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At least 271 records · Page 15Linked to original sources

USGS2020

Field-based method for assessing duration of infectivity for influenza A viruses in the environment

Understanding influenza A virus (IAV) persistence in wetlands is limited by a paucity of field studies relating to the maintenance of infectivity over time. The duration of IAV infectivity in water has been assessed under variable laboratory conditions, but results are difficult to translate to more complex field conditions. We tested a field-based method to assess the viability of IAVs in an Alaska wetland during fall and winter which incorporated physical and chemical properties of the waterbody in which samples were held. Filtered pond water was inoculated with avian fecal samples collected from the environment, aliquoted into a series of duplicate sealed vials and submerged back in the wetland for up to 132 days (October 2018–March 2019). Sample aliquots were sequentially recovered and tested for IAVs by rRT-PCR and virus isolation. One sample remained rRT-PCR positive for the duration of the study and virus isolation positive for 118 days. The surrounding water temperature was 1°–6 °C with near neutral pH (6.6–7.3) for the duration of the study. This proof of concept study demonstrates a protocol for testing the persistence of infectious IAV naturally shed from waterfowl under ambient environmental conditions.

Alaska↗

USGS2012

Land change variability and human-environment dynamics in the United States Great Plains

Land use and land cover changes have complex linkages to climate variability and change, biophysical resources, and socioeconomic driving forces. To assess these land change dynamics and their causes in the Great Plains, we compare and contrast contemporary changes across 16 ecoregions using Landsat satellite data and statistical analysis. Large-area change analysis of agricultural regions is often hampered by change detection error and the tendency for land conversions to occur at the local-scale. To facilitate a regional-scale analysis, a statistical sampling design of randomly selected 10 km × 10 km blocks is used to efficiently identify the types and rates of land conversions for four time intervals between 1973 and 2000, stratified by relatively homogenous ecoregions. Nearly 8% of the overall Great Plains region underwent land-use and land-cover change during the study period, with a substantial amount of ecoregion variability that ranged from less than 2% to greater than 13%. Agricultural land cover declined by more than 2% overall, with variability contingent on the differential characteristics of regional human–environment systems. A large part of the Great Plains is in relatively stable land cover. However, other land systems with significant biophysical and climate limitations for agriculture have high rates of land change when pushed by economic, policy, technology, or climate forcing factors. The results indicate the regionally based potential for land cover to persist or fluctuate as land uses are adapted to spatially and temporally variable forcing factors.

Colorado;Iowa;Kansas;Minnesota;Missouri;Montana;Ne↗

USGS2010

Vertical movements of ocean island volcanoes: Insights from a stationary plate environment

Uplift reconstructions based on the Cape Verde's geological record provide a unique opportunity to study the long-term isostatic movements associated with hotspot activity on a stationary plate environment. The archipelago is considered stationary with respect to its melting source so the hotspot-driven isostatic effects affecting the ocean islands are expected to be enhanced. In this study, Ar–Ar and U–Th geochronology techniques were used to date a set of palaeo-markers of sea-level from Santiago's and São Nicolau's edifices, two of the main Cape Verde Islands. A comparison between relative sea-level and eustatic sea-level (from a modern eustatic curve) was established to extract the vertical displacement undergone by the markers, and to reconstruct the uplift/subsidence history of each island. The resulting uplift reconstructions confirm that both Santiago and São Nicolau experienced a general uplift trend over the last 6 Ma, seemingly synchronous with the vigorous volcanic activity that built their exposed edifices. These islands, however, exhibit different uplift histories despite their common uplift trend. Several uplift mechanisms were tested and a local rather than regional mechanism is proposed as the main cause of uplift, generally unrelated with far-field effects of surface loading. This mechanism is probably associated with magmatic additions at crustal level.

