Survey (USGS) has been involved in the development of regional regression equations for estimating flood magnitude and frequency at ungaged sites. These regression equations are used to transfer flood characteristics from gaged to ungaged sites through the use of watershed and climatic characteristics as explanatory or predictor variables. Generally these equations have been developed on a statewide or metropolitan area basis as part of cooperative study programs with specific State Departments of Transportation or specific cities. The USGS, in cooperation with the Federal Highway Administration and the Federal Emergency Management Agency, has compiled all the current (as of September 1993) statewide and metropolitan area regression equations into a micro-computer program titled the National Flood Frequency Program.This program includes regression equations for estimating flood-peak discharges and techniques for estimating a typical flood hydrograph for a given recurrence interval peak discharge for unregulated rural and urban watersheds. These techniques should be useful to engineers and hydrologists for planning and design applications. This report summarizes the statewide regression equations for rural watersheds in each State, summarizes the applicable metropolitan area or statewide regression equations for urban watersheds, describes the National Flood Frequency Program for making these computations, and provides much of the reference information on the extrapolation variables needed to run the program.

Water-Resources Investigations Report

Estimated public-water supply and industrial-commercial ground-water withdrawals and returns in Nassau County, Long Island, New York, 1973-79

Nassau County, New York depends upon ground water for its freshwater supply. The primary water uses are for public-water supply and industrial-commercial purposes, which together accounted for 202 Mgal/d (million gallons per day) in 1975. Public-water suppliers withdrew 85 percent of their water from the Magothy Formation. About 133 Mgal/d was returned to the ground after use in 1975, and about 69; Mgal/d was discharged to tidewater. In addition, about 34 Mgal/d infiltrated into sewerlines in 1975 and was also discharged to tidewater. Because of the importance of this freshwater supply, the New York State Department of Environmental conservation reviews applications for the installation of wells and compiles data on pumpage throughout Long Island. It also reviews applications to discharge wastewater into the surface water and ground water of the State. This report summarizes the data filed with the New York State Department of Environmental Conservation for Nassau County during 1973-79. It presents data and estimates on withdrawals for public and industrial-commercial supply, returns to the ground, and discharges through sewer systems. It also includes information on population and land use.

New York

Water-quality assessment of the Albermarle-Pamlico drainage basin, North Carolina and Virginia— A summary of selected trace element, nutrient, and pesticide data for bed sediments, 1969-90

Spatial distributions of metals and trace elements, nutrients, and pesticides and polychiorinated biphenyls (PCB's) in bed sediment were characterized using data collected from 1969 through 1990 and stored in the U.S. Geological Survey's National Water Data Storage and Retrieval (WATSTORE) system and the U.S. Environmental Protection Agency's Storage and Retrieval (STORET) system databases. Bed-sediment data from WATSTORE and STORET were combined to form a single database of 1,049 records representing 301 sites. Data were examined for concentrations of 16 metals and trace elements, 4 nutrients, 10 pesticides, and PCB's. Maximum bed-sediment concentrations were evaluated relative to sediment-quality guidelines developed by the National Oceanic and Atmospheric Administration, the Ontario Ministry of Environment and Energy, and the Virginia Department of Environmental Quality. Sites were not selected randomly; therefore, results should not be interpreted as representing average conditions. Many sites were located in or around lakes and reservoirs, urban areas, and areas where special investigations were conducted. Lakes and reservoirs function as effective sediment traps, and elevated concentrations of some constituents occurred at these sites. High concentrations of many metals and trace elements also occurred near urban areas where streams receive runoff or inputs from industrial, residential, and municipal activities. Elevated nutrient concentrations occurred near lakes, reservoirs, and the mouths of major rivers. The highest concentrations of arsenic, beryllium, chromium, iron. mercury, nickel, and selenium occurred in the Roanoke River Basin and may be a result of geologic formations or accumulations of bed sediment in lakes and reservoirs. The highest concentrations of cadmium, lead, and thallium were detected in the Chowan River Basin; copper and zinc were reported highest in the Neuse River Basin. Total phosphorus and total ammonia plus organic nitrogen concentrations exceeded the sediment evaluation guidelines in each major river basin, possibly resulting from wastewater inputs and agricultural applications. Exceedances of pesticide guidelines were detected in the upper Neuse River Basin near Falls Lake and in the lower Tar River Basin.

