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At least 271 records · Page 15Linked to original sources

Establishing major permeability controls in the Mak-Ban geothermal field, Philippines

Recent updating of the conceptual model of the Mak-Ban (Bulalo) geothermal field verified both structural and stratigraphic controls on permeability and connectivity in the reservoir. Two silicic units within the predominantly andesitic production zone were identified from borehole logs, core and drill cuttings. Whole rock chemical data and petrographic analysis confirmed two rhyolite units that consist of partially welded ash-flow tuffs and lava with primary devitrification and vapor-phase alteration textures typical of subaerial rhyolites. U/Pb dating of zircons from the units showed two distinct episodes of silicic volcanism at 352 ± 16 ka and 501 ± 12 ka, respectively. A recent drilling campaign allowed the running of more gamma ray (GR) in tandem with PTS logs. The logs validated the presence of two units with high GR response generally coinciding with permeable zones just below the interpreted top of the reservoir. Naphthalene disulfonate tracer testing defined a predominantly fault-controlled flow path of fluids from the edges of the field into the central production area. Fifteen to 25% of injected tracers were recovered in production wells over a five-year monitoring period. Peak arrival of tracer returns indicated average speeds between 0.1 to 1.3 m/hr, allowing for sufficient time for the fluids to heat up prior to re-emergence in production wells. Although faults are known to be important pathways in most geothermal reservoirs, the identification of specific structures with high connectivities in Mak-Ban provide an important insight on fluid migration from peripheral areas. This information is critical in preparing a reservoir management strategy for addressing the entry of cool marginal recharge into the center of the field.

Mak-Ban geothermal field↗

Geology of the Bighorn Mountains

This report is the result of studies made in the field during the seasons of 1901, 1902, 1903, 1904, and 1905. It relates to an area of about 9,000 square miles, situated mainly in the north-central portion of Wyoming and extending northward into Montana. Its location and general surroundings are shown on PL II. It covers the greater portion of the Bighorn uplift, together with an adjoining area of the Great Plains on the east. It also includes a small part of the Bighorn Basin and the eastern end of the Bridger Range. The report describes the various rocks, their structure, history, and mineral resources, including underground water, coal, gypsum, and various other products. It also contains information as to surface waters available for irrigation. Throughout the work assistance has been rendered by Mr. C. A. Fisher, who mapped portions of the area, measured numerous sections, collected fossils, and examined most of the crystalline rocks; and the author is indebted to Mr. Albert Johannsen for some of the petrographic descriptions. Previous observers have given but little information regarding the geology of the Bighorn Mountains, though Dr. F. V. Hayden ascertained the general relations of the uplift in his exploration of the Northwest, and Mr. George H. Eldridge, who crossed the range near Bald Mountain and southwest of Buffalo during the summer of 1893, described 0 some of the broader features of the geologic succession and structure in a remarkably comprehensive manner, considering how small an area he had the opportunity to examine. The Bighorn region is very thinly settled, there being no permanent habitations among the mountains, and it is but little visited by others than hunters, prospectors, and herders. There have recently been established two summer resorts in the mountains, and each year a larger number of persons visit the region. Unfortunately the mineral prospects have proved disappointing to the prospectors, and there appears to be but little promise that the area will become important on account of its mineral resources. In the Bridger uplift promising prospects of gold and copper have recently been discovered, which may prove of value. There are extensive, forests in the mountains, which are now included in a Government forest reserve, but their timber is not of great value. Much of the area below timber line contains an abundance of luxuriant grasses and other plants, which afford excellent pasturage for stock, and large herds of sheep and cattle are ranged in the region during the short summer season. Game is moderately abundant, and most of the streams contain large numbers of trout. The region is one of great interest geologically on account of its variety of sedimentary rocks, interesting structure, and remarkably instructive glacial features. The central area, with its high peaks, presents alpine scenery of notable character. Doubtless in the future the region will be extensively visited by tourists, hunters, and geologists.

