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Methods of analysis by the U. S. Geological Survey National Water Quality Laboratory-Determination of organic plus inorganic mercury in filtered and unfiltered natural water with cold vapor; atomic fluorescence spectrometry

An analytical method using cold vapor-atomic fluorescence spectrometry was developed by the U.S. Geological Survey in 2001 for the determination of organic plus inorganic mercury in filtered and unfiltered natural water. This method was developed to eliminate the use of acid dichromate preservative and to provide capability to measure ambient mercury concentrations in natural water. Dissolved mercury includes all oxidizable mercury species present in natural water that has been filtered through a 0.45- micrometer pore size capsule filter. Wholewater recoverable mercury includes dissolved mercury species and mercury species adsorbed to particulate matter in unfiltered natural water. Mercury species can include elemental mercury, mercury (II), mercury (II) complexes, various alkyl- and phenylmercury compounds, and other forms of mercury. In this method, samples are collected and processed according to standard U.S. Geological Survey protocols. Samples are preserved onsite with 6N hydrochloric acid in a ratio of 1 to 100 in a borosilicateglass bottle with fluoropolymer-lined cap. Mercury species are oxidized to mercury (II) by using bromine monochloride; excess oxidation reagent is neutralized with hydroxylamine hydrochloride. Elemental mercury produced after adding stannous chloride is purged from the solution with ultrapure argon gas into a cell in which the mercury concentration is measured by atomic fluorescence emission at 253.7 nanometers. The analytical response is linear up to 125 nanograms per liter (ng/L) of mercury, and the short-term method detection limit is about 5 ng/L. The analytical variability at 50 ng/L is about 10 percent. This report describes the method and compares the use of hydrochloric acid to acid dichromate as a field preservative. Ambient mercury concentrations in hydrochloric acidpreserved samples stored in borosilicate-glass bottles with fluoropolymer-lined caps are shown to be stable for at least 30 days. Mercury concentrations are stable for at least 5 months after bromine monochloride is added to the sample bottles in the laboratory. The long-term average percent recoveries at 20, 45, and 75 ng/L in reagent water, filtered and unfiltered ground water, and filtered and unfiltered surface water range from 89 to 108, 96 to 103, and 94 to 98 percent, respectively.

Water-Resources Investigations Report

Regional equations for estimation of peak-streamflow frequency for natural basins in Texas

Peak-streamflow frequency estimates are needed for flood-plain management; for objective assessment of flood risk; and for cost-effective design of dams, levees, other flood-control structures, roads, bridges, and culverts. Peak-streamflow frequency represents the peak discharges for recurrence intervals of 2, 5, 10, 25, 50, and 100 years. The U.S. Geological Survey, in cooperation with the Texas Department of Transportation, conducted an investigation to develop regional regression equations for the estimation of peak-streamflow frequency for ungaged sites in natural basins in Texas. Peak-streamflow frequency data from streamflow-gaging stations in natural drainage basins of Texas were used. Peak-streamflow frequency for 559 Texas stations with natural (unregulated and rural or nonurbanized) basins was estimated with annual peak-streamflow data through 1993. The peak-streamflow frequency and drainage-basin characteristics for the Texas stations were used to develop 16 sets of equations to estimate peak-streamflow frequency for ungaged natural stream sites in each of 11 regions in Texas. The relation between peak-streamflow frequency and contributing drainage area for 5 of the 11 regions is curvilinear, requiring that one set of equations be developed for drainage areas less than 32 square miles and another set be developed for drainage areas greater than 32 square miles. These equations, developed through multiple-regression analysis using weighted least squares, are based on the relation between peak-streamflow frequency and basin characteristics for streamflow-gaging stations. The regions represent areas with similar flood characteristics. The use and limitations of the regression equations also are discussed. Additionally, procedures are presented to compute the 50-, 67-, and 90-percent confidence limits for any estimation from the equations. Also, supplemental peak-streamflow frequency and basin characteristics for 105 selected stations bordering Texas are included in the report. This supplemental information will aid in interpretation of flood characteristics for sites near the state borders of Texas.