North Carolina, Virginia

Partial compilation and revision of basic data in the WATEQ programs

Several portions of the basic data in the WATEQ series of computer programs (WATEQ, WATEQF, WATEQ2, WATEQ3, and PHREEQE) are compiled. The density and dielectric constant of water and their temperature dependence are evaluated for the purpose of updating the Debye-Huckel solvent parameters in the activity coefficient equations. The standard state thermodynamic properties of the Fe2+ and Fe3+ aqueous ions are refined. The main portion of this report is a comprehensive listing of aluminum hydrolysis constants, aluminum fluoride, aluminum sulfate, calcium chloride, magnesium chloride, potassium sulfate and sodium sulfate stability constants, solubility product constants for gibbsite and amorphous aluminum hydroxide, and the standard electrode potentials for Fe (s)/Fe2+(aq) and Fe2 +(aq)/Fe3+(aq). (USGS)

Water-Resources Investigations Report

Estimation of Median Streamflows at Perennial Stream Sites in Hawaii

The most accurate estimates of median streamflows at perennial stream sites in Hawaii are those made at streamflow-gaging stations. Two alternative methods for estimating median streamflows at ungaged sites are described in this report. Multiple-regression equations were developed for estimating median streamflows at ungaged, unregulated, perennial stream sites. The equations relate combinations of drainage area, mean altitude of the main stream channel, and mean annual precipitation to median streamflow. Streamflow data from 56 long-term continuous-record gaging stations were used in the analysis. Median-streamflow data for all 56 sites were adjusted using record-extension techniques to reflect base period (1912 through 1986) conditions. Hawaii was subdivided into two geographic groups and multiple-regression equations were developed for each. The standard error of predication for the equation developed for the first group, the islands of Oahu, Molokai, and Hawaii, is 41 percent. The standard error of predication for the equation developed for the second group, the islands of Kauai and Maui, is 54 percent. A method for estimating median-streamflow, based on discharge measurements and data from nearby streamflow-gaging stations, was also developed for 27 regulated, perennial windward Oahu sites. Standard errors of prediction for 23 of the sites range from 5 to 34 percent. Median-streamflow estimates for the four remaining sites were considered poor and no measures of accuracy are provided. Discharge measurements can be used to make estimates of median streamflows at ungaged, regulated sites where the regression equations developed in this report are not applicable. Discharge measurements can also be used to make estimates of median streamflows at ungaged, unregulated sites. Estimates of median streamflows based on discharge measurements have greater standard errors than estimates based on continuous streamflow records and in general have smaller standard errors than estimates based on regression equations.

Water-Resources Investigations Report

Surface-water and suspended-sediment inflow and outflow for Nutria Reservoir No. 3, Zuni Indian Reservation, New Mexico, March 1994 to September 1995

