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At least 289 records · Page 16Linked to original sources

USGS2018

Input data processing tools for the integrated hydrologic model GSFLOW

Integrated hydrologic modeling (IHM) encompasses a vast number of processes and specifications, variable in time and space, and development of models can be arduous. Model input construction techniques have not been formalized or made easily reproducible. Creating the input files for integrated hydrologic models requires complex GIS processing of raster and vector datasets from various sources. Developing stream network topology that is consistent with the model grid-scale digital elevation model (DEM) is important for robust simulation of surface water and groundwater exchanges. Distribution of meteorological data over the model domain is difficult in complex terrain at the model-grid scale, but is necessary for realistic simulations. As model development requires extensive GIS and computer programming expertise, the use of IHMs has mostly been limited to research groups with available financial, human, and technical resources. Here we present a series of open-source Python scripts that are combined with ESRI ArcGIS to provide a formalized technique for the parameterization and development of inputs for the readily available IHM called GSFLOW. This Python toolkit automates many of the necessary and laborious processes of parameterization, including stream network development, land coverages, and meteorological distribution over the model domain. The final products of the toolkit are PRMS ready Parameter Files, along with several input parameters for a MODFLOW model, including input for the Streamflow Routing Package. A demonstration of the toolkit is provided to illustrate its capabilities.

Environmental Modelling and Software↗

USGS2005

Conceptual model of sediment processes in the upper Yuba River watershed, Sierra Nevada, CA

This study examines the development of a conceptual model of sediment processes in the upper Yuba River watershed; and we hypothesize how components of the conceptual model may be spatially distributed using a geographical information system (GIS). The conceptual model illustrates key processes controlling sediment dynamics in the upper Yuba River watershed and was tested and revised using field measurements, aerial photography, and low elevation videography. Field reconnaissance included mass wasting and channel storage inventories, assessment of annual channel change in upland tributaries, and evaluation of the relative importance of sediment sources and transport processes. Hillslope erosion rates throughout the study area are relatively low when compared to more rapidly eroding landscapes such as the Pacific Northwest and notable hillslope sediment sources include highly erodible andesitic mudflows, serpentinized ultramafics, and unvegetated hydraulic mine pits. Mass wasting dominates surface erosion on the hillslopes; however, erosion of stored channel sediment is the primary contributor to annual sediment yield. We used GIS to spatially distribute the components of the conceptual model and created hillslope erosion potential and channel storage models. The GIS models exemplify the conceptual model in that landscapes with low potential evapotranspiration, sparse vegetation, steep slopes, erodible geology and soils, and high road densities display the greatest hillslope erosion potential and channel storage increases with increasing stream order. In-channel storage in upland tributaries impacted by hydraulic mining is an exception. Reworking of stored hydraulic mining sediment in low-order tributaries continues to elevate upper Yuba River sediment yields. Finally, we propose that spatially distributing the components of a conceptual model in a GIS framework provides a guide for developing more detailed sediment budgets or numerical models making it an inexpensive way to develop a roadmap for understanding sediment dynamics at a watershed scale.

Geomorphology↗

USGS2006

Controls on soil pore water solutes: An approach for distinguishing between biogenic and lithogenic processes

Spatial and temporal variations in pore water compositions are characterized for a deep regolith profile developed on a marine terrace chronosequence near Santa Cruz California. Variations are resolved in terms of the dominance of either a lithogenic process, i.e. chemical weathering, or a biogenic process, i.e. plant nutrient cycling. The concept of elemental fractionation is introduced describing the extent that specific elements are mobilized and cycled as a result of these processes.

Journal of Geochemical Exploration↗

USGS2017

The role of deep-water sedimentary processes in shaping a continental margin: The Northwest Atlantic

