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Platinum-group elements

The platinum-group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium, and osmium—are metals that have similar physical and chemical properties and tend to occur together in nature. PGEs are indispensable to many industrial applications but are mined in only a few places. The availability and accessibility of PGEs could be disrupted by economic, environmental, political, and social events. The United States net import reliance as a percentage of apparent consumption is about 90 percent. PGEs have many industrial applications. They are used in catalytic converters to reduce carbon monoxide, hydrocarbon, and nitrous oxide emissions in automobile exhaust. The chemical industry requires platinum or platinum-rhodium alloys to manufacture nitric oxide, which is the raw material used to manufacture explosives, fertilizers, and nitric acid. In the petrochemical industry, platinum-supported catalysts are needed to refine crude oil and to produce aromatic compounds and high-octane gasoline. Alloys of PGEs are exceptionally hard and durable, making them the best known coating for industrial crucibles used in the manufacture of chemicals and synthetic materials. PGEs are used by the glass manufacturing industry in the production of fiberglass and flat-panel and liquid crystal displays. In the electronics industry, PGEs are used in computer hard disks, hybridized integrated circuits, and multilayer ceramic capacitors. Aside from their industrial applications, PGEs are used in such other fields as health, consumer goods, and finance. Platinum, for example, is used in medical implants, such as pacemakers, and PGEs are used in cancer-fighting drugs. Platinum alloys are an ideal choice for jewelry because of their white color, strength, and resistance to tarnish. Platinum, palladium, and rhodium in the form of coins and bars are also used as investment commodities, and various financial instruments based on the value of these PGEs are traded on major exchanges. PGEs are among the rarest metals; Earth’s upper crust contains only about 0.0005 part per million (ppm) platinum. Today, the average grade of PGEs in ores that are mined primarily for their PGE concentrations varies from 5 to 15 ppm, although the concentration of PGEs in hand-picked ore specimens may range from tens to hundreds of parts per million. More than 100 different minerals have one of the PGEs as an essential component. PGE minerals occur as native metals. They also occur as compounds with other transition metals (copper, iron, mercury, nickel, and silver), post-transition metals (bismuth, lead, and tin), metalloids (antimony, arsenic, and tellurium), and nonmetals (selenium and sulfur). From 1900 to 2011, approximately 14,200 metric tons of PGEs was produced, and roughly 95 percent of that production (13,500 metric tons) took place between 1960 and 2011. The breakdown of production by country shows that, since 1900, about 90 percent of the production came from South Africa and Russia. The secondary supply of platinum, palladium, and rhodium is obtained through the recycling of catalytic converters from end-of-life vehicles, jewelry, and electronic equipment. Recycled platinum, palladium, and rhodium provide a significant proportion of the world’s total supply; these secondary sources are sufficient to close the gap between world mine production and consumption. Exploration and mining companies report resources of about 104,000 metric tons of PGEs (including minor amounts of gold) in mineral deposits around the world that could be developed. For PGEs, almost all the reported production and identified resources are associated with deposits in three geologic features—the Bushveld Complex, which is a layered mafic-to-ultramafic intrusion in South Africa; the Great Dyke, which is a layered mafic-to-ultramafic intrusion in Zimbabwe; and sill-like intrusions associated with flood basalts in the Noril’sk-Talnakh area of Russia. The metallic forms of PGEs are generally considered to be inert. PGEs pose a risk to human health only in cases where individuals are occupationally exposed to synthetic PGE compounds, especially workers in precious-metal refineries. In the natural environment, background PGE concentrations are low in water, sediment, soil, and plants. Anthropogenic sources of PGEs in the environment include catalytic converters used in modern automobiles, platinum-based chemotherapy drugs, and smelter emissions. The abundance of sulfide minerals defines the environmental and geologic characteristics of PGE-enriched magmatic sulfide deposits; those deposits with the highest amount of sulfide minerals could have the highest environmental impact. Acid rock drainage from reef-type and contact-type deposits is unlikely because the ores and their host rocks contain low proportions of sulfide minerals. For some conduit-type orebodies with massive ores, mineral-processing techniques separate and produce concentrates of copper-, iron-, and nickel-bearing sulfide minerals; those with copper and nickel are processed to extract metal, but the iron-sulfide minerals, mainly pyrrhotite, are discarded as waste. This results in waste material with a high acid-generating potential. The most significant primary source of PGEs in the United States is a deposit in the Stillwater Complex, which is a layered igneous intrusion in Montana. Approximately 305 metric tons of platinum and palladium have been mined from the Stillwater Complex deposit since 1986. Exploration and development drilling indicate that another 2,200 metric tons are present. Mining has progressed to depths of 1,800 meters below the surface, but the bottom of the ore deposit has not been reached; geologic estimates suggest that another 1,000 to 6,200 metric tons of PGEs could be present at depth. In the future, PGEs may be mined from deposits found near the base of the Duluth Complex, which is a group of igneous intrusions in Minnesota.

