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Time-varying rates of organic and inorganic mass accumulation in southeast Louisiana marshes: Relationships to sea-level anomalies and tropical storms

Louisiana's coastal wetlands are complex systems that require a continuous input of organic and inorganic material to keep pace with relative sea-level rise. Coastal restoration projects such as sediment diversions are being implemented to mitigate land loss and increase availability of inorganic sediment to coastal wetlands, and marshes specifically rely on organic material to build soil volume and maintain surface elevation. Interannual-to-decadal sea-level anomalies such as hurricanes can affect marsh accretion, mineral deposition, and plant productivity. In this light, complex ecogeomorphic feedback controls whether a marsh surface is sustainable or eroded/drowns. This study performs some of the first differential vertical accretion rates (VARs) and organic and inorganic mass accumulation rates (MARs) over time in SE Louisiana marshes determined from the 210 Pb Constant Rate of Supply model, coupled with standard 137 Cs VARs. These accumulation rates over the past ∼100 years were measured from a total of six brackish and salt marsh locations in Barataria Basin near the proposed Mid-Barataria Sediment Diversion. They were then related to interannual sea-surface elevations at Grand Isle, Louisiana, over the last ∼60 years and recorded hurricane activity in the delta. Results show VARs range from 0.63 cm/y to 1.69 cm/y and total MARs range from 0.11 to 0.43 g/cm 2 /y. Temporally, VARs and MARs (total, inorganic, and organic) are characterized by gradual increases in rates with decreasing age along with episodic peaks in VARs and MARs. The findings of this study indicate that no relationship occurs between sea-level anomalies and VARs or organic and inorganic MARs; however, a strong relationship appears to occur between major hurricanes to VAR and MAR contributions. Furthermore, high water content (81 ± 8%) and organic-rich soils in the sediment cores highlight the significance of belowground biomass and associated pore volume in maintaining marsh elevation in the study area.

Louisiana

Groundwater quality near an oil field in a stream-dominated recharge setting, California, USA

Alluvial valley aquifers are important sources of water supply in many areas but effects of co-located oil and gas development on these resources have not been widely reported, especially in settings where recharge is dominated by stream infiltration. Interpreting the presence of geochemical indicators in the context of hydrology, geology, and other factors provides a more complete understanding of the relations between groundwater and sources of oil-field fluids and aids in identifying risks associated with oil and gas development. Groundwater and Salinas River water samples were collected in an alluvial valley near the San Ardo Oil Field in Monterey County, California and analyzed for a wide range of dissolved chemical, gas, and isotopic constituents to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with fresh groundwater used for supply. Hydraulic gradients, age-dating tracers, and other geochemical indicators show that recharge from the Salinas River has the potential to dilute oil-field fluids that might migrate or seep into the aquifer. Groundwater and Salinas River water collected downgradient of the San Ardo Oil Field showed little or no evidence of mixing with oil-field fluids. Some samples within the oil field contained trace amounts of hydrocarbons or elevated temperatures, indicating that any potential effects from oil-field activities are minor or have been diluted by recharge from the Salinas River. The two samples with the most geochemical evidence of potential mixing with oil-field fluids (SP-18 and GW-17) were collected west of or along the Los Lobos fault, where naturally occurring hydrocarbons are near the land surface. Those samples are also near active or inactive oil-field wells, and so anthropogenic activities and pathways cannot be ruled out as a cause of trace detections of hydrocarbons and elevated temperatures in the aquifer.

California

Multi-scale geophysical mapping of the brine and bedrock surfaces along the Dolores River, Paradox Valley, Colorado, December 2023