The tectonic history of a margin dictates its general shape; however, its geomorphology is generally transformed by deep-sea sedimentary processes. The objective of this study is to show the influences of turbidity currents, contour currents and sediment mass failures on the geomorphology of the deep-water northwestern Atlantic margin (NWAM) between Blake Ridge and Hudson Trough, spanning about 32° of latitude and the shelf edge to the abyssal plain. This assessment is based on new multibeam echosounder data, global bathymetric models and sub-surface geophysical information. The deep-water NWAM is divided into four broad geomorphologic classifications based on their bathymetric shape: graded, above-grade, stepped and out-of-grade. These shapes were created as a function of the balance between sediment accumulation and removal that in turn were related to sedimentary processes and slope-accommodation. This descriptive method of classifying continental margins, while being non-interpretative, is more informative than the conventional continental shelf, slope and rise classification, and better facilitates interpretation concerning dominant sedimentary processes. Areas of the margin dominated by turbidity currents and slope by-pass developed graded slopes. If sediments did not by-pass the slope due to accommodation then an above grade or stepped slope resulted. Geostrophic currents created sedimentary bodies of a variety of forms and positions along the NWAM. Detached drifts form linear, above-grade slopes along their crests from the shelf edge to the deep basin. Plastered drifts formed stepped slope profiles. Sediment mass failure has had a variety of consequences on the margin morphology; large mass-failures created out-of-grade profiles, whereas smaller mass failures tended to remain on the slope and formed above-grade profiles at trough-mouth fans, or nearly graded profiles, such as offshore Cape Fear.

Marine Geology↗

USGS2016

Optimization of a sample processing protocol for recovery of Bacillus anthracis spores from soil

Following a release of Bacillus anthracis spores into the environment, there is a potential for lasting environmental contamination in soils. There is a need for detection protocols for B. anthracis in environmental matrices. However, identification of B. anthracis within a soil is a difficult task. Processing soil samples helps to remove debris, chemical components, and biological impurities that can interfere with microbiological detection. This study aimed to optimize a previously used indirect processing protocol, which included a series of washing and centrifugation steps. Optimization of the protocol included: identifying an ideal extraction diluent, variation in the number of wash steps, variation in the initial centrifugation speed, sonication and shaking mechanisms. The optimized protocol was demonstrated at two laboratories in order to evaluate the recovery of spores from loamy and sandy soils. The new protocol demonstrated an improved limit of detection for loamy and sandy soils over the non-optimized protocol with an approximate matrix limit of detection at 14 spores/g of soil. There were no significant differences overall between the two laboratories for either soil type, suggesting that the processing protocol will be robust enough to use at multiple laboratories while achieving comparable recoveries.

Journal of Microbiological Methods↗

USGS2025

Assimilatory processes dominate diel inorganic nitrogen cycling in a shallow open-water constructed wetland

Shallow, unit process open water (UPOW) constructed wetlands effectively remove a range of water contaminants. Yet, much remains to be learned about internal carbon and nitrogen cycling within these systems and their diel functionality. The current study focused on light/dark fluctuations in water column and biomat geochemistry and N cycle processes in a field-scale UPOW. Dissolved oxygen concentrations fluctuated daily from 50 to 250 % air saturation, while nitrate (NO 3 − ) and ammonium (NH 3+4 ) concentrations cyclically ranged from 30 to 125 μM and 2–20 μM, respectively. NO 3 − concentrations increased at night and decreased during the day, while N isotope values (δ 15 N-[NO 3 − ]) varied inversely with concentration. Ammonium concentrations and N isotope values (δ 15 N-[NH 3+4 ]) both increased at night, decreasing during the day. Column incubations containing biomat and overlying water, conducted in situ with 15 N-NO 2 − , determined nearly equivalent rates of nitrite production and denitrification in the dark (6.6 and 7.2 μmol L −1 d −1 , respectively), but both decreased 82–84% in daylight. Combined nighttime rates of anammox and dissimilatory NO 3 − reduction to NH 3+4 (DNRA) were nearly equal to denitrification. A time-step N process model was used to reproduce diel N species concentration and stable isotope changes, and N dissimilatory rates. Best-fit results to field data indicated that N photoassimilation rates far outpaced dissimilatory rates in either light or dark conditions while denitrification and DNRA rates were greater than incubation-measured rates. Redox gradients and potential diatom migration within the biomat, coupled with diatom DNRA respiration, are factors that complicate the diel function and wetland efficacy by short-circuiting N removal as nitrogen gas.

California↗

USGS2005

Processing of strong-motion accelerograms: Needs, options and consequences

Recordings from strong-motion accelerographs are of fundamental importance in earthquake engineering, forming the basis for all characterizations of ground shaking employed for seismic design. The recordings, particularly those from analog instruments, invariably contain noise that can mask and distort the ground-motion signal at both high and low frequencies. For any application of recorded accelerograms in engineering seismology or earthquake engineering, it is important to identify the presence of this noise in the digitized time-history and its influence on the parameters that are to be derived from the records. If the parameters of interest are affected by noise then appropriate processing needs to be applied to the records, although it must be accepted from the outset that it is generally not possible to recover the actual ground motion over a wide range of frequencies. There are many schemes available for processing strong-motion data and it is important to be aware of the merits and pitfalls associated with each option. Equally important is to appreciate the effects of the procedures on the records in order to avoid errors in the interpretation and use of the results. Options for processing strong-motion accelerograms are presented, discussed and evaluated from the perspective of engineering application. ?? 2004 Elsevier Ltd. All rights reserved.