Professional Paper↗

Optical dating of the anastasia formation, northeastern florida, USA

The single-aliquot regenerative-dose (SAR) procedure was used to obtain optically stimulated luminescence ages to determine the depositional age of the upper part of the Anastasia Formation. This unit, which crops out along the east coast of Florida, is one of the most culturally and economically important coquina deposits in North America. Rock samples from the upper three meters of exposure at three locations were collected. Additional materials for paleontological analysis were also taken. Based on our samples, the luminescence ages of the Anastasia Formation are well within marine isotope stage 5, which is supported by the results of Osmond et al. (1970) based on U/Th ages. The associated fossil assemblages support our luminescence age determinations. Associated fossils fall within the Rancholabrean North American Land Mammal Age (300 10 ka) and the fossil mollusk assemblage consists entirely of modern species.

Southeastern Geology↗

Phosphate rock in Colombia - a preliminary report, with a section on the phosphate occurrence at Turmeque

Exploration for phosphate rock in Colombia was successfully carried out in 3 1/2 months by the U.S. Geological Survey and the Inventorio Minero of the Servicio Geologico Nacional, under the auspices of the U.S. Agency for International Development. A modern theory of exploration based on model studies of phosphorite deposits is that phosphate is deposited in the miogeosyncline adjacent to the foreland or craton, where parts of the ocean are deep, where deposition of clastic material is at a minimum, and where upwelling currents deposit a suite of rocks characterized by chert, black shale, carbonate rock, and phosphorite. Although phosphate is found in rocks of all geologic periods, economic deposits are known only in certain of: the periods--one of these being the Late Cretaceous. As previous work had demonstrated that phosphate is present in Colombia only in rocks of Cretaceous age, and is most abundant in rocks of Late Cretaceous age--the La Luna Formations and Guadalupe--in the Cordillera Oriental, work was accordingly confined to the Cordillera Oriental and to rocks of Late Cretaceous age. Particular emphasis was paid to facies changes in the miogeosyncline; the field investigation pointed to the area in Norte de Santander where the best phosphorite was found. Phosphate deposits were found in both the geosynclinal and the platform facies in Upper Cretaceous rocks spread through a large area of the Cordillera Oriental, from Huila in the south to Norte de Santander in the north, a distance of more than 600 kilometers.

Open-File Report↗

Testing characteristic magnitude distributions in modern PSHA models

The characteristic magnitude distribution hypothesis predicts a higher rate of large earthquakes than a Gutenberg–Richter extrapolation of the small‐earthquake rate would imply. Characteristic magnitude distributions have been commonly applied to faults in probabilistic seismic hazard analysis (PSHA), and in modern models they can emerge from the way short‐term seismicity constraints are combined with long‐term geologic and geodetic constraints. We test the characteristic magnitude distribution hypothesis by comparing the fault‐based magnitude distributions from the 2023 update to the National Seismic Hazard Model (NSHM23) in the Western United States with observed seismicity over the past 93 yr. We find that observed magnitude distributions fall outside the model‐predicted confidence bounds in regions where NSHM23 produces characteristic magnitude distributions: in these regions, the model predicts higher rates of large earthquakes than are observed. An analysis of the earlier California model (Uniform California Earthquake Rupture Forecast, version 3) also reveals discrepancies between the modeled and observed magnitude distributions. In addition, we find that observed magnitude distributions near modeled faults are not significantly different from those in background regions. These results challenge the prevalence of characteristic magnitude distributions in fault‐based seismic hazard models and call for a reassessment of how disparate data sets are integrated in PSHA.

western United States↗

Sketch of paleobotany

To understand the true force of the facts of paleobotany as arguments for geology it is essential that their full biologic significance be grasped. It has therefore been deemed proper, in this introduction to the several tabular and systematic statements which will make up the bulk of the volume and bear chiefly upon the geological aspect of the subject, to consider certain of the more important biologic questions, in addition to the specially geologic ones, and to discuss, from an historical and developmental standpoint, some of the leading problems of modern phytology.

