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At least 289 records · Page 16Linked to original sources

USGS1976

Solute transport and modeling of water quality in a small stream

An injection of chloride, sodium, and stable strontium was made at a constant rate for 3 hours into Uvas Creek, Santa Clara County, Calif., to determine the mass transport processes in a small stream. Five observation points were selected within a 610-metre reach of the stream below the injection site. Water samples were collected at the observation points during and immediately after the injection. A mathematical model of the stream was obtained by solving analytically and optimally the one-dimensional mass transport equation of the solutes in the stream. Comparison of field results with a simplified mathematical model indicates the dominance of convection in the behavior of sodium and chloride. The concentration of chloride and sodium can be closely simulated by the model. However, strontium cannot be well represented by the simplified model, which contains a first-order decay-type sink.

California↗

USGS2011

Climate change, uncertainty, and natural resource management

Climate change and its associated uncertainties are of concern to natural resource managers. Although aspects of climate change may be novel (e.g., system change and nonstationarity), natural resource managers have long dealt with uncertainties and have developed corresponding approaches to decision-making. Adaptive resource management is an application of structured decision-making for recurrent decision problems with uncertainty, focusing on management objectives, and the reduction of uncertainty over time. We identified 4 types of uncertainty that characterize problems in natural resource management. We examined ways in which climate change is expected to exacerbate these uncertainties, as well as potential approaches to dealing with them. As a case study, we examined North American waterfowl harvest management and considered problems anticipated to result from climate change and potential solutions. Despite challenges expected to accompany the use of adaptive resource management to address problems associated with climate change, we conclude that adaptive resource management approaches will be the methods of choice for managers trying to deal with the uncertainties of climate change. ?? 2010 The Wildlife Society.

Journal of Wildlife Management↗

USGS2021

Machine learning predictions of mean ages of shallow well samples in the Great Lakes Basin, USA

The travel time or “age” of groundwater affects catchment responses to hydrologic changes , geochemical reactions, and time lags between management actions and responses at down-gradient streams and wells. Use of atmospheric tracers has facilitated the characterization of groundwater ages, but most wells lack such measurements. This study applied machine learning to predict ages in wells across a large region around the Great Lakes Basin using well, chemistry, and landscape characteristics. For a dataset of age tracers in 961 samples, the travel time from the land surface to the sample location was estimated for each sample using parametric functions. The mean travel times were then modeled using a gradient boosting machine (GBM) algorithm with cross validation tuning of model metaparameters. The GBM approach was able to closely match estimated ages for the training data (RMSE = 0.26 natural-log scale years) and provided a reasonable match to testing data (RMSE = 0.84). Of the variables tested, well characteristics (e.g. depth), land use, hydrologic indicators (e.g. topographic wetness index), and water chemistry (e.g. nitrate, fluoride, and pH), substantially affected the predictions of age. GBM prediction was applied to 14,335 groundwater samples with median sample depth of 5.4 m, indicating for the Great Lakes Basin a broad distribution of ages among wells with a median of 32.9 years. Lag times of decades are likely for these wells to respond to changing solute fluxes near land surface. While depth variables most strongly affected predicted mean ages, chemical constituents exhibited smooth trends with age, consistent with prevailing conceptual models of evolving sources and geochemistry flowpaths. The results provide proof of concept for use of readily available variables of well, landscape, and chemical characteristics to improve groundwater age estimates across large regions.

Great Lakes basin↗

USGS2001

Interparticle migration of metal cations in stream sediments as a factor in toxics transport