Surface-water and suspended-sediment inflow to and outflow from Nutria Reservoir No. 3 on the Zuni Indian Reservation, western New Mexico, were calculated. The period of study was March 3, 1994, to September 30, 1995. Total runoff into Nutria Reservoir No. 3 during the study period was 6,812 acre-feet. During the study period, 24,310 tons of suspended sediment was transported into Nutria Reservoir No. 3, and 259 tons of suspended sediment was transported out of Nutria Reservoir No. 3. Runoff during the study period, recorded at an upstream gage with 25 years of record, was 137 percent higher than that for a 19-month period similar to the study period. This may indicate that suspended-sediment loads transported into Nutria Reservoir No. 3 also were larger than average. Based on the difference between inflow and outflow of suspended sediment, 24,050 tons of suspended sediment was deposited in Nutria Reservoir No. 3. From March 1994 to May 1994 the spillway elevation of Nutria Reservoir No. 3 was raised to allow water to be diverted into an adjacent reservoir, Nutria Reservoir No. 4. This flow and sediment transported into Nutria Reservoir No. 4 were not recorded. If the elevation of the spillway had not been raised, suspended- sediment loads recorded downstream from Nutria Reservoir No. 3 would have been larger and the calculated amount of sediment deposited in Nutria Reservoir would have been smaller. Of the total suspended-sediment load entering Nutria Reservoir No. 3 during the study period, 94 percent was transported by an arroyo, Garcia Draw. Garcia Draw drains only 15 percent of the total drainage area of Nutria Reservoir No. 3 and contributed less than 5 percent of the total surface runoff to the reservoir. The average annual amount of sediment deposited in Nutria Reservoir No. 3 during the study was 15,355 tons. By using a dry-weight density of 99.4 pounds per cubic foot for the deposited sediment, the annual volume of sediment deposited in Nutria Reservoir No. 3 is 7.09 acre-feet per year. This number is smaller than the previously reported sedimentation rate of 15.0 acre-feet per year obtained from past surveys. The capacity of Nutria Reservoir No. 3 in 1993 was 191 acre-feet. By using the calculated average sedimentation rate of 7.09 acre-feet per year, Nutria Reservoir No. 3 could be completely filled approximately 27 years after the 1993 survey.

New Mexico

Users manual for an expert system (HSPEXP) for calibration of the hydrological simulation program; Fortran

Expert system software was developed to assist less experienced modelers with calibration of a watershed model and to facilitate the interaction between the modeler and the modeling process not provided by mathematical optimization. A prototype was developed with artificial intelligence software tools, a knowledge engineer, and two domain experts. The manual procedures used by the domain experts were identified and the prototype was then coded by the knowledge engineer. The expert system consists of a set of hierarchical rules designed to guide the calibration of the model through a systematic evaluation of model parameters. When the prototype was completed and tested, it was rewritten for portability and operational use and was named HSPEXP. The watershed model Hydrological Simulation Program--Fortran (HSPF) is used in the expert system. This report is the users manual for HSPEXP and contains a discussion of the concepts and detailed steps and examples for using the software. The system has been tested on watersheds in the States of Washington and Maryland, and the system correctly identified the model parameters to be adjusted and the adjustments led to improved calibration.

Water-Resources Investigations Report

Water withdrawals in the Black Warrior-Tombigbee Basin and Alcorn County, Mississippi, 1985-87

Public-supply and industrial water withdrawals were inventoried for the Mississippi part of the Black Warrior-Tombigbee Basin and for Alcorn County, Mississippi. The study area, located in the northeastern part of the State, is largely forested or agricultural land, with some industries near the larger towns. A water-resource capacity analysis was done to determine a risk rating for each inventoried facility, evaluating the likelihood of the facility exceeding the capacity of its current source of water at the existing level of use. Published reports and potentiometric maps were used in this analysis to determine the source capacity and the effects withdrawals have had on each water source. The public-supply and industrial water withdrawals in the basin are from ground water, with the exception of the city of Columbus. About 97 percent of the total withdrawal of 80 million gallons per day is from ground water. Water-supply systems in three areas were determined to have a high risk of exceeding the water-resource capacity: the Tupelo-Lee County area, the West Point (Clay County) area, and the Starkville (Oktibbeha County) area.

