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260 records · Page 15Linked to original sources
USGS1985

Uranium mineralization in the Smith Lake district of the Grants uranium region, New Mexico.

The Mariano Lake and Ruby 1 uranium orebodies, which together comprise much of the uranium ore in the Smith Lake district of the Grants uranium region, New Mexico, occur in sandstones in the lower part of the Brushy Basin Member of the Upper Jurassic Morrison Formation. The orebodies, which are offset by faults of Laramide age, are enriched in an amorphous organic material that was introduced into the host sandstone after deposition. The enrichment by this organic material, in ore, is an important characteristic of the primary uranium deposits in the Grants uranium region. However, the close proximity of the chemically reduced ore zones to oxidized rock is suggestive that the deposits represent accumulations of uranium redistributed by reduction-oxidation processes from preexisting primary deposits.Within the ores, whole-rock abundances of organic carbon correlate positively with uranium contents. This correlation is consistent with petrologic evidence which indicates that uranium is everywhere intimately admixed with the amorphous organic material. Ore zones are also enriched in vanadium (as ore-stage vanadiferous chlorite) and sulfur (as ore-stage iron disulfide minerals with delta 34 S values ranging from -29 to -42ppm).Petrographic observations demonstrate that Smith Lake uranium mineralization occurred early (before major burial compaction) in the paragenetic sequence of host-rock diagenetic alterations but was preceded by precipitation of authigenic iron disulfides (delta 34 S values ranging from -11 to -38ppm), mixed-layered smectite-illite clays, and potassium feldspars.Additional preore alterations included dissolution of detrital sanidine and plagioclase and the leaching of iron from detrital iron-titanium oxide grains. Following mineralization, varying amounts of authigenic calcite and barite formed, both of which were partly replaced by kaolinitc. Oxidation of some previously formed iron disulfide minerals occurred late in the paragenetic sequence, as did localized precipitation of native selenium, pyrite, and very minor amounts of uranium minerals.The positive correlation between contents of uranium and organic carbon and the admixture of uranium with the amorphous organic material indicates that the Mariano Lake and Ruby 1 deposits are primary-type uranium orebodies. The offset of orebodies by Laramide faults and radiometric age determinations of the ores are also consistent with a primary origin for the deposits. Late Tertiary oxygenated ground waters locally modified original chemical and mineralogical characteristics of the ores in part by leaching some uranium. Secondary uranium minerals precipitated from the partly leached primary ores are sparse in the mine area; such recycled uranium appears to represent an insignificant proportion of the total uranium in the Smith Lake district.

Economic Geology↗
USGS1998

The petrogenesis of felsic calc-alkaline magmas from the southernmost Cascades, California: Origin by partial melting of basaltic lower crust

The majority of felsic rocks from composite centers in the southernmost Cascades have geochemical and Sr, Nd and Pb isotopic ratios that suggest derivation by partial melting of lower crust that is compositionally similar to calc-alkaline basalts observed in the region. Only a few felsic rocks have δ 18 O and Pb isotopic compositions that indicate interaction with the upper crust. Mineralogical and geochemical differences among the felsic magmas result primarily from melting under variable f (H 2 O) and temperature conditions. Partial melting under low f (H 2 O) and high temperature conditions leaves an amphibole-poor residuum, and produces magmas that have orthopyroxene as the most abundant ferromagnesian phenocryst, relatively low silica contents, and straight rare earth element patterns. Partial melting under higher f (H 2 O) and lower temperature conditions leaves an amphibole-rich residuum, and produces magmas that have amphibole ± biotite phenocrysts, relatively high silica contents, and pronounced middle rare earth element depletions. These conclusions are consistent with published thermal models that suggest that reasonable volumes of basaltic magma emplaced beneath large composite centers in the southernmost Cascades can serve as the heat source for melting of the lower crust. Melting of the lower crust under variable f (H 2 O) conditions is likely to result from differences in the H 2 O contents of these basaltic magmas.

