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Advancing current understanding of Martian impact-generated hydrothermal systems through novel coupled modeling: Insights from Gale, Jezero, and other craters

Impact-generated hydrothermal systems are considered potentially habitable environments on Mars, Earth, and other planetary bodies for microbial life. However, there is an ongoing debate regarding what geological features on Mars provide definitive evidence for such systems. Although earlier studies have modeled hydrothermal processes in Martian craters, they often lacked integration with shock physics hydrocodes to constrain initial impact conditions. The importance of this two-code coupling was demonstrated by successfully replicating alteration signatures in the Earth's Haughton impact structure. In this study, we use a similar two-code approach, combining the iSALE hydrocode with the HYDROTHERM hydrothermal model to simulate the full evolution of impact-generated hydrothermal systems. We apply this method to craters the size of Jezero (∼50 km) and Gale (∼154 km) in diameter. Although Jezero's interior is largely buried, our results align with hypothesized hydrothermal vents and alteration minerals near central uplifts in similarly sized exposed craters, such as Toro and Auki. Furthermore, our models correspond to alteration patterns observed by the Curiosity in the lower layers of Mount Sharp, which may represent remnants of impact-driven hydrothermal activity. A key finding is that these systems may persist much longer than previously estimated. Our simulations suggest that a Jezero-sized system could remain habitable for thermophiles for approximately 720,000 years, whereas a Gale-sized system could persist for nearly 2 million years. Additionally, simulations under unsaturated crustal conditions reveal that air-dominated near-surface layers can suppress vertical fluid flow, enabling deep subsurface alteration without producing detectable mineral signatures at the surface.

Journal of Geophysical Research - Planets

Using peak geometry and shifts in the x-ray spectrum of carbon from electron probe microanalysis to determine thermal maturity of organic matter

During the burial of mudstones, the associated organic matter undergoes gradual thermal maturation, a key process that can influence the reactivity of organic matter during catagenesis, the formation of hydrocarbon deposits and the chemical weathering of mudstones. Conventional methods for assessing the thermal maturity of organic matter often fail to reflect the geochemical heterogeneity between individual organic phases in mudstone samples. Here, we report an alternative, non-destructive, surficial and micro-scale (analytical spot size of ~ 300 nm with about 4 μm diffusion depth for micrometre-size organic grains) method to evaluate the thermal maturity of organic matter in mudstones using the carbon K α X-ray spectrum measured by field emission-electron probe microanalyser (FE-EPMA). Using this method, we observed correlations between parameter values derived from FE-EPMA spectra, including the peak position, the peak area and the intra-sample heterogeneity of these measurements, and independently measured vitrinite/solid bitumen reflectance for a suite of mudstones, representing different age, geological context and burial depth. With the increased values in peak area and position, we identified an increase in the carbon mass fraction of organic matter and the mean nominal oxidation state of carbon approaching zero. These trends, which are consistent with aromatisation and graphitisation, provide the rationale for using FE-EPMA to estimate the thermal maturity of organic matter. To explore some of these trends in more detail, we employed time-of-flight secondary ionisation mass spectrometry, X-ray photoelectron spectroscopy and optical reflectance measurements on a subset of samples.

Geostandards and Geoanalytical Research

Quantifying groundwater response and uncertainty in beaver-influenced mountainous floodplains using machine learning-based model calibration

Beavers ( Castor canadensis ) alter river corridor hydrology by creating ponds and inundating floodplains, and thereby improving surface water storage. However, the impact of inundation on groundwater, particularly in mountainous alluvial floodplains with permeable gravel/cobble layers overlain by a soil layer, remains uncertain. Numerical modeling across various floodplain structures considers topographic and sediment complexity and multidirectional flow, linking inundation to groundwater response. This study develops a model-data integration workflow to address uncertainty in groundwater response to beaver-induced inundations in a mountainous alluvial floodplain in the Upper Colorado River Basin. Uncertain factors include seasonal hydrologic dynamics, hydraulic conductivities, floodplain structures, and meteorological forcings. We employed an ensemble of groundwater models, based on geophysical and hydrologic data, with machine learning-based calibration using a neural density estimator. This allowed us to quantify the vertical flux from the soil layer to the permeable gravel bed, the down-valley underflow within the gravel bed, and their ratios. Results show a significant increase in the vertical flux relative to down-valley underflow, from 2% during dry pond periods to 20% during wet periods, serving as an analogy for conditions without and with beaver ponds. The study highlights the influence of floodplain structure on groundwater storage, water balance, and water quality impacted by beaver ponds. A thick gravel bed layer, with a large down-valley underflow, minimizes the effect of beaver-induced inundation on water quality. We emphasize the need for field-scale measurements of floodplain structure and improved characterization of evapotranspiration changes to reduce uncertainty in groundwater response.

