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Land Disturbance Associated with Oil and Gas Development and Effects of Development-Related Land Disturbance on Dissolved-Solids Loads in Streams in the Upper Colorado River Basin, 1991, 2007, and 2025

Oil and gas resource development in the Upper Colorado River Basin (UCRB) has increased substantially since the year 2000. The UCRB encompasses several significant oil and gas producing areas that have the potential for continued oil and gas resource development. Land disturbance associated with oil and gas resource development is caused by activities related to constructing drill pads to contain drilling and well maintenance equipment and roads to access the drill pad. Land disturbed by oil and gas development has the potential to cause increased erosion, stream degradation, habitat fragmentation and alteration, and increase public use of areas that may be environmentally sensitive. Land disturbance resulting from oil and gas resource development has not been monitored and mapped on a regional scale in the UCRB. However, information on the location and age of oil and gas wells in the UCRB is available. These data combined with geographic data analysis and modeling techniques were used to estimate the total area of disturbed land associated with oil and gas resource development in 1991 and in 2007 in the UCRB. Additional information about anticipated oil and gas development in the UCRB was used to project land disturbance to the year 2025. Results of the analysis indicate that approximately 117,500 acres (183 mi2) of total land disturbance was associated with drill pads and related roads in the UCRB in 1991. The estimated area of disturbed land associated with oil and gas development increased 53 percent to 179,400 acres (280 mi2) in 2007. Projecting oil and gas development through 2025 results in a potential near doubling of the land surface disturbance to approximately 319,300 acres (500 mi2). Estimated land disturbance for 1991 and 2007 were input to a contaminant transport model developed for the UCRB to assess the statistical significance of energy-related land disturbance to contributing dissolved solids to basin streams. The statistical assessment was an observational study based on an existing model and available water-quality monitoring data for the basin. No new data were collected for the analysis. The source coefficient calibrated for the disturbed lands associated with oil and gas development in 2007 was zero, which indicated that estimated land disturbance from oil and gas development is not statistically significant in explaining dissolved solids in UCRB streams. The lack of significance in the contaminant transport modeling framework may be due to the amount of available monitoring data, the spatial distribution of monitoring sites with respect to land disturbance, or the overall quantity of land disturbance associated with oil and gas development basin wide. Finally, dissolved-solids loads derived from natural landscapes may be similar to loads derived from lands disturbed by oil and gas resource development. The model recalibration done for this study confirms calibration results from Kenney and others (2009): the most significant contributor to dissolved solids in the UCRB is irrigated agricultural land, which covers an area substantially larger than the estimated area disturbed by oil and gas development and is subjected to artificially applied water.

Scientific Investigations Report↗

Ground-water geology of Grayson County, Texas

Grayson County in north-central Texas is near the north edge of the West Gulf Coastal Plain. The county has an area of 927 square miles and had an estimated population of 79,500 in 1957. The major town is Sherman, which has an estimated population of 31,000. The northern two-thirds of the county is drained by tributaries of the Red River; the southern one-third is drained by tributaries of the Trinity River Sedimentary rocks exposed at the surface in Grayson County are of Cretaceous and Quaternary age. Sand, clay, marl, and limestone of Cretaceous age, having a maximum thickness of about 3,600 feet, underlie the county; the beds dip regionally to the southeast. Quaternary alluvium mantles part of the surface along the Red River and occurs in scattered patches elsewhere in the county. The Trinity group and Woodbine formation of Cretaceous age are the principal water-bearing formations. Other stratigraphic units that yield water to wells are, in order of importance, the Quaternary alluvium and the Pawpaw formation, Eagle Ford shale, and Austin chalk of Cretaceous age. Ground water in Grayson County generally moves eastward and southward from areas of recharge to areas of discharge. Average rates of water movement in the Trinity group and Woodbine formation are estimated to be about 1.5 and 15 feet per year, respectively. The chief source of recharge to these aquifers is precipitation on the outcrop, although Lake Texoma contributed some recharge to the Trinity where it crops out in the lake. Ground water discharges naturally by evapotranspiration, by vertical leakage, through springs, artificially through wells, and by underflow out of the county to the southeast. The withdrawal of ground water in Grayson County in 1957 was about 5 mgd. Of this amount, about 61 percent came from the Woodbine formation, about 36 percent from the Trinity group, and about 3 percent from the other water-bearing formations. About 65 percent of the ground water pumped in Grayson County is withdrawn in the Sherman area. Increased withdrawal of water since World War II has resulted in a rapid decline of the water levels in parts of Grayson County. The maximum decline in the Trinity group at Sherman from 1945 to 1958 was 113 feet, or about 8 feet per year. During the same period, water levels in the Woodbine formation at Sherman declined as much as 156 feet, an average of 12 feet per year. Total declines since the early part of the 20th century were at least 180 feet in the Trinity group and about 240 feet in the Woodbine formation. Water levels in the area of outcrop of the principal aquifers, fluctuating chiefly in response to rainfall or changes in the natural rate of recharge, showed no appreciable decline from 1957 to 1959. Coefficients of transmissibility, determined from pumping tests in Grayson County, averaged 2,800 gpd per ft for the Trinity group and 3,200 gpd per ft for the Woodbine formation. Kesults of chemical analyses of water samples indicate that the ground water in Grayson County is suitable for most purposes. The Trinity group generally yields soft water that has a high sodium bicarbonate content and is of questionable quality for irrigation. The water from the Woodbine formation ranges more widely in chemical composition than the water from the Trinity. It generally is soft but has a high iron content; it is usually suitable for irrigation in the outcrop area but unsuitable in the downdip area. Water from the other water-bearing formation, though generally hard, is suitable for most purposes, judging from the few analyses available. The ground-water resources of Grayson County have been only partly developed. The volume of fresh water in transient storage in the Trinity group and Woodbine formation is estimated to be about 60 and 25 million acre-feet, respectively. Most of this water is not practicably recoverable because of the depth at which it occurs, but relatively high artesian heads and large available drawdowns in much of the county are favorable to future development within economic limits of pumping lift. In the Sherman area, however, concentrated pumping has caused large declines in the water levels, resulting in some dewatering of the Woodbine. Because of the large margin of 'safety before dewatering of the Trinity group begins, the Trinity is the most favorable source of additional ground water for Sherman. However, the higher lifting costs should be considered. Large to moderate amounts of additional ground water can be obtained from the Trinity group and Woodbine formation in most presently undeveloped areas in the county. Water suitable for irrigation is available in moderate to large amounts from the Woodbine formation in places on its outcrop. A limiting factor to any large ground-water development, however, is the extent and thickness of saturated fresh-water sand available in the area. The thickness of saturated fresh-water sand in the Trinity decreases northward; the thickness of the sand in the Woodbine is more erratic and has little definite pattern. Moderate to large supplies of water may be available from the alluvium near the Red River, but more information is needed before definite conclusions can be reached.

Water Supply Paper↗

Summary of the Snake River plain Regional Aquifer-System Analysis in Idaho and eastern Oregon

