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At least 289 records · Page 16Linked to original sources

USGS2021

Middle Holocene hydrologic changes catalyzed by river avulsion in Big Soda Lake, Nevada, USA

Big Soda Lake is a 63 m deep, 1.6 km 2 maar lake in the Great Basin of Nevada, USA. Water level in the lake is controlled by groundwater inputs from the surrounding aquifer and the only surface water input is rainfall, which is negligible. A core taken in 2010 records an 8.75 m depositional history of the lake. A radiocarbon date on fossil pollen from 8.4 m below the sediment water interface (BSWI) of 14,740 (+1120/−825) cal yr BP suggests that the core may cover the latest Pleistocene and Holocene depositional history of the lake. Stable isotope values of oxygen and carbon (δ 18 O and δ 13 C) on authigenic calcite, diatom assemblages, and sedimentary structures all show consistent hydrological change from initially saline water at the bottom of the core to fresh/brackish water at about 6 m BWSI, back to saline water at 4.3 m. At 4.3 m depth, the bedding and color of the core change abruptly, and the stable- isotope and diatom assemblages indicate a consistently hypersaline lake until near the top of the core, when fresh water entered the lake due to irrigation and canal building in the twentieth century. The stable isotopes of the calcite abruptly change from inversely varying isotopic compositions below 4.3 m depth to covarying above. This break between relatively fresh and saline conditions in the lake occurs during the middle Holocene, although the exact timing of the transition is unknown due to variability in the 14 C age determinations. The cause for such an abrupt change is difficult to explain through climate shifts, as evidence suggests climate in the Great Basin was different from what the Big Soda Lake record indicates in the Early Holocene. It is hypothesized that the Walker River flowed to the Carson River basin before 5600 cal yr BP, with water either flowing directly into the lake or raising the groundwater table sufficiently to freshen Big Soda Lake. The initial increase in salinity likely was caused by decreased flow of the Walker River due to Middle Holocene aridity. The lake level lowered slowly, and more saline conditions prevailed until 4.3 m depth when water from the Walker River stopped flowing into the Carson River basin. Above 4.3 m depth, diatom and isotopic evidence indicates that the lake became consistently saline. The isotopic and diatom assemblage transitions observed in Big Soda Lake sediment are not consistent with climate reconstructions and demonstrate that hydrologic shifts in a basin can be an important driver of change regardless of climatic conditions. However, climate shifts may also play a role in the hydrologic changes by supplying more or less water to river courses that may induce river avulsion.

Nevada↗

USGS2010

Late eighteenth century Old Maid eruption and lahars at Mount Hood, Oregon (USA) dated with tree rings and historical observations

Tree rings of subfossil trees buried by lahars and lahar-derived sediments along the Sandy and Zigzag Rivers record the onset of a late eighteenth century eruption at Mount Hood, Oregon, USA (Figs. 1–2). Crandell (1980) described and named this eruptive activity the ‘Old Maid eruptive period’ and estimated its age at about “200–300 year” using radiocarbon ages of trees killed by lahars. Cameron and Pringle (1986, 1987, 1991) used dendrochronology to constrain the major eruptive events to several decades in the late 1700s. Precise dating of the Old Maid eruption using tree rings, however, has been complicated by the inconsistent wood quality and scarcity of victim subfossil trees. A lack of nearby master chronologies, diverse physiography and microclimates of the region, and the generally low sensitreivity of local tree-ring series to climate variation also create problems with interpretation.

Oregon↗

USGS2012

Using age of colonizing douglas-fir for the dating of young geomorphic surfaces: a case study

Dating of many types of young (<500 year), dynamic, geomorphic landforms (e.g. mass-movement erosional tracks and deposits, alluvial terraces, flood plains, etc.) for purposes of hazard assessment and mitigation commonly requires greater dating precision than is available through radiocarbon dating or other methods. Ages of trees growing on landform surfaces have been used in a number of studies to estimate the time of landform creation or surface clearing, but the time lag between surface formation or disturbance and the reestablishment of trees can vary from 1 to more than 200 years (Desloges and Ryder 1990; Frenzen et al. 1988, 2005; Larsen and Bliss 1998; McCarthy and Luckman 1993; Sigafoos and Hendricks 1969; Winter et al. 2002). Appropriate lag times for selected tree species and for particular climatic and altitudinal ranges must be determined for the method to be useful.