Texas

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from activities of man. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural fresh water. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position: of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken all together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in composition of moving water and the effects of particulate suspended material. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, most probable forms of elements and ions in solution, solubility controls, expected concentration ranges and other chemical factors. Concentrations of elements that are commonly present in amounts less than a few tens of micrograms per liter cannot always be easily explained, but present information suggests many are controlled by solubility of hydroxide or carbonate or by sorption on solid particles. Chemical analyses may be grouped and statistically evaluated by averages, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among waters, probable sources of solutes, areal water-quality regimen, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrologic parameters, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 75 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also utilized in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Activities of man may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of sea water in ground-water aquifiers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural water composition is required for rational management of water quality.

Water Supply Paper

Study and interpretation of the chemical characteristics of natural water

The chemical composition of natural water is derived from many different sources of solutes, including gases and aerosols from the atmosphere, weathering and erosion of rocks and soil, solution or precipitation reactions occurring below the land surface, and cultural effects resulting from human activities. Broad interrelationships among these processes and their effects can be discerned by application of principles of chemical thermodynamics. Some of the processes of solution or precipitation of minerals can be closely evaluated by means of principles of chemical equilibrium, including the law of mass action and the Nernst equation. Other processes are irreversible and require consideration of reaction mechanisms and rates. The chemical composition of the crustal rocks of the Earth and the composition of the ocean and the atmosphere are significant in evaluating sources of solutes in natural freshwater. The ways in which solutes are taken up or precipitated and the amounts present in solution are influenced by many environmental factors, especially climate, structure and position of rock strata, and biochemical effects associated with life cycles of plants and animals, both microscopic and macroscopic. Taken together and in application with the further influence of the general circulation of all water in the hydrologic cycle, the chemical principles and environmental factors form a basis for the developing science of natural-water chemistry. Fundamental data used in the determination of water quality are obtained by the chemical analysis of water samples in the laboratory or onsite sensing of chemical properties in the field. Sampling is complicated by changes in the composition of moving water and by the effects of particulate suspended material. Some constituents are unstable and require onsite determination or sample preservation. Most of the constituents determined are reported in gravimetric units, usually milligrams per liter or milliequivalents per liter. More than 60 constituents and properties are included in water analyses frequently enough to provide a basis for consideration of the sources from which each is generally derived, the most probable forms of elements and ions in solution, solubilitycontrols, expected concentration ranges, and other chemical factors. Mechanisms that control concentrations of elements commonly present in amounts less than a few tens of micrograms per liter cannot always be easily ascertained, but present information suggests that many are controlled by solubility of their hydroxides or carbonates or by sorption on solid particles. Many dissolved organic compounds can now be specifically determined. Chemical analyses may be grouped and statistically evaluated by means, medians, frequency distributions, or ion correlations to summarize large volumes of data. Graphing of analyses or of groups of analyses aids in showing chemical relationships among water, probable sources of solutes, areal water-quality regimen, temporal and spatial variation, and water-resources evaluation. Graphs may show water type based on chemical composition, relationships among ions, or groups of ions in individual waters or many waters considered simultaneously. The relationships of water quality to hydrogeologic characteristics, such as stream discharge rate or ground-water flow patterns, can be shown by mathematical equations, graphs, and maps. About 80 water analyses selected from the literature are tabulated to illustrate the relationships described, and some of these, along with many others that are not tabulated, are also used in demonstrating graphing and mapping techniques. Relationships of water composition to source rock type are illustrated by graphs of some of the tabulated analyses. Human activities may modify water composition extensively through direct effects of pollution and indirect results of water development, such as intrusion of seawater in groundwater aquifers. Water-quality standards for domestic, agricultural, and industrial use have been published by various agencies. Irrigation project requirements for water quality are particularly intricate. Fundamental knowledge of processes that control natural-water composition is required for rational management of water quality.