Regional aquifers underlying the 15,600-square-mile Snake River Plain in southern Idaho and eastern Oregon was studied as part of the U.S. Geological Survey's Regional Aquifer-System Analysis program. The largest and most productive aquifers in the Snake River Plain are composed of Quaternary basalt of the Snake River Group, which underlies most of the 10,8000-square-mile eastern plain. Aquifer tests and simulation indicate that transmissivity of the upper 200 feet of the basalt aquifer in the eastern plain commonly ranges from about 100,000 to 1,000,000 feet squared per day. However, transmissivity of the total aquifer thickness may be as much as 10 million feet squared per day. Specific yield of the upper 200 feet of the aquifer ranges from about 0.01 to 0.20. Average horizontal hydraulic conductivity of the upper 200 feet of the basalt aquifer ranges from less than 100 to 9,000 feet per day. Values may be one to several orders of magnitude higher in parts in individual flows, such as flow tops. Vertical hydraulic conductivity is probably several orders of magnitude lower than horizontal hydraulic conductivity and is generally related to the number of joints. Pillow lava in ancestral Snake River channels has the highest hydraulic conductivity of all rock types. Hydraulic conductivity of the basalt decreases with depth because of secondary filling of voids with calcite and silica. An estimated 80 to 120 million acre-feet of water is believed to be stored in the upper 200 feet of the basalt aquifer in the eastern plain. The most productive aquifers in the 4,800-square-mile western plain are alluvial sand and gravel in the Boise River valley. Although aquifer tests indicate that transmissivity of alluvium in the Boise River valley ranges from 5,000 to 160,000 feet squared per day, simulation suggests that average transmissivity of the upper 500 feet is generally less than 20,000 feet squared per day. Vertically averaged horizontal hydraulic conductivity of the upper 500 feet of alluvium ranges from about 4 to 40 feet per day; higher values can be expected in individual sand and gravel zones. Vertical hydraulic conductivity is considerably lower because of the presence of clay layers. Hydraulic heads measured in piezometers, interpreted from diagrams showing ground-water flow and equipotential lines and estimated by computer simulation, demonstrate that water movement is three dimensional through the rock framework. Natural recharge takes place along the margins of the plain where head decreases with depth; discharge takes place near some reaches of the Snake River and the Boise River where head increases with depth. Geothermal water in rhyolitic rocks in the western plain and western part of the eastern plain has higher hydraulic head than the overlying cold water. Geothermal water, therefore, moves upward and merges into the cold-water system. Basin water-budget analyses indicate that the volume of cold water. Carbon-14 age determinations, which indicate that residence time of geothermal water is 17,700 to 20,300 years, plus or minus 4,000 years, imply slow movement of water through the geothermal system. Along much of its length, the Snake River gains large quantities of ground water. On the eastern plain, the river gained about 1.9 million acre-feet of water between Blackfoot and Neeley, Idaho, in 1980. Between Milner and King Hill, Idaho, the river gained 4.7 million acre-feet, mostly as spring flow from the north side. Upstream from Blackfoot and in the vicinity of Lake Walcott, the rover loses flow to ground water during parts or all of the year. On the western plain, river gains from ground water are small relative to those on the eastern plain; most are from seepage. Streams in tributary drainage basins supply calcium/bicarbonate type and calcium/magnesium/bicarbonate type water to the plain. Water type is a reflection of the chemical composition of rocks in the drainage basin, Concentrations of dissolved solids are smallest, about 50 milligrams per liter, in streams such as the Boise River that drain areas of granitic rocks; concentrations are greatest, about 400 milligrams per liter, in streams such as the Owyhee and Raft Rivers that drain area of sedimentary rocks. Water chemistry reflects the interaction of surface water and ground water. The chemical composition of ground water in the plain is essentially the same as that in streamflow and groundwater discharge from tributary drainage basins. Tributary drainage basins supplied 85 percent of the ground-water recharge in the eastern plain during 1980 and a nearly equivalent percentage of the solute load in ground water; human activities and dissolution of minerals supplied the other solutes. Dissolved-solids concentrations in ground water were generally less than 400 milligrams per liter. Water from the lower geothermal system is chemically different from water from the upper cold-water system. Geothermal water typically has greater concentrations of sodium, bicarbonate, sulfate, chloride, fluoride, silica, arsenic, boron, and lithium and smaller concentrations of calcium, magnesium, and hydrogen. Difference are attributed to ion exchange as geothermal moves through the rock framework. Irrigation, mostly on the Snake River Plain, accounted for about 96 percent of consumptive water use in Idaho during 1980. The use of surface water for irrigation for more than 100 years has caused major changes in the hydrologic system on the plain. Construction of dams, reservoirs, and diversifications effected planned changes in the surface-water system but resulted in largely unplanned changes in the ground-water system. During those years of irrigation, annual recharge in the main part of the eastern plain increased to about 6.7 million acre-feet in 1980, or by about 70 percent. Most of the increase was from percolation of surface water diverted for irrigation. From preirrigation to 1952, groundwater storage increased about 24 million acre-feet, and storage decreased from 1952 to 1964 and from 1976 to 1980 because of below-normal precipitation and increased withdrawals of ground water for irrigation. Annual ground-water discharge increased to about 7.1 million acre-feet in 1980, or about 80 percent since the start of irrigation. About 10 percent of the 1980 total discharge was ground-water pumpage. About 3.1 million acres, or almost one-third of the plain, was irrigated during 1980: 2.0 million acres with surface water, 1.0 million acres with ground water, and 0.1 million acres with combined surface and ground water. About 8.9 million acre-feet of Snake River water was diverted for irrigation during 1980 and 2.3 million acre-feet of ground water was pumped from 5,300 wells. Most irrigation wells on the eastern plain are open to basalt. About two-thirds of them yield more than 1,500 gallons per minute with a reported maximum of 7,240 gallons per minute; drawdown is less than 20 feet in two-thirds of the wells. Most irrigation wells on the western plain are open to sedimentary rocks. About one-third of them yield more than 1,00 gallons per minute with a reported maximum of 3,850 gallons per minute; drawndown is less than 20 feet in about one-fifth of the wells. The major instream use of water on the Snake River Plain is hydroelectric power generation. Fifty-two million acre-feet of water generated 2.6 million megawatthours of electricity during 1980. Digital computer ground-water flows models of the eastern and western plain reasonably simulated regional changes in water levels and ground-water discharges from 1880 (preirrigation) to 1980. Model results support the concept of three-dimensional flow and the hypotheses of no underflow between the eastern and western plain. Simulation of the regional aquifer system in the eastern plain indicates that is 1980 hydrologic conditions, including pumpage, were to remain the same for another 30 years, moderate declines in ground-water levels and decreases in spring discharges would continue. Increased ground-water pumpage to irrigate an additional 1 million acres could cause ground-water levels to decline a few tens of feet in the central part of the plain and could cause corresponding decreases in ground-water discharge. A combination of actions such as increased ground-water pumpage and decreased use of surface water for irrigation (resulting in reduced recharge) would accentuate the changes.

Idaho;Oregon↗

Ground-water resources: Cumberland County, New Jersey

Cumberland County is located in the Atlantic Coastal Plain physiographic province along the northeastern shore of Delaware Bay in Southwestern New Jersey. An average annual hydrologic budget was computed for Cumberland County. Water gains are: precipitation, 1,050 mgd (million gallons per day); surface-water inflow, 142 mgd; ground-water inflow negligible. Water losses are: evapotranspiration, 685 mgd; surface-water outflow, 370 mgd; ground-water outflow, 137 mgd. Unconsolidated and semiconsolidated Coastal Plain sediments, 2,500 to 4,500 feet thick, and ranging in age from Cretaceous to Holocene, consist of layers of clay, silt, sand and gravel. Aquifers composed mainly of sand and gravel occur in the Potomac Group and Raritan and Magothy Formations, the Wenonah Formation and Mount Laurel Sand, the Piney Point Formation, and the Kirkwood Formation and Cohansey Sand. Aquifers in the Potomac-Raritan-Magothy sequence contain saline water and are not currently utilized in Cumberland County. However, they may be utilized in the future for underground storage of fresh water, or possibly other uses when more is known about this aquifer system. The aquifer in the Wenonah Formation and Mount Laurel Sand is not presently utilized in Cumberland County. It is probably suitable for future development, however of wells yielding as much as 300 gpm (gallons per minute) of good quality water in the northern part of the county. The Piney Point Formation is tapped in Cumberland County by only a few wells; each of these generally yield less than 100 gpm. Additional small supplies can be developed from this aquifer. Water from this aquifer requires little or no treatment for domestic use. Two principal aquifers occur in the Kirkwood Formation and Cohansey Sand: (1) the lower Kirkwood aquifer and (2) the Cohansey-Kirkwood aquifer. Most wells tapping the lower Kirkwood aquifer yield less than 50 gpm but are capable of yielding as much as 400 gpm. Wells in the lower Kirkwood range in depth from 200 to 370 feet. The Cohansey-Kirkwood aquifer is the shallowest and most important source of ground-water in the county but is highly susceptible to surface contamination. This aquifer is highly permeable; analysis of data from two pumping tests indicates permeabilities of 1,200 and 2,700 gpm per square foot. It generally yields large supplies of water (300 to 1,200 gpm) to wells from depths of less than 180 feet. Water in the Cohansey-Kirkwood aquifer is characterized by 1mv dissolved-solids content (63 mg/l, median), low hardness (21 mg/l, median), and low pH values (5.5 pH units, median). Water use in Cumberland County varies and is highly seasonal, mainly because of increasing requirements for irrigation and the food processing industries in the county. In 1964 seasonal use ranged from 27 mgd in March to 145 mgd in August. This is much higher than withdrawals in neighboring Salem and Cape May Counties. In 1964 withdrawals in Cumberland County averaged about 51 mgd; almost all of this, 49.4 mgd, was from ground-water supplies. The total annual water use in 1964 according to type of use was: for public supply, 10.6 mgd; for industrial uses, 19.0 mgd; irrigation, 15.4 mgd; suburban, rural, residential, institutional, farm, and commercial, 5.9 mgd.

