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Occurrence and behavior of the herbicide Prometon in the hydrologic system

Prometon, a triazine herbicide, is used for total vegetation control on industrial sites, on noncrop areas on farms, in and under asphalt, and to a small extent by homeowners. Prometon has often been detected in surface water and groundwater in studies reported in the literature, but its presence is seldom discussed, partly because of its infrequent inclusion on lists of herbicides used in either agricultural or urban areas. In recent large-scale studies by the U.S. Geological Survey, prometon has been the most commonly detected herbicide in surface water and groundwater in urban areas and the third and fourth most commonly detected herbicide in groundwater and surface water, respectively, in agricultural areas. It also has been detected in rain. The frequent detection of prometon in the environment is discussed in relation to its use practices and predicted environmental behavior. Prometon is compared to atrazine, a structurally similar agricultural triazine herbicide that is one of the most studied and most commonly detected herbicides found in the hydrologic environment. The environmental data presented here demonstrate the wide-scale occurrence of prometon in all components of the hydrologic system, particularly in the surface water and groundwater of urban areas.Prometon, a triazine herbicide, is used for total vegetation control on industrial sites, on noncrop areas on farms, in and under asphalt, and to a small extent by homeowners. Prometon has often been detected in surface water and groundwater in studies reported in the literature, but its presence is seldom discussed, partly because of its infrequent inclusion on lists of herbicides used in either agricultural or urban areas. In recent large-scale studies by the U.S. Geological Survey, prometon has been the most commonly detected herbicide in surface water and groundwater in urban areas and the third and fourth most commonly detected herbicide in groundwater and surface water, respectively, in agricultural areas. It also has been detected in rain. The frequent detection of prometon in the environment is discussed in relation to its use practices and predicted environmental behavior. Prometon is compared to atrazine, a structurally similar agricultural triazine herbicide that is one of the most studied and most commonly detected herbicides found in the hydrologic environment. The environmental data presented here demonstrate the wide-scale occurrence of prometon in all components of the hydrologic system, particularly in the surface water and groundwater of urban areas.

Environmental Science & Technology

Groundwater availability of the Northern High Plains aquifer in Colorado, Kansas, Nebraska, South Dakota, and Wyoming

Executive Summary The Northern High Plains aquifer underlies about 93,000 square miles of Colorado, Kansas, Nebraska, South Dakota, and Wyoming and is the largest subregion of the nationally important High Plains aquifer. Irrigation, primarily using groundwater, has supported agricultural production since before 1940, resulting in nearly $50 billion in sales in 2012. In 2010, the High Plains aquifer had the largest groundwater withdrawals of any major aquifer system in the United States. Nearly one-half of those withdrawals were from the Northern High Plains aquifer, which has little hydrologic interaction with parts of the aquifer farther south. Land-surface elevation ranges from more than 7,400 feet (ft) near the western edge to less than 1,100 ft near the eastern edge. Major stream primarily flow west to east and include the Big Blue River, Elkhorn River, Loup River, Niobrara River, Republican River and Platte River with its two forks—the North Platte River and South Platte River. Population in the Northern High Plain aquifer area is sparse with only 2 cities having a population greater than 30,000. Droughts across much of the area from 2001 to 2007, combined with recent (2004–18) legislation, have heightened concerns regarding future groundwater availability and highlighted the need for science-based water-resource management. Groundwater models with the capability to provide forecasts of groundwater availability and related stream base flows from the Northern High Plains aquifer were published recently (2016) and were used to analyze groundwater availability. Stream base flows are generally the dominant component of total streamflow in the Northern High Plains aquifer, and total streamflows or shortages thereof define conjunctive management triggers, at least in Nebraska. Groundwater availability was evaluated through comparison of aquifer-scale water budgets compared for periods before and after major groundwater development and across selected future forecasts. Groundwater-level declines and the forecast amount of groundwater in storage in the aquifer also were examined. Major Findings Aquifer losses to irrigation withdrawals increased greatly from 1940 to 2009 and were the largest average 2000–9 outflow (49 percent of total). Basin to basin groundwater flows were not a large part of basin water budgets. Development of irrigated land and associated withdrawals were not uniform across the Northern High Plains aquifer, and different parts of the Northern High Plains aquifer responded differently to agricultural development. For the Northern High Plains aquifer, areas with high recharge and low evapotranspiration had the most streamflow, and most streams only remove water from the aquifer. Results of a baseline future forecast indicated that groundwater levels declined overall, indicating an overdraft of the aquifer when climate was about average and agricultural development was held at the same state as 2009. Results of two human stresses future forecasts indicated that increases of 13 percent or 23 percent in agricultural development, mostly near areas of previous development, caused increases in groundwater pumping of 8 percent or 11 percent, and resulted in continued groundwater-level declines, at rates 0.3 or 0.5 million acre-feet per year larger than the baseline forecast. Results of environmental stresses forecasts (generated from two downscalings of global climate model outputs) compared with the baseline forecast indicated that even though annual precipitation was nearly the same, differences in temperature and a redistribution of precipitation from the spring to the growing season (from about May 1 through September 30), created a large (12–15 percent) decrease in recharge to the aquifer. For the two environmental stresses forecasts, temperature and precipitation were distributed about the same among basins of the Northern High Plains aquifer, but the amounts were different.

