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Structural geology of the proposed site area for a high-level radioactive waste repository, Yucca Mountain, Nevada

Geologic mapping and fracture studies have documented the fundamental patterns of joints and faults in the thick sequence of rhyolite tuffs at Yucca Mountain, Nevada, the proposed site of an underground repository for high-level radioactive waste. The largest structures are north-striking, block-bounding normal faults (with a subordinate left-lateral component) that divide the mountain into numerous 1-4-km-wide panels of gently east-dipping strata. Block-bounding faults, which underwent Quaternary movement as well as earlier Neogene movement, are linked by dominantly northwest-striking relay faults, especially in the more extended southern part of Yucca Mountain. Intrablock faults are commonly short and discontinuous, except those on the more intensely deformed margins of the blocks. Lithologic properties of the local tuff stratigraphy strongly control the mesoscale fracture network, and locally the fracture network has a strong influence on the nature of intrablock faulting. The least faulted part of Yucca Mountain is the north-central part, the site of the proposed repository. Although bounded by complex normal-fault systems, the 4-km-wide central block contains only sparse intrablock faults. Locally intense jointing appears to be strata-bound. The complexity of deformation and the magnitude of extension increase in all directions away from the proposed repository volume, especially in the southern part of the mountain where the intensity of deformation and the amount of vertical-axis rotation increase markedly. Block-bounding faults were active at Yucca Mountain during and after eruption of the 12.8-12.7 Ma Paintbrush Group, and significant motion on these faults postdated the 11.6 Ma Rainier Mesa Tuff. Diminished fault activity continued into Quaternary time. Roughly half of the stratal tilting in the site area occurred after 11.6 Ma, probably synchronous with the main pulse of vertical-axis rotation, which occurred between 11.6 and 11.45 Ma. Studies of sequential formation of tectonic joints, in the context of regional paleostress studies, indicate that north- and northwest-striking joint sets formed coevally with the main faulting episode during regional east-northeast-west-southwest extension and that a prominent northeast-striking joint set formed later, probably after 9 Ma. These structural analyses contribute to the understanding of several important issues at Yucca Mountain, including potential hydrologic pathways, seismic hazards, and fault-displacement hazards. ?? 2004 Geological Society of America.

Geological Society of America Bulletin

Groundwater quality, age, and susceptibility and vulnerability to nitrate contamination with linkages to land use and groundwater flow, Upper Black Squirrel Creek Basin, Colorado, 2013