New Jersey↗

Hydrogeologic characterization of the Modesto Area, San Joaquin Valley, California

Hydrogeologic characterization was done to develop an understanding of the hydrogeologic setting near Modesto by maximizing the use of existing data and building on previous work in the region. A substantial amount of new lithologic and hydrologic data are available that allow a more complete and updated characterization of the aquifer system. In this report, geologic units are described, a database of well characteristics and lithology is developed and used to update the regional stratigraphy, a water budget is estimated for water year 2000, a three-dimensional spatial correlation map of aquifer texture is created, and recommendations for future data collection are summarized. The general physiography of the study area is reflected in the soils. The oldest soils, which have low permeability, exist in terrace deposits, in the interfan areas between the Stanislaus, Tuolumne, and Merced Rivers, at the distal end of the fans, and along the San Joaquin River floodplain. The youngest soils have high permeability and generally have been forming on the recently deposited alluvium along the major stream channels. Geologic materials exposed or penetrated by wells in the Modesto area range from pre-Cretaceous rocks to recent alluvium; however, water-bearing materials are mostly Late Tertiary and Quaternary in age. A database containing information from more than 3,500 drillers'logs was constructed to organize information on well characteristics and subsurface lithology in the study area. The database was used in conjunction with a limited number of geophysical logs and county soil maps to define the stratigraphic framework of the study area. Sequences of red paleosols were identified in the database and used as stratigraphic boundaries. Associated with these paleosols are very coarse grained incised valley-fill deposits. Some geophysical well logs and other sparse well information suggest the presence of one of these incised valley-fill deposits along and adjacent to the Tuolumne River east of Modesto, a feature that may have important implications for ground-water flow and transport in the region. Although extensive work has been done by earlier investigators to define the structure of the Modesto area aquifer system, this report has resulted in some modification to the lateral extent of the Corcoran Clay and the regional dip of the Mehrten Formation. Well logs in the database indicating the presence of the Corcoran Clay were used to revise the eastern extent of the Corcoran Clay, which lies approximately parallel to the axis of valley. The Mehrten Formation is distinguished in the well-log database by its characteristic black sands consisting of predominantly andesitic fragments. Black sands in wells listed in the database indicate that the formation may lie as shallow as 120 meters (400 feet) below land surface under Modesto, approximately 90 meters (300 feet) shallower than previously thought. The alluvial aquifer system in the Modesto area comprises an unconfined to semiconfined aquifer above and east of the Corcoran Clay confining unit and a confined aquifer beneath the Corcoran Clay. The unconfined aquifer is composed of alluvial sediments of the Modesto, Riverbank, and upper Turlock Lake formations. The unconfined aquifer east of the Corcoran Clay becomes semiconfined with depth due to the numerous discontinuous clay lenses and extensive paleosols throughout the aquifer thickness. The confined aquifer is composed primarily of alluvial sediments of the Turlock Lake and upper Mehrten Formations, extending from beneath the Corcoran Clay to the base of fresh water. Ground water in the unconfined to semiconfined aquifer flows to the west and southwest. The primary source of present-day recharge is percolating excess irrigation water. The primary ground-water discharge is extensive ground-water pumping in the unconfined to semiconfined aquifer, imposing a significant component of vertical flow in the system. A water budget was calculated for water year 2000 using a land-use approach. During water year 2000, the total water supply in the Modesto area was more than 2.5 billion m3 (cubic meter) (2 million acre-ft [acre-foot]). Surface-water deliveries accounted for 60 percent of the total water supply, whereas ground-water pumpage accounted for 40 percent. Ninety-four percent of the water supply was used to meet irrigation demand and approximately 6 percent was used to meet urban demand. The total recharge in the model area was estimated at 1.4 billion m3 (1,100,000 acre-ft). The largest component of recharge is from excess irrigation water (58 percent); precipitation in excess of crop requirements accounted for 41 percent of the recharge. Geostatistical methods were used to develop a spatial correlation model of the percentage of coarse-grained texture in the Modesto area. The mean percentage coarse-grained texture calculated for each depth increment indicates a regional trend of decreasing coarse-grained texture with increasing depth, which is consistent with increasingly consolidated sediments with depth in the study area. The three-dimensional kriged estimates of percentage coarse-grained texture show significant heterogeneity in the texture of the sedimentary deposits. Assuming the hydraulic conductivity is correlated to the texture, the kriged result implies significant heterogeneity in the hydrogeologic framework.

California↗

Geohydrology and water utilization in the Willcox Basin, Graham and Cochise Counties, Arizona

The Willcox basin is an area of interior drainage in the northern part of Sulphur Springs Valley, Cochise and Graham Counties, Ariz. The basin comprises about 1,500 square miles, of which the valley floor occupies about 950 square miles. The basin probably formed during middle and late Tertiary time, when the area was subjected to large-scale faulting accompanied by the uplift of the mountain ranges that presently border it. During and after faulting, large quantities of alluvium were deposited in the closed basin. The rocks in the basin are divided into two broad groups--the rocks of the mountain blocks, of Precambrian through Tertiary age, and the rocks of the basin, of Tertiary and Quaternary age. The mountain blocks consist of igneous, metamorphic, and sedimentary rocks; the water-bearing characteristics of these rocks depend primarily on their degree of weathering and fracturing. Even in areas where these rocks are fractured and jointed, only small amounts of water have been developed. The rocks of the basin consist of moderately consolidated alluvium, poorly consolidated alluvium, and unconsolidated alluvium. The water-bearing characteristics of the moderately and poorly consolidated alluvium are not well known. The unconsolidated alluvium underlies most of the valley floor and consists of two facies, stream deposits and lake beds associated with the old playa. The lenticular sand and gravel layers interbedded in silt- and clay-size material of the unconsolidated alluvium constitute the principal aquifer in the basin. The other aquifers, which yield less water, consist of beds of poorly to moderately consolidated sand- and gravel-size material; these beds occur in both the poorly consolidated and moderately consolidated alluvium. In the Stewart area the median specific capacity of wells per 100 feet of saturated unconsolidated alluvium was 20 gallons per minute, and in the Kansas Settlement area the specific capacity of wells penetrating the poorly and moderately consolidated alluvium, undifferentiated, was only 7.4 gallons per minute per 100 feet of saturated material penetrated. The aquifer in the Kansas Settlement area is much less permeable but more homogeneous than the aquifer in the Stewart area. The coefficient of transmissibility of the aquifers, which was estimated from the specific-capacity data, ranged from 58,000 to 160,000 gal. tons per day per foot. Prior to extensive ground-water pumpage, the ground-water system probably was in equilibrium, with discharge equaling recharge. At that time, ground water moved toward the playa, where it was discharged by transpiration and evaporation. The estimate of the evapotranspiration in the playa area before large-scale development was about 75,000 acre-feet per year. On the basis of estimates of coefficients of transmissibility of the aquifer and on the basis of the water-table configuration, underflow toward the playa was computed to be about 54,000 acre-feet per year. By 1963, large-scale pumping had caused marked changes in the shape of the piezometric surface; large cones of depression had developed, and ground-water movement was toward the centers of pumping. The cones of depression caused by large-scale pumping have since expanded, and water-level declines have been measured in the recharge areas along the mountain fronts. Ground water has been used for irrigation since 1910. In 1928, about 4,000 acre-feet of ground water was pumped, and by 1963 180,000 acre-feet per year was being pumped. An estimated 1,860,000 acre-feet of water has been pumped for irrigation in the Willcox basin through 1963; 680,000 acre-feet from the Stewart area, 990,000 acre-feet from the Kansas Settlement area, and 190,000 acre-feet from the Pearce-Cochise area. In the Sierra Bonita Ranch area and the north playa area, ground-water withdrawal for irrigation through 1963 was small. From the spring of 1952 to the spring of 1964 water-level declines resulting from the

Water Supply Paper↗

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

Colorado↗

Geology and ground-water resources of Hays County, Texas

The Edwards limestone of Early Cretaceous age is the chief aquifer for San Marcos Springs and about 160 other springs and wells in Hays County, along the Balcones fault zone in South-central Texas. Hays County is underlain by a basement of Paleozoic rocks; and in the southeastern part of the county the Hosston and Sligo formations of Early Cretaceous age, correlative with the Coahuila series of Mexico, have been encountered in the subsurface. Rocks exposed in the county are principally Cretaceous and Quaternary sedimentary units, which are assigned to the Trinity, Fredericksburg, and Washita groups in the Comanche series; the Eagle Ford shale, Austin chalk, Taylor marl, and Navarro group in the Gulf series: and the Leona formation and equivalent rocks in the Pleistocene series. Recent alluvium and colluvium locally overlie the older rocks. In addition to the Edwards limestone in the Fredericksburg group, waterbearing rock units in Hays County include the Pearsall formation (Travis Peak of outcrop areas) and the Glen Rose limestone in the Trinity group, the Austin chalk and Taylor marl, and the Quaternary rocks. The surface slope and regional dip are toward the southeast. Several normal strike faults have displaced the Cretaceous rocks downward to the southeast, the aggregate displacement being about 1,700 feet within the county. The boundaries of the Edwards limestone ground-water reservoir are formed by major faults which are the major controls of movement of water. Much of the water discharged at San Marcos Springs is derived from influent seepage from streams and infiltration from precipitation in recharge areas southwest of Hays County. The average underground inflow from Comal County through the Edwards limestone reservoir is estimated as 70,000 acre-feet per year for the period 1934-47. The discharge of San Marcos Springs, averaging about 55 million gallons a day during 1955, greatly exceeds local ground-water recharge within Hays County. Depth to water, direction of movement of water, subsurface location of aquifers, and quality of water in Hays County have been determined from records of 519 wells and springs, drillers' logs of 49 wells, periodic water-level measurements in about 70 wells, and chemical analyses of water samples from 238 wells and springs. Ground water from wells in the Pearsall formation generally contains less than 500 parts per million of dissolved solids. Water from the Glen Rose limestone in some places contains more than 500 parts per million of sulfate and more than 1,000 parts per million of dissolved solids; locally it is high in nitrate also. Except in the southeastern part of the county, water from the Edwards limestone is commonly very hard but is otherwise of good quality for most uses. Analyses of two water samples from the Austin chalk indicate a high content of bicarbonate. Water from the Taylor marl and from Quaternary sediments generally is hard, and locally it contains excessive nitrate. Most wells in Hays County are used for domestic and stock supplies. About 20 wells, most of them in the Edwards limestone, yield water in relatively large amounts for industrial use, irrigation, or public supplies.

