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At least 271 records · Page 15Linked to original sources

USGS2021

Mainstems: A logical data model implementing mainstem and drainage basin feature types based on WaterML2 Part 3: HY Features concepts

The Mainstems data model implements the catchment and flowpath concepts from WaterML2 Part 3: Surface Hydrology Features (HY_Features) for persistent, cross-scale, identification of hydrologic features. The data model itself provides a focused and lightweight method to describe hydrologic networks with minimum but sufficient information. The design is intended to provide a model for data integration that can be used for network navigation and persistent hydrologic indexing (hydrographic addressing) functionality. Mainstems is designed to provide long-term stability with minimal maintenance requirements. The data model is not meant to advance hydrologic process representation or uniquely represent geomorphic characteristics. The principle assumption in Mainstems is that all drainage basins have one - and only one - headwater source area and a single mainstem that flows to a single outlet . Using these base feature types, ( headwater , outlet , mainstem , and drainage basin ) a nested set of drainage basins - and the associated dendritic network of mainstems - can be identified.

Environmental Modelling and Software↗

USGS2009

Biological soil crusts exhibit a dynamic response to seasonal rain and release from grazing with implications for soil stability

In Northern Mexico, long-term grazing has substantially degraded semiarid landscapes. In semiarid systems, ecological and hydrological processes are strongly coupled by patchy plant distribution and biological soil crust (BSC) cover in plant-free interspaces. In this study, we asked: 1) how responsive are BSC cover/composition to a drying/wetting cycle and two-year grazing removal, and 2) what are the implications for soil erosion? We characterized BSC morphotypes and their influence on soil stability under grazed/non-grazed conditions during a dry and wet season. Light- and dark-colored cyanobacteria were dominant at the plant tussock and community level. Cover changes in these two groups differed after a rainy season and in response to grazing removal. Lichens with continuous thalli were more vulnerable to grazing than those with semi-continuous/discontinuous thalli after the dry season. Microsites around tussocks facilitated BSC colonization compared to interspaces. Lichen and cyanobacteria morphotypes differentially enhanced resistance to soil erosion; consequently, surface soil stability depends on the spatial distribution of BSC morphotypes, suggesting soil stability may be as dynamic as changes in the type of BSC cover. Longer-term spatially detailed studies are necessary to elicit spatiotemporal dynamics of BSC communities and their functional role in biotically and abiotically variable environments. ?? 2009 Elsevier Ltd.

Journal of Arid Environments↗

USGS2025

Monitoring visitor activity and informal trail disturbance in Yosemite Valley meadows to assess temporal changes in use and impacts

Montane meadows provide vital habitat that supports ecosystems, regulate hydrological processes, and offer valuable recreational opportunities. Meadows account for 3 % of Yosemite National Park's area, including Yosemite Valley, and are particularly susceptible to human impacts such as formation of informal trails. We collected observational data on visitor activity and quantified social trail disturbance to compare with resource monitoring datasets and through similar parameters to Walden-Schreiner and Leung (2013) who studied visitor use and behavior in three Yosemite Valley meadows in 2011. We documented change in number of visitors per hour and primary activity pursued. We also compared trends of meadow disturbance (informal trail length and disturbed area) from the early 2000s - 2023. Informal trail length at El Capitan Meadow decreased from 2004 to 2018, followed by recent increases. Disturbed area for Cooks A, Sentinel A, Slaughterhouse B, Stoneman A, and Stoneman B sub-meadows increased from 2006 to 2023. Between 2011 and 2023, the proportion of those engaged in active versus stationary pursuits showed that visitors engaged in more active pursuits in two of three meadows. Moreover, there were >3.5 times more visitors per hour in Cooks, El Capitan, and Leidig meadows in 2023 compared to 2011, yet, most visitors utilized designated trails. Meadow locational context was linked to activity preference and types of impacts. Management strategies, such as fencing and signage have been effective at minimizing impacts in several meadows. Parsing nuances of informal trail use and drivers of disturbance for various meadows is crucial for informed park management decisions and actions.

