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Results for “Journal of Comparative Physiology A”

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Climate-driven sulfate export in alpine watersheds may stimulate methylmercury production

Climate change is increasing sulfate export and changing wetland extent in mountain regions. These changes may increase microbially mediated production of the neurotoxic substance methylmercury due to enhanced sulfate metabolism in mountain environments. Here, we assess methylmercury concentrations and formation rates across high-elevation wetlands in the Colorado Rocky Mountains. We also investigate sulfate controls on methylmercury production within subalpine peatlands by amending soils with sulfate to mimic increased stream export of sulfate from the alpine zone and measuring methylmercury formation rates for different sulfate treatments. We found that subalpine peatlands have statistically significant higher methylmercury concentrations and formation rates compared to alpine, mineral-soil wetlands. Methylmercury production in subalpine peatlands also increased significantly ( p < 0.05) following sulfate additions; the highest rates occurred in sediments with intermediate extractable sulfate concentrations (∼0.60–1.4 mg sulfate g −1 dry soil). Our study is the first to identify soil sulfate-related thresholds for methylmercury production and sulfate-limitation of methylmercury production in subalpine peatlands. These findings highlight important linkages between climate-driven mineral weathering and mercury cycling in mountain regions globally.

Colorado

The SCEC/USGS community stress drop validation study using the 2019 Ridgecrest earthquake sequence

We introduce a community stress drop validation study using the 2019 Ridgecrest, California, earthquake sequence, in which researchers are invited to use a common dataset to independently estimate comparable measurements using a variety of methods. Stress drop is the change in average shear stress on a fault during earthquake rupture, and as such is a key parameter in many ground motion, rupture simulation, and source physics problems in earthquake science. Spectral stress drop is commonly estimated by fitting the shape of the radiated energy spectrum, yet estimates for an individual earthquake made by different studies can vary hugely. In this community study, sponsored jointly by the U. S. Geological Survey and Southern/Statewide California Earthquake Center, we seek to understand the sources of variability and uncertainty in earthquake stress drop through quantitative comparison of submitted stress drops. The publicly available dataset consists of nearly 13,000 earthquakes of M1 to 7 from two weeks of the 2019 Ridgecrest sequence recorded on stations within 1-degree. As a community study, findings are shared through workshops and meetings and all are invited to join at any time, at any interest level.

Seismica

Critical Minerals in Ores (CMiO) database

Critical minerals are commodities essential to modern industrial and strategic technologies and are highly vulnerable to supply chain disruption. The Critical Minerals Mapping Initiative (CMMI) is a collaboration among the U.S. Geological Survey (USGS), the Geological Survey of Canada, and Geoscience Australia that aims to deepen global understanding of where critical minerals are located. A key output of this initiative is the Critical Minerals in Ores (CMiO) database that is advancing our collective understanding of critical minerals distributions. For instance, publicly available data on the concentrations of many critical minerals are sparse because these commodities can only be produced in small, yet essential, quantities compared to the primary commodities like copper and zinc. The CMiO database helps bridge this gap by offering high-quality, multielement geochemical data from a wide variety of critical mineral-bearing deposits around the world. Importantly, it uses a novel consensus deposit environment, group, and type classification scheme developed by the agencies that allows comparisons among ore deposits from different regions. The CMiO database contains geochemical data for more than 20,000 samples from more than 100 deposit types comprising 10 deposit environments.

Fact Sheet

Estimating paleotemperature using stable isotopes of soil-formed phyllosilicates from paleosols: A review

