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Guide for interpreting and reporting luminescence dating results

The development and application of luminescence dating and dosimetry techniques have grown exponentially in the last several decades. Luminescence methods provide age control for a broad range of geological and archaeological contexts and can characterize mineral and glass properties linked to geologic origin, Earth-surface processes, and past exposure to light, heat, and ionizing radiation. The applicable age range for luminescence methods spans the last 500,000 years or more, which covers the period of modern human evolution, and provides context for rates and magnitudes of geological processes, hazards, and climate change. Given the growth in applications and publications of luminescence data, there is a need for unified, community-driven guidance regarding the publication and interpretation of luminescence results. This paper presents a guide to the essential information necessary for publishing and archiving luminescence ages as well as supporting data that is transportable and expandable for different research objectives and publication outlets. We outline the information needed for the interpretation of luminescence data sets, including data associated with equivalent dose, dose rate, age models, and stratigraphic context. A brief review of the fundamentals of luminescence techniques and applications, including guidance on sample collection and insight into laboratory processing and analysis steps, is presented to provide context for publishing and data archiving.

GSA Bulletin↗

Validation of earthquake ground-motion models in southern California, USA, using precariously balanced rocks

Accurate estimates of earthquake ground shaking rely on uncertain ground-motion models derived from limited instrumental recordings of historical earthquakes. A critical issue is that there is currently no method to empirically validate the resultant ground-motion estimates of these models at the timescale of rare, large earthquakes; this lack of validation causes great uncertainty in ground-motion estimates. Here, we address this issue and validate ground-motion estimates for southern California utilizing the unexceeded ground motions recorded by 20 precariously balanced rocks. We used cosmogenic 10 Be exposure dating to model the age of the precariously balanced rocks, which ranged from ca. 1 ka to ca. 50 ka, and calculated their probability of toppling at different ground-motion levels. With this rock data, we then validated the earthquake ground motions estimated by the Uniform California Earthquake Rupture Forecast, Version 3 (UCERF3) seismic-source characterization and the Next Generation Attenuation (NGA)-West2 ground-motion models. We found that no ground-motion model estimated levels of earthquake ground shaking consistent with the observed continued existence of all 20 precariously balanced rocks. The ground-motion model I14 estimated ground-motion levels that were inconsistent with the most rocks; therefore, I14 was invalidated and removed. At a 2475 year mean return period, the removal of this invalid ground-motion model resulted in a 2–7% reduction in the mean and a 10–36% reduction in the 5th–95th fractile uncertainty of the ground-motion estimates. Our findings demonstrate the value of empirical data from precariously balanced rocks as a validation tool for removing invalid ground-motion models and, in turn, reducing the uncertainty in earthquake ground-motion estimates.

California↗

Ages of the granitic basement of Long Valley Caldera, California, USA, and siting of the Quaternary granite-rhyolite pluton

The leucogranitic crystal-mush pluton beneath the iconic Long Valley Caldera, California, USA, released >820 km 3 of crystal-poor Pleistocene rhyolite, which was hosted by numerous Mesozoic granitic plutons, only a few of which had been dated until now. Reported here are U-Pb zircon ages, determined by sensitive high-resolution ion microprobe−reverse geometry (SHRIMP-RG), for 11 circumcaldera granitoids, all of them either Triassic or Cretaceous. Growth of the 35-km-wide Quaternary rhyolite-leucogranite plutonic reservoir was fostered by collocation of (1) a dense swath of late Pliocene basaltic vents, (2) a left-stepping extensional reentrant in the rangefront fault zone of the Sierra Nevada batholith, and (3) a sharp offset of the Proterozoic continental margin as represented by the Sr-isotope 0.706 line. We further consider whether the basement architecture of as many as 26 separate Triassic and Cretaceous plutons and intervening septa and pendants of Paleozoic metasedimentary rocks influenced siting of the Quaternary pluton and whether the ragged margin of Proterozoic lithosphere helped to focus asthenospheric edge upwelling that intensified crustal melting and intrusion in both the Triassic and the Quaternary.

