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Erosion rates at the Mars Exploration Rover landing sites and long-term climate change on Mars

Erosion rates derived from the Gusev cratered plains and the erosion of weak sulfates by saltating sand at Meridiani Planum are so slow that they argue that the present dry and desiccating environment has persisted since the Early Hesperian. In contrast, sedimentary rocks at Meridiani formed in the presence of groundwater and occasional surface water, and many Columbia Hills rocks at Gusev underwent aqueous alteration during the Late Noachian, approximately coeval with a wide variety of geomorphic indicators that indicate a wetter and likely warmer environment. Two-toned rocks, elevated ventifacts, and perched and undercut rocks indicate localized deflation of the Gusev plains and deposition of an equivalent amount of sediment into craters to form hollows, suggesting average erosion rates of ???0.03 nm/yr. Erosion of Hesperian craters, modification of Late Amazonian craters, and the concentration of hematite concretions in the soils of Meridiani yield slightly higher average erosion rates of 1-10 nm/yr in the Amazonian. These erosion rates are 2-5 orders of magnitude lower than the slowest continental denudation rates on Earth, indicating that liquid water was not an active erosional agent. Erosion rates for Meridiani just before deposition of the sulfate-rich sediments and other eroded Noachian areas are comparable with slow denudation rates on Earth that are dominated by liquid water. Available data suggest the climate change at the landing sites from wet and likely warm to dry and desiccating occurred sometime between the Late Noachian and the beginning of the Late Hesperian (3.7-3.5 Ga). Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research E: Planets

Clostridium perfringens in Long Island Sound sediments: An urban sedimentary record

Clostridium perfringens is a conservative tracer and an indicator of sewage-derived pollution in the marine environment. The distribution of Clostridium perfringens spores was measured in sediments from Long Island Sound, USA, as part of a regional study designed to: (1) map the distribution of contaminated sediments; (2) determine transport and dispersal paths; (3) identify the locations of sediment and contaminant focusing; and (4) constrain predictive models. In 1996, sediment cores were collected at 58 stations, and surface sediments were collected at 219 locations throughout the Sound. Elevated concentrations of Clostridium perfringens in the sediments indicate that sewage pollution is present throughout Long Island Sound and has persisted for more than a century. Concentrations range from undetectable amounts to 15,000 spores/g dry sediment and are above background levels in the upper 30 cm at nearly all core locations. Sediment focusing strongly impacts the accumulation of Clostridium perfringens spores. Inventories in the cores range from 28 to 70,000 spores/cm2, and elevated concentrations can extend to depths of 50 cm. The steep gradients in Clostridium perfringens profiles in muddier cores contrast with concentrations that are generally constant with depth in sandier cores. Clostridium perfringens concentrations rarely decrease in the uppermost sediment, unlike those reported for metal contaminants. Concentrations in surface sediments are highest in the western end of the Sound, very low in the eastern region, and intermediate in the central part. This pattern reflects winnowing and focusing of Clostridium perfringens spores and fine-grained sediment by the hydrodynamic regime; however, the proximity of sewage sources to the westernmost Sound locally enhances the Clostridium perfringens signals.

Connecticut, Massachusetts, New Hampshire, New Jer

Gas exchange rates across the sediment-water and air-water interfaces in south San Francisco Bay

Radon 222 concentrations in the water and sedimentary columns and radon exchange rates across the sediment-water and air-water interfaces have been measured in a section of south San Francisco Bay. Two independent methods have been used to determine sediment-water exchange rates, and the annual averages of these methods agree within the uncertainty of the determinations, about 20%. The annual average of benthic fluxes from shoal areas is nearly a factor of 2 greater than fluxes from the channel areas. Fluxes from the shoal and channel areas exceed those expected from simple molecular diffusion by factors of 4 and 2, respectively, apparently due to macrofaunal irrigation. Values of the gas transfer coefficient for radon exchange across the air-water interface were determined by constructing a radon mass balance for the water column and by direct measurement using floating chambers. The chamber method appears to yield results which are too high. Transfer coefficients computed using the mass balance method range from 0.4 m/day to 1.8 m/day, with a 6-year average of 1.0 m/day. Gas exchange is linearly dependent upon wind speed over a wind speed range of 3.2–6.4 m/s, but shows no dependence upon current velocity. Gas transfer coefficients predicted from an empirical relationship between gas exchange rates and wind speed observed in lakes and the oceans are within 30% of the coefficients determined from the radon mass balance and are considerably more accurate than coefficients predicted from theoretical gas exchange models.