Colorado, Kansas, Nebraska, South Dakota, Wyoming

Millennial-scale climatic and cultural impacts on vegetation and fire at the southern edge of the Rocky Mountains, USA

Mountain forests and woodlands in semiarid regions of the world are threatened by climatic change and other human impacts. In the southwestern USA, climate and culturally driven changes to the structure and fire regimes of dry coniferous forests over recent centuries are well documented by tree-ring archives. However, the roles of climate and people as drivers of millennial-scale changes are less understood. We present a new record of vegetation dynamics and regional fire activity inferred from pollen, microscopic charcoal, and sediment geochemistry from Santa Fe Lake, NM (3532 m a.s.l.), the southernmost natural lake in the Rocky Mountains. Declining elemental intensities (e.g., Ti, Fe, Si) record local deglaciation after 14,000 cal yr BP followed by upslope expansion of trees indicated by increasing Pinus and Picea pollen percentages as the climate warmed during the Late Glacial. Cool, dry growing seasons probably limited the establishment of dense forests until after 12,200 cal yr BP when we hypothesize that Pinus ponderosa (ponderosa pine) expanded regionally (i.e., within 10–100 km) due to continued warming and a possible increase in monsoonal precipitation. Subalpine forests established near Santa Fe Lake by 10,300 cal yr BP as indicated by abundant conifer stomates and increasing Picea and Pinus aristata pollen percentages, which are highest after 5100 cal yr BP. Increasing Juniperus -type, Quercus , and Pinus edulis -type pollen record changes in vegetation belts at lower elevations after 10,300 cal yr BP. Maize pollen, an unambiguous indicator of Puebloan agriculture, first appears at 800 cal yr BP (1150 cal yr CE) and is present through 1600 cal yr CE when Spanish colonization brought cultural upheaval and population loss to local indigenous communities. Regional fire activity, inferred from microscopic charcoal influx, remained relatively constant for most of our record. However, average microscopic charcoal influx more than doubled relative to the rest of the Holocene during the last 2000 years, with the highest influx after 1550 cal yr BP (400 cal yr CE). The increased influx of microscopic charcoal coincides with archaeological evidence for dramatic regional population growth in the northern Rio Grande region and probably reflects extensive cultural burning associated with the development of an agricultural economy. Although climate was an important driver of vegetation change and fire regimes in the mountains of the southwestern USA during the Holocene, our results suggest that human impacts on regional burning during the last 2000 years far exceeded earlier climate-driven variation.

Rocky Mountains

Fates and fingerprints of sulfur and carbon following wildfire in economically important croplands of California, U.S.