Journal of Petrology↗
USGS2002

The Fish Canyon magma body, San Juan volcanic field, Colorado: Rejuvenation and eruption of an upper-crustal batholith

More than 5000 km 3 of nearly compositionally homogeneous crystal-rich dacite (∼68 wt % SiO 2 : ∼45% Pl + Kfs + Qtz + Hbl + Bt + Spn + Mag + Ilm + Ap + Zrn + Po) erupted from the Fish Canyon magma body during three phases: (1) the pre-caldera Pagosa Peak Dacite (an unusual poorly fragmented pyroclastic deposit, ∼200 km 3 ); (2) the syn-collapse Fish Canyon Tuff (one of the largest known ignimbrites, ∼5000 km 3 ); (3) the post-collapse Nutras Creek Dacite (a volumetrically minor lava). The late evolution of the Fish Canyon magma is characterized by rejuvenation of a near-solidus upper-crustal intrusive body (mainly crystal mush) of batholithic dimensions. The necessary thermal input was supplied by a shallow intrusion of more mafic magma represented at the surface by sparse andesitic enclaves in late-erupted Fish Canyon Tuff and by the post-caldera Huerto Andesite. The solidified margins of this intrusion are represented by holocrystalline xenoliths with Fish Canyon mineralogy and mineral chemistry and widely dispersed partially remelted polymineralic aggregates, but dehydration melting was not an important mechanism in the rejuvenation of the Fish Canyon magma. Underlying mafic magma may have evolved H 2 O–F–S–Cl-rich fluids that fluxed melting in the overlying crystal mush. Manifestations of the late up-temperature magma evolution are: (1) resorbed quartz, as well as feldspars displaying a wide spectrum of textures indicative of both resorption and growth, including Rapakivi textures and reverse growth zoning (An 27–28 to An 32–33 ) at the margins of many plagioclase phenocrysts; (2) high Sr, Ba, and Eu contents in the high-SiO 2 rhyolite matrix glass, which are inconsistent with extreme fractional crystallization of feldspar; (3) oscillatory and reverse growth zoning toward the margins of many euhedral hornblende phenocrysts (rimward increases from ∼5·5–6 to 7·7–8·5 wt % Al 2 O 3 ). Homogeneity in magma composition at the chamber-wide scale, contrasting with extreme textural and chemical complexities at the centimeter–millimeter scale, is consistent with a dynamic environment, wherein crystals with a variety of growth and resorption histories were juxtaposed shortly before eruption by convective currents.

Colorado↗
USGS1986

Aluminum enrichment in silicate melts by fractional crystallization: some mineralogic and petrographic constraints.

The degree of aluminum saturation of an igneous rock may be described by its Aluminum Saturation Index (ASI) defined as the molar ratio Al 2 O 3 (CaO + K 2 O + Na 2 O). One suggested origin for mildly peraluminous granites (ASI between 1 and about 1.1) is by fractional crystallization of subaluminous (ASI < 1) magmas; hornblende, having ASI < 0.5, could be a major driving force in such a fractionation process. The efficacy of the process depends not only on precipitation of hornblende and its effective removal from the reacting system, but on the composition and nature of other coprecipitating phases, weighted by their modal abundances in the reactive system. Precipitation of feldspar (ASI = 1), for instance, would retard or even prevent aluminum enrichment in the melt if the ASI of melt is < 1, but would enhance such evolution if the ASI of the melt is > 1. Discussion of the efficacy of any mineral must be made in the context of the total reacting system. For hornblende to effectively cause a melt to evolve into a peraluminous composition, it must be able to coexist with peraluminous magmas. Experimental phase equilibrium data show that at pressure > 5 kb hornblende can coexist with strongly peraluminous melts (ASI ˜ 1.5). Scantily phyric volcanic rocks show that hornblende can coexist with granitic magma having ASI ˜ 1.1 –1.2. The aggregate ASI of last-stage minerals of a typical granite is less than this value; therefore, even after hornblende has reacted out, the residual magma may be expected to continue to evolve toward more aluminous compositions.