Report↗

Sea surface temperature estimates for the mid-Piacenzian Indian Ocean—Ocean Drilling Program sites 709, 716, 722, 754, 757, 758, and 763

Despite the wealth of global paleoclimate data available for the warm period in the middle of the Piacenzian Stage of the Pliocene Epoch (about 3.3 to 3.0 million years ago [Ma]; Dowsett and others, 2013, and references therein), the Indian Ocean has remained a region of sparse geographic coverage in terms of microfossil analysis. In an effort to characterize the surface Indian Ocean during this interval, we examined the planktic foraminifera from Ocean Drilling Program (ODP) sites 709, 716, 722, 754, 757, 758, and 763, encompassing a wide range of oceanographic conditions. We quantitatively analyzed the data for sea surface temperature (SST) estimation using both the modern analog technique (MAT) and a factor analytic transfer function. The data will contribute to the U.S. Geological Survey (USGS) Pliocene Research, Interpretation and Synoptic Mapping (PRISM) Project’s global SST reconstruction and climate model SST boundary condition for the mid-Piacenzian and will become part of the PRISM verification dataset designed to ground-truth Pliocene climate model simulations (Dowsett and others, 2013).

Open-File Report↗

Review of the Lake Washington Ship Canal and Ballard Locks model, Seattle, Washington, 2014–20

Executive Summary The Hiram M. Chittenden (Ballard) Locks and Lake Washington Ship Canal connect freshwater Lake Washington and saline Shilshole Bay of Puget Sound in Seattle, Washington. The locks and canal allow for ships to traverse this reach. Anadromous salmonids also migrate through, transitioning between saline and freshwater environments, and making use of a fish ladder at the locks when traveling upstream. WEST Consultants, Inc., constructed a two-dimensional hydrodynamic and water-quality model (CE-QUAL-W2) simulating flow, water temperature, and salinity for the Ballard Locks and the Lake Washington Ship Canal. An initial model was built for calendar years 2014–15, and the model was updated using a more recent and modern dataset for calendar years 2016–20. The U.S. Army Corps of Engineers requested that the U.S. Geological Survey review this model and its documentation to evaluate the technical aspects of its development and calibration. Findings from this review include the following: Overall, the Lake Washington Ship Canal CE-QUAL-W2 model was well-documented and constructed largely following typical model-development methods. The Lake Washington Ship Canal model was built with CE-QUAL-W2 model version 4.5, compiled and released by Portland State University in April 2021. CE-QUAL-W2 updates and improvements are regularly released with bug fixes and new features, so any model updates would benefit from the use of the most-recent software release. The model grid that represents the Lake Washington Ship Canal bathymetry was 9.2 kilometers (5.7 miles) long, matching the expected length of the waterway. The deepest model segments were near sampling site LLLW (Large Locks site) near the locks. Lake Union is reported to constitute most of the volume of the Lake Washington Ship Canal and is depicted as such in the model grid. The model includes several water outflows at Ballard Locks, including the large and small locks, a saltwater drain, a spillway, smolt flumes, and a fish ladder. Flows from the spillway, smolt flumes, and fish ladder were combined into one structure outflow in the model and assigned one withdrawal elevation from the Lake Washington Ship Canal. The smolt flume and spillway withdraw from the same elevation, but the fish ladder flow withdraws from a higher elevation in Lake Washington Ship Canal, and that flow could be separated into its own withdrawal. The model input files were created using the Coordinated Universal Time standard instead of the more typical choice of using local standard time. This is not incorrect, but sub-daily results would need to be converted to local time for science-communication purposes. The meteorological dataset had some unexpected anomalies, such as a baseline shift in the wind-speed dataset. Other nearby meteorological datasets could be used instead or used to correct the current meteorological inputs. The upstream boundary was configured with water-temperature data from a continuous monitor buoy in Lake Washington. The boundary salinity was set at 0 parts per thousand for the duration of the model simulation. A more realistic estimate of salinity at the upstream boundary could be constructed using data from the same buoy. Saline inflow at the downstream boundary of the Lake Washington Ship Canal model through lock exchanges at the large lock was included as a tributary in the model. Salinity and temperature inputs in this tributary at the large locks were set as constant values for the entire simulation. Saline inflow through the small lock was not included in the model because few data were available, and the input was likely to be small because of the smaller surface area and volume of the small lock relative to the large lock. The model did not include any flow, water temperature, or salinity inputs to the Lake Washington Ship Canal other than at the locks and at the upstream boundary. Any point sources, small tributaries, or stormwater inputs were omitted from the model. It is unclear whether this is a substantial omission relative to model results. Most model parameters were set as defaults or to reasonable values. However, the value of the WINDH parameter, the height of the wind speed measurement, was different than the height of the meteorological site. Compared to measured data, the model simulated water-surface elevations and water temperatures with reasonable accuracy. Differences in the modeled and measured salinities revealed some opportunities to improve the simulation of salinity, both baseline salinity and the salinity maxima in summer and autumn.