California↗

USGS2017

Enhancing wind erosion monitoring and assessment for U.S. rangelands

On the Ground Wind erosion is a major resource concern for rangeland managers because it can impact soil health, ecosystem structure and function, hydrologic processes, agricultural production, and air quality. Despite its significance, little is known about which landscapes are eroding, by how much, and when. The National Wind Erosion Research Network was established in 2014 to develop tools for monitoring and assessing wind erosion and dust emissions across the United States. The Network, currently consisting of 13 sites, creates opportunities to enhance existing rangeland soil, vegetation, and air quality monitoring programs. Decision-support tools developed by the Network will improve the prediction and management of wind erosion across rangeland ecosystems.

Rangelands↗

USGS2018

Insights from long-term ungrazed and grazed watersheds in a salt desert Colorado Plateau ecosystem

Dryland ecosystems cover over 41% of the earth’s land surface, and living within these important ecosystems are approximately 2 billion people, a large proportion of whom are subsistence agropastoralists. Improper grazing in drylands can negatively impact ecosystem productivity, soil conservation, hydrologic processes, downstream water quantity and quality, and ultimately human health and economic well-being. Concerns regarding the degraded state of western US rangelands in the 1950s resulted in an interagency committee to study the effects of land use on runoff and erosion processes. In 1953, a federal research group established four paired watersheds in western Colorado to study the interaction of grazing by domestic livestock, runoff, and sediment yield. Exclusion of livestock from half of the watersheds dramatically reduced runoff and sediment yield after the first 10 yr—primarily due to changes in ground cover but not vegetation. Here, we report results of repeated soils and vegetation assessments of the experimental watersheds after more than 50 yr of grazing exclusion. Results show that many of the differences in soil conditions between grazed and ungrazed watersheds observed in the 1950s and 1960s were still present in 2004, despite reduced numbers of livestock: few differences in vegetation cover but large differences in biological soil crusts, soil stability, soil compaction, and soil biogeochemistry. There were differences among soil types in response to grazing history, especially soil lichen cover and soil organic matter, nitrogen, and sodium. Comparisons of ground cover measured in 2004 with those measured in 1953, 1966, and 1972 suggest much of the differences between grazed and ungrazed watersheds likely were driven by high sheep numbers during droughts in the 1950s. Persistence of these differences, despite large reductions in stocking rates , suggest the combination of overgrazing and drought may have pushed these salt desert ecosystems into a persistent, degraded ecological state.

Salt Desert Colorado Plateau Ecosystem↗

USGS2019

Effects of a changing climate on the hydrological cycle in cold desert ecosystems of the Great Basin and Columbia Plateau

Climate change is already resulting in changes in cold desert ecosystems, lending urgency to the need to understand climate change effects and develop effective adaptation strategies. In this review, we synthesize information on changes in climate and hydrologic processes during the last century for the Great Basin and Columbia Plateau, and discuss future projections for the 21st century. We develop mid-century projections of temperature and climate for the Great Basin and Columbia Plateau at timescales relevant to managers (2020 -2050), and discuss concepts and strategies for adapting to the projected changes. For the instrumented record in the Great Basin and Columbia Plateau (1985-2011), a temperature increase of 0.7°C to 1.4°C has been documented, but changes in precipitation have been relatively minor with no clear trends. Climate projections for 2020 to 2050 indicate that temperatures will continue to increase, especially in winter and during the night. Precipitation is more difficult to project and estimates range from an 11% decrease to 25% increase depending on location. Recent records indicate that the Great Basin and Columbia Plateau are becoming more arid, a trend that is projected to continue. Droughts are likely to become more frequent and last longer, invasive annual grasses are likely to continue to expand, and the duration and severity of wildfire seasons are likely to increase. Climate projections can help in developing adaptive management strategies for actual or expected changes in climate. Strategies include reducing the risks of nonnative invasive plant spread and wildfires that result in undesirable transitions, planning for drought, and where necessary, facilitating the transition of populations, communities and ecosystems to new climatic conditions. A proactive approach to planning for and adapting to climate change is needed and publicly available internet based resources on climate data and planning strategies are available to help meet that need.