Water Supply Paper

Collecting a sample of loggerhead sea turtle hatchlings before a natural emergence does not reduce nest productivity

In numerous studies involving hatchling sea turtles, researchers have collected small numbers of hatchlings from nests a few hours before the turtles would otherwise have emerged naturally. This procedure makes it possible to do experiments in which the behavioral or physiological responses of numerous hatchlings must be tested in a limited period of time, and also allows hatchlings to be released back into the sea in time to migrate offshore before dawn. In principle, however, the procedure might inadvertently reduce nest productivity (the number of hatchlings that successfully leave the nest), if digging into a nest prior to emergence somehow reduces the ability of the remaining turtles to emerge. We compared nest productivity in 67 experimental loggerhead nests, from which we removed 10 hatchlings before a natural emergence, to 95 control nests left undisturbed before a natural emergence. The 2 groups showed no statistical differences in productivity. We conclude that taking a few hatchlings from a loggerhead nest shortly before a natural emergence has no negative impact on hatchling production if sampling is done with care at locations where there are few nest predators, and at sites where an emergence can be predicted because nest deposition dates are known.

Florida

Adélie penguins coping with environmental change: Results from a natural experiment at the edge of their breeding range

We investigated life history responses to extreme variation in physical environmental conditions during a long-term demographic study of Adélie penguins at 3 colonies representing 9% of the world population and the full range of breeding colony sizes. Five years into the 14-year study (1997–2010) two very large icebergs (spanning 1.5 latitude degrees in length) grounded in waters adjacent to breeding colonies, dramatically altering environmental conditions during 2001–2005. This natural experiment allowed us to evaluate the relative impacts of expected long-term, but also extreme, short-term climate perturbations on important natural history parameters that can regulate populations. The icebergs presented physical barriers, not just to the penguins but to polynya formation, which profoundly increased foraging effort and movement rates, while reducing breeding propensity and productivity, especially at the smallest colony. We evaluated the effect of a variety of environmental parameters during breeding, molt, migration and wintering periods during years with and without icebergs on penguin breeding productivity, chick mass, and nesting chronology. The icebergs had far more influence on the natural history parameters of penguins than any of the other environmental variables measured, resulting in population level changes to metrics of reproductive performance, including delays in nesting chronology, depressed breeding productivity, and lower chick mass. These effects were strongest at the smallest, southern-most colony, which was most affected by alteration of the Ross Sea Polynya during years the iceberg was present. Additionally, chick mass was negatively correlated with colony size, supporting previous findings indicating density-dependent energetic constraints at the largest colony. Understanding the negative effects of the icebergs on the short-term natural history of Adélie penguins, as well as their response to long-term environmental variation, are important to our overall understanding of climate change effects in this and other species facing both rapid and persistent environmental change.

Frontiers in Ecology and Evolution

A coupled human and natural systems framework to characterize emerging infectious diseases: The case of fibropapillomatosis in marine turtles

Emerging infectious diseases of wildlife have markedly increased in the last few decades. Unsustainable, continuous, and rapid alterations within and between coupled human and natural systems have significantly disrupted wildlife disease dynamics. Direct and indirect anthropogenic effects, such as climate change, pollution, encroachment, urbanization, travel, and trade, can promote outbreaks of infectious diseases in wildlife. We constructed a coupled human and natural systems framework identifying three main wildlife disease risk factors behind these anthropogenic effects: (i) immune suppression, (ii) viral spillover, and (iii) disease propagation. Through complex and convoluted dynamics, each of the anthropogenic effect listed in our framework can lead, to some extent, to one or more of the identified risk factors accelerating disease outbreaks in wildlife. In this review, we present a novel framework to study anthropogenic impacts within coupled human and natural systems that facilitate emergence of infectious disease involving wildlife. We demonstrate the utility of the framework by applying it to Fibropapillomatosis disease of marine turtles. We aim to articulate the intricate and complex nature of anthropogenically-exacerbated wildlife infectious diseases as multifactorial. This paper supports the adoption of a One Health approach and invites the collaboration of multiple disciplines for the achievement of effective and long-lasting conservation and wildlife emerging diseases mitigation outcomes.