Sulfur (S) is widely used in agriculture, yet little is known about its fates within upland watersheds, particularly in combination with disturbances like wildfire. Our study examined the effects of land use and wildfire on the biogeochemical “fingerprints,” or the quantity and chemical composition, of S and carbon (C). We conducted our research within the Napa River Watershed, California, U.S., where high S applications to vineyards are common, and ~ 20% of the watershed burned in October 2017, introducing a disturbance now common across the warmer, drier Western U.S. We used a laboratory rainfall experiment to compare unburned and low severity burned vineyard and grassland soils. We then sampled streams draining sub-catchments with differing land use and degrees of burn and burn severity to understand combined effects at broader spatial scales. Before the laboratory experiment, vineyard soils had 2–3.5 times more S than grassland soils, while burned soils—regardless of land use—had 1.5–2 times more C than unburned soils. During the laboratory experiment, vineyard soil leachates had 16–20 times more S than grassland leachates, whereas leachate C was more variable across land use and burn soil types. Unburned and burned vineyard soils leached S with δ 34 S values enriched 6–15‰ relative to grassland soils, likely due to microbial S processes within vineyard soils. Streams draining vineyards also had the fingerprint of agricultural S, with ~2–5 fold higher S concentrations and ~ 10‰ enriched δ 34 S-SO 4 2− values relative to streams draining non-agricultural areas. However, streams draining a higher fraction of burned non-agricultural areas also had enriched δ 34 S values relative to unburned non-agricultural areas, which we attribute to loss of 32 S during combustion. Our findings illustrate the interacting effects of wildfire and land use on watershed S and C cycling—a new consideration under a changing climate, with significant implications for ecosystem function and human health.

California

A global long-term daily reanalysis of reference evapotranspiration for drought and food-security monitoring

NOAA has developed a global reference evapotranspiration (ET 0 ) reanalysis using the UN Food and Agriculture Organization formulation (FAO-56) of the Penman-Monteith equation forced by MERRA phase 2 (MERRA2) meteorological and radiative drivers. The NOAA ET 0 reanalysis is provided daily from January 1, 1980 to the near-present at a resolution of 0.5° latitude × 0.625° longitude. The reanalysis is verified against station data across southern Africa, a region presenting both significant challenges regarding hydroclimatic variability and observational quantity and quality and significant potential benefits to food-insecure populations. These data are generated from observations from the Southern African Science Service Centre for Climate Change and Adaptive Land Management (SASSCAL) network. We further verified globally against spatially distributed ET 0 derived from two reanalyses–the Global Data Assimilation System (GDAS) and Princeton Global Forcing (PGF)–and these verifications produced similar results, yet demonstrated wide regional and seasonal differences. We also present cases that verify the operational applicability of the reanalysis in long-established drought, famine, crop- and pastoral-stress metrics, and in predictability assessments of drought forecasts.

Nature Scientific Data

Improving the ability to include freshwater wetland plants in process-based models

Considerable effort and resources have been placed into conservation programs designed to reduce or alleviate negative environmental effects of crop production and into evaluation of the benefits of these programs. Wetlands are an important source of ecosystem services, but modeling wetland plants is an emerging science. To date, wetland plant growth has not been explicitly accounted for in ecosystem service models that quantify conservation program effects. As part of an effort to more accurately simulate wetland plants within process-based models, we expanded upon plant growth data collected in an earlier effort with additional sampling at two of four previously sampled areas, and included a fifth sampling site. We then used data from the five sites spanning five years as wetland plant parameters at both the species and functional group levels for the Agricultural Land Management Alternative with Numerical Assessment Criteria (ALMANAC) model. In addition to individual species, modelers are interested in functional groups representing a collection of species because it is unrealistic to model every species occurring in an ecosystem. ALMANAC simulations were completed at three sites for both individual wetland plant species and functional groups. At each site, simulated plant yields were within 1 Mg ha –1 (±7%) of measured values ( r 2 = 0.99). Multisite species simulated yields were within 37% of measured values ( r 2 = 0.95). Functional groups performed as well as individual species simulations. Functional group simulated yields were within 1 Mg ha –1 (±5%) of measured yields. Plant growth is a major component of these wetland ecosystems, and ALMANAC verified wetland plant parameters support more accurate assessments of conservation programs and practices on the influence of wetland ecosystems embedded within agricultural fields. The improved plant parameters we provide here will be transferred to other process-based models that focus on other ecosystem components such as soil and water effects, facilitating wetland evaluations across the United States and elsewhere.