California

Possible effects of multiphase methane evolution during a glacial cycle on underpressure development in sedimentary basins: An analysis with application to the northeast Michigan Basin

In low-permeability systems, groundwater may be accompanied by separate-phase fluids, and measured pore water pressures may deviate from those expected in steady-state, single-phase systems. These same systems may be of interest for storage of nuclear waste in Deep Geologic Repositories. Therefore, it is important to understand the relationship between the presence of a separate phase and anomalous pressure development. At the Bruce site in Southern Ontario, a significant underpressure was observed, and there is evidence for the presence of gas-phase methane in situ. This study used a one-dimensional (vertical) numerical model of the subsurface down to a depth of 844 m beneath the Bruce site to evaluate possible effects of hydromechanical coupling with multiphase flow on pressure evolution during glacial loading and unloading. The simulated pressure conditions were affected strongly by the amount of methane initially present in the system, and the maximum simulated underpressure varied nonmonotonically with increasing initial methane content. When the initial methane content was below the solubility limit, exsolution led to underpressures that briefly exceeded those that formed in the single-phase case. At intermediate initial methane contents (sufficient to produce an immobile gas phase), the gas phase dampened the hydromechanical effects of the glacial cycle. At large initial methane contents (when a mobile gas phase was present), gas migration caused a large decrease in relative liquid permeability, which further contributed to underpressure development in the pore water. Multiple scenarios that spanned a range of initial methane contents yielded underpressures like those observed at the Bruce site.

Journal of Geophysical Research - Solid Earth

Sedimentary depositional environments of uranium and petroleum host rocks of the Jackson Group, south Texas

Determination of depositional environments in rocks of the Jackson Group of late Eocene age aids in the exploration for uranium and petroleum in south Texas. During deposition of the Jackson Group, conditions were similar to those existing along the modern Gulf Coast of Texas except for a less arid climate and a greater supply of volcanic sediment. Sedimentary depositional environments recognized in both the modern coast and the Jackson rocks, in order from sea toward land, are: shoreface, beach, lagoon and bay, and paludal. Sediment deposited in these environments in places is interbedded with or transected by fluvial sediment. Both uranium and petroleum are found in the shoreface, beach, and fluvial facies. These facies are characterized by permeable well-sorted sandstone, which is commonly overlain and underlain by less permeable mudstone. A typical vertical sequence in ascending order through a unit containing a beach sandstone facies is (1) lagoonal or paludal clay stone and siltstone, (2) crossbedded fine-grained beach sandstone which contains Ophiomorpha burrows and, which, in places, is locally interbedded with lacustrine or lagoonal mudstone, (3) weakly laminated beach sandstone which contains root impressions at the top and Ophiomorpha , and (4) lagoonal or paludal claystone and siltstone. Gulfward, the beach sandstone apparently grades into highly burrowed, generally finer grained, more poorly sorted, less porous shoreface rocks. The beach facies may include barrier island beaches and mainland beaches, some of which were probably cheniers. Beach facies sandstone units extend many miles along the depositional strike, which nearly parallels the present outcrop strike, but extend only a mile or two (2-3 km) normal to the depositional strike into the subsurface. Recognition of the various facies in outcrops and drill holes is necessary for determination of true stratigraphic relations and for aid in exploration for beach and fluvial sandstone favorable for uranium and petroleum accumulations.