Sorption of metal cations by stream sediments is an important process affecting the movement of released contaminants in the environment. The ability of cations to desorb from one sediment particle and subsequently sorb to another can greatly affect metal transport rates but rates for this process have not been reported. The objective of this study was to determine the rate at which sorbed metals can migrate from contaminated sediment particles to uncontaminated sediment particles as a function of the concentration of the contaminating solution and the duration of the contact with the contaminating solution. Samples of small sediment particles were exposed to solutions containing cobalt, after which they were rinsed and combined with larger uncontaminated sediment particles in the presence of stream water. Initial concentrations of the contaminating solution ranged from 1ng/l to 1000mg/l and exposures to the contaminating solution ranged from 6h to 14 days. The rate of the migration increased with increasing concentrations in the contaminating solution and with decreasing times of exposure to the contaminating solution. Under the conditions of these experiments, the time required for the migration to reach equilibrium was on the order of months or longer. In separate experiments, the kinetics of adsorption and desorption of cobalt were measured as a function of concentration of the contaminating solution. The time required to reach adsorption equilibrium increased with increasing concentration in the contaminating solution. Times to sorption equilibrium were on the order of months. Desorption was much slower than adsorption and, together with intraparticle diffusion, probably controls the rate of migration from contaminated to uncontaminated sediment. The results of this study show that interparticle migration of metal cations can proceed at significant rates that are strongly influenced by the length of time that the metal has been in contact with the sediment. Copyright ?? 2001 Elsevier Science B.V.Sorption of metal cations by stream sediments is an important process affecting the movement of released contaminants in the environment. The ability of cations to desorb from one sediment particle and subsequently sorb to another can greatly affect metal transport rates but rates for this process have not been reported. The objective of this study was to determine the rate at which sorbed metals can migrate from contaminated sediment particles to uncontaminated sediment particles as a function of the concentration of the contaminating solution and the duration of the contact with the contaminating solution. Samples of small sediment particles were exposed to solutions containing cobalt, after which they were rinsed and combined with larger uncontaminated sediment particles in the presence of stream water. Initial concentrations of the contaminating solution ranged from 1 ng/l to 1000 mg/l and exposures to the contaminating solution ranged from 6 h to 14 days. The rate of the migration increased with increasing concentrations in the contaminating solution and with decreasing times of exposure to the contaminating solution. Under the conditions of these experiments, the time required for the migration to reach equilibrium was on the order of months or longer. In separate experiments, the kinetics of adsorption and desorption of cobalt were measured as a function of concentration of the contaminating solution. The time required to reach adsorption equilibrium increased with increasing concentration in the contaminating solution. Times to sorption equilibrium were on the order of months. Desorption was much slower than adsorption and, together with intraparticle diffusion, probably controls the rate of migration from contaminated to uncontaminated sediment. The results of this study show that interparticle migration of metal cations can proceed at significant rates that are strongly influenced by the length of time that the metal has

Journal of Hazardous Materials↗

USGS1974

Myxosoma cerebralis: Comparative sensitivity of spore detection methods

Physical and biophysical methods of detecting spores of Myxosoma cerebralis were used in sequence on 87 individual fingerling rainbow trout ( Salmo gairdneri ) from two populations with a low incidence of infection. Physical methods of releasing spores from the organs of equilibrium, gill arches, or the axial skeleton gave an estimated rate of infection of 2.3–4.6%. Each succeeding step — pepsin digestion, trypsin digestion, and differential centrifugation through 55% dextrose solution — revealed additional infected fish. The final step of the sequence detected 10.5 times more infected fish than were found by examination of the organs of equilibrium or the axial skeleton with physical means; the true incidence was at least 24.1%. Procedures are described for using biophysical methods on 60-fish pools for hatchery inspection work and also on the more bony skeletons of mature fish.

Journal of the Fisheries Research Board of Canada↗

USGS1976

Gravity studies in the Carolina slate belt near the Haile and Brewer mines, north-central South Carolina

The Bouguer gravity map of part of the Carolina slate belt near the Haile and Brewer mines in South Carolina shows anomalies related to rock units. The most conspicuous of the anomalies coincide with coarse-grained granitic plutons. Mathematically calculated models using an iterative three-dimensional solution of the gravity anomalies show that these plutons are steep-sided intrusive bodies that constrict at depth to small pipes or roots. The plutons are emplaced in and are probably largely confined to a unit of volcaniclastic rocks. The volcaniclastic rocks are probably 6,000 m to 10,000 m thick and similar in composition to those exposed in the vicinity of the plutons.

South Carolina↗

USGS2013

Anesthesia of juvenile Pacific Lampreys with MS-222, BENZOAK, AQUI-S 20E, and Aquacalm

Effective anesthetics are a critical component of safe and humane fish handling procedures. We tested three concentrations each of four anesthetics—Finquel (tricaine methanesulfonate, herein referred to as MS-222), BENZOAK (20% benzocaine), AQUI-S 20E (10% eugenol), and Aquacalm (metomidate hydrochloride)—for efficacy and safety in metamorphosed, outmigrating juvenile Pacific Lampreys Entosphenus tridentatus . The anesthetics MS-222 (100 mg/L) and BENZOAK (60 mg/L) were the most effective for anesthetizing juvenile Pacific Lampreys to a handleable state with minimal irritation to the fish. Fish anesthetized with BENZOAK also had lower rates of fungal infection than those exposed to MS-222, AQUI-S 20E, or no anesthetic. Exposure to AQUI-S 20E irritated juvenile Pacific Lampreys, causing them to leap or climb out of the anesthetic solution, and Aquacalm anesthetized fish to a handleable state too slowly and incompletely for effective use with routine handling procedures. Our results indicate that MS-222 and BENZOAK are effective anesthetics for juvenile Pacific Lampreys, but field studies are needed to determine whether exposure to MS-222 increases risk of fungal infection in juvenile Pacific Lampreys released to the wild.