California↗

Oligocene–Miocene northward growth of the Tibetan Plateau: Insights from intermontane basins in the West Qinling Belt, NW China

Growth of the Tibetan Plateau, Earth’s broadest and highest elevation collisional system, shapes orographic barriers, reorganizes drainage networks, and influences surface erosion and sediment delivery, whose changes in space and provenance feed back to intracontinental tectonic processes. Studies of interior basins within the northern Tibetan Plateau provide new sediment accumulation, provenance, paleodrainage, and deformation timing data that enable a reconstruction of the far-field tectono-geomorphic evolution of the rising Tibetan Plateau. Along the northern plateau margin, topographic growth in the West Qinling Belt is inferred to have initiated in the Eocene, nearly coeval with the India-Asia collision, as well as in the late Miocene. However, geological knowledge about the intervening period remains at present enigmatic, and the kinematics and dynamics are uncertain. This study presents a multidisciplinary data set from the intermontane Anhua-Huicheng Basin (AHB; Gansu Province, China) to fill this gap. Magnetostratigraphic dating, regional mapping, and sedimentological analysis imply that contractional deformation and thrust-top basin systems formed within the West Qinling Belt in the Oligocene (not later than ca. 24 Ma). A combination of observations including paleocurrent changes, detrital zircon U-Pb age variations, and appearance of growth strata along the Anhua-Huicheng Basin reveal the rapid uplift of the West Qinling Belt at ca. 15 Ma. Sedimentation in the intermontane basins ended after the late Miocene (ca. 8 Ma), when the region experienced intrabasinal deformation, uplift, and erosion with the establishment of an external drainage system. Since the late Miocene, the growth of the West Qinling Belt reached a climax with the lack of substantial contractional deformation in Cenozoic sequences heralding the onset of the modern kinematic regime and attainment of high elevation. Observed transitions in the tectonostratigraphy and paleodrainage define different phases of deformation and plateau-wide shifts in stress reorganization, which led to the northward growth and later lateral expansion of the Tibetan Plateau.

GSA Bulletin↗

Petrology and geochronology of Cretaceous–Eocene plutonic rocks in northeastern Washington, USA: Crustal thickening, slab rollback, and origin of the Challis episode

Cretaceous through Eocene plutonic rocks in northeastern Washington, USA, document a 60 m.y. history of crustal thickening and subsequent collapse and extension in response to two terrane-accretion events. Rocks emplaced 113–53 Ma have increasing La/Yb ratios reflecting orogenic plateau development after arrival of the Insular terrane by 100 Ma. Plutons emplaced 52–45 Ma (the Challis episode) document collapse of this plateau and define a SW-younging age progression attributed to breakoff and rollback of the Farallon slab following accretion of the Siletzia terrane at ca. 50 Ma. All of the rocks have chemical traits of arc magmas, likely inherited from their lower-crustal sources, but low B/Be ratios and the lack of evidence for amphibole fractionation indicate the Eocene magmas formed under drier conditions than are typical of active subduction settings. These magmas also originated at greater depth (eclogitic vs. gabbroic source) and were emplaced more shallowly than the earlier ones. All rocks have overlapping Sr-Nd and O isotopic data, indicating significant contributions from older continental crust, and depleted mantle Nd model ages become older toward the east, defining three regions that correspond with previously inferred lower-crustal domains. Farallon slab rollback also drove extension (core complex formation, dike swarms) and crustal uplift, which, along with voluminous magmatism, define the Challis episode. This tectonic model is further supported by seismic tomography, which has identified remnants of a detached slab in the upper mantle beneath the region.

Washington↗

Upper crustal seismic velocity structure of the Hayward fault zone, San Francisco Bay, California, USA: Results from the 2016 East Bay Seismic Experiment (EBSI-16)

We developed Vp, Vs, Vp / Vs ratio, and Poisson’s ratio models of the uppermost crust (<4 km depth) from the eastern San Francisco (SF) Bay (California, USA) to near the Calaveras fault along a 15-km-long, linear profile. Upper crustal velocities are highly variable beneath, west, and well east of the Hayward fault. We observe eight notable features, from west to east: (1) Near San Francisco Bay, there is an ~2-km-wide structure with high Vp / Vs ratios (up to 5) and Poisson’s ratios (up to 0.48) extending from the surface to the base of our model, which we suggest the structure is a near-vertical fault that lies along a straight-line projection between the Silver Creek fault to the south and the Point Richmond fault to the north. The structure may be part of an ~90-km-long fault along the eastern SF Bay. (2) The western East Bay Plain, the lower lying area between the bay and the hills, includes up to 800 m of low-velocity sediments ( Vp ~1600–3000 m/s, Vs ~500 m/s to ~1000 m/s), underlain by higher velocity basement rocks ( Vp ~3000–5800 m/s; Vs ~1000–1500 m/s). (3) Between ~1 km and 3 km east of the Bay shoreline, sediments thin in a series of steps (likely faults) toward the Hayward fault. (4) Between ~3 km west and ~1 km east of the Hayward fault (at the East Chabot fault) at depths greater than 1 km, basement Vp (up to 6000 m/s) and Vs (up to 2800 m/s) are high, and Vp / Vs ratios (<2) and Poisson’s ratios (<0.3) are low, suggesting crystalline rocks. Furthermore, a near-vertical zone of low Vp / Vs ratios and Poisson’s ratios is between near-surface traces of the Hayward and East Chabot faults, likely corresponding to the San Leandro Gabbro of Ponce et al. (2003) . (5) Eastward of the East Chabot fault in the upper 1.5 km, basement Vp (~3000 m/s to ~4200 m/s) and Vs (~1200–2000 m/s) are lower than those west of the fault. (6) In the eastern Hayward/Oakland Hills, there are zones of laterally varying, high- and low-velocity ( Vp ~2500–3000 m/s) Jurassic–Cretaceous and Tertiary sediments in the shallow subsurface that likely extend much deeper than imaged. (7) Seismic energy that propagates westward from sources east of the Hayward fault (HF) appear weaker than energy that propagates eastward from sources west of the HF, suggesting that the HF acts as a partial barrier to shallow seismic energy propagation into the more populated eastern SF Bay area. (8) Unlike many fault zones, it appears that the active trace of the Hayward fault (in our study area) is not cored by a prominent, low-velocity zone relative to rocks to the east and west of the active trace. However, the active trace does mark a prominent change from relatively higher velocities to the west and lower velocities to the east.