Book chapter↗

USGS2017

Application of molluscan analyses to the reconstruction of past environmental conditions in estuaries

Molluscs possess a number of attributes that make them an excellent source of past environmental conditions in estuaries: they are common in estuarine environments; they typically have hard shells and are usually well preserved in sediments; they are relatively easy to detect in the environment; they have limited mobility as adults; they grow by incremental addition of layers to their shells; and they are found in all the major environments surrounding estuaries—terrestrial, freshwater, brackish, and marine waters. Analysis of molluscan assemblages can contribute information about past changes in sea level, climate, land use patterns, anthropogenic alterations, salinity, and other parameters of the benthic habitat and water chemistry within the estuary. High-resolution (from less than a day to annual) records of changes in environmental parameters can be obtained by analyzing the incremental growth layers in mollusc shells (sclerochronology). The shell layers retain information on changes in water temperature, salinity, seasonality, climate, river discharge, productivity, pollution and human activity. Isotopic analyses of mollusc shell growth layers can be problematic in estuaries where water temperatures and isotopic ratios can vary simultaneously; however, methods are being developed to overcome these problems. In addition to sclerochronology, molluscs are important to Holocene and Pleistocene estuarine palaeoenvironmental studies because of their use in the development of age models through radiocarbon dating, amino acid racemization, uranium-thorium series dating, and electron spin resonance (ESR) dating.

Book chapter↗

USGS1990

Volcanic geology and eruption frequency, São Miguel, Azores

Six volcanic zones comprise São Miguel, the largest island in the Azores. All are Quaternary in age except the last, which is partly Pliocene. From west to east the zones are (1) the trachyte stratovolcano of Sete Cidades, (2) a field of alkali-basalt cinder cones and lava flows with minor trachyte, (3) the trachyte stratovolcano of Agua de Pau, (4) a field of alkali-basalt cinder cones and lava flows with minor trachyte and tristanite, (5) the trachyte stratovolcano of Furnas, and (6) the Nordeste shield, which includes the Povoação caldera and consists of alkali basalt, tristanite, and trachyte. New radiocarbon and K-Ar ages augment stratigraphic data obtained during recent geologic mapping of the entire island and provide improved data to interpret eruption frequency. Average dormant intervals for the past approximately 3000 years in the areas active during that time are about 400 years for Sete Cidades, 145 for zone 2, 1150 for Agua de Pau, and 370 for Furnas. However, the average dormant interval at Sete Cidades increased from 400 to about 680 years before each of the past two eruptions, and the interval at Furnas decreased from 370 to about 195 years before each of the past four eruptions. Eruptions in zone 4 occurred about once every 1000 years during latest Pleistocene and early Holocene time; none has occurred for about 3000 years. The Povoação caldera truncates part of the Nordeste shield and probably formed during the middle to late Pleistocene. Calderas formed during latest Pleistocene time at the three younger stratovolcanoes in the sequence: outer Agua de Pau (between 46 and 26.5 ka), Sete Cidades (about 22 ka), inner Agua de Pau (15.2 ka), and Furnas (about 12 ka). Normal faults are common, but many are buried by Holocene trachyte pumice. Most faults trend northwest or west-northwest and are related to the Terceira rift, whose most active segment on São Miguel passes through Sete Cidades and zone 2. A major normal fault displaces Nordeste lavas 150–250 m and may mark the location of an ancestral Terceira rift. Recent seismicity (e.g., in the 1980s) generally has been scattered, but some small earthquake swarms have occurred beneath the north-eastern flank of Agua de Pau.

