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At least 289 records · Page 16Linked to original sources

Daily fluctuating flows affect riparian plant species distributions from local to regional scales

Aims The number of hydropower dams has grown globally over recent decades, with significant impacts on downstream riparian plant communities. Many of these dams generate daily fluctuating flows known as hydropeaking to meet sub-daily variation in energy demands. Hydropeaking can significantly impact riparian plant communities, with obligate riparian species tending to experience the greatest negative effects on habitat suitability. Whether this pattern holds in arid biomes where daily soil moisture enhancements could benefit some plants is an open question. Location Colorado River, Grand Canyon, Western USA. Methods We used occurrence records to model species responses to variation in daily flow fluctuations across 32 689 river segments in the Western United States. We then applied estimates of hydropeaking responses derived from those models to understanding the abundance and fine scale hydrologic niches of riparian plant species in the Colorado River ecosystem downstream of Glen Canyon Dam, which has experienced vegetation expansion attributed to river regulation, including hydropeaking that began in 1964. Results At the regional scale, species with greater wetland dependence exhibited increasingly negative responses to hydropeaking across 1 496 species, consistent with previous studies at smaller scales. At the local scale of the Colorado River, we found that species inhabiting near-channel habitat characterized by daily inundation and exposure had positive modeled responses to hydropeaking, consistent with a long history of selection for species tolerant of hydropeaking. In contrast, species inhabiting the zone immediately above peak daily river stage had negative modeled responses to hydropeaking, suggesting that they are being excluded from otherwise suitable habitat nearer the channel. Conclusions These results demonstrate that hydropeaking can impact species distributions from local to regional scales by excluding obligate wetland species and reducing habitat suitability for some facultative wetland species. These results from an arid river system are consistent with those reported from other biomes.

Arizona

Earthquake mechanism and predictability shown by a laboratory fault

Slip events generated in a laboratory fault model consisting of a circulinear chain of eight spring-connected blocks of approximately equal weight elastically driven to slide on a frictional surface are studied. It is found that most of the input strain energy is released by a relatively few large events, which are approximately time predictable. A large event tends to roughen stress distribution along the fault, whereas the subsequent smaller events tend to smooth the stress distribution and prepare a condition of simultaneous criticality for the occurrence of the next large event. The frequency-size distribution resembles the Gutenberg-Richter relation for earthquakes, except for a falloff for the largest events due to the finite energy-storage capacity of the fault system. Slip distributions, in different events are commonly dissimilar. Stress drop, slip velocity, and rupture velocity all tend to increase with event size. Rupture-initiation locations are usually not close to the maximum-slip locations. ?? 1994 Birkha??user Verlag.

Pure and Applied Geophysics PAGEOPH

Quality assurance and quality control in light stable isotope laboratories: A case study of Rio Grande, Texas, water samples

New isotope laboratories can achieve the goal of reporting the same isotopic composition within analytical uncertainty for the same material analysed decades apart by (1) writing their own acceptance testing procedures and putting them into their mass spectrometric or laser-based isotope-ratio equipment procurement contract, (2) requiring a manufacturer to demonstrate acceptable performance using all sample ports provided with the instrumentation, (3) for each medium to be analysed, prepare two local reference materials substantially different in isotopic composition to encompass the range in isotopic composition expected in the laboratory and calibrated them with isotopic reference materials available from the International Atomic Energy Agency (IAEA) or the US National Institute of Standards and Technology (NIST), (4) using the optimum storage containers (for water samples, sealing in glass ampoules that are sterilised after sealing is satisfactory), (5) interspersing among sample unknowns local laboratory isotopic reference materials daily (internationally distributed isotopic reference materials can be ordered at three-year intervals, and can be used for elemental analyser analyses and other analyses that consume less than 1 mg of material) – this process applies to H, C, N, O, and S isotope ratios, (6) calculating isotopic compositions of unknowns by normalising isotopic data to that of local reference materials, which have been calibrated to internationally distributed isotopic reference materials, (7) reporting results on scales normalised to internationally distributed isotopic reference materials (where they are available) and providing to sample submitters the isotopic compositions of internationally distributed isotopic reference materials of the same substance had they been analysed with unknowns, (8) providing an audit trail in the laboratory for analytical results – this trail commonly will be in electronic format and might include a laboratory information management system, (9) making at regular intervals a complete backup of laboratory analytical data (both of samples logged into the laboratory and of mass spectrometric analyses), being sure to store one copy of this backup offsite, and (10) participating in interlaboratory comparison exercises sponsored by the IAEA and other agencies at regular intervals.