Soil Dynamics and Earthquake Engineering↗

USGS2000

Temporal variations in parameters reflecting terminal-electron-accepting processes in an aquifer contaminated with waste fuel and chlorinated solvents

A fundamental issue in aquifer biogeochemistry is the means by which solute transport, geochemical processes, and microbiological activity combine to produce spatial and temporal variations in redox zonation. In this paper, we describe the temporal variability of TEAP conditions in shallow groundwater contaminated with both waste fuel and chlorinated solvents. TEAP parameters (including methane, dissolved iron, and dissolved hydrogen) were measured to characterize the contaminant plume over a 3-year period. We observed that concentrations of TEAP parameters changed on different time scales and appear to be related, in part, to recharge events. Changes in all TEAP parameters were observed on short time scales (months), and over a longer 3-year period. The results indicate that (1) interpretations of TEAP conditions in aquifers contaminated with a variety of organic chemicals, such as those with petroleum hydrocarbons and chlorinated solvents, must consider additional hydrogen-consuming reactions (e.g., dehalogenation); (2) interpretations must consider the roles of both in situ (at the sampling point) biogeochemical and solute transport processes; and (3) determinations of microbial communities are often necessary to confirm the interpretations made from geochemical and hydrogeological measurements on these processes.

Michigan↗

USGS2001

Wildfire-related debris-flow initiation processes, Storm King Mountain, Colorado

A torrential rainstorm on September 1, 1994 at the recently burned hillslopes of Storm King Mountain, CO, resulted in the generation of debris flows from every burned drainage basin. Maps (1:5000 scale) of bedrock and surficial materials and of the debris-flow paths, coupled with a 10-m Digital Elevation Model (DEM) of topography, are used to evaluate the processes that generated fire-related debris flows in this setting. These evaluations form the basis for a descriptive model for fire-related debris-flow initiation. The prominent paths left by the debris flows originated in 0- and 1st-order hollows or channels. Discrete soil-slip scars do not occur at the heads of these paths. Although 58 soil-slip scars were mapped on hillslopes in the burned basins, material derived from these soil slips accounted for only about 7% of the total volume of material deposited at canyon mouths. This fact, combined with observations of significant erosion of hillslope materials, suggests that a runoff-dominated process of progressive sediment entrainment by surface runoff, rather than infiltration-triggered failure of discrete soil slips, was the primary mechanism of debris-flow initiation. A paucity of channel incision, along with observations of extensive hillslope erosion, indicates that a significant proportion of material in the debris flows was derived from the hillslopes, with a smaller contribution from the channels. Because of the importance of runoff-dominated rather than infiltration-dominated processes in the generation of these fire-related debris flows, the runoff-contributing area that extends upslope from the point of debris-flow initiation to the drainage divide, and its gradient, becomes a critical constraint in debris-flow initiation. Slope-area thresholds for fire-related debris-flow initiation from Storm King Mountain are defined by functions of the form Acr(tan ??)3 = S, where Acr is the critical area extending upslope from the initiation location to the drainage divide, and tan ?? is its gradient. The thresholds vary with different materials. ?? 2001 Elsevier Science B.V. All rights reserved.

Geomorphology↗

USGS2006

Chapter 13 Petrogenesis of the Campanian Ignimbrite: Implications for crystal-melt separation and open-system processes from major and trace elements and Th isotopic data