Bulletin of Volcanology↗

USGS1992

Volcanic geology and eruption frequency, lower east rift zone of Kilauea volcano, Hawaii

Detailed geologic mapping and radiocarbon dating of tholeiitic basalts covering about 275 km2 on the lower east rift zone (LERZ) and adjoining flanks of Kilauea volcano, Hawaii, show that at least 112 separate eruptions have occurred during the past 2360 years. Eruptive products include spatter ramparts and cones, a shield, two extensive lithic-rich tuff deposits, aa and pahoehoe flows, and three littoral cones. Areal coverage, number of eruptions and average dormant interval estimates in years for the five age groups assigned are: (I) historic, i.e. A D 1790 and younger: 25%, 5, 42.75; (II) 200-400 years old: 50%, 15, 14.3: (III) 400-750 years old: 20%, 54, 6.6; (IV) 750-1500 years old: 5%, 37, 20.8; (V) 1500-3000 years old: <1%, 1, unknown. At least 4.5-6 km3 of tholeiitic basalt have been erupted from the LERZ during the past 1500 years. Estimated volumes of the exposed products of individual eruptions range from a few tens of cubic meters for older units in small kipukas to as much as 0.4 km3 for the heiheiahulu shield. The average dormant interval has been about 13.6 years during the past 1500 years. The most recent eruption occurred in 1961, and the area may be overdue for its next eruption. However, eruptive activity will not resume on the LERZ until either the dike feeding the current eruption on the middle east rift zone extends farther down rift, or a new dike, unrelated to the current eruption, extends into the LERZ. ?? 1992 Springer-Verlag.

Bulletin of Volcanology↗

USGS1994

A synthesis of post-glacial diatom records from Lake Baikal

The biostratigraphy of fossil diatoms contributes important chronologic, paleolimnologic, and paleoclimatic information from Lake Baikal in southeastern Siberia. Diatoms are the dominant and best preserved microfossils in the sediments, and distinctive assemblages and species provide inter-core correlations throughout the basin at millennial to centennial scales, in both high and low sedimentation-rate environments. Distributions of unique species, once dated by radiocarbon, allow diatoms to be used as dating tools for the Holocene history of the lake. Diatom, pollen, and organic geochemical records from site 305, at the foot of the Selenga Delta, provide a history of paleolimnologic and paleoclimatic changes from the late glacial (15 ka) through the Holocene. Before 14 ka diatoms were very rare, probably because excessive turbidity from glacial meltwater entering the lake impeded productivity. Between 14 and 12 ka, lake productivity increased, perhaps as strong winds promoted deep mixing and nutrient regeneration. Pollen evidence suggests a cold shrub — steppe landscape dominated the central Baikal depression at this time. As summer insolation increased, conifers replaced steppe taxa, but diatom productivity declined between 11 and 9 ka perhaps as a result of increased summer turbidity resulting from violent storm runoff entering the lake via short, steep drainages. After 8 ka, drier, but more continental climates prevailed, and the modern diatom flora of Lake Baikal came to prominence. On Academician Ridge, a site of slow sedimentation rates, Holocene diatom assemblages at the top of 10-m cores reappear at deeper levels suggesting that such cores record at least two previous interglacial (or interstadial?) periods. Nevertheless, distinctive species that developed prior to the last glacial period indicate that the dynamics of nutrient cycling in Baikal and the responsible regional climatic environments were not entirely analogous to Holocene conditions. During glacial periods, the deep basin sediments of Lake Baikal are dominated by rapidly deposited clastics entering from large rivers with possibly glaciated headwaters. On the sublacustrine Academician Ridge (depth = 300 m), however, detailed analysis of the diatom biostratigraphy indicates that diastems (hiatuses of minor duration) and (or) highly variable rates of accumulation complicate paleolimnologic and paleoclimatic reconstructions from these records.