Isotopes in Environmental and Health Studies

Climate change implications for tropical islands: Interpolating and interpreting statistically downscaled GCM projections for management and planning

The potential ecological and economic effects of climate change for tropical islands were studied using output from 12 statistically downscaled general circulation models (GCMs) taking Puerto Rico as a test case. Two model selection/model averaging strategies were used: the average of all available GCMs and the average of the models that are able to reproduce the observed large-scale dynamics that control precipitation over the Caribbean. Five island-wide and multidecadal averages of daily precipitation and temperature were estimated by way of a climatology-informed interpolation of the site-specific downscaled climate model output. Annual cooling degree-days (CDD) were calculated as a proxy index for air-conditioning energy demand, and two measures of annual no-rainfall days were used as drought indices. Holdridge life zone classification was used to map the possible ecological effects of climate change. Precipitation is predicted to decline in both model ensembles, but the decrease was more severe in the “regionally consistent” models. The precipitation declines cause gradual and linear increases in drought intensity and extremes. The warming from the 1960–90 period to the 2071–99 period was 4.6°–9°C depending on the global emission scenarios and location. This warming may cause increases in CDD, and consequently increasing energy demands. Life zones may shift from wetter to drier zones with the possibility of losing most, if not all, of the subtropical rain forests and extinction risks to rain forest specialists or obligates.

Puerto Rico

Multivariate analysis relating oil shale geochemical properties to NMR relaxometry

Low-field nuclear magnetic resonance (NMR) relaxometry has been used to provide insight into shale composition by separating relaxation responses from the various hydrogen-bearing phases present in shales in a noninvasive way. Previous low-field NMR work using solid-echo methods provided qualitative information on organic constituents associated with raw and pyrolyzed oil shale samples, but uncertainty in the interpretation of longitudinal-transverse ( T 1 – T 2 ) relaxometry correlation results indicated further study was required. Qualitative confirmation of peaks attributed to kerogen in oil shale was achieved by comparing T 1 – T 2 correlation measurements made on oil shale samples to measurements made on kerogen isolated from those shales. Quantitative relationships between T 1 – T 2 correlation data and organic geochemical properties of raw and pyrolyzed oil shales were determined using partial least-squares regression (PLSR). Relaxometry results were also compared to infrared spectra, and the results not only provided further confidence in the organic matter peak interpretations but also confirmed attribution of T 1 – T 2 peaks to clay hydroxyls. In addition, PLSR analysis was applied to correlate relaxometry data to trace element concentrations with good success. The results of this work show that NMR relaxometry measurements using the solid-echo approach produce T 1 – T 2 peak distributions that correlate well with geochemical properties of raw and pyrolyzed oil shales.

Energy & Fuels

Simulation of the effects of proposed tide gates on circulation, flushing, and water quality in residential canals, Cape Coral, Florida

Decades of dredging and filling of Florida's low-lying coastal wetlands have produced thousands of miles of residential tidal canals and adjacent waterfront property. Typically, these canals are poorly flushed, and over time, accumulated organic-rich bottom materials, contribute to an increasingly severe degraded water quality. One-dimensional hydrodynamic and constituent-transport models were applied to two dead-end canal systems to determine the effects of canal system interconnection using tide gates on water circulation and constituent flushing. The model simulates existing and possible future circulation and flushing conditions in about 29 miles of the approximately 130 miles of tidally influenced canals in Cape Coral, located on the central west coast of peninsular Florida. Model results indicate that tidal water-level differences between the two canal systems can be converted to kinetic energy, in the form of increased water circulation, but the use of one-way tide gate interconnections. Computations show that construction of from one to four tide gates will cause replacement of a volume of water equivalent to the total volume of canals in both systems in 15 to 9 days, respectively. Because some canals flush faster than others, 47 and 21 percent of the original canal water will remain in both systems 50 days after start of operation of one and four tide gates, respectively. Some of the effects that such increased flushing are expected to have include reduced density stratification and associated dissolved-oxygen depletion in canal bottom waters, increased localized reaeration, and more efficient discharge of stormwater runoff entering the canals.