California↗

Geophysical constraints on continental rejuvenation in central China: Implications for outward growth of the Tibetan Plateau

Continental rejuvenation results from the tectonic reactivation of crustal structures and lithospheric reworking by mantle flow. Geochemical observations and field mapping have traditionally provided the primary evidence for the secular evolution of crustal composition and tectonic processes during continental rejuvenation. Nonetheless, the impact of continental rejuvenation on the observed present-day strain rate and orogenic-scale lithospheric structure has not been well constrained. The pre-existing E-W–trending Central China Orogenic Belt has been overprinted by the N-S–trending Central Longitudinal Seismic Belt and constitutes the intracontinental West Qinling Syntaxis in central China, where the tectonic setting changes eastward from contraction to extension. Combining updated global positioning system data and high-resolution crustal seismic tomography, we reveal a modern continental rejuvenation process within the West Qinling Syntaxis in central China. The northward extrusion of the Tibetan Plateau's weak lithospheric layer (middle-lower crust and lithospheric mantle) of southwestern China relative to the rigid Sichuan Basin/Ordos Block of the eastern West Qinling Syntaxis results in regional dextral shearing that shapes the Central Longitudinal Seismic Belt and defines the eastern Tibetan Plateau margin. The pre-existing E-W–trending Central China Orogenic Belt has been preserved above the brittle-ductile transition zone, and the northward movement of the deep lithospheric layer drives the deformation of the upper crust in the West Qinling Syntaxis. Our results, along with previous studies, suggest the presence of an intracontinental lithospheric interchange structure in central China. The continental rejuvenation of the West Qinling Syntaxis results from a combination of fault reactivation in the upper crust (Stage I, Eocene–Oligocene) and reworking of the deep lithosphere (Stage II, middle–late Miocene) related to the plateau-wide shift in stress accommodation ultimately driven by the redistribution of mass outward from the central Tibetan Plateau. At present, the transition zone between the high- and low-velocity anomalies along the Central Longitudinal Seismic Belt not only shapes the landscape boundary but controls the size and recurrence interval of earthquakes within the West Qinling Syntaxis in central China.

GSA Bulletin↗

Travertine records climate-induced transformations of the Yellowstone hydrothermal system from the late Pleistocene to the present

Chemical changes in hot springs, as recorded by thermal waters and their deposits, provide a window into the evolution of the postglacial hydrothermal system of the Yellowstone Plateau Volcanic Field. Today, most hydrothermal travertine forms to the north and south of the ca. 631 ka Yellowstone caldera where groundwater flow through subsurface sedimentary rocks leads to calcite saturation at hot springs. In contrast, low-Ca rhyolites dominate the subsurface within the Yellowstone caldera, resulting in thermal waters that rarely deposit travertine. We investigated the timing and origin of five small travertine deposits in the Upper and Lower Geyser Basins to understand the conditions that allowed for travertine deposition. New 230 Th-U dating, oxygen (δ 18 O), carbon (δ 13 C), and strontium ( 87 Sr/ 86 Sr) isotopic ratios, and elemental concentrations indicate that travertine deposits within the Yellowstone caldera formed during three main episodes that correspond broadly with known periods of wet climate: 13.9−13.6 ka, 12.2−9.5 ka, and 5.2−2.9 ka. Travertine deposition occurred in response to the influx of large volumes of cold meteoric water, which increased the rate of chemical weathering of surficial sediments and recharge into the hydrothermal system. The small volume of intracaldera travertine does not support a massive postglacial surge of CO 2 within the Yellowstone caldera, nor was magmatic CO 2 the catalyst for postglacial travertine deposition.