Colorado

Beyond the wedge: Impact of tidal streams on salinization of groundwater in a coastal aquifer stressed by pumping and sea-level rise

Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume.

Delaware

Modeling future groundwater depletion to evaluate sustainability goals set under the Sustainable Groundwater Management Act in the critically overdrafted basins of the Central Valley, California, USA (2020–2070)

In 2014, California's Sustainable Groundwater Management Act (SGMA) mandated local agencies to devise and implement groundwater sustainability plans to address critically overdrafted conditions throughout the state's aquifers. However, the feasibility of these agencies' sustainability goals has not previously been assessed through a regional-scale, integrative lens. Here, we develop and analyze a novel, basin-wide database of 936 sustainability indicator wells located within Central Valley subbasins designated as critically overdrafted, most of which lie in the San Joaquin Valley. Our database shows 2040 groundwater elevation goals vary widely from 60 m above to 80 m below 2020 levels, with variability within and between adjacent subbasins. To evaluate the feasibility of achieving these goals, we coupled the database with a regional hydrologic model (Central Valley Hydrologic Model version 2) and simulated multiple future pumping scenarios. Results show that under increased groundwater demand, 60%–70% of indicator wells may fail to meet their 2040 goals. Even a 50% reduction from 2020 demand levels leaves nearly 40% of wells failing to meet their sustainability thresholds by 2040. Baseline models show that by 2070, up to 70% of wells could fail to meet their goals due to large-scale, spatially connected regions of groundwater depletion. This integrated framework, linking the first region-wide compilation of SGMA indicator wells with a regional groundwater model, demonstrates that many local sustainability goals may be unattainable with substantial (up to 50%) reductions in pumping. Additional management interventions, such as expanded recharge or coordinated demand reductions, may help achieve sustainability goals.

California

A roadmap for identifying and interpreting physical processes and national water model prediction bias associated with baseflow index regimes across the contiguous United States

Understanding how groundwater–surface water interactions shape streamflow variability is critical for diagnosing low flow behavior and prediction bias in continental scale hydrologic models. We present a process informed framework that links observed baseflow (BF) dynamics, watershed attributes, and National Water Model (NWM) performance across the contiguous United States. Using daily observed streamflow from 797 reference quality streamgages, we developed monthly baseflow index (BFI) signatures using a streamgage specific, calibrated digital filter. Hierarchical clustering of these signatures identified seven distinct BFI regimes capturing regional and seasonal variability. We evaluated NWM v3.0 retrospective streamflow performance within each regime using multiple hydrograph and flow duration curve-based metrics. Model skill varied systematically across regimes: mixed flow systems were simulated most accurately, while predominantly BF dominated and quickflow dominated regimes exhibited substantially poorer performance. Across nearly all regimes, the NWM underestimated observed BFI magnitude and frequently failed to reproduce seasonal BF patterns, indicating systematic biases in simulated low flow contributions. To relate these regimes to potential process controls, we trained a Random Forest classifier using static watershed attributes and applied Shapley Additive Explanations to identify features most strongly associated with each regime. Results highlight regionally varying influences, including the dominant role of snow fraction and seasonal runoff timing in snow dominated basins and the importance of evapotranspiration and aridity in quickflow dominated systems. Collectively, these findings demonstrate how hydrologic signatures combined with interpretable machine learning can diagnose regime specific model biases and generate process-based hypotheses about limitations in large scale hydrologic prediction systems.

contiguous United States

Megafaunal community structure on ferromanganese and phosphorite hardgrounds in the Southern California Borderland