Florida

Rotenone persistence model for montane streams

The efficient and effective use of rotenone is hindered by its unknown persistence in streams. Environmental conditions degrade rotenone, but current label instructions suggest fortifying the chemical along a stream based on linear distance or travel time rather than environmental conditions. Our objective was to develop models that use measurements of environmental conditions to predict rotenone persistence in streams. Detailed measurements of ultraviolet radiation, water temperature, dissolved oxygen, total dissolved solids (TDS), conductivity, pH, oxidation–reduction potential (ORP), substrate composition, amount of organic matter, channel slope, and travel time were made along stream segments located between rotenone treatment stations and cages containing bioassay fish in six streams. The amount of fine organic matter, biofilm, sand, gravel, cobble, rubble, small boulders, slope, pH, TDS, ORP, light reaching the stream, energy dissipated, discharge, and cumulative travel time were each significantly correlated with fish death. By using logistic regression, measurements of environmental conditions were paired with the responses of bioassay fish to develop a model that predicted the persistence of rotenone toxicity in streams. This model was validated with data from two additional stream treatment reaches. Rotenone persistence was predicted by a model that used travel time, rubble, and ORP. When this model predicts a probability of less than 0.95, those who apply rotenone can expect incomplete eradication and should plan on fortifying rotenone concentrations. The significance of travel time has been previously identified and is currently used to predict rotenone persistence. However, rubble substrate, which may be associated with the degradation of rotenone by adsorption and volatilization in turbulent environments, was not previously considered.

Transactions of the American Fisheries Society

Modeling of high‐frequency seismic‐wave scattering and propagation using radiative transfer theory

This is a study of the nonisotropic scattering process based on radiative transfer theory and its application to the observation of the M 4.3 aftershock recording of the 2008 Wells earthquake sequence in Nevada. Given a wide range of recording distances from 29 to 320 km, the data provide a unique opportunity to discriminate scattering models based on their distance‐dependent behaviors. First, we develop a stable numerical procedure to simulate nonisotropic scattering waves based on the 3D nonisotropic scattering theory proposed by Sato (1995). By applying the simulation method to the inversion of M 4.3 Wells aftershock recordings, we find that a nonisotropic scattering model, dominated by forward scattering, provides the best fit to the observed high‐frequency direct S waves and S ‐wave coda velocity envelopes. The scattering process is governed by a Gaussian autocorrelation function, suggesting a Gaussian random heterogeneous structure for the Nevada crust. The model successfully explains the common decay of seismic coda independent of source–station locations as a result of energy leaking from multiple strong forward scattering, instead of backscattering governed by the diffusion solution at large lapse times. The model also explains the pulse‐broadening effect in the high‐frequency direct and early arriving S waves, as other studies have found, and could be very important to applications of high‐frequency wave simulation in which scattering has a strong effect. We also find that regardless of its physical implications, the isotropic scattering model provides the same effective scattering coefficient and intrinsic attenuation estimates as the forward scattering model, suggesting that the isotropic scattering model is still a viable tool for the study of seismic scattering and intrinsic attenuation coefficients in the Earth.

Bulletin of the Seismological Society of America

Insecticide contaminations in wetland habitats and their effects on fish- eating birds

An unusual mortality of fish-eating birds occurred at the Tule Lake National Wildlife Refuge in California between 1960 and 1962. Over 1100 dead birds of ten species were found during that period. Investigations of the mortality indicated that birds died as a result of their exposure to toxaphene, which was applied to adjoining agricultural areas, transported to the refuge in waste irrigation water, and accumulated in fish eaten by the birds. Toxaphene was used in agriculture for only 3 years, 1958-60, and by 1962 residues were no longer found in the marsh habitat. However, results also showed that a potentially hazardous contamination of DDT and its metabolites was present in the birds and the environment. Studies were, therefore, continued to determine the food-chain relationships of DDT in marsh ecosystems, and the effects of the insecticide on birds. Sampling for insecticide residues was undertaken at four waterfowl refuges, each representing a somewhat different set of environmental conditions. DDT residues in water at each refuge were found to be relatively low, but filtered samples showed that residues in suspended material were 10 000 to 20 000 times as great as those in the filtrate. Much of the suspended material was organic matter, which is an important source of energy for the ecosystems. In environments with invertebrates, DDT residues were relatively low in sediments and high in fish, while residues in vegetation were highest where invertebrates were absent. Results suggest that organic materials and invertebrates can be important factors in determining the fate and involvement of insecticides in aquatic environments. Studies of the movements, exposure to pesticides, productivity, and longevity of individuals in three nesting colonies of White Pelicans were begun in 1962 to depict the relationships of pesticides to a migratory population of birds dependent upon wetland habitats. To date there is no evidence that the exposure of pelicans to DDT is influencing the population dynamics of the birds.