Water Supply Paper↗

Distribution and demography of Southwestern Willow Flycatchers in San Diego County, 2015–19

We surveyed for Southwestern Willow Flycatchers ( Empidonax traillii extimus ; flycatcher) at 33 locations along multiple drainages in San Diego County, including portions of Agua Hedionda Creek, Cottonwood Creek, Escondido Creek, Los Penasquitos Creek, Otay River, San Diego River, San Dieguito River, San Luis Rey River, Sweetwater River, and Tijuana River. Resident flycatchers were only found on two drainages in San Diego County, at San Dieguito and San Luis Rey Rivers, with 99 percent occurring on the San Luis Rey River. Resident flycatchers were detected at 18 percent of survey locations (Bonsall, Cleveland National Forest, Rey River Ranch, San Dieguito, and Vista Irrigation District [VID], and VID Lake Henshaw). Resident flycatchers were documented for the first time at Lake Henshaw, the only new location surveyed that supported flycatchers. We detected a minimum of 80 resident flycatchers from 2015 to 2019, most of these were upstream and downstream from Lake Henshaw. Transient flycatchers were found at 42 percent of survey locations; 38 transient individuals were detected at Agua Hedionda Creek, Otay River, San Diego River, San Dieguito River, and the San Luis Rey River. Over the course of this study, 11 locations historically occupied by resident flycatchers were resurveyed; only 5 were found to have resident flycatchers: (1) Bonsall, (2) Cleveland National Forest, (3) Rey River Ranch, (4) San Dieguito, and (5) Vista Irrigation District. The number of resident flycatchers declined from previous high counts at all five locations. Collectively, the number of resident flycatcher territories within the historically occupied area of the upper San Luis Rey River downstream from Lake Henshaw (Cleveland National Forest, Rey River Ranch, and Vista Irrigation District) declined 71 percent between 1999 (48) and 2019 (14); 42 percent of the decline occurred between 1999 and 2016, with an additional decline (50 percent) occurring between 2016 and 2019. In 2016, the distribution of flycatcher territories at the historically occupied area of the upper San Luis Rey River changed relative to the distribution in 1999: the proportion of territories at Cleveland National Forest and Rey River Ranch decreased to 36 percent each, while Vista Irrigation District increased to 29 percent, creating a more equal distribution of territories across the historically occupied area. By 2019, the distribution changed relative to 2016, with most of the territories spread equally between Cleveland National Forest and Rey River Ranch (43 percent each), while the proportion of territories at Vista Irrigation District declined to 14 percent. During countywide surveys, we documented the dispersal of two natal banded flycatchers; both were females that were originally banded as nestlings at Marine Corps Base Camp Pendleton and were seen for the first time as breeding adults. One of the females dispersed to San Dieguito, a distance of 41 kilometers, and a second female dispersed to Cleveland National Forest, a distance of 55 kilometers. We also documented the within-season movement of a uniquely banded male that was seen at the beginning of the 2017 breeding season at Bonsall and was later documented at San Dieguito, a movement distance of 31 kilometers. We completed nest monitoring activities along the upper San Luis Rey River near Lake Henshaw in Santa Ysabel, California from 2016 to 2019. Monitoring occurred at three locations: (1) Cleveland National Forest, (2) Rey River Ranch, and (3) Vista Irrigation District, collectively the upper San Luis Rey River monitoring area. The number of flycatcher territories monitored each year ranged from 14 to 27. We observed polygynous pairings (one male paired with multiple females) in all years, with the lowest rate of polygyny (number of polygynous pairs/total number of pairs) observed in 2016 (10 percent) and the highest in 2017 (70 percent). The proportion of paired males that were polygynous ranged from 5 to 54 percent between 2016 and 2019. We monitored the nesting activity of 14–27 pairs annually during the course of the study. Most of the first nesting attempts were initiated during late May and early June. We monitored 18–41 Southwestern Willow Flycatcher nests per year from 2016 to 2019. Apparent nest success ranged from 11 to 37 percent and differed significantly by year, with higher success in 2016 and 2017 compared to 2018 and 2019. Predation was the presumed to be the primary source of nest failure, with 63–84 percent of failures annually attributed to predation. Although none of the failures were attributed to Brown-headed cowbird ( Molothrus ater ) parasitism, 4–27 percent of nests were parasitized annually from 2016 to 2019, with increased parasitism rates observed in 2018 and 2019 compared to 2016 and 2017. We “rescued” 11 parasitized nests between 2016 and 2019 by removing cowbird eggs; if those nests had been allowed to fail, apparent nest success would have been up to 45 percent lower annually. Flycatcher egg clutch size ranged from 2.8±0.8 to 3.1±0.8 annually and did not vary significantly between years. The number of fledglings per pair ranged from 0.5±1.0 to 1.6±1.5 annually from 2016 to 2019. There was a significant difference in the number of young fledged per pair between years, with pairs in 2016 producing more than three times the number of fledglings compared to 2019. The percent of pairs fledging at least one young ranged from 18 to 62 percent annually but did not vary significantly by year. Analysis of flycatcher daily nest survival rates suggested that both early and late winter precipitation influenced nest survival, with increases in early winter precipitation positively influencing nest survival and later winter precipitation negatively influencing nest survival. The second-best supported model included year, with the lowest daily nest survival occurring in 2018 and 2019. A total of 119 flycatchers were newly banded over the course of this study; 36 adult flycatchers were banded with a unique color combination, and 83 nestlings (57 of which survived to fledging) were banded with a single band on the left or right leg. In addition, two adults that were banded before 2015 were observed in the monitoring area. Between 2015 and 2019, we accumulated 94 resights of 49 individual color-banded adult flycatchers that ranged in age from 1 to 8 years old. Banding allowed us to examine differences in annual survivorship among flycatchers of different ages and sexes. We estimated annual survivorship of adult males to be 69±7 percent, which is higher than estimates of female survivorship (45±10 percent). Annual survivorship of first-year flycatchers ranged from 24 to 41 percent, which is roughly half the estimates calculated for adult flycatchers (52–75 percent). We found no evidence that precipitation in the previous breeding year had an effect on flycatcher survival. We were also able to observe dispersal and movement among adults and first-year flycatchers. Average first-year dispersal distance was 3.1±2.6 kilometers, with the longest dispersal (8.5 kilometers) by a natal female dispersing from the monitoring area to Lake Henshaw. Of the first-year flycatchers, 65 percent returned to the monitoring area to establish an adult breeding territory, while the remaining 35 percent dispersed to Lake Henshaw. Territory fidelity among adult flycatchers was high with 69±13 percent of returning adults occupying the same territory (or within 100 meters) from the previous year. There was no significant difference in territory fidelity between males and females, or across years. Nesting success in the previous year appeared to be a strong driver of territory fidelity, with adults more likely to return to the same territory following years when they successfully fledged young. The average between-year movement for returning adult flycatchers was 0.5±0.8 km. We documented the movement of two adult males from the monitoring area to Lake Henshaw. Between-year movement distances did not differ by sex or year. Resident flycatchers in the upper San Luis Rey River monitoring area used five habitat types from 2016 to 2019: (1) willow-oak, (2) willow-ash, (3) oak-sycamore, (4) mixed willow riparian, and (5) willow-sycamore, with willow-oak the most commonly used habitat type. The most commonly recorded dominant species at flycatcher territories included coast live oak ( Quercus agrifolia ), red or arroyo willow ( Salix laevigata or Salix lasiolepis ), California sycamore ( Platanus racemosa ), and velvet ash ( Fraxinus velutina ). In 2018, we anecdotally began to observe dead and dying oaks in the monitoring area, which we believe to be the result of goldspotted oak borer ( Agrilus auroguttatus ) infestation. At the conclusion of this study, we investigated the overall change in normalized difference vegetation index (NDVI) in flycatcher territories within the monitoring area. The greatest negative change in NDVI occurred in territories closest to Lake Henshaw, and many of the affected territories were no longer occupied in the later years of the study. Flycatchers used 13 plant species for nesting at the monitoring area from 2016 to 2019; 70 percent of all nests were placed in coast live oak. None of the nest characteristics including host height, nest height, distance to the edge of the host, or distance to the edge of the vegetation clump where the nest was placed differed between years. In 2016, successful nests were placed higher than unsuccessful nests; no other within-year differences were observed.