Total dissolved solids derived from salt dome–sourced brine in the underlying alluvial aquifer substantially increase with distance in the reach of the Dolores River that passes through Paradox Valley in southwestern Colorado. The area has been the site of salinity control operations since the 1990s to reduce salt loading to the downstream Colorado River. Previous airborne and ground/water-based electromagnetic (EM) geophysical data have successfully mapped the top of the brine surface, albeit with relatively coarse near-surface resolution and limited spatial coverage. This present December 2023 study used ground-based high-resolution EM and passive seismic (horizontal-to-vertical spectral ratio, HVSR) tools to map in detail the depth and thickness of the brine zone in the alluvial aquifer (top of the brine down to bedrock contact) in areas immediately surrounding the Dolores River where previous airborne EM (AEM) results indicated brine within 10 m of land surface. Results indicate the deepest bedrock is generally associated with the shallowest brine and local depressions in the collapse breccia (caprock to the Paradox Formation salt) may facilitate vertical migration of brine into the alluvial aquifer. Additionally, the ground-based EM mapping corroborated general patterns in depth to brine that were observed in previous AEM results while also revealing additional detail, including suspected focused brine discharge zones to the Dolores River. A river-based survey wherein EM data, channel depth and river water–specific conductance information were collected augmented these findings and indicated specific areas on both the western and eastern sides of the river where focused brine discharge may occur. This study comprises a large-scale, ground- and water-based geophysical mapping effort, including hundreds of HVSR soundings and 100s of kilometres of EM data, which were successfully translated into digital brine and bedrock surfaces that could be incorporated into groundwater modelling efforts, future well siting or other decision-making.

Colorado

Bathymetric survey and storage capacity of Upper Lake Mary near Flagstaff, Arizona in 2024

The U.S. Geological Survey (USGS), in cooperation with the city of Flagstaff, collected bathymetric, light detection and ranging (lidar), and land-survey data of Upper Lake Mary in Arizona during the months of April and October 2024. The city of Flagstaff uses a combination of groundwater from well fields throughout the Flagstaff area and surface water, mainly from Upper Lake Mary, for its potable water supply. The purpose of the survey is to update previous surveys using new technology and compare the results to previous surveys to determine if there was a decrease in storage capacity that could affect the city’s water supply. The lakebed was mapped in April 2024 using a vessel equipped with a multibeam echosounder (MBES) and mobile lidar scanner with positioning captured using a real-time kinematic global navigation satellite system (RTK GNSS) base and receivers. In October 2024, areas of the reservoir that were too shallow for the boat and shoreline that were not captured by the vessel-based lidar were surveyed on foot using hand-held RTK GNSS receivers. At full pool (spillway elevation of 6,831.82 feet above NAVD 88 [2,082.34 meters (m)], Upper Lake Mary has a storage capacity of 16,449.80 acre-feet (20,290,611.73 cubic meters) and a surface area of 953.57 acres (3,860,926.075 square meters). The reservoir is 5.7 miles (9.7 kilometers) long and varies in width from 326 feet (99.36 m) near the central, narrow portion of the reservoir to 2,613 feet (796.44 m) in the upper portion. Comparisons between this survey and the previous two surveys from the 1950s and 2006 indicate no apparent decrease in reservoir area or storage capacity. Results of the 2024 survey indicate that Upper Lake Mary’s storage capacity increased by 0.9 percent from the 2006 survey and a 1.6 percent increase in surface area from the 2006 survey.

Arizona

Groundwater flowpath characteristics drive variability in per- and polyfluoroalkyl substances (PFAS) loading across a stream-wetland system

Groundwater-dependent ecosystems in areas with industrial land use are at risk of exposure to a PFAS chemicals. We investigated one such system with several known PFAS source areas, where high and low permeability sediments (glacial) coupled with groundwater-lake and groundwater/surface-water interactions created complex ‘source to seep’ dynamics. Using heat-tracing and chemical methods, numerous preferential groundwater discharge zones were identified and sampled across the upper Quashnet River stream-wetland system in Mashpee, MA, USA, downgradient of Joint Base Cape Cod (JBCC). Surface-water and groundwater samples were analyzed for 40 PFAS compounds between March and October 2022. Samples were collected from groundwater seeps identified as preferential discharge points (PDPs), wells upgradient of the stream-wetland system, contributing flow-through kettle lakes, and along Quashnet River surface-waters. PFAS from sampled waters contained perfluorinated carboxylates (PFPea, PFHxA, PFNA), perfluorinated sulfonates (PFBS, PFPeS, PFHxS, PFOS), fluorotelomer sulfonates (6:2, 8:2 FtS), and perfluoroalkyl sulfonamides (PFOSA). Samples from PDPs and wells had measured PFAS concentrations ranging from non-detect to 4677 ng/L ng/L (mean = 418 ng/L, std. = 709 ng/L), and a range of deuterium excess values (3.2 to 15.9 per mil) indicative of varying degrees of groundwater-lake interaction prior to groundwater flowpath emergence at PDPs. Correlations ( p < 0.01) between deuterium excess, %PFAS precursors, and terminal PFAS compounds highlighted potential precursor transformations associated with lake-groundwater exchange along flowpaths sourcing PDPs. However, some seepages had higher total PFAS concentrations (>1000 ng/L) than upgradient kettle lakes despite showing lake (evaporative) isotopic signatures, indicating the potential for groundwater flowpath convergence at wetland discharge zones and the influence of lakebed PFAS precursor reactions. Results from these synoptic surveys address gaps in the existing PFAS literature by demonstrating the importance of subsurface fate and transport on PFAS compound concentrations and mass loading in preferential groundwater discharge zones.