Texas

Role of future reef growth on morphological response of coral reef islands to sea-level rise

Coral reefs are widely recognised for providing a natural breakwater effect that modulates erosion and flooding hazards on low‐lying sedimentary reef islands. Increased water depth across reef platforms due sea‐level rise (SLR) can compromise this breakwater effect and enhance island exposure to these hazards, but reef accretion in response to SLR may positively contribute to island resilience. Morphodynamic studies suggest that reef islands can adjust to SLR by maintaining freeboard (island crest elevation above still water level) through overwash deposition and island accretion, but the impact of different future reef accretion trajectories on the morphological response of islands remain unknown. Here we show, using a process‐based morphodynamic model, that, although reef growth significantly affects wave transformation processes and island morphology, it does not lead to decreased coastal flooding and island inundation. According to the model, reef islands evolve during SLR by attuning their elevation to the maximum wave runup and islands fronted by a growing reef platform attain lower elevations than those without reef growth, but have similar overwash regimes. The mean overwash discharge Q over across the island crest plays a key role in the ability of islands to keep up with SLR and maintain freeboard, with a Q over value of O (10 l m ‐1 s ‐1 ) separating island construction from destruction. Islands, therefore, can grow vertically to keep up with SLR via flooding and overwash if specific forcing and sediment supply conditions are met, offering hope for uninhabited and sparely populated islands. However, this physical island response will negatively impact infrastructure and assets on developed islands.

Journal of Geophysical Research--Earth Surface

Differentiating pedogenesis from diagenesis in early terrestrial paleoweathering surfaces formed on granitic composition parent materials

Unconformable surfaces separating Precambrian crystalline basement and overlying Proterozoic to Cambrian sedimentary rocks provide an exceptional opportunity to examine the role of primitive soil ecosystems in weathering and resultant formation of saprolite (weathered rock retaining rock structure) and regolith (weathered rock without rock structure), but many appear to have been affected by burial diagenesis and hydrothermal fluid flow, leading some researchers to discount their suitability for such studies. We examine one modern weathering profile (Cecil series), four Cambrian paleoweathering profiles from the North American craton (Squaw Creek, Franklin Mountains, Core SQ-8, and Core 4), one Neoproterozoic profile (Sheigra), and one late Paleoproterozoic profile (Baraboo), to test the hypothesis that these paleoweathering profiles do provide evidence of primitive terrestrial weathering despite their diagenetic and hydrothermal overprinting, especially additions of potassium. We employ an integrated approach using (1) detailed thin-section investigations to identify characteristic pedogenic features associated with saprolitization and formation of well-drained regoliths, (2) electron microprobe analysis to identify specific weathered and new mineral phases, and (3) geochemical mass balance techniques to characterize volume changes during weathering and elemental gains and losses of major and minor elements relative to the inferred parent materials. There is strong pedogenic evidence of paleoweathering, such as clay illuviation, sepic-plasmic fabrics, redoximorphic features, and dissolution and alteration of feldspars and mafic minerals to kaolinite, gibbsite, and Fe oxides, as well as geochemical evidence, such as whole-rock losses of Na, Ca, Mg, Si, Sr, Fe, and Mn greater than in modern profiles. Evidence of diagenesis includes net additions of K, Ba, and Rb determined through geochemical mass balance, K-feldspar overgrowths in overlying sandstone sections, and K-feldspars with reaction rims in weathered basement. The sub-Cambrian paleoweathering profiles formed on granite are remarkably similar to modern weathering profiles formed on granite, in spite of overprinting by potassium diagenesis. ?? 2007 by The University of Chicago. All rights reserved.