California, Oregon

Stress resistance strategy in an arid land shrub: interactions between developmental instability and fractal dimention

This paper investigates allocation of energy to mechanisms that generate and preserve architectural forms (i.e. developmental stability, complexity of branching patterns) and productivity (growth and reproduction) in response to environmental disturbances (i.e. grazing and resource availability). The statistical error in translational symmetry was used to detect random intra-individual variability during development. This can be thought of as a measure of developmental instability caused by stress. Additionally, we use changes in fractal complexity and shoot distribution of branch structures as an alternate indicator of stress. These methods were applied to Anthyllis cytisoides L., a semi-arid environment shrub, to ascertain the effect of grazing and slope exposure on developmental traits in a 2×2 factorial design. The results show that A. cytisoides maintains developmental stability at the expense of productivity. Anthyllis cytisoides was developmentally more stable when grazed and when on south-facing, as opposed to north-facing slopes. On the contrary, shoot length, leaf area, fractal dimension and reproductive-to-vegetative allocation ratio were larger in north- than in south-facing slopes. As a consequence, under extreme xeric conditions, shrub mortality increased in north-facing slopes, especially when not grazed. The removal of transpiring area and the reduction of plant competition favoured developmental stability and survival in grazed plants. Differences between grazed and ungrazed plants were most evident in more mesic (north-facing) areas.

Journal of Fish Diseases

Electron transport in the dissimilatory iron reducer, GS-15

Mechanisms for electron transport to Fe(III) were investigated in GS-15, a novel anaerobic microorganism which can obtain energy for growth hy coupling the complete oxidation of organic acids or aromatic compounds to the reduction of Fe(III) to Fe(II). The results indicate that Fe(III) reduction proceeds through a type b cytochrome and a membrane-bound Fe(III) reductase which is distinct from the nitrate reductase.

Applied and Environmental Microbiology

U.S. Geological Survey ecosystems science strategy—Advancing discovery and application through collaboration

