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At least 289 records · Page 16Linked to original sources

A reappraisal of explosive–effusive silicic eruption dynamics: Syn-eruptive assembly of lava from the products of cryptic fragmentation

Silicic volcanic eruptions range in style from gently effusive to highly explosive, and may switch style unpredictably during a single eruption. Direct observations of subaerial rhyolitic eruptions (Chaiten 2008, Cordón Caulle 2011–2012, Chile) challenged long-standing paradigms of explosive and effusive eruptive styles and led to the formulation of new models of hybrid activity. However, the processes that govern such hybrid explosive–effusive activity remain poorly understood. Here, we bring together observations of the well-studied 2011–2012 Cordón Caulle eruption with new textural and petrologic data on erupted products, and video and still imagery of the eruption. We infer that all of the activity – explosive, effusive, and hybrid – was fed by explosive fragmentation at depth, and that effusive behaviour arose from sticking and sintering, in the shallow vent region, of the clastic products of deeper, cryptic fragmentation. We use a scaling approach to determine that there is sufficient time available, during emplacement, for diffusive pyroclast degassing and sintering to produce a degassed plug that occludes the shallow conduit, feeding clastogenic, apparently effusive, lava-like deposits. Based on evidence from Cordón Caulle, and from other similar eruptions, we further argue that hybrid explosive–effusive activity is driven by episodic gas-fracking of the occluding lava plug, fed by the underlying pressurized ash- and pyroclast-laden region. The presence of a pressurized pocket of ash-laden gas within the conduit provides a mechanism for generation of harmonic tremor, and for syn-eruptive laccolith intrusion, both of which were features of the Cordón Caulle eruption. We conclude that the cryptic fragmentation models is more consistent with available evidence than the prevailing model for effusion of silicic lava that assume coherent non-fragmental rise of magma from depth to the surface without wholesale explosive fragmentation.

Journal of Volcanology and Geothermal Research↗

Petrology, composition, and age of intrusive rocks associated with the Quartz Hill molybdenite deposit, southeastern Alaska

A large porphyry molybdenum deposit (Quartz Hill deposit) was recently discovered in the heart of the Coast Range batholithic complex about 70 km east of Ketchikan, southeastern Alaska. Intrusive rocks associated with the mineral deposit form two composite epizonal to hypabyssal stocks and many dikes in country rocks. The stocks are characterized by a variety of textural rock types varying from equigranular or weakly seriate biotite granite to porphyries with aphanitic or very fine grained and aplitic groundmasses. These rocks contain about equal amounts of quartz, albitic plagioclase, and microperthitic microcline and less than 2.5% biotite. Unaltered rocks contain between 0.2 and 1% CaO, less than 1.7% combined Fe 2 O 3 , FeO, and MgO, and 74.4 to 77.7% SiO 2 . Total alkalis are between 8 and 9%, and K 2 O/Na 2 O is about 1.1. The range of major-oxide variation is small, but it is systematically related to lithology. Many trace-elements, including B, Pb, Sn, and Li have low concentrations. Intrusive rocks associated with the Quartz Hill deposit are more albitic and possibly trace-element depleted compared to some other rocks associated with porphyry molybdenum deposits.All observed metallization and alteration is within the Quartz Hill stock. Molybdenite forms fracture coatings and occurs in veins with quartz. Alteration is widespread and includes development of secondary quartz, pyrite, K-feldspar, biotite, white mica, chlorite, and zeolite. Field relations indicate that the stocks were emplaced after regional uplift and erosion of the Coast Range batholithic complex, and K–Ar data show that intrusion and alteration took place in late Oligocene time, about 27 to 30 Ma ago. Data from the Ketchikan quadrangle indicate that porphyry molybdenum metallization in the Coast Range batholithic complex is associated with regionally extensive but spotty, middle Tertiary or younger, felsic magmatism.