Journal of Petrology↗
USGS1994

Evidence from xenoliths for a dynamic lower crust, eastern Mojave Desert, California

Garnet-rich xenoliths in a Tertiary dike in the eastern Mojave Desert, California, preserve information about the nature and history of the lower crust. These xenoliths record pressures of ∼ 10–12 kbar and temperatures of ∼ 750–800°C. Approximately 25% have mafic compositions and bear hornblende + plagioclase + clinopyroxene + quartz in addition to garnet. The remainder, all of which contain quartz, include quartzose, quartzofeldspathic, and aluminous (kyanite±sillimanite-bearing) varieties. Most xenoliths have identifiable protoliths—mafic from intermediate or mafic igneous rocks, quartzose from quartz-rich sedimentary rocks, aluminous from Al-rich graywackes or pelites, and quartzofeldspathic from feldspathic sediments and/or intermediate to felsic igneous rocks. However, many have unusual chemical compositions characterized by high FeO(t), FeO(t)/MgO, Al 2 O 3 , and Al 2 O 3 /CaO, which correspond to high garnet abundance. The mineralogy and major-and trace-element compositions are consistent with the interpretation that the xenoliths are the garnet-rich residues of high-pressure crustal melting, from which granitic melt was extracted. High 87 Sr/ 86 Sr and low 143 Nd/ 144 Nd, together with highly discordant zircons from a single sample with Pb/Pb ages of ∼ 1.7 Ga, demonstrate that the crustal material represented by the xenoliths is at least as old as Early Proterozoic. This supracrustal-bearing lithologic assemblage may have been emplaced in the lower crust during either Proterozoic or Mesozoic orogenesis, but Sr and Nd model ages> 4 Ga require late Phanerozoic modification of parent/daughter ratios, presumably during the anatectic event. Pressures of equilibration indicate that peak metamorphism and melting occurred before the Mojave crust had thinned to its current thickness of <30 km. The compositions of the xenoliths suggest that the lower crust here is grossly similar to estimated world-wide lower-crustal compositions in terms of silica and mafic content; however, it is considerably more peraluminous, has a lower mg -number, and is distinctive in some trace element concentrations, reflecting its strong metasedimentary and restitic heritage.

Journal of Petrology↗
USGS2010

El Salvador, Chile porphyry copper deposit revisited: Geologic and geochronologic framework