Mississippi

Plan of study for the regional aquifer-system analysis of the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

The San Juan structural basin is an 18,000 sq mi area that contains several extensive aquifers. The basin includes three surface drainage basins and parts of New Mexico, Colorado, Arizona, and Utah. Surface water in the area is fully appropriated, and the steadily increasing demand for groundwater has resulted in water supply concerns. Competition is great between mining and electric power companies, municipalities, and Indian communities for the limited groundwater supplies. This report outlines a 4-year plan for a study of the regional aquifer system in the San Juan structural basin. The purposes of the study are to define and understand the aquifer system; to assess the effects of groundwater use on the aquifers and streams; and to determine the availability and quality of groundwater in the basin. (Author 's abstract)

Water-Resources Investigations Report

Low-flow and flow-duration characteristics of Alabama streams

Estimates of minimum 7-day average discharges with recurrence intervals of 2 and 10 years for 228 continuous-record gaging stations are presented in this report. Low-flow frequency discharge estimates for 447 partial-record stations are also presented. These discharge estimates were computed by relating base-flow discharge measurements at the partial- record stations to daily-mean discharge values at selected continuous-record gaging stations. Flow- duration characteristics for 207 continuous-record gaging stations are also provided.

Water-Resources Investigations Report

Surface-Water Quality of the Skokomish, Nooksack, and Green-Duwamish Rivers and Thornton Creek, Puget Sound Basin, Washington, 1995-98

Streamflow and surface-water-quality data were collected from November 1995 through April 1998 (water years 1996-98) from a surface-water network in the Puget Sound Basin study unit of the U.S. Geological Survey National Water-Quality Assessment program. Water samples collected monthly and during storm runoff events were analyzed for nutrients, major ions, organic carbon, and suspended sediment, and at selected sites, samples were analyzed for pesticides and volatile organic compounds. Eleven sites were established in three major watersheds--two in the Skokomish River Basin, three in the Nooksack River Basin, five in the Green-Duwamish River Basin, and one site in Thornton Creek Basin, a small tributary to Lake Washington. The Skokomish River near Potlatch, Nooksack River at Brennan, and Duwamish River at Tukwila are integrators of mixed land uses with the sampling sites locally influenced by forestry practices, agriculture, and urbanization, respectively. The remaining eight sites are indicators of relatively homogeneous land use/land cover in their basins. The site on the North Fork Skokomish River is an indicator site chosen to measure reference or background conditions in the study unit. In the Nooksack River Basin, the site on Fishtrap Creek is an indicator of agriculture, and the Nooksack River at North Cedarville is an indicator site of forestry practices in the upper watershed. In the Green-Duwamish River Basin, Springbrook Creek is an urban indicator, Big Soos Creek is an indicator of a rapidly developing suburban basin; Newaukum Creek is an indicator of agriculture; and the Green River above Twin Camp Creek is an indicator of forestry practices. Thornton Creek is an indicator of high-density urban residential and commercial development. Conditions during the first 18 months of sampling were dominated by above-normal precipitation. For the Seattle-Tacoma area, water year 1997 was the wettest of the 3 years during the sample-collection period. Nearly 52 inches fell (about 14 inches above average) and monthly precipitation was often 200 percent of normal. The wet years kept streamflows generally above normal and contributed to high concentrations of pesticides, nutrients, suspended sediment, and organic carbon in samples. On the basis of chemical concentrations, dissolved oxygen concentrations, and water temperature, the relative quality of water among the 11 study sites ranged from exceptionally high in the North Fork Skokomish and the Green to fair in Springbrook and Thornton. Water in the large rivers (Skokomish, Nooksack, Green-Duwamish) and in two of the small streams in the Puget Sound Lowlands (Big Soos and Newaukum) was characterized by dilute water chemistry with dissolved solids concentrations less than 130 milligrams per liter. Water in three other small streams in the Lowlands (Fishtrap, Springbrook, and Thornton) had dissolved solids concentrations as high as 320 milligrams per liter. Nutrient and pesticide concentrations mostly were higher in the small streams than in the large rivers. Suspended-sediment concentrations, however, were highest in the large rivers, with averages ranging from 85 to 443 milligrams per liter. During storm and flood events, suspended-sediment concentrations in samples from the Nooksack were as much as 2,800 milligrams per liter, and from the Skokomish, 1,500 milligrams per liter. Out of 86 pesticides and 86 volatile organic compounds analyzed, a total of 35 pesticides and 11 volatile organic compounds were detected at concentrations above laboratory reporting levels in samples collected from the four intensively studied sites, the lower Nooksack River, Duwamish River, Fishtrap Creek, and Thornton Creek. Herbicides were detected more frequently than insecticides. The herbicide prometon was detected in 66 percent of all 124 samples collected, followed by simazine (65 percent), atrazine (64 percent), and the insecticide diazinon (50 percent). The detected volatile organic c