The Upper Black Squirrel Creek Basin is located about 25 kilometers east of Colorado Springs, Colorado. The primary aquifer is a productive section of unconsolidated deposits that overlies bedrock units of the Denver Basin and is a critical resource for local water needs, including irrigation, domestic, and commercial use. The primary aquifer also serves an important regional role by the export of water to nearby communities in the Colorado Springs area. Changes in land use and development over the last decade, which includes substantial growth of subdivisions in the Upper Black Squirrel Creek Basin, have led to uncertainty regarding the potential effects to water quality throughout the basin. In response, the U.S. Geological Survey, in cooperation with Cherokee Metropolitan District, El Paso County, Meridian Service Metropolitan District, Mountain View Electric Association, Upper Black Squirrel Creek Groundwater Management District, Woodmen Hills Metropolitan District, Colorado State Land Board, and Colorado Water Conservation Board, and the stakeholders represented in the Groundwater Quality Study Committee of El Paso County conducted an assessment of groundwater quality and groundwater age with an emphasis on characterizing nitrate in the groundwater. Groundwater-quality samples were collected from 50 randomly selected wells between May and June 2013. The samples were analyzed for major ions, nutrients, dissolved gases, tritium ( 3 H), chlorofluorocarbons (CFC-11, CFC-12, and CFC-113), and fuel products (such as benzene, toluene, ethylbenzene, and xylenes). None of the groundwater samples exceeded the U.S. Environmental Protection Agency (EPA) National Primary Drinking Water Regulations for primary maximum contaminant levels (MCL) for major ions. Secondary maximum contaminant levels, which are not health concerns and affect mainly taste, color, or odor of the water, were observed in rare instances for pH (2 samples), chloride (1 sample), iron (3 samples), and manganese (8 samples). The secondary maximum contaminant level for total dissolved solids was also exceeded for two samples. Nitrate (nitrite plus nitrate as nitrogen in groundwater) was elevated above the estimated background concentration of natural recharge waters of 1 milligram per liter (mg/L) in 44 of the 50 wells sampled and showed a median concentration of 5.4 mg/L. Nitrate concentrations were above the MCL of 10 mg/L in 5 of the 50 wells sampled and above half of the EPA MCL (5 mg/L) in 27 of the 50 wells sampled, which included samples above the MCL. Dissolved-oxygen concentrations exceeded 0.5 mg/L in 95 percent of reported values (40 of 42 samples) and exceeded 2.0 mg/L in 90 percent of reported values (38 of 42 samples). The oxidized conditions observed in most areas indicate that nitrate from fertilizers and animal or human waste was geochemically stable and could persist in the groundwater for decades or perhaps longer. A historical analysis of median nitrate concentrations over nearly three decades showed an increase in nitrate of approximately 1 mg/L from 4.3 to 5.4 mg/L, although the increase was not determined to be significantly different using nonparametric statistical methods. Major-ion data indicate that groundwater representative of the primary aquifer was classified as calcium-sodium bicarbonate type water. Other water samples from wells located mainly along the periphery of the primary aquifer had cation-anion compositions consistent with distinct water sources, including groundwater contributions from the underlying bedrock aquifers. The areas with differentiable water sources were located mainly where alluvial deposits were thin and geologic contacts to the underlying bedrock aquifers were relatively shallow. Nitrate concentrations in the groundwater were evaluated for relations to land use. An agricultural region was defined using a sequence of land satellite imagery. Groundwater flow directions interpreted from median water-table elevations measured from 2000 to 2013 were used in conjunction with cropland locations to define the agricultural region boundaries by encompassing potential pathways of nitrate transport in the groundwater from nitrogen-based fertilizers. A statistically significant higher median nitrate concentration was observed for areas inside the agricultural region (6.7 mg/L) compared to areas outside the agricultural region (2.3 mg/L), although median concentrations in both areas were below the MCL (10 mg/L). Median nitrate concentration was also significantly greater in land parcels with septic use (4.9 mg/L) compared to nonseptic parcels (1.7 mg/L). In general, agriculture or septic use was identified as the primary source of nitrate, depending on location, while commercial, county, grazing, and residential land uses were generally secondary sources of nitrate. Apparent groundwater ages were estimated from chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) and tritium ( 3 H) data using models that assumed piston flow and binary mixing (dilution of a young component with old, tracer-free water). The mean and median groundwater ages were about 30 years and the standard deviation was 6 years, indicating that most groundwater in the primary aquifer was “young” water that had recharged to the aquifer over the last few decades (post-1950s). The median fraction of young water was about 71 percent, and the standard deviation was 29 percent. The remaining water predated the 1950s, which may have originated from deeper geologic formations or may represent slow moving groundwater within the primary aquifer. Some of the oldest groundwater ages (older than 30 years) were observed in the upper reaches of the aquifer to the northwest where the primary aquifer is thin and intersects bedrock, supporting the hypothesis of geochemically distinct groundwater entering the primary aquifer from below. Groundwater that had reached the central part of the aquifer from upgradient areas of the basin was variable in age because of differences in flow paths and travel velocities. The groundwater age analysis showed that current (2013) land-use practices could affect water quality over decades to come, and that responses to remedial actions could be slow, especially for constituents, such as nitrate, that are stable under oxidized conditions. Fuel products (including acetone, benzene, diisopropyl ether, ethylbenzene, methyl acetate, methyl tertiary butyl ether (MTBE), methyl tert-pentyl ether, m- + p-xylene, o-xylene, tert-amyl alcohol, tert-butyl alcohol, tert-butyl ethyl ether, and toluene) were analyzed in groundwater from 49 of the 50 wells. Water from seven sites had detections for fuel compounds; all concentrations were below MCL. The results provided assurance of water quality and a valuable baseline to evaluate future trends of fuel constituents as the region is further developed. Probability maps were developed from logistic regression models to examine the likelihood that nitrate concentrations in groundwater exceeded specified levels. Susceptibility analysis examined relations between mid-level (5.0 mg/L) nitrate concentrations and climatic, hydrologic, and geologic variables; the significant variables were identified as depth to groundwater, soil organic matter, and soil water storage to 25-centimeter (cm) depth. The vulnerability assessments included natural factors driving susceptibility but also human factors related to land use and septic use. Vulnerability to low-level (2.5 mg/L) nitrate was related to depth to groundwater, septic zoning, and soil organic matter. The results highlighted that septic zoning affected low-level nitrate concentrations. Vulnerability to mid-level (5.0 mg/L) nitrate was examined using all 50 samples and also with two data outliers removed, which showed relatively high nitrate concentrations but also anomalous water chemistry or were located beyond the primary study area. Vulnerability to mid-level (5.0 mg/L) nitrate using all 50 samples was related to depth to groundwater, land use, septic use within a 500-meter (m) radius, soil water storage to a 25-cm depth, soil organic matter, and whether a location was within the agricultural region. The mid-level (5.0 mg/L) vulnerability model using 48 samples (two outliers removed) produced the best overall fit and was related to the same variables as when using all samples except septic use. The results for mid-level vulnerability provided additional support that septic use was associated with low levels of nitrate in the groundwater. Soil properties and land use were identified as the main drivers of moderate nitrate concentrations. Probabilities of exceeding low-level nitrate concentrations were high in most areas with the lowest probabilities usually to the northwest along thin geologic deposits in the upper part of the basin. The results of this investigation offer the foundational information needed for developing best management practices to mitigate nitrate contamination, basic concepts on water quality to aid public education, and information to guide regulatory measures if policy makers determine this is warranted. Science-based decision making will require continued monitoring and analysis of water quality in the future.