California, Idaho, Nevada, Oregon, Utah, Washingto↗

USGS2026

Hydrologic variability drives environmental and geospatial relationships in Smallmouth Bass (Micropterus dolomieu) distribution

Hydrologic variation is a primary driver of stream ecosystems. Changing hydrology can lead to assemblage shifts and alterations in suitable habitat for freshwater species. As climate change is predicted to alter flow patterns in addition to increasing water temperatures, insight into relationships between species occupancy, hydrology, and temperature is critical for understanding current and future distributions. We examined how hydrologic variability, temperature, and other environmental variables interact to influence Micropterus dolomieu (Smallmouth Bass) occurrence. We used Spatial Stream Network models, allowing for the incorporation of spatial autocorrelation along streams' unique dendritic network, to examine Smallmouth Bass occupancy across a range of hydrologic variation in the Ozark-Ouachita Interior Highlands, USA. Hydrologic variation was the main driver of Smallmouth Bass occurrence, with occurrence more likely in groundwater streams with low hydrologic variation and high flow permanence. For groundwater streams, occurrence was positively associated with summer stream temperature and negatively associated with annual stream temperature. As variation increased, more variables showed significant relationships with occurrence. Distance metrics were important for all models, however as hydrologic disturbance increased, flow connected distance played a lesser role and stream distance played a greater role. Hydrologic variability was the overarching determinant of Smallmouth Bass occurrence and strongly influenced the predictive importance of environmental variables and geospatial relationships. Greater hydrologic variability resulted in stronger statistical relationships between occurrence and environmental variables and an increased importance of system connectivity. As climate change alters hydrologic processes and streams become more variable, understanding and accounting for these shifting relationships is essential.

Arkansas, Kansas, Missouri, Oklahoma↗

USGS2004

Subsurface fate of spilled petroleum hydrocarbons in continuous permafrost

Accidental releases of approximately 2000 m3 of fuel have resulted in subsurface contamination adjacent to Imikpuk Lake, a drinking-water source near Barrow, AK. This paper presents a conceptual model of the distribution and transport of subsurface free-phase hydrocarbons at this site. The mean annual temperature in Barrow is -13 ??C, and average monthly temperatures exceed 0 ??C only during the months of June, July, and August. As a result, the region is underlain by areally continuous permafrost that extends to depths of up to 300 m and constrains subsurface hydrologic processes to a shallow zone that temporarily thaws each summer. During the 1993 and 1994 thaw seasons, the measured depth of thaw varied across the site from approximately 0.5 to 2 m. However, exploratory borings in 1995 showed that free-phase hydrocarbons were present at depths greater than 3 m, indicating that permafrost at this site is not a barrier to the vertical migration of nonaqueous-phase liquids. In 1996, a subsurface containment barrier was installed to prevent lateral movement of contaminated water to Imikpuk Lake, and a recovery trench was excavated upgradient of the barrier to facilitate removal of free-phase hydrocarbons. Free-phase hydrocarbons were recovered from the trench during 1996, 1997, and 1998. Recovery rates diminished over this time, and in 1999, no further product was recovered and the recovery operation was halted. Subsequent exploratory borings in 2001 and 2002 have revealed that some product remains in the subsurface. Data indicate that this remaining product exists in small discrete pockets or very thin layers of hydrocarbon floating on brine. These small reservoirs appear to be isolated from one another by relatively impermeable permafrost. Published by Elsevier B.V.