Montana, Wyoming↗

Geochemical evolution of a high arsenic, alkaline pit-lake in the Mother Lode Gold District, California

The Harvard orebody at the Jamestown gold mine, located along the Melones fault zone in the southern Mother Lode gold district, California, was mined in an open-pit operation from 1987 to 1994. Dewatering during mining produced a hydrologic cone of depression; recovery toward the premining ground-water configuration produced a monomictic pit lake with alkaline Ca-Mg-HCO 3 -SO 4 –type pit water, concentrations of As up to 1,200 μ g/L, and total dissolved solids (TDS) up to 2,000 mg/L. In this study, pit-wall rocks were mapped and chemically analyzed to provide a context for evaluating observed variability in the composition of the pit-lake waters in relationship to seasonal weather patterns. An integrated hydrogeochemical model of pit-lake evolution based on observations of pit-lake volume, water composition (samples collected between 1998–2000, 2004), and processes occurring on pit walls was developed in three stages using the computer code PHREEQC. Stage 1 takes account of seasonally variable water fluxes from precipitation, evaporation, springs, and ground water, as well as lake stratification and mixing processes. Stage 2 adds CO 2 fluxes and wall-rock interactions, and stage 3 assesses the predictive capability of the model. Two major geologic units in fault contact comprise the pit walls. The hanging wall is composed of interlayered slate, metavolcanic and metavolcaniclastic rocks, and schists; the footwall rocks are chlorite-actinolite and talc-tremolite schists generated by metasomatism of greenschist-facies mafic and ultramafic igneous rocks. Alteration in the ore zone provides evidence for mineralizing fluids that introduced CO 2 , S, and K 2 O, and redistributed SiO 2 . Arsenian pyrite associated with the alteration weathers to produce goethite and jarosite on pit walls and in joints, as well as copiapite and hexahydrite efflorescences that accumulate on wall-rock faces during dry California summers. All of these pyrite weathering products incorporate arsenic at concentrations from <100 up to 1,200 ppm. In the pit lake, pH and TDS reach seasonal highs in the summer epilimnion; pH is lowest in the summer hypolimnion. Arsenic and bicarbonate covary in the hypolimnion, rising as stratification proceeds and declining during winter rains. The computational model suggests that water fluxes alone do not account for this seasonal variability. Loss of CO 2 to the atmosphere, interaction with pit walls including washoff of efflorescent salts during the first flush and seasonal rainfall, and arsenic sorption appear to contribute to the observed pit-lake characteristics.

California↗

Gold, base-metal, and related deposits of North Carolina

Gold, silver, copper, lead, zinc, pyrite, tin, cobalt, molybdenum, tungsten, barite, and rare-earths have been mined in North Carolina. Gold, with by-product silver, occurs in veins and mineralized shear zones in metamorphic rocks of the Piedmont province and in placers derived from these deposits. Copper occurs with complex sulfide ores in quartz veins in the metamorphic rocks of the Piedmont province and in massive pyrrhotite-pyrite deposits in crystalline rocks west of the Blue Ridge. Lead and zinc occur in complex ores of gold, copper, lead, zinc, and silver in veins and replacements in metamorphic rocks. Pyrite occurs in crystalline metamorphic rocks. Tin occurs in pegmatite and placer deposits in crystalline rocks near Kings Mountain. Cobalt minerals with ores of iron or gold have been reported in a few areas in the Piedmont. Molybdenum occurs along the borders of a granite body in Halifax County. Tungsten minerals occur with copper sulfide ores in Cabarrus and Vance Counties. Barite occurs in quartz veins and associated with sulfide minerals in Orange, Madison, Cleveland, and Gaston Counties. Ore-earths occur with sulfides in vein deposits in Cabarrus County.

Open-File Report↗

Potentiometric surface of the Upper Floridan aquifer in Florida and parts of Georgia, South Carolina, and Alabama, May &ndash; June 2010