Colorado

Geologic framework and evidence for neotectonism in the epicentral area of the 2011 Mineral, Virginia, earthquake

The epicenters of the main shock and associated aftershocks of the 2011 moment magnitude, M w 5.8 Mineral, Virginia (USA), earthquake, and the updip projection of the possible fault plane that triggered the quakes, are contained in the areas of 2 adjoining 7.5′ quadrangles in the central Virginia Piedmont. These quadrangles have therefore been the focus of concentrated geologic study in the form of bedrock and surficial mapping and near-surface trenching in order to identify potential seismogenic structures. Bedrock mapping has outlined a series of northeast-southwest–trending lithologic belts that include the Ordovician Chopawamsic and Quantico Formations, the narrow neck of the Late Ordovician Ellisville pluton, and mélange zone III of the Mine Run Complex. The region was affected by at least two ductile deformational events, one in the early Paleozoic that was broadly synchronous with the intrusion of the pluton, and one later in the Paleozoic. The earlier deformation produced the Quantico synclinorium and other regional folds, and the later deformation produced faults with associated high-strain zones. Two of these faults have been trenched at their intersection along the east-dipping eastern contact of the Ellisville neck, near where the causative fault for the earthquake projects to the surface. The trenches have exposed abundant evidence of post-Paleozoic fracturing and faulting, including brecciated quartz-tourmaline veins, slickensided thrust and strike-slip faults, and clay-filled fractures. Fluvial and colluvial gravels that overlie these brittle structures have yielded optically stimulated luminescence ages ranging from ca. 27 to 10 ka. These structures are likely representative of surface features associated with Quaternary earthquakes in the Central Virginia seismic zone.

GSA Special Papers

The geologic history of the Mid-Pacific Mountains in the central North Pacific Ocean; A synthesis of deep-sea drilling studies

The Mid-Pacific Mountains constitute one of the largest aseismic rises in the central North Pacific Ocean. They have been generated by mid-plate volcanic events prior to Barremian time, but their volcanic activity continued through the remainder of the Cretaceous. Evidence of the latest stages of this volcanism are the trachytic ashes included in mid- and Late Cretaceous sediments and the presence of guyots atop the main volcanic pedestal. The thermal and volcanic history of the oldest part of the Pacific Plate and its plate tectonic movements since Cretaceous time have led to considerable horizontal and vertical movements of the Mid-Pacific Mountains. Reconstruction of their subsidence and evidence from the sediments from Site 463 suggest that they once, in Cretaceous time, constituted large, tropical volcanic islands which were covered by vegetation and which shed their erosional debris over the adjacent island slopes. Neritic fossils in Maastrichtian sediments document the presence of shoal areas until the end of the Mesozoic. Since then they have subsided to their present water depth. The horizontal movements of the Pacific Plate have carried the Mid-Pacific Mountains from a position well south of the Cretaceous equator to their present position under the unproductive surface waters of the subtropical central North Pacific Ocean. Site 463, on the western Mid-Pacific Mountains, probably crossed the equator in Maastrichtian time. Shallow-water-derived calcareous fossils are incorporated into the pelagic sediments covering the Mid-Pacific Mountains. They have been displaced from their source areas along the flanks of seamounts over the adjacent regions during times of low sea-level stands. Debris of land plants in Aptian sediments documents the presence of emergent volcanoes during that time. The pelagic sediments penetrated at Site 463 consist largely of a sequence of Cretaceous chalks, limestones, and cherts which accumulated fast and which document the presence of highly productive surface water masses around the former volcanic islands and above the shoals. The development of oxygen-deficient depositional environments and the lack of evidence for intensive reworking suggest at the same time very sluggish water movements in the meso- and bathypelagic environment during Early and mid-Cretaceous times. The Cenozoic calcareous oozes, on the other hand, are very condensed. They are interrupted in several places by hiatuses, and despite their position well above the CCD they show effects of dissolution and poor preservation of the calcareous faunas and floras. The frequency of reworked pelagic material together with the hiatuses indicate episodes of intensive renewal of the meso- and bathypelagic water masses which generated intensive sea-floor erosion and which were probably triggered by the climatic deterioration in the polar regions

Initial Reports of the D.S.D.P.