Alaska↗

Microscopical characterization of carbon materials derived from coal and petroleum and their interaction phenomena in making steel electrodes, anodes and cathode blocks for the Microscopy of Carbon Materials Working Group of the ICCP

This paper describes the evaluation of petrographic textures representing the structural organization of the organic matter derived from coal and petroleum and their interaction phenomena in the making of steel electrodes, anodes and cathode blocks. This work represents the results of the Microscopy of Carbon Materials Working Group in Commission III of the International Committee for Coal and Organic Petrology between the years 2009 and 2013. The round robin exercises were run on photomicrograph samples. For textural characterization of carbon materials the existing ASTM classification system for metallurgical coke was applied. These round robin exercises involved 15 active participants from 12 laboratories who were asked to assess the coal and petroleum based carbons and to identify the morphological differences, as optical texture (isotropic/anisotropic), optical type (punctiform, mosaic, fibre, ribbon, domain), and size. Four sets of digital black and white microphotographs comprising 151 photos containing 372 fields of different types of organic matter were examined. Based on the unique ability of carbon to form a wide range of textures, the results showed an increased number of carbon occurrences which have crucial role in the chosen industrial applications. The statistical method used to evaluate the results was based on the “raw agreement indices”. It gave a new and original view on the analysts' opinion by not only counting the correct answers, but also all of the knowledge and experience of the participants. Comparative analyses of the average values of the level of overall agreement performed by each analyst in the exercises during 2009–2013 showed a great homogeneity in the results, the mean value being 90.36%, with a minimum value of 83% and a maximum value of 95%.

International Journal of Coal Geology↗

Thermal thickness and evolution of Precambrian lithosphere: A global study

The thermal thickness of Precambrian lithosphere is modeled and compared with estimates from seismic tomography and xenolith data. We use the steady state thermal conductivity equation with the same geothermal constraints for all of the Precambrian cratons (except Antarctica) to calculate the temperature distribution in the stable continental lithosphere. The modeling is based on the global compilation of heat flow data by Pollack et al. [1993] and more recent data. The depth distribution of heat‐producing elements is estimated using regional models for ∼300 blocks with sizes varying from 1°×1° to about 5°×5° in latitude and longitude and is constrained by laboratory, seismic and petrologic data and, where applicable, empirical heat flow/heat production relationships. Maps of the lateral temperature distribution at depths 50, 100, and 150 km are presented for all continents except Antarctica. The thermal thickness of the lithosphere is calculated assuming a conductive layer overlying the mantle with an adiabat of 1300°C. The Archean and early Proterozoic lithosphere is found to have two typical thicknesses, 200–220 km and 300–350 km. In general, thin (∼220 km) roots are found for Archean and early Proterozoic cratons in the Southern Hemisphere (South Africa, Western Australia, South America, and India) and thicker (>300 km) roots are found in the Northern Hemisphere (Baltic Shield, Siberian Platform, West Africa, and possibly the Canadian Shield). We find that the thickness of continental lithosphere generally decreases with age from >200 km beneath Archean cratons to intermediate values of 200±50 km in early Proterozoic lithosphere, to about 140±50 km in middle and late Proterozoic cratons. Using known crustal thickness, our calculated geotherms, and assuming that isostatic balance is achieved at the base of the lithosphere, we find that Archean and early Proterozoic mantle lithosphere is 1.5% less dense (chemically depleted) than the underlying asthenosphere, while middle and late Proterozoic subcrustal lithosphere should be depleted by ∼0.6–0.7%. Our results suggest three contrasting stages of lithosphere formation at the following ages: >2.5 Ga, 2.5–1.8 Ga, and <1.8 Ga. Ages of komatiites, greenstone belts, and giant dike swarms broadly define similar stages and apparently reflect secular changes in mantle temperature and, possibly, convection patterns.

Journal of Geophysical Research B: Solid Earth↗

On the formation of granulites

The tectonic settings for the formation and evolution of regional granulite terranes and the lowermost continental crust can be deduced from pressure–temperature–time ( P–T –time) paths and constrained by petrological and geophysical considerations. P–T conditions deduced for regional granulites require transient, average geothermal gradients of greater than 35°C km −1 , implying minimum heat flow in excess of 100 mWm −2 . Such high heat flow is probably caused by magmatic heating. Tectonic settings wherein such conditions are found include convergent plate margins, continental rifts, hot spots and at the margins of large, deep-seated batholiths. However, particular P–T –time paths do not allow specific tectonic settings to be distinguished at this time. Under different conditions, both clockwise, CW ( P max attained before T max ), and anticlockwise, ACW ( P max attained slightly after T max ), paths are possible in the same tectonic setting. Both CW and ACW end-member paths can yield nearly isobaric cooling, IBC, paths. Such cooling paths are clearly not an artefact of thermobarometry, but can be constrained by solid–solid and devolatilization equilibria and geophysical modelling. In terms of understanding the evolution of the deep crust, a potentially significant group of regional granulite terranes are those that show evidence for ACW-IBC paths. Such paths are the likely result of: (i) episodic igneous activity resulting in intrusions within all levels of the crust, (ii) thickening of the crust by magmatic underplating, (iii) slow uplift as a result of the formation of a deep, garnet-rich crustal root and (iv) excavation resulting from a later tectonic event unrelated to that resulting in the formation of the granulites. The later event might be triggered by the delamination of the garnet-rich, lowermost crust.