Washington↗

Development of a national, dynamic reservoir-sedimentation database

The importance of dependable, long-term water supplies, coupled with the need to quantify rates of capacity loss of the Nation’s re servoirs due to sediment deposition, were the most compelling reasons for developing the REServoir- SEDimentation survey information (RESSED) database and website. Created under the auspices of the Advisory Committee on Water Information’s Subcommittee on Sedimenta ion by the U.S. Geological Survey and the Natural Resources Conservation Service, the RESSED database is the most comprehensive compilation of data from reservoir bathymetric and dry-basin surveys in the United States. As of March 2010, the database, which contains data compiled on the 1950s vintage Soil Conservation Service’s Form SCS-34 data sheets, contained results from 6,616 surveys on 1,823 reservoirs in the United States and two surveys on one reservoir in Puerto Rico. The data span the period 1755–1997, with 95 percent of the surveys performed from 1930–1990. The reservoir surface areas range from sub-hectare-scale farm ponds to 658 km 2 Lake Powell. The data in the RESSED database can be useful for a number of purposes, including calculating changes in reservoir-storage characteristics, quantifying sediment budgets, and estimating erosion rates in a reservoir’s watershed. The March 2010 version of the RESSED database has a number of deficiencies, including a cryptic and out-of-date database architecture; some geospatial inaccuracies (although most have been corrected); other data errors; an inability to store all data in a readily retrievable manner; and an inability to store all data types that currently exist. Perhaps most importantly, the March 2010 version of RESSED database provides no publicly available means to submit new data and corrections to existing data. To address these and other deficiencies, the Subcommittee on Sedimentation, through the U.S. Geological Survey and the U.S. Army Corps of Engineers, began a collaborative project in November 2009 to modernize the RESSED database architecture; provide public online input capability; and produce online reports. The ultimate goal of the Subcommittee on Sedimentation is to build a comprehensive, quality-assured database describing capacity changes over time for the largest suite of the Nation’s reservoirs.

Conference Paper↗

Data release of reprocessed select National Uranium Resources Evaluation program samples in Wyoming

The U.S. Atomic Energy Commission established the National Uranium Resources Evaluation (NURE) program in 1973 to identify uranium resources throughout the United States. Part of this program focused on the collection of stream-sediment samples and subsequent geochemical analyses of these samples for uranium, in addition to 47 other elements. As part of the original program, 18,424 stream-sediment samples were collected from Wyoming and analyzed. All original samples are stored at the U.S. Geological Survey’s (USGS) National Geochemical Sample Archive (NGSA). The Wyoming State Geological Survey (WSGS) recently selected 159 of the original Wyoming NURE stream samples to be reanalyzed using modern and standardized analytical equipment. The raw results of the reanalysis are provided with this report.