The Floridan aquifer system covers nearly 100,000 square miles in the southeastern United States throughout Florida and in parts of Georgia, South Carolina, and Alabama, and is one of the most productive aquifers in the world (Miller, 1990). This sequence of carbonate rocks is hydraulically connected and is over 300 feet thick in south Florida and thins toward the north. Typically, this sequence is subdivided into the Upper Floridan aquifer, the middle confining unit, and the Lower Floridan aquifer. The majority of freshwater is contained in the Upper Floridan aquifer and is used for water supply (Miller, 1986). The Lower Floridan aquifer contains fresh to brackish water in northeastern Florida and Georgia, while in south Florida it is saline. The potentiometric surface of the Upper Floridan aquifer in May&ndash;June 2010 shown on this map was constructed as part of the U.S. Geological Survey Floridan Aquifer System Groundwater Availability Study (U.S. Geological Survey database, 2011). Previous synoptic measurements and regional potentiometric maps of the Upper Floridan aquifer were prepared for May 1980 (Johnston and others, 1981) and May 1985 (Bush and others, 1986) as part of the Floridan Regional Aquifer System Analysis.

Alabama, Florida, Georgia, South Carolina↗

Ground-water provinces of southern Rhodesia

Ground-water development, utilization, and occurrence in nine ground-water provinces of Southern Rhodesia are summarized in this report. Water obtained from drilled wells for domestic and stock use has played an important part in the social and economic development of Southern Rhodesia from the beginnings of European settlement to the present. Most of the wells obtain water from fractures and weathered zones in crystalline rocks, before recently, there has been an interest in the possibility of obtaining water for irrigation from wells. Studies of the authors indicate that quantities of water sufficient for irrigation can be obtained from alluvial sediments in the S'abi Valley, from Kalahari sands in the western part of the country, are perhaps from aquifers in other areas. The ground-water provinces fall into two groups--those in the crystalline rocks and those in the noncrystalline rocks. Historically, the wells in crystalline rocks, especially the Gold belts province and the Intrusive granites province, have played a major role in supplying water for the needs of man. These provinces, together with two other less important crystalline rock provinces, form the broad arch which constitutes the central core of the country. The noncrystalline rocks overlie and flank the crystalline rocks to the southeast, northwest, and north. The noncrystalline rock provinces, especially the Alluvium-Kalahari province, contain the most productive or potentially productive ground-water reservoirs in Southern Rhodesia and offer promise of supplying water for irrigation and for other purposes.

Water Supply Paper↗

A review of silver-rich mineral deposits and their metallogeny

Mineral deposits with large inventories or high grades of silver are found in four genetic groups: (1) volcanogenic massive sulfide (VMS), (2) sedimentary exhalative (SEDEX), (3) lithogene, and, (4) magmatichydrothermal. Principal differences between the four groups relate to source rocks and regions, metal associations, process and timing of mineralization, and tectonic setting. These four groups may be subdivided into specific metal associations on ternary diagrams based on relative metal contents. The VMS deposits rarely contain more than 15,600 t Ag (500 Moz). Grades average 33 g/t Ag. Variable Ag- Pb-Zn-Cu-Au ± Sn concentrations are interpreted as having been derived both from shallow plutons and by leaching of the volcanic rock pile in regions of thin or no continental crust and the mineralization is syngenetic. Higher silver grades are associated with areas of abundant felsic volcanic rocks. The SEDEX deposits rarely contain more than 15,600 t Ag (500 Moz). Grades average 46 g/t Ag. Silver, lead, and zinc in relatively consistent proportions are leached from sedimentary rocks filling rift-related basins, where the continental crust is thin, and deposited as syngenetic to diagenetic massive sulfides. Pre-mineral volcanic rocks and their detritus may occur deep within the basin and gold is typically absent. Lithogene silver-rich deposits are epigenetic products of varying combinations of compaction, dewatering, meteoric water recharge, and metamorphism of rift basin-related clastic sedimentary and interbedded volcanic rocks. Individual deposits may contain more than 15,600 t Ag (500 Moz) at high grades. Ores are characterized by four well-defined metal associations, including Ag, Ag-Pb-Zn, Ag-Cu, and Ag-Co-Ni-U. Leaching, transport, and deposition of metals may occur both in specific sedimentary strata and other rock types adjacent to the rift. Multiple mineralizing events lasting 10 to 15 m.y., separated by as much as 1 b.y., may occur in a single basin. Gold is absent at economic levels. The magmatic-hydrothermal silver-rich deposits are epigenetic and related to cordilleran igneous and volcanic suites. Six magmatic-hydrothermal districts each contain more than 31,000 t Ag (1,000 Moz) with grades of veins >600 g/t Ag. Mineralization occurs as veins, massive sulfides in carbonate rocks, and disseminated deposits including porphyry silver deposits, a proposed exploration model. Most deposits are epithermal with low-sulfidation alteration assemblages. Deposits are often telescoped and well-zoned. All large and high-grade magmatic-hydrothermal deposits appear confined to regions of relatively thick continental crust above Cenozoic consuming plate margins on the eastern side of the Pacific Rim. Silver in these deposits may be partly derived by hydrothermal leaching of rocks under or adjacent to the deposits. Specific metal associations in SEDEX and lithogene deposits may reflect confinement of fluid flow to and derivation of metals from specific source rock types. Variable metal associations in VMS and magmatichydrothermal deposits may reflect derivation of metals from a more diverse suite of rocks by convecting hydrothermal systems and processes related to the generation of magma. The discovery rate for silver-rich deposits has accelerated during the past decade, with new deposit types, metal associations, and exploration models being identified that provide numerous exploration and research opportunities.