Animals

Forested wetlands constructed for mitigation of destroyed natural wetlands

Forested wetlands constructed for mitigation were evaluated at six sites in Maryland to determine the success of these areas for providing suitable wildlife habitat. Natural forested wetlands were used as reference sites. Initial mortality of planted woody shrubs and trees was high (avg. 55%) and mostly attributed to excessive moisture. The number of woody seedlings from natural regeneration was inversely proportional to the amount of grass cover on the site, which was planted for erosion control. The number of volunteer woody seedlings was also inversely proportional to the distance from adjacent natural forests. Preliminary data indicate that cost does not support use of transplants and that enhancement of soil with organic supplements, followed by widespread and heavy seeding of woody plants would be more efficient and effective. Wildlife use of areas measured by avian surveys and trapping of mammals, reptiles, and amphibians showed that in general wildlife species were more representative of open grassland areas than forested habitats. Natural succession of the sites probably will take at least 20-30 years before typical values and functions of forested wetlands are obtained.

Book chapter

Thunder on the Yellowstone revisited: An assessment of management of native ungulates by natural regulation, 1968-1993

Natural regulation of native ungulates was initiated in 1968 in Yellowstone National Park (YNP) based on the premise that ungulates would reach an equilibrium with their plant resources. The natural-regulation management model stated: density dependence will regulate ungulates (i.e., a dynamic equilibrium will result between ungulates and their food supply, within some bounds of vegetation and soil effects); and no retrogression of soil and vegetation will occur from elk (Cervus elaphus) grazing during this process. The historical record indicated that elk were abundant in the system and elk were primarily food limited before settlement by European man (i.e., wolves [Canis lupus] and Native Americans were only an adjunct to the density dependent population regulation of ungulates). Density dependence was demonstrated in elk, but not in bison (Bison bison). No widespread evidence of overgrazing was observed through 1993 in study sites within vegetation communities that comprised about 97% of the winter range. No evidence of increased exotics, increased sediment yield, warming or drying of the soil, changes in soil nutrients, or differences in aboveground standing-crop biomass of plants was found between grazed and ungrazed plots. Ungulate herbivory apparently stimulated aboveground production of grasses, enhanced nitrogen and macronutrients in grasses, increased nutrient cycling, and enhanced measures of fitness in 6 common plants. However, exposed soil surface (bare ground and pebbles combined) was 11-18% greater on grazed than ungrazed plots, apparently due to a 71% decline in dead and standing litter on grazed plots. Percent live-plant basal cover, however, did not differ on grazed versus ungrazed plots, and there was no difference in soil microclimate or sediment yield. Differences in the abundance of 12% of the herbaceous species were found in grazed versus ungrazed sites (16 of 128 species); 10 were declines and 6 were increases. Willow (Salix spp.) and aspen (Populus tremuloides) declines predated the new management policy, but their slow declines also continued after 1968. Three uncommon plant species (aspen, willow, and Wyoming big sagebrush [Artemisia tridentata tridentata]) and 1 herbivore (moose [Alces alces]) declined under natural-regulation management. Two uncommon species of woody browse (aspen, Wyoming big sagebrush) were overutilized by ungulates (consumption of >2/3 current annual growth occurred). We conclude the natural-regulation model for YNP was flawed in its assumptions of a single, steady state for the park, based on conditions presumed to exist in 1870 prior to establishment of the national park. The period selected as a standard (1870) was an unusual period characterized by frequent large fires and floods, common wolves, few elk, and a cooler, wetter climate. We also conclude there is a high level of uncertainty surrounding what elk densities were in pre-Columbian times (element 3 of the management model) and what effects wolves and Native Americans had in regulating the elk population.