The Campanian Ignimbrite is a large-volume trachytic to phonolitic ignimbrite that was deposited at ≈39.3 ka and represents one of a number of highly explosive volcanic events that have occurred in the region near Naples, Italy. Thermodynamic modeling using the MELTS algorithm reveals that major element variations are dominated by crystal-liquid separation at 0.15 GPa. Initial dissolved H 2 O content in the parental melt is ∼3 wt.% and the magmatic system fugacity of oxygen was buffered along QFM+1. Significantly, MELTS results also indicate that the liquid line of descent is marked by a large change in the proportion of melt (from 0.46 to 0.09) at ∼884°C, which leads to a discontinuity in melt composition (i.e., a compositional gap) and different thermodynamic and transport properties of melt and magma across the gap. Crystallization of alkali feldspar and plagioclase dominates the phase assemblage at this pseudo-invariant point temperature of ∼884°C. Evaluation of the variations in the trace elements Zr, Nb, Th, U, Rb, Sm, and Sr using a mass balance equation that accounts for changing bulk mineral-melt partition coefficients as crystallization occurs indicates that crystal-liquid separation and open-system processes were important. Th isotope data yield an apparent isochron that is ∼20 kyr younger than the age of the deposit, and age-corrected Th isotope data indicate that the magma body was an open system at the time of eruption. Because open-system behavior can profoundly change isotopic and elemental characteristics of a magma body, these Th results illustrate that it is critical to understand the contribution that open-system processes make to magmatic systems prior to assigning relevance to age or timescale information derived from such systems. Fluid-magma interaction has been proposed as a mechanism to change isotopic and elemental characteristics of magma bodies, but an evaluation of the mass and thermal constraints on such a process suggests large-scale interaction is unlikely. In the case of the magma body associated with the Campanian Ignimbrite, the most likely source of the open-system signatures is assimilation of partial melts of compositionally heterogeneous basement composed of cumulates and intrusive equivalents of volcanic activity that has characterized the Campanian region for over 300 kyr.

Developments in Volcanology↗

USGS2009

Estimation of potential loss of two pesticides in runoff in Fillmore County, Minnesota using a field-scale process-based model and a geographic information system

In assessing the occurrence, behavior, and effects of agricultural chemicals in surface water, the scales of study (i.e., watershed, county, state, and regional areas) are usually much larger than the scale of agricultural fields, where much of the understanding of processes has been developed. Field-scale areas are characterized by relatively homogeneous conditions. The combination of process-based simulation models and geographic information system technology can be used to help extend our understanding of field processes to water-quality concerns at larger scales. To demonstrate this, the model "Groundwater Loading Effects of Agricultural Management Systems" was used to estimate the potential loss of two pesticides (atrazine and permethrin) in runoff to surface water in Fillmore County in southeastern Minnesota. The county was divided into field-scale areas on the basis of a 100 m by 100 m grid, and the influences of soil type and surface topography on the potential losses of the two pesticides in runoff was evaluated for each individual grid cell. The results could be used for guidance for agricultural management and regulatory decisions, for planning environmental monitoring programs, and as an educational tool for the public.

Minnesota↗

USGS1996

Comparison of Eh and H2 measurements for delineating redox processes in a contaminated aquifer

Measurements of oxidation-reduction potential ( E h ) and concentrations of dissolved hydrogen (H 2 ) were made in a shallow groundwater system contaminated with solvents and jet fuel to delineate the zonation of redox processes. E h measurements ranged from +69 to -158 mV in a cross section of the contaminated plume and accurately delineated oxic from anoxic groundwater. Plotting measured E h and pH values on an equilibrium stability diagram indicated that Fe(III) reduction was the predominant redox process in the anoxic zone and did not indicate the presence of methanogenesis and sulfate reduction. In contrast, measurements of H 2 concentrations indicated that methanogenesis predominated in heavily contaminated sediments near the water table surface (H 2 ∼ 7.0 nM) and that the methanogenic zone was surrounded by distinct sulfate-reducing (H 2 ∼ 1-4 nM) and Fe(III)-reducing (H 2 ∼ 0.1-0.8 nM) zones. The presence of methanogenesis, sulfate reduction, and Fe(III) reduction was confirmed by the distribution of dissolved oxygen, sulfate, Fe(II), and methane in groundwater. These results show that H 2 concentrations were more useful for identifying anoxic redox processes than E h measurements in this groundwater system. However, H 2 -based redox zone delineations are more reliable when H 2 concentrations are interpreted in the context of electron-acceptor (oxygen, nitrate, sulfate) availability and the presence of final products [Fe(II), sulfide, methane] of microbial metabolism.