Cold Regions Science and Technology↗

USGS2003

Summary of recent research in Long Valley Caldera, California

Since 1978, volcanic unrest in the form of earthquakes and ground deformation has persisted in the Long Valley caldera and adjacent parts of the Sierra Nevada. The papers in this special volume focus on periods of accelerated seismicity and deformation in 1980, 1983, 1989-1990, and 1997-1998 to delineate relations between geologic, tectonic, and hydrologic processes. The results distinguish between earthquake sequences that result from relaxation of existing stress accumulation through brittle failure and those in which brittle failure is driven by active intrusion. They also indicate that in addition to a relatively shallow (7-10-km) source beneath the resurgent dome, there exists a deeper (???15-km) source beneath the south moat. Analysis of microgravimety and deformation data indicates that the composition of the shallower source may involve a combination of silicic magma and hydrothermal fluid. Pressure and temperature fluctuations in wells have accompanied periods of crustal unrest, and additional pressure and temperature changes accompanying ongoing geothermal power production have resulted in land subsidence. The completion in 1998 of a 3000-m-deep drill hole on the resurgent dome has provided useful information on present and past periods of circulation of water at temperatures of 100-200??C within the crystalline basement rocks that underlie the post-caldera volcanics. The well is now being converted to a permanent geophysical monitoring station. ?? 2003 Elsevier B.V. All rights reserved.

Journal of Volcanology and Geothermal Research↗

USGS2007

Uranium(VI) release from contaminated vadose zone sediments: Estimation of potential contributions from dissolution and desorption

A key difficulty in developing accurate, science-based conceptual models for remediation of contaminated field sites is the proper accounting of multiple coupled geochemical and hydrologic processes. An example of such a difficulty is the separation of desorption and dissolution processes in releasing contaminants from sediments to groundwaters; very few studies are found in the literature that attempt to quantify contaminant release by these two processes. In this study, the results from several extraction techniques, isotopic exchange experiments, and published spectroscopic studies were combined to estimate the contributions of desorption and dissolution to U(VI) release from contaminated sediments collected from the vadose zone beneath former waste disposal ponds in the Hanford 300-Area (Washington State). Vertical profiles of sediments were collected at four locations from secondary pond surfaces down to, and slightly below, the water table. In three of the four profiles, uraniumconcentration gradients were observed in the sediments, with the highest U concentrations at the top of the profile. One of the vertical profiles contained sediments with U concentrations up to 4.2×10 −7 mol g −1 (100 ppm). U(VI) release to artificial groundwater solutions (AGWs) and extracts from these high-U concentration sediments occurred primarily from dissolution of precipitated U(VI) minerals, including the mineral metatorbernite, [Cu(UO 2 PO 4 ) 2 ·8H 2 O]. At the bottom of this profile, beneath the water table, and in all three of the other profiles, U concentrations were <5.88×10 −8 mol g −1 (14 ppm), and U(VI) release to AGWs occurred primarily due to desorption of U(VI). When reacted in batch experiments with AGWs with compositions representative of the range of chemical conditions in the underlying aquifer, all samples released U(VI) at concentrations greater than regulatory limits within few hours. A semi-mechanistic surface complexation model was developed to describe U(VI) adsorption on sediments collected from near the water table, as a function of pH, alkalinity, and Ca and U(VI) concentrations, using ranges in these variables relevant to groundwater conditions in the aquifer. Dilute (bi)carbonate solution extractions and uranium isotopic exchange methods were capable of estimating adsorbed U(VI) in samples where U(VI) release was predominantly due to U(VI) desorption; these techniques were not effective at estimating adsorbed U(VI) where U(VI) release was affected by dissolution of U(VI) minerals. The combination of extraction and isotopic exchange results, spectroscopic studies, and surface complexation modeling allow an adequate understanding for the development of a geochemical conceptual model for U(VI) release to the aquifer. The overall approach has generic value for evaluating the potential for release of metals and radionuclides from sediments that contain both precipitated and adsorbed contaminant speciation.