Cape Verde Archipelago↗

USGS2016

Organic petrology and geochemistry of Eocene Suzak bituminous marl, north-central Afghanistan: Depositional environment and source rock potential

Organic geochemistry and petrology of Eocene Suzak bituminous marl outcrop samples from Madr village in north-central Afghanistan were characterized via an integrated analytical approach to evaluate depositional environment and source rock potential. Multiple proxies suggest the organic-rich (TOC ∼6 wt.%) bituminous marls are ‘immature’ for oil generation (e.g., vitrinite R o < 0.4%, T max < 425 °C, PI ≤ 0.05, C 29 ααα S/S + R ≤ 0.12, C 29 ββS/ββS+ααR ≤ 0.10, others), yet oil seeps are present at outcrop and live oil and abundant solid bitumen were observed via optical microscopy. Whole rock sulfur content is ∼2.3 wt.% whereas sulfur content is ∼5.0–5.6 wt.% in whole rock extracts with high polar components, consistent with extraction from S-rich Type IIs organic matter which could generate hydrocarbons at low thermal maturity. Low Fe-sulfide mineral abundance and comparison of Pr/Ph ratios between saturate and whole extracts suggest limited Fe concentration resulted in sulfurization of organic matter during early diagenesis. From these observations, we infer that a Type IIs kerogen in ‘immature’ bituminous marl at Madr could be generating high sulfur viscous oil which is seeping from outcrop. However, oil-seep samples were not collected for correlation studies. Aluminum-normalized trace element concentrations indicate enrichment of redox sensitive trace elements Mo, U and V and suggest anoxic-euxinic conditions during sediment deposition. The bulk of organic matter observed via optical microscopy is strongly fluorescent amorphous bituminite grading to lamalginite, possibly representing microbial mat facies. Short chain n- alkanes peak at C 14 –C 16 ( n- C 17 / n- C 29 > 1) indicating organic input from marine algae and/or bacterial biomass, and sterane/hopane ratios are low (0.12–0.14). Monoaromatic steroids are dominated by C 28 clearly indicating a marine setting. High gammacerane index values (∼0.9) are consistent with anoxia stratification and may indicate intermittent saline-hypersaline conditions. Stable C isotope ratios also suggest a marine depositional scenario for the Suzak samples, consistent with the presence of marine foraminifera including abundant planktic globigerinida (?) and rare benthic discocyclina (?) and nummulites (?). Biomarker 2α-methylhopane for photosynthetic cyanobacteria implies shallow photic zone deposition of Madr marls and 3β-methylhopane indicates presence of methanotrophic archaea in the microbial consortium. The data presented herein are consistent with deposition of Suzak bituminous marls in shallow stratified waters of a restricted marine basin associated with the southeastern incipient or proto-Paratethys. Geochemical proxies from Suzak rock extracts (S content, high polar content, C isotopes, normal (αααR) C 27–29 steranes, and C 29 /C 30 and C 26 /C 25 hopane ratios) are similar to extant data from Paleogene oils produced to the north in the Afghan-Tajik Basin. This observation may indicate laterally equivalent strata are effective source rocks as suggested by previous workers; however, further work is needed to strengthen oil-source correlations.