Journal of Geology

Chemistry and texture of the rocks at Rocknest, Gale Crater: Evidence for sedimentary origin and diagenetic alteration

A suite of eight rocks analyzed by the Curiosity Rover while it was stopped at the Rocknest sand ripple shows the greatest chemical divergence of any potentially sedimentary rocks analyzed in the early part of the mission. Relative to average Martian soil and to the stratigraphically lower units encountered as part of the Yellowknife Bay formation, these rocks are significantly depleted in MgO, with a mean of 1.3 wt %, and high in Fe, averaging over 20 wt % FeOT, with values between 15 and 26 wt % FeOT. The variable iron and low magnesium and rock texture make it unlikely that these are igneous rocks. Rock surface textures range from rough to smooth, can be pitted or grooved, and show various degrees of wind erosion. Some rocks display poorly defined layering while others seem to show possible fractures. Narrow vertical voids are present in Rocknest 3, one of the rocks showing the strongest layering. Rocks in the vicinity of Rocknest may have undergone some diagenesis similar to other rocks in the Yellowknife Bay Formation as indicated by the presence of soluble calcium phases. The most reasonable scenario is that fine-grained sediments, potentially a mixture of feldspar-rich rocks from Bradbury Rise and normal Martian soil, were lithified together by an iron-rich cement.

Journal of Geophysical Research E: Planets

The influence of drying on the aeolian transport of river-sourced sand

Transgression and regression of water levels (stages) have impacted the evolution of aeolian landforms and sedimentary deposits throughout geologic history. We studied this phenomenon over a five-day period of reduced flow on the Colorado River in Grand Canyon National Park, AZ, USA, in March 2021. These transient low flows exposed river-channel sand deposits to the air, causing progressive desiccation (drying) and thereby making these deposits susceptible to aeolian transport. We measured aeolian threshold friction velocities ( u *t ) for sand saltation and PM10 dust emissions, as well as other characteristics, on a subaerially exposed sandbar and downwind aeolian dunefield during each day of the low river flow. The sandbar transitioned from supply-limited to transport-limited aeolian sediment transport conditions during the regression in river water stage. A possible tipping point between the two transport conditions occurred approximately 48 hours after the drop in river flow. The empirically measured u *t decreased as the sandbar sediment dried with increased subaerial exposure time. Theoretical estimates and empirical measurements of u *t corresponded closely on the aeolian dunefield and on the sandbar when it was drier during the third and fourth day of the experiment. Eighty-seven percent of the variability in u *t was explained by empirical models that provide practical estimates of aeolian transport potential of subaerial river sediment deposits using monitoring data that are commonly available in this and other river systems. The work provides theoretical insight into the response of aeolian processes to sediment supply changes driven by periods of anthropogenic activity, drought, and climate change.

Arizona

A rock record of complex aeolian bedforms in a Hesperian desert landscape: The Stimson formation as exposed in the Murray Buttes, Gale Crater, Mars

Lithified aeolian strata encode information about ancient planetary surface processes and the climate during deposition. Decoding these strata provides insight regarding past sediment transport processes, bedform kinematics, depositional landscape, and the prevailing climate. Deciphering these signatures requires a detailed analysis of sedimentary architecture to reconstruct dune morphology, motion, and the conditions that enabled their formation. Here, we show that a distinct sandstone unit exposed in the foothills of Mount Sharp, Gale crater, Mars, records the preserved expression of compound aeolian bedforms that accumulated in a large dune field. Analysis of Mastcam images of the Stimson formation shows that it consists of cross‐stratified sandstone beds separated by a hierarchy of erosive bounding surfaces formed during dune migration. The presence of two orders of surfaces with distinct geometrical relations reveals that the Stimson‐era landscape consisted of large dunes (draas) with smaller, superimposed dunes migrating across their lee slopes. Analysis of cross‐lamination and subset bounding surface geometries indicate a complex wind regime that transported sediment toward the north, constructing oblique dunes. This dune field was a direct product of the regional climate and the surface processes active in Gale crater during the fraction of the Hesperian Period recorded by the Stimson formation. The environment was arid, supporting a large aeolian dune field; this setting contrasts with earlier humid depositional episodes, recorded by the lacustrine sediments of the Murray formation (also Hesperian). Such fine‐scale reconstruction of landscapes on the ancient surface of Mars is important to understanding the planet’s past climate and habitability.