Water-Resources Investigations Report

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of organophosphate pesticides in whole water by continuous liquid-liquid extraction and capillary-column gas chromatography with flame photometric detection

A method for the isolation of 20 parent organophosphate pesticides and 5 organophosphate pesticide degradates from natural-water samples is described. Compounds are extracted from water samples with methylene chloride using a continuous liquid-liquid extractor for 6 hours. The solvent is evaporated using heat and a flow of nitrogen to a volume of 1 milliliter and solvent exchanged to ethyl acetate. Extracted compounds are determined by capillary-column gas chromatography with flame photometric detection. Single-operator derived method detection limits in three water-matrix samples ranged from 0.003 to 0.009 microgram per liter. Method performance was validated by spiking all compounds in three different matrices at three different concentrations. Eight replicates were analyzed at each concentration in each matrix. Mean recoveries of most method compounds spiked in surface-water samples ranged from 54 to 137 percent and those in ground-water samples ranged from 40 to 109 percent for all pesticides. Recoveries in reagent-water samples ranged from 42 to 104 percent for all pesticides. The only exception was O-ethyl-O-methyl-S-propylphosphorothioate, which had variable recovery in all three matrices ranging from 27 to 79 percent. As a result, the detected concentration of O-ethyl-O-methyl-S-propylphosphorothioate in samples is reported in this method with an estimated remark code. Based on the performance issue, two more compounds, disulfoton and ethion monoxon, also will be reported in this method with an estimated remark code. Estimated-value compounds, which are ?E-coded? in the data base, do not meet the performance criteria for unqualified quantification, but are retained in the method because the compounds are important owing to high use or potential environmental effects and because analytical performance has been consistent and reproducible.

Water-Resources Investigations Report

A technique for estimating the time of travel of water in Indiana streams

Estimates of the traveltime of waterborne particles in streams is important for pollution studies and in the event of spills of contaminants. This report provides data for the 16 Indiana streams on which time-of-travel information has been obtained and a means for estimating the velocity of any naturally flowing stream in Indiana with a drainage area of 80 square miles (210 square kilometres) or more. Measured velocity rates compiled from the time-of-travel data collected in Indiana are releated to 25, 50, 100, and 200 percent of the average discharge of streams shown in this report. Velocities at these discharges are significantly related to their respective watershed characteristics (average discharge and slope). Generalized relations of the velocities as functions of the streams' watershed characteristics are developed as multivariate regression equations using the data from each of the measured streams. Examples of uses and applications of the measured data and the predictive equations are given.

Indiana

Chapter A6. Section 6.7. Turbidity

Turbidity is one of the indicators used to assess the environmental health of water bodies. Turbidity is caused by the presence of suspended and dissolved matter, such as clay, silt, finely divided organic matter, plankton and other microscopic organisms, organic acids, and dyes. This section of the National Field Manual (NFM) describes the USGS protocols for determining turbidity in surface and ground waters, including extensive guidance for equipment selection and data reporting. It includes the revised approach to turbidity measurement and reporting that was implemented by the U.S. Geological Survey (USGS) in October 2004 to account for technological advances and consequent measurement complexities. Each chapter of the National Field Manual is published separately and revised periodically. Newly published and revised chapters will be announced on the USGS Home Page on the World Wide Web under 'New Publications of the U.S. Geological Survey.'

Techniques of Water-Resources Investigations