Journal of Metamorphic Geology↗

Petrology and age of alkalic lava from the Ratak Chain of the Marshall Islands

Volcanic rock dredged from the flanks of four volcanic edifices in the Ratak chain of the Marshall Islands consist of alkalic lava that erupted above sea level or in shallow water. Compositions of recovered samples are predominantly differentiated alkalic basalt and hawaiite but include strongly alkalic melilitite. Whole rock 40 Ar/ 39 Ar total fusion and incremental heating ages of 87.3±0.6 Ma and 82.2±1.6 Ma determined for samples from Erikub Seamount and Ratak Guyot, respectively, are within the range predicted by plate rotation models but show no age progression consistent with a simple hot spot model. Whole rock major element, and mineral chemistry are similar to those of alkalic lavas from other oceanic islands, but isotopic and certain trace element ratios reveal distinctive mantle source characteristics. Zr/Nb ratios of ∼3.0±0.2 for Bikar and Ratak Guyot, compared to 5.2±0.3 for Majuro Atoll and Erikub Seamount, at comparable degree of differentiation, suggest a more alkalic trend for the northern sites. The 143 Nd/ 144 Nd isotopic ratios range from 0.51283 to 0.51289 and 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, and 208 Pb/ 204 Pb ratios range from 20.55 to 21.11, 15.71 to 15.77, and 39.93 to 40.75, for samples from Erikub and Ratak. Variations in isotopic and some incompatible element ratios suggest interisland heterogeneity. Similar highly radiogenic lead isotopes, coupled with distinct incompatible element ratios, especially with low Ba/Nb ratios (∼6), are observed for St. Helena in the South Atlantic and for Tubuai and Mangaia in the South Pacific. The similar mantle signature shown by lavas from Tubuai and Mangaia in the Austral-Cook chain, which are located at approximately the position where the Ratak edifices formed during the Late Cretaceous, indicates that this mantle anomaly is not of recent origin but has erupted distinctive lava compositions for at least 87 m.y.

Journal of Geophysical Research Solid Earth↗

Vent-specific unrest at Pavlof Volcano, Alaska: Insights from multidisciplinary data

Pavlof Volcano, a frequently active volcano in the Aleutian arc, has erupted six times between 2007 and 2022. Many Pavlof Volcano eruptions lack detectable precursory seismicity or ground deformation, making them challenging to forecast. Since 2007, these eruptions have ranged from Strombolian to Subplinian (VEI 2–3), with their characteristics seemingly related to their active vent location. Summit vent eruptions tend to be abrupt and explosive, while southeast flank vent eruptions tend to be more effusive and longer-lived. To better understand Pavlof Volcano’s plumbing system and improve eruption forecasts, we integrate geophysical, petrologic, and satellite-based thermal infrared and gas data to conduct a multidisciplinary data synthesis for eruptions between 2007 and 2022. Notably, a recently developed volcano seismicity detection model reveals unique pre- and syn-eruptive seismic tremor regimes associated with each vent system. The summit vent eruptions show greater tremor diversity and resurgent eruptive behavior, whereas the southeast flank vent eruptions show a steady tremor transition over a single eruptive phase. We use local infrasound data and air-to-ground coupled waves to build explosion catalogs, revealing gas-rich explosions during the 2021–2022 eruption from the summit vent, which was previously thought to be inactive during that eruption. Whole-rock composition and ash analyses indicate a near-uniform basaltic andesite composition spanning multiple eruptions, and a consistent anomalous presence of altered olivines in erupted material. We use these findings to propose a new conceptual model for Pavlof Volcano’s plumbing system: a shallow T-junction outlet controlling seismic tremor diversity and the partitioning of gas-charged magma; and an elongated, heated conduit transporting magma from depth and storing partly molten, residual magma between eruptions. We suggest that magma ascent rate and vent sealing modulate eruption style at Pavlof Volcano, where the T-junction directs rapidly ascending, gas-rich magma to the summit vent, and diverts slower rising, gas-poor magma towards the southeast flank vent.

