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Geochemistry of sulfate minerals in high- and low-temperature environments: A tribute to Robert O. Rye

This special issue is a tribute to Robert O. Rye, known as "Bob" to most, in light of his highly productive and ongoing career. Almost all of the papers in this issue are derived from topical sessions on sulfate minerals in hydrothermal and low-temperature environments. The sessions, held at the 2000 Geological Society of America meeting in Reno, NV, and sponsored jointly by the Mineralogical Society of America, the Society of Economic Geologists and the Geochemical Society, included 29 oral and 9 poster presentations. The sessions complemented a short course on the crystallography, geochemistry and environmental significance of sulfate minerals, sponsored by the Mineralogical Society of America and the Geochemical Society, which immediately preceded the meeting (Alpers et al., 2000). The 23 papers in this special issue typify the breadth of Bob Rye’s research in this important area of geochemistry.

Chemical Geology↗

A global perspective on the use, sales, exposure pathways, occurrence, fate and effects of veterinary antibiotics (VAs) in the environment

Veterinary antibiotics (VAs) are widely used in many countries worldwide to treat disease and protect the health of animals. They are also incorporated into animal feed to improve growth rate and feed efficiency. As antibiotics are poorly adsorbed in the gut of the animals, the majority is excreted unchanged in faeces and urine. Given that land application of animal waste as a supplement to fertilizer is often a common practice in many countries, there is a growing international concern about the potential impact of antibiotic residues on the environment. Frequent use of antibiotics has also raised concerns about increased antibiotic resistance of microorganisms. We have attempted in this paper to summarize the latest information available in the literature on the use, sales, exposure pathways, environmental occurrence, fate and effects of veterinary antibiotics in animal agriