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Overview of future USGS Gulf of Mexico buoyant storage assessment project

The United States Geological Survey (USGS) is a member of a U.S. Department of Energy-funded partnership headed by the University of Texas Bureau of Economic Geology that is working to assess the feasibility of offshore geologic carbon dioxide (CO2) storage in the Gulf of Mexico. The role of the USGS is to assess the buoyant geologic CO2 storage resource of the western half of the offshore Gulf of Mexico (GoM). Buoyant CO2 storage is the CO2 held in place by a top and lateral seal (either a sealing formation or a sealing fault), that creates a column of CO2 in communication across pore space in a geologic reservoir. This assessment will be similar to the USGS assessment of onshore buoyant geologic CO2 storage [1] and will employ a modified version of existing USGS methodology [2] to assess the buoyant CO2 storage capacity in the GoM.

Gulf of Mexico↗

Geology and ground-water resources of North Dakota, with a discussion of the chemical character of the water

Water is the most valuable of the mineral resources. The study of ground waters is therefore clearly within the field of economic geology and constitutes an important part of the work of the geological surveys, both State and national, as defined by law. In the spring of 1911 the investigation of the ground waters of North Dakota was begun by the North Dakota Geological Survey, and the work was assigned to the author of this paper. During each of the three summers 1911, 1912, and 1913 several weeks were devoted by the author to the field work of a general survey. A report on the ground waters of the State was then prepared by him and was transmitted by the director of the North Dakota Geological Survey to the State printing commission for publication. However, owing to lack of available funds the report was not published. A portion of the summer of 1914 was given to a study of artesian conditions in the Souris River Basin. Since that time considerable work has been done in connection with detailed surveys made for a number of cities and villages in an effort to obtain the best available supply of water for public use. During the summer of 1920 arrangements were made by the United States Geological Survey with the North Dakota Geological Survey whereby the author completed the work as fully as possible by correspondence and brought the report up to date. In the spring of 1921 samples of water from 196 sources were collected by the author and J. H. Buchanan and were sent to the United States Geological Survey for analysis. Most of these samples were analyzed by H. B. Riffenburg, who has used the analyses for a description of the chemical character of ground waters in the State. In addition to the analyses of samples collected in connection with the preparation of this report, over 700 partial analyses from different sources were examined. These analyses are not given in this paper, because the location of many of the wells was not stated definitely, and most of the analyses were incomplete. They were useful, however, in confirming the conclusions based on the analyses that are printed, particularly for counties where only a few samples were collected for this report.

North Dakota↗

Carolina slate belt gold deposits in Virginia, North Carolina, South Carolina, and Georgia

The Southeastern United States, in particular, the Carolina slate belt of Virginia, North Carolina, South Carolina, and Georgia, has been an important region of mineral production (fig. 1). This region is thought to have major potential for containing large undiscovered deposits of gold and silver, as well as copper, lead, zinc, molybdenum, and tin. Gold production from the major mines (Haile, Brewer, Ridgeway, and Barite Hill) in South Carolina ranked sixth in the Nation in 1992. Despite the closing of all but one mine in 1997, the region continues to attract intense scrutiny by the mining industry. Current U.S. Geological Survey (USGS) efforts in the slate belt are led by a multidisciplinary team focused on an integrated, multistate, and multiyear project that has the potential to result in a fundamental reinterpretation of the economic geology of the region. The slate belt is considered a scientific frontier because of the rapid pace of data acquisition by the USGS, academia, and private sector geologists and because emerging concepts of its geologic evolution are controversial. Establishing the origin of the gold deposits is important, not only in guiding exploration, but for more accurate assessment of the potential for the occurrence of new deposits throughout the southern Appalachians. These efforts may result in further industry exploration that may lead to discovery of new economically viable mineral deposits, which would have a broad economic impact on the region. Another goal is to find ways to prevent human activities related to gold extraction from remobilizing toxic metals found in these deposits, which could have potential harmful effects on the environment.