California↗

Quality of Shallow Groundwater and Drinking Water in the Mississippi Embayment-Texas Coastal Uplands Aquifer System and the Mississippi River Valley Alluvial Aquifer, South-Central United States, 1994-2004

The Mississippi embayment-Texas coastal uplands aquifer system is an important source of drinking water, providing about 724 million gallons per day to about 8.9 million people in Texas, Louisiana, Mississippi, Arkansas, Missouri, Tennessee, Kentucky, Illinois, and Alabama. The Mississippi River Valley alluvial aquifer ranks third in the Nation for total withdrawals of which more than 98 percent is used for irrigation. From 1994 through 2004, water-quality samples were collected from 169 domestic, monitoring, irrigation, and public-supply wells in the Mississippi embayment-Texas coastal uplands aquifer system and the Mississippi River Valley alluvial aquifer in various land-use settings and of varying well capacities as part of the U.S. Geological Survey's National Water-Quality Assessment Program. Groundwater samples were analyzed for physical properties and about 200 water-quality constituents, including total dissolved solids, major inorganic ions, trace elements, radon, nutrients, dissolved organic carbon, pesticides, pesticide degradates, and volatile organic compounds. The occurrence of nutrients and pesticides differed among four groups of the 114 shallow wells (less than or equal to 200 feet deep) in the study area. Tritium concentrations in samples from the Holocene alluvium, Pleistocene valley trains, and shallow Tertiary wells indicated a smaller component of recent groundwater than samples from the Pleistocene terrace deposits. Although the amount of agricultural land overlying the Mississippi River Valley alluvial aquifer was considerably greater than areas overlying parts of the shallow Tertiary and Pleistocene terrace deposits wells, nitrate was rarely detected and the number of pesticides detected was lower than other shallow wells. Nearly all samples from the Holocene alluvium and Pleistocene valley trains were anoxic, and the reducing conditions in these aquifers likely result in denitrification of nitrate. In contrast, most samples from the Pleistocene terrace deposits in Memphis, Tennessee, were oxic, and the maximum nitrate concentration measured was 6.2 milligrams per liter. Additionally, soils overlying the Holocene alluvium and Pleistocene valley trains, generally in areas near the wells, had lower infiltration rates and higher percentages of clay than soils overlying the shallow Tertiary and Pleistocene terrace deposits wells. Differences in these soil properties were associated with differences in the occurrence of pesticides. Pesticides were most commonly detected in samples from wells in the Pleistocene terrace deposits, which generally had the highest infiltration rates and lowest clay content. Median dissolved phosphorus concentrations were 0.07, 0.11, and 0.65 milligram per liter in samples from the shallow Tertiary, Pleistocene valley trains, and Holocene alluvium, respectively. The widespread occurrence of dissolved phosphorus at concentrations greater than 0.02 milligram per liter suggests either a natural source in the soils or aquifer sediments, or nonpoint sources such as fertilizer and animal waste or a combination of natural and human sources. Although phosphorus concentrations in samples from the Holocene alluvium were weakly correlated to concentrations of several inorganic constituents, elevated concentrations of phosphorus could not be attributed to a specific source. Phosphorus concentrations generally were highest where samples indicated anoxic and reducing conditions in the aquifers. Elevated dissolved phosphorus concentrations in base-flow samples from two streams in the study area suggest that transport of phosphorus with groundwater is a potential source contributing to high yields of phosphorus in the lower Mississippi River basin. Water from 55 deep wells (greater than 200 feet deep) completed in regional aquifers of Tertiary age represent a sample of the principal aquifers used for drinking-water supply in the study area. The wells were screened in both confined and

Scientific Investigations Report↗

Ground-water resources of the Houston district, Texas

This report covers the current phase of an investigation of the supply of ground water available for the Houston district and adjacent region, Texas,- that has been in progress during the past 10 years. The field operations included routine inventories of pumpage, measurements of water levels in observation wells and collection of other hydrologic data, pumping tests on 21 city-owned wells to determine coefficients of permeability and storage, and the drilling of 13 deep test wells in unexplored parts of the district. Considerable attention has been given to studies of the location of areas or beds of sand that contain salt water. The ground water occurs in beds of sand, sandstone, and gravel of Miocene, Pliocene, and Pleistocene age. These formations crop out in belts that dip southeastward from their outcrop areas and are encountered by wells at progressively greater depths toward the southeast. The beds throughout the section are lithologically similar, and there is little agreement among geologists as to their correlation. -In this investigation, however, the sediments, penetrated by the wells are separated into six zones, chiefly on the basis of electrical logs. Most of the water occurs in zone 3, which ranges in thickness from 800 to 1,200 feet. Large quantities of ground water are pumped in three areas in the Houston district, as follows: The Houston tromping area, which includes Houston and the areas immediately adjacent; the Pasadena pumping area, which includes the industrial section extending along the ship channel from the Houston city limits eastward to Deer Park; and the Katy pumping area, an irregular-shaped area of several hundred square miles, which is roughly centered around the town of Katy, 30 miles west of Houston. In 1930 the total combined withdrawal of ground water in the Houston and Pasadena pumping areas averaged about 50 million gallons a day. It declined somewhat during 1932 and 1933 and then gradually increased, until in 1935 the total pumpage was about the same as it was in 1930. About March 1, 1937, the pumpage was increased by about 40 percent, when new wells near Pasadena were put into operation. During 1940 it is estimated that the total pumpage in the Houston and Pasadena areas averaged about 79 million gallons a day, an increase of about 65 percent over the pumpage in 1935. About 25 million gallons of this increase has occurred in the Pasadena area. In the Katy rice-growing area the pumpage in 1935 was about 14 million gallons a day; in 1937 it was about 30 million gallons a day; in 1939 about 40 million gallons a day; and in 1940 about 45 million gallons a day. In 1940 the estimated total pumpage from the Houston, Pasadena, and Katy pumping areas was about 124 million gallons a day, or twice as much as it was in 1935. The increase in pumping at Pasadena in the spring-of 1937 caused the water leveling wells in the Houston and Pasadena areas, which had not varied materially for about 7 years, to decline at a rapid rate. Further increases in the pumping both at Houston and Pasadena in 1939 and 1940 has caused further substantial decline. The water levels in wells in the Katy rice-growing area also declined materially. The evidence points to the probability that in all parts of the Houston district, except the Katy rice-growing area, the rainfall is recharging the aquifers at a rate greater than that at which the water is transmitted down the dip. In the Katy area the recharge is insufficient to balance the joint discharge by transmission down the dip and withdrawal from rice-irrigating wells. The average coefficient of transmissibility was. calculated as 160,000 gallons a day. On the basis of these estimates the inflow in February 1940 across the artesian contour 10 feet below sea level (see pl. 10) was computed as 72 million gallons a day. The amount of water taken out of artesian storage in the 300-square mile area within the -10 contour during the period February 1939 to February

Water Supply Paper↗

Status and understanding of groundwater quality in the Monterey-Salinas Shallow Aquifer Study Unit, 2012–13: California GAMA Priority Basin Project