Wyoming↗

Geological context and significance of the clay-sulfate transition region in Mount Sharp, Gale crater, Mars: An integrated assessment based on orbiter and rover data

On Mars, phyllosilicate (“clay”) minerals are often associated with older terrains, and sulfate minerals are associated with younger terrains, and this dichotomy is taken as evidence that Mars’ surface dried up over time. Therefore, in situ investigation of the Mount Sharp strata in Gale crater, which record a shift from dominantly clay-bearing to sulfate-bearing minerals, as seen in visible−near-infrared orbital reflectance spectra, is a key science objective for the Mars Science Laboratory (MSL) Curiosity rover mission. Here, we present regional (orbiter-based) and in situ (rover-based) evidence for a low-angle erosional unconformity that separates the lacustrine and marginal lacustrine deposits of the Carolyn Shoemaker formation from the dominantly eolian deposits of the lower Mirador formation within the orbitally defined clay-sulfate transition region. The up-section record of wetter (Carolyn Shoemaker formation) to drier (lower Mirador formation) depositional conditions is accompanied by distinct changes in diagenesis. Clay minerals occur preferentially within the Carolyn Shoemaker formation and are absent within the lower members of the Mirador formation. At and above the proposed unconformity, strata are characterized by an increase in diagenetic nodules enriched in X-ray amorphous Mg-sulfate. Early clay formation in the Carolyn Shoemaker formation may have created a hydraulic barrier such that later migrating magnesium- and sulfur-rich fluids accumulated preferentially within the lower members of the Mirador formation. The proposed unconformity may have also acted as a fluid conduit to further promote Mg-sulfate nodule formation at the Carolyn Shoemaker−Mirador formation boundary. These results confirm an association of the clay-sulfate transition with the drying of depositional environments, but they also suggest that at least some orbital sulfate signatures within the region are not time-congruent with the environmental signals extracted from primary sedimentology. Our findings highlight that complex interactions among primary depositional environment, erosion, and diagenesis contribute to the transition in clay-sulfate orbital signatures observed in the stratigraphy of Mount Sharp.

GSA Bulletin↗

Late Triassic paleogeography of southern Laurentia and its fringing arcs: Insights from detrital zircon U-Pb geochronology and Hf isotope geochemistry, Auld Lang Syne basin (Nevada, USA)

Fluvial strata of the Upper Triassic Chinle Formation and Dockum Group, exposed across the Western Interior of North America, have long been interpreted to record a transcontinental river system that connected the ancestral Ouachita orogen of Texas and Oklahoma, USA, to the Auld Lang Syne basin of northwestern Nevada, USA, its inferred marine terminus. Fluvial strata are well-characterized by existing detrital zircon data, but the provenance of the Auld Lang Syne basin is poorly constrained. We present new detrital zircon U-Pb and Hf isotopic data that characterize the provenance of Norian siliciclastic strata that dominate the Auld Lang Syne basin. Mixture modeling of Auld Lang Syne basin data identifies the Alleghany−Ouachita−Marathon belt of eastern Laurentia as a dominant source of sediment, but the presence of Triassic detrital zircon grains in Auld Lang Syne basin strata indicates that at least one peri-Laurentian arc segment had to have also contributed sediment. A comparison of new Hf isotopic data with those characterizing various peri-Laurentian volcanic arcs demonstrates that although multiple arc segments may have simultaneously contributed zircons to the Auld Lang Syne basin, the west Pangean arc of northern Mexico stands out as a unique source of highly evolved Permian to Triassic detrital zircon grains in samples from the Auld Lang Syne basin. Altogether, our data and analyses demonstrate source-to-sink connectivity between the Late Triassic (Norian) Cordilleran margin and remnant late Paleozoic highlands of southern to eastern Laurentia, which ultimately framed a Mississippi River−scale, transcontinental watershed that traversed the topographically subdued Laurentian continental interior.

Nevada↗

Timing and geometry of the Chemehuevi Formation reveal a late Pleistocene sediment pulse into the Lower Colorado River