Georgia, North Carolina, South Carolina, Virginia↗

Physiographic, stratigraphic, and structural development of the Quadrilatero Ferrifero, Minas Gerais, Brazil

The Quadrilatero Ferrifero is an area of some 7,000 square kilometers in central Minas Gerais, Brazil centered about lat. 20°15' S, long. 43°30' W. For 250 years the region has poured forth a variety of mineral riches, now totaling more than $2 billion, and future production will undoubtedly be even greater. The main products are iron ore, manganese ore, and gold. To assist this development, the Braziliam and American Governments in 1946 jointly undertook the first detailed geologic study of the region: this report is a synthesis of the results of work and mapping by 17 Brazilian and American geologists under this program; other reports discussing the economic geology, the metamorphic geology, and the igneous geology of the region as a whole are being prepared.

Minas Gerais↗

Principal coal beds in the Buckhorn quadrangle, Breathitt, Leslie, and Perry Counties, Kentucky

This report on coal in the Buckhorn quadrangle, Kentucky, is the second of a series of preliminary reports published by the U.S. Geological Survey as part of a program of investigation of the geology and coal resources of eastern Kentucky. The first report, Coal Investigations Map C5 (Johnston and Heck, 1950), described the Fire Clay and Whitesburg coals in the Hyden quadrangle. The Buckhorn quadrangle; the present report discusses the economic geology of the Fire Clay, Fire Clay Rider, Haddix, Hazard, and Hazard No. 7 coal beds.

Kentucky↗

Memoranda reports on the geologic spot examinations of mines and prospects in Iran, February 1954, through June, 1955

A series of twenty-nine geological spot examinations of mines and prospects in Iran were carried out by Dr. Russell Gibson, Geologist, U.S. Geological Survey between February 1954 and June 1955. These studies were under the joint auspices of the U.S. Operation Mission of the International Cooperation Administration and the Iranian Ministry of National Economy. Dr. Gibson acted as Advisor in economic geology to both the Mission and the Government of Iran during this period. All mine or prospect visits including those two properties owned by private operators were made at the request of the agencies of the Government of Iran.

Open-File Report↗

Understanding contaminants associated with mineral deposits

Interdisciplinary studies by the U.S. Geological Survey (USGS) have resulted in substantial progress in understanding the processes that control the release of metals and acidic water from inactive mines and mineralized areas, the transport of metals and acidic water to streams, and the fate and effect of metals and acidity on downstream ecosystems. The potential environmental effects associated with abandoned and inactive mines, resulting from the complex interaction of a variety of chemical and physical processes, is an area of study that is important to the USGS Mineral Resources Program. Understanding the processes contributing to the environmental effects of abandoned and inactive mines is also of interest to a wide range of stakeholders, including both those responsible for managing lands with historically mined areas and those responsible for anticipating environmental consequences of future mining operations. The recently completed (2007) USGS project entitled 'Process Studies of Contaminants Associated with Mineral Deposits' focused on abandoned and inactive mines and mineralized areas in the Rocky Mountains of Montana, Colorado, New Mexico, Utah, and Arizona, where there are thousands of abandoned mines. Results from these studies provide new information that advances our understanding of the physical and biogeochemical processes causing the mobilization, transport, reaction, and fate of potentially toxic elements (including aluminum, arsenic, cadmium, copper, iron, lead, and zinc) in mineralized near-surface systems and their effects on aquatic and riparian habitat. These interdisciplinary studies provide the basis for scientific decisionmaking and remedial action by local, State, and Federal agencies charged with minimizing the effects of potentially toxic elements on the environment. Current (2007) USGS research highlights the need to understand (1) the geologic sources of metals and acidity and the geochemical reactions that release them from their sources, (2) the pathways that facilitate transport from those sources, and (3) the processes that control the fate of the elements once released from the sources. Experts in the fields of economic geology, structural geology, mineralogy, geophysics, geochemistry, hydrology, ground-water modeling, microbiology, and toxicology came together for a series of studies that address these relationships on scales ranging from the microscopic to the watershed. This Circular presents results and highlights from the detailed, interdisciplinary studies that include investigations in both mining-affected areas and mineralized but unmined areas. The first section of the Circular describes laboratory and site-scale field investigations that primarily focus on mineralogic and biologic controls on the source and release of metals and acidity from mine-waste rock and hydrothermally altered areas. The second section describes a set of basin- to watershed-scale studies that not only investigate the source and release of metals and acidity but also the transport of these constituents away from the source areas. The third section is a summary of results from postremediation ecosystem monitoring. For more information on these and other project-related studies, please visit the project Web site at http://minerals.cr.usgs.gov/projects/contaminants/index.html. The Web site includes a complete bibliography and detailed descriptions of each interdisciplinary study.

Circular↗

Manganese nodules

The existence of manganese (Mn) nodules (Figure 1) has been known since the late 1800s when they were collected during the Challenger expedition of 1873–1876. However, it was not until after WWII that nodules were further studied in detail for their ability to adsorb metals from seawater. Many of the early studies did not distinguish Mn nodules from Mn crusts. Economic interest in Mn nodules began in the late 1950s and early 1960s when John Mero finished his Ph.D. thesis on this subject, which was published in the journal Economic Geology (Mero, 1962) and later as a book (Mero, 1965). By the mid-1970s, large consortia had formed to search for and mine Mn nodules that occur between the Clarion and Clipperton fracture zones (CCZ) in the NE Pacific (Figure 2). This is still the area considered of greatest economic potential in the global ocean because of high nickel (Ni), copper (Cu), and Mn contents and the dense distribution of nodules in the area. While the mining of nodules was fully expected to begin in the late 1970s or early 1980s, this never occurred due to a downturn in the price of metals on the global market. Since then, many research cruises have been undertaken to study the CCZ nodules, and now 15 contracts for exploration sites have been given or are pending by the International Seabed Authority (ISA). Many books and science journal articles have been published summarizing the early work (e.g., Baturin, 1988; Halbach et al., 1988), and research has continued to the present day (e.g., ISA, 1999; ISA, 2010). Although the initial attraction for nodules was their high Ni, Cu, and Mn contents, subsequent work has shown that nodules host large quantities of other critical metals needed for high-tech, green-tech, and energy applications (Hein et al., 2013; Hein and Koschinsky, 2014).

Book chapter↗

From exploration to production: Understanding the development dynamics of lithium mining projects

Recently, there has been considerable recent controversy whether current and new lithium mines will be able to supply the rapidly growing needs of the electromobility transition. Mineral exploration projects are typically active for many years, and only some become operational mines. From exploration to production, the projects go through several stages of characterisation and evaluation. At each stage, decisions are made by companies and stakeholders to advance, continue or stop the project. This is a complex process, and even projects with very similar geological and technical characteristics may take very different trajectories, depending on external factors such as global market conditions and local regulatory environments. The present study investigates the dynamics of this process for lithium exploration projects. A global database of 397 lithium projects was compiled, covering their progression through major development stages between 2004 and 2022. Ordinal logistic regression was used for the statistical analysis of this data. Different explanatory variables were tested, including economic, geological, technical, and geographic factors, to identify the best predictors for project progress at each development stage. The results suggest an essential role for lithium carbonate prices, and a variable role for other factors at each stage. Critically, the already elapsed lead time and project economics, which are traditionally considered important for the prediction of the start-up of individual mines, do not appear to be relevant in all cases. The results provide important insights into the dynamics of lithium supply and may eventually allow more realistic forecasts to be made for future lithium market dynamics.

Resources Policy↗

Map showing outcrops of ash-flow tuffs, Basin and Range Province and vicinity, Trans-Pecos Texas

This map report is one of a series of geologic and hydrologic maps covering all or parts of the States within the Basin and Range province of the western United States, resulting from work under the U.S. Geological Survey's program for geologic and hydrologic evaluation of the Basin and Range province to identify potentially suitable regions for future study relative to isolation of high-level nuclear waste (Bedinger, Sargent, and Reed, 1984) . The map report on the ash-flow tuffs of Trans-Pecos Texas was prepared from published maps and reports and from recent work in progress by geologists of the Texas Bureau of Economic Geology, and was compiled utilizing the project guidelines of Sargent and Bedinger (1984). The map shows the outcrops and localities of measured thicknesses of the ash-flow tuffs that resulted from silicic volcanism 38 to 28 million years ago (Henry and McDowell, 1982). Locally, however, some thin, inadequately studied tuffs of limited distribution have been excluded from the map. Such tuffs are reported in the "lower rhyolite" in the Eagle Mountains (Underwood, 1963), in the southern Davis Mountains (Parker, 1977), within parts of the Shely Group and Morita Ranch Formation in the Chinati Mountains (Cepeda and Henry, 1983) , and in the Rawls Formation in the Bofecillos Mountains (McKnight, 1969). The distribution of most ash-flow tuffs in the northern Davis and Wylie Mountains is not well known. The Chambers Tuff, largely tuffaceous sedimentary rocks, is reported to contain several ash-flow tuffs (Walton, 1972), but their distribution is poorly documented. Metamorphosed ash-flow tuffs of Precambrian age in the Thunderbird Group in the Franklin Mountains (Thomann, 1981) and in the Carrizo Mountain Group near Van Horn (Rudnick , 1983) were not included on the map. In some areas studied in reconnaissance, the definitive lithology of some volcanic units described as lava flows or tuffs has not been determined. In the Description of Map Units, the general location, caldera source and volume of tuff, isotopic age, if available, lithologic data, and the reference sources for each geologic unit are described. The nomenclature of the geologic units is from published reports and does not necessarily conform to U.S. Geological Survey usage.