The Southern California Borderland (SCB) is a topographically complex region on the active continental margin that hosts varied hardground habitats, including ferromanganese (FeMn) crusts and phosphorites, marine minerals being considered for resource extraction. The SCB is influenced by seasonal upwelling and terrestrial inputs, and has a well-defined oxygen-minimum zone (OMZ). We analyzed megafaunal community composition, density, and diversity across 41 ROV video transects at 10 SCB hard substrate sites spanning depth (378–2765 m), temperature (1.79–7.96 °C), and oxygen (3.91–105.67 μM) gradients, with varying rock types (FeMn crusts, phosphorites, other rocks). We counted 32,426 individuals representing 146 unique taxa over a total area of 21,935 m 2 . Echinodermata contributed 48 % of the total abundance; Cnidaria 24 %; Porifera 13 %; Annelida 6 %; Arthropoda 6 %; Chordata 2 %; Mollusca, Foraminifera, and Hemichordata <1 %. Megafauna communities showed clear heterogeneity, with density, diversity, and community composition varying among transects within sites and across sites. Rock type recorded no influence on megafaunal density, but habitats that included FeMn crusts had higher diversity and distinct taxonomic composition. Location, depth, and oxygen were the most important variables explaining variance among megafaunal communities, with distinct communities formed at deeper depths and within the OMZ. This study provides baseline information about the megafauna inhabiting SCB hardgrounds, particularly those associated with minerals considered for their resource potential. It extends existing documentation of such communities to greater depths, reveals increased representation of sponges and corals below 1000 m, and highlights the variability within and among deep-sea megafaunal communities, offering context for informed policy decisions.

Southern California borderland

Quantitative mineral resource assessment of lithium pegmatite deposits in the northern Appalachian orogen, USA

Lithium demand is projected to increase more than 48 times by 2040 due to electric vehicle production and other energy storage needs. Most lithium production is outside of the USA, thereby increasing supply chain vulnerability. The combined end use importance and heightened supply risk of lithium make this lightest metallic element a critical commodity to the USA. To mitigate this supply risk, the US Geological Survey is actively assessing lithium deposits in the USA. Herein, we detail an assessment for lithium-mineralized pegmatites in the US northern Appalachian Mountains. Permissive tracts were generated by cross-referencing tectonic and geologic maps and mineral occurrence data with mappable criteria derived from generalized and region-specific lithium pegmatite ore deposit models; tracts were then ranked as having high, medium, or low permissibility. Available geophysical and geochemical data were found to be of minimal utility for this deposit type at the scale of the assessment. The number of undiscovered deposits were estimated and integrated into probabilistic simulations, which included an expanded and updated global grade and tonnage model of pegmatite-hosted lithium ore. The estimated total amount of undiscovered resources for the northern Appalachian Orogen has a median value of 1,410,000 metric tons of Li 2 O when considering moderate correlation across sub-regions. At a confidence level of 90%, a resource of at least 90,000 metric tons of Li 2 O remains undiscovered, and at a 10% confidence level, a resource of as much as 7,380,000 metric tons Li 2 O remains undiscovered. After applying an up-to-date economic filter to convert median contained lithium to recoverable material, a correlated total of 900,000 metric tons of Li 2 O may be economically extractable, equating to enough Li 2 O to provide the current annual US lithium supply deficit (presently obtained through net imports) for 127 years at 2025 rates of apparent consumption. This period of provision will inevitably shorten with projected increasing consumption rates, emphasizing that further research could be completed to better delineate regions of high lithium resource potential and support exploration and domestic production.

Connecticut, Delaware, Maine, Massachusetts, New H

New paleomagnetic constraints on the eruption timing, stratigraphy, and post-emplacement deformation of the Picture Gorge Basalt within the Columbia River Basalt Group