Lake Baikal↗

USGS1984

Great Salt Lake, and precursors, Utah: The last 30,000 years

Sediment cores up to 6.5 m in length from the South Arm of Great Salt Lake, Utah, have been correlated. Radiocarbon ages and volcanic tephra layers indicate a record of greater than 30,000 years. A variety of approaches have been employed to collect data used in stratigraphic correlation and lake elevation interpretation; these include acoustic stratigraphy, sedimentologic analyses, mineralogy, geochemistry (major element, C, O and S isotopes, and organics), paleontology and pollen. The results indicate that prior to 32,000 year B.P. an ephemeral saline lake-playa system was present in the basin. The perennial lake, which has occupied the basin since this time, rose in a series of three major steps; the freshest water conditions and presumably highest altitude was reached at about 17,000 year B.P. The lake remained fresh for a brief period, followed by a rapid increase in salinity and sharp lowering in elevation to levels below that of the present Great Salt Lake. The lake remained at low elevations, and divided at times into a north and south Basin, until about 8,000 year B.P. Since that time, with the exception of two short rises to about 1290 m, the lake level has remained near the present elevation of 1280 m. ?? 1984 Springer-Verlag.

Contributions to Mineralogy and Petrology↗

USGS2016

Holocene vegetation and fire history of the mountains of northern Sicily (Italy)

Knowledge about vegetation and fire history of the mountains of Northern Sicily is scanty. We analysed five sites to fill this gap and used terrestrial plant macrofossils to establish robust radiocarbon chronologies. Palynological records from Gorgo Tondo, Gorgo Lungo, Marcato Cixé, Urgo Pietra Giordano and Gorgo Pollicino show that under natural or near natural conditions, deciduous forests ( Quercus pubescens , Q. cerris , Fraxinus ornus , Ulmus ), that included a substantial portion of evergreen broadleaved species ( Q. suber , Q. ilex , Hedera helix ), prevailed in the upper meso-mediterranean belt. Mesophilous deciduous and evergreen broadleaved trees ( Fagus sylvatica , Ilex aquifolium ) dominated in the natural or quasi-natural forests of the oro-mediterranean belt. Forests were repeatedly opened for agricultural purposes. Fire activity was closely associated with farming, providing evidence that burning was a primary land use tool since Neolithic times. Land use and fire activity intensified during the Early Neolithic at 5000 bc , at the onset of the Bronze Age at 2500 bc and at the onset of the Iron Age at 800 bc . Our data and previous studies suggest that the large majority of open land communities in Sicily, from the coastal lowlands to the mountain areas below the thorny-cushion Astragalus belt (ca. 1,800 m a.s.l.), would rapidly develop into forests if land use ceased. Mesophilous Fagus - Ilex forests developed under warm mid Holocene conditions and were resilient to the combined impacts of humans and climate. The past ecology suggests a resilience of these summer-drought adapted communities to climate warming of about 2 °C. Hence, they may be particularly suited to provide heat and drought-adapted Fagus sylvatica ecotypes for maintaining drought-sensitive Central European beech forests under global warming conditions.

Sicily↗

USGS2003

Staghorn tempestites in the Florida Keys

Thirty-one samples of transported Holocene Acropora cervicornis "sticks" sampled from carbonate sand tempestite accumulations at 19 sites along a 180-km-long stretch of the Florida reef tract were dated using the radiocarbon (14C) method. The "modern fossils" collected from just a few centimeters below the surface ranged in age from 0.5 to 6.4 ka. The majority lived between 3.5 and 5.5 ka. The time of transport and deposition is not known. There were no A. cervicornis samples centered around 4.5 ka. Acropora cervicornis is living on many Florida reefs, but the youngest tempestite sample was 500 years old. Two 500-year-long gaps in dated staghorn suggest that the documented decline in living A. cervicornis over the past 25 years may not be without precedent.