Executive Summary Ecosystem science is critical to making informed decisions about natural resources that can sustain our Nation’s economic and environmental well-being. Resource managers and policymakers are faced with countless decisions each year at local, regional, and national levels on issues as diverse as renewable and nonrenewable energy development, agriculture, forestry, water supply, and resource allocations at the urban-rural interface. The urgency for sound decisionmaking is increasing dramatically as the world is being transformed at an unprecedented pace and in uncertain directions. Environmental changes are associated with natural hazards, greenhouse gas emissions, and increasing demands for water, land, food, energy, mineral, and living resources. At risk is the Nation’s environmental capital, the goods and services provided by resilient ecosystems that are vital to the health and wellbeing of human societies. Ecosystem science—the study of systems of organisms interacting with their environment and the consequences of natural and human-induced change on these systems—is necessary to inform decisionmakers as they develop policies to adapt to these changes. This Ecosystems Science Strategy is built on a framework that includes basic and applied science. It highlights the critical roles that U.S. Geological Survey (USGS) scientists and partners can play in building scientific understanding and providing timely information to decisionmakers. The strategy underscores the connection between scientific discoveries and the application of new knowledge, and it integrates ecosystem science and decisionmaking, producing new scientific outcomes to assist resource managers and providing public benefits. We envision the USGS as a leader in integrating scientific information into decisionmaking processes that affect the Nation’s natural resources and human well-being. The USGS is uniquely positioned to play a pivotal role in ecosystem science. With its wide range of expertise, the Bureau can bring holistic, cross-scale, interdisciplinary capabilities to the design and conduct of monitoring, research, and modeling and to new technologies for data collection, management, and visualization. Collectively, these capabilities can be used to reveal ecological patterns and processes, explain how and why ecosystems change, and forecast change over different spatial and temporal scales. USGS science can provide managers with options and decision-support tools to use resources sustainably. The USGS has long-standing, collaborative relationships with the Department of the Interior (DOI) and other partners in the natural sciences, in both conducting science and applying the results. The USGS engages these partners in cooperative investigations that otherwise would lack the necessary support or be too expensive for a single bureau to conduct. The heart of this strategy is a framework for USGS ecosystems science that focuses on five long-term goals, which are seen as interconnected components that reinforce our vision of the USGS providing science that is at the forefront of decisionmaking: Improve understanding of ecosystem structure, function, and processes. The focus for this goal is an understanding of how ecosystems work, including the dynamics of species, their populations, interactions, and genetics, and how they change across spatial and temporal scales. Advance understanding of how drivers influence ecosystem change. The challenges here are explaining the drivers of ecosystem change, their spatio-temporal patterns, their uncertainties and interactions, and their influence on ecosystem processes and dynamics. Improve understanding of the services that ecosystems provide to society. Here the emphasis is on the measurement of environmental capital and ecosystem services, and the identification of sources and patterns of change in space and time. Develop tools, technologies, and capacities to inform decisionmaking about ecosystems. This includes developing new technologies and approaches for conducting applications-oriented ecosystem science. A principal challenge will be how to quantify uncertainty and incorporate it in decision analysis. Apply science to enhance strategies for management, conservation, and restoration of ecosystems. These challenges include development of novel approaches to monitoring, assessment, and restoration of ecosystems; new methods to address species of concern and communities at risk; and innovations in decision analysis and support to address imminent ecosystem changes or those that are underway. Closely integrated with the five goals are four strategic approaches that provide the path forward for the USGS Ecosystems Mission Area. These approaches cross-cut all of the goals and are seen as essential to the implementation of this strategy: Assess information needs for ecosystem science through enhanced partnerships. Work with the DOI and other agencies and institutions to identify, design, and implement priority decision-driven ecological research. Promote the use of interdisciplinary ecosystem science. Design and conduct interdisciplinary process-oriented research in ecosystem science. Enhance modeling and forecasting. Build models to forecast ecosystem change, assess future management scenarios, and reduce uncertainties through an adaptive learning process. Support decisionmaking. Use quantitative approaches to assess the vulnerabilities of ecosystems, habitats, and species, and evaluate strategies for adaptation, restoration, and sustainable management. Following the four strategic approaches are a set of proposed actions that represent a sampling of specific USGS activities that align with this strategy and that address the Nation’s most pressing environmental needs. The strategy emphasizes coordination of activities across the USGS mission areas pursuant to these goals. Ecosystem science is inherently interdisciplinary and requires a broad perspective that incorporates the biological and physical sciences, climate science, information technology, and scientific capacity in mission areas across the Bureau. With its emphasis on coordination, this strategy can provide a critical underpinning for integrated science efforts with scientists from multiple mission areas of the USGS working together. Of course, the USGS will continue to conduct discipline-specific and interdisciplinary investigations, and both will continue to be vital parts of the ecosystem science portfolio. Finally, the strategy stresses the importance of coordination with other Federal agencies and organizations in the natural resources community. The USGS collaborates with resource agencies in the DOI and other organizations throughout the world to meet societal needs for species and ecosystem management. Working with these agencies and organizations, the USGS will play a key role in guiding sound decisionmaking during the next decade by advancing the scientific foundation for sustaining the natural resources that diverse, productive, resilient ecosystems provide.

Circular

Lithosphere stress and deformation

After several decades of investigation, a surprisingly simple view of the lithospheric state of stress has emerged. Broad regions of the lithosphere (scales up to thousands of kilometers) are characterized by remarkably uniform stress fields, both in terms of orientations and relative magnitudes. There is a strong correlation between observed intraplate stress orientations and orientations predicted by models of the plate-driving forces acting on the plate geometry, suggesting that the same forces that drive the plates also stress their interiors. Lateral variations in density and thickness of the crust and lithosphere give rise to gravitational potential energy differences that locally induce forces comparable in magnitude to plate-driving forces. In addition, mantle density inhomogeneities may also influence lithospheric stresses through the linkage of mantle flow. Direct measurements of stress magnitudes at depth indicate that the brittle crust is in a state of ‘frictional faulting equilibrium’, that is, the stress differences are close to, and limited by, the stress levels required to induce slip on the most well-oriented pre-exising planes. This characteristic of ‘critically stressed crust’ stress applies equally well to active plate boundary regions as well as ‘stable’ intraplate regions, indicating that stress differences at depth are comparable in these very distinct tectonic provinces. The difference in deformation between the two provinces is simply the rate of deformation, primarily controlled by the integrated strength of the lithosphere. Warmer, weaker lithosphere (such as along plate boundaries) will deform about eight orders of magnitude more rapidly than old, cold lithosphere in the interior of plates.