Hydrologic conditions, habitat characteristics, and occurrence of fishes in the Apalachicola River floodplain, Florida; second annual report of progress, October 1993-September 1994

This report describes progress and interim results of the second year of a 4-year study. The purpose of the 4-year study is to describe aquatic habitat types in the Apalachicola River floodplain and quantify the amount of habitat inundated by the river at various stages. Final results will be used to determine possible effects of altered flows on floodplain habitats and their associated fish communities. The study is being conducted by the U.S. Geological Survey in cooperation with the Northwest Florida Water Management District as part of a comprehensive study of water needs throughout two large river basins in Florida, Georgia, and Alabama. By the end of the second year, approxi- mately 80 to 90 percent of field data collection was completed. Water levels at 56 floodplain and main channel locations at study sites were read numerous times during low water and once or twice during high water. Rating curves estimating the relationship between stage at a floodplain site and flow of the Apalachicola River at Chattahoochee are presented for 3 sites in the upper river. Elevation, substrate type, and amount of vegetative structure were described at 27 cross sections representing eight different floodplain tributary types at upper, middle, and lower river study sites. A summary of substrate and structure information from all cross sections is presented. Substrate and structure characteristics of floodplain habitats inundated when river flow was at record low flow, mean annual low flow, and mean flow are described for 3 cross sections in the upper river. Digital coverage of high-altitude infra-red aerial photography was processed for use in a Geographic Information System which will be used to map aquatic habitats in the third year of the study. A summary of the literature on fish utilization of floodplain habitats is described. Eighty-one percent of the species collected in the main channel of the Apalachicola River are known to occur in floodplain habitats of eastern rivers.

Open-File Report

Volcanic history, geologic analysis and map of the Prometheus Patera region on Io

Data from Jupiter's moon Io returned by the Galileo spacecraft have been used to create a geologic map of Prometheus Patera, its associated flow field, and nearby features. We have identified the location of the vent that fed the Prometheus flow field during the Galileo epoch in the north-eastern portion of the main Prometheus flow field. This vent is the probable source of a small sulphur-rich plume. Previous studies suggested that the vent may be atop a tectonic fault but we find that the vent is offset from the putative fault. It is plausible that, in the past, magma exploited the fault to reach the surface at Prometheus Patera, but subsequent magma cooling in the conduit could have caused an obstruction preventing further eruptions from providing significant contributions to the Prometheus flow field. We also speculate on how a new Prometheus plumbing system may be fed by mafic magmas after melt stalls in magma reservoirs during its ascent through the lithosphere from the mantle.

Journal of Volcanology and Geothermal Research

Methodology for assessment of undiscovered oil and gas resources for the 2008 Circum-Arctic Resource Appraisal

The methodological procedures used in the geologic assessments of the 2008 Circum-Arctic Resource Appraisal (CARA) were based largely on the methodology developed for the 2000 U.S. Geological Survey World Petroleum Assessment. The main variables were probability distributions for numbers and sizes of undiscovered accumulations with an associated risk of occurrence. The CARA methodology expanded on the previous methodology in providing additional tools and procedures more applicable to the many Arctic basins that have little or no exploration history. Most importantly, geologic analogs from a database constructed for this study were used in many of the assessments to constrain numbers and sizes of undiscovered oil and gas accumulations.

Professional Paper

Geochronology and geology of late Oligocene through Miocene volcanism and mineralization in the western San Juan Mountains, Colorado

This paper presents 25 new 40Ar/39Ar dates from the main calc-alkaline ash-flow sheets and related younger plutons of the western San Juan volcanic field, the ash-flow sheets of the Lake City caldera cycle, and veins and other altered rocks in the Lake City region. The goal of the study was to produce similar quality 40Ar/39Ar ages to those currently published for the eastern and central San Juan Mountains. These new data provide a much more precise chronological framework for interpreting durations of events and their relationship to mineralization than do previously published conventional K-Ar dates for the western San Juan Mountains.

Professional Paper

Geologic map of the Cochetopa Park and North Pass Calderas, northeastern San Juan Mountains, Colorado

The San Juan Mountains in southwestern Colorado have long been known as a site of exceptionally voluminous mid-Tertiary volcanism, including at least 22 major ignimbrite sheets (each 150-5,000 km 3 ) and associated caldera structures active at 33-23 Ma. Recent volcanologic and petrologic studies in the San Juan region have focused mainly on several ignimbrite-caldera systems: the southeastern area (Platoro complex), western calderas (Uncompahgre-Silverton-Lake City), and the central cluster (La Garita-Creede calderas). Far less studied has been the northeastern San Juan region, which occupies a transition between earlier volcanism in central Colorado and large-volume younger ignimbrite-caldera foci farther south and west. The present map is based on new field coverage of volcanic rocks in seventeen 7.5' quadrangles in northeastern parts of the volcanic field, high-resolution age determinations for 120 new sites, and petrologic studies involving several hundred new chemical analyses. This mapping and the accompanying lab results (1) document volcanic evolution of the previously unrecognized North Pass caldera and the morphologically beautifully preserved but enigmatic Cochetopa basin, including unique features not previously described from ignimbrite calderas elsewhere; (2) provide evidence for a more rapid recurrence of large ignimbrite eruptions than previously known elsewhere; (3) quantify the regional time-space-volume progression from the earlier Sawatch magmatic trend southward into the San Juan region; and (4) permit more rigorous comparison between the broad mid-Tertiary magmatic belt in the western U.S. Cordillera and the type continental-margin arc volcanism in the central Andes.