Marine and Petroleum Geology↗

USGS2017

Formation of Fe-Mn crusts within a continental margin environment

This study examines Fe-Mn crusts that form on seamounts along the California continental-margin (CCM), within the United States 200 nautical mile exclusive economic zone. The study area extends from approximately 30° to 38° North latitudes and from 117° to 126° West longitudes. The area of study is a tectonically active northeast Pacific plate boundary region and is also part of the North Pacific Subtropical Gyre with currents dominated by the California Current System. Upwelling of nutrient-rich water results in high primary productivity that produces a pronounced oxygen minimum zone. Hydrogenetic Fe-Mn crusts forming along the CCM show distinct chemical and mineral compositions compared to open-ocean crusts. On average, CCM crusts contain more Fe relative to Mn than open-ocean Pacific crusts. The continental shelf and slope release both Fe and Mn under low-oxygen conditions. Silica is also enriched relative to Al compared to open-ocean crusts. This is due to the North Pacific silica plume and enrichment of Si along the path of deep-water circulation, resulting in Si enrichment in bottom and intermediate waters of the eastern Pacific. The CCM Fe-Mn crusts have a higher percentage of birnessite than open-ocean crusts, reflecting lower dissolved seawater oxygen that results from the intense coastal upwelling and proximity to zones of continental slope pore-water anoxia. Carbonate fluorapatite (CFA) is not present and CCM crusts do not show evidence of phosphatization, even in the older sections. The mineralogy indicates a suboxic environment under which birnessite forms, but in which pH is not high enough to facilitate CFA deposition. Growth rates of CCM crusts generally increase with increasing water depth, likely due to deep-water Fe sources mobilized from reduced shelf and slope sediments. Many elements of economic interest including Mn, Co, Ni, Cu, W, and Te have slightly or significantly lower concentrations in CCM crusts relative to crusts from the Pacific Prime Crust Zone and other open-ocean basins. However, concentrations of total rare earth elements and yttrium average only slightly lower contents and in the future may be a strategic resource for the U.S.

California↗

USGS2015

A 3400 year paleolimnological record of prehispanic human–environment interactions in the Holmul region of the southern Maya lowlands

The timing, magnitude and drivers of late Holocene environmental change in the Holmul region of the southern Maya lowlands are examined by combining paleoenvironmental and archeological data. Environmental proxy analyses on a ~ 3350 cal yr lacustrine sediment record include pollen, charcoal, loss on ignition, magnetic suscep- tibility, and elemental geochemistry. Archeological evidence is derived from extensive settlement surveys conducted near the study site. Results indicate nearby settlement and agricultural activity taking place in an environment characterized by open forest from around 3350 to 950 cal yr BP. The fire history shows a dramatic increase in burning during the Classic period, possibly reflecting changing agricultural strategies. A distinct band of carbonate deposited from 1270 to 1040 cal yr BP suggests decreased hydrologic input associated with drier conditions. Abrupt changes in proxy data around 940 cal yr BP indicate a cessation of human disturbance and local abandonment of the area.

Peten↗

USGS2015

Variables and potential models for the bleaching of luminescence signals in fluvial environments

Luminescence dating of fluvial sediments rests on the assumption that sufficient sunlight is available to remove a previously obtained signal in a process deemed bleaching. However, luminescence signals obtained from sediment in the active channels of rivers often contain residual signals. This paper explores and attempts to build theoretical models for the bleaching of luminescence signals in fluvial settings. We present two models, one for sediment transported in an episodic manner, such as flood-driven washes in arid environments, and one for sediment transported in a continuous manner, such as in large continental scale rivers. The episodic flow model assumes that the majority of sediment is bleached while exposed to sunlight at the near surface between flood events and predicts a power-law decay in luminescence signal with downstream transport distance. The continuous flow model is developed by combining the Beer–Lambert law for the attenuation of light through a water column with a general-order kinetics equation to produce an equation with the form of a double negative exponential. The inflection point of this equation is compared with the sediment concentration from a Rouse profile to derive a non-dimensional number capable of assessing the likely extent of bleaching for a given set of luminescence and fluvial parameters. Although these models are theoretically based and not yet necessarily applicable to real-world fluvial systems, we introduce these ideas to stimulate discussion and encourage the development of comprehensive bleaching models with predictive power.