Coral Reefs↗

USGS2011

Coral skeletal carbon isotopes (δ 13 C and Δ 14 C) record the delivery of terrestrial carbon to the coastal waters of Puerto Rico

Tropical small mountainous rivers deliver a poorly quantified, but potentially significant, amount of carbon to the world’s oceans. However, few historical records of land–ocean carbon transfer exist for any region on Earth. Corals have the potential to provide such records, because they draw on dissolved inorganic carbon (DIC) for calcification. In temperate systems, the stable- (δ 13 C) and radiocarbon (Δ 14 C) isotopes of coastal DIC are influenced by the δ 13 C and Δ 14 C of the DIC transported from adjacent rivers. A similar pattern should exist in tropical coastal DIC and hence coral skeletons. Here, δ 13 C and Δ 14 C measurements were made in a 56-year-old Montastraea faveolata coral growing ~1 km from the mouth of the Rio Fajardo in eastern Puerto Rico. Additionally, the δ 13 C and Δ 14 C values of the DIC of the Rio Fajardo and its adjacent coastal waters were measured during two wet and dry seasons. Three major findings were observed: (1) synchronous depletions of both δ 13 C and Δ 14 C in the coral skeleton are annually coherent with the timing of peak river discharge, (2) riverine DIC was always more depleted in δ 13 C and Δ 14 C than seawater DIC, and (3) the correlation of δ 13 C and Δ 14 C was the same in both coral skeleton and the DIC of the river and coastal waters. These results indicate that coral skeletal δ 13 C and Δ 14 C are recording the delivery of riverine DIC to the coastal ocean. Thus, coral records could be used to develop proxies of historical land–ocean carbon flux for many tropical regions. Such information could be invaluable for understanding the role of tropical land–ocean carbon flux in the context of land-use change and global climate change.

Puerto Rico↗

USGS2001

Holocene geomagnetic secular variation recorded by volcanic deposits at Mount St. Helens, Washington

A compilation of paleomagnetic data from volcanic deposits of Mount St. Helens is presented in this report. The database is used to determine signature paleomagnetic directions of products from its Holocene eruptive events, to assign sampled units to their proper eruptive period, and to begin the assembly of a much larger database of paleomagnetic directions from Holocene volcanic rocks in western North America. The paleomagnetic results from Mount St. Helens are mostly of high quality, and generally agree with the division of its volcanic deposits into eruptive episodes based on previous geologic mapping and radiocarbon dates. The Muddy River andesite's paleomagnetic direction, however, indicates that it is more likely part of the Pine Creek eruptive period rather than the Castle Creek period. In addition, the Two-Fingers andesite flow is more likely part of the Middle Kalama eruptive period and not part of the Goat Rocks period. The paleomagnetic data from Mount St. Helens and Mount Hood document variation in the geomagnetic field's pole position over the last ~2,500 years. A distinct feature of the new paleosecular variation (PSV) record, similar to the Fish Lake record (Oregon), indicates a sudden change from rapid clockwise movement of the pole about the Earth's spin axis to relatively slow counterclockwise movement at ???800 to 900 years B.P.

Bulletin of Volcanology↗

USGS1998

Tsunami generation by pyroclastic flow during the 3500-year B.P. caldera-forming eruption of Aniakchak Volcano, Alaska

A discontinuous pumiceous sand, a few centimeters to tens of centimeters thick, is located up to 15 m above mean high tide within Holocene peat along the northern Bristol Bay coastline of Alaska. The bed consists of fine-to-coarse, poorly to moderately well-sorted, pumice-bearing sand near the top of a 2-m-thick peat sequence. The sand bed contains rip-up clasts of peat and tephra and is unique in the peat sequence. Major element compositions of juvenile glass from the deposit and radiocarbon dating of enclosing peat support correlation of the pumiceous sand with the caldera-forming eruption of Aniakchak Volcano. The distribution of the sand and its sedimentary characteristics are consistent with emplacement by tsunami. The pumiceous sand most likely represents redeposition by tsunami of climactic fallout tephra and beach sand during the approximately 3.5 ka Aniakchak caldera-forming eruption on the Alaska Peninsula. We propose that a tsunami was generated by the sudden entrance of a rapidly moving, voluminous pyroclastic flow from Aniakchak into Bristol Bay. A seismic trigger for the tsunami is unlikely, because tectonic structures suitable for tsunami generation are present only south of the Alaska Peninsula. The pumiceous sand in coastal peat of northern Bristol Bay is the first documented geologic evidence of a tsunami initiated by a volcanic eruption in Alaska.