Colorado

Stratigraphy and structure of the area of the Kurupa, Oolamnagavik, Killik, and Colville Rivers

The area between 68° 3C' and 69° 08 N. latitude and between 154° and 155° 20 W. longitude was covered by U. S. Geological Survey party 4 during the period May 18 to September 2. Traverses were confined mainly to the valleys of the Kurupa, Oolamnagavik, and Colville Rivers inasmuch as very little rock is exposed in the interstream areas. This report is a compilation of the field data and of the results of office and laboratory work on rock specimens, fossils, and aerial photographs of the area. An interpretation of the structure and stratigraphy of this area is presented, and possible correlations with the Killik River area to the east are suggested. Some revisions of the conclusions in this report may become necessary in the light of further field work in adjacent areas and heavy mineral studies, but it is believed that any changes will not materially alter the geologic picture of the area.

Alaska

Stable isotopes and mineral resource investigations in the United States

The elements oxygen, hydrogen, sulfur, and carbon are important constituents of hydrothermal ore-forming systems and the weathering processes of mineral deposits in the surficial environment. They also play key roles in volcanic activity, ecosystem dynamics, climate change, and hydrologic and atmospheric processes. Therefore, study of the stable isotopes of these elements can provide powerful insights into these processes. This is especially true for ongoing U.S. Geological Survey (USGS) projects in the Eastern United States that are concerned with the origins of base (copper, lead, and zinc) and precious (gold and silver) metal deposits in the Carolina slate belt and northern Maine and with the environmental effects of weathering of mineral deposits (fig. 1).

Information Handout

Distribution of streamflow, sediment, and nutrients entering Galveston Bay from the Trinity River, Texas, 2016–19

The U.S. Geological Survey (USGS), in cooperation with the Texas Water Development Board, collected streamflow and water-quality data at USGS monitoring stations in the lower Trinity River Basin from January 2016 to December 2019 to characterize streamflow, nutrients, and suspended sediment entering Galveston Bay from the Trinity River. Results from previous studies indicate that water from the main channel of the Trinity River is diverted into surrounding wetlands and water bodies and is stored or discharged directly into Galveston Bay through distributary channels in the delta. This study provides an assessment of the distribution of streamflow in the various channels that form the delta of the Trinity River to evaluate the effects of streamflow diversions on the eventual supply of freshwater, nutrients, and suspended sediment to Galveston Bay. Instantaneous streamflow data and continuous streamflow records from USGS monitoring stations in the delta of the Trinity River were used to quantify freshwater inflow into Galveston Bay and assess the distribution of streamflow in the lowermost reaches of the Trinity River Basin. In this report, periods in which releases from Lake Livingston caused a rise in streamflow farther downstream at USGS station 08067000 Trinity River at Liberty, Tex. (hereinafter referred to as the “Liberty site”) that did not exceed 20,000 cubic feet per second (ft 3 /s) are referred to as “low-flow events,” and periods in which streamflow at the Liberty site exceeded 20,000 ft 3 /s are referred to as “high-flow events.” During this study, it was estimated that only about 55 percent of the total water volume released from Lake Livingston was accounted for at USGS station 08067252 Trinity River at Wallisville, Tex. (hereinafter referred to as the “Wallisville site”), which is approximately 8 river miles upstream from where the Trinity River enters Galveston Bay. The difference in water volumes between what is released from Lake Livingston and what is measured at the Wallisville site is consistent with findings from previous studies and indicates that a large part of the volume released from Lake Livingston does not reach Galveston Bay through the main channel of the Trinity River. To assess the distribution of streamflow and estimate the amount of water diverted from the main channel of the Trinity River into distributary channels, instantaneous streamflow measurements were made at USGS station 08067230 Old River Lake near Wallisville, Tex. (hereinafter referred to as the “Old River Lake site”) and the Wallisville site during a range of hydrologic conditions. Results indicate that a large portion of the freshwater inflow was likely delivered to Galveston Bay through pathways other than the main channel of the Trinity River, including Old River Lake. When streamflow at the Liberty site, located upstream from the Wallisville site, exceeded approximately 40,000 ft 3 /s, Old River Lake and its network of hydrologically connected channels likely became the primary pathway for freshwater inflow entering Galveston Bay. Water quality was characterized from discrete samples collected during a range of hydrologic conditions at the Old River Lake site and the Wallisville site in order to evaluate the effects of streamflow diversions on the supply of suspended sediment and nutrients into Galveston Bay. Suspended-sediment concentrations were typically higher at the Wallisville site than at the Old River Lake site, likely because of lower water velocities at the Old River Lake site than at the Wallisville site; low water velocities allow suspended sediment to settle, thus reducing concentrations. Suspended-sediment loads were also typically higher at the Wallisville site than at the Old River Lake site during high-flow events. However, when streamflows at the Liberty site exceeded approximately 60,000 ft 3 /s, suspended-sediment loads were higher at the Old River Lake, which likely became the primary pathway for suspended-sediment delivery into Galveston Bay. Suspended-sediment concentrations and loads were computed at the Wallisville and Liberty sites for the duration of 11 hydrologic events representing different streamflows by using the regression equations developed for each monitoring station. Overall, approximately 25 percent of the total sediment load measured during events at the Liberty site was measured at the Wallisville site, indicating that only a portion of the suspended-sediment load from the Liberty site reached Galveston Bay through the main channel of the Trinity River during the measured events. Based on data from discrete samples, some of this sediment load was diverted into Old River Lake and associated distributary channels. Results from analysis of nutrient samples indicate that streamflow conditions affect the nitrogen concentrations in the delta of the Trinity River. At the Old River Lake site, nitrate plus nitrite and total dissolved nitrogen concentrations were typically lower during low-flow conditions than during high-flow events; low-flow conditions represent low-flow events or tidal-flow conditions (during low-flow conditions the streamflow at the Liberty site was less than 20,000 ft 3 /s). Lower concentrations of nitrate plus nitrite and total dissolved nitrogen at the Old River Lake site may be associated with various physical and biogeochemical processes, including the transformation and biological uptake of nitrate, nitrite, and other species of nitrogen resulting from extended water residence times and relatively small inputs of nitrogen from the upstream reaches of the Trinity River Basin. During high-flow events, the proportions of nitrogen species were similar among sites, indicating that the travel path through wetlands and channels surrounding Old River Lake likely does not affect the relative concentrations of the various nitrogen species present in freshwater inflow to Galveston Bay. Results from analysis of nutrient samples also indicate that the pathways for nutrient delivery from the Trinity River into Galveston Bay are dependent on event magnitude. When streamflows at the Liberty site were low (approximately 20,000 ft 3 /s), the main channel of the Trinity River was the primary pathway for nitrogen and phosphorus entering Galveston Bay. Once streamflow at the Liberty site exceeded 20,000 ft 3 /s, however, the contribution of nutrient loading through Old River Lake to Galveston Bay increased proportionally to the nutrient loading in the main channel, and when streamflow at the Liberty site exceeded approximately 50,000 ft 3 /s, Old River Lake likely became the primary pathway for nutrient delivery into Galveston Bay.