Wildlife Society Bulletin

Scanning electron microscopy investigations of laboratory-grown gas clathrate hydrates formed from melting ice, and comparison to natural hydrates

Scanning electron microscopy (SEM) was used to investigate grain texture and pore structure development within various compositions of pure sI and sII gas hydrates synthesized in the laboratory, as well as in natural samples retrieved from marine (Gulf of Mexico) and permafrost (NW Canada) settings. Several samples of methane hydrate were also quenched after various extents of partial reaction for assessment of mid-synthesis textural progression. All laboratory-synthesized hydrates were grown under relatively high-temperature and high-pressure conditions from rounded ice grains with geometrically simple pore shapes, yet all resulting samples displayed extensive recrystallization with complex pore geometry. Growth fronts of mesoporous methane hydrate advancing into dense ice reactant were prevalent in those samples quenched after limited reaction below and at the ice point. As temperatures transgress the ice point, grain surfaces continue to develop a discrete "rind" of hydrate, typically 5 to 30 ??m thick. The cores then commonly melt, with rind microfracturing allowing migration of the melt to adjacent grain boundaries where it also forms hydrate. As the reaction continues under progressively warmer conditions, the hydrate product anneals to form dense and relatively pore-free regions of hydrate grains, in which grain size is typically several tens of micrometers. The prevalence of hollow, spheroidal shells of hydrate, coupled with extensive redistribution of reactant and product phases throughout reaction, implies that a diffusion-controlled shrinking-core model is an inappropriate description of sustained hydrate growth from melting ice. Completion of reaction at peak synthesis conditions then produces exceptional faceting and euhedral crystal growth along exposed pore walls. Further recrystallization or regrowth can then accompany even short-term exposure of synthetic hydrates to natural ocean-floor conditions, such that the final textures may closely mimic those observed in natural samples of marine origin. Of particular note, both the mesoporous and highly faceted textures seen at different stages during synthetic hydrate growth were notably absent from all examined hydrates recovered from a natural marine-environment setting.

American Mineralogist

Evaluation of thematic mapper data for natural resource assessment

The U.S. Geological Survey EROS Data Center evaluated the utility of Landsat Thematic Mapper (TM) date for natural resource assessment, emphasizing manual interpretation and digital classification of the data for U.S. Department of the Interior applications. Substantially more information was derived from TM data than from Landsat Multispectral Scanner (MSS) data. Greater resolution of TM data aided in locating roads, small stock ponds, and many other land features that could be used as landmarks. The improved spatial resolution of TM data also permitted more efficient visual interpretations of land use, better identification of resource types, and improved assessment of ecological status of natural vegetation. TM data also provided a new source of spectral information that was useful for natural resource assessment. New mid-infrared spectral bands, TM band 5 and band 7, aided in distinguishing water resources, wetland vegetation resources, and other important terrain features. The added information was useful for both manual interpretation and digital data classification of vegetation resources and land features. Results from the analyses of both TM and TM simulator (TMS) spectral data suggest that the coefficient of variation for major land cover types is generally less for TM data than for MSS data taken from the same area. This reduction in variance should contribute to an improved multispectral analysis, contributing new information about vegetation in natural ecosystems. Although the amount of new information in TM bands 5 and 7 is mall, it is unique in that the same information cannot be derived from four-band Landsat MSS spectral data.

Conference Paper

Well log characterization of natural gas-hydrates

In the last 25 years there have been significant advancements in the use of well-logging tools to acquire detailed information on the occurrence of gas hydrates in nature: whereas wireline electrical resistivity and acoustic logs were formerly used to identify gas-hydrate occurrences in wells drilled in Arctic permafrost environments, more advanced wireline and logging-while-drilling (LWD) tools are now routinely used to examine the petrophysical nature of gas-hydrate reservoirs and the distribution and concentration of gas hydrates within various complex reservoir systems. Resistivity- and acoustic-logging tools are the most widely used for estimating the gas-hydrate content (i.e., reservoir saturations) in various sediment types and geologic settings. Recent integrated sediment coring and well-log studies have confirmed that electrical-resistivity and acoustic-velocity data can yield accurate gas-hydrate saturations in sediment grain-supported (isotropic) systems such as sand reservoirs, but more advanced log-analysis models are required to characterize gas hydrate in fractured (anisotropic) reservoir systems. New well-logging tools designed to make directionally oriented acoustic and propagation-resistivity log measurements provide the data needed to analyze the acoustic and electrical anisotropic properties of both highly interbedded and fracture-dominated gas-hydrate reservoirs. Advancements in nuclear magnetic resonance (NMR) logging and wireline formation testing (WFT) also allow for the characterization of gas hydrate at the pore scale. Integrated NMR and formation testing studies from northern Canada and Alaska have yielded valuable insight into how gas hydrates are physically distributed in sediments and the occurrence and nature of pore fluids(i.e., free water along with clay- and capillary-bound water) in gas-hydrate-bearing reservoirs. Information on the distribution of gas hydrate at the pore scale has provided invaluable insight on the mechanisms controlling the formation and occurrence of gas hydrate in nature along with data on gas-hydrate reservoir properties (i.e., porosities and permeabilities) needed to accurately predict gas production rates for various gas-hydrate production schemes.