The Picture Gorge Basalt (PGB) is part of the Miocene Columbia River Basalt Group (CRBG). The PGB, which outcrops in eastern Oregon, is considered coincident in time with the voluminous Grande Ronde Basalt. New radiometric ages have expanded the age‐range of the PGB, suggesting it began erupting prior to the Steens Basalt to its south and continued until after cessation of the Grande Ronde Basalt eruptions, an interval of 1.5 Ma. However, the existing paleomagnetism of the PGB implies this eruption timeline is an overestimate. To reconcile the radiometric and paleomagnetic timescales for the PGB, we conducted a paleomagnetic study on sections of the PGB to construct a detailed, high‐quality magnetostratigraphy. Our data indicate the stratigraphically lowest lava flows in the PGB are of reversed polarity, revealing a new paleomagnetic transition with the PGB and a reversed (R)–normal (N)–reversed (R) sequence. This suggests one of two timeline possibilities for PGB volcanism: (a) eruptions began and during through CRBG polarity chrons R0–N0–R1, penecontemporaneous with Steens Basalt, or (b) eruptions began and persisted during CRBG polarity chrons R1–N1–R2. Our work supports a longer interval of PGB volcanism than was suggested by previous paleomagnetic data but is at odds with the suggestion that PGB eruptions lasted through the entire main CRBG. We favor a scenario wherein PGB eruptions begin with R0 and continue into the R1 paleomagnetic interval. The paleomagnetic results also record a ∼18° vertical‐axis rotation of east‐central Oregon after ∼16 Ma with respect to stable North America.

Oregon

Satellite tracking of Galapagos Petrel Pterodroma phaeopygia reveals distribution and movements during chick rearing

We tracked 19 adult Galapagos Petrels Pterodroma phaeopygia during the chick-rearing seasons in 2009 and 2010 (Santa Cruz Island [ n = 16] and Floreana Island [ n = 3]) in the Galápagos Islands, Ecuador. Eight petrels performed 27 complete foraging trips lasting 0.6 to 18.8 days. Short trips (3.2 ± 2.1 days; 785 km; max displacement 671 km) and long trips (10.8 ± 3.9 days; 2,856 km; max displacement 1,034 km) resulted in concentrated use of waters off southern and western Isabela Island and within the Galápagos Marine Reserve (GMR). Less concentrated time extended farther southwest and eastward, in that case toward mainland Ecuador. Total distance covered among all completed trips, independent of duration, was strongly correlated with trip duration ( R ² = 0.92), indicating a strategy favoring active searching and foraging over commuting. Petrels ranged across Ecuador's exclusive economic zone (EEZ), as well as other countries' (Colombia, Costa Rica, Perú), and waters beyond; they spent 46%, 27%, and 34% of their time in the GMR during short, long, and apparent (incomplete) trips, respectively. However, overlap with EEZs or marine protected areas (MPAs) does not necessarily confer protection, because commercial tuna fishing, including legal fishing historically permitted inside the GMR, occurs within these waters. Including all complete and incomplete trips, petrels spent 37% of their time in high-seas waters without formal protection, outside both MPAs and EEZs. While some hot spots overlapped Galápagos MPAs, the far-ranging nature of chick-provisioning petrels underscores the importance for this species of also having coordinated, multinational protection of the high seas.

Floreana Island, Galápagos Islands, Santa Cruz Isl

Competition between invasive round goby and native slimy sculpin in a coldwater laboratory setting

Slimy sculpin ( Cottus cognatus ) abundance has substantially declined in many regions of the Laurentian Great Lakes coincident with the arrival and range expansions of invasive round goby ( Neogobius melanostomus ). Previous studies have shown that round goby can outcompete native mottled sculpin ( C. bairdii ) for shelter and negatively affect native spoonhead sculpin ( C. ricei ) growth, but direct behavioral interactions of slimy sculpin and round goby have not been observed. We conducted a laboratory experiment in which a pair of slimy sculpin were placed in an aquarium that contained an artificial spawning shelter and one round goby (treatment, n = 10) or no other fish (control, n = 10) for at least 30 days at temperatures reflective of their potential offshore overlap. We measured slimy sculpin egg deposition, aggressive interactions, artificial shelter occupancy, growth, and survival. Slimy sculpin were less likely to occupy shelters and experienced increased intraspecific competition when a round goby was present. In contrast, round goby rarely chased slimy sculpin, slimy sculpin were more likely to chase round goby, and slimy sculpin growth, egg deposition, and survival were not significantly different between groups. Differences in density between treatments and the relative size of fish could confound our observations. However, the dominant slimy sculpin occupied the shelter at similar rates between experimental groups if the round goby was smaller. Our results indicate that larger round goby overlapping with slimy sculpin could affect slimy sculpin shelter and space use, but the Great Lakes environment may create more stress for slimy sculpin than we observed.