California, Delaware, Maryland, North Dakota, Texa

NASA's surface biology and geology designated observable: A perspective on surface imaging algorithms

The 2017–2027 National Academies' Decadal Survey, Thriving on Our Changing Planet , recommended Surface Biology and Geology (SBG) as a “Designated Targeted Observable” (DO). The SBG DO is based on the need for capabilities to acquire global, high spatial resolution, visible to shortwave infrared (VSWIR; 380–2500 nm; ~30 m pixel resolution) hyperspectral (imaging spectroscopy) and multispectral midwave and thermal infrared (MWIR: 3–5 μm; TIR: 8–12 μm; ~60 m pixel resolution) measurements with sub-monthly temporal revisits over terrestrial, freshwater, and coastal marine habitats. To address the various mission design needs, an SBG Algorithms Working Group of multidisciplinary researchers has been formed to review and evaluate the algorithms applicable to the SBG DO across a wide range of Earth science disciplines, including terrestrial and aquatic ecology, atmospheric science, geology, and hydrology. Here, we summarize current state-of-the-practice VSWIR and TIR algorithms that use airborne or orbital spectral imaging observations to address the SBG DO priorities identified by the Decadal Survey: (i) terrestrial vegetation physiology, functional traits, and health; (ii) inland and coastal aquatic ecosystems physiology, functional traits, and health; (iii) snow and ice accumulation, melting, and albedo; (iv) active surface composition (eruptions, landslides, evolving landscapes, hazard risks); (v) effects of changing land use on surface energy, water, momentum, and carbon fluxes; and (vi) managing agriculture, natural habitats, water use/quality, and urban development. We review existing algorithms in the following categories: snow/ice, aquatic environments, geology, and terrestrial vegetation, and summarize the community-state-of-practice in each category. This effort synthesizes the findings of more than 130 scientists.

Remote Sensing of Environment

Linking the agricultural landscape of the Midwest to stream health with structural equation modeling

Multiple physical and chemical stressors can simultaneously affect the biological condition of streams. To better understand the complex interactions of land-use practices, water quality, and ecological integrity of streams, the U.S. Geological Survey National Water Quality Assessment Project is conducting regional-scale assessments of stream condition across the United States. In the summer of 2013, weekly water samples were collected from 100 streams in the Midwestern United States. Employing watershed theory, we used structural equation modeling (SEM) to represent a general hypothesis for how 16 variables (previously identified to be important to stream condition) might be inter-related. Again, using SEM, we evaluated the ability of this “stressor network” to explain variations in multimetrics of algal, invertebrate, and fish community health, trimming away any environmental variables not contributing to an explanation of the ecological responses. Seven environmental variables—agricultural and urban land use, sand content of soils, basin area, percent riparian area as forest, channel erosion, and relative bed stability—were found to be important for all three-community metrics. The algal and invertebrate models included water-chemistry variables not included in the fish model. Results suggest that ecological integrity of Midwest streams are affected by both agricultural and urban land uses and by the natural geologic setting, as indicated by the sand content of soils. Chemicals related to crops (pesticides and nutrients) and residential uses (pyrethroids) were found to be more strongly related to ecological integrity than were natural factors (riparian forest, watershed soil character).