Journal of Geophysical Research - Planets

Thermophysical and compositional properties of paleobedforms on Mars

Bedforms on Earth and Mars are often preserved in the rock record in the form of sedimentary rock with distinct cross-bedding. On rare occasions, the full-surface geometry of a bedform can be preserved through burial and lithification. These features, known as paleobedforms, are found in a variety of geographic locations on Mars. Evidence in the morphology of paleobedforms, such as the retention of impact craters and steep erosional scarps, suggests that these features are well-lithified and capable of withstanding prolonged weathering and erosion. Here, we present results from thermophysical and compositional analyses on a subset of the best preserved paleobedform candidate fields on Mars. Thermophysical modeling elucidates the changes these bedforms underwent from their unconsolidated, particulate nature to their currently observed properties. Certain paleobedforms have elevated thermal inertias (e.g., ∼300–500 J·m −2 ·s −1/2 ·K −1 ) when compared with modern bedforms (∼250 J·m −2 ·s −1/2 ·K −1 ), and modeling indicates that they have cement volumes of 0.8%–1.5% even as high as 30%. However, most paleobedform candidates have unexpectedly low thermal inertia when compared with modern dunes. Additionally, compositional analyses reveal a range of spectral characteristics within paleobedforms (e.g., primary and secondary alteration products). These features add to the already existing class of Martian surfaces in which thermal inertia does not seem to correspond to erodibility, cohesion, or mechanical strength. Studying paleobedforms with both raised and nonraised thermal inertia has provided new insights into lithification on Mars and constrained the environmental conditions leading to the formation of these enigmatic features.

Journal of Geophysical Research - Planets

Intrusion of horizontal dikes: tectonic significance of Middle Proterozoic diabase sheets widespread in the upper crust of the southwestern United States

Initially horizontal sheet intrusions of Middle Proterozoic diabase are abundant in a region 650 by 300 km across in Arizona and California. The diabase forms discordant sheets in basement granite and gneiss and sills in overlying shelf sedimentary sequences. Massive granite is the most common basement host for the sheets, probably because it fractured more easily than foliated hosts during sheet emplacement. Steep feeder dikes are rare compared to the sheets. The diabase in many places is exposed in fault blocks that were tilted during Tertiary tectonic extension. Structure sections restored from the map patterns of upended blocks show that the sheets were intruded at levels throughout the upper crust, to depths of at least 13 km. Sheet intrusion implies a vertical orientation of the least compressive stress, so I conclude that the crust was under tectonic compression or in an isotropic state of stress at the time of diabase intrusion about 1.1 Ga. Magma overpressures, water encountered by rising magma, vertical changes in the crustal stress regime, and flotation of low-density granite all may be important factors for sheet intrusion. The stress conditions suggested by the presence of the sheets argue against an extensional tectonic regime earlier proposed for the diabase event. The diabase province contrasts structurally with similar-age provinces of basaltic magmatism elsewhere in North America that show evidence of tectonic extension, such as the midcontinent rift. The consistent orientations of the sheets commonly allow them to be used as structural markers for postdiabase deformation of basement blocks. Sheet intrusions in the geologic record may be seriously underreported. Their recognition is important for the interpretation of seismic reflection profiles of continental crust. Sheets in Arizona may be responsible for the Bagdad reflection sequence, which extends to depths of at least 15 km.