Fossilized soils, or paleosols, contain soil-formed phyllosilicates whose stable isotopic compositions may be used to calculate paleotemperature and thus reconstruct ancient terrestrial environments. Though paleosols are common in the geologic record, the use of phyllosilicates as paleotemperature proxies is limited in the literature owing to difficulties with selecting optimal paleosols, isolation from non-clay minerals and organic materials, mixtures of phyllosilicates in natural samples, wide variations of chemical compositions for phyllosilicates, and limited to undefined equilibrium fractionation factors between phyllosilicates-water. Here, we address these challenges by examining and comparing methods used for sample selection, mineral isolation, pretreatments, mineral identification, conventional and developing methods for oxygen and hydrogen isotopic analyses, and determination of phyllosilicate-water equilibrium fractionation factors, concluding with recommendations for best approaches for paleotemperature estimation. Additionally, we discuss how to identify and avoid detrital phyllosilicates, the impacts of diagenesis, comparison of stable isotope and non-isotope paleosol paleotemperature proxies, and challenges and opportunities for broadly using paleosols as paleoclimate archives. With ongoing efforts to refine this multi-faceted paleotemperature approach, the stable isotope geochemistry of soil-formed phyllosilicates continues to be an invaluable proxy system, enhancing our understanding of terrestrial paleoenvironments and paleoclimate.

Kansas

Deformed submarine terraces in Puget Sound, Pacific Northwest, indicate only one M >~7.5 earthquake on the Seattle fault zone in the past 11,000 yr

Submerged marine terraces in Puget Sound, deformed across the Seattle fault zone (SFZ), indicate that only one earthquake as large as M~7.5 has occurred in at least the past 11 kyr. Previous paleoseismic studies document a M~7.5 earthquake between 923–4 CE, which uplifted coastal marine terraces by as much as 8 m. We demonstrate that this earthquake was the only such event since ~11 ka by mapping and quantifying deformation of older marine terraces, now submerged in Puget Sound. The submerged terraces, attributed to a late-glacial sea-level lowstand, record both glacial isostatic rebound and tectonic deformation. Vertical offset of the ~11 ka terraces within the SFZ is comparable to that of the marine terraces uplifted in 923 CE, implying no additional large (M>~7.5) earthquake on the SFZ since ~11 ka. This result implies a longer recurrence interval than current hazard estimates, which assumes recurrence of M>7.1 events every 5 kyr. Our mapping of SFZ deformation since ~11 ka also supports fault segmentation and contiguous block uplift between the Seattle and Tacoma fault zones.

Washington

Teach me how to pycap: A high-capacity well decision support tool using analytical solutions in Python

Regulatory agencies in humid temperate environments rely on timely evaluations of streamflow depletion and drawdown to protect aquatic ecosystems and existing water users. Numerical models offer detailed insights, but their complexity and time demands often preclude their practical use in rapid decision-making. We present pycap-dss, an open-source Python package that implements a suite of analytical solutions for estimating streamflow depletion and drawdown. The tool supports superposition of multiple wells and time-varying pumping, enabling cumulative impact assessments in situations with multiple wells and streams. The software is modular and extensible, allowing users to interchange solutions or add new analytical methods. A YAML-based configuration supports batch processing of multiple wells, and an optional AnalysisProject class facilitates integration with regulatory workflows. Rigorous unit and regression testing ensures computational reliability, and continuous integration supports ongoing development. We demonstrate deterministic examples of drawdown where multiple solutions are readily compared and streamflow depletion with multiple wells in the Central Sands region of Wisconsin. We also show the value of Monte Carlo analyses of streamflow depletion in the same Central Sands example, leveraging computational efficiency to evaluate the uncertainty of individual and cumulative streamflow depletion calculations from over 200 high-capacity wells.

Wisconsin

Hydrogeology and groundwater quality in the Snake River alluvial aquifer at Jackson Hole Airport, Wyoming, 2011–20

The Snake River alluvial aquifer underlying the Jackson Hole Airport (JHA) in northwest Wyoming is an important source of water used for domestic, commercial, and irrigation purposes by the airport and nearby residents. The U.S. Geological Survey, in response to previously identified water-quality concerns in the area, monitored and evaluated changes in hydrogeologic characteristics and groundwater-quality conditions of the alluvial aquifer during 2011–20. During that period, the Jackson Hole Airport made several changes that potentially improved water quality at and downgradient from the airport. Well, water level, and hydrogeologic data were collected from the alluvial aquifer to identify hydrogeologic characteristic and groundwater quality changes. Additionally, results of statistical tests were applied to water-quality results to evaluate trends in selected physical properties and constituent concentrations with time. The trends of those data show that water quality did improve overall during the study period compared to previously collected data. Presumably, these trends are in response to the changes in the aircraft deicing/anti-icing fluid (ADAF) formulation used by the JHA, the many JHA infrastructure improvements made during 2011–20, the degradation of existing ADAFs in subsurface soils and groundwater, or some combination of these possibilities.