Alaska↗

Long-period seismicity at Redoubt Volcano, Alaska, 1989-1990 related to magma degassing

The mass of exsolved magmatic H2O is estimated and compared to the mass of superheated steam (25-50 Mtons) released through the resonating crack producing the December 13-14, 1989 swarm of long-period seismic events at Redoubt Volcano. Results indicate degassing of a H2O-CO2-SO2-saturated magma upon ascending from at least 12 km to 3-4 km beneath the crater as the source of the superheated steam. The mass of exsolved H2O (3.2-250 Mtons) is estimated from solubility diagrams of H2O-CO2-saturated silicate melts for the ascent history of the Redoubt magmas. Crystal size distribution, seismological, petrological, and geochemical data are used to constrain the ascent history of the two andesitic magmas prior to the eruption. Two stages of crystallization are inferred from crystal size distributions of plagioclase crystals in andesites erupted in December 1989. The first stage occurred 30-150 years before the eruption in both magmas and the second stage occurred at least 8 years and 15 years before the eruption in the dacitic andesite and rhyolitic andesite, respectively. The depths of crystallization are constrained from the spatial and temporal variations of volcano-tectonic earthquakes locations (Lahr et al., 1994) and from the P-wave and S-wave velocity structures (Benz et al., 1996). These data suggest that the rhyolitic andesite magma ascended to a depth of 7-8 km within at least 15 years of the eruption. Within at least 8 years of the eruption, the dacitic andesite magma migrated to a depth just below the other magma body where it resided until hours to days of the eruption. At this time, the dacitic andesite magma mixed with the rhyolitic andesite magma and established the reservoir for the eruption. Near the top of the reservoir, some of the mixed magma was displaced into fractures which extended 4-5 km toward the surface. This displaced magma created the eruption conduit and released the fluids related to the resonating crack. This scenario is consistent with the trends in major-and trace-element chemistry, and the stability of hornblende in the pre-eruption Redoubt magmas. It also provides a source for the SO2 and CO2 emissions measured during the eruption.

Journal of Volcanology and Geothermal Research↗

Organic petrology of the Aptian-age section in the downdip Mississippi Interior Salt Basin, Mississippi, USA: Observations and preliminary implications for thermal maturation history

This study identifies a thermal maturity anomaly within the downdip Mississippi Interior Salt Basin (MISB) of southern Mississippi, USA, through examination of bitumen reflectance data from Aptian-age strata (Sligo Formation, Pine Island Shale, James Limestone, and Rodessa Formation). U.S. Geological Survey (USGS) reconnaissance investigations conducted in 2011–2012 examined Aptian-age thermal maturity trends across the onshore northern Gulf of Mexico region and indicated that the section in the downdip MISB is approaching the wet gas/condensate window (R o ~1.2%). A focused study in 2012–2013 used 6 whole core, one sidewall core, and 49 high-graded cutting samples (depth range of 13,000–16,500 ft [3962.4–5029.2 m] below surface) collected from 15 downdip MISB wells for mineralogy, fluid inclusion, organic geochemistry, and organic petrographic analysis. Based on native solid bitumen reflectance (R o generally > 0.8%; interpreted to be post-oil indigenous bitumens matured in situ), R o values increase regionally across the MISB from the southeast to the northwest. Thermal maturity in the eastern half of the basin (R o range 1.0 to 1.25%) appears to be related to present-day burial depth and shows a gradual increase with respect to depth. To the west, thermal maturity continues to increase even as the Aptian section shallows structurally on the Adams County High (R o range 1.4 to > 1.8%). After evaluating the possible thermal agents responsible for increasing maturity at shallower depths (i.e., igneous activity, proximity to salt, variations in regional heat flux, and uplift), we tentatively propose that either greater paleoheat flow or deeper burial coupled with uplift in the western part of the MISB could be responsible for the thermal maturity anomaly. Further research and additional data are needed to determine the cause(s) of the thermal anomaly.