Texas

Stable isotopes and volatile organic compounds along seven ground-water flow paths in divergent and convergent flow systems, southern California, 2000

Ground water is a major source of drinking water in southern California. In an effort to understand factors influencing the susceptibility of ground water tapped by public supply wells, the U.S. Geological Survey has undertaken studies in cooperation with the California State Water Resources Control Board. The vertical and lateral distribution of stable isotopes (deuterium and oxygen-18) and volatile organic compounds (VOC) were examined along seven ground-water flow paths in three urban ground-water basins in southern California: Central Basin in Los Angeles County, Main Basin in Orange County, and Bunker Hill Basin in San Bernardino County. Forty-seven monitoring wells and 100 public supply wells were sampled. The results of this study suggest that the direction of flow and perhaps the degree of confinement in an aquifer system are important controls on the distribution of VOCs. Ground-water flow in the Central and Main Basins in the southern California coastal plain is characterized as radially divergent, with ground-water flow directions moving outward from focused areas of recharge in the unconfined part of the aquifer system toward dispersed areas of discharge in the more confined part. In these basins, there is a volume of water containing VOCs that extends out into a volume of water containing no VOCs. This pattern suggests that radially divergent flow systems disperse VOCs in distal areas. The overall pattern also suggests that ground water in the pressure area is generally insulated from compounds introduced at land surface. These two factors?dispersion of VOCs due to divergence of flow and insulation from land-surface inputs?suggest that the susceptibility of public supply wells to surface contamination decreases with distance in radially divergent, well confined ground-water flow system. In the inland Bunker Hill Basin, ground-water flow is characterized as radially convergent; ground-water flow directions move inward from dispersed recharge areas in the unconfined part of the aquifer system, toward an area of focused discharge in the more confined part. The number of VOCs increased and the concentrations of individual VOCs increased, or remained the same, with increasing travel distance. Methyl tert-butyl ether was detected only in wells in the confined part of the aquifer system, suggesting that the confining units present in the distal part of the Bunker Hill Basin do not prevent VOCs from reaching ground water. These results suggest that VOCs in the Bunker Hill Basin are collected and concentrated as ground water moves downgradient because of radial convergenence of flow. They also suggest that ground water in the Bunker Hill Basin has an increasing opportunity to pick up VOCs introduced at land surface as it moves along a flow path. Some of the downgradient increase in VOC occurrence and concentration may be due to pumping that selectively removes cleaner ground water, thus leaving ground water containing more VOCs in the aquifer. These two factors?collection of VOCs due to convergence of flow and increasing opportunity to collect surficial contaminants perhaps due to a relative absence of confinement?suggest that the susceptibility of public supply wells to surface contamination increases with distance in radially convergent ground-water flow systems, particularly those that are unconfined.