Wyoming

A soil velocity model for improved ground motion simulations in the U. S. Pacific Northwest

Near-surface seismic velocity structure may significantly impact the intensity, duration, and frequency content of ground shaking during an earthquake. In this study, we compile 649 shear wave velocity (Vs) profiles throughout the U.S. Pacific Northwest and southern British Columbia (PNW) and use these measured profiles to develop a representative soil velocity model for four major Holocene soil provinces: Puget Lowlands, Willamette Valley, fill and alluvium, and `other' soils. The resulting soil velocity model shows good agreement to measured data for a wide range of site conditions, with variability between different geologic domains reflecting fundamental differences in depositional environments. We then show that using this regional soil velocity model in simulations of the 2001 M6.8 Nisqually, Washington earthquake improves the fit to observed high-frequency (≥ 0.5 Hz) ground motions in the Puget Sound region compared to simulations that do not incorporate shallow (≤ 200 m) seismic velocity structure. Overall, this work shows that incorporating localized soil velocity profiles into seismic velocity models is important for accurately estimating high-frequency ground motion and regional seismic hazard in earthquake simulations. Future earthquake simulations and hazard studies in the PNW could incorporate these soil velocity profiles to capture the region's distinct site response characteristics.

Washington

Rapid earthquake magnitude classification via P-wave strains from borehole strainmeters and Distributed Acoustic Sensing

Distributed Acoustic Sensing (DAS) offers a promising approach for earthquake early warning (EEW) in settings where seismic networks are costly to maintain. By repurposing fiber-optic cables as dense strainmeter arrays, DAS enables real-time earthquake detection wherever those fibers are accessible. However, poor azimuthal coverage and challenges in estimating magnitude from strain measurements remain key hurdles in applying for earthquake monitoring. Here, we develop a machine learning method to distinguish large (M≥5.4) earthquakes from smaller ones within the first 4 seconds of a strain waveform after a P-wave arrival without determining location. Using ensemble decision tree models trained on borehole strainmeter data (3.5≤M≤7.1) and tested on onshore DAS waveforms (including the 2024 M7 Offshore Cape Mendocino earthquake), we find that low-frequency (0.2–0.5 Hz) continuous wavelet transform coefficients are the strongest predictors of magnitude, in addition to strain amplitude. Both DAS and borehole strainmeters effectively capture long-period strain signals, making these findings valuable for EEW systems. Our method shows high precision compared to the real-time EEW system, ShakeAlert®, supporting the position that DAS is a viable technology for earthquake monitoring and magnitude classification.

California

Comparison of two approaches for determining ground-water discharge and pumpage in the lower Arkansas River Basin, Colorado, 1997-98