International Journal of Coal Geology↗

Quantification of the intrusion process at Kīlauea volcano, Hawai'i

The characteristic size of two types of intrusions identified beneath Kīlauea's East Rift zone are uniquely estimated by combining time constraints from fractional crystallization and the rates of magma solidification during cooling. Some intrusions were rapidly emplaced as dikes, but stalled before reaching the surface, and cooled and crystallized to feed later fractionated eruptions. More specifically, using the observed time interval between initial emplacement and eruption of fractionated lava, whose degree of fractionation is estimated from petrologic mixing calculations, the extent of solidification or cooling needed to produce this amount of fractionation can be directly inferred. And from the known erupted volumes the spatial extent or size of this fractionated volume can be analytically related to the full size of the source body itself. Two examples yield dike widths of 82 and 68 m. Other intrusions remain close to the east rift magma transport path and are observed to last for decades or longer as viable magma bodies that may participate in feeding later eruptions. The thickness of semi-permanent reservoirs near the East Rift Zone magma transport path can be estimated by assuming a resupply rate that is sufficiently frequent to restrict cooling to < 10 °C. It is inferred that both types of intrusions likely began as dike offshoots from the East Rift Zone magma transport path, but the frequently resupplied bodies may have later been converted to sills or laccoliths of heights estimated at 43–62 m. Our modeled intrusions contrast with models of rapidly emplaced thinner dikes feeding shallow intrusions, which are accompanied by intense rift earthquake swarms and are often associated with eruptions. These calculations show that long-term heating of the wallrock of the magma transport paths serves to slow conduit cooling, which may be partly responsible for sustaining long East Rift Zone eruptions. Adjacent to the vertical transport path beneath Kīlauea's summit, the combined effects of heating and ever-increasing magma supply rate may have forced a commensurate enlarging of the conduit, perhaps explaining the occurrence of a temporary burst of deep (5–15 km) long-period earthquake swarms between 1987 and 1992.

Hawaii↗

Juvenile magma recognition and eruptive dynamics inferred from the analysis of ash time series: The 2015 reawakening of Cotopaxi volcano

Forecasting future activity and performing hazard assessments during the reactivation of volcanoes remain great challenges for the volcanological community. On August 14, 2015 Cotopaxi volcano erupted for the first time in 73 years after approximately four months of precursory activity, which included an increase in seismicity, gas emissions, and minor ground deformation. Here we discuss the use of near real-time petrological monitoring of ash samples as a complementary aid to geophysical monitoring, in order to infer eruption dynamics and evaluate possible future eruptive activity at Cotopaxi. Twenty ash samples were collected between August 14 and November 23, 2015 from a monitoring site on the west flank of the volcano. These samples contain a range of grain types that we classified as: hydrothermal/altered, lithic, juvenile, and free crystals. The relative proportions of theses grains evolved as the eruption progressed, with increasing amounts of juvenile material and a decrease in hydrothermally altered material. In samples from the initial explosion, juvenile grains are glassy, microlite-poor and contain hydrothermal minerals (opal and alunite). The rising magma came in contact with the hydrothermal system under confinement, causing hydro-magmatic explosions that cleared the upper part of the plumbing system. Subsequently, the magmatic column produced a thermal aureole in the conduit and dried out the hydrothermal system, allowing for dry eruptions. Magma ascent rates were low enough to allow for efficient outgassing and microlite growth. Constant supply of magma from below caused quasi-continuous disruption of the uppermost magma volume through a combination of shear-deformation and gas expansion. The combination of increasing crystallinity of juvenile grains, and high measured SO 2 flux indicate decreasing integrated magma ascent rates and clearing of the hydrothermal system along transport pathways in a system open to gas loss. The near real-time monitoring of ash samples combined with traditional geophysical monitoring techniques during the reawakening of Cotopaxi allowed us to gain a much clearer understanding of events than when using traditional geophysical monitoring alone.

Cotopaxi volcano↗

Identification of alginite and bituminite in rocks other than coal. 2006, 2009, and 2011 round robin exercises of the ICCP Identification of Dispersed Organic Matter Working Group

The paper presents results of round robin exercises on photomicrograph-based identification of dispersed organic matter in source rocks that represent a range of marine and lacustrine deposits from worldwide localities and cover a range of thermal maturities. The round robin exercises were conducted by the Identification of Dispersed Organic Matter Working Group (IDOM WG) of the International Committee for Coal and Organic Petrology (ICCP). The round robin exercises aimed to (1) assess the applicability of the established ICCP definitions of bituminite, (2) identify deficiencies and improve the existing nomenclatures, and (3) provide a basis for the revision of the bituminite and alginite definitions in the ICCP Handbook (Taylor et al., 1998). Three round robin exercises performed in 2006, 2009 and 2011 involved 18 participants from research laboratories at universities and within government and industry. Participants were asked to identify macerals on the basis of existing definitions in 129 photomicrographs taken in incident white light and fluorescent mode and also in fluorescence light mode at prolonged (15 min) blue light irradiation. The results indicate that the definition of telalginite permits its positive and satisfactory agreement among the participants. In contrast, the descriptive characteristics of lamalginite referring to film-like appearance (filamentous) and lack of inner or outer structure are insufficient and inadequate to enable an unequivocal discrimination between it and telalginite. Furthermore, based on the amorphous nature of bituminite and lack of adherence to its established description and character (Taylor et al., 1998), the highest discrepancies were observed in its identification. Differentiation of bituminite from a fluorescent groundmass and in some cases from lamalginite proved to be particularly challenging. The findings of these round robin exercises are useful for improving the identification of sedimentary organic matter in source rocks and may be an important foundation for the modification of the ICCP definitions of alginite and bituminite.