Book chapter↗

USGS2017

Geochemical and hydrologic factors controlling subsurface transport of poly- and perfluoroalkyl substances, Cape Cod, Massachusetts

Growing evidence that certain poly- and perfluoroalkyl substances (PFASs) are associated with negative human health effects prompted the U.S. Environmental Protection Agency to issue lifetime drinking water health advisories for perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) in 2016. Given that groundwater is a major source of drinking water, the main objective of this work was to investigate geochemical and hydrological processes governing the subsurface transport of PFASs at a former fire training area (FTA) on Cape Cod, Massachusetts, where PFAS-containing aqueous film-forming foams were used historically. A total of 148 groundwater samples and 4 sediment cores were collected along a 1200-m-long downgradient transect originating near the FTA and analyzed for PFAS content. The results indicate that unsaturated zones at the FTA and at hydraulically downgradient former domestic wastewater effluent infiltration beds both act as continuous PFAS sources to the groundwater despite 18 and 20 years of inactivity, respectively. Historically different PFAS sources are evident from contrasting PFAS composition near the water table below the FTA and wastewater-infiltration beds. Results from total oxidizable precursor assays conducted using groundwater samples collected throughout the plume suggest that some perfluoroalkyl acid precursors at this site are transporting with perfluoroalkyl acids.

Massachusetts↗

USGS2016

Using continuous underway isotope measurements to map water residence time in hydrodynamically complex tidal environments

Stable isotopes present in water (δ 2 H, δ 18 O) have been used extensively to evaluate hydrological processes on the basis of parameters such as evaporation, precipitation, mixing, and residence time. In estuarine aquatic habitats, residence time (τ) is a major driver of biogeochemical processes, affecting trophic subsidies and conditions in fish-spawning habitats. But τ is highly variable in estuaries, owing to constant changes in river inflows, tides, wind, and water height, all of which combine to affect τ in unpredictable ways. It recently became feasible to measure δ 2 H and δ 18 O continuously, at a high sampling frequency (1 Hz), using diffusion sample introduction into a cavity ring-down spectrometer. To better understand the relationship of τ to biogeochemical processes in a dynamic estuarine system, we continuously measured δ 2 H and δ 18 O, nitrate and water quality parameters, on board a small, high-speed boat (5 to >10 m s –1 ) fitted with a hull-mounted underwater intake. We then calculated τ as is classically done using the isotopic signals of evaporation. The result was high-resolution (∼10 m) maps of residence time, nitrate, and other parameters that showed strong spatial gradients corresponding to geomorphic attributes of the different channels in the area. The mean measured value of τ was 30.5 d, with a range of 0–50 d. We used the measured spatial gradients in both τ and nitrate to calculate whole-ecosystem uptake rates, and the values ranged from 0.006 to 0.039 d –1 . The capability to measure residence time over single tidal cycles in estuaries will be useful for evaluating and further understanding drivers of phytoplankton abundance, resolving differences attributable to mixing and water sources, explicitly calculating biogeochemical rates, and exploring the complex linkages among time-dependent biogeochemical processes in hydrodynamically complex environments such as estuaries.

California↗

USGS2017

Effects of an extreme flood on trace elements in river water—From urban stream to major river basin

Major floods adversely affect water quality through surface runoff, groundwater discharge, and damage to municipal water infrastructure. Despite their importance, it can be difficult to assess the effects of floods on streamwater chemistry because of challenges collecting samples and the absence of baseline data. This study documents water quality during the September 2013 extreme flood in the South Platte River, Colorado, USA. Weekly time-series water samples were collected from 3 urban source waters (municipal tap water, streamwater, and wastewater treatment facility effluent) under normal-flow and flood conditions. In addition, water samples were collected during the flood at 5 locations along the South Platte River and from 7 tributaries along the Colorado Front Range. Samples were analyzed for 54 major and trace elements. Specific chemical tracers, representing different natural and anthropogenic sources and geochemical behaviors, were used to compare streamwater composition before and during the flood. The results differentiate hydrological processes that affected water quality: (1) in the upper watershed, runoff diluted most dissolved constituents, (2) in the urban corridor and lower watershed, runoff mobilized soluble constituents accumulated on the landscape and contributed to stream loading, and (3) flood-induced groundwater discharge mobilized soluble constituents stored in the vadose zone.