Massachusetts

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers within northern Medina County, Texas

During 2023–24, the U.S. Geological Survey, in cooperation with the Edwards Aquifer Authority, revised a previous publication of the geologic framework and hydrostratigraphy of the Edwards and Trinity aquifers that was completed during 2018–20 within northern Medina County, Texas. The purpose of this report is to present the updated geologic framework and hydrostratigraphy of the rocks containing the Edwards and Trinity aquifers in northern Medina County from field observations of the surficial expressions of the rocks. The report includes a detailed 1:24,000-scale hydrostratigraphic map with names and descriptions of the geologic and hydrostratigraphic units (HSUs) in the study area. This study includes updates to the geology of the Kainer Formation (or its stratigraphic equivalent, the Fort Terrett Formation) with the addition of a burrowed unit between the basal nodular and dolomitic members. The hydrostratigraphy was also updated with the addition of HSU IIA for the upper part of the Devils River Limestone and the Seco Pass HSU for the burrowed member of the Kainer (or Fort Terrett) Formation. The Cretaceous age rocks (listed in ascending order) in the study area are part of the Trinity Group, Edwards Group and stratigraphically equivalent Devils River Limestone, Washita Group, Eagle Ford Group, Austin Group, and Taylor Group, with isolated areas where Late Cretaceous age igneous rocks have intruded. The groups and formations are composed primarily of relatively thick layers of clays, shales, and limestone. The igneous rocks are coarse-grained ultramafic in composition. Hydrostratigraphically, the rocks exposed in the study area (listed in descending order from land surface) are igneous, the upper confining unit to the Edwards aquifer, the Edwards aquifer, the upper zone of the Trinity aquifer, and the upper part of the middle zone of the Trinity aquifer. The karstic carbonate Edwards and Trinity aquifers developed because of their original depositional history, primary and secondary porosity, diagenesis, fracturing, and faulting. These factors have resulted in development of modified porosity, permeability, and transmissivity within and between the aquifers.

Texas

Groundwater-level elevations in the Denver Basin bedrock aquifers and Upper Black Squirrel Creek alluvial aquifer, El Paso County, Colorado, 2021–24

El Paso County is the second-most populous county in Colorado and is projected to grow another 15 percent by 2030. Within El Paso County is the Upper Black Squirrel Creek Designated Groundwater Basin (Black Squirrel Basin), an area where surface water is scarce and water users rely primarily on groundwater from five different aquifers (the Upper Black Squirrel Creek alluvial aquifer and four bedrock aquifers within the Denver Basin aquifer system: the lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) to meet their needs. Currently (2024), land within the Upper Black Squirrel Creek Basin is primarily used for rural grazing and agriculture; however, municipal development is ongoing. In 2021, the U.S. Geological Survey, in cooperation with the Upper Black Squirrel Creek Ground Water Management District, began a study to establish a baseline dataset and assess the groundwater resources of the aquifers within the Black Squirrel Basin. A network of 39 wells was established in 2021; discrete groundwater-level measurements were made bimonthly. Nine of the 39 wells were equipped with pressure transducers to record hourly groundwater-level data. Seven wells had statistically significant seasonal trends, and trends at 3 wells were negative. For the discrete data, 16 wells had a significant trend for the study period, and 4 wells had negative trends. For the time-series data, 8 wells had significant trends, and 3 wells had negative trends. Potentiometric surface maps were created for this study using discrete, static groundwater levels measured in April 2023. These maps showed the estimated groundwater flow direction from the north-northwest to the south-southeast in the alluvial aquifer and from the northwest to the east-southeast for the lower Dawson and Denver aquifer wells. This study indicates the potential benefit of monitoring wells in the areas near municipal pumping. Additional monitoring could lead to a better understanding of connectivity between aquifers and be an important tool for assessing long-term sustainability of groundwater use.