Groundwater quality in the approximately 7,820-square-kilometer (km 2 ) Monterey-Salinas Shallow Aquifer (MS-SA) study unit was investigated from October 2012 to May 2013 as part of the second phase of the Priority Basin Project of the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The study unit is in the central coast region of California in the counties of Santa Cruz, Monterey, and San Luis Obispo. The GAMA Priority Basin Project is being conducted by the California State Water Resources Control Board in cooperation with the U.S. Geological Survey and the Lawrence Livermore National Laboratory. The MS-SA study was designed to provide a statistically robust assessment of untreated-groundwater quality in the shallow aquifer systems. The assessment was based on water-quality samples collected by the U.S. Geological Survey from 100 groundwater sites and 70 household tap sites, along with ancillary data such as land use and well-construction information. The shallow aquifer systems were defined by the depth interval of wells associated with domestic supply. The MS-SA study unit consisted of four study areas—Santa Cruz (210 km 2 ), Pajaro Valley (360 km 2 ), Salinas Valley (2,000 km 2 ), and Highlands (5,250 km 2 ). This study had two primary components: the status assessment and the understanding assessment . The first primary component of this study—the status assessment —assessed the quality of the groundwater resource indicated by data from samples analyzed for volatile organic compounds (VOCs), pesticides, and naturally present inorganic constituents, such as major ions and trace elements. The status assessment is intended to characterize the quality of groundwater resources in the shallow aquifer system of the MS-SA study unit, not the treated drinking water delivered to consumers by water purveyors. As opposed to the public wells, however, water from private wells, which often tap the shallow aquifer, is usually consumed without any treatment. The second component of this study—the understanding assessment —identified the natural and human factors that potentially affect groundwater quality by evaluating land-use characteristics, measures of location, geologic factors, groundwater age, and geochemical conditions of the shallow aquifer. An additional component of this study was a comparison of MS-SA water-quality results to those of the GAMA Monterey Bay and Salinas Valley Groundwater Basins study unit. This study unit covered much of the same areal extent as the MS-SA, but assessed the deeper, public drinking-water aquifer system. Relative concentrations (sample concentration divided by the benchmark concentration) were used to evaluate concentrations of constituents in groundwater samples relative to water-quality benchmarks for those constituents that have Federal or California benchmarks, such as maximum contaminant levels. For organic and special-interest constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.1 and less than or equal to 1.0; or low, less than or equal to 0.1. For inorganic constituents, relative concentrations were classified as high, greater than 1.0; moderate, greater than 0.5 and less than or equal to 1.0; or low, less than or equal to 0.5. A relative concentration greater than 1.0 indicates that the concentration was greater than a benchmark. Aquifer-scale proportions were used to quantify regional-scale groundwater quality. The aquifer-scale proportions are the areal percentages of the shallow aquifer system where relative concentrations for a given constituent or class of constituents were high, moderate, or low. Inorganic constituents were measured at high and moderate relative concentrations more frequently than organic constituents. In the MS-SA study unit, inorganic constituents with benchmarks were detected at high relative concentrations in 51 percent of the study unit. The greatest proportions of high relative concentrations of trace elements and radioactive constituents were in the Highlands and Santa Cruz study areas, whereas high relative concentrations of nutrients were most often detected in the Salinas Valley and Pajaro Valley study areas and salinity indicators were most often detected in the Highlands and Salinas Valley study areas. The trace elements detected at high relative concentrations were arsenic, boron, iron, manganese, molybdenum, selenium, and strontium. The radioactive constituents detected at high relative concentrations were adjusted gross alpha radioactivity and uranium. The nutrient detected at high relative concentrations was nitrate plus nitrite. The salinity indicators detected at high relative concentrations were chloride, sulfate, and total dissolved solids. Organic constituents (VOCs and pesticides) were not detected at high relative concentrations in any of the study areas. The fumigant 1,2-dichloropropane was detected at moderate relative concentrations. The VOC chloroform and the pesticide simazine were the only organic constituents detected in more than 10 percent of samples. The constituents of special interest NDMA ( N -nitrosodimethylamine) and perchlorate were detected at high relative concentrations in the MS-SA study unit. Selected constituents were evaluated with explanatory factors to identify potential sources or processes that could explain their presence and distribution. Trace elements and radioactive constituents came from natural sources and were not elevated by anthropogenic sources or processes, except for selenium and the radioactive constituent uranium. Arsenic, manganese, iron, selenium, and uranium concentrations were all influenced by oxidation-reduction conditions. Unlike other trace elements and radioactive constituents, uranium and selenium can be affected by agricultural practices. Uranium and selenium can be released from aquifer sediments as a result of irrigation recharge water interacting with bicarbonate systems. Nitrate can be strongly affected by anthropogenic sources. Nitrate concentrations were significantly higher in modern groundwater, indicating recent inputs of nitrate to the shallow aquifer system. Nitrate was positively correlated with agricultural land use, indicating that irrigation-return water could be leaching nitrogen fertilizer and naturally present nitrate to elevate nitrate concentrations in shallow groundwater. The salinity indicators total dissolved solids, chloride, and sulfate all had natural sources in the MS-SA study unit, primarily marine sediments. Concentrations of the constituents were elevated as a result of evaporative concentration of irrigation water or precipitation. Sulfate concentrations were significantly correlated to agricultural land use, indicating that agricultural land-use practices are a contributing source of sulfate to groundwater. The samples with most of the detections of VOCs were from sites in the Pajaro Valley and northern part of the Salinas Valley. Most of the samples with pesticide detections were from sites in the Salinas Valley study area. The herbicide simazine was positively correlated to the percentage of agricultural land use, and its concentrations were higher in modern groundwater than in pre-modern groundwater. Perchlorate, similar to nitrate, has natural and anthropogenic sources. Correlations of perchlorate to dissolved oxygen, nitrate, and percentage of agricultural land use indicated that the irrigation-return water could be leaching naturally present perchlorate, as well as perchlorate from historical applications of Chilean nitrate fertilizer, to increase perchlorate concentrations in groundwater. The quality of the water in the shallow aquifer system from this study was compared with the quality of water in the public drinking-water aquifer in a previous GAMA (MS-PA) study in the same area. The shallow system was more oxic and had more sites with modern groundwater than the public drinking-water aquifer, which was more anoxic and had sites with more pre-modern groundwater. Arsenic and selenium were found at high relative concentrations in a greater proportion of the shallow system. Manganese and iron were found at high relative concentrations in a greater proportion of the public drinking-water aquifer. Uranium was found at higher relative concentrations in a greater proportion of the shallow system. Concentrations of arsenic, iron, manganese, and molybdenum are not likely to change much as groundwater percolates from the shallow system to the public drinking-water aquifer because there are no anthropogenic sources affecting these constituents. Uranium and selenium concentrations in the public drinking-water aquifer could be affected by the higher concentrations in the shallow system because of irrigation-return water, however. Nitrate and salinity indicators had concentrations that were much higher in the shallow system than the deeper public drinking-water aquifer. High concentrations of these constituents in the shallow system could lead to increased concentrations in the public drinking-water aquifer in parts of the study units because of land-use practices, such as irrigated agriculture. Organic constituents were detected more frequently in the public drinking-water aquifer than in the shallow system, possibly because more of the sites sampled in the public drinking-water aquifer were in urban areas compared to the sites sampled for the shallow system or because sources of contamination have decreased as a result of changes in use at the land surface.

California↗

Geologic framework and hydrogeology of the middle Carson River Basin, Eagle, Dayton, and Churchill Valleys, West-Central Nevada

Changes in land use and water use and increasing development of water resources in the middle Carson River basin may affect flow of the river and, in turn, affect downstream water users dependent on sustained river flows to Lahontan Reservoir. The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, began a study in 2008 of the middle Carson River basin, extending from Eagle Valley to Churchill Valley. Various types of geologic and hydrologic data were compiled from previous studies, collected for this study, and compiled and analyzed to provide a framework for development of a numerical model of the groundwater and surface-water flow systems of the basin. Geologic units that are assumed to have similar hydrologic characteristics were grouped into hydrogeologic units comprised of consolidated rocks of pre-Cenozoic age that underlie a unit of consolidated volcanic rock and semi-consolidated sediments of Tertiary age. The principal aquifer in the study area is comprised of unconsolidated sediments of Quaternary age. The Quaternary sediments include alluvial fan, fluvial, and lake sediments, and were grouped into a basin-fill hydrogeologic unit that overlies the pre-Cenozoic and Tertiary hydrologic units. The thickness of the combined section of Tertiary volcanic and sedimentary rocks and Quaternary basin-fill deposits previously was estimated to range from zero where pre-Cenozoic rocks are exposed to greater than 10,000 feet in the Bull Canyon subbasin, and greater than 6,000 feet on the western side of Churchill Butte and beneath the Desert Mountains. The thickness of Quaternary basin-fill sediments was estimated using gravity data and lithologic descriptions from driller’s logs. The most permeable parts of basin-fill sediments are greater than 1,000 feet thick in the Carson Plains subbasin, greater than 800 feet and 600 feet thick in the western and northeastern parts of the Stagecoach subbasin, and greater than 1,000 feet and 800 feet thick in the northern and southern parts of Churchill Valley, respectively. The distribution of aquifer properties was estimated for basin-fill sediments using slug-test and aquifer test data, and the lithologic descriptions of previously mapped geologic units. Slug-test data show hydraulic conductivity is greater than 10 to greater than 100 feet per day for fluvial sediments near the flood plain, less than 10 feet per day for basin-fill sediments outside the flood plain, and less than 1 foot per day for consolidated rocks. Estimates of transmissivity exceed 20,000 feet squared per day near the Carson River in Dayton, Churchill, and western Lahontan Valleys and in the northern part of the Stagecoach subbasin, and exceed 10,000 feet squared per day in the western part of Churchill Valley. A transmissivity of 90,000 feet squared per day was estimated from results of an aquifer test in the Carson Plains subbasin, indicating that permeable gravel and cobble zones at depths greater than 400 feet supplied water to the pumping well. Estimates of specific yield ranged from less than 1 to 2 percent for most consolidated rocks, from 1 to 15 percent for semi-consolidated Tertiary sediments, and from 10 to 40 percent for unconsolidated basin-fill sediments. Water-level altitude maps based on measurements at about 300 wells in 2009 show water levels have declined as much as 70 feet since 1964 on the northwestern side of Eagle Valley, about 10 feet since 1995 near Dayton in the Carson Plains subbasin, and from 5 to 10 feet since 1982 in the western and northeastern parts of the Stagecoach subbasin and the northwestern part of Churchill Valley. The declines are likely the result of municipal and agricultural pumping. The maps show a groundwater divide between the Carson Plains and Stagecoach subbasins, and a continuous hydraulic gradient between the Stagecoach subbasin and Churchill Valley. Groundwater flow directions are uncertain beneath parts of the boundary of Churchill Valley. The altitude of the top of pre-Cenozoic rocks shows thick sections of saturated Tertiary rocks and sediments south of the Dead Camel Mountains and beneath the eastern part of the Desert Mountains through which groundwater flow between Churchill Valley, Mason Valley, and Lahontan Valley may take place. North of Lahontan reservoir, beneath the Dead Camel Mountains, and beneath the southern part of Adrian Valley, the altitude of pre-Cenozoic rocks indicates groundwater flow between the three valleys is minimal. Streamflow measurements, supported by data on the deuterium content and specific conductance of surface-water samples, indicate a loss of Carson River streamflow in the Riverview subbasin, streamflow gains in the Moundhouse subbasin and the eastern part of the Carson Plains subbasin, and streamflow losses in the Bull Canyon subbasin. Comparisons of fluctuations in groundwater levels to those in stream stage in the Carson Plains subbasin indicate that streamflow lost to infiltration from the Carson River, from irrigation ditches, and from irrigated fields is an important source of groundwater recharge. Fluctuations in groundwater levels compared with the stage of Lahontan Reservoir in Churchill Valley indicate losses to infiltration from the reservoir during high stage and groundwater seepage to the reservoir during low stage.