Book chapter↗

Gas hydrate saturation estimation from acoustic log data in the 2018 Alaska North Slope Hydrate-01 stratigraphic test well

Completed in December 2018, the Alaska North Slope Hydrate 01 stratigraphic test well provides a wealth of logging-while-drilling (LWD) data for strata to below the base of gas hydrate stability (BGHS). This well is intended to be the first of three wells drilled for a long-term gas hydrate production test to be conducted by the U.S. Department of Energy National Energy Technology Laboratory, the Japan Oil, Gas and Metals National Corporation, and the U.S. Geological Survey (USGS). The Hydrate 01 stratigraphic test well confirmed the presence of gas hydrate in two sand reservoirs within the hydrate stability zone, indicating the suitability of this location for a long-term gas hydrate production test. The USGS, using an effective-medium-theory rock-physics approach, has estimated gas hydrate saturations from compressional (P) and shear (S) wave log data acquired in the Hydrate 01 well. We assume that gas hydrate occurs as pore-filling load-bearing material (i.e., part of the grain matrix). For Unit D, approximately 500 feet above the BGHS, both P-wave and S-wave acoustic logs indicate high gas hydrate saturations with S-wave results slightly lower than those for P-waves. For Unit B, located just above the BGHS, we obtain high gas hydrate saturation estimates from both sonic logs. Our P-wave saturation estimates agree well with results from electrical-resistivity-based estimates, whereas estimates from nuclear magnetic resonance LWD data generally suggest 5 to 10 percent higher saturations; our S-wave results suggest lower saturations. These differences likely indicate complexities in the form of gas hydrate occurrence within the sediment pore space, potentially including differences between hydrate occurrence in Units B and D.

Alaska↗

Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo 72−84 ) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo 57−78 ). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO 2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO 2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.

Grey Porri Tuff;Monte Dei Porri;Salina;Aeolian Isl↗

The transition from melt accumulation to eruption initiation recorded by orthopyroxene Fe-Mg diffusion timescales in late Holocene rhyolites, South Sister volcano, Oregon Cascade Range

South Sister volcano, Oregon Cascade Range, USA, has repeatedly erupted rhyolite since ca. 40 ka. The youngest such eruptions are the ca. 2 ka Rock Mesa and Devils Chain rhyolites, erupted several hundred years apart from two multi-vent complexes separated by 3–6 km. Fe-Mg interdiffusion models of orthopyroxene rims from both rhyolites produce timescales up to several-thousand years, but dominantly decades-to-centuries. Notably, the timescales of step-normal zoned orthopyroxene rims (i.e., normally zoned with a steep chemical gradient) from the Rock Mesa rhyolite are longer than those of reversely zoned crystals, whereas the Devils Chain produced mostly decadal timescales for both zoning types. Despite the proximity and broadly similar products of these episodes, their respective timescales indicate distinct sequences of events leading up to each eruption. The Rock Mesa timescales record centuries of magma chamber growth followed by decades of predominantly magma rejuvenation, reorganization, and destabilization. In contrast, the Devils Chain episode was preceded by a single episode of coupled rhyolite extraction, rejuvenation, and hybridization. Rare, high-An plagioclase cores and evidence of reheating implicate cryptic emplacement of mafic magma at the base of the rhyolite reservoirs. However, the diffusion timescales do not unequivocally support a single magma recharge event that affected both. Fluid fluxing and the reorganization of melt into buoyant magma chambers likely provided the source of increasing pressurization that initiated each eruption after several decades. Geodetic models of ongoing deformation west of South Sister could consider these processes in addition to magma emplacement.