Colorado

Geomorphic map of the Umatilla River corridor, Oregon

This map portrays the distribution of landforms along the Umatilla River in northeastern Oregon and covers a corridor 127 kilometers long from the confluence of the Umatilla River with the Columbia River upstream to Meacham Creek. The map encompasses the valley bottom and extends about 1 kilometer up the adjoining hillslopes. Map data are intended to support water quality and fisheries enhancement efforts pursuant to the First Foods, a resource-management approach that focuses on traditionally gathered foods including water, fish, big game, roots, and berries and calls attention to the reciprocity between people and the foods upon which humans depend. The Umatilla River drains about 6,300 square kilometers on the northwest slope of the Blue Mountains in northeast Oregon. Most of the drainage basin is underlain by Miocene basalt flows of the Columbia River Basalt Group. Younger, weakly lithified, late Miocene and early Pliocene gravel deposits of local origin (for example, McKay Formation) are mapped in a few places. Upland surfaces are mantled with windborne silt (loess) correlative with deposits elsewhere known as the Palouse Formation. Surfaces below an elevation of about 340 meters were inundated repeatedly by large Pleistocene glacial outburst floods, most emanating from glacial Lake Missoula in western Montana. In backflooded areas such as the lower Umatilla River valley, Missoula floods deposited extensive slack-water silt. Areas mapped as open water, active channel and tie channel, flood basin, valley bottom, and modified land constitute the geomorphic floodplain: the area subject to occasional inundation by the Umatilla River. Deposits and landforms within the floodplain are inset into Missoula flood deposits and hence postdate the 20–15-kilo-annum Missoula floods. Some floodplain deposits are no more than a few centuries old, as indicated by substantial erosion and deposition during the Umatilla River flood of February 2020, the largest since systematic measurements began in October 1903. Deposits and landforms of the floodplain are transient features within the longer-term incision of the Umatilla River into mid-Miocene flood basalts and younger gravel of the McKay Formation.

Oregon

Separating signals in elevation data improves supervised machine learning predictions for hydrothermal favorability

A recent study identified topography (land surface elevation above sea level) as an important input dataset (feature) for predicting the location of hydrothermal systems in the Great Basin in Nevada. Yet, topography is generally a result of more than one geological process and may consequently contain multiple distinct signals. For example, the geologic evolution of the Great Basin has produced both crustal thickening (i.e., regional-scale trends in elevation) and thinning via Basin and Range extensional faulting (i.e., valley-scale topographic relief). We postulate that these geologic processes may affect the occurrence of hydrothermal systems differently. Therefore, we separate the regional trend from the valley-scale signal in the Great Basin, and then use them separately to evaluate the importance of each as predictors for hydrothermal favorability. Our prior work applying supervised machine learning (ML) using the data from the Nevada Machine Learning Project demonstrated that employing a training strategy that randomly selects negative training sites produces better performing models for predicting hydrothermal favorability than a training strategy that uses expert-selected negatives. The models created using both training strategies exhibited a west-east geographic trend in the predictions for the favorability of hydrothermal resources. These models generally predicted higher favorability in western Nevada and lower favorability in eastern Nevada. This west-east trend in predicted favorability correlates with elevation across the Great Basin, which trends higher from west to east. By separating the original elevation feature into distinct features for elevation trend (i.e., regional-scale topography) and detrended elevation (i.e., valley-scale or local relative topography), we find that models using the separated topographic signals consistently outperform competing models that use the original elevation feature. Although western Nevada still exhibits higher favorability than eastern Nevada, using separated signals for regional elevation and local structure reduces the west-east prediction trend in the region and emphasizes structures associated with hydrothermal upflow. This work emphasizes how carefully engineering features to represent geological conditions relevant to hydrothermal systems allows ML algorithms to detect important patterns for predicting hydrothermal resource favorability and leads to better model performance.