Book

Well log characterization of natural gas hydrates

In the last 25 years we have seen significant advancements in the use of downhole well logging tools to acquire detailed information on the occurrence of gas hydrate in nature: From an early start of using wireline electrical resistivity and acoustic logs to identify gas hydrate occurrences in wells drilled in Arctic permafrost environments to today where wireline and advanced logging-while-drilling tools are routinely used to examine the petrophysical nature of gas hydrate reservoirs and the distribution and concentration of gas hydrates within various complex reservoir systems. The most established and well known use of downhole log data in gas hydrate research is the use of electrical resistivity and acoustic velocity data (both compressional- and shear-wave data) to make estimates of gas hydrate content (i.e., reservoir saturations) in various sediment types and geologic settings. New downhole logging tools designed to make directionally oriented acoustic and propagation resistivity log measurements have provided the data needed to analyze the acoustic and electrical anisotropic properties of both highly inter-bedded and fracture dominated gas hydrate reservoirs. Advancements in nuclear-magnetic-resonance (NMR) logging and wireline formation testing have also allowed for the characterization of gas hydrate at the pore scale. Integrated NMR and formation testing studies from northern Canada and Alaska have yielded valuable insight into how gas hydrates are physically distributed in sediments and the occurrence and nature of pore fluids (i.e., free-water along with clay and capillary bound water) in gas-hydrate-bearing reservoirs. Information on the distribution of gas hydrate at the pore scale has provided invaluable insight on the mechanisms controlling the formation and occurrence of gas hydrate in nature along with data on gas hydrate reservoir properties (i.e., permeabilities) needed to accurately predict gas production rates for various gas hydrate production schemes.

Conference Paper

International decade for natural disaster reduction

Throughout history, humanity has found itself in conflict with naturally occurring events of geologic, hydrologic, and atmospheric origin. this conflict has been demonstrated repeatedly when people build urban centers at the water's edge, in or near active fault systems capable of generating earthquakes, on steep slopes, near active volcanoes, or at the urban-wilderness interface prone to wildfires. Naturally occurring, recurrent events such as floods, windstorms, tsunamis, earthquakes, landslides, volcanic eruptions, and wildfires have tested human-engineered works many times and have often found them unable to withstand the forces generated by the event. In the past 20 years, for example, events like these throughout the world have claimed more than 2.8 million lives and adversely affected 820 million people; single disasters have caused economic losses of billions of dollars. Industrialized countries like the United States and Japan have been able to absorb the socioeconomic losses of past natural disasters, but the economics of many developing countries have been devastated by losses equal to a large percentage of their gross national product. Furthermore, the magnitude of the losses is increasing at a rapid rate as the building wealth of nations is expanded to meet the needs of rapidly increasing population, often without adequate consideration of the potential threat posed by the recurrent natural hazards and without implementing effective loss-reduction measures because of lack of knowledge or lack of technical capability.