International Journal of Coal Geology↗

Distribution of recent volcanism and the morphology of seamounts and ridges in the GLIMPSE study area: Implications for the lithospheric cracking hypothesis for the origin of intraplate, non-hot spot volcanic chains

Lithospheric cracking by remotely applied stresses or thermoelastic stresses has been suggested to be the mechanism responsible for the formation of intraplate volcanic ridges in the Pacific that clearly do not form above fixed hot spots. As part of the Gravity Lineations Intraplate Melting Petrology and Seismic Expedition (GLIMPSE) project designed to investigate the origin of these features, we have mapped two volcanic chains that are actively forming to the west of the East Pacific Rise using multibeam echo sounding and side-scan sonar. Side-scan sonar reveals the distribution of rough seafloor corresponding to recent, unsedimented lava flows. In the Hotu Matua volcanic complex, recent flows and volcanic edifices are distributed over a region 450 km long and up to 65 km wide, with an apparent, irregular age progression from older flows in the west to younger in the east. The 550-km-long Southern Cross Seamount/Sojourn Ridge/Brown Ridge chain appears to have been recently active only at its eastern end near the East Pacific Rise. A third region of recent flows is found 120 km north of Southern Cross Seamount in seafloor approximately 9 Myr old. No indication of lithospheric extension in the form of faulting or graben formation paralleling the trend of the volcanic chains is found in the vicinity of recent flows or anywhere else in the study area. Thermoelastic cracking could be a factor in the formation of a few small, very narrow volcanic ridges, but most of the volcanic activity is broadly distributed in wide swaths with no indication of formation along narrow cracks. The Sojourn and Brown chains appear to begin as distributed zones of small seamounts that later develop into segmented ridges, perhaps under the influence of membrane stresses from self-loading. We suggest that the linear volcanic chains are created by moving melting anomalies in the asthenosphere and that lithospheric cracking plays at most a secondary role. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

Geochemical and petrological studies of a uraniferous granite from the Granite Mountains, Wyoming

Granite rocks from the Granite Mountains, Wyo. have been proposed as the source of uranium deposits in the Crooks Gap, Gas Hills and Shirley Basin uranium districts, Wyoming. We have divided these granitic rocks into four units: (1) a biotitic phase which forms the dominant unit at the western end of the Granite Mountains, (2) a leucocratic phase which was found from 215 to 405 metres in drill hole GM-1, (3) silicified zones which crosscut the granitic rocks and form topographic highs, and (4) fractured zones, in drill hole GM-1, which seem to have been hydrothermally altered. The biotitic phase is hypidiomorphic-granular to xenomorphic-granular alkali granite with anomalously high contents of U (10 parts per million), Th (50 ppm), and Pb (50 ppm). Fission-track studies show that uranium is located in zircon, sphene, apatite, monzite, xenotime, biotite, chlorite, epidote, and magnetite; no intergranular uranium was found. The leucocratic phase is mineralogically similar to the biotitic phase, but contains less than half as much iron. It is xenomorphic granular and commonly contains rounded and retrograded garnets, which suggests that this phase is either metamorphic or contaminated with metamorphic materials. The leucocratic phase has anomalously high contents of U (8 ppm) and Pb (55 ppm), but has a low Th content (10 ppm). The silicified phase and fracture zones exhibit cataclastic and crystalloblastic textures and are highly variable in mineralogy. Potassium-bearing minerals are generally absent. Microcline is replaced by albite and (or) quartz, and biotite is replaced by clinozoisite. Uranium values may be anomalously high in the fracture zones. One sample contains 1100 ppm radium-equivalent uranium. In this and other uranium-rich samples from the fracture zones, the uranium is associated with iron oxides which commonly fill microfractures. According to our model and currently available data, an alkali granite is the best crystalline source rock for uranium, especially if it is unmetamorphosed and rapidly exposed to near-surface conditions for the first time when a favorable basin existed nearby.