The Chemehuevi Formation is a distinctive 50−150-m-thick wedge-shaped Pleistocene sedimentary unit deposited by the Colorado River. It lines the perimeters of the river’s floodplains and bedrock canyons for more than 600 km between the mouth of the Grand Canyon and the delta region in the Gulf of California. The formation is composed of a basal tan to light-yellowish-brown and pale-orange mud-dominated facies overlain and interbedded by a light-yellow-brown sand-dominated facies. The unit is one of two extensively exposed aggradational packages in the Lower Colorado River corridor, in addition to a series of other smaller alluvial terrace deposits. The Chemehuevi Formation appears to represent the response of a fully integrated Colorado River system to a significant perturbation, in contrast to the Bullhead Alluvium, which is likely a unique result of Pliocene river integration. The aggradation of the Chemehuevi Formation in the Lower Colorado River corridor may be similarly due to a unique event in the Colorado River system, or it may instead be a well-preserved sedimentary sequence recording typical behavior of the Colorado River below the Grand Canyon in the late Pleistocene. As such, multiple causal mechanisms have been proposed, but no study to date has conclusively explained the Chemehuevi Formation. To help resolve its timing, duration, and origin, we applied post-infrared infrared stimulated luminescence, carbonate U-Th series, and zircon sensitive high-resolution ion microprobe U-Th series geochronology to determine the ages of key exposures of the unit over a wide spatial area. These new data demonstrate that the Chemehuevi Formation was deposited ca. 110−90 ka. The depositional ages collectively overlap, suggesting that deposition occurred rapidly relative to the resolution of the geochronometers. The new depositional timing coincides with a shift from glacial to interglacial conditions after the marine isotope stage 5-6 transition. This observation is consistent with a climate-induced sediment pulse as a causal mechanism, yet correlations with similar deposits in the Colorado River headwaters or in neighboring catchments appear elusive. Potentially, climate transitions between glacial and interglacial periods induced a sediment pulse from hillslopes of the Colorado River system that resulted in the Chemehuevi Formation. An alternative or additional explanation is that the Chemehuevi Formation represents release of lava dam−impounded sediment in the Grand Canyon. The surface geometry of the Chemehuevi Formation projects upstream to the approximate location of lava dams, and the largest possible lava dam impoundment (the Upper Prospect dam) is comparable in volume to the formation. The lava dam hypothesis appears to be a possible explanation for the Chemehuevi Formation. However, tying deposition to a specific lava dam or series of lava dams remains challenging due to discrepancies in timing and volume. The combined effects of a series of lava dams may have led to the Chemehuevi Formation, as the last Pleistocene lava dam eruption coincides with the onset of deposition. Alternatively, the formation may result from the combined effects of both regional climate transitions and the lava dams that created a transient reservoir to compound a climate transition−driven sediment pulse. The geochronologic data presented here do not allow us to distinguish between the lava dam or climate transition hypotheses but will need to be reconciled with any future proposed depositional model.

Arizona, California, Nevada↗

The Hardscrabble Creek complex: A newly discovered, mostly buried, Mesoproterozoic mafic-ultramafic pluton in the Wet Mountains, Colorado, USA

The origin of prolific ca. 1.4 Ga ferroan magmatism between the southwestern USA and eastern Canada is enigmatic and has been explained by various models, including extensional, mantle plume, and convergent plate-margin models. Rare mafic plutons are associated with the ferroan plutons, which may help constrain their mantle source and tectonic setting. In the southwestern USA, only two such mafic plutons are known to exist. We present the first evidence for a third, mostly buried, potentially layered, mafic-ultramafic Mesoproterozoic pluton, informally referred to as the Hardscrabble Creek complex, in the central Wet Mountains of Colorado, USA. Recent geophysical data show an elliptical magnetic and gravity high spatially coincident with local gabbroic outcrops. New field and petrographic analyses of these exposed rocks reveal that they consist of ultramafic to mafic cumulates, including orthopyroxenite, olivine norite, norite, and anorthosite. High-precision U-Pb dating of zircon from orthopyroxenite and norite yield weighted mean 206 Pb/ 238 U dates of 1352.36 ± 1.60 Ma and 1352.37 ± 1.71 Ma, respectively. These dates indicate that the complex formed over a narrow timeframe, after the adjacent 1362 ± 7 Ma ferroan San Isabel Granite, and during the waning stages of the regional ca. 1.4 Ga ferroan magmatism. Whole-rock geochemistry and Nd-Sr-Pb isotope compositions of samples from the Hardscrabble Creek complex are similar to those of the San Isabel Granite, suggesting that they were derived from the same or a similar mantle source. The mineral chemistry of the samples is comparable to Proterozoic massif-type anorthosites and related mafic intrusions, indicating that the Hardscrabble Creek complex and San Isabel Granite together represent a rare anorthosite-mangerite-charnockite-granite (AMCG) suite in the southwestern USA. The Hardscrabble Creek complex is unique because it formed ~80 m.y. after the other few mafic plutons in the southwestern USA, and it contains an ultramafic section that is absent from these plutons and rare to the AMCG suite in general. A combination of arc-like whole-rock geochemistry, chondrite uniform reservoir-like Nd-Sr-Pb isotopes, and ocean island basalt (OIB)-like zircon trace element chemistry suggests that the complex was derived from a partial melt of OIB-like mantle and interacted with metasomatically enriched lithospheric mantle. The enriched lithospheric mantle signature, combined with the long ~160 m.y. duration of magmatism in the region, is consistent with a period of protracted convergent tectonism.