In March 1994, the Colorado Division of Water Resources (CDWR) adopted “Rules Governing the Measurement of Tributary Ground Water Diversions Located in the Arkansas River Basin” (Office of the State Engineer, 1994); these initial rules were amended in February 1996 (Office of the State Engineer, 1996). The amended rules require users of wells that divert tributary ground water to annually report the water pumped monthly by each well. The rules allow a well owner to report the pumpage measured by a totalizing flowmeter (TFM) or pumpage determined from electrical power data and a power conversion coefficient (PCC) (Hurr and Litke, 1989). Opinions by representatives of the State of Kansas, presented before the Special Master hearing a court case [State of Kansas v. State of Colorado, No. 105 Original (1996)] concerning post-Compact well pumping, stated that the PCC approach does not provide the same level of accuracy and reliability as a TFM when used to determine pumpage. In 1997, the U.S. Geological Survey (USGS), in cooperation with the CDWR, began a 2-year study to compare ground-water pumpage estimates made using the TFM and the PCC approaches. The study area was along the Arkansas River between Pueblo, Colorado, and the Colorado-Kansas State line (fig. 1). The two approaches for estimating ground-water discharge and pumpage were compared for more than 100 wells completed in the alluvial aquifer of the Arkansas River Basin. The TFM approach uses an inline flowmeter to directly measure instantaneous discharge and the total volume of water pumped at a well. The PCC approach uses electrical power consumption records and a power conversion coefficient to estimate the pumpage at ground-water wells. This executive summary describes the results of the comparison of the two approaches. Specifically, (1) the differences in instantaneous discharge measured with three portable flowmeters and measured with an inline TFM are evaluated, and the statistical differences in paired instantaneous discharge between the two approaches are determined; (2) short- and long-term variations in the PCC’s are presented; (3) differences in pumpage between the two approaches are evaluated, and the statistical differences in pumpage between the two approaches are determined; (4) potential sources of discrepancy between pumpage estimates are discussed; and (5) differences in total network pumpage using the two approaches are presented. During the irrigation seasons of 1997 and 1998, instantaneous discharge and electrical power demand were measured at randomly selected wells to determine PCC’s. At more than 100 wells, the PCC’s determined during the 1998 season were applied to total electrical power consumption data that was recorded between the initial and final readings at each network well site in 1998 to estimate total ground-water pumpage. At each site, an inline TFM was installed in a full-flowing, acceptable test section of pipe on the discharge side of the pump where the measurement of discharge was made. Measurements of instantaneous ground-water discharge also were made using three different types of portable flowmeters. The average velocity multiplied by the cross-sectional area of the discharge pipe was used to compute the discharge in gallons per minute. Whenever possible, discharge measurements were made at each network site using all three types of portable flowmeters.

Colorado

Turbidite correlation for paleoseismology

Marine turbidite paleoseismology relies on the assumption of synchronous triggering of turbidity currents by earthquake shaking to infer rupture extent and recurrence. Such inference commonly depends on age dating and correlation of the physical stratigraphy of deposits carried by turbidity currents (i.e., turbidites) across great distances. Along the Cascadia subduction zone, which lies offshore the Pacific Northwest, USA, turbidite facies in core photographs, X-ray computed tomography images, and magnetic susceptibility (MS) data exhibit differences in character over relatively short distances, which implies that not all deposits can be correlated with confidence. Thus, subjective correlation based on expected similarity over great distances and weak age constraints does not independently support paleoseismic models. We present a new method for correlating turbidites along the Cascadia margin that can yield a more objective and repeatable stratigraphic framework to underpin earthquake recurrence. We use dynamic time warping to correlate MS logs and measure correlation coefficients of core pairs to evaluate correlation strength. We then compare these measures to a distribution of correlation coefficients of randomly generated turbidite sequences and find that only a small number of core pairs can be correlated more confidently than randomly stacked turbidites. This methodology promises a more robust correlation strategy for future stratigraphic studies.

Oregon, Washington

SlideDetect: Spatio-temporal landslide detection using a three-dimensional convolutional neural network

Landslides pose a serious and ongoing threat to both human lives and infrastructure worldwide; therefore, it is of interest to predict where and when landslides are likely to occur. Advances in machine learning techniques have spurred numerous studies aimed at estimating relative landslide propensity, but are limited to spatial (as opposed to temporal) prediction due to the sparsity of landslide timing data. We address this data gap by training SlideDetect, a 3-dimensional convolutional neural network (3D CNN), to identify landslides based on their spatial and temporal occurrence within multitemporal image stacks. We use an inventory of landsides triggered by the 2018 Hokkaido earthquake and two years of monthly composite optical imagery spanning this event. The model can identify not only landslide location but also landslide date with an area under the precision-recall curve (PR-AUC) of 0.84. We further present a new standard for presenting PR curve results that explicitly compares model performance at different confidence thresholds, allowing for clearer model evaluation and comparison. Our new approach to constraining landslide timing paired with this more consistent and objective method for evaluating model performance shows considerable promise, and with further application and testing, SlideDetect could enhance the data availability and tools needed to advance landslide hazard and risk assessments.