Book chapter

A review of spatially resolved techniques and applications of organic petrography in shale petroleum systems

This review examines new techniques and applications of organic petrography in source-rock reservoir petroleum systems that have occurred along with development of the global ‘shale revolution’ in energy resources. The review is limited to techniques and instrumentation that provide spatially resolved information, typically at or below microscales, for dispersed organic matter occurring in situ in samples of shale and mudrock. A brief summary of ion beam sample preparation is followed by discussion of the most common analytical techniques and applications. Advantages and limitations of each technique, including requisite sample preparation, types of information generated [e.g., molecular or elemental (isotopic) abundance], sensitivity, and resolution are discussed. In a few cases, techniques not yet applied to organic petrology of shale or mudrock are described (e.g., X-ray photoelectron spectroscopy imaging), in anticipation of near-term future application. The most common in situ techniques applied for characterization of organic matter in shale and mudrock include optical (including fluorescence) and electron microscopies, Raman, fluorescence, and infrared spectroscopies, and surficial measurements via force microscopy. Techniques that show growing application to organic petrography of shale include tip-enhanced photothermal infrared spectroscopy, mass spectrometry imaging, and synchrotron-based spectroscopies, among others. It is anticipated that the future of dispersed organic matter petrography will hold continued development of integrated instrument techniques (e.g., simultaneous or sequential correlative microscopies and/or spectroscopies of the same location), increased instrumental resolution, increased use of multiscale and multimodal organic petrography investigations, and three-dimensional imaging and chemical speciation mapping applications via multiple analytical approaches.

International Journal of Coal Geology

Eagle fatalities are reduced by automated curtailment of wind turbines

Collision‐caused fatalities of animals at wind power facilities create a ‘green versus green’ conflict between wildlife conservation and renewable energy. These fatalities can be mitigated via informed curtailment whereby turbines are slowed or stopped when wildlife are considered at increased risk of collision. Automated monitoring systems could improve efficacy of informed curtailment, yet such technology is undertested. We test the efficacy of an automated curtailment system—a camera system that detects flying objects, classifies them and decides whether to curtail individual turbines to avoid potential collision—in reducing counts of fatalities of eagles, at Top of the World Windpower Facility (hereafter, the treatment site) in Wyoming, USA. We perform a before–after–control–impact study, comparing the number of eagle fatalities observed at the treatment site with those at a nearby (15 km) control site without automated curtailment, both before and after the implementation of automated curtailment at the treatment site. After correcting for carcass detection probability and scaling fatality estimates to turbine‐years, we estimate that the number of fatalities at the treatment site declined by 63% (95% CI = 59%–66%) between before and after periods while increasing at the control site by 113% (51%–218%). In total, there was an 82% (75%–89%) reduction in the fatality rate at the treatment site relative to the control site. Synthesis and applications . Automated curtailment of wind turbine operation substantially reduced eagle fatalities. This technology therefore has the potential to lessen the conflict between wind energy and raptor conservation. Although automated curtailment reduced fatalities, they were not fully eliminated. Therefore, automated curtailment, as implemented here, is not a panacea and its efficacy could be improved if considered in conjunction with other mitigation actions.