Texas↗

Unscrambling the Proterozoic supercontinent record of northeastern Washington State, USA

The time interval from Supercontinent Nuna assembly in the late Paleoproterozoic to Supercontinent Rodinia breakup in the Neoproterozoic is considered by some geologists to comprise the “Boring Billion,” an interval possibly marked by a slowdown in plate tectonic processes. In northeastern Washington State, USA, similar to much of western Laurentia, early workers generally thought the tectonostratigraphic framework of this interval of geologic time consisted of two major sequences, the (ca. 1480–1380 Ma) Mesoproterozoic Belt Supergroup and unconformably overlying (<720 Ma) Neoproterozoic Windermere Supergroup. However, recent research indicates that strata considered by early workers as Belt Supergroup equivalents are actually younger, and a post-Belt, pre-Windermere record is present within the <1360 Ma Deer Trail Group and <760 Ma Buffalo Hump Formation. Thus, the northeastern Washington region perhaps comprises the most complete stratigraphic record of the “Boring Billion” time interval in the northwestern United States and holds important insights into global Proterozoic supercontinent tectonic processes. In light of these exciting developments, this field guide will address the early historic economic geology and original mapping of these Proterozoic sequences in the northeastern Washington region, and from that foundation explore more recent isotopic provenance data and their regional to global context. Finally, the guide will end with a discussion of remaining questions with a goal of stimulating interest in these relatively understudied, yet important, rocks.

Washington↗

Chemical analyses of lignite from the Wilcox Group, Texas region, central and eastern Texas

As part of a continuing program by the U.S. Geological Survey to collect and chemically analyze representative sales of U.S. coal, 45 samples of lignite and lignite-associated rocks were collected strip mines and drill holes in Freestone and Milam counties in central Texas, and in Harrison, Rains, Titus, Van Zandt, and Wood Counties in eastern Texas. The sampled areas are in the Texas region of the Gulf province (Trumbull, 1960). Figure 1 shows the counties from which the samples were collected. Brief descriptions of the 45 samples are given in table 1. Thirty-one samples (twenty-six lignite and five lignite-associated rock) were collected from four active strip mines in Freestone, Harrison, Milam, and Titus Counties by the Texas Bureau of Economic Geology; 14 samples (13 lignite and 1 carbonaceous shale) were collected from nine drill holes in connection with the U.S. Bureau of Mines evaluation of coal resources in the proposed Carl L. Estes Lake site, Rains, Van Zandt, and Wood Counties (Ward, 1977). All samples included in this report are from the Wilcox Group of Eocene age. The Wilcox Group is undifferentiated in Harrison, Rains, Titus, Van Zandt, and Wood Counties. Lignite in this area is in the upper two-thirds of the Wilcox. In Freestone and Milam Counties, the Wilcox Group is subdivided into the Hooper, Simsboro, and Calvert Bluff Formations. Lignite in this area is predominantly in the Calvert Bluff Formation, with minor amounts in the Hooper Formation. A generalized stratigraphic column of the Wilcox Group and associated Tertiary strata is given in figure 2. The Calvert Bluff Formation and undifferentiated Wilcox Group consist of clastic debris deposited in a fluvial environment, in which major channel complexes characterized by sand deposition divide interchannel areas composed of mud. Lignite was deposited as a blanket peat in freshwater swamps and marshes within interchannel areas. Individual lignite beds are lenticular bodies extending 3 to 20 km laterally; thicknesses are generally 1 to 3 m, rarely as much as 6 m. Descriptions of geology and lignite occurrences are in Fisher (1963), Kaiser (1974, 1978), and Kaiser and others (1978).