JGR Machine Learning and Computation

Testing characteristic magnitude distributions in modern PSHA models

The characteristic magnitude distribution hypothesis predicts a higher rate of large earthquakes than a Gutenberg–Richter extrapolation of the small‐earthquake rate would imply. Characteristic magnitude distributions have been commonly applied to faults in probabilistic seismic hazard analysis (PSHA), and in modern models they can emerge from the way short‐term seismicity constraints are combined with long‐term geologic and geodetic constraints. We test the characteristic magnitude distribution hypothesis by comparing the fault‐based magnitude distributions from the 2023 update to the National Seismic Hazard Model (NSHM23) in the Western United States with observed seismicity over the past 93 yr. We find that observed magnitude distributions fall outside the model‐predicted confidence bounds in regions where NSHM23 produces characteristic magnitude distributions: in these regions, the model predicts higher rates of large earthquakes than are observed. An analysis of the earlier California model (Uniform California Earthquake Rupture Forecast, version 3) also reveals discrepancies between the modeled and observed magnitude distributions. In addition, we find that observed magnitude distributions near modeled faults are not significantly different from those in background regions. These results challenge the prevalence of characteristic magnitude distributions in fault‐based seismic hazard models and call for a reassessment of how disparate data sets are integrated in PSHA.

western United States

Simulation of groundwater flow in the Silurian aquifer, eastern Iowa, 2020–45

The Silurian aquifer is an important water source for municipalities, industry, and rural households and communities in eastern Iowa, including Johnson County. Increasing demand for groundwater from the aquifer indicated that analytical tools may be beneficial to quantify groundwater resources and inform water-management decisions for the aquifer. The U.S. Geological Survey, in cooperation with the Johnson County Board of Supervisors, developed conceptual and numerical groundwater models to simulate water levels in the Silurian aquifer, determine groundwater budgets, and forecast changes in groundwater levels through 2045. A MODFLOW numerical model was constructed to match water levels for 2020 through 2022. Model performance was assessed by comparing simulated and observed water-level hydrographs at several pumping and monitoring wells. Hydrograph comparison indicates that the model simulates water levels accurately at monitoring wells that are not near areas of pumping and generally overpredicts water levels near pumping wells, while accurately simulating the drawdown trend over time at pumping wells. This transient model framework was then used to predict water levels through 2045 in a scenario of moderate drought and increased groundwater withdrawals. Results from the predictive model indicate as much as 13 meters of additional drawdown in 2045 from 2020 water levels in the area of pumping wells.

Iowa

Classification of lakebed geologic substrate in autonomously collected benthic imagery using machine learning

Mapping benthic habitats with bathymetric, acoustic, and spectral data requires georeferenced ground-truth information about habitat types and characteristics. New technologies like autonomous underwater vehicles (AUVs) collect tens of thousands of images per mission making image-based ground truthing particularly attractive. Two types of machine learning (ML) models, random forest (RF) and deep neural network (DNN), were tested to determine whether ML models could serve as an accurate substitute for manual classification of AUV images for substrate type interpretation. RF models were trained to predict substrate class as a function of texture, edge, and intensity metrics (i.e., features) calculated for each image. Models were tested using a manually classified image dataset with 9-, 6-, and 2-class schemes based on the Coastal and Marine Ecological Classification Standard (CMECS). Results suggest that both RF and DNN models achieve comparable accuracies, with the 9-class models being least accurate (~73–78%) and the 2-class models being the most accurate (~95–96%). However, the DNN models were more efficient to train and apply because they did not require feature estimation before training or classification. Integrating ML models into benthic habitat mapping process can improve our ability to efficiently and accurately ground-truth large areas of benthic habitat using AUV or similar images.