Wyoming↗

Timing, distribution, amount, and style of Cenozoic extension in the northern Great Basin

This field trip examines contrasting lines of evidence bearing on the timing and structural style of Cenozoic (and perhaps late Mesozoic) extensional deformation in northeastern Nevada. Studies of metamorphic core complexes in this region report extension beginning in the early Cenozoic or even Late Cretaceous, peaking in the Eocene and Oligocene, and being largely over before the onset of “modern” Basin and Range extension in the middle Miocene. In contrast, studies based on low-temperature thermochronology and geologic mapping of Eocene and Miocene volcanic and sedimentary deposits report only minor, localized extension in the Eocene, no extension at all in the Oligocene and early Miocene, and major, regional extension in the middle Miocene. A wealth of thermochronologic and thermobarometric data indicate that the Ruby Mountains–East Humboldt Range metamorphic core complex (RMEH) underwent ~170 °C of cooling and 4 kbar of decompression between ca. 85 and ca. 50 Ma, and another 450 °C cooling and 4–5 kbar decompression between ca. 50 and ca. 21 Ma. These data require ~30 km of exhumation in at least two episodes, accommodated at least in part by Eocene to early Miocene displacement on the major west-dipping mylonitic zone and detachment fault bounding the RMEH on the west (the mylonitic zone may also have been active during an earlier phase of crustal extension). Meanwhile, Eocene paleovalleys containing 45–40 Ma ash-flow tuffs drained eastward from northern Nevada to the Uinta Basin in Utah, and continuity of these paleovalleys and infilling tuffs across the region indicate little, if any deformation by faults during their deposition. Pre–45 Ma deformation is less constrained, but the absence of Cenozoic sedimentary deposits and mappable normal faults older than 45 Ma is also consistent with only minor (if any) brittle deformation. The presence of ≤1 km of late Eocene sedimentary—especially lacustrine—deposits and a low-angle angular unconformity between ca. 40 and 38 Ma rocks attest to an episode of normal faulting at ca. 40 Ma. Arguably the greatest conundrum is how much extension occurred between ca. 35 and 17 Ma. Major exhumation of the RMEH is interpreted to have taken place in the late Oligocene and early Miocene, but rocks of any kind deposited during this interval are scarce in northeastern Nevada and absent in the vicinity of the RMEH itself. In most places, no angular unconformity is present between late Eocene and middle Miocene rocks, indicating little or no tilting between the late Eocene and middle Miocene. Opinions among authors of this report differ, however, as to whether this indicates no extension during the same time interval. The one locality where Oligocene deposits have been documented is Copper Basin, where Oligocene (32.5–29.5 Ma) conglomerates are ~500 m thick. The contact between Oligocene and Eocene rocks in Copper Basin is conformable, and the rocks are uniformly tilted ~25° NW, opposite to a normal fault system dipping ~35° SE. Middle Miocene rhyolite (ca. 16 Ma) rests nonconformably on the metamorphosed lower plate of this fault system and appears to rest on the tilted upper-plate rocks with angular unconformity, but the contact is not physically exposed. Different authors of this report interpret geologic relations in Copper Basin to indicate either (1) significant episodes of extension in the Eocene, Oligocene, and middle Miocene or (2) minor extension in the Eocene, uncertainty about the Oligocene, and major extension in the middle Miocene. An episode of major middle Miocene extension beginning at ca. 16–17 Ma is indicated by thick (up to 5 km) accumulations of sedimentary deposits in half-graben basins over most of northern Nevada, tilting and fanning of dips in the synextensional sedimentary deposits, and apatite fission-track and (U-Th)/He data from the southern Ruby Mountains and other ranges that indicate rapid middle Miocene cooling through near-surface temperatures (~120–40 °C). Opinions among authors of this report differ as to whether this period of extension was merely the last step in a long history of extensional faulting dating back at least to the Eocene, or whether it accounts for most of the Cenozoic deformation in northeastern Nevada. Since 10–12 Ma, extension appears to have slowed greatly and been accommodated by high-angle, relatively wide-spaced normal faults that give topographic form to the modern ranges. Despite the low present-day rate of extension, normal faults are active and have generated damaging earthquakes as recently as 2008.