Quaternary International↗

USGS2021

A multi-decadal geochemical record from Rano Aroi (Easter Island/Rapa Nui): Implications for the environment, climate and humans during the last two millennia

The small and remote Easter Island (Rapa Nui) has a complex and still partially unknown history of human colonization and interactions with the environment. Previous research from sedimentary archives collected in the three freshwater bodies of Rapa Nui document dramatic environmental changes over the last two millennia. Yet, the characteristics of sediments and paleoenvironmental records are challenging to interpret, mainly due to poor temporal resolution, hiatuses and sediment mixing. In this study, we reconstruct past changes in lithogenic inputs, weathering processes, redox conditions, productivity and water levels in the Rano Aroi wetland over the last 2000 years through the determination of major, trace and rare earth elements in a new peat core collected in 2017. The chronology is based on 8 14 C AMS dates for the upper 1.5 m and provides decadal to multi-decadal resolution which is unprecedented for the island of Rapa Nui. The multielemental proxies depict seven distinct chronological phases marked by well-defined geochemical transitions. With only a few minor fluctuations, climate conditions were dry and the mire was mildly anoxic during the first millennium (0–1000 CE) to the arrival of the first Polynesians in Rapa Nui (800–1300 CE) and until ∼1400 CE, followed by wetter conditions afterwards. The record documents with unprecedented accuracy and resolution intense droughts occurring during the middle Little Ice Age between 1520 and 1710 CE, which may have been exacerbated by human activities and triggered dramatic cultural shifts. During the interval of first contact between the Rapanuis and Europeans, the climate changed to wetter conditions, followed by intense precipitations between 1790 and 1900 CE.

Quaternary Science Reviews↗

USGS2015

Landscape community genomics: understanding eco-evolutionary processes in complex environments

Extrinsic factors influencing evolutionary processes are often categorically lumped into interactions that are environmentally (e.g., climate, landscape) or community-driven, with little consideration of the overlap or influence of one on the other. However, genomic variation is strongly influenced by complex and dynamic interactions between environmental and community effects. Failure to consider both effects on evolutionary dynamics simultaneously can lead to incomplete, spurious, or erroneous conclusions about the mechanisms driving genomic variation. We highlight the need for a landscape community genomics (LCG) framework to help to motivate and challenge scientists in diverse fields to consider a more holistic, interdisciplinary perspective on the genomic evolution of multi-species communities in complex environments.

Trends in Ecology and Evolution↗

USGS2017

Environment and paleoecology of a 12 ka mid-North American Younger Dryas forest chronicled in tree rings

Until now, availability of wood from the Younger Dryas abrupt cooling event (YDE) in N. America ca. 12.9 to 11.6 ka has been insufficient to develop high-resolution chronologies for refining our understanding of YDE conditions. Here we present a multi-proxy tree-ring chronology (ring widths, “events” evidenced by microanatomy and macro features, stable isotopes) from a buried black spruce forest in the Great Lakes area (Liverpool East site), spanning 116 yr at ca. 12,000 cal yr BP. During this largely cold and wet period, the proxies convey a coherent and precise forest history including frost events, tilting, drowning and burial in estuarine sands as the Laurentide Ice Sheet deteriorated. In the middle of the period, a short mild interval appears to have launched the final and largest episode of tree recruitment. Ultimately the tops of the trees were sheared off after death, perhaps by wind-driven ice floes, culminating an interval of rising water and sediment deposition around the base of the trees. Although relative influences of the continental ice sheet and local effects from ancestral Lake Michigan are indeterminate, the tree-ring proxies provide important insight into environment and ecology of a N. American YDE boreal forest stand.

Quaternary Research↗

USGS1999

Distributions of uronic acids and O-methyl sugars in sinking and sedimentary particles in two coastal marine environments