Colorado↗

Latest Pleistocene to 19th-century earthquakes on bending-moment reverse faults of the Seattle fault zone, Washington

Fault-related folds and their associated secondary faults play a critical yet often underrecognized role in accommodating strain and generating earthquakes in active fold-and-thrust belts. In the Seattle fault zone (SFZ), Washington, USA, we present new paleoseismic, geomorphic, and geophysical evidence for late Pleistocene and Holocene earthquakes on shallow, south-dipping secondary faults—the Lytle Beach and Vasa Park faults—that lie within the hanging wall of the greater SFZ and are on trend with the primary, blind Blakely Harbor fault. Our data show that these structures have ruptured independently, producing localized uplift and deformation at the surface, with the most recent event (RH2) likely occurring in the early nineteenth century. While a temporal overlap between the late Pleistocene RH1 and VP1 earthquakes raises the possibility of a ≥35 km rupture along the Blakely Harbor fault, structural and temporal evidence instead supports independent rupture on individual faults related to folding. We interpret these faults as bending-moment reverse faults that formed within a synclinal hinge zone of the main fault, reflecting mechanical and kinematic influences of the broader fault system. Combined with prior studies, our findings indicate that faulting related to folding dominates the mode of strain release within the SFZ since the late Pleistocene with more frequent earthquake recurrence (∼350 yr) over the past ∼2500 yr.

Washington↗

Evidence for organic and igneous carbon sources in the Mesoproterozoic Adirondack Highlands graphite district, New York

This study examined the origin of graphite mineralization in the Mesoproterozoic Adirondack Highlands. Flake graphite was mined from the historic mining district around Ticonderoga, New York, USA, from the 1850s to the 1920s. Most of the production and reserves from the district are disseminated graphite from feldspathic quartz schists (e.g., Dixon-American Graphite Co. mine, Faxon property, Flake Graphite Company). Protolith sediments of the schists were deposited in the Trans-Adirondack backarc basin at ca. 1.25 Ga and were metamorphosed to high grade at 1.18–1.15 Ga during the accretionary Shawinigan orogeny and at 1.09–1.02 Ga during the Ottawan phase of the Grenvillian orogeny. Major elements and carbon isotopes of graphite from schists (δ 13 C = −28.1‰ to −5.4‰ relative to Vienna Peedee belemnite) are consistent with derivation from organic carbon in protolith sandstones that devolatilized during metamorphism. Some small mines and prospects in the district mined graphitic calcite marbles and clinopyroxene ± scapolite skarns associated with a pegmatite suite dated by U-Pb in zircon to 1.04–1.01 Ga (e.g., Lead Hill and Crown Point deposits), and rare graphite veins are observed at several deposits. Hydrothermal flake graphite from pegmatites, skarns, and veins are distinct from graphite in schist-hosted deposits and have δ 13 C values that cluster around −7‰ to −5‰, consistent with deposition from igneous CO 2 . Covariation of carbon and oxygen stable isotopes and U-Pb zircon geochronology are not compatible with precipitation from fluids derived from country rock metapelites or marbles. Some graphite districts elsewhere show compelling evidence for remobilization and redeposition of sedimentary-derived carbon as hydrothermal graphite, sometimes as thick veins producing world-class, high-grade deposits. In the Adirondacks, there is evidence for two generations of graphite mineralization with distinct carbon sources: syngenetic graphite with an organic origin in Shawinigan quartz schists and epigenetic graphite with an igneous origin in Ottawan skarns and pegmatites.

New York↗

The Great Salt Lake (Utah, USA) acoustic and sedimentary archive of Wasatch Front earthquakes

As the largest low-relief basin in the western United States, the Great Salt Lake offers an opportunity to explore acoustic and sedimentary archives of earthquake ruptures in a shallow terminal basin. Here, we use subbottom compressed high intensity radiated pulse (Chirp) profiles and sedimentary cores to address questions related to how Great Salt Lake sediments respond to surface rupture and earthquake shaking and whether the lake is sensitive to both Great Salt Lake fault (GSLF) and Wasatch fault zone (WFZ) earthquakes. Chirp profiles reveal laterally continuous seismic stratigraphy with vertically displaced strata, onlap surfaces, and growth stratigraphy produced by GSLF surface ruptures. We identify and date two ruptures on the Fremont Island section and three on the Antelope Island section; temporal overlap of these ruptures supports synchronous rupture of both sections. Combined with previous data, our results yield a record of four Holocene surface-rupturing (M W 6.9−7.3) earthquakes on the GSLF with a mean recurrence of ∼3.2 k.y. Sediment cores include ≤41-cm-thick, massive, homogeneous to normally graded disturbance beds that interrupt laminated bioclastic sediment. Disturbance bed correlations yield four lacustrine earthquake deposits since ca. 1.7 ka; the youngest possibly records the most recent GSLF surface rupture whereas older deposits were likely produced by WFZ earthquakes. Modeled historical earthquakes yield a Great Salt Lake sediment disturbance shaking threshold of MMI ∼VI, controlled in part by the lake-bottom expression of the GSLF scarp. Our integration of primary (fault-related) and secondary (shaking-related) earthquake evidence improves our understanding of sediment disturbance processes and the archival potential of low-relief lake basins.