Colorado↗

USGS2002

Multispecies reactive tracer test in an aquifer with spatially variable chemical conditions, Cape Cod, Massachusetts: Dispersive transport of bromide and nickel

Dispersive transport of groundwater solutes was investigated as part of a multispecies reactive tracer test conducted under spatially variable chemical conditions in an unconfined, sewage‐contaminated sand and gravel aquifer on Cape Cod, Massachusetts. Transport of the nonreactive tracer bromide (Br) reflected physical and hydrologic processes. Transport of the reactive tracer nickel (Ni) complexed with an organic ligand (NiEDTA) varied in response to pH and other chemical conditions within the aquifer. A loss of about 14% of the Ni mass was calculated from the distribution of tracers through time. This loss is consistent with reversible adsorption of NiEDTA onto the iron and aluminum oxyhydroxide coatings on the aquifer sediments. The Ni consistently lagged behind Br with a calculated retardation coefficient of 1.2. Longitudinal dispersivities reached constant values of 2.2 and 1.1 m for Br and Ni, respectively, by at least 69 m of travel. The smaller dispersivity for Ni possibly was due to nonlinear or spatially variant adsorption of NiEDTA. In the upper, uncontaminated zone of the aquifer, longitudinal dispersion of Ni was greater than that of Br early in the test as a result of reversible adsorption of NiEDTA. In general, transverse dispersivities were much smaller (horizontal: 1.4–1.5 × 10 −2 m; vertical: 0.5–3.8 × 10 −3 m) than the longitudinal dispersivities. The Br results are similar to those from a test conducted eight years earlier, suggesting that transport parameters are spatially stationary within the aquifer at the scale of 300 m covered by the spatially overlapping tests. A significant difference between the two tests was the travel distance (69 and 26 m) needed to reach a constant longitudinal dispersivity.

Massachusetts↗

USGS2006

Evaluating uncertainty in predicting spatially variable representative elementary scales in fractured aquifers, with application to Turkey Creek Basin, Colorado

Computational limitations and sparse field data often mandate use of continuum representation for modeling hydrologic processes in large‐scale fractured aquifers. Selecting appropriate element size is of primary importance because continuum approximation is not valid for all scales. The traditional approach is to select elements by identifying a single representative elementary scale (RES) for the region of interest. Recent advances indicate RES may be spatially variable, prompting unanswered questions regarding the ability of sparse data to spatially resolve continuum equivalents in fractured aquifers. We address this uncertainty of estimating RES using two techniques. In one technique we employ data‐conditioned realizations generated by sequential Gaussian simulation. For the other we develop a new approach using conditioned random walks and nonparametric bootstrapping (CRWN). We evaluate the effectiveness of each method under three fracture densities, three data sets, and two groups of RES analysis parameters. In sum, 18 separate RES analyses are evaluated, which indicate RES magnitudes may be reasonably bounded using uncertainty analysis, even for limited data sets and complex fracture structure. In addition, we conduct a field study to estimate RES magnitudes and resulting uncertainty for Turkey Creek Basin, a crystalline fractured rock aquifer located 30 km southwest of Denver, Colorado. Analyses indicate RES does not correlate to rock type or local relief in several instances but is generally lower within incised creek valleys and higher along mountain fronts. Results of this study suggest that (1) CRWN is an effective and computationally efficient method to estimate uncertainty, (2) RES predictions are well constrained using uncertainty analysis, and (3) for aquifers such as Turkey Creek Basin, spatial variability of RES is significant and complex.