Although recent research has indicated that bacteria may contribute an important fraction of biochemical residues in terrestrial and marine environments, it is difficult for geochemists to identify contributions from these ubiquitous and biochemically diverse organisms. Previous studies have suggested uronic acids and O -methyl sugars may be useful indicators of microbial abundance and activity, but have been limited primarily to analyses of a small number of isolated samples. We report here comparative distributions of O -methyl sugars, uronic acids, and aldoses in sediment trap material and sediments from Dabob Bay, WA and nearby Saanich Inlet, BC, where temporal and spatial trends may be used together with well-established patterns in other biochemicals to identify bacterial contributions against the background of other carbohydrate sources. O -methyl sugars and uronic acids were important contributors to the overall flux and burial of polysaccharide material in Dabob Bay and Saanich Inlet, composing ≤12 wt% of the total carbohydrate yields from sediment trap and sediment samples. O -methyl sugars accounted for an average of 5% of the carbohydrate yields from sediment trap materials and sediments, but were found rarely and only in low abundance in vascular plant tissues, phytoplankton, and kelp. In contrast, uronic acids were abundant products of sediment trap material and sediments, as well as vascular plant tissues, where in some cases they predominated among all carbohydrates. Uronic acid abundance in sediment trap material averaged 3% and ranged to >6% of total carbohydrate yields. The persistence of total minor sugar yields in water column collections from Dabob Bay throughout the seasonal cycle indicated they had a primary source that was not directly related to plankton bloom cycles nor pulsed inputs of vascular plant remains. Subsurface maxima in total minor sugar yields (and several individual components) within sediment cores from both sites indicate in situ sedimentary sources. Taken together, the observed environmental distributions strongly suggest that the minor sugar abundances in Dabob Bay and Saanich Inlet were controlled by in situ microbial production.

British Columbia, Washington↗

USGS2003

Biogeochemical sulphur cycle in an extreme environment - Life beneath a high arctic glacier, Nunavut, Canada

Unique springs discharge from the surface of a high arctic glacier, releasing H2S, and depositing native sulphur, gypsum, and calcite. A rare CaCO3 polymorph, vaterite, is also observed. Physical and chemical conditions of the spring water and surrounding environment, as well as mineralogical and isotopic signatures, argue for biologically mediated redox reactions controlling sulfur. Cell counts and DNA analyses, confirm bacteria are present in the spring system. ?? 2003 Elsevier Science B.V. All rights reserved.

Conference Paper↗

USGS2004

Seasonal methane emissions by diffusion and ebullition from oligohaline marsh environments in coastal Louisiana

Methane is an important atmospheric greenhouse gas that is emitted from many natural and anthropogenic sources. In order to evaluate the global methane budget, precise data are needed from the diverse sources including coastal wetlands. Over 100 time-series determinations of methane emissions from an oligohaline wetland (brackish marsh) in coastal Louisiana show large variability during five seasonal sampling periods. Emission by both diffusion and ebullition (bubbles) was measured, however, neither of these emission modes were strongly dependent on either water depth or temperature (except in winter). Methane emission to static collectors placed over plants ( Scirpus olneyi and Spartina patens ) was not significantly different from shallow open water or mud. However, considerable heterogeneity in methane emissions and processes occurs even at a single site. Thus, establishing a reasonable estimate of the overall methane emission for a particular marsh environment and season requires multiple measurements at several sites. The average emissions for April, May, July, and September ranged from 31 to 54 mg/m2/h (744–1296 mg/m 2 /day). This can be separated into emissions from diffusion ranging from 8.3 to 20 mg/m 2 /h (18–50% of total) and emissions due to ebullition of 20–44 mg/m /h (50–82%). January emissions were much lower, amounting to 0.2 mg/m 2 /h (6 mg/m 2 /day), mainly by diffusion with only one episode of ebullition. Extrapolating these data to annual emissions gives total annual methane emissions of 203 g/m 2 /yr (61 g/m 2 /yr by diffusion and 142 g/m 2 /yr by ebullition).

Book chapter↗

USGS2006

The relative roles of environment, history and local dispersal in controlling the distributions of common tree and shrub species in a tropical forest landscape, Panama