Utah↗

Refined chronology of late Quaternary eruptions at Harrat Khaybar, Saudi Arabia, with implications for magma dynamics and regional volcanic history

Determining accurate and precise ages for Quaternary volcanic centers is essential for reconstructing volcanic field histories, understanding magmatic processes, and assessing potential hazards or risk. Harrat Khaybar, western Saudi Arabia, is one of the youngest and potentially most active volcanic fields on the Arabian plate, has been active since ca. 1.7 Ma, and is characterized by a spectrum of rock compositions ranging from predominantly alkalic basalt to trachyte and comendite. Previous work in Harrat Khaybar utilizing 40 Ar/ 39 Ar incremental heating geochronology to constrain morphological preservation and superpositional relationships bracketed the volcanic activity into broad age groups in intervals of ∼150 k.y., and the youngest and most compositionally evolved volcanoes, including Jabal Abyad, Jabal Bayda, and Jabal Qidr, were assigned to the age groups between ca. 300 ka and present. Herein, we establish a detailed chronology of prehistoric silicic and historical basaltic eruptions at central Harrat Khaybar using four independent eruption age determination techniques: zircon double-dating (ZDD), which combines 238 U- 230 Th disequilibrium or U-Pb with (U-Th)/He dating; zircon U-Pb dating; cosmogenic 3 He dating; and cosmogenic 36 Cl geochronology. These were employed to accurately date six volcanic centers, including the comenditic Jabal Abyad, Jabal Bayda, Jabal Ibayl, and Jabal Alhayyirah, the trachytic Jabal Aluthmor, and the basaltic Jabal Qidr. Additionally, our previously published 40 Ar/ 39 Ar ages have been recalculated using isochron intercept (nonatmospheric) 40 Ar/ 36 Ar for the trapped Ar component. Our new results reveal that zircon rims from Jabal Abyad and Jabal Bayda define isochron 238 U- 230 Th crystallization ages of 125 ± 4 ka and 144 ± 6 ka, concordant with ZDD eruption ages of 132 ± 4 ka and 149 ± 5 ka, respectively. Zircon U-Pb crystallization and (U-Th)/He eruption ages from Jabal Alhayyirah are concordant at 471 ± 14 ka and 458 ± 18 ka, respectively. Finally, zircons from the nearby Jabal Ibayl yield a U-Pb weighted mean crystallization age of 566 ± 16 ka concordant with the corresponding (U-Th)/He eruption age of 554 ± 12 ka, both of which are notably older than the previously proposed eruption ages of 300−150 ka. Recalculations of published 40 Ar/ 39 Ar ages for the youngest volcanoes at central Harrat Khaybar are now in excellent agreement with new geochronological data. Our new age data reveal several new insights into the development of Harrat Khaybar. It is now clear that the comenditic eruptions do not belong to the same eruptive phase and indicate an extended history during which comendites have episodically punctuated the basaltic volcanism since at least 600 ka. The data indicate that Jabal Ibayl and Jabal Alhayyirah represent separate older volcanic events, whereas the younger Jabal Abyad and Jabal Bayda volcanoes appear to be coeval, and their spatial proximity implies that they share a magmatic lineage and maybe a common plumbing system. Zircon age spectra of the comendites reveal obvious xenocrysts and antecrysts indicating assimilation of basement and plutonic progenitors, but otherwise they define broad unimodal populations of crystallization ages that overlap within error with the respective eruption ages. We interpret this to indicate that zircon crystallization continued up to the time of eruption. The cosmogenic ages of Jabal Aluthmor and Jabal Qidr reveal that these centers erupted as recently as ca. 2000 and 760 years ago, respectively. Broadly coeval young silicic and basaltic eruptions at northern Harrat Rahat, the harrat immediately south of Harrat Khaybar, may imply a shared geodynamic forcing between the two adjacent volcanic fields.