Northern Great Basin↗

Submarine geology and topography in the Northern Marshalls

The atomic bomb tests at Bikini in 1946 provided an opportunity to study the characteristics of atolls using modern surveying techniques. The work has shown that many of the important features, both above and below sea level, are definitely related to the direction of the prevailing winds, waves, and currents. Beyond the windward (north and east) reefs of Bikini, the steep outer slope is broken in most places by a terrace at ten fathoms. The margin of the windward reef is a Lithothamnion ridge, cut by strong grooves or surge channels; large islands are developed on these reefs. Lee reefs have nearly vertical outer slopes near the surface; their margins are smooth and are adapted to light surf; occasional storms have eroded large slump areas; and islands are small and few. Passes are largely confined to the southern reefs. The lagoons studied are 25 to 35 fathoms deep and are bordered by a ten‐fathom terrace. The floors are covered with living Halimeda and algal debris surrounded by a belt of foraminiferal and coral sand. Steep coral knolls, some rising nearly to sea level, are scattered in the lagoons. Many flat‐topped seamounts are present in the area. The 14 that were well surveyed rise from 2500 fathoms to depths between 470 and 850 fathoms. ©1949. American Geophysical Union. All Rights Reserved.

Eos, Transactions, American Geophysical Union↗

The shallow stratigraphy and sand resources offshore from Cat Island, Mississippi

In collaboration with the U.S. Army Corps of Engineers, scientists from the U.S. Geological Survey (USGS) St. Petersburg Coastal and Marine Science Center collected over 487 line kilometers (> 300 miles) of high-resolution geophysical data around Cat Island, Mississippi, to improve understanding of the island's geologic evolution and identify potential sand resources for coastal restoration. In addition, 40 vibracores were collected on and around the island, generating more than 350 samples for grain-size analysis. The results indicate that the geologic evolution of Cat Island has been influenced by deltaic, lagoonal/estuarine, tidal, and oceanographic processes, resulting in a stratigraphic record that is quite complex. The region north of the island is dominated by lagoonal/estuarine deposition, whereas the region south of the island is dominated by deltaic and tidal deposition. In general, the veneer of modern sediment surrounding the island is composed of newly deposited sediment and highly reworked relict sediments. The region east of the island shows the interplay of antecedent barrier-island change with delta development despite a significant ravinement of sediments. The data show from little to no modern sediment east of the island, exposing relict sediments at the seafloor. Finally, the data reveal four subaqueous sand units around the island. Two of the units are northwest of the modern island and one is southwest. Given the dominant, westward, longshore transport along the Mississippi and Alabama barrier islands, the geographic location of these three units suggests that they do not contribute to the modern sediment budget of Cat Island. The last unit is directly east of the island and represents the antecedent island platform that has supplied sand over geologic time for creation of the spits that form the eastern shoreline. Because of its location east of the island, the antecedent island unit may still supply sediment to the island today.

Mississippi↗

Critical mineral resources of the United States—Economic and environmental geology and prospects for future supply

Summary Mineral commodities are vital for economic growth, improving the quality of life, providing for national defense, and the overall functioning of modern society. Minerals are being used in larger quantities than ever before and in an increasingly diverse range of applications. With the increasing demand for a considerably more diverse suite of mineral commodities has come renewed recognition that competition and conflict over mineral resources can pose significant risks to the manufacturing industries that depend on them. In addition, production of many mineral commodities has become concentrated in relatively few countries (for example, tungsten, rare-earth elements, and antimony in China; niobium in Brazil; and platinum-group elements in South Africa and Russia), thus increasing the risk for supply disruption owing to political, social, or other factors. At the same time, an increasing awareness of and sensitivity to potential environmental and health issues caused by the mining and processing of many mineral commodities may place additional restrictions on mineral supplies. These factors have led a number of Governments, including the Government of the United States, to attempt to identify those mineral commodities that are viewed as most “critical” to the national economy and (or) security if supplies should be curtailed. This book presents resource and geologic information on the following 23 mineral commodities currently among those viewed as important to the national economy and national security of the United States: antimony (Sb), barite (barium, Ba), beryllium (Be), cobalt (Co), fluorite or fluorspar (fluorine, F), gallium (Ga), germanium (Ge), graphite (carbon, C), hafnium (Hf), indium (In), lithium (Li), manganese (Mn), niobium (Nb), platinum-group elements (PGE), rare-earth elements (REE), rhenium (Re), selenium (Se), tantalum (Ta), tellurium (Te), tin (Sn), titanium (Ti), vanadium (V), and zirconium (Zr). For a number of these commodities—for example, graphite, manganese, niobium, and tantalum—the United States is currently wholly dependent on imports to meet its needs. The first two chapters (A and B) deal with general information pertinent to the study of mineral resources. Chapters C through V describe individual mineral commodities and include an overview of current uses of the commodity, identified resources and their distribution nationally and globally, the state of current geologic knowledge, the potential for finding additional deposits nationally and globally, and geoenvironmental issues that may be related to the production and uses of the commodity. These chapters are updates of the commodity chapters published in 1973 in U.S. Geological Survey Professional Paper 820, “United States Mineral Resources.”