Oregon↗

Geology and uranium-vanadium deposits of the slick rock district, San Miguel and Dolores counties, Colorado

Sedimentary rocks known in the Slick Rock district in southwestern Colorado range in age from Devonian (?) to Cretaceous, and aggregate about 13,000 feet in maximum thickness. Important uranium-vanadium production has come from deposits in the Salt Wash member of the Morrison formation of Late Jurassic age. The sedimentary rocks are gently folded in the Dolores and Glade anticlines and the Disappointment syncline, and are cut by the Dolores fault zone in the north part of the district and by the Glade fault zone in the south part of the district . Principal fracture sets are oriented approximately parallel to the major faults. Detrital hematite, magnetite, and ilmenite in rocks of the Morrison formation not affected by epigenetic alteration contain appreciable amounts of several of the elements found in the ore deposits . Epigenetic alteration processes have bleached large volumes of rock and largely destroyed these minerals. Such alteration is spatially associated with the Dolores fault zone. Most of the known ore deposits are in the north part of the Slick Rock district in a belt called the Dolores ore zone. The zone lies along the Dolores fault zone but is wider than the fault zone. All known deposits are associated with abundant carbonaceous plant material. Uranium-vanadium deposits in the district are chiefly tabular to lenticular and are roughly parallel to the sedimentary bedding. Some ore bodies, however, are narrow, elongate, and curve sharply across bedding; these bodies have been called "rolls" by the miners. Mineral zoning is evident in some roll bodies; carbonates, goethite (altered from pyrite), selenides, and sulfides are commonly found in concentric layers at the concave edge of rolls. This zoning, and the relationship of roll ore bodies to sedimentary structures and lithology, suggest that ore was deposited at an interface between two solutions, possibly cool connate water and a warmer ore solution. On a district scale, copper and lead are distinctly most abundant in the ore deposits within and immediately adjacent to the Dolores fault zone, and less abundant in deposits toward the edge of the zone. Uranium-vanadium deposits in the district occur only in sandstone that is considered to be epigenetically altered, and the most extensive epigenetic changes have occurred close to ore bodies. It is concluded that ground water, heated and set into circulation near the end of Cretaceous time by igneous intrusions in the La Sal and other centers on the Colorado Plateau, picked up elements from sedimentary rocks where they had been faulted and fractured, and deposited the elements at solution interfaces where accumulations of carbonaceous material provided favorable chemical conditions for precipitation.

Colorado, Utah↗

Geothermal brine well: Mile-deep drill hole may tap ore-bearing magmatic water and rocks undergoing metamorphism

A deep geothermal well in California has tapped a very saline brine extraordinarily high in heavy metals and other rare elements; copper and silver are precipitated during brine production. Preliminary evidence suggests that the brine may be pure magmatic water and an active ore-forming solution. Metamorphism of relatively young rocks may also be occurring within accessible depths.

California↗

The modern muds of Laguna Mar Chiquita (Argentina): Particle size and geochemical trends from a large saline lake in the "thick-skinned" Andean foreland

Laguna Mar Chiquita (central Argentina; ~latitude 31°S, longitude 63°W) provides an outstanding opportunity to examine organic facies development and petroleum source-rock potential in a modern thick-skinned foreland basin lake. In this case study, we define profundal, paleodelta, and lake-margin depositional environments based on trends in bathymetry and lake-floor sediment particle size. Sedimentary geochemical analyses indicate that organic carbon–rich muds accumulate in profundal environments during the extant lake-level highstand. The lateral variability of organic facies is minimal. The quality of organic facies is controlled by lake level and depositional environment, both of which dictate patterns of algal productivity, siliciclastic dilution, and early diagenesis. We present conceptual models of lacustrine source rocks in both thick-skinned and thin-skinned foreland basins based on modern analog data from both Laguna Mar Chiquita and other lakes in the central Andean foreland. Over relatively short time intervals (10 2 –10 4 yr), climatically driven water-level fluctuations influence the source-rock potential of these basins. Over time intervals >10 5 yr, contraction and lateral migration of the basin flexural profile control stratal stacking patterns and the potential for hydrocarbon play development.