Wyoming↗

Palynologic and petrographic intervals in the upper Pennsylvanian McLeansboro Group, Western Kentucky

The McLeansboro Group (formerly the Sturgis Formation) in the Western Kentucky coal field spans the upper Desmoinesian (Westphalian D) and the Missourian and Virgilian series (Stephanian). Extensive drilling has demonstrated the lateral continuity of major and minor beds in the group, making it possible to study vertical and lateral changes in palynology and petrology. Significant features of the McLeansboro Group are the marine zones over most of the coals and paleochannels, which are the only disruptions to the continuity of other lithologies. The Desmoinesian Baker (No. 13) and Wheatcroft (No. 13a) coal beds were included in the study but the primary emphasis is on the Missourian and Virgilian coals. Patoka Formation (lower Missourian) coals are dominated by tree fern spores with lesser amounts of sphenopsids, ferns and cordaites spores. This is in marked contrast to the arborescent lycopod-dominated Desmoinesian coals. Only the No. 15 coal bed exceeds 80% vitrinite: the vitrinite content of the No. 16 coal bed is less than 72%, the lowest of any Western Kentucky humic coal. The Bond Formation (upper Missourian) represents a distinct floristic interval, with a greater diversity of plant groups than in the Patoka Formation. Herbaceous lycopod spores, which are relatively minor contributors to the Patoka coals, are common in the Bond Formation. The coals generally exceed 80% vitrinite. The Mattoon Formation (Virgillian) coals have a variety of palynomorph assemblages. The low-sulfur Geiger Lake coal bed is dominated by tree fern spores, with important contributions from other ferns and sphenopsids. Similar to the underlying tree fern interval, vitrinite contents are less than 80%. The uppermost Mattoon coals are dominated by tree ferns and are notable in being the only coals more than 1 m thick in the Stephanian portion of the section, with the top coal being 4.3 m thick. The uppermost coals generally contain more than 80% vitrinite. The Permian Mauzy Formation overlies the McLeansboro Group. The palynologic/petrographic intervals appear to represent fluctuating dry (low vitrinite) and wet intervals within the Stephanian, which was itself drier than the Westphalian D.

International Journal of Coal Geology↗

Petrology and isotopic composition of Quaternary basanites dredged from the Bering Sea continental margin near Navarin Basin

Quaternary basanites were recovered from shallow water depth from the continental margin of the Bering Sea (58°39.0′N, 177°12.9′W) near Navarin Basin. The basanites are highly vesicular flow rock and hyaloclastites similar to other alkalic volcanic rocks erupted repeatedly during the late Cenozoic on islands in the Bering Sea region and in mainland Alaska. K–Ar ages for the basanites indicate at least two episodes of volcanism at about 1.1 and 0.4 Ma. Similar alkalic volcanism occurred sporadically at geographically widely separated centers in the Bering Sea region for at least the past 6 Ma. Chemically, these alkalic lavas are intraplate basalts similar to those erupted from oceanic islands and in some continental settings. Trace-element data indicate these alkalic lavas have been generated by small, but variable, amounts of partial melting of a meta-somatized lherzolite source. The relatively primitive compositions (MgO > 9%), presence of mantle-derived xenoliths in some alkalic lavas, and presence of forsteritic olivine with low CaO and high NiO suggest that magma rose rapidly from greath depth without spending time in large, long-lived magma chambers. Although lavas from different volcanic centers in the Bering Sea region are similar with respect to major elements and many trace-element ratios, isotopic compositions indicate heterogeneities in the source. The Navarin basanites have higher 87 Sr/ 86 Sr and lower 143 Nd/ 144 Nd values than any other lavas so far reported from this region. The 207 Pb/ 204 Pb isotopic ratios indicate involvement of a crustal component, which may have resulted from metasomatism associated with subduction-related magmatic activity during the Early Eocene in this region. Although some volcanic episodes appear to have occurred roughly synchronously at geographically widely separated centers, no large-scale regional extension nor presence of large mantle plumes are indicated. Instead, alkalic volcanism apparently resulted from upwelling and decompressional melting of small isolated mantle diapirs in response to local lithospheric attenuation associated with jostling of blocks during adjustment to regional stresses.