Nevada↗

Geologic and hydrogeologic characteristics of the White River Formation, Lance Formation, and Fox Hills Sandstone, northern greater Denver Basin, southeastern Laramie County, Wyoming

In cooperation with the Wyoming State Engineer’s Office, the U.S. Geological Survey studied the geologic and hydrogeologic characteristics of Cenozoic and Upper Cretaceous strata at a location in southeastern Laramie County within the Wyoming part of the Cheyenne Basin, the northern subbasin of the greater Denver Basin. The study aimed to improve understanding of the aquifers/aquifer systems in these strata, motivated in part by declining groundwater levels and interest in exploring future groundwater supplies. Based on detailed geologic characterization using information obtained by drilling and coring a 960-foot-(ft) deep exploratory borehole, and comparisons with previously published descriptions, identified Cenozoic lithostratigraphic units included 40 ft of Quaternary older alluvial fan deposits consisting of an unconsolidated mixture of sand and gravel with lesser quantities of silt and clay in varying proportions and the underlying 407.3-ft-thick White River Formation of late Eocene-Oligocene age consisting largely of mudrocks with sparse thin beds of sandstone, muddy gravel, and conglomeratic mudrocks. Identified Upper Cretaceous lithostratigraphic units included the 351.6-ft-thick Lance Formation, consisting of terrestrial sedimentary rocks including mudrocks (muddy shale and silty and sandy shale, siltstone, claystone, and mudstone) interbedded with much smaller quantities of very fine- to medium-grained muddy and silty sandstone and coal; the 79.6-ft-thick Fox Hills Sandstone, consisting of a transitional marine sequence of muddy or silty sandstone present in five individual beds; and 86.7 ft of the upper transition member of the Pierre Shale, consisting largely of marine sedimentary rocks such as muddy shale. Beds of the upper and lower Fox Hills Sandstone were separated by tongues of the Lance Formation and upper transition member of the Pierre Shale, respectively. The White River hydrogeologic unit, consisting of the entire White River Formation or Group at the study site, did not contain any substantial secondary permeability features in the mudrocks that composed almost all the unit. A monitoring well (BR–1) was completed in the White River aquifer with the well screen open to the only coarse-grained unit (muddy sandstone) that had sufficient thickness and permeability to be considered as an aquifer. Sampling of the well for a broad suite of constituents indicated groundwater generally was of excellent quality except dissolved arsenic was detected at a concentration greater than the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level, and dissolved sodium was measured at a concentration greater than several EPA Drinking Water Advisory Levels (DWAs) for the constituent. Well development, well purging for groundwater sampling, and calculated aquifer properties indicated the sandstone aquifer screened by monitoring well BR–1 was not very productive. Analysis of the well water-level responses in BR–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response with wellbore-storage effects. Hydraulic properties estimated based on these responses yielded values of hydraulic conductivity ( K , 0.057 foot per day [ft/d]), specific storage ( Ss , 1.6×10 −6 per foot [ft −1 ]) and porosity ( n , 0.43). Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated an upward trend (+1.13 foot per year [ft/yr]) during the period analyzed, September 5, 2014, to September 30, 2017. Lithologic characteristics of the Lance hydrogeologic unit, consisting of the entire Lance Formation at the study site, indicated a potential aquifer in a “sandy” interval in the upper part of the unit. Most of the Lance hydrogeologic unit below the “sandy” interval consisted of various low-permeability lithologies unlikely to yield substantial quantities of water. This lower part of the hydrogeologic unit likely functions as a confining unit separating the underlying Lance-Fox Hills aquifer. A geologic cross section constructed for this study indicated fine-grained sediments composed most of the Lance Formation/hydrogeologic unit not only at the study location, but also throughout southern Laramie County along the line of section and throughout the Wyoming and Colorado parts of the Cheyenne Basin. A monitoring well (LN–1) completed in a sandstone bed in the “sandy” interval of the Lance hydrogeologic unit produced a mean of about 23 gallons per minute (gal/min) during well development, indicating sandstone beds can form moderately productive confined subaquifers in this part of the hydrogeologic unit. Analysis of the well water-level responses in well LN–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties estimated based on these responses yielded values for a lower bounding K of 0.60 ft/d, Ss of 1.6×10 −6 ft −1 , and n of 0.38. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−0.86 ft/yr) during the period analyzed (November 8, 2014, to September 30, 2017). Analyses for a broad suite of constituents in samples from well LN–1 indicated groundwater quality generally was excellent, although dissolved sodium was measured at a concentration greater than two EPA DWA levels for the constituent. Because of the absence of any overlying or intertonguing sandstone beds belonging to the lower/basal part of the Lance Formation, the Lance-Fox Hills aquifer at the study site consisted only of the five sandstone beds of the Fox Hills Sandstone. The cross section constructed for this study illustrated how the Fox Hills Sandstone, and thus, most of the Lance-Fox Hills aquifer, consists of a series of sandstone bodies that overlap (shingle) upward to the east across southern Laramie County. These bodies collectively form a fairly continuous body of sandstone, thus potentially forming an areally extensive aquifer across southern Laramie County, and by extension, throughout most of the formation’s extent in the Wyoming part of the Cheyenne Basin, as is the case in the Colorado part of the basin. A monitoring well (FH–1) completed in part of the thickest sandstone bed of the Lance-Fox Hills aquifer was moderately to highly productive and easily produced 25 to 30 gal/min after development. Substantially larger water production rates likely could be obtained by penetrating the full thickness of this bed and by completing a well open to the other overlying and underlying sandstone beds of the aquifer. Analysis of the water-level responses in well FH–1 to atmospheric loading and Earth tides indicated the responses were consistent with a confined-aquifer response. Hydraulic properties computed based on these responses yielded values for a lower bounding estimate for K of 0.26 ft/d, for Ss of 1.0×10 −6 ft −1 , and for n of 0.41. Water levels filtered to remove the effects of atmospheric loading and Earth tides indicated a downward trend (−1.74 ft/yr) during the period analyzed, December 19, 2014, to September 30, 2017. Sampling of monitoring well FH–1 and two production wells completed in the Fox Hills Sandstone in other parts of Laramie County indicated groundwater quality generally is excellent, although pH exceeded a recommended EPA aesthetic drinking-water standard (Secondary Maximum Contaminant Level) in two of three sampled wells, total dissolved solids concentrations exceeded the Secondary Maximum Contaminant Level in one of the two sampled production wells, and dissolved sodium was measured in all three sampled wells at a concentration greater than two EPA DWA levels for the constituent. The Wyoming Class II agricultural (irrigation) sodium adsorption ratio standard of 8 was exceeded in all three sampled wells, indicating these waters are not suitable for irrigation use. Computed vertical hydraulic gradients indicated a strong potential for downward flow throughout the groundwater system at the study site, including from the low-yielding aquifer in the upper White River Formation/hydrogeologic unit (monitoring well BR–1) to the sandstone subaquifer in the Lance Formation/hydrogeologic unit (monitoring well LN–1), and from the Lance subaquifer (monitoring well LN–1) to the sandstone bed/aquifer that composes much of the Lance-Fox Hills aquifer thickness at the study site (monitoring well FH–1). However, large hydraulic-head differences between wells indicated high resistance to vertical flow attributable to the low vertical hydraulic conductivity of intervening strata, which consisted almost entirely of low-permeability mudrocks. The confined nature of the sandstone aquifers monitored by the various wells coupled with dissimilarities between groundwater-level fluctuations and trends in groundwater levels indicated downward flow through the intervening strata (primarily mudrocks in the various lithostratigraphic/hydrogeologic units) between the examined sets of wells likely was small.