Laguna Mar Chiquita↗

Qingshankou-Putaohua/Shaertu and Jurassic Coal-Denglouku/Nongan total petroleum systems in the Songliao Basin, China

The Qingshankou-Putaohua/Shaertu petroleum system involves the generation of oil and gas from a mature pod of lacustrine source rock near the center of the Songliao Basin in northeastern China. The primary source rock is the Lower Cretaceous Qingshankou Formation, and a secondary source rock is Member 1 of the Lower Cretaceous Nenjiang Formation. The most productive of six sandstone reservoirs are the Putaohua reservoir (Member 1 of the Lower Cretaceous Yaojia Formation) and the Shaertu reservoir (Members 2 and 3 of the Yaojia Formation and Member 1 of the Nenjiang Formation). Most oil and associated gas generated from the Qingshankou Formation and Nenjiang Formation (Member 1) are trapped in large faulted anticlines, fault blocks, and faulted anticlinal noses in combination with facies-change and (or) diagenetic stratigraphic traps. Two assessment units are defined in the petroleum system: (1) an anticlinal assessment unit; and (2) a subtle-traps assessment unit consisting of (a) anticlinal noses in combination with fault or stratigraphic traps, (b) stratigraphic traps, and (c) unconventional reservoirs. Undiscovered conventional oil and gas resources are expected in both assessment units in small (5?10 million barrels of oil; 30?60 billion ft3 gas) and medium (10?25 million barrels of oil; 60?150 billion ft3 of gas) fields. Also, undiscovered conventional oil and gas resources are expected in several large fields (25?73 million barrels of oil; 150?173 billion ft3 of gas). The Jurassic coal?Dengloukou/Nongan petroleum system involves the generation of natural gas from multiple pods of mature source rock in graben structures at the base of the Songliao Basin. Sandstone and conglomeratic sandstone in the Lower Cretaceous Denglouku Formation and the Lower Cretaceous Quantou Formation are the major reservoir rocks. Most of the known natural gas is trapped in anticlines, anticlinal noses, and fault blocks. This petroleum system is largely unexplored in comparison to the Qingshankou-Putaohua/Shaertu petroleum system and has good potential for undiscovered gas in the structural traps assessment unit. Undiscovered conventional gas is expected in small (30?60 billion ft3 of gas), medium (60?150 billion ft3 of gas), and large (150?395 billion ft3 of gas) fields. The U.S. Geological Survey World Energy Assessment Team (2000) estimated that the Songliao Basin has, at a mean value, about 1.03 billion barrels of undiscovered conventional oil resources and 5.71 trillion ft3 of undiscovered conventional gas resources.

Bulletin↗

The advantages of electric-grade heat storage in long closed-loop wells

Though long (e.g., tens of kilometers) closed-loop geothermal wells are under consideration for the extraction of subsurface heat, these wells might also serve as an efficient energy storage mechanism for electricity generation. Using a semi-analytic model solution, the potential for electric-grade heat storage as a function of ambient temperature (e.g., corresponds to depth of loop), well length, well diameter, and flow rate is evaluated. The following simplified cases for comparison of standard closed loop operation with energy storage operation were considered: [1] constant flow rate and constant temperature (90 °C) injection to represent the standard closed-loop base-case; and [2] constant flow rate and annual cycle sinusoidal temperature (90-150 °C) to represent seasonal (summer) charging while solar resources are peak. Initial temperatures for all scenarios considered herein are a uniform 175 °C. Electric-grade heat is assumed to be delivered whenever temperatures at the extraction point exceed 90 °C. For calculation purposes only, if temperature falls below 100 °C, it is assumed that heat delivered is sub-economic, so no electricity would be produced. For all scenarios, temperatures at the extraction well asymptotically approach the flow-weighted average injection temperature, but energy storage scenarios exhibited a damped time-varying signal that diminishes in magnitude with length of the loop. The asymptotic approach depends on initial temperatures in the rock and the heat extraction rate (a function of well diameter and flowrate). This analysis demonstrates that shorter closed loops can produce more electricity over time than longer closed-loops previously proposed for electricity production over typical engineering design lifetimes (e.g., 30 years). Although only a high-temperature scenario is considered herein, rock that is initially below boiling temperature would not host a standard closed-loop resource, but injection of hot water seasonally would asymptotically heat this low-temperature system to temperatures capable of electricity production. In other words, regardless of initial temperatures, closed loops could be used to store electricity with no critical minerals in the geothermal battery.