Water-Resources Investigations Report

Reassessment of the Georgetown limestone as a hydrogeologic unit of the Edwards Aquifer, Georgetown area, Texas

The Edwards aquifer consists of geologic units known as the Comanche Peak (oldest) and Edwards Limestones, Kiamichi Formation, and Georgetown Limestone. The Edwards Limestone is the main water-bearing zone. The shallow geologic units dip to the east-southeast at a slope of 50 to 100 feet per mile in the Georgetown area. The Edwards aquifer extends from the western limits of the outcrop to the transition zone from freshwater to saline water to the east. The downdip continuity of the geologic units is interrupted by several faults in the Balcones fault zone. The aquifer is recharged by the infiltration of precipitation and streamflow in the outcrop and is discharged by springs in the outcrop and by wells, evapotranspiration, and leakage through the overlying confining bed in the confined area. Streams in the area regionally flow from the west to the east. A reassessment of the uppermost geologic unit of the Edwards aquifer, the Georgetown Limestone, was conducted in the Georgetown area, Texas, using: (1) data from six surveys of streamflow gains and losses and ground-water levels, (2) aquifer tests at three clusters of test wells, (3) variation in water-quality characteristics to indicate ground-water circulation, and (4) previous studies. Data from the six surveys did not show a pattern of corresponding streamflow gains and losses with positive (upward) and negative (downward) head differentials, respectively, between the main water-bearing zone of the Edwards aquifer and the streams. A consistent and corresponding pattern was shown only for the subreach containing Berry Springs. The aquifer tests consisted of "slug" test analyses to determine the transmissive characteristics of the Georgetown Limestone and produced 8 9 hydraulic conductivity values ranging from 1.4 X 10 -8 to 2.8 X 10 -9 centimeters per second at four of the six test wells. The other two test wells did not produce data suitable for conventional aquifer-test analysis. An analysis of the water-quality characteristics suggests that the Edwards Limestone and the streams have a significant hydraulic connection but the ground-water circulation between the Edwards Limestone and the Georgetown Limestone is very limited. The only area where a high degree of hydraulic connection between the main water-bearing zone of the Edwards aquifer (Edwards Limestone) and the streams was found is near the updip limits of the Georgetown Limestone, where a nearby major fault occurs and where major springs have developed. These findings suggest that the Georgetown Limestone does not function as a unit of the Edwards aquifer but as a regional confining bed with localized avenues that allow flow to and from the underlying Edwards aquifer.

Water-Resources Investigations Report

Water quality characterization in some birimian aquifers of the Birim Basin, Ghana

The objective of this study was to determine the main controls on the hydrochemistry of groundwater in the study area. Mass balance modeling was used simultaneously with multivariate R-mode hierarchical cluster analysis to determine the significant sources of variation in the hydrochemistry. Two water types have been revealed in this area: (1) waters influenced more significantly by the weathering of silicate minerals from the underlying geology, and are rich in silica, sodium, calcium, bicarbonate, and magnesium ions, and (2) waters that have been influenced by the effects of fertilizers and other anthropogenic activities in the area. Mineral speciation and silicate mineral stability diagrams generated from the data suggest that montmorillonite, probably derived from the incongruent dissolution of feldspars and micas, is the most stable silicate phase in the groundwater. The apparent incongruent weathering of silicate minerals in the groundwater system has led to the enrichment of sodium, calcium, magnesium and bicarbonate ions as well as silica, leading to the supersaturation of calcite, aragonite, dolomite and quartz. Stability in the montmorillonite field suggests restricted flow conditions whereby groundwater residence time is relatively high, leading to greater contact of groundwater with the rock to enhance weathering. Cation exchange processes have also been determined to play minor roles in the hydrochemistry.