Wyoming↗

Geophysics- and geochemistry-based assessment of the geochemical characteristics and groundwater-flow system of the U.S. part of the Mesilla Basin/Conejos-Médanos aquifer system in Doña Ana County, New Mexico, and El Paso County, Texas, 2010–12

One of the largest rechargeable groundwater systems by total available volume in the Rio Grande/Río Bravo Basin (hereinafter referred to as the “Rio Grande”) region of the United States and Mexico, the Mesilla Basin/Conejos-Médanos aquifer system, supplies water for irrigation as well as for cities of El Paso, Texas; Las Cruces, New Mexico; and Ciudad Juárez, Chihuahua, Mexico. The U.S. Geological Survey in cooperation with the Bureau of Reclamation assessed the groundwater resources in the Mesilla Basin and surrounding areas in Doña Ana County, N. Mex., and El Paso County, Tex., by using a combination of geophysical and geochemical methods. The study area consists of approximately 1,400 square miles in Doña Ana County, N. Mex., and 100 square miles in El Paso County, Tex. The Mesilla Basin composes most of the study area and can be divided into three parts: the Mesilla Valley, the West Mesa, and the East Bench. The Mesilla Valley is the part of the Mesilla Basin that was incised by the Rio Grande between Selden Canyon to the north and by a narrow valley (about 4 miles wide) to the southeast near El Paso, Tex., named the Paso del Norte, which is sometimes referred to in the literature as the “El Paso Narrows.” Previously published geophysical data for the study area were compiled and these data were augmented by collecting additional geophysical and geochemical data. Geophysical resistivity measurements from previously published helicopter frequency domain electromagnetic data, previously published direct-current resistivity soundings, and newly collected (2012) time-domain electromagnetic soundings were used in the study to detect spatial changes in the electrical properties of the subsurface, which reflect changes that occur within the hydrogeology. The geochemistry of the groundwater system was evaluated by analyzing groundwater samples collected in November 2010 for physicochemical properties, major ions, trace elements, nutrients, pesticides (reported but not used in the assessment), and environmental tracers. The data obtained from these samples (with the exception of the pesticide data) were used to gain insights into processes controlling the groundwater movement through the groundwater system in the study area. Results from the geophysical and geochemical assessments facilitated the interpretation of the geochemical characteristics of the groundwater sources and geochemical groups within the groundwater system. The groundwater-flow system in the study area consists primarily of the Mesilla Basin aquifer system, which can be divided into four hydrogeologic units by using an informal classification scheme based on basin-fill stratigraphy and sedimentology with an emphasis on aquifer characteristics. The four hydrogeologic units are (1) the Rio Grande alluvium, which is the shallow aquifer of the Mesilla Basin within the confines of the Mesilla Valley, and the three hydrogeologic units that compose the Santa Fe Group: (2) the lower part of the Santa Fe Group, which is the least productive zone, (3) the middle part of the Santa Fe Group, which is the primary water-bearing hydrogeologic unit in the basin and is generally saturated, and (4) the upper part of the Santa Fe Group, which is the most productive water-bearing unit within the Santa Fe Group but is only partially saturated in the north and largely unsaturated in the south and western parts of the Mesilla Basin. The helicopter frequency domain electromagnetic survey results indicated that approximately half of the resistivity values were less than 10 ohm-meters at depths of 50 and 100 feet with a transition where the resistivity values changed from relatively high values (greater than 20 ohm-meters) to relatively low resistivity values (less than 10 ohm-meters) near Vado, New Mexico. Slightly more than 25 percent of the gridded resistivity values from the three-dimensional grid of the combined inverse modeling results of the direct-current resistivity and time-domain electromagnetic soundings were equal to or less than 10 ohm-meters with large regions of low resistivity becoming apparent in the southernmost part of the study area near the Paso Del Norte where these low resistivity features are spatially the widest at or below the top of the bedrock. These low resistivity values might represent clayey deposits, sediments composed largely of sand and gravel saturated with saline water, or both. Historical dissolved-solids-concentration data within the surface geophysical subset area of the study area were compiled and compared to the inverse modeling results of the combined direct-current resistivity and time-domain soundings; this comparison was done to strengthen the interpretation made from the combined inverse modeling results that the low resistivity features were representative of sand and gravel deposits saturated with saline water and not clayey deposits. Water-level altitudes within the Rio Grande alluvium generally decreased from north to south, with a west to east decrease in water-level altitudes near Las Cruces, New Mexico, as a result of groundwater pumping. Groundwater flow within the Santa Fe Group is more complex than the groundwater flow within the Rio Grande alluvium because of the larger lateral and vertical extent of the Santa Fe Group compared to the Rio Grande alluvium. Groundwater from the Organ Mountains flows directly south towards the Paso del Norte. Groundwater from the Robledo Mountains, the Rough and Ready Hills, and the Sleeping Lady Hills generally flows to the southeast. Groundwater flowing near the north end of the midbasin uplift generally continues east towards the Rio Grande and then flows south on the east side of the midbasin uplift. Groundwater flowing near the west side of the midbasin uplift generally continues south parallel to the faults that make up the midbasin uplift and then flows east towards the Paso del Norte when it reaches the south end of the midbasin uplift. Groundwater from the Aden Hills and the East and West Potrillo Mountains flows to the south end of the midbasin uplift and then continues east towards the Paso del Norte. Throughout most of the Mesilla Valley, the vertical hydraulic gradient was downward because the water-level altitude in the Rio Grande alluvium was higher than it was in the Santa Fe Group, but in some areas (typically in the middle and southern parts of the Mesilla Valley), the vertical hydraulic gradient was substantially reduced or even reversed to an upward hydraulic gradient. The geochemistry data indicate that there was a complex system of multiple geochemical endmembers and mixing between these endmembers with recharge to the Rio Grande alluvium and Santa Fe Group composed mostly of seepage from the Rio Grande, inflows from deeper or neighboring water systems, and mountain-front recharge. Five distinct geochemical groups were identified in the Mesilla Basin study area: (1) ancestral Rio Grande (pre-Pleistocene) geochemical group, (2) modern Rio Grande (Pleistocene to present) geochemical group, (3) mountain-front geochemical group, (4) deep groundwater upwelling geochemical group, and (5) unknown freshwater geochemical group. The ancestral Rio Grande groundwater was water that recharged into the system as seepage losses from the ancestral Rio Grande; this groundwater generally flows from north to south-southeast towards the Paso del Norte. Groundwater on the west side of the midbasin uplift generally flows south until it reaches the southern part of the study area; from the southern part of the study area, the groundwater flows east towards the Paso del Norte. Groundwater on the east side of the midbasin uplift flows south-southeast towards the Paso del Norte where it mixes with groundwater from the modern Rio Grande, uplifted areas in the west, and the deep saline source. The water type of the modern Rio Grande geochemical group ranged from calcium-sulfate water type in the northern part of the study area to sodium-chloride-sulfate water type in the southern part of the study area; from north to south there was a substantial increase in specific conductance, strontium-87/strontium-86 ratio, potassium, and the trace metals of iron and lithium, changing the water chemistry such that it became similar to the water chemistry of the deep groundwater upwelling geochemical group. From age-dating results, water in the modern Rio Grande geochemical group was recharged to the Rio Grande alluvium within the past 10 years. The mountain-front geochemical group was generally old water (apparent age was greater than 10,000 carbon-14 years before present) that was somewhat mineralized and has relatively high concentrations of fluoride and silica, which might indicate longer exposure to volcanic and siliciclastic rocks or aluminosilicate minerals. There were five different locations of recharge determined from the groundwater geochemistry within the mountain-front geochemical group, all having a slightly different geochemical signature: (1) the Rough and Ready Hills, Robledo Mountains, and the Sleeping Lady Hills, (2) the Doña Ana Mountains, (3) the Aden Hills and West Potrillo Mountains, (4) the East Potrillo Mountains, and (5) the Sierra Juárez in Mexico. The groundwater from the Rough and Ready Hills, Robledo Mountains, the Sleeping Lady Hills, and the Doña Ana Mountains generally flows toward the Rio Grande and eventually mixes together and with the modern Rio Grande groundwater. The groundwater originating from the Aden Hills and East and West Potrillo Mountains generally flows east to southeast at a slow rate and eventually mixes and continues east, where it mixes with groundwater from the ancestral Rio Grande geochemical group and with the groundwater from the Sierra Juárez. The groundwater from the Sierra Juárez flows north and then east towards the Paso del Norte where it mixes with groundwater from the uplifted areas in the west, ancestral and modern Rio Grande groundwater, and the upwelling groundwater from a deep saline source. The deep groundwater upwelling geochemical group had the highest concentrations of bicarbonate, potassium, silica, aluminum, iron, and lithium within the study area, indicating that it had been in contact with carbonate and siliciclastic rocks for a much longer period of time and at higher temperatures compared to the other geochemical groups, and was most likely ancient marine groundwater originating from the Paleozoic and Cretaceous carbonate rocks which was upwelling into the Mesilla Basin aquifer system in the southeastern part of the study area through the extensive fault systems. Direct-current resistivity and time-domain electromagnetic soundings support the interpretation of ancient marine groundwater upwelling into the Mesilla Basin aquifer system, as do the analytical results from wells, and the helicopter frequency domain electromagnetic data collected along the Rio Grande. The hydrogen-2/hydrogen-1 ratio and oxygen-18/oxygen-16 ratio isotopic results for samples in the unknown freshwater geochemical group did not plot on the Rio Grande evaporation line, indicating this group did not have a Rio Grande signature (that is, there was no isotopic evidence of a component of Rio Grande water) and it also had the lowest mineralized content of any geochemical group in the study area.

New Mexico, Texas↗