Conference Paper↗

Scheelite in the precambrian gneisses of Colorado

Scheelite of Precambrian age has been found at several localities in Colorado and Wyoming in recent years. Most of it is disseminated in regionally metamorphosed rocks, principally in calc-silicate gneiss , but also in amphibolite. Small amounts are found in pegmatites and in gold-or copper-quartz veins of Precambrian age. The scheelite in most of the deposits contains molybdenum, and much of it is accompanied by discrete powellite (CaMoCX). The scheelite deposits vary in age with the rocks that contain them and show no consistent genetic associations. Many of the deposits are products of some phase of the major plutonic stage that included regional metamorphism, migmatization, and emplacement of syntectonic granites, A few deposits may be related to younger Precambrian granites, and some are related to late diorite and pegmatite. Tungsten originally present in minor concentration in the sedimentary rocks that gave rise to the gneisses was evidently redistributed and r eery stall ized through successive Precambrian plutonic episodes. Reworked Precambrian deposits may have been a source of the tungsten in the economically important Tertiary deposits, and possibly also of molybdenum. The Precambrian scheelite deposits found thus far have proved to be of minor economic importance, but others are still being found, and many more can be presumed to exist; among these may be some of importance.

Colorado↗

Supergene iron ores of minas Gerais, Brazil

The iron ores of Minas Gerais , Brazil , fall into two categories: (1) hypogene hematite ore averaging 66 percent or more Fe, and (2) lower-grade supergene ores . Most ore now extracted is high-grade hypogene ore ; lower-grade supergene ores will be of much future value. All supergene ores formed by weathering of itabirite, a metamorphosed oxide-facies iron formation averaging about 38 percent Fe and 44 percent Si02. The Caue Itabirite crops out for about 540 linear kilometers in central Minas Gerais . Supergene ores fall into three intergradational categories: (1) enriched itabirite, averaging 49 percent Fe, easily con-centratable, with reserves about 25,000 million tons; (2) intermediate grade ores , averaging perhaps 63 percent Fe, with indicated and inferred reserves more than 600 million tons; and (3) canga, averaging between 57 and 62 percent Fe, with reserves in the hundreds of millions of tons. Disaggregation of hard and brittle itabirite by solution primarily of quartz and secondarily of other soluble constituents causes residual enrichment in iron with minor hydration of hematite. As weathering continues, most of the quartz is removed and more of the hematite is hydrated, producing intermediate grade ore . Secondary enrichment by limonite is important. The final weathering product is canga. In canga, almost all the iron is hydrated, and the rock is still further impoverished in Si02 and residually enriched in A1203 and P. Canga also forms by cementation of iron -rich detritus by limonite. Four factors control the supergene ore -forming process: (1) physiography, for ores occur on ridges and plateaus; (2) climate, for seasonal rainfall is apparently needed for the formation of extensive canga blankets; (3) grain size of the original itabirite, for quartz with a grain size much greater than 0.1 millimeter is not readily soluble; and (4) composition of the iron formation. The chemically inert and physically resistant canga blanket is essential to supergene ore formation because soft weathering products would otherwise be removed as fast as formed. Thus, canga gives time for the formation of other ore types. Iron fixed as cementing limonite in canga and as enriching limonite in intermediate grade ore was derived by leaching and hydration of hematite from itabirite. It probably moved in the ferrous state and was precipitated as insoluble hydrous ferric oxide primarily by oxygenation of the solutions, to a lesser extent by their evaporation at or near the surface, and to a still smaller degree by pH changes. The data show that the high-grade hematite ore , 66 percent Fe or higher, cannot have formed directly by supergene action. Geochemical processes resulting in supergene concentration of iron also concentrated alumina and phosphorus. The high-grade ore contains about the same low percentages of these materials as unweathered itabirite.