Journal of Geophysical Research

100 Myr record of sequences, sedimentary facies and sea level change from Ocean Drilling Program onshore coreholes, US Mid-Atlantic coastal plain

We analyzed the latest Early Cretaceous to Miocene sections (???110-7Ma) in 11 New Jersey and Delaware onshore coreholes (Ocean Drilling Program Legs 150X and 174AX). Fifteen to seventeen Late Cretaceous and 39-40 Cenozoic sequence boundaries were identified on the basis of physical and temporal breaks. Within-sequence changes follow predictable patterns with thin transgressive and thick regressive highstand systems tracts. The few lowstands encountered provide critical constraints on the range of sea-level fall. We estimated paleowater depths by integrating lithofacies and biofacies analyses and determined ages using integrated biostratigraphy and strontium isotopic stratigraphy. These datasets were backstripped to provide a sea-level estimate for the past ???100 Myr. Large river systems affected New Jersey during the Cretaceous and latest Oligocene-Miocene. Facies evolved through eight depositional phases controlled by changes in accommodation, long-term sea level, and sediment supply: (1) the Barremian-earliest Cenomanian consisted of anastomosing riverine environments associated with warm climates, high sediment supply, and high accommodation; (2) the Cenomanian-early Turonian was dominated by marine sediments with minor deltaic influence associated with long-term (107 year) sea-level rise; (3) the late Turonian through Coniacian was dominated by alluvial and delta plain systems associated with long-term sea-level fall; (4) the Santonian-Campanian consisted of marine deposition under the influence of a wave-dominated delta associated with a long-term sea-level rise and increased sediment supply; (5) Maastrichtian-Eocene deposition consisted primarily of starved siliciclastic, carbonate ramp shelf environments associated with very high long-term sea level and low sediment supply; (6) the late Eocene-Oligocene was a starved siliciclastic shelf associated with moderately high sea-level and low sediment supply; (7) late early-middle Miocene consisted of a prograding shelf under a strong wave-dominated deltaic influence associated with major increase in sediment supply and accommodation due to local sediment loading; and (8) over the past 10 Myr, low accommodation and eroded coastal systems were associated with low long-term sea level and low rates of sediment supply due to bypassing. ?? 2008 The Authors. Journal compilation ?? 2008 Blackwell Publishing.

Basin Research

Geochemistry of Florida Bay sediments: Nutrient history at five sites in eastern and central Florida Bay

Recent seagrass dieoff and massive microalgal blooms have focused attention on the health of the Florida Bay ecosystem. Changes in nutrient input and the nutrient dynamics of Florida Bay are hypothesized to be linked to these problems, but crucial baseline information is still lacking. Efforts to restore Florida Bay to its natural condition will require information on the nutrient history of the bay. The purpose of this study was to examine distributions of organic C, total N, and total P in carbonate sediments from sites of continuous and known sedimentation rate (210Pb and 137Cs dated), in eastern and central Florida Bay. These sediments provide a record of historical changes in the C, N, and P load to the eastern and central bay. Analyses were conducted on sediments from cores collected at five sites, and on buried seagrass fragments at two sites. At three of the sites, sediments from seagrass-covered and adjacent barren areas were examined to determine differences in sedimentary geochemistry. Stable isotope analyses (??13C and ??15N) of sedimentary organic C and total N and of buried seagrass fragments were also carried out at two sites to examine possible changes in nutrient sources to the estuary. Results were consistent with recent increases in N and P in eastern Florida Bay, beginning in the early to mid 1980's. The timing of the increase in nutrient load observed in the sediment data directly preceded the first observations of massive microalgal blooms and seagrass dieoff in Florida Bay in 1987. The observed nutrification was greater for P than N, and was most pronounced at the most northeasterly site sampled (Pass Key). Isotope data (??15N) suggested that an increase in algal production accompanied the increase in N load at the Pass Key site. Along record of organic C, total N, and total P distributions from Whipray Basin in central Florida Bay showed historical peaks (mid 1700's and late 1800's) in organic C and total N, but not total P; these enrichments were nearly equivalent to recent inputs to the estuary. Barren areas were observed to have generally lower concentrations of organic C, total N, and total P in near surface sediments compared to seagrass-covered areas, but had generally similar concentrations in deeper sediments. This suggested that barren areas adjacent to seagrass-covered sites were places where relict sediment was physically transported and covered seagrass beds. This dataset provides an historical view of changes in nutrient inputs to Florida Bay, and baseline information needed for nutrient modeling of the bay.