Alaska↗

USGS1999

Kilauea summit overflows: Their ages and distribution in the Puna District, Hawai'i

The tube-fed pahoehoe lava flows covering much of the northeast flank of Kilauea Volcano are named the 'Aila'au flows. Their eruption age, based on published and six new radiocarbon dates, is approximately AD 1445. The flows have distinctive paleomagnetic directions with steep inclinations (40??-50??) and easterly declinations (0??-10??E). The lava was transported ~40 km from the vent to the coast in long, large-diameter lava tubes; the longest tube (Kazumura Cave) reaches from near the summit to within several kilometers of the coast near Kaloli Point. The estimated volume of the 'Aila'au flow field is 5.2 ?? 0.8 km3, and the eruption that formed it probably lasted for approximately 50 years. Summit overflows from Kilauea may have been nearly continuous between approximately AD 1290 and 1470, during which time a series of shields formed at and around the summit. The 'Aila'au shield was either the youngest or the next to youngest in this series of shields. Site-mean paleomagnetic directions for lava flows underlying the 'Aila'au flows form only six groups. These older pahoehoe flows range in age from 2750 to <18,000 BP, and the region was inundated by lava flows only three times in the past 5000 years. The known intervals between eruptive events average ~1600 years and range from ~1250 years to >2200 years. Lava flows from most of these summit eruptions also reached the coast, but none appears as extensive as the 'Aila'au flow field. The chemistry of the melts erupted during each of these summit overflow events is remarkably similar, averaging approximately 6.3 wt.% MgO near the coast and 6.8 wt.% MgO near the summit. The present-day caldera probably formed more recently than the eruption that formed the 'Aila'au flows (estimated termination ca. AD 1470). The earliest explosive eruptions that formed the Keanakako'i Ash, which is stratigraphically above the 'Aila'au flows, cannot be older than this age.

Bulletin of Volcanology↗

USGS2000

Stratigraphic and structural evolution of the Selenga Delta Accommodation Zone, Lake Baikal Rift, Siberia

Seismic reflection profiles from the Lake Baikal Rift reveal extensive details about the sediment thickness, structural geometry and history of extensional deformation and syn-rift sedimentation in this classic continental rift. The Selenga River is the largest single source of terrigenous input into Lake Baikal, and its large delta sits astride the major accommodation zone between the Central and South basins of the lake. Incorporating one of the world's largest lacustrine deltas, this depositional system is a classic example of the influence of rift basin structural segmentation on a major continental drainage. More than 3700 km of deep basin-scale multi-channel seismic reflection (MCS) data were acquired during the 1989 Russian and the 1992 Russian–American field programs. The seismic data image most of the sedimentary section, including pre-rift basement in several localities. The MCS data reveal that the broad bathymetric saddle between these two major half-graben basins is underlain by a complex of severely deformed basement blocks, and is not simply a consequence of long-term deltaic deposition. Maximum sediment thickness is estimated to be more than 9 km in some areas around the Selenga Delta. Detailed stratigraphic analyses of the Selenga area MCS data suggest that modes of deposition have shifted markedly during the history of the delta. The present mode of gravity- and mass-flow sedimentation that dominates the northern and southern parts of the modern delta, as well as the pronounced bathymetric relief in the area, are relatively recent developments in the history of the Lake Baikal Rift. Several episodes of major delta progradation, each extending far across the modern rift, can be documented in the MCS data. The stratigraphic framework defined by these prograding deltaic sequences can be used to constrain the structural as well as depositional evolution of this part of the Baikal Rift. An age model has been established for this stratigraphy, by tying the delta sequences to the site of the Baikal Drilling Project 1993 Drill Hole. Although the drill hole is only 100 m deep, and the base of the cores is only ∼670 ka in age, ages were extrapolated to deeper stratigraphic intervals using the Reflection-Seismic-Radiocarbon method of Cohen et al. (1993). The deep prograding delta sequences now observed in the MCS data probably formed in response to major fluctuations in sediment supply, rather than in response to shifts in lake level. This stratigraphic framework and age model suggest that the deep delta packages developed at intervals of approximately 400 ka and may have formed as a consequence of climate changes affiliated with the northern hemisphere glaciations. The stratigraphic analysis also suggests that the Selenga Basin and Syncline developed as a distinct depocentre only during the past ∼2–3 Ma.