The Eocene (42 to 41 Ma) El Salvador porphyry copper deposit in the Indio Muerto district, northern Chile (26° 15′ S Lat.), formerly thought to have formed at the culmination of a 9-m.y. period of episodic magmatism, is shown by new mapping, U-Pb and K-Ar geochronology, and petrologic data to have formed during the younger of two distinct but superposed magmatic events-a Paleocene (∼63 to 58 Ma) and an Eocene (44 to 41 Ma) event. In the district, high-K Paleocene volcano-plutonic activity was characterized by a variety of eruptive styles and magmatic compositions, including a collapse caldera associated with explosive rhyolitic magmatism (El Salvador trapdoor caldera), a post-collapse rhyolite dome field (Cerro Indio Muerto), and andesitic-trachyandesitic stratovolcanos (Kilometro Catorce-Los Amarillos sequence). Pre-caldera basement faults were reactivated during Paleocene volcanism as part of the collapse margin of the caldera. Beneath Cerro Indio Muerto, where the porphyry Cu deposit subsequently formed, the intersection of two major basement faults and the NNE-striking rotational axis of tilted ignimbrites of the Paleocene El Salvador caldera localized emplacement of post-collapse rhyolite domes and peripheral dikes and sills. Subsequent Eocene rhyolitic and granodioritic-dacitic porphyries intruded ~14 m.y. after cessation of Paleocene magmatism along the same NNE-striking structural belt through Cerro Indio Muerto as did the post-collapse Paleocene rhyolite domes. Eocene plutonism over a 3-m.y. period was contemporaneous with NW-SE-directed shortening associated with regional sinistral transpression along the Sierra Castillo fault, lying ∼10 km to the east. Older Eocene rhyolitic porphyries in the Indio Muerto district were emplaced between 44 and 43 Ma, and have a small uneconomic Cu center associated with a porphyry at Old Camp. The oldest granodioritic-dacitic porphyries also were emplaced at ∼44 to 43 Ma, but their petrogenetic relation to the rhyolitic porphyries and younger granodioritic-dacitic porphyries in the district is unclear. The main porphyry Cu-Mo-related granodioritic-dacitic stocks in Quebrada Turquesa on Cerro Indio Muerto intruded, cooled, and were mineralized within ∼1 m.y. between 42 and 41 Ma. Volumetrically minor late- to post-mineral porphyries are slightly more mafic than earlier granodioritic-dacitic porphyries, a compositional trend possibly repeated on several scales and more than once over the 3-million-year Eocene magmatic history of the Indio Muerto district. This compositional trend requires either addition of basaltic material into an open-system silicic magma chamber or tapping of progressively deeper levels of a vertically zoned magma chamber. Eocene porphyry magmas were more hydrous and their residual source mineralogy richer in garnet than the relatively anhydrous Paleocene rocks, whose source was rich in pyroxene. The presence of inherited zircons in Paleocene and Eocene rocks requires interaction with crustal rocks of Paleozoic and/or Proterozoic age.

International Geology Review↗
USGS1983

Oxygen and strontium isotopic studies of basaltic lavas from the Snake River plain, Idaho

The Snake Creek-Williams Canyon pluton of the southern Snake Range crops out over an area of about 30 km2, about 60 km southeast of Ely, Nev. This Jurassic intrusion displays large and systematic chemical and mineralogical zonation over a horizontal distance of 5 km. Major-element variations compare closely with Dalyls average andesite-dacite-rhyolite over an SiO2 range of 63 to 76 percent. For various reasons it was originally thought that assimilation played a dominant role in development of the Snake Creek-Williams Canyon pluton. However, based on modeling of more recently obtained trace element and isotopic data, we have concluded that the zonation is the result of in-situ fractional crystallization, with little assimilation at the level of crystallization. This report summarizes data available for each of the mineral species present in the zoned intrusion. Special attention has been paid to trends We present oxygen and strontium isotopic data for olivine tholeiites, evolved (that is, differentiated and (or) contaminated) lavas, rhyolites, and crustal- derived xenoliths from the Snake River Plain. These data show that the olivine tholeiites are fairly uniform in d80 (5.1 to 6.2) and 87Sr/86Sr (0.7056 to 0.7076) and reveal no correlation between these ratios. The tholeiites are considered representative of mantle-derived magmas that have not interacted significantly with crustal material or meteoric water. The evolved lavas display a wider range in d 80 (5.6 to 7.6) and 87Sr/86Sr (0.708 to 0.717) with positive correlations between these ratios in some suites but not in others. Crustal xenoliths have high and variable 8?Sr/86Sr (0.715 to 0.830) and d80 values that vary widely (6.7 to 9.2) and are a few permil greater than d80 values of the Snake River basalts. Thus, isotopic data for the evolved lavas are permissive of small degrees of contamination by crustal rocks similar to the most d80-depleted xenoliths. The d80 enrichments in some evolved lavas also are consistent with crystal fractionation processes and do not necessarily require bulk interaction with crustal rocks. Enrichment in d80 but not in 87Sr/86Sr in one suite of evolved lavas suggests that crustal contamination may not be essential to the petrogenesis of those lavas. Other suites of evolved lavas display large variations in 87Sr/86Sr that reflect at least some selective contamination with 87St. Bulk solid/liquid oxygen-isotope fractionation factors (a's) calculated for the evolved lavas from Craters of the Moon National Monument are comparatively large. These a's are dependent upon the nature and proportions of phases removed by crystal fractionation; basaltic lava a's differ from latitic lava a?s in accordance with different phenocryst assemblages in these rocks. Snake River Plain rhyolites are isotopically distinct from both the analyzed crustal xenoliths and olivine tholeiites. Their origin remains poorly understood, but crustal or sub-crustal sources may be viable. In the first case, they must be derived by anatexis of material distinct from the analyzed crustal xenoliths. In the second case, they must be derived from material unlike the source for tholeiites. No cogenetic relation with the tholeiites seems likely on the basis of available data. that might relate to the variation in the chemical petrology of the pluton.