Journal of Coastal Research

Scanning electron microscopic evaluation of broad ion beam milling effects to sedimentary organic matter: Sputter-induced artifacts or naturally occurring porosity?

Research examining organic-matter hosted porosity has significantly increased during the last decade due to greater focus on understanding hydrocarbon migration and storage in source-rock reservoirs, and technological advances in scanning electron microscopy (SEM) capabilities. The examination of nanometer-scale organic-matter hosted porosity by SEM requires the preparation of exceptionally flat geologic samples beyond the abilities of traditional mechanical polishing, which can deform or otherwise obscure organic surfaces. To meet this demand, broad ion beam (BIB) milling was introduced as a sample preparation technique for SEM petrographic analysis of geologic samples. As with any sample preparation technique, there can be unintended consequences. In this study, we examined the development of nanometer-scale sputter-induced voids caused by BIB milling of thermoset plastic binder material [poly(methyl methacrylate), PMMA] used for the mounting of geologic samples, and artifact sputter-induced voids in the organic matter of Green River Formation and Kimmeridge Clay Formation source rocks. Development of artifact sputter-induced voids was evaluated in relation to variations in the slope of the sample examination surface (0.0–4.9% slope), effectively varying the angle of ion incidence. The results indicate that only minor variations in the angle of ion incidence can generate sputter-induced voids in both PMMA (10.0–386.2 nm diameter sputter-induced voids) and sample sedimentary organic matter (solid bitumen; 12.2–103.6 nm diameter sputter-induced voids). Overall, average artifact pore diameters increased with increasing ion incidence angle within PMMA. Although sputter-induced voids within solid bitumen in the Green River Formation sample were only found in limited extent, the size of these void artifacts falls within the same size range as naturally occurring meso-macroporosity. That is, the pore-like artifacts could easily be misconstrued as naturally developed organic porosity, which is a major concern for SEM-based porosity evaluation methods. This study describes the factors that contribute to the creation of artifact sputter-induced voids, their distinguishing characteristics, and best practices for avoiding the creation of ion-induced artifacts.

International Journal of Coal Geology

Mercury in Long Island Sound sediments

Mercury (Hg) concentrations were measured in 394 surface and core samples from Long Island Sound (LIS). The surface sediment Hg concentration data show a wide spread, ranging from <50 ppb Hg in eastern LIS to >600 ppb Hg in westernmost LIS. Part of the observed range is related to variations in the bottom sedimentary environments, with higher Hg concentrations in the muddy depositional areas of central and western LIS. A strong residual trend of higher Hg values to the west remains when the data are normalized to grain size. Relationships between a tracer for sewage effluents (C. perfringens) and Hg concentrations indicate that between 0-50 % of the Hg is derived from sewage sources for most samples from the western and central basins. A higher percentage of sewage-derived Hg is found in samples from the westernmost section of LIS and in some local spots near urban centers. The remainder of the Hg is carried into the Sound with contaminated sediments from the watersheds and a small fraction enters the Sound as in situ atmospheric deposition. The Hg-depth profiles of several cores have well-defined contamination profiles that extend to pre-industrial background values. These data indicate that the Hg levels in the Sound have increased by a factor of 5-6 over the last few centuries, but Hg levels in LIS sediments have declined in modern times by up to 30 %. The concentrations of C. perfringens increased exponentially in the top core sections which had declining Hg concentrations, suggesting a recent decline in Hg fluxes that are unrelated to sewage effluents. The observed spatial and historical trends show Hg fluxes to LIS from sewage effluents, contaminated sediment input from the Connecticut River, point source inputs of strongly contaminated sediment from the Housatonic River, variations in the abundance of Hg carrier phases such as TOC and Fe, and focusing of sediment-bound Hg in association with westward sediment transport within the Sound.