Lake Baikal Rift↗

USGS2015

Differences in ecosystem carbon distribution and nutrient cycling linked to forest tree species composition in a mid-successional boreal forest

In the boreal forest of Alaska, increased fire severity associated with climate change is expanding deciduous forest cover in areas previously dominated by black spruce ( Picea mariana ). Needle-leaf conifer and broad-leaf deciduous species are commonly associated with differences in tree growth, carbon (C) and nutrient cycling, and C accumulation in soils. Although this suggests that changes in tree species composition in Alaska could impact C and nutrient pools and fluxes, few studies have measured these linkages. We quantified C, nitrogen, phosphorus, and base cation pools and fluxes in three stands of black spruce and Alaska paper birch ( Betula neoalaskana ) that established following a single fire event in 1958. Paper birch consistently displayed characteristics of more rapid C and nutrient cycling, including greater aboveground net primary productivity, higher live foliage and litter nutrient concentrations, and larger ammonium and nitrate pools in the soil organic layer (SOL). Ecosystem C stocks (aboveground + SOL + 0–10 cm mineral soil) were similar for the two species; however, in black spruce, 78% of measured C was found in soil pools, primarily in the SOL, whereas aboveground biomass dominated ecosystem C pools in birch forest. Radiocarbon analysis indicated that approximately one-quarter of the black spruce SOL C accumulated prior to the 1958 fire, whereas no pre-fire C was observed in birch soils. Our findings suggest that tree species exert a strong influence over C and nutrient cycling in boreal forest and forest compositional shifts may have long-term implications for ecosystem C and nutrient dynamics.

Ecosystems↗

USGS2005

Geochemistry and the understanding of ground-water systems

Geochemistry has contributed significantly to the understanding of ground-water systems over the last 50 years. Historic advances include development of the hydrochemical facies concept, application of equilibrium theory, investigation of redox processes, and radiocarbon dating. Other hydrochemical concepts, tools, and techniques have helped elucidate mechanisms of flow and transport in ground-water systems, and have helped unlock an archive of paleoenvironmental information. Hydrochemical and isotopic information can be used to interpret the origin and mode of ground-water recharge, refine estimates of time scales of recharge and ground-water flow, decipher reactive processes, provide paleohydrological information, and calibrate ground-water flow models. Progress needs to be made in obtaining representative samples. Improvements are needed in the interpretation of the information obtained, and in the construction and interpretation of numerical models utilizing hydrochemical data. The best approach will ensure an optimized iterative process between field data collection and analysis, interpretation, and the application of forward, inverse, and statistical modeling tools. Advances are anticipated from microbiological investigations, the characterization of natural organics, isotopic fingerprinting, applications of dissolved gas measurements, and the fields of reaction kinetics and coupled processes. A thermodynamic perspective is offered that could facilitate the comparison and understanding of the multiple physical, chemical, and biological processes affecting ground-water systems.

Hydrogeology Journal↗

USGS2016

Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine, Arizona (USA)

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio 234 U/ 238 U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.

Arizona↗