Open-File Report↗
USGS2004

Ultramafic xenoliths from the Bearpaw Mountains, Montana, USA: Evidence for multiple metasomatic events in the lithospheric mantle beneath the Wyoming craton

Ultramafic xenoliths in Eocene minettes of the Bearpaw Mountains volcanic field (Montana, USA), derived from the lower lithosphere of the Wyoming craton, can be divided based on textural criteria into tectonite and cumulate groups. The tectonites consist of strongly depleted spinel lherzolites, harzbugites and dunites. Although their mineralogical compositions are generally similar to those of spinel peridotites in off-craton settings, some contain pyroxenes and spinels that have unusually low Al2O3 contents more akin to those found in cratonic spinel peridotites. Furthermore, the tectonite peridotites have whole-rock major element compositions that tend to be significantly more depleted than non-cratonic mantle spinel peridotites (high MgO, low CaO, Al2O3 and TiO2) and resemble those of cratonic mantle. These compositions could have been generated by up to 30% partial melting of an undepleted mantle source. Petrographic evidence suggests that the mantle beneath the Wyoming craton was re-enriched in three ways: (1) by silicate melts that formed mica websterite and clinopyroxenite veins; (2) by growth of phlogopite from K-rich hydrous fluids; (3) by interaction with aqueous fluids to form orthopyroxene porphyroblasts and orthopyroxenite veins. In contrast to their depleted major element compositions, the tectonite peridotites are mostly light rare earth element (LREE)-enriched and show enrichment in fluid-mobile elements such as Cs, Rb, U and Pb on mantle-normalized diagrams. Lack of enrichment in high field strength elements (HFSE; e.g. Nb, Ta, Zr and Hf) suggests that the tectonite peridotites have been metasomatized by a subduction-related fluid. Clinopyroxenes from the tectonite peridotites have distinct U-shaped REE patterns with strong LREE enrichment. They have 143Nd/144Nd values that range from 0??5121 (close to the host minette values) to 0??5107, similar to those of xenoliths from the nearby Highwood Mountains. Foliated mica websterites also have low 143Nd/144Nd values (0??5113) and extremely high 87Sr/86Sr ratios in their constituent phlogopite, indicating an ancient (probably mid-Proterozoic) enrichment. This enriched mantle lithosphere later contributed to the formation of the high-K Eocene host magmas. The cumulate group ranges from clinopyroxene-rich mica peridotites (including abundant mica wehrlites) to mica clinopyroxenites. Most contain >30% phlogopite. Their mineral compositions are similar to those of phenocrysts in the host minettes. Their whole-rock compositions are generally poorer in MgO but richer in incompatible trace elements than those of the tectonite peridotites. Whole-rock trace element patterns are enriched in large ion lithophile elements (LILE; Rb, Cs, U and Pb) and depleted in HFSE (Nb, Ta Zr and Hf as in the host minettes, and their Sr-Nd isotopic compositions are also identical to those of the minettes. Their clinopyroxenes are LREE-enriched and formed in equilibrium with a LREE-enriched melt closely resembling the minettes. The cumulates therefore represent a much younger magmatic event, related to crystallization at mantle depths of minette magmas in Eocene times, that caused further metasomatic enrichment of the lithosphere. ?? Oxford University Press 2004; all rights reserved.

Journal of Petrology↗