Professional Paper↗

Lacustrine varve formation through time

Studies using sediment traps in lakes reveal that the seasonal flux of sediment regulates both the composition and timing of deposition of materials that reach the bottoms of lakes. If the bottom waters of a lake are partly or totally anoxic, the seasonally deposited materials are preserved as annual groupings of laminae (varves). Common components that form individual laminae consist of allochthonous clastic material derived from the drainage basin, precipitated carbonate minerals, diatom frustules, iron-rich and manganese-rich flocs, autochthonous organic detritus, and autochthonous and allochthonous materials resuspended from the bottom. The "style" of varving has changed over geologic time, reflecting changes in biologic evolution and types of materials available. Precipitated iron-rich laminations were common in the middle Precambrian. Graded sets of clastic organic laminations persisted through the Precambrian, prior to the evolution of bioturbating benthic organisms. Glaciolacustrine varves appear to have retained their distinctive character through time. Carbonate-rich varves occurred sporadically in the Precambrian and Phanerozoic. With the exception of diatoms, major components of modern lacustrine varves were present through the Paleozoic and Mesozoic, and yet varves are rare in strata of these ages, and may have accumulated in marine to brackish-water environments. Diatoms were introduced into lacustrine systems in Early Tertiary time and are common components of varves from then on. Diatom laminae, combined with a greater chance for geologic preservation of younger lake deposits, have increased the number of geologically young occurrences of varved sediments. However, seasonal associations of modern varve components, and the processes they represent, are present in ancient deposits and provide clues to the interpretation of ancient environments.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

Conversion factors: SI metric and U.S. customary units

The policy of the U.S. Geological Survey is to foster use of the International System of Units (SI) which was defined by the 11th General Conference of Weights and Measures in 1960. This modernized metric system constitutes an international "language" by means of which communications throughout the world's scientific and economic communities may be improved. This publication is designed to familiarize the reader with the SI units of measurement that correspond to the common units frequently used in programs of the Geological Survey. In the near future, SI units will be used exclusively in most publications of the Survey; the conversion factors provided herein will help readers to obtain a "feel" for each unit and to "think metric."