Conference Paper

Ground-water flow in the surficial aquifer system and potential movement of contaminants from selected waste-disposal sites at Cecil Field Naval Air Station, Jacksonville, Florida

As part of the Installation Restoration Program, Cecil Field Naval Air Station, Jacksonville, Florida, is considering remedialaction alternatives to control the possible movement of contaminants from sites that may discharge to the surface. This requires a quantifiable understanding of ground-water flow through the surficial aquifer system and how the system will respond to any future stresses. The geologic units of interest in the study area consist of sediments of Holocene to Miocene age that extend from land surface to the base of the Hawthorn Group. The hydrogeology within the study area was determined from gamma-ray and geologists' logs. Ground-water flow through the surficial aquifer system was simulated with a seven-layer, finite-difference model that extended vertically from the water table to the top of the Upper Floridan aquifer. Results from the calibrated model were based on a long-term recharge rate of 6 inches per year, which fell in the range of 4 to 10 inches per year, estimated using stream hydrograph separation methods. More than 80 percent of ground-water flow circulates within the surficial-sand aquifer, which indicates that most contaminant movement also can be expected to move through the surficial-sand aquifer alone. The surficial-sand aquifer is the uppermost unit of the surficial aquifer system. Particle-tracking results showed that the distances of most flow paths were 1,500 feet or less from a given site to its discharge point. For an assumed effective porosity of 20 percent, typical traveltimes are 40 years or less. At all of the sites investigated, particles released 10 feet below the water table had shorter traveltimes than those released 40 feet below the water table. Traveltimes from contaminated sites to their point of discharge ranged from 2 to 300 years. The contributing areas of the domestic supply wells are not very extensive. The shortest traveltimes for particles to reach the domestic supply wells from their respective contributing areas ranged from 70 to 200 years.

Florida

Hydrogeologic characterization of the Cahuilla Valley and Terwilliger Valley Groundwater Basins, Riverside County, California

The relation between the groundwater and the amount of natural recharge to the Cahuilla Valley and Terwilliger Valley groundwater basins is not well understood. During the 20th century, the reliance on groundwater near Anza, California, used for agricultural, domestic, and municipal reasons has increased, and there is the potential for changes in groundwater availability related to climate change. Several types of existing data were evaluated, and new data were collected for this study, with the goal of characterizing the region’s hydrogeology. The study’s scope included constructing a geologic framework model to show where the groundwater-bearing units are present and their relation to each other, estimating the major components of the groundwater budget, and understanding local short-term and regional long-term groundwater flow and how that has changed since the early 1900s. Two electrical resistivity tomography surveys were done in the Durasno Valley about 2,150 feet apart to identify the thickness of the alluvium, its horizontal extent, and the depth-to-basement along two profiles perpendicular to Cahuilla Creek. The subsurface sediments were mostly horizontally layered and the transitional boundary between the alluvium and basement was thinner and shallower along the upgradient profile where the depth-to-basement was about 70 feet below land surface; the depth-to-basement at the downgradient profile was more than about 140 feet below land surface. The results from the surveys were used to place four monitoring wells at two sites along the survey profiles. Artesian flow from the deepest well at the downgradient site indicated that the decomposed and competent basement likely contributed some groundwater to the overlying alluvium, laterally, from below, or both. A digital three-dimensional geologic framework model was constructed using EarthVision software to represent the subsurface geometry of the alluvium, decomposed basement, and competent basement. Maps and cross sections of the modeled thicknesses of the alluvium and decomposed basement, and the modeled elevation of the top of the competent basement, were made to show the subsurface geometry of vertical faults, selected wells, and the groundwater-bearing units. Because natural recharge is related to the variable cycles of precipitation, estimates are difficult to quantify. Recharge and runoff have extreme interannual variability in the study area; recharge and runoff can be sporadic, and a substantive amount may not occur in some years. Estimates of recharge from a previous study and the regional-scale Basin Characterization Model for California for four different periods ranged from 3,800 acre-feet/year for 1897–1947 to 5,900 acre-feet/year for 1971–2000. Potential recharge from the disposal of domestic septic systems may have been as much as 500 acre-feet in 2020. It was estimated that between about 400 and 2,400 acre-feet/year of groundwater is lost through evapotranspiration by vegetation and evaporation from open water bodies, but the main source of discharge is through pumpage, mainly used for agriculture from the alluvium in the Cahuilla Valley and Terwilliger Valley groundwater basins. The estimated total pumpage for 1991–2021 ranged from about 1,140 acre-feet in 2019 to about 3,450 acre-feet in 1994. When summed, the cumulative amount of estimated pumpage between 1991 and 2021 was about 81,400 acre-feet. The general direction of groundwater flow is from the northeast along the San Jacinto fault zone at the headwaters of Cahuilla and Hamilton Creeks, to the surface-water outlets at the west and southeast parts of the study area. Groundwater-level data from the 1950s and earlier indicate that there was a natural groundwater divide between the Cahuilla Valley and Terwilliger Valley groundwater basins, but the changing magnitude and extent of the groundwater depressions caused by pumping since about 1950 indicate that the location of the natural groundwater boundary between the Cahuilla Valley and Terwilliger Valley groundwater basins has migrated over time. Flow from the upper to the lower parts of the Cahuilla Valley groundwater basin roughly follows the course of Cahuilla Creek through the narrow Durasno Valley where an estimated volume of flow in April 2019 was about 10–150 acre-feet/year. Short-term trends in groundwater levels, particularly in wells where groundwater is shallow and in the basement unit, show how some areas respond quickly to recharge and discharge. Wells located further to the east within the Cahuilla Valley groundwater basin in the alluvium show much less of a response to recharge events; areas of sustained pumpage from the alluvium, primarily for agriculture, show long-term declines in groundwater levels and generally do not show the effects of storm events or recent runoff. Groundwater levels in wells that are farthest from where most of the recharge occurs and where pumping has been the greatest, had some of the largest long-term groundwater-level declines at a rate of about 0.8 foot/year between 1971 and 2021.