Harrat Khaybar↗

Reconstructing ancient sedimentary source-to-sink systems – Examples from southern Laurentia’s Proterozoic accretionary orogens

Provenance analysis is a powerful tool for investigating sediment delivery networks, constraining magmatic histories, and reconstructing the tectonic evolution of orogenic belts and basins. Basin analysis studies increasingly use detrital zircon (DZ) U-Pb forward mixture modeling to enhance provenance interpretations by quantifying the relative contributions of different sources. Forward mixture modeling requires significant a priori knowledge that limits deep-time applications. This challenge is overcome with an inverse mixture modeling approach non-negative matrix factorization to reconstruct the number and age distributions of paleo-source regions of Proterozoic metasedimentary rocks in the southwestern United States. This analysis indicates eight reconstructed end-member distributions representing unique sediment sources: two multi-modal end members characterized by ages older than ca. 1.8 Ga from cratonic Laurentia, five unimodal age distributions between ca. 1.80 Ga and 1.65 Ga consistent with Paleoproterozoic arc magmatic sources, and a ca. 1.6−1.5 Ga end member likely derived from exotic cratons in supercontinent Nuna (Columbia). Sediments deposited between ca. 1.80 Ga and 1.73 Ga yield heterogeneous age distributions suggesting multiple arc-backarc systems and several phases of slab roll back, contraction, and accretionary orogenesis, including input from pre−1.8 Ga Laurentian cratons. Homogenization of DZ signatures during the Yavapai orogeny (ca. 1.72−1.68 Ga) reflect crustal assembly as well as the uplift of Paleoproterozoic arcs in the orogenic hinterland. Detrital zircon age distributions from strata deposited during the Mazatzal orogeny (ca. 1.65−1.60 Ga) suggest the Mazatzal Province is a continental arc constructed on older crust. Mesoproterozoic samples are consistent with multiple basins derived from local recycling and long-distance sediment transport. Collectively, these data record the tectonic transition from the episodic accretion of disparate crustal domains to an increasingly integrated continental margin. These results provide new insights into the Proterozoic tectonic and paleogeographic evolution of the southwestern United States at basin to orogen scales and highlight the power of inverse DZ modeling to extract geologically meaningful quantitative mixture models from sedimentary records alone, offering a powerful tool for deep-time tectonic and basin analysis.

Arizona, California, Colorado, New Mexico, Nevada,↗

Unraveling protracted modification of Archean and Paleoproterozoic crust in central Laurentia, Penokean orogen, with garnet and accessory mineral geochronology and microstructural analysis

Proterozoic metamorphism and deformation of the southern margin of the Superior craton in the Lake Superior region is attributed to the Penokean orogeny (1890−1830 Ma). This model includes a period of crustal inversion in which Archean basement blocks were exhumed through overlying Paleoproterozoic strata, producing the corridor of gneiss domes that parallels the trend of the Penokean orogen across the northern Midcontinent, USA. However, recent geologic mapping and 40 Ar/ 39 Ar geochronology challenge this interpretation, suggesting instead that the gneiss dome structures reflect younger episodes of tectonic activity along the southern margin of Laurentia. In absence of integrated pressure-temperature-time-deformation constraints for these rocks, interpretations are largely limited to their final cooling history, making it difficult to both identify the tectonic forces that shaped the architecture of the Penokean orogenic belt and assess the extent to which later Proterozoic tectonism modified the southern Superior craton. We address this problem with an approach joining thermodynamic modeling, garnet and accessory mineral geochronology, and microstructural analysis for several metamorphic rocks across the gneiss dome corridor. The U-Pb ages of titanite reveal that the Proterozoic geometries of exhumed basement gneiss domes are governed by preexisting Archean structures. Garnet Lu-Hf geochronology constrains the timing of prograde-to-peak metamorphism in the Penokean orogenic belt. Granulite facies metamorphism is related to the final stages of the Penokean orogeny at 1837 Ma and localized in a belt of high-grade rocks near a major Penokean suture. Garnet Lu-Hf ages of samples adjacent to gneiss domes reflect regional metamorphism following the accretionary phase of the Penokean orogeny, between 1825 Ma and 1782 Ma, which we suggest reflects continued crustal thickening related to convergence farther south during this time interval. Combination of garnet microstructures and Sm-Nd ages reflects later exhumation of gneiss domes and buried metasedimentary rocks by ca. 1750 Ma, consistent with previously published 40 Ar/ 39 Ar cooling ages across the region. Reset Lu-Hf and Sm-Nd garnet ages and U-Pb ages of syn-kinematic titanite reflect reactivation of primary Penokean structures during this period of basement uplift. These data document significant modification of the Penokean orogen and the Archean crust of the southern Superior province between 1800 Ma and 1700 Ma. Tectonic activity during this interval coincides with collisional events recognized in western Laurentia, suggesting that the period immediately following the Penokean orogeny may be a broadly important time for crustal growth and modification in proto-North America.

Michigan, Wisconsin↗