Environmental Science & Technology

Pesticides in U.S. streams and rivers: occurrence and trends during 1992-2011

During the 20 years from 1992 to 2011, pesticides were found at concentrations that exceeded aquatic-life benchmarks in many rivers and streams that drain agricultural, urban, and mixed-land use watersheds. Overall, the proportions of assessed streams with one or more pesticides that exceeded an aquatic-life benchmark were very similar between the two decades for agricultural (69% during 1992−2001 compared to 61% during 2002−2011) and mixed-land-use streams (45% compared to 46%). Urban streams, in contrast, increased from 53% during 1992−2011 to 90% during 2002−2011, largely because of fipronil and dichlorvos. The potential for adverse effects on aquatic life is likely greater than these results indicate because potentially important pesticide compounds were not included in the assessment. Human-health benchmarks were much less frequently exceeded, and during 2002−2011, only one agricultural stream and no urban or mixed-land-use streams exceeded human-health benchmarks for any of the measured pesticides. Widespread trends in pesticide concentrations, some downward and some upward, occurred in response to shifts in use patterns primarily driven by regulatory changes and introductions of new pesticides.

Environmental Science & Technology

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Executive summary. In Second State of the Carbon Cycle Report (SOCCR2): A Sustained Assessment Report

Central to life on Earth, carbon is essential to the molecular makeup of all living things and plays a key role in regulating global climate. To understand carbon’s role in these processes, researchers measure and evaluate carbon stocks and fluxes. A stock is the quantity of carbon contained in a pool or reservoir in the Earth system (e.g., carbon in forest trees), and a flux is the direction and rate of carbon’s transfer between pools (e.g., the movement of carbon from the atmosphere into forest trees during photosynthesis). This document, the Second State of the Carbon Cycle Report (SOCCR2), examines the patterns of carbon stocks and fluxes—collectively called the “carbon cycle.” Emphasis is given to these patterns in specific sectors (e.g., agriculture and energy) and ecosystems (e.g., forests and coastal waters) and to the response of the carbon cycle to human activity. The purpose of SOCCR2 is to assess the current state of the North American carbon cycle and to present recent advances in understanding the factors that influence it. Concentrating on North America—Canada, the United States, and Mexico—the report describes carbon cycling for air, land, inland waters (streams, rivers, lakes, and reservoirs), and coastal waters (see Figure ES.1, p. 23). The questions framing the publication A U.S. Carbon Cycle Science Plan (Michalak et al., 2011) inspired development of three slightly modified questions that guide SOCCR2’s content and focus on North America in a global context: How have natural processes and human actions affected the global carbon cycle on land, in the atmosphere, in the ocean and other aquatic systems, and at ecosystem interfaces (e.g., coastal, wetland, and urban-rural)? How have socioeconomic trends affected atmospheric levels of the primary carbon-containing gases, carbon dioxide (CO2) and methane (CH4)? How have species, ecosystems, natural resources, and human systems been impacted by increasing greenhouse gas (GHG) concentrations, associated changes in climate, and carbon management decisions and practices? SOCCR2 synthesizes the most recent understanding of carbon cycling in North America, assessing new carbon cycle findings and information, the state of knowledge regarding core methods used to study the carbon cycle, and future research needed to best inform carbon management and policy options. Focusing on scientific developments in the decade since the First State of the Carbon Cycle Report (SOCCR1; CCSP 2007), SOCCR2 summarizes the past, current, and projected state of carbon sources, sinks, and natural processes, as well as contributions by human activities. In addition to CO2 and CH4, the report sometimes discusses nitrous oxide (N2O), a GHG associated with activities and processes that affect fluxes of carbon gases.1 SOCCR2 also describes improvements in analysis tools; developments in decision support; and new insights into ecosystem carbon cycling, human causes of changes in the carbon cycle, and social science perspectives on carbon. Since publication of SOCCR1, coordinated research from agencies in the three North American countries has enabled innovative observational, analytical, and modeling capabilities to further advance understanding of the North American carbon cycle (see Appendix D: Carbon Measurement Approaches and Accounting Frameworks, p. 834). Some of the report’s main conclusions, based on the Key Findings of each chapter, are highlighted in Box ES.1, Main Findings of SOCCR2, p. 24.