California

Peak streamflow trends and their relation to changes in climate in Illinois, Iowa, Michigan, Minnesota, Missouri, Montana, North Dakota, South Dakota, and Wisconsin

Flood-frequency analysis, also called peak-flow frequency or flood-flow frequency analysis, is essential to water resources management applications including critical structure design and floodplain mapping. Federal guidelines for doing flood-frequency analyses are presented in a U.S. Geological Survey Techniques and Methods report known as Bulletin 17C. A basic assumption within Bulletin 17C is that for drainage basins without major hydrologic alterations, statistical properties of the distribution of annual peak streamflows (peak flows) are stationary; that is, the mean, variance, and skew are constant. The stationarity assumption has been widely accepted within the flood-frequency community; however, a better understanding of long-term climatic persistence and concerns about potential climate change and land-use change has caused a reexamination of the stationarity assumption. This work is part of that reexamination. The stationarity assumption is a concern because flood-frequency analyses that do not incorporate observed trends and abrupt changes may result in a poor representation of the true flood risk. Bulletin 17C does not offer guidance for incorporating nonstationarities when estimating floods, and it describes a need for studies that incorporate changing climate or basin characteristics. In response to this need and a history of concern regarding nonstationarity peak flows in the region, this study was done to assess potential nonstationarity in peak flows in the north-central United States. This report summarizes the methods used to detect hydroclimatic changes in peak-flow data in the study region. Four periods were selected for analysis of peak flow, daily streamflow, and climate data. The periods are (1) a 100-year period, 1921–2020; (2) a 75-year period, 1946–2020; (3) a 50-year period, 1971–2020; and (4) a 30-year period, 1991–2020. The starting point for these analyses was the initial data analysis of peak flow described in Bulletin 17C, which includes plotting the peak flow and checking for autocorrelation, monotonic trends, and changes points. Analyses were added to examine additional features in the data. Results are provided in a U.S. Geological Survey data release. The study limitations are documented for users of the results.

Scientific Investigations Report

Distribution of ancient carbon in groundwater and soil gas from degradation of petroleum near the Red Hill Bulk Fuel Storage Facility, O‘ahu, Hawai‘i

The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.