Michigan, Wisconsin

The feasibility of using lidar-derived digital elevation models for gravity data reduction

Gravity data require submeter elevation accuracy for data processing, and differential global navigation satellite system (dGNSS) equipment is commonly used to acquire three-dimensional positional data to achieve such accuracy. However, lidar (light detection and ranging) data are commonly used to develop digital elevation models (DEMs) of Earth’s surface. Therefore, using elevations from lidar-derived DEMs for gravity-data acquisition and reduction may improve field efficiency and reduce cost. This study examines the feasibility of using DEMs for gravity-data reduction by comparing dGNSS elevation data from 435 gravity stations in Michigan, Wyoming, and Colorado with their respective DEM elevations. The results show that the average difference between DEM and dGNSS elevations is 13 centimeters (cm) and that 93 percent of those differences are less than 50 cm, even in areas with steep terrain. Because an elevation discrepancy of 50 cm corresponds to an error of roughly 0.1 milligals (mGal) in the simple Bouguer gravity anomaly, the results suggest that lidar-derived DEMs are a viable source for acquiring the elevation data needed to process gravity data, thus improving both the cost and efficiency of data collection for regional surveys where an accuracy of less than 1.0 mGal is desired.

Open-File Report

Compact seismicity bursts have different characteristics from regional seismicity

Earthquakes tend to cluster, developing into sequences driven by stress perturbations and transient fault-zone processes. Depending on the driving process, earthquake sequences show differing behaviors. This variability challenges our ability to observe or distinguish these driving processes in high resolution. Here we systematically identify seismicity bursts throughout southern California using new statistical methods and examine their causes with other independent geophysical observations. Seismicity bursts are defined as statistically significant seismicity rate anomalies. Our approach has the advantage of being data driven, depending on few earthquake occurrence assumptions. We find abundant seismicity bursts across southern California, most frequently occurring along the San Jacinto Fault and in the Salton Sea and Coso geothermal fields. These seismicity bursts are highly compact in space and time, often encompassed by a 5 km radius and have durations less than 10 hr. Many of the seismicity bursts have their largest earthquake near the beginning of the sequence, but the largest earthquake is usually not an obvious mainshock. We utilize a variety of independent geophysical data sets to analyze the characteristics of the seismicity bursts, finding that the seismicity bursts have low b-values, low spectral stress drops, and varied stress ratios compared to regional seismicity. These differences suggest that seismicity bursts are driven by transient processes acting frequently across fault networks.

California

Examining the compositional selectivity of hydrocarbon oxidation products using liquid–liquid extraction and solid-phase extraction techniques

The effect of extraction methods on detecting hydrocarbon oxidation products (HOPs) in groundwater remains unclear. HOPs are polar, water-soluble byproducts of petroleum biodegradation. Our previous work showed that liquid–liquid extraction (LLE), a method commonly used in regulatory monitoring, has a significantly lower extraction efficiency for HOPs compared to solid-phase extraction (SPE). In this study, we evaluate the analytical limitations and compositional selectivity of LLE and SPE using groundwater samples from the Bemidji, MN, crude oil spill site. Optical properties were characterized using excitation–emission matrix spectroscopy (EEMs), and a three-component PARAFAC model was validated, showing consistent trends across both extracts and whole water samples. Ultrahigh-resolution mass spectrometry (UHR-MS) revealed that LLE selectively recovered aliphatic-like compounds but underrepresented more polar oxygenated HOPs. In contrast, SPE methods were more effective at isolating highly oxidized compound classes. These differences were consistent across a gradient of contamination. Overall, the LLE was less precise and less representative of polar HOPs, introducing bias in the characterization of HOPs. This study is the first to quantitatively demonstrate the compositional selectivity and analytical bias of LLE versus SPE for HOPs using combined EEM-PARAFAC and UHR-MS techniques, with implications for long-term monitoring and site assessment protocols.

Environmental Science and Technology