North American Journal of Fisheries Management↗

USGS2009

Hydrologic and biogeochemical controls of river subsurface solutes under agriculturally enhanced ground water flow

The relative influences of hydrologic processes and biogeochemistry on the transport and retention of minor solutes were compared in the riverbed of the lower Merced River (California, USA). The subsurface of this reach receives ground water discharge and surface water infiltration due to an altered hydraulic setting resulting from agricultural irrigation. Filtered ground water samples were collected from 30 drive point locations in March, June, and October 2004. Hydrologic processes, described previously, were verified by observations of bromine concentrations; manganese was used to indicate redox conditions. The separate responses of the minor solutes strontium, barium, uranium, and phosphorus to these influences were examined. Correlation and principal component analyses indicate that hydrologic processes dominate the distribution of trace elements in the ground water. Redox conditions appear to be independent of hydrologic processes and account for most of the remaining data variability. With some variability, major processes are consistent in two sampling transects separated by 100 m.

Journal of Environmental Quality↗

USGS2014

Observations of static Coulomb stress triggering of the November 2011 M5.7 Oklahoma earthquake sequence

In November 2011, a M 5.0 earthquake occurred less than a day before a M 5.7 earthquake near Prague, Oklahoma, which may have promoted failure of the mainshock and thousands of aftershocks along the Wilzetta fault, including a M 5.0 aftershock. The M 5.0 foreshock occurred in close proximity to active fluid injection wells; fluid injection can cause a buildup of pore fluid pressure, decrease the fault strength, and may induce earthquakes. Keranen et al . [ 2013 ] links the M 5.0 foreshock with fluid injection, but the relationship between the foreshock and successive events has not been investigated. Here we examine the role of coseismic Coulomb stress transfer on earthquakes that follow the M 5.0 foreshock, including the M 5.7 mainshock. We resolve the static Coulomb stress change onto the focal mechanism nodal plane that is most consistent with the rupture geometry of the three M ≥ 5.0 earthquakes, as well as specified receiver fault planes that reflect the regional stress orientation. We find that Coulomb stress is increased, e.g., fault failure is promoted, on the nodal planes of ~60% of the events that have focal mechanism solutions, and more specifically, that the M 5.0 foreshock promoted failure on the rupture plane of the M 5.7 mainshock. We test our results over a range of effective coefficient of friction values. Hence, we argue that the M 5.0 foreshock, induced by fluid injection, potentially triggered a cascading failure of earthquakes along the complex Wilzetta fault system.

Oklahoma↗

USGS2007

A path-independent integral for the characterization of solute concentration and flux at biofilm detachments

A path-independent (conservation) integral is developed for the characterization of solute concentration and flux in a biofilm in the vicinity of a detachment or other flux limiting boundary condition. Steady state conditions of solute diffusion are considered and biofilm kinetics are described by an uptake term which can be expressed in terms of a potential (Michaelis-Menten kinetics). An asymptotic solution for solute concentration at the tip of the detachment is obtained and shown to be analogous to that of antiplane crack problems in linear elasticity. It is shown that the amplitude of the asymptotic solution can be calculated by evaluating a path-independent integral. The special case of a semi-infinite detachment in an infinite strip is considered and the amplitude of the asymptotic field is related to the boundary conditions and problem parameters in closed form for zeroth and first order kinetics and numerically for Michaelis-Menten kinetics. ?? Springer Science+Business Media, Inc. 2007.

International Journal of Fracture↗

USGS1974

Activity-product constants of aragonite at 90° and 51°C

The activity-product constants of aragonite, K A =[Ca 2+ ][CO 3 2- ] (where the brackets denote activities), were determined experimentally at 90°C and at 51°C. Results at 90°C were obtained from four separate dolomite dissolution runs, in which aragonite precipitated and came to equilibrium with the aqueous phase (from the direction of. supersaturation), and from two runs starting with aragonite suspended in dilute MgCl 2 solutions (from the direction of undersaturation). The average values of K A from the six runs were in excellent agreement; for the negative logarithm of K A , P K A , they yield a value of 8.95±0.05. One run was made at 51° C starting with aragonite suspended in dilute MgCl 2 solution; the value of p K A at 51°C is 8.61±0.05. No X-ray detectable calcite was found at the conclusion of any of the runs, including a dolomite dissolution run at 90°C (D-10) that was sampled over a period of 10,268 h and toward the end had a concentration of approximately 0.002 molal total dissolved magnesium.