Report

Assessment of general health of fishes collected at selected sites in the Great Lakes Basin In 2012

During the past decade, there has been a substantive increase in the detection of “emerging contaminants”, defined as a new substance, chemical, or metabolite in the environment; or a legacy substance with a newly expanded distribution, altered release, or a newly recognized effect (such as endocrine disruption). Emerging contaminants include substances such as biogenic hormones (human and animal), brominated flame retardants, pharmaceuticals, personal care products, plasticizers, current use pesticides, detergents, and nanoparticles. These contaminants are frequently not regulated or inadequately regulated by state or Federal water quality programs. Information about the toxicity of these substances to fish and wildlife resources is generally limited, compared to more highly regulated contaminants, and some classes have been shown to cause affects (for example feminization of male fish, immunomodulation) that are not evaluated via traditional toxicity testing protocols. As a result, these compounds may pose a substantial, but currently poorly documented threat to aquatic ecosystems. Failure to identify and understand the impacts of these emerging contaminants on fish and wildlife resources may result in deleterious impacts to Great Lakes resources that can result in adverse ecological, economic and recreational consequences. The U. S. Fish and Wildlife Service received funding through the Great Lakes Restoration Initiative (GLRI) for an Early Warning Program to detect and identify emerging contaminants and to evaluate the effects of these contaminants on fish and wildlife. The U.S. Geological Survey (WV Cooperative Fish and Wildlife Research Unit and National Fish Health Research Laboratory, Leetown Science Center) developed and implemented a biological effects monitoring protocol to assist in this program. Fish collections and measurements of biomarkers of exposure in Fall 2010 and Spring 2011 occurred at individual sites within select Areas of Concern (AOCs). They provided an assessment of the utility of the suite of biomarkers and also identified sites for more in-depth analyses. Selected areas are characterized as areas with known emerging contaminants, sensitive or listed species, areas downstream from municipal wastewater discharges or receiving waters for industrial facilities, and/or areas susceptible to agricultural or urban contamination, or harbors or ports. The results of the 2010- 2011 studies were summarized in Blazer et al. 2014 a, b, c; Braham et al. in review and Blazer et al. in review.

Great Lakes

Management case study: Tampa Bay, Florida

Tampa Bay, Florida, USA, is a shallow, subtropical estuary that experienced severe cultural eutrophication between the 1940s and 1980s, a period when the human population of its watershed quadrupled. In response, citizen action led to the formation of a public- and private-sector partnership (the Tampa Bay Estuary Program), which adopted a number of management objectives to support the restoration and protection of the bay’s living resources. These included numeric chlorophyll a and water-clarity targets, as well as long-term goals addressing the spatial extent of seagrasses and other selected habitat types, to support estuarine-dependent faunal guilds. Over the past three decades, nitrogen controls involving sources such as wastewater treatment plants, stormwater conveyance systems, fertilizer manufacturing and shipping operations, and power plants have been undertaken to meet these and other management objectives. Cumulatively, these controls have resulted in a 60% reduction in annual total nitrogen (TN) loads relative to earlier worse-case (latter 1970s) conditions. As a result, annual water-clarity and chlorophyll a targets are currently met in most years, and seagrass cover measured in 2008 was the highest recorded since 1950. Factors that have contributed to the observed improvements in Tampa Bay over the past several decades include the following: (1) Development of numeric, science-based water-quality targets to meet a long-term goal of restoring seagrass acreage to 1950s levels. Empirical and mechanistic models found that annual average chlorophyll a concentrations were a primary manageable factor affecting light attenuation. The models also quantified relationships between TN loads, chlorophyll a concentrations, light attenuation, and fluctuations in seagrass cover. The availability of long-term monitoring data, and a systematic process for using the data to evaluate the effectiveness of management actions, has allowed managers to track progress and make adaptive changes when needed. (2) Citizen involvement, that is, the initial reductions in TN loads, which occurred in the late 1970s and early 1980s, was a result of state regulations that were developed in response to citizens’ call for action. Improved water clarity and better fishing and swimming conditions were identified as primary goals by citizens again in the early 1990s, and led to development of numeric water-quality targets and seagrass restoration goals. More recent citizen actions, from pet waste campaigns to support of reductions in residential fertilizer use, are important elements of the nitrogen management strategy. (3) Collaborative actions, that is, in addition to numerous other collaborative ventures that have benefitted Tampa Bay, the public/private Nitrogen Management Consortium, which includes more than 40 participating organizations, has implemented over 250 nutrient-reduction projects. These projects have addressed stormwater treatment, fertilizer manufacturing and shipping, agricultural practices, reclaimed water use, and atmospheric emissions from local power stations, providing more than 300 tons of TN load reductions since 1995. (4) State and federal regulatory programs, that is, regulatory requirements, such as state statutes and rules requiring compliance with advanced wastewater treatment standards by municipal sewerage works, have played a key role in Tampa Bay management efforts. The technical basis and implementation plan of the Tampa Bay nitrogen management strategy have been developed in cooperation with state and federal regulatory agencies, and the strategy has been recognized by them as an appropriate tool for meeting water-quality standards, including federally mandated total maximum daily loads. Subsequent management efforts have focused on maintaining and extending those improvements in Tampa Bay’s environmental resources by addressing water and sediment quality and habitat protection and restoration. Implementation of a collaborative, watershed-based management process, driven by an integrated science approach, has played a central role in supporting progress toward the achievement of science-based estuary management goals.