Hawaii

Insights and strategic opportunities from the USGS 2024 Per- and Polyfluoroalkyl Substances (PFAS) Interagency Workshop

Introduction In 2021, the U.S. Geological Survey (USGS) published Circular 1490 titled, “Integrated Science for the Study of Perfluoroalkyl and Polyfluoroalkyl Substances (PFAS) in the Environment: A Strategic Science Vision for the U.S. Geological Survey” (Tokranov and others, 2021). Circular 1490 was created to be a resource for USGS scientists prioritizing and planning research related to per- and polyfluoroalkyl substances (PFAS) and to be a guide for developing partnerships with other scientists, State and Federal agencies, and stakeholders engaged in PFAS research and management and mitigation of the environmental and human-health effects of PFAS. This USGS PFAS Strategic Science Vision document was intended to be the foundation for a “living strategic vision,” periodically providing updates on the state of USGS PFAS research, emerging PFAS data gaps and needs, and progress on interagency and stakeholder PFAS partnerships and priorities. To meet this objective, the USGS planned to host an Interagency and Stakeholder PFAS Workshop every 2–3 years. During September 10–12, 2024, the USGS hosted the first Interagency and Stakeholder PFAS Workshop in Reston, Virginia. The Workshop brought together experts from other Federal agencies (U.S. Environmental Protection Agency, National Institute of Environmental Health Sciences, Food and Drug Administration, Department of Defense [Air Force, Army]), State agencies (Washington Fish and Wildlife, Virginia Department of Transportation), and academia (Harvard University, University of Maryland) to address key challenges relating to the measurement and modeling of PFAS and the implications for environmental health. Participants engaged in in-depth discussions centered around six pivotal topics related to PFAS: (1) sampling protocols, methods and interpretation; (2) environmental sources, source apportionment, and occurrence; (3) environmental fate and transport; (4) human and wildlife exposure routes and risk; (5) bioconcentration, bioaccumulation, and biomagnification; and (6) ecotoxicology and effects. Each topic had three breakout sessions. A recurrent theme of workshop discussions was how data on a nationwide scale for PFAS occurrence in various environmental matrices, including air, water, food crops, biota, soil, and streambed sediment could help to advance scientific understanding. Participants noted significant geospatial data gaps, particularly in the midwestern and southern United States and the Pacific Northwest. PFAS data collection tends to be more robust along the eastern seaboard and in California. Participants stressed how enhancing the integration of large and small datasets across various agencies could help to support national scale understanding of PFAS. To address these gaps, attendees suggested leveraging datasets from Federal entities like the USGS and the U.S. Department of Defense, State agencies, and municipal utility services to develop predictive contaminant detection and transport models. Improved coordination between water quality programs and USGS research could help to facilitate access to valuable data, leading to comprehensive databases that inform PFAS point (wastewater treatment plants and landfills) and nonpoint (runoff from land, atmospheric deposition, food packaging) sources, environmental transport mechanisms, environmental detection and concentrations, potential exposure routes, and health effects on different biota, including humans. A specific request was made to develop a map demarking the depth of modern (1953 or later) groundwater, which is susceptible to surface-derived anthropogenic (that is, human-made) contamination, based on tritium-age dating. Emphasis was placed on incorporation of hydrology, groundwater flow paths, groundwater–surface water interactions, and landscape factors in predictive statistical models as a step to improve contaminant source identification and tracking. Molecular fingerprinting approaches garnered attention as techniques to link specific PFAS mixtures detected in a sample to environmental sources and levels in biota (Dávila-Santiago and others, 2022). Integrating data from abiotic (that is, water, soil, and air) and biotic (that is, living organisms) systems identified as a research opportunity. For example, understanding the composition of soils and sediments, which include a mixture of mineral, plant, and animal components, could advance understanding of exposure pathways. The discussions highlighted opportunities to explore and understand the potential redistribution and biotic exposures of PFAS from biosolid and wastewater treatment plant effluent land application practices, in addition to atmospheric releases and discharges from landfill and wastewater treatment plants. Participants identified research gaps surrounding how these sources may contribute to contamination and may affect surrounding ecosystems, including a better definition of anthropogenic background concentrations. Moving forward, the collection of co-occurrence data was noted as a means to improve understanding of complex mixtures and to leverage companion modeling efforts focused on areas with high and low contamination levels to identify areas of concern and unaffected resources. Participants emphasized how centralized USGS databases and the establishment of sample-metadata archives can help to ensure that samples are preserved and accessible for future research. In conclusion, the workshop participants identified opportunities to bridge data gaps and improve measurement techniques, modeling frameworks, databases, and communication, to enhance the understanding of PFAS and their effects on environmental and human health. Upon completion of the workshop, participants indicated an interest in developing strategic data collection, modeling, and analytical approaches to address these challenges.