Lake Michigan, Lake Superior

Seismic characteristics of the April 2024 eruption of Ruang Volcano, North Sulawesi, Indonesia

The two most recent eruptions of Ruang volcano, in 2002 and 2024, have been large (VEI 4) with very short precursory periods, 3 and 6 days, respectively. Background seismicity at Ruang volcano is generally low with 0–2 volcano-tectonic (VT) earthquakes per day. The 2024 eruptions were preceded by a notable increase in VT earthquakes from 11 to 15 April with a rapid escalation from 16 to 17 April in the form of increased VT swarms, and the appearance of low frequency earthquakes and short bursts of VT drumbeats shortly before the eruption. Similar VT seismic unrest was recorded in March 2015, May 2016, and April 2022, although none of these episodes culminated in an eruption. A comparison of seismic energy release between April 2022 and April 2024 shows distinct differences. In 2024, cumulative seismic energy reached its peak within 5 days, just before the onset of eruption on 17 April. In contrast, during the 2022-episode, energy release followed a more gradual increase over 8 days peaking on 16 April, then declining gradually without leading to eruption. Notably, low frequency (LF) and drumbeat earthquakes were absent in non-eruptive unrest episodes. The transition to proximal LFs in 2024 likely signals pressure fluctuations, intensified magma degassing, and conduit formation, acting as an important precursor to eruption. Additionally, the occurrence of short bursts of drumbeat seismicity likely reflects the onset of the shallow magma ascent and was an important short-term precursor to the eruption. Finally, we examine the potential influence of regional tectonic earthquakes on the escalation of precursory unrest in 2024.

North Sulawesi, Ruang volcano

Gas emissions from the Sulphur Bank Mercury Mine hydrothermal system, Clear Lake volcanic field, California

The Sulphur Bank Mercury Mine (SBMM) hydrothermal system offers insights into active degassing processes in the Clear Lake volcanic field (CLVF), a high-threat region based on its record of Holocene eruptions and proximity to populated areas. Here we present chemical and isotopic analyses of gas samples collected between 2015 and 2023, along with the first comprehensive CO 2 flux survey of the SBMM area conducted in 2023. Sampled gases are CO 2 - and CH 4 -rich (≥84 and 6 mol% in dry gas, respectively) with high mantle-derived helium contributions ( 3 He/ 4 He = 6.54–7.86 R C /R A ). Carbon isotopic compositions of CO 2 (δ 13 C = −10.0 to −9.5 ‰) and CH 4 (δ 13 C = −35.8 ‰) indicate mixed sources, with significant contributions from metamorphism of organic-rich Franciscan Complex rocks hosting the hydrothermal system. Modeling of gas compositions shows that scrubbing by interaction with air-saturated groundwater strongly influences observed compositional variability. From our CO₂ flux measurements, we estimate the deeply derived CO 2 emission rate from the SBMM hydrothermal area (0.2 km 2 ) at 240 t d −1 , comparable to many quiescently degassing volcanoes worldwide. We also provide a first-order estimate of CH 4 emissions at approximately 0.5 t d −1 . Our findings establish crucial baseline data for future volcanic monitoring efforts, enhancing detection capabilities for potential changes in this active hydrothermal system. This work contributes to the broader understanding of volatile contributions from volcanic and metamorphic sources to the global carbon budget, while highlighting the strong influence of bedrock geology on gas compositions in the CLVF.

California

Re-examining the growing degree day minimum for grass carp spawning initiation in Lake Erie: Have we missed the mark?

Understanding the timing of life history processes of invasive fish species, such as adult aggregations during spawning, allows natural resource managers to optimize targeted population control efforts. Temperature-based estimates of the timing of spawning initiation for grass carp ( Ctenopharyngodon idella ) exist from its native range, but have not previously been developed for grass carp reproduction in its invaded range in the Laurentian Great Lakes of North America. We accounted for differences among methods across studies and calculated cumulative growing degree days (GDD) for the dates of grass carp egg capture in Lake Erie tributaries (Sandusky, Maumee, and Huron rivers) during 2015–2024 and compared these values to the existing GDD base 15°C requirement estimate from the native range (633 GDD–15°C). The earliest egg detection in Lake Erie (Sandusky River) was 19 GDD–15°C or 361 GDD–5°C (latest egg detection was 2285 GDD–5°C from the Sandusky River), indicating that spawning was initiated up to 25 days earlier than would be predicted by the native range GDD. Moreover, spawning in Lake Erie tributaries occurred earlier than predicted for 58% of spawning events examined based on the native range GDD. The GDD values for spawning initiation in Lake Erie tributaries can be used to refine the timing of control efforts targeting pre-spawn and spawning adult fish, inform the timing of egg sampling, and provide linkages to existing early life stage models to infer the length of the growing season available for age-0 fish to reassess tributary suitability.