Florida

Modeled historical land use and land cover for the conterminous United States

The landscape of the conterminous United States has changed dramatically over the last 200 years, with agricultural land use, urban expansion, forestry, and other anthropogenic activities altering land cover across vast swaths of the country. While land use and land cover (LULC) models have been developed to model potential future LULC change, few efforts have focused on recreating historical landscapes. Researchers at the US Geological Survey have used a wide range of historical data sources and a spatially explicit modeling framework to model spatially explicit historical LULC change in the conterminous United States from 1992 back to 1938. Annual LULC maps were produced at 250-m resolution, with 14 LULC classes. Assessment of model results showed good agreement with trends and spatial patterns in historical data sources such as the Census of Agriculture and historical housing density data, although comparison with historical data is complicated by definitional and methodological differences. The completion of this dataset allows researchers to assess historical LULC impacts on a range of ecological processes.

Journal of Land Use Science

Application and comparison of the MODIS-Derived Enhanced Vegetation Index (EVI) to VIIRS, Landsat 5 TM, and Landsat 8 OLI platforms: A case study in the arid Colorado River Delta, Mexico

The Enhanced Vegetation Index (EVI) is a key Earth science parameter used to assess vegetation, originally developed and calibrated for the Moderate Resolution Imaging Spectroradiometer (MODIS) aboard the Terra and Aqua satellites. With the impending decommissioning of the MODIS sensors by the year 2020/2022, alternative platforms will need to be used to estimate EVI. We compared Landsat 5 (2000–2011), 8 (2013–2016) and the Visible Infrared Imaging Radiometer Suite (VIIRS; 2013–2016) to MODIS EVI (2000–2016) over a 420,083-ha area of the arid lower Colorado River Delta in Mexico. Over large areas with mixed land cover or agricultural fields, we found high correspondence between Landsat and MODIS EVI (R 2 = 0.93 for the entire area studied and 0.97 for agricultural fields), but the relationship was weak over bare soil (R 2 = 0.27) and riparian vegetation (R 2 = 0.48). The correlation between MODIS and Landsat EVI was higher over large, homogeneous areas and was generally lower in narrow riparian areas. VIIRS and MODIS EVI were highly similar (R 2 = 0.99 for the entire area studied) and did not show the same decrease in performance in smaller, narrower regions as Landsat. Landsat and VIIRS provide EVI estimates of similar quality and characteristics to MODIS, but scale, seasonality and land cover type(s) should be considered before implementing Landsat EVI in a particular area.