Wyoming

Energy-related rare earth element sources

Energy-related materials such as coal, coal-bearing wastes, and coal combustion products are traditionally thought of as sources or by-products of electric power generation. Increasingly, these materials are considered resources for their content of rare earth elements (REEs) and other useful constituents. In this chapter, we examine the distribution, modes of occurrence, and relative extractability of REEs from coal-derived materials. We also consider economic factors associated with recovery of REEs from these sources. While several coal-derived sources show promise for REE recovery at the pilot scale, in all cases, REE contents are much below those of primary ores, such that extraction and concentrating the REEs require new and innovative approaches that are largely developmental. Among coal-related sources, fly ash is the most REE-enriched, as REEs from coal are strongly retained in these refractory solids remaining after coal combustion. Partitioning of coal-derived elements into fly ash has been known for decades but this has yet to be commercially exploited. A key drawback shown in this chapter is that a significant fraction of REEs in fly ash is contained in highly insoluble aluminosilicate glasses that make up the largest portion of this material. In addition to testing chemical or physical pretreatment approaches to help improve the extractability of REEs from fly ash, current research is applying modern analytical approaches to better understand the distribution of REEs on increasingly smaller scales, in the interest of targeting their recovery. Next-most REE-enriched among coal-related materials are solid waste products of coal mining and wastes from coal preparation, both of which are REE-enriched relative to coal itself. These waste coals concentrate mineralogical constituents that are excluded during mining or removed during coal preparation because they do not contribute to the heating value of coal for power generation. Recovery of REEs from coal waste has shown promise at the pilot scale and has the added benefit of converting a waste into useful constituents. Total REE contents of commercial coals are, on average, much below the 300 parts per million interest level for REE recovery set by the U.S. Department of Energy (DOE). However, as reviewed in this chapter, certain horizons within coal beds show preferential REE enrichment and could be targeted by selective mining. Beyond this, certain coals are REE-enriched overall due to their unique geologic histories involving derivation from REE-enriched sediment sources, deposition of volcanic ash during coal formation, or interaction of coal with REE-bearing fluids. Acidic drainage from abandoned coal mines is produced by the breakdown of pyrite (FeS 2 ), which is unstable in oxygenated conditions. While these acidic fluids have lower REE contents than any of the coal-based solids described above, they are proportionally enriched in certain heavy rare earths, especially yttrium (Y). Precipitates from coal-based acid-mine drainage concentrate REEs to levels that are of interest for recovery, and these are also promising sources for extraction at the pilot scale.

Book chapter

Hierarchical mixture models and high-resolution monitoring data can inform siting and operational strategies to mitigate bat fatalities at wind turbines

Bats provide critical ecosystem services, but bat fatalities due to wind energy development may imperil some bat populations. Statistical models are used to estimate the total fatalities that occur based on carcasses observed during monitoring surveys. Current models often estimate fatalities aggregated across species, time, and/or turbines, but fall short of reliably informing siting and operational collision mitigation strategies that account for species-specific fatality patterns on a fine spatiotemporal scale. We developed a hierarchical mixture model for estimating species-specific covariate effects and total fatalities per species at each turbine on weekly intervals. We applied the model to a high-resolution dataset of bat carcasses found during turbine searches across nineteen wind facilities in Iowa over two years. Our model explains species-specific variation in bat fatalities at individual wind turbines according to turbine proximity to bat habitat, turbine design specifications, seasonal trends, and weather conditions such as nightly air temperature, air pressure, and wind speed. Turbines located on the edge of wind facilities had higher fatalities, and proximity to roosting and foraging habitat accounted for variation in species-specific fatality estimates. These insights into turbine placement effects can inform siting strategies. We also discovered species-specific relationships with average nightly wind speed and air temperature, among other weather conditions, that could inform operational mitigation strategies such as smart curtailment. Our model can transform observations of carcasses found during turbine searches across multiple facilities, years, and variable search efforts into estimates of total fatalities per species associated with species-specific spatial, temporal, and environmental covariate effects.

Ecological Informatics

Applying linear programming to estimate fluxes in ecosystems or food webs: An example from the herpetological assemblage of the freshwater Everglades

We present the application of Linear Programming for estimating biomass fluxes in ecosystem and food web models. We use the herpetological assemblage of the Everglades as an example. We developed food web structures for three common Everglades freshwater habitat types: marsh, prairie, and upland. We obtained a first estimate of the fluxes using field data, literature estimates, and professional judgment. Linear programming was used to obtain a consistent and better estimate of the set of fluxes, while maintaining mass balance and minimizing deviations from point estimates. The results support the view that the Everglades is a spatially heterogeneous system, with changing patterns of energy flux, species composition, and biomasses across the habitat types. We show that a food web/ecosystem perspective, combined with Linear Programming, is a robust method for describing food webs and ecosystems that requires minimal data, produces useful post-solution analyses, and generates hypotheses regarding the structure of energy flow in the system.

Ecological Modelling