KSCE Journal of Civil Engineering

Generalized sediment budgets of the Lower Missouri River, 1968–2014

Sediment budgets of the Lower Missouri River were developed in a study led by the U.S. Geological Survey in cooperation with the U.S. Army Corps of Engineers. The scope of the study included the development of a long-term (post-impoundment, 1968–2014) average annual sediment budget and selected annual, monthly, and daily sediment budgets for a reach and period that adequate data were available. Included in the analyses were 31 main-stem and tributary stations of the Lower Missouri River and two Mississippi River stations—the Mississippi River below Grafton, Illinois, and the Mississippi River at St. Louis, Missouri. Long-term average annual suspended-sediment loads of Missouri River main-stem stations ranged from 0.33 million tons at the Missouri River at Yankton, South Dakota, station to 71.2 million tons at Missouri River at Hermann, Mo., station. Gaged tributary gains accounted for 9–36 percent of the local reach budgets and cumulative gaged tributary contributions accounted for 84 percent of the long-term average suspended-sediment load of the Missouri River at Hermann, Mo., station. Although the sediment budgets for seven defined main-stem reaches generally were incomplete—missing bedload, reach storage, and ungaged tributary contributions—the budget residuals (net result of sediment inputs and outputs) for six of the seven reaches ranged from -7.0 to 1.7 million tons, or from -9.2 to 4.0 percent of the reach output suspended-sediment load, and were within the 10 percent reported measurement error of annual suspended-sediment loads for large rivers. The remaining reach, downstream from Gavin’s Point Dam, extended from Yankton, S. Dak., to Sioux City, Iowa, and had a budget residual of -9.8 million tons, which was -88 percent of the suspended-sediment load at Sioux City. The Lower Missouri River reach from Omaha, Nebraska, to Nebraska City, Nebr., had periods of concurrent sediment data for each primary budget component with which to analyze and determine a suspended-sediment budget for selected annual, monthly, and daily time increments. The temporal changes in the cumulative annual budget residuals were poorly correlated with the comparatively steady 1968–2011 annual stage trends at the Missouri River at Nebraska City, Nebr., station. An accurate total sediment budget is developed by having concurrent data available for all primary suspended and bedload components for a reach of interest throughout a period. Such a complete budget, with concurrent record for suspended-sediment load and bedload components, is unavailable for any reach and period in the Lower Missouri River. The primary data gaps are in bedload data, and also in suspended-sediment gains and losses including ungaged tributary inputs and sediment storage. Bedload data gaps in the Missouri River Basin are much more prevalent than suspended-sediment data gaps, and the first step in the development of reach bedload budgets is the establishment of a standardized bedload monitoring program at main-stem stations. The temporal changes in flow-adjusted suspended-sediment concentrations analyzed at main-stem Missouri River stations indicated an overall downward change in concentrations between 1968 and 2014. Temporary declines in flow-adjusted suspended-sediment concentrations during and following large floods were evident but generally returned to near pre-flood values within about 6 months. Data uncertainties associated with the development of a sediment budget include uncertainties associated with the collection of suspended-sediment and bedload data and the computation of suspended-sediment loads. These uncertainties vary depending on the frequency of data collection, the variability of conditions being represented by the discrete samples, and the statistical approach to suspended-sediment load computations. The coefficients of variation of suspended-sediment loads of Missouri River tributary stations for 1968–2014 were greater, 75.0 percent, than the main-stem stations, 47.1 percent. The lower coefficient of variation at main-stem stations compared to tributaries, primarily is the result of the lower variability in streamflow and sediment discharge identified at main-stem stations. To obtain similar accuracy between suspended-sediment loads at main-stem and tributary stations, a longer period of record is required of the tributary stations. During 1968–2014, however, the Missouri River main-stem station record was much more complete (87 percent) than the tributary station record (28 percent).

Missouri River Basin

Hydrologic and Hydraulic Analyses of Selected Streams in Lorain County, Ohio, 2003

Hydrologic and hydraulic analyses were done for selected reaches of nine streams in Lorain County Ohio. To assess the alternatives for flood-damage mitigation, the Lorain County Engineer and the U.S. Geological Survey (USGS) initiated a cooperative study to investigate aspects of the hydrology and hydraulics of the nine streams. Historical streamflow data and regional regression equations were used to estimate instantaneous peak discharges for floods having recurrence intervals of 2, 5, 10, 25, 50, and 100 years. Explanatory variables used in the regression equations were drainage area, main-channel slope, and storage area. Drainage areas of the nine stream reaches studied ranged from 1.80 to 19.3 square miles. The step-backwater model HEC-RAS was used to determine water-surface-elevation profiles for the 10-year-recurrence-interval (10-year) flood along a selected reach of each stream. The water-surface pro-file information was used then to generate digital mapping of flood-plain boundaries. The analyses indicate that at the 10-year flood elevation, road overflow results at numerous hydraulic structures along the nine streams.

Water-Resources Investigations Report

Tremors from earthquakes and blasting in the Powder River basin of Wyoming and Montana

Coal in the Powder River Basin of Wyoming and Montana (fig. 1) is greatly in demand. It can be economically mined from the surface, and the land is much easier to reclaim than land above underground mines that has been damaged by subsidence or by underground fires. Exploitation of the vast coals resources in the basin has caused a rapid influx of population into the area and an associated increase in building construction. The activity has also generated concern about possible regulation of development. With these facts in mind, the U.S Geological Survey has been investigating the geologic implications of development in the Powder River Basin. One area of study has been the effect of earth tremors caused by blasting in the large coal surface mines or by naturally occurring earthquakes. The basin proper was classified by Algermissen and Perkins (1976) as belonging to a region of low seismic risk. Naturally occurring earthquakes are, therefore, mainly of scientific interest, unless of course there was an isolated event that occurred near a populated area or a surface mine. We are not aware of any damage to people or to property caused by blasting in the coal surface mines even though thousands of tons of explosives are detonated each year in the basin. The maximum weight of an individual explosive charge and the time interval between blasts are regulated so that any nearby structures will not be damaged or the residents disturbed. Blasting, nevertheless, does produce seismic tremors that can be recorded over 200 kilometers away. In addition, at one mine, some very low order aftershocks were recorded relatively close to the source within 2 hours after blasting.

Montana; Wyoming