Colorado River Delta

Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States

Science data in support of environmental health studies in the U.S.-Mexico border region

The border region of the United States and Mexico encompasses a vast and diverse array of physical settings and habitats that include wetlands, deserts, rangeland, mountains, and forests, which are unique in terms of the diversity of their water, mineral, and biological resources. The region is interconnected economically, politically, and socially owing to its binational heritage. In 1995, nearly 11 million people lived immediately adjacent to the border. By one account, that population could more than double by 2020. This rapid population growth and consequent economic development and land-use changes are pushing the limits of environmental sustainability and quality. Infrastructure development has lagged behind the rapid growth of the region, resulting in a shortage of water for municipal, agricultural, and industrial uses. These stressors threaten the quality of life in the region and raise concerns about the interdependence of environmental quality and human health. To allow for continued economic growth while protecting the area’s natural resources and fostering a high quality of life, the United States and Mexico need an improved understanding of the threats posed by these anthropogenic changes. Issues of particular concern include (1) contaminants in ground water, surface water, and biota from agricultural, municipal, and industrial activities; (2) airborne pollutants from fossil-fuel combustion and other activities; (3) contaminants from past and present mining activities and mineral deposits; and (4) pathogens, pharmaceuticals, hormones, and other contaminants released in treated and untreated human and animal wastewaters.

Fact Sheet

Annotated bibliography of scientific research on Taeniatherum caput-medusae published from January 2010 to January 2022

Integrating recent scientific knowledge into management decisions supports effective natural resource management and can lead to better resource outcomes. However, finding and accessing scientific knowledge can be time consuming and costly. To assist in this process, the U.S. Geological Survey is creating a series of annotated bibliographies on topics of management concern for western lands. Previously published reports introduced a methodology for preparing annotated bibliographies to facilitate the integration of recent, peer-reviewed science into resource management decisions. Therefore, relevant text from those efforts is reproduced here to frame the presentation. Invasive annual grasses are widely distributed throughout the western United States and threaten native ecosystems by altering fire regimes, replacing native plants, and altering grazing patterns, often with tremendous associated costs. One invasive annual grass, Taeniatherum caput-medusae (hereafter, medusahead), was first documented in the United States in 1887 and has been identified as a species of management concern. Medusahead’s life history traits allow it to quickly and effectively dominate native plant communities, and it has already taken over millions of acres in western North America. Although medusahead can spread widely and disrupt ecosystem function, it has been studied less than other western invasive grass species. We compiled and summarized peer-reviewed journal articles, data products, and formal technical reports (such as U.S. Department of Agriculture Forest Service General Technical Reports and U.S. Geological Survey Open-File Reports) on medusahead, published between January 2010 and January 2022. We first performed a systematic search of three reference databases and three government databases using the search phrase “medusahead” OR “medusa head” OR “ Taeniatherum caput-medusae ” OR “ Taeniatherum caputmedusae ” OR “ Taeniatherum asperum .” We refined the initial list of products by removing (1) duplicates, (2) products not written in English, (3) publications that were not focused on North America, (4) publications that were not published as research, data products, or scientific review articles in peer-reviewed journals or as formal technical reports, and (5) products for which medusahead was not a research focus, or the study did not present new data or findings about medusahead. We summarized each product using a consistent structure (background, objectives, methods, location, findings, and implications) and identified the management topics (for example, species and population characteristics; habitat; and control and management efforts) addressed by each product. We also noted which publications included new geospatial data. The review process for this annotated bibliography included an initial internal colleague review of each summary, requesting input on each summary from an author of the original publication, and a formal peer review. Our initial searches resulted in 4,245 total products, of which 211 met our criteria for inclusion. The most commonly addressed management topics addressed in products summarized in the annotated bibliography were as follows: nonnative invasive plants, weed management, site-scale habitat characteristics, habitat restoration or reclamation, and cultural management of weeds. All published bibliographies, including the online version of this bibliography, are available at the Science for Resource Managers ( https://apps.usgs.gov/science-for-resource-managers ). This database is searchable by topic, location, and year and includes links to each original publication. The studies compiled and summarized here may inform planning and management actions that seek to maintain and restore sagebrush landscapes and associated native species across the western United States.

Open-File Report