Connecticut;New York

A lacustrine paleoenvironment recorded at Vera Rubin ridge, Gale crater: Overview of the sedimentology and stratigraphy observed by the Mars Science Laboratory Curiosity rover

For ~500 Martian solar days (sols), the Mars Science Laboratory team explored Vera Rubin ridge (VRR), a topographic feature on the northwest slope of Aeolis Mons. Here we review the sedimentary facies and stratigraphy observed during sols 1,800–2,300, covering more than 100 m of stratigraphic thickness. Curiosity's traverse includes two transects across the ridge, which enables investigation of lateral variability over a distance of ~300 m. Three informally named stratigraphic members of the Murray formation are described: Blunts Point, Pettegrove Point, and Jura, with the latter two exposed on VRR. The Blunts Point member, exposed just below the ridge, is characterized by a recessive, fine-grained facies that exhibits extensive planar lamination and is crosscut by abundant curvi-planar veins. The Pettegrove Point member is more resistant, fine-grained, thinly planar laminated, and contains a higher abundance of diagenetic concretions. Conformable above the Pettegrove Point member is the Jura member, which is also fine-grained and parallel stratified, but is marked by a distinct step in topography, which coincides with localized meter-scale inclined strata, a thinly and thickly laminated facies, and occasional crystal molds. All members record low-energy lacustrine deposition, consistent with prior observations of the Murray formation. Uncommon outcrops of low-angle stratification suggest possible subaqueous currents, and steeply inclined beds may be the result of slumping. Collectively, the rocks exposed at VRR provide additional evidence for a long-lived lacustrine environment (in excess of 10 6 years via comparison to terrestrial records of sedimentation), which extends our understanding of the duration of habitable conditions in Gale crater.

Journal of Geophysical Research: Planets

The Cenomanian/Turonian carbon burial event, Bass River, NJ, USA: Geochemical, paleoecological, and sea-level changes

The Bass River borehole (ODP Leg 174AX) recovered approximately 200 ft (61 m) of upper Cenomanian to lower Turonian strata from the New Jersey Coastal Plain, USA, including the expression of a global carbon burial event. The Cenomanian/Turonian (C/T) boundary is recognized at Bass River at ???1935.5 ft (589.9 m) based on the contact of nannofossil Microstaurus chiastius and Eiffellithus eximius Subzones of the Parhabdolithus asper Zone. Carbon isotopic records of both Gavelinella and Epistomina show a large (>2???) increase immediately below the C/T boundary, with maximum values of 6??? in Epistomina and 4.3??? in Gavelinella. The ??13C offset between these taxa is constant and we conclude that Epistomina, like Gavelinella, faithfully records seawater ??13C changes. Above the sharp ??13C increase, elevated ??13C and sedimentary organic carbon (>0.9%) values continue into the lower Turonian, culminating in a sharp ??13C decrease. High ??13C values in the uppermost Cenomanian-lower Turonian at Bass River correlate with a global carbon burial event recorded in Europe and the U.S. Western Interior; we estimate the duration of this event at Bass River as 400-500 k.y. Although the carbon burial event occurred during a long-term eustatic rise (10 m.y. scale), it occurs within a 1-2 m.y. long sequence at Bass River that indicates no relationship with sea-level lowering on the m.y. scale. The carbon burial event does not appear to be associated with maximum flooding either, indicating little correlation with sea-level rise on a m.y. scale. Within the sequence spanning the carbon event, there are at least 4 shallowing-upward parasequences (durations ???350-460 k.y.) indicated by changes in abundance and type of Epistomina species, ??18O variations, and minor lithologic variations. The highest occurrences of 6 Epistomina species and the origination of Epistomina sliteri Olsson n. sp. are associated with the parasequences and possibly with higher ??18O values. There is no clear association of parasequence boundaries inferred at Bass River with the carbon burial event; thus, there does not appear to be a relationship of the event with sea-level change on the 100 k.y. scale. We conclude that while the organic carbon burial event was associated with a general long-term (10 m.y. scale) eustatic rise, the initiation and termination of the peak organic burial event itself were unrelated to sea-level change.

Journal of Foraminiferal Research