Open-File Report

Ten new insights in climate science 2025

Interdisciplinary understanding is vital for delivering sound climate policy advice. However, navigating the ever-growing and increasingly diverse scholarly literature on climate change is challenging for any individual researcher. This annual synthesis highlights and explains recent advances across a variety of fields of climate change research. This year, the 10 insights focus on: (1) the record-warmth of 2023/2024 and the elevated Earth energy imbalance; (2) acceleration of ocean warming and intensifying marine heatwaves; (3) northern land carbon sinks under strain; (4) reinforcing feedback between biodiversity loss and climate change; (5) accelerated depletion of groundwater; (6) global dengue incidence; (7) global income losses and labour productivity declines; (8) strategic scaling of CDR; (9) integrity challenges in carbon credit markets and emerging responses; and (10) effective policy mixes for emissions reductions. The insights have been written to be accessible to researchers from different fields, serving as entry-points to specific topics, as well as providing an overview of the evolving landscape of climate change research. In the final section, the insights are used to develop overarching policy-relevant messages. This paper provides the basis for a science-policy report that was shared with all Party delegations ahead of COP30 in Belém, Brazil.

Global Sustainability

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–2023, California groundwater ambient monitoring and assessment program, priority basin project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–2023. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban- and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert-butyl ether (MTBE) showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids (TDS) statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in TDS by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and MTBE are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

EarthArXiv

Near-surface geophysics: Environmental applications

The field of geophysics encompasses a broad and diverse compilation of methodologies that employs principles of physics to characterize properties of earth materials within the subsurface. While geophysical methods have a long history in resource exploration and studies of Earth’s interior, the subdiscipline of “near-surface geophysics” has evolved in recent decades for examination of the shallow, near-surface environment for a range of purposes ranging from archaeological or forensic investigations to assessment of geologic, hydrologic, biologic, and geochemical properties and processes. “Environmental geophysics” are near-surface geophysical studies and methods that focus on understanding natural systems (e.g., watershed hydrology, groundwater–surface water connections, biophysical processes) as well as research pertaining to anthropogenic impacts and land management, (e.g., contamination and remediation, saltwater intrusion, agricultural practices). This field can be further subdivided into subdisciplines focused on specific topics and applications, such as water resources and hydrology (hydrogeophysics) or biologic and microbial processes (biogeophysics). Studies in environmental geophysics span a range of scales, from pore-scale laboratory tests to watershed-scale or regional field experiments. Methods vary by the nature of physics employed, the specific measurement acquired, and how that data is ultimately processed and analyzed to produce interpretable results. There exists further diversity in the acquisition logistics, geometry, and timing of data collection. Geophysical data can be collected in boreholes (one-dimensional, 1-D, vertical profiles), along survey lines (two-dimensional, 2-D, cross-sections), or in dense sensor arrays or gridded profiles (three-dimensional, 3-D, models). Regarding the temporal aspect, studies can conduct one-time geophysical surveys to obtain detailed imaging of subsurface structure or use timelapse and continuous monitoring to investigate variations in subsurface properties over time. The cumulation of all possible permutations of these factors (method, acquisition geometry, survey design, and target application) results in an immense diversity among environmental geophysical studies. Nevertheless, this field remains unified in the pursuit of understanding natural and human-impacted near-surface environments through geophysical investigations. Here we highlight some key references within environmental geophysics. Resources on geophysical theory, acquisition logistics, processing and inversion workflows, and example case studies are categorized into the most common geophysical classes within Geophysical Methods. Lastly, example references for the dominant types of applications in environmental geophysical studies are catalogued in Environmental Applications.

Book chapter