Texas↗

The petroleum fields of the Pacific coast of Alaska, with an account of the Bering River coal deposits

This report contains the result of a hasty examination of the structural and economic geology of the localities where indications of petroleum have been found. Though only a few wells have been drilled and it is too soon to predict an important future for the region as a petroleum producer, studies have shown that there is ample justification for further prospecting and that the region may yet be an important source of illuminating oil. In this connection it is of interest to note that the Bering River coal is the best that has yet been found on the Pacific coast of North America. These coal and petroleum fields have been deemed of sufficient importance to justify the further investigation already begun, and it is hoped that this, together with the commercial development, will soon permit of more definite statements regarding the economic importance of this field.

Alaska↗

Stratigraphy of parts of De Soto and Hardee Counties, Florida

The late Cenozoic stratigraphy of part of central Florida immediately south of the land-pebble phosphate district was studies in detail to determine the southern limit of the economically important Bone Valley formation and its relations with marine rocks of late Miocene and Pliocene age in south-central Florida. In addition a reconnaissance type appraisal of the phosphate and uranium resources of this area was desired. The upper Tertiary and Quaternary rocks were mapped, and the economic geology was studied in a general manner. The Hawthorn formation of middle Miocene age, is the oldest rock Exposed. Undifferentiated phosphatic sand and clay may be composed of the Bone Valley formation, of late Miocene to Pliocene age; a combination of Bone Valley formation and residuum of weathered Hawthorn formation; or Hawthorn residuum alone. The Bone Valley formation and residuum of Hawthorn formation appear almost identical in cuttings from auger drilling in this area. It was not feasible nor practical to map these two units separately. The undifferentiated phosphatic sand and clay interfingers with a marine sand of late Miocene age, The Caloosahatchee marl of Pliocene age, is present in the southeast corner of the area investigated. It is apparent that the undifferentiated phosphatic sand and clay was undergoing subaerial erosion and reworking during deposition or the Caloosahatchee marl. Stratified sand and clayey sand containing scattered thin lenses of fresh-water limestone and marl of Pleistocene age are either floodplain deposits or subaerial topset beds of a delta made by the Pleistocene Peace River. Sediments of Recent age are local stream deposits. Bars and shoals in the Peace River south of Brownville, De Soto County, contain appreciable tonnages of low grade "river-pebble" phosphate. The phosphate and uranium content of the undifferentiated phosphatic sand and clay in Hardee County is too low to be of economic significance.