Minas Gerais↗

Lithofacies, Age, and Sequence Stratigraphy of the Carboniferous Lisburne Group in the Skimo Creek Area, Central Brooks Range

The Lisburne Group, a mainly Carboniferous carbonate succession that is widely distributed across northern Alaska, contains notable amounts of oil and gas at Prudhoe Bay. Detailed studies of the Lisburne in the Skimo Creek area, central Brooks Range, delineate its lithofacies, age, conodont biofacies, depositional environments, and sequence stratigraphy and provide new data on its hydrocarbon source-rock and reservoir potential, as well as its thermal history, in this area. We have studied the Lisburne Group in two thrust sheets of the Endicott Mountains allochthon, herein called the Skimo and Tiglukpuk thrust sheets. The southern, Skimo Creek section, which is >900 m thick, is composed largely of even-bedded to nodular lime mudstone and wackestone intercalated with intervals of thin- to thick-bedded bioclastic packstone and grainstone. Some parts of the section are partially to completely dolomitized and (or) replaced by chert. A distinctive, 30-m-thick zone of black, organic-rich shale, lime mudstone, and phosphorite is exposed 170 m below the top of the Lisburne. The uppermost 40 m of section is also distinctive and made up of dark shale, lime mudstone, spiculite, and glauconitic grainstone. The northern, Tiglukpuk Creek section, which is similar to the Skimo Creek section but only ~760 m thick, includes more packstone and grainstone and less organic-rich shale. Analyses of conodonts and foraminifers indicate that both sections range in age from late Early Mississippian (Osagean) through Early Pennsylvanian (early Morrowan) and document a hiatus of at least 15 m.y. at the contact between the Lisburne and the overlying Siksikpuk Formation. No evidence of subaerial exposure was observed along this contact, which may represent a submarine erosional surface. Lithofacies and biofacies imply that the Lisburne Group in the study area was deposited mainly in midramp to outer-ramp settings. Deepest water strata are mud rich and formed below storm or fair-weather wave base on the outer ramp to outer midramp; shallowest facies are storm, sand-wave, and shoal deposits of the inner midramp to inner ramp. A relatively diverse, open-marine fauna occurs throughout much of the Lisburne in the study area, but some beds also contain clasts typical of more restricted, shallow-water environments that were likely transported seaward by storms and currents. Radiolarians are abundant in the shale and phosphorite unit at Skimo Creek and also occur in equivalent strata at Tiglukpuk Creek; high gamma-ray response and elevated total organic-carbon contents (max 5?8 weight percent) also characterize this unit at Skimo Creek. Lithologic, faunal, and geochemical data all suggest that these rocks formed mainly in an outer-ramp to basinal setting with low sedimentation rates, high productivity, and poorly oxygenated bottom water. Shale and mudstone at the top of the Lisburne Group accumulated in a similarly sediment starved, mainly outer ramp environment but lack comparable evidence for high nutrient and low oxygen levels during deposition. Vertical shifts in rock types and faunas delineate numerous parasequences and six probable third-order sequences in the study area; the same sequences are also recognized in the Lisburne Group to the east. Transgressive-system tracts in these sequences generally fine upward, whereas highstand-system tracts coarsen upward. Sequences in the Tiglukpuk Creek section are mostly thinner, contain thinner and more numerous parasequences, and accumulated in somewhat shallower settings than those in the Skimo Creek section. These differences reflect the more seaward position and, thus, increased accommodation space of the Skimo Creek section relative to the Tiglukpuk Creek section during deposition. Organic-rich calcareous shale in the shale and phosphorite unit has a cumulative thickness of at least 15 m and a lateral extent of >50 km; this lithology is the best potential hydrocarbon source rock in the Lisburne Group

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