Earthquakes & Volcanoes (USGS)

The need for the International Decade of Natural Hazard Reduction

Natural disasters affect countires large and small, rich or poor, whatever their political persuasion. The toll exacted by natural calamities each year drains the human and economic resources of every nation and stands as one of the formidable barriers to national, regional, and world development. Over the last 20 years, natural disasters have killed nearly 3 million people and disrupted the lives of over 800 million others. In 2 years there were more than 50 serious natural disasters, including landslides in Italy, France, and Colombia; a typhoon in Korea; wildfires in China and the United State; a windstorm in England; grasshopper plagues in Africa's horns and the Sahel; tornadoes in Canada; devastating earthquakes in Soviet Armenia and Tadzhikistan; infestations in Africa; landslides in Brazil; and tornadoes in the United States.

Earthquakes & Volcanoes (USGS)

Areal lithologic changes in bedrock aquifers in southeastern Minnesota as determined from natural-gamma borehole logs methods

Sedimentary rocks of Paleozoic age in the Hollandale embayment in southeastern Minnesota are as much as 2,000 feet thick and, with the underlying Hinckley sandstone of Proterozoic age, comprise the following five layered aquifers (beginning with the oldest): the Mount Simon-Hinckley, Ironton-Galesville, Prairie du Chien-Jordan, St. Peter and Upper Carbonate. Many of the Paleozoic formations show transitional facies changes from a deep marine depositional environment in the middle of the embayment to a near shore environment along the periphery. Borehole natural-gamma logs were collected to investigate the effects of regional lithologic changes on the hydrology of the Ironton-Galesville, Prairie du Chien-Jordan and St. Peter aquifers. Interpretation of natural-gamma logs shows that a fine-grained sandstone at the base of the Galesville sandstone (basal part of the Ironton-Galesville aquifer) thickens toward the central part of the embayment, which may account for the decrease in hydraulic conductivity of the Ironton-Galesville aquifer in that direction. The Jordan sandstone, which underlies the Prairie du Chien Group, consists of three members in southeastern Minnesota: the basal Norwalk member, a silty, fine-grained sandstone; the middle Van Oser member, a coarse- to medium-grained quartzose sandstone; and the upper Sunset Point member, a clayey dolomitic sandstone. The Norwalk and Van Oser members were identified by interpretation of natural-gamma logs. Hydraulic conductivity of the Prairie du Chien-Jordan aquifer generally is highest in the Twin City basin (50 feet per day) where the Van Oser is the predominant member; it is lowest to the east and southeast (25 feet per day) where the Norwalk member thickens. Interpretation of natural-gamma logs indicates that the shaley and silty sandstones that comprise the basal St. Peter confining bed, which separates the St. Peter and Prairie du Chien aquifers, are as much as 80 feet thick in the Twin City basin, but are absent in the southern part of the embayment. Differences in potentiometric head across the basal St. Peter are about 30 feet in the Twin City basin where the confining bed is present but only 5 to 10 feet to the south where the confining bed is absent and where the St. Peter aquifer directly overlies the Prairie du Chien-Jordan aquifer.

Minnesota

Natural gas hydrate in oceanic and permafrost environments

THE BEGINNINGS OF HYDRATE RESEARCH Until very recently, our understanding of hydrate in the natural environment and its impact on seafloor stability, its importance as a sequester of methane, and its potential as an important mechanism in the Earth's climate change system, was masked by our lack of appreciation of the vastness of the hydrate resource. Only a few publications on naturally occurring hydrate existed prior to 1975. The first published reference to oceanic gas hydrate (Bryan and Markl, 1966) and the first publication in the scientific literature (Stoll, et a1., 1971) show how recently it has been since the topic of naturally occurring hydrate has been raised. Recently, however, the number of hydrate publications has increased substantially, reflecting increased research into hydrate topics and the initiation of funding to support the researchers. Awareness of the existence of naturally occurring gas hydrate now has spread beyond the few scientific enthusiasts who pursued knowledge about the elusive hydrate because of simple interest and lurking suspicions that hydrate would prove to be an important topic. The first national conference on gas hydrate in the U.S. was held as recently as April, 1991 at the U.S. National Center of the U.s. Geological Survey in Reston Virginia (Max et al., 1991). The meeting was co-hosted by the U.s. Geological Survey, the Naval Research Laboratory, and the U.S.

Book