Environmental Science & Technology↗

USGS2001

Geological processes and evolution

Geological mapping and establishment of stratigraphic relationships provides an overview of geological processes operating on Mars and how they have varied in time and space. Impact craters and basins shaped the crust in earliest history and as their importance declined, evidence of extensive regional volcanism emerged during the Late Noachian. Regional volcanism characterized the Early Hesperian and subsequent to that time, volcanism was largely centered at Tharsis and Elysium, continuing until the recent geological past. The Tharsis region appears to have been largely constructed by the Late Noachian, and represents a series of tectonic and volcanic centers. Globally distributed structural features representing contraction characterize the middle Hesperian. Water-related processes involve the formation of valley networks in the Late Noachian and into the Hesperian, an ice sheet at the south pole in the middle Hesperian, and outflow channels and possible standing bodies of water in the northern lowlands in the Late Hesperian and into the Amazonian. A significant part of the present water budget occurs in the present geologically young polar layered terrains. In order to establish more firmly rates of processes, we stress the need to improve the calibration of the absolute timescale, which today is based on crater count systems with substantial uncertainties, along with a sampling of rocks of unknown provenance. Sample return from carefully chosen stratigraphic units could calibrate the existing timescale and vastly improve our knowledge of Martian evolution.

Conference Paper↗

USGS2001

Carbon balance of the terrestrial biosphere in the twentieth century: analyses of CO 2 , climate and land use effects with four process-based ecosystem models

The concurrent effects of increasing atmospheric CO 2 concentration, climate variability, and cropland establishment and abandonment on terrestrial carbon storage between 1920 and 1992 were assessed using a standard simulation protocol with four process-based terrestrial biosphere models. Over the long-term(1920–1992), the simulations yielded a time history of terrestrial uptake that is consistent (within the uncertainty) with a long-term analysis based on ice core and atmospheric CO 2 data. Up to 1958, three of four analyses indicated a net release of carbon from terrestrial ecosystems to the atmosphere caused by cropland establishment. After 1958, all analyses indicate a net uptake of carbon by terrestrial ecosystems, primarily because of the physiological effects of rapidly rising atmospheric CO 2 . During the 1980s the simulations indicate that terrestrial ecosystems stored between 0.3 and 1.5 Pg C yr−1, which is within the uncertainty of analysis based on CO 2 and O 2 budgets. Three of the four models indicated (in accordance with O 2 evidence) that the tropics were approximately neutral while a net sink existed in ecosystems north of the tropics. Although all of the models agree that the long-term effect of climate on carbon storage has been small relative to the effects of increasing atmospheric CO 2 and land use, the models disagree as to whether climate variability and change in the twentieth century has promoted carbon storage or release. Simulated interannual variability from 1958 generally reproduced the El Niño/Southern Oscillation (ENSO)-scale variability in the atmospheric CO 2 increase, but there were substantial differences in the magnitude of interannual variability simulated by the models. The analysis of the ability of the models to simulate the changing amplitude of the seasonal cycle of atmospheric CO 2 suggested that the observed trend may be a consequence of CO 2 effects, climate variability, land use changes, or a combination of these effects. The next steps for improving the process-based simulation of historical terrestrial carbon include (1) the transfer of insight gained from stand-level process studies to improve the sensitivity of simulated carbon storage responses to changes in CO 2 and climate, (2) improvements in the data sets used to drive the models so that they incorporate the timing, extent, and types of major disturbances, (3) the enhancement of the models so that they consider major crop types and management schemes, (4) development of data sets that identify the spatial extent of major crop types and management schemes through time, and (5) the consideration of the effects of anthropogenic nitrogen deposition. The evaluation of the performance of the models in the context of a more complete consideration of the factors influencing historical terrestrial carbon dynamics is important for reducing uncertainties in representing the role of terrestrial ecosystems in future projections of the Earth system.

Global Biogeochemical Cycles↗

USGS2002

Using chemical, hydrologic, and age dating analysis to delineate redox processes and flow paths in the riparian zone of a glacial outwash aquifer‐stream system