Journal of Research of the U.S. Geological Survey↗

USGS1982

Anion-exchange separation of Pt and Pd using perchloric and hydrochloric acid solutions

On Biorad Ag-1X8 anion-exchange resin (200-400 mesh), Pd and Pt may be separated from one another by elution with 0.2M HClO4, and 5M HClO4, respectively. If present, Au may be retained by making the elutriants 0.003M in HCl. Alternatively, reduction by H2SO3 enables elution of Pt2+ with 6M HCl before recovery of Pd2+ with 0.2M HClO4??Ir4+ is reduced to Ir3+ by H2SO3 and may be eluted ahead of Pt2+ by 2M HCl. ?? 1982 Akade??miai Kiado??.

Journal of Radioanalytical Chemistry↗

USGS2013

Shallow groundwater and soil chemistry response to 3 years of subsurface drip irrigation using coalbed-methane-produced water

Disposal of produced waters, pumped to the surface as part of coalbed methane (CBM) development, is a significant environmental issue in the Wyoming portion of the Powder River Basin, USA. High sodium adsorption ratios (SAR) of the waters could degrade agricultural land, especially if directly applied to the soil surface. One method of disposing of CBM water, while deriving beneficial use, is subsurface drip irrigation (SDI), where acidified CBM waters are applied to alfalfa fields year-round via tubing buried 0.92 m deep. Effects of the method were studied on an alluvial terrace with a relatively shallow depth to water table (∼3 m). Excess irrigation water caused the water table to rise, even temporarily reaching the depth of drip tubing. The rise corresponded to increased salinity in some monitoring wells. Three factors appeared to drive increased groundwater salinity: (1) CBM solutes, concentrated by evapotranspiration; (2) gypsum dissolution, apparently enhanced by cation exchange; and (3) dissolution of native Na–Mg–SO 4 salts more soluble than gypsum. Irrigation with high SAR (∼24) water has increased soil saturated paste SAR up to 15 near the drip tubing. Importantly though, little change in SAR has occurred at the surface.

Wyoming↗

USGS1982

Uraniferous opal, Virgin Valley, Nevada: Conditions of formation and implications for uranium exploration

Uraniferous, fluorescent opal, which occurs in tuffaceous sedimentary rocks at Virgin Valley, Nevada, records the temperature and composition of uranium-rich solutions as well as the time of uranium-silica coprecipitation. Results are integrated with previous geologic and geochronologic data for the area to produce a model for uranium mobility that may be used to explore for uranium deposits in similar geologic settings. Uraniferous opal occurs as replacements of diatomite, or silicic air-fall ash layers in tuffaceous lakebeds of the Virgin Valley Formation (Miocene) of Merriam (1907). Fission-track radiography shows uranium to be homogeneously dispersed throughout the opal structure, suggesting coprecipitation of dissolved uranium and silica gel. Fluid inclusions preserved within opal replacements of diatomite have homogenization temperatures in the epithermal range and are of low salinity. Four samples of opal from one locality all have U-Pb apparent ages which suggest uraniferous opal precipitation in late Pliocene time. These ages correspond to a period of local, normal faulting, and highangle faults may have served as vertical conduits for transport of deep, thermalized ground water to shallower levels. Lateral migration of rising solutions occurred at intersections of faults with permeable strata. Silica and some uranium were dissolved from silica-rich host strata of 5–20 ppm original uranium content and reprecipitated as the solutions cooled. The model predicts that in similar geologic settings, ore-grade concentrations of uranium will occur in permeable strata that intersect high-angle faults and that contain uranium source rocks as well as efficient reductant traps for uranium. In the absence of sufficient quantities of reductant materials, uranium will be flushed from the system or will accumulate in low-grade disseminated hosts such as uraniferous opal.

Nevada↗

USGS2011

Electrical conductivity of electrolytes applicable to natural waters from 0 to 100 degrees C

The electrical conductivities of 34 electrolyte solutions found in natural waters ranging from (10 -4 to 1) molkg -1 in concentration and from (5 to 90) °C have been determined. High-quality electrical conductivity data for numerous electrolytes exist in the scientific literature, but the data do not span the concentration or temperature ranges of many electrolytes in natural waters. Methods for calculating the electrical conductivities of natural waters have incorporated these data from the literature, and as a result these methods cannot be used to reliably calculate the electrical conductivity over a large enough range of temperature and concentration. For the single-electrolyte solutions, empirical equations were developed that relate electrical conductivity to temperature and molality. For the 942 molar conductivity determinations for single electrolytes from this study, the mean relative difference between the calculated and measured values was 0.1 %. The calculated molar conductivity was compared to literature data, and the mean relative difference for 1978 measurements was 0.2 %. These data provide an improved basis for calculating electrical conductivity for most natural waters.