Florida↗

Geology and ore deposits of the Pioche district, Nevada

LOCATION AND SURFACE FEATURES The Bristol Range, Highland, and Ely Range quadrangles make up the larger part of a. rectangular area 35 miles north and south by 24 miles east and west, which lies 19 miles west of the Nevada-Utah line and about 250 miles southwest of Salt Lake City. The district lies within the Great Basin, a semiarid region of alternating mountain ranges and intermontane plains floored largely by outwash from the mountains. The plain, which slopes away from the ranges, stands between 4,700 and 6,000 feet above the sea. The Bristol and Highland Ranges, which are separated only by a low gap, form an almost continuous north-south range that rises about 2,500 feet above the highest part of the surrounding plain, to general altitudes of 8,000 to 9,000 feet, though the highest point, Highland Peak, reaches 9,395 feet. A lower range, the Ely Range, with a northwesterly trend, lies farther east and nearly in touch with the Bristol-Highland Range. The town of Pioche lies midway on the. eastern foot of the Ely Range. ROOKS OF THE PIOOHB REGION The rocks of the ranges are Paleozoic sediments, Tertiary (?) lavas and intrusive rocks, and Pliocene (?) tuffs. The Paleozoic sediments have a total thickness of nearly 18,000 feet. Over 8,000 feet of the Cambrian has been measured without reaching its base. The lowest Cambrian formation is a quartzite, of which only the upper 1,500 feet is exposed, and this is followed by 1,200 feet of shale, 400 feet of limestone, aoid 150 feet of shale. Above this second shale the upper three-fourths of the Cambrian consists of limestone and dolomitic limestone. It is in the quartzite and in the limestone interbedded in and bounding the shales that the main ore bodies of the district have been found. Above the Cambrian comes 1,795 feet of Ordovician limestone, with some interbedded dolomite and with a 50-foot quartzite a, third of the way down from the top; 75 feet of Silurian dolomite; 3,000 feet of Middle Devonian dolomite with thin interbedded quartzite near the top, followed by 550 feet of Upper Devonian limestone; 3,775 feet of Mississippian limestone with a heavy quartzitic sandstone just below the middle; then, at the top of the series, 700 feet of Pennsylvania n limestone. The Paleozoic formations are tilted, bent, and faulted, but sharp folding is extremely rare. Dips between 10&deg; and 30&deg; are common, but there are few greater than 40&deg;. The rocks are cut by many large and innumerable small normal faults, which in many parts of the area are difficult to recognize because they cut thick formations of similar rocks. A large thrust fault occurs along the west side of the Bristol-Highland Range. A thick series of lavas with interbedded tuffs lies along the flanks of the ranges and makes up a large part of the hilly northwest corner of the Bristol quadrangle. The lavas lie unconformably on the Paleozoic sediments and consist mainly of dacite, latite, and andesite, with some basalt and a little rhyolite. About 6,000 feet of lavas and tuffs were measured in Condor Canyon, near the south end of the Ely Range. The age of the lavas is not sharply fixed; they may be early Tertiary or even late Mesozoic. It is not unlikely that they are the result of volcanic action extending over a long period. The lavas are tilted and faulted, though their average dip is less than that of the Paleozoic sediments. At Blind Mountain, on the west side of the Bristol Range, stocks of quartz monzonite and dikes of similar composition cut an infaulted block consisting of sediments, chiefly Devonian, and lavas. Both the sediments and the lavas are metamorphosed, and a belt of marked metamorphism extends south along the west base of the Bristol-Highland Range for several miles. The quartz porphyry dikes of the region, including those near Pioche, are believed to have come in at the same time. The plain west of the Bristol-Highland Range is a. valley of interior drainage floored with outwash from the mountains, coarser near the range but finer and making a clay flat along the west side of the Bristol Range and Highland quadrangles. The valley east of the Bristol-Highland Range, however, has outside drainage by way of Meadow Valley to the Virgin and Colorado Rivers. The stream in upper Meadow Valley and its tributaries have cut through the surface wash from the mountains and laid bare several hundred feet of white, yellow, and red water-laid Pliocene tuffs that lie in nearly the position in which they were laid down. This erosion has developed a striking badland topography in the Pliocene beds. HISTORICAL SUMMARY The general succession of events may be summarized as follows: 1. Sedimentation during most of Paleozoic time from Cambrian to Pennsylvanian. 2. Uplift, slight warping, and erosion. 3. Volcanism of perhaps late Mesozoic or early Tertiary time, producing lavas and tuffs. This period of volcanism may have lasted a long time and spanned one or more of the epochs of faulting. 4. Tilting and normal faulting. 5. Thrust faulting. 6. Quartz monzonite intrusions at Blind Mountain. 7. Normal block faulting of the Basin Range type. 8. Erosion of the faulted blocks to maturity and to essen-. tially the topography of to-day. 9. Outbursts of volcanic ash, probably in late Pliocene time, and the deposition of several hundred feet of water-laid tuffs in the valleys. 10. In Meadow Valley, valley cutting, which has produced a badland topography in the soft Pliocene tuffs and canyons where the streams cross the harder Paleozoic limestones. ECONOMIC GEOLOGY The Pioche district during four years in the early seventies was second only to the Comstock district in output of silver. The bonanza ore of those stirring times came from fissure veins in the Prospect Mountain quartzite, of Lower Cambrian age. In recent years the main interest has shifted to the bedded replacement deposits of silver-bearing lead-zinc sulphide ore occurring in the limestone members of the Pioche shale a type of ore body which was discovered accidentally during the prospecting of the fissure veins. The ore deposits of the district comprise three groups (1) silver-bearing fissure veins in quartzite; (2) silver-bearing mineralized granite porphyry; (3) replacement deposits in limestone and dolomite. All of them appear to have been formed at about the same time, in the epoch of mineralization that occurred shortly after the intrusion of the granitic rocks and their allied dikes of granite porphyry and lamprophyre. The entire present output of the district is coming from the replacement deposits in limestone and dolomite, but exploratory work is still in progress on the fissure veins and mineralized porphyry. The replacement deposits include both replacement fissure veins and stratiform ("bedded") replacement deposits. The replacement fissure veins dip steeply and cut across the bedding of the carbonate rocks in which they are inclosed. They are thoroughly oxidized, as deep at least as 1,100 feet, for on none of them have the mine workings penetrated to water level, and they are highly manganiferous and limonitic and low in silica. At-certain horizons stratiform replacement deposits extend out as lateral branches from the fissure veins. Deposits of this kind occur mainly in the Mendha limestone, Highland Peak limestone, and Lyndon limestone. The stratigraphic range is therefore at least 5,500 feet, and as some of the fissure veins extend down through the underlying Pioche shale the indicated range may exceed 6,500 feet. The most notable representatives of the replacement fissure veins are at the Bristol mine, where they yield silver-bearing copper-leadzinc ores. So far unique among the ore bodies of the district is the pipe of wad and pyrolusite ore at the Jackrabbit mine, the periphery of the pipe consisting of a girdle of extraordinarily coarse white calcite spar produced by the recrystallization of the surrounding limestones. The stratiform replacement deposits that are attracting most attention occur at the intersections of steep fissures with the limestone members of the Pioche shale. In recent years the " bedded " ore of the Combined Metals mine has been of main interest. The ore is essentially a.n intimate intergrowth of pyrite, sphalerite, and galena. Although above water level, the ore is unoxidized. It extends on both sides of the mineralizing fissure as far as 100 feet. At the Prince mine ore beds were formed at seven successively higher horizons in the Pioche shale and the overlying Lyndon and Highland Peak limestones. The ore " beds " above water level in the Prince mine are thoroughly oxidized and consist of manganese-iron oxides low in silver, lead, and zinc. About 800,000 tons of ore carrying 2.5 to 3 ounces of silver to the ton, 3 per cent of lead, 35 per cent of iron, and 15 per cent of manganese has been shipped. The Prince mine was in 1915-1918 the premier producer of lead in Nevada. The ore " bed " that occurs here below water level consists of sphalerite, galena, and pyrite in a gangue of manganosiderite and minor quartz. This is the only locality in the district in which the primary source of the abundant oxidized manganese minerals (wad, pyrolusite, and braunite) has so far been found. Some of the stratiform ore bodies the ore beds, as they are locally called were formed adjacent to exceedingly insignificant-looking fissures; and this dependence on inconspicuous mineralizing fissures is beyond doubt one of the most impressive features in the geology of the district. It opens the possibility that there may be many other bedded deposits which, like the Combined Metals ore bed, do not crop out. To find these ore bodies will be difficult, but their discovery will be aided primarily by applying skillfully a knowledge of the geologic column and by determining the faulting that has disturbed or changed the normal sequence of the strata.