A combination of chemical and dissolved gas analyses, chlorofluorocarbon age dating, and hydrologic measurements were used to determine the degree to which biogeochemical processes in a riparian wetland were responsible for removing NO 3 − from groundwaters discharging to the Otter Tail River in west central Minnesota. An analysis of river chemistry and flow data revealed that NO 3 − concentrations in the river increased in the lower half of the 8.3 km study reach as the result of groundwater discharge to the river. Groundwater head measurements along a study transect through the riparian wetland revealed a zone of groundwater discharge extending out under the river. On the basis of combined chemical, dissolved gas, age date, and hydrologic results, it was determined that water chemistry under the riparian wetland was controlled largely by upgradient groundwaters that followed flow paths up to 16 m deep and discharged under the wetland, creating a pattern of progressively older, more chemically reduced, low NO 3 − water the farther one progressed from the edge of the wetland toward the river. These findings pose challenges for researchers investigating biogeochemical processes in riparian buffer zones because the progressively older groundwaters entered the aquifer in earlier years when less NO 3 − fertilizer was being used. NO 3 − concentrations originally present in the groundwater had also decreased in the upgradient aquifer as a result of denitrification and progressively stronger reducing conditions there. The resulting pattern of decreasing NO 3 − concentrations across the riparian zone may be incorrectly interpreted as evidence of denitrification losses there instead of in the upgradient aquifer. Consequently, it is important to understand the hydrogeologic setting and age structure of the groundwaters being sampled in order to avoid misinterpreting biogeochemical processes in riparian zones.

Water Resources Research↗

USGS2006

Aqueous processes at Gusev crater inferred from physical properties of rocks and soils along the Spirit traverse

Gusev crater was selected as the landing site for Spirit on the basis of morphological evidence of long-lasting water activity, including possibly fluvial and lacustrine episodes. From the Columbia Memorial Station to the Columbia Hills, Spirit's traverse provides a journey back in time, from relatively recent volcanic plains showing little evidence for aqueous processes up to the older hills, where rock and soil composition are drastically different. For the first 156 sols, the only evidence of water action was weathering rinds, vein fillings, and soil crust cementation by salts. The trenches of Sols 112-145 marked the first significant findings of increased concentrations of sulfur and magnesium varying in parallel, suggesting that they be paired as magnesium-sulfate. Spirit's arrival at West Spur coincided with a shift in rock and soil composition with observations hinting at substantial amounts of water in Gusev's past. We used the Microscopic Imager data up to Sol 431 to analyze rock and soil properties and infer plausible types and magnitude of aqueous processes through time. We show the role played early by topography and structure. The morphology, texture, and deep alteration shown by the rocks in West Spur and the Columbia Hills Formation (CHF) suggest conditions that are not met in present-day Mars and required a wetter environment, which could have included transport of sulfur, chlorine, and bromine in water, vapor in volcanic gases, hydrothermal circulation, or saturation in a briny fluid containing the same elements. Changing conditions that might have affected flow circulation are suggested by different textural and morphological characteristics between the rocks in the CHF and those of the plains, with higher porosity proxy, higher void ratio, and higher water storage potential in the CHF. Soils were used to assess aqueous processes and water pathways in the top layers of modern soils. We conclude that infiltration might have become more difficult with time.

Journal of Geophysical Research E: Planets↗

USGS2020

Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems

Gas hydrate is an ice-like form of water and low molecular weight gas stable at temperatures of roughly -10ºC to 25ºC and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one-sixth of Earth’s methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean-atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean-atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth’s near-surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some fields studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

Journal of Geophysical Research-Solid Earth↗

USGS2019

Process-guided deep learning predictions of lake water temperature

The rapid growth of data in water resources has created new opportunities to accelerate knowledge discovery with the use of advanced deep learning tools. Hybrid models that integrate theory with state‐of‐the art empirical techniques have the potential to improve predictions while remaining true to physical laws. This paper evaluates the Process‐Guided Deep Learning (PGDL) hybrid modeling framework with a use‐case of predicting depth‐specific lake water temperatures. The PGDL model has three primary components: a deep learning model with temporal awareness (long short‐term memory recurrence), theory‐based feedback (model penalties for violating conversation of energy), and model pretraining to initialize the network with synthetic data (water temperature predictions from a process‐based model). In situ water temperatures were used to train the PGDL model, a deep learning (DL) model, and a process‐based (PB) model. Model performance was evaluated in various conditions, including when training data were sparse and when predictions were made outside of the range in the training data set. The PGDL model performance (as measured by root‐mean‐square error (RMSE)) was superior to DL and PB for two detailed study lakes, but only when pretraining data included greater variability than the training period. The PGDL model also performed well when extended to 68 lakes, with a median RMSE of 1.65 °C during the test period (DL: 1.78 °C, PB: 2.03 °C; in a small number of lakes PB or DL models were more accurate). This case‐study demonstrates that integrating scientific knowledge into deep learning tools shows promise for improving predictions of many important environmental variables.

Minnesota, Wisconsin↗