Alaska↗

Chemical, multispectral, and textural constraints on the composition and origin of rocks at the Mars Pathfinder landing site

Rocks at the Mars Pathfinder site are probably locally derived. Textures on rock surfaces may indicate volcanic, sedimentary, or impact-generated rocks, but aeolian abration and dust coatings prevent unambiguous interpretation. Multispectral imaging has resolved four spectral classes of rocks: gray and red, which occur on different surfaces of the same rocks; pink, which is probably soil crusts; and maroon, which occurs as large boulders, mostly in the far field. Rocks are assigned to two spectral trends based on the position of peak reflectance: the primary spectral trend contains gray, red, and pink rocks; maroon rocks constitute the secondary spectral trend. The spatial pattern of spectral variations observed is oriented along the prevailing wind direction. The primary spectral trend arises from thin ferric coatings of aeolian dust on darker rocks. The secondary spectral trend is apparently due to coating by a different mineral, probably maghemite or ferrihydrite. A chronology based on rock spectra suggests that rounded maroon boulders constitute the oldest petrologic unit (a flood deposit), succeeded by smaller cobbles possibly deposited by impact, and followed by aeolian erosion and deposition. Nearly linear chemical trends in alpha proton X-ray spectrometer rock compositions are interpreted as mixing lines between rock and adhering dust, a conclusion supported by a correlation between sulfur abundance and red/blue spectral ratio. Extrapolations of regression lines to zero sulfur give the composition of a presumed igneous rock. The chemistry and normative mineralogy of the sulfur-free rock resemble common terrestrial volcanic rocks, and its classification corresponds to andesite. Igneous rocks of this composition may occur with clastic sedimentary rocks or impact melts and breccias. However, the spectral mottling expected on conglomerates or breccias is not observed in any APXS-analyzed rocks. Interpretation of the rocks as andesites is complicated by absence of a "1 μm" pyroxene absorption band. Plausible explanations include impact glass, band masking by magnetite, or presence of calcium- and iron-rich pyroxenes and olivine which push the absorption band minimum past the imager's spectral range. The inferred andesitic composition is most similar to terrestrial anorogenic icelandites, formed by fractionation of tholeiitic basaltic magmas. Early melting of a relatively primitive Martian mantle could produce an appropriate parent magma, supporting the ancient age of Pathfinder rocks inferred from their incorporation in Hesperian flood deposits. Although rocks of andesitic composition at the Pathfinder site may represent samples of ancient Martian crust, inferences drawn about a necessary role for water or plate tectonics in their petrogenesis are probably unwarranted.

Journal of Geophysical Research E: Planets↗

Effect of concentration of dispersed organic matter on optical maturity parameters: Interlaboratory results of the organic matter concentration working group of the ICCP.

The main objective of this work was to study the effect of the kerogen isolation procedures on maturity parameters of organic matter using optical microscopes. This work represents the results of the Organic Matter Concentration Working Group (OMCWG) of the International Committee for Coal and Organic Petrology (ICCP) during the years 2008 and 2009. Four samples have been analysed covering a range of maturity (low and moderate) and terrestrial and marine geological settings. The analyses comprise random vitrinite reflectance measured on both kerogen concentrate and whole rock mounts and fluorescence spectra taken on alginite. Eighteen participants from twelve laboratories from all over the world performed the analyses. Samples of continental settings contained enough vitrinite for participants to record around 50 measurements whereas fewer readings were taken on samples from marine setting. The scatter of results was also larger in the samples of marine origin. Similar vitrinite reflectance values were in general recorded in the whole rock and in the kerogen concentrate. The small deviations of the trend cannot be attributed to the acid treatment involved in kerogen isolation but to reasons related to components identification or to the difficulty to achieve a good polish of samples with high mineral matter content. In samples difficult to polish, vitrinite reflectance was measured on whole rock tended to be lower. The presence or absence of rock fabric affected the selection of the vitrinite population for measurement and this also had an influence in the average value reported and in the scatter of the results. Slightly lower standard deviations were reported for the analyses run on kerogen concentrates. Considering the spectral fluorescence results, it was observed that the ??max presents a shift to higher wavelengths in the kerogen concentrate sample in comparison to the whole-rock sample, thus revealing an influence of preparation methods (acid treatment) on fluorescence properties. ?? 2010 Elsevier B.V.

International Journal of Coal Geology↗