Journal of Chemical and Engineering Data↗

USGS2009

Microseismicity at the North Anatolian Fault in the Sea of Marmara offshore Istanbul, NW Turkey

The North Anatolian Fault Zone (NAFZ) below the Sea of Marmara forms a “seismic gap” where a major earthquake is expected to occur in the near future. This segment of the fault lies between the 1912 Ganos and 1999 İzmit ruptures and is the only NAFZ segment that has not ruptured since 1766. To monitor the microseismic activity at the main fault branch offshore of Istanbul below the Çınarcık Basin, a permanent seismic array (PIRES) was installed on the two outermost Prince Islands, Yassiada and Sivriada, at a few kilometers distance to the fault. In addition, a temporary network of ocean bottom seismometers was deployed throughout the Çınarcık Basin. Slowness vectors are determined combining waveform cross correlation and P wave polarization. We jointly invert azimuth and traveltime observations for hypocenter determination and apply a bootstrap resampling technique to quantify the location precision. We observe seismicity rates of 20 events per month for M < 2.5 along the basin. The spatial distribution of hypocenters suggests that the two major fault branches bounding the depocenter below the Çınarcık Basin merge to one single master fault below ∼17 km depth. On the basis of a cross-correlation technique we group closely spaced earthquakes and determine composite focal mechanisms implementing recordings of surrounding permanent land stations. Fault plane solutions have a predominant right-lateral strike-slip mechanism, indicating that normal faulting along this part of the NAFZ plays a minor role. Toward the west we observe increasing components of thrust faulting. This supports the model of NW trending, dextral strike-slip motion along the northern and main branch of the NAFZ below the eastern Sea of Marmara.

Istanbul↗

USGS1984

A simple model of ice segregation using an analytic function to model heat and soil-water flow

For slowly moving freezing fronts in soil, the heat-transport equation may be approximated by the Laplacian of temperature. Consequently, potential theory may be assumed to apply and the temperature state can be approximated by an analytic function. The movement of freezing fronts may be approximated by a time-stepped solution of the phase-change problem, thus solving directly for heat flow across a freezing or thawing front. Moisture transport may approximated by using an exact solution of the moisture-transport equation assuming quasi-steady-state conditions, appropriate boundary conditions, and an exponential function relating unsaturated hydraulic conductivity (defined within the thawed zones) to pore water pressure (tension). This approach is used to develop a single model of ice segregation (frost-heave) in freezing soils. Applications to published and experimental one-dimension soil column freezing data show promising results.

Journal of Energy Resources Technology, Transactio↗

USGS2000

The use of mathematical models to predict beach behavior for U.S. coastal engineering: A critical review

A number of assumed empirical relationships (e.g., the Bruun Rule, the equilibrium shoreface profile, longshore transport rate equation, beach length: durability relationship, and the renourishment factor) and deterministic numerical models (e.g., GENESIS, SBEACH) have become important tools for investigating coastal processes and for coastal engineering design in the U.S. They are also used as the basis for making public policy decisions, such as the feasibility of nourishing recreational beaches. A review of the foundations of these relationships and models, however, suggests that they are inadequate for the tasks for which they are used. Many of the assumptions used in analytical and numerical models are not valid in the context of modern oceanographic and geologic principles. We believe the models are oversimplifications of complex systems that are poorly understood. There are several reasons for this, including: (1) poor assumptions and important omissions in model formulation; (2) the use of relationships of questionable validity to predict the morphologic response to physical forcing; (3) the lack of hindsighting and objective evaluation of beach behavior predictions for engineering projects; (4) the incorrect use of model calibration and verification as assertions of model veracity; and (5) the fundamental inability to predict coastal evolution quantitatively at the engineering and planning time and space scales our society assumes and demands. It is essential that coastal geologists, beach designers and coastal modelers understand these model limitations. Each important model assumption must be examined in isolation; incorporating them into a model does not improve their validity. It is our belief that the models reviewed here should not be relied on as a design tool until they have been substantially modified and proven in real-world situations. The 'solution,' however, is not to increase the complexity of a model by increasing the number of variables. What is needed is a thoughtful review of what beach behavior questions should or could be answered by modeling. Viable alternatives to the use of models do exist to predict the behavior of beaches. Three such alternatives to models are discussed for nourished beach design.

Journal of Coastal Research↗