Nevada↗

Measurement of in situ sulfur isotopes by laser ablation multi-collector ICPMS: opening Pandora’s Box

Laser ablation multi-collector ICPMS is a modern tool for in situ measurement of S isotopes. Advantages of the technique are speed of analysis and relatively minor matrix effects combined with spatial resolution sufficient for many applications. The main disadvantage is a more destructive sampling mechanism relative to the ion microprobe technique. Recent advances in instrumentation allow precise measurement with spatial resolutions down to 25 microns. We describe specific examples from economic geology where increased spatial resolution has greatly expanded insights into the sources and evolution of fluids that cause mineralization and illuminated genetic relations between individual deposits in single mineral districts.

Procedia Earth and Planetary Science↗

Appendix C—A selected list of papers relating to ground‐water hydrology

In the following list brief statements have been added to certain references to call attention to special phases of ground ‐ water problems which are not apparent from the titles. Abstracts of most of these papers have been or will be published in the Annotated Bibliography of Economic Geology.

Eos, Transactions, American Geophysical Union↗

Appendix A—A selected list of papers relating to ground‐water hydrology

In the following list, brief‐statements have been added to certain references to call attention to special phases of ground‐water problems which are not apparent from the titles. Abstracts of most of the papers have been or will be published in the Annotated Bibliography of Economic Geology.

Eos, Transactions, American Geophysical Union↗