We used regression models and information-theoretic model selection to assess the relative importance of environment, local dispersal and historical contingency as controls of the distributions of 26 common plant species in tropical forest on Barro Colorado Island (BCI), Panama. We censused eighty-eight 0.09-ha plots scattered across the landscape. Environmental control, local dispersal and historical contingency were represented by environmental variables (soil moisture, slope, soil type, distance to shore, old-forest presence), a spatial autoregressive parameter (??), and four spatial trend variables, respectively. We built regression models, representing all combinations of the three hypotheses, for each species. The probability that the best model included the environmental variables, spatial trend variables and ?? averaged 33%, 64% and 50% across the study species, respectively. The environmental variables, spatial trend variables, ??, and a simple intercept model received the strongest support for 4, 15, 5 and 2 species, respectively. Comparing the model results to information on species traits showed that species with strong spatial trends produced few and heavy diaspores, while species with strong soil moisture relationships were particularly drought-sensitive. In conclusion, history and local dispersal appeared to be the dominant controls of the distributions of common plant species on BCI. Copyright ?? 2006 Cambridge University Press.

Journal of Tropical Ecology↗

USGS2026

Depositional environment and diagenetic history of gas hydrate-bearing sediments of the Alaska North Slope (HYDRATE 02 Geo Data Well)

We characterized the lithological, solid-phase geochemical, and rock magnetic properties of sediment cores from subpermafrost strata on the Alaska North Slope collected as part of the U.S. Department of Energy (DOE), the Japan Organization for Metals and Energy Security (JOGMEC), and the U.S. Geological Survey (USGS) Collaborative Gas Hydrate Research and Development (R&D) Project in Alaska. Pressure cores were recovered from the HYDRATE 02 Geo Data Well (GDW) at the Kuparuk State 7-11-12 site through two hydrate-bearing sand reservoirs, the B1 and D1 sands, and their finer-grained bounding sediments. Both the B1 and D1 sands are quartz-rich, chert-bearing, very fine litharenite sands. These submature to immature sands are poorly to moderately sorted and angular with local fine-scale cross-stratification. The B1 sand has larger grains and a lower clay content as compared to the D1 sand. These sands are the upper portions of upward coarsening progradational sequences. The clay- and silt-rich bounding muds exhibit fine-scale wavy and lenticular laminations, suggesting episodic high energy deposition events. Overall, these sediments were deposited in a shoreface to nearshore marine environment during the Paleogene, modulated by changing depositional energy associated with sea level variation. Organic matter δ 13 C and C/N composition of these sediments indicate a source mixture of land plants and freshwater plankton, with possible minor presence of oil within the B1 sand. These sediments contain high and variable total sulfur (TS) content, suggesting porewater conditions influenced by variable salinity over time. Rock magnetic analyses indicate precipitation of greigite in the mud beneath the D1 sand, in the basal C shale overlying the B1 sand, and the mud beneath the B1 sand, likely due to intervals of sulfate limitation during periods of lower Arctic Ocean salinity. Based on pyrite abundance, TS, and δ 34 S-TS composition, the D1 sand and bounding sediments experienced more substantial sulfide precipitation. The unit E basal shale overlying the D1 sand contains a 0.25 m thick pyrite-dominant sand, indicating local bottom water anoxic conditions. X-ray fluorescence scanning and discrete measurements provide additional supporting interpretation of the depositional and diagenetic processes that have occurred at this site and track the relative amount of drilling fluid contamination with barium abundance in the core samples.

Alaska↗

USGS2016

Using continuous underway isotope measurements to map water residence time in hydrodynamically complex tidal environments