Lake Erie, Maumee, River, Sandusky river

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research

RioM-1: A new calcite reference material for U-Pb LA-ICP-MS geochronology

Determining absolute ages of carbonate diagenesis, faulting, fossil formation, speleothem growth, carbonate-hosted hydrocarbon deposits, vein mineralisation and hydrothermal alteration has become increasingly accessible through LA-ICP-MS U-Pb dating of calcite, complementing traditional isotope dilution methods still applicable to certain materials (e.g., speleothems via micro-drilling). However, well-calibrated reference materials for LA-ICP-MS calcite geochronology remain scarce. Here, we characterise the Rio Maior calcite, designated ‘RioM-1’, as a potential reference material for U-Pb dating by LA-ICP-MS. Fragments (0.1 to 1 cm 3 ) from a single scalenohedral crystal were analysed by ID-TIMS (U-Pb), LA-ICP-MS (U-Pb and 87 Sr/ 86 Sr), and SIMS (O isotopes). RioM-1 displays high U mass fraction and low, though variable, proportions of common Pb. Combined ID-TIMS analyses from two independent laboratories yielded a Tera-Wasserburg lower intercept date of 63.93 ± 0.11 Ma (2 s , MSWD = 1.3, n = 16). LA-ICP-MS U-Pb data from three independent laboratories are concordant with the TIMS age, producing a pooled date of 64.10 ± 0.12/1.2 Ma (2 s , MSWD = 7.7, n = 708) and an initial 207 Pb/ 206 Pb ratio of 0.85 ± 0.01. Other calcite reference materials, when normalised to RioM-1, yielded dates within uncertainty of their published values. SIMS measurements returned a mean 18 O/ 16 O of 0.002044450 ± 181 (1 s ) and δ 18 O SMOW of 19.57 ± 0.92‰ (1 s ), while LA-ICP-MS strontium isotope measurement yielded a mean 87 Sr/ 86 Sr of 0.708177 ± 9 (2 s ).

Geostandards and Geoanalytical Research

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado

Rapid seismic and infrasound assessment of large landslides: A case study from Denali National Park and Preserve (Alaska)

Large, rapid landslides are a global hazard that can occur in remote, mountainous areas. Eyewitness reports of landslides and satellite imagery can often be limited or delayed, particularly during inclement weather. However, landslide-generated seismic and infrasound (low-frequency atmospheric sound) waves can be remotely detected in near real-time. This information can significantly expedite characterization and possible landslide response activities. Here, we highlight these capabilities using a > 4 million m³ ice–rock avalanche in Denali National Park and Preserve (Alaska). This event was detected via a landslide-specific seismic location and volume estimation algorithm deployed in Alaska, and — notably — by standard earthquake monitoring systems. Following rapid detection of this event, we combined its seismic and infrasound dataset with optical, synthetic aperture radar, and oblique aerial imagery, multitemporal digital elevation models, and a numerical flow model to reconstruct its failure timeline and dynamics. We apply array processing to infrasound signals traveling > 250 km and find that two precursory events occurred minutes prior to the main failure. We use long-period seismic signals to infer the force exerted by the landslide on the Earth and constrain the rheological parameters of our numerical flow simulation with this result and deposit morphology. The main failure produced a steeply-dipping impulsive initial downward force and reached speeds exceeding 60 m/s. This impulsive force generated relatively strong seismic body waves, which contributed to the earthquake system detection. This large, remote Alaska landslide underscores the key value of seismic and infrasound analysis for rapid landslide assessment and motivates efforts to further operationalize these approaches.

Alaska