Water Resources Research↗

USGS2019

Multiorder hydrologic position in the conterminous United States: A set of metrics in support of groundwater mapping at regional and national scales

The location of a point on the landscape within a stream network (hydrologic position) can be an important predictive measure in hydrology. Hydrologic position is defined here by two metrics: lateral position and distance from stream to divide, both measured horizontally. Lateral position (dimensionless) is the relative position of a point between the stream and its watershed divide. Distance from stream to divide (units of length) is an indicator of position within a watershed: generally small near a confluence and generally large in headwater areas. Watersheds and watershed divides are defined here by Thiessen polygons rather than topographic divides. Lateral position and distance from stream to divide are also defined in the context of hydrologic order. Hydrologic order “ n ” is defined as the network of streams, and associated divides, of order n and higher. And given that a point can have different positions in different hydrologic orders the term multiorder hydrologic position (MOHP) is used to describe the ensemble of hydrologic positions. MOHP was mapped across the conterminous United States for nine hydrologic orders at a spatial resolution of 30 m (about 8.7 billion pixels). There are 18 metrics for each pixel. Four case studies are presented that use MOHP metrics as explanatory factors in random forest machine learning models. The case studies show that lower order MOHP metrics can serve as indicators of hydrologic process while higher‐order metrics serve as indicators of location. MOHP is shown to have utility as a predictor variable across a large range of scales (50,000 to 8,000,000 km 2 ).

Water Resources Research↗

USGS2021

Seasonality of solute flux and water source chemistry in a coastal glacierized watershed undergoing rapid change: Wolverine Glacier watershed, Alaska

As glaciers around the world rapidly lose mass, the tight coupling between glaciers and downstream ecosystems is resulting in widespread impacts on global hydrologic and biogeochemical cycling. However, a range of challenges make it difficult to conduct research in glacierized systems and our knowledge of seasonally changing hydrologic processes and solute sources and signatures is limited. This in turn hampers our ability to make predictions on solute composition and flux. We conducted a broad water sampling campaign in order to understand the present-day partitioning of water sources and associated solutes in Alaska’s Wolverine Glacier watershed. We established a relationship between electrical conductivity (EC) and streamflow at the watershed outlet to divide the melt season into four hydroclimatic periods. Across hydroclimatic periods, we observed a shift in off-glacier source waters from snowmelt-dominated overland and shallow subsurface flow paths to deeper groundwater flow paths. We also observed the shift from a low- to high-efficiency subglacial drainage network and the associated flushing of water stored sub-glacially with higher solute loads. We used calcium, the dominant dissolved ion, from watershed outlet samples to estimate solute fluxes for each hydroclimatic period across two melt seasons. We found between 40 and 55 percent of Ca2+ export occurred during the late season rainy period. This partitioning of the melt season coupled with a characterization of the chemical makeup and magnitude of solute export provides new insight into a rapidly changing watershed and creates a framework to quantify and predict changes to solute fluxes across a melt season.

Alaska↗

USGS2008

Groundwater flow and solute movement to drain laterals, western San Joaquin Valley, California: 1. Geochemical assessment

A study was undertaken to quantitatively evaluate the hydrologic processes affecting the chemical and isotopic composition of drain lateral water in a drained agricultural field in the western San Joaquin Valley, California. The results elucidate the process of mixing of deep and shallow groundwater (below and within 6 m from land surface) entering the drain laterals. The deep groundwater was subject to evapoconcentration prior to drainage system installation and has been displaced downward (to depths greater than 6 m) in the groundwater system. The proportions of deep and shallow groundwater entering the drain laterals was calculated from the end-member oxygen 18 compositions determined in groundwater samples. The percentage of total drain lateral flow which is deep groundwater flow is about 30% for the shallow drain lateral (1.8 m below land surface) (drain lateral 1)) and 60% for the deep drain lateral (2.7 m below land surface (drain lateral 2)). During irrigation, the percentages of deep groundwater flow decrease to 0 and 30% for the shallow and deep drain laterals, respectively. Selenium concentrations in drain lateral waters decrease during irrigation but selenium loads increase. Total estimated annual loads were 1.1 and 5.4 kg of selenium for drain laterals 1 and 2, respectively. Substantial percentages of the annual load occurred during 8 days of irrigation, 23 and 9% for drain laterals 1 and 2, respectively.

California↗