Stable isotopes present in water (δ 2 H, δ 18 O) have been used extensively to evaluate hydrological processes on the basis of parameters such as evaporation, precipitation, mixing, and residence time. In estuarine aquatic habitats, residence time (τ) is a major driver of biogeochemical processes, affecting trophic subsidies and conditions in fish-spawning habitats. But τ is highly variable in estuaries, owing to constant changes in river inflows, tides, wind, and water height, all of which combine to affect τ in unpredictable ways. It recently became feasible to measure δ 2 H and δ 18 O continuously, at a high sampling frequency (1 Hz), using diffusion sample introduction into a cavity ring-down spectrometer. To better understand the relationship of τ to biogeochemical processes in a dynamic estuarine system, we continuously measured δ 2 H and δ 18 O, nitrate and water quality parameters, on board a small, high-speed boat (5 to >10 m s –1 ) fitted with a hull-mounted underwater intake. We then calculated τ as is classically done using the isotopic signals of evaporation. The result was high-resolution (∼10 m) maps of residence time, nitrate, and other parameters that showed strong spatial gradients corresponding to geomorphic attributes of the different channels in the area. The mean measured value of τ was 30.5 d, with a range of 0–50 d. We used the measured spatial gradients in both τ and nitrate to calculate whole-ecosystem uptake rates, and the values ranged from 0.006 to 0.039 d –1 . The capability to measure residence time over single tidal cycles in estuaries will be useful for evaluating and further understanding drivers of phytoplankton abundance, resolving differences attributable to mixing and water sources, explicitly calculating biogeochemical rates, and exploring the complex linkages among time-dependent biogeochemical processes in hydrodynamically complex environments such as estuaries.

California↗

USGS2010

Measurement of dissolved organic matter fluorescense in aquatic environments: An interlaboratory comparison

The fluorescent properties of dissolved organic matter (DOM) are often studied in order to infer DOM characteristics in aquatic environments, including source, quantity, composition, and behavior. While a potentially powerful technique, a single widely implemented standard method for correcting and presenting fluorescence measurements is lacking, leading to difficulties when comparing data collected by different research groups. This paper reports on a large-scale interlaboratory comparison in which natural samples and well-characterized fluorophores were analyzed in 20 laboratories in the U.S., Europe, and Australia. Shortcomings were evident in several areas, including data quality-assurance, the accuracy of spectral correction factors used to correct EEMs, and the treatment of optically dense samples. Data corrected by participants according to individual laboratory procedures were more variable than when corrected under a standard protocol. Wavelength dependency in measurement precision and accuracy were observed within and between instruments, even in corrected data. In an effort to reduce future occurrences of similar problems, algorithms for correcting and calibrating EEMs are described in detail, and MATLAB scripts for implementing the study's protocol are provided. Combined with the recent expansion of spectral fluorescence standards, this approach will serve to increase the intercomparability of DOM fluorescence studies.

Environmental Science & Technology↗

USGS2010

Natural chlorate in the environment: Application of a new IC-ESI/MS/MS method with a Cl18O3- internal standard

A new ion chromatography electrospray tandem mass spectrometry (IC-ESI/MS/MS) method has been developed for quantification and confirmation of chlorate (ClO 3 − ) in environmental samples. The method involves the electro-chemical generation of isotopically labeled chlorate internal standard (Cl 18 O 3 − ) using 18 O water (H 2 18 O). The standard was added to all samples prior to analysis thereby minimizing the matrix effects that are associated with common ions without the need for expensive sample pretreatments. The method detection limit (MDL) for ClO 3 − was 2 ng L −1 for a 1 mL volume sample injection. The proposed method was successfully applied to analyze ClO 3 − in difficult environmental samples including soil and plant leachates. The IC-ESI/MS/MS method described here was also compared to established EPA method 317.0 for ClO 3 − analysis. Samples collected from a variety of environments previously shown to contain natural perchlorate (ClO 4 − ) occurrence were analyzed using the proposed method and ClO 3 − was found to co-occur with ClO 4 − at concentrations ranging from <2 ng L −1 in precipitation from Texas and Puerto Rico to >500 mg kg −1 in caliche salt deposits from the Atacama Desert in Chile. Relatively low concentrations of ClO 3 − in some natural groundwater samples (<0.1 μg L −1 ) analyzed in this work may indicate lower stability when compared to ClO 4 − in the subsurface. The high concentrations of ClO 3 − in caliches and soils (3−6 orders of magnitude greater) as compared to precipitation samples indicate that ClO 3 − , like ClO 4 − , may be atmospherically produced and deposited, then concentrated in dry soils, and is possibly a minor component in the biogeochemical cycle of chlorine.

Environmental Science & Technology↗