General Information Product↗

Fluorine, fluorite, and fluorspar in central Colorado

Fluorine (F) is a widespread element that was deposited in a variety of rocks, minerals, and geologic environments in central Colorado. It occurs as a trace element, as a major component of the mineral fluorite (CaFs), and as a major economic source of fluorine in fluorspar deposits, which are massive concentrations of fluorite. This study has compiled available geochemical analyses of rocks, both unmineralized and mineralized, to determine the distribution of fluorine in specific age-lithologic categories, ranging from 1.8-giga-annum (Ga) metamorphic rocks to modern soils, throughout central Colorado. It also draws upon field studies of fluorine-rich mineral deposits, including fluorspar deposits, to decipher the nearly two-billion-year-long geologic history of fluorine in the study area, with implications for mineral-resource evaluations and exploration. The resulting compilation provides an important inventory of the naturally occurring levels and sources of fluorine that ultimately weather, erode, and become part of surface waters that are used for domestic water supplies in densely populated areas along the Colorado Front Range. Most commonly, fluorine is a trace element in virtually all rocks in the region. In the 3,798 unmineralized rocks that were analyzed for fluorine in the study area, the average fluorine content was 1,550 parts per million (ppm). The median was 640 ppm, nearly identical to the average crustal abundance of 650 ppm, and some high-fluorine rocks in the Pikes Peak area skewed the average to a value much greater than the median. Most unmineralized age-lithologic rock suites, including Proterozoic metamorphic rocks, 1.7- and 1.4-Ga granitic batholiths, Cambrian igneous rocks, Phanerozoic sedimentary rocks, and Laramide and Tertiary igneous rocks, had median fluorine values of 400 to 740 ppm fluorine. In all suites, however, a small number of analyzed samples contained more than 1 percent (10,000 ppm) fluorine. The 1.1-Ga plutonic rocks related to the Pikes Peak batholith had a mean fluorine content of 1,700 ppm, and primary magmatic fluorite and fluorite-bearing pegmatites are common throughout that igneous mass. Fluorine was deposited in many types of economic mineral deposits in central Colorado, and it currently is a significant trace element in some thermal springs. In the fluorspar deposits, fluorine contents were as high as 37 percent. Some fluorine-rich porphyry systems, such as Jamestown, had fluorine values that ranged from 200 ppm to nearly 37 percent fluorine, and veins in other deposits contained hydrothermal fluorite, although it was not ubiquitous. For the 495 samples from non-fluorspar mining districts (and excluding Jamestown), however, the median fluorine content was 990 ppm. This is above the crustal average but still relatively modest compared to the fluorspar deposits, and it indicates that the majority of the mineralizing systems in central Colorado did not deposit large amounts of fluorine. Nevertheless, the fluorine- and fluorite-rich mineral deposits could be used as guides for the evaluation and discovery of related but concealed porphyry and epithermal base- and precious-metal deposits. The Cenozoic geologic history of central Colorado included multiple periods during which fluorine-bearing rocks and mineral deposits were exposed, weathered, and eroded. This protracted history has released fluorine into soils and regoliths, and modern rainfall and snowmelt interact with these substrates to add fluorine to the hydrosphere. This study did not evaluate the fluorine contents of water or make any predictions about what areas might be major sources for dissolved fluorine. However, the abundant data that are available on fluorine in surface water and ground water can be coupled with the results of this study to provide additional insight into natural sources of fluorine in domestic drinking water.

Scientific Investigations Report↗

Preliminary geologic map of early Miocene felsic eruptive centers in the Aquarius Mountains, west-central Arizona

The first author, Gary S. Fuis, conducted this mapping in the summer of 1967 in partial fulfillment of the entry requirements into the Ph.D program of the Division of Geological and Planetary Sciences of the California Institute of Technology, Pasadena, Calif. The area mapped lies wholly within the Fort Rock Ranch, a private ranch spanning ~50 square miles in Mohave and Yavapai Counties, Arizona. Access to the ranch is limited, and it is uncertain whether a detailed geologic map of the Aquarius Mountains can be recreated today. Therefore, we are making this map available to the public in this Open-File Report. The original mapping was compiled on an enlarged single aerial photograph at an approximate scale of 1:15,600. The second author, J. Luke Blair, photogrammetrically rectified the original map and added modern topography, which was not available at the time the original map was completed. Modern roads and drainages were also added, including I–40, built after the original map was completed. Both authors reformatted the original map using current USGS geologic map standards.

Arizona↗

Environmental implications of test-to-substrate attachment among some modern sublittoral foraminifera

Topographic highs on the outer continental shelf of New Jersey are sites for the concentration of three species of attached calcareous benthic foraminifera. Elphidium subarcticum Cushman, normally considered a vagrant species, cements itself by an organic film to one or more quartz grains. Webbinella concave (Williamson) attaches to quartz grains by secreting a flange-like calcite skirt at one side of its globuline test. Vasiglobulina reticulate n. sp. has evolved the most elaborate system of attachment: numerous closely spaced spines connect the globuline test to a thin calcite lamina, which is in turn cemented to quartz grains. The attachment mode of these species suggests that the added weight of the quartz grains may reduce displacement during the periodic resuspension of the shelf sediments by longshore and tidal current motion. The distribution of living populations of these species corroborates sedimentological inferences that little or no modern deposition takes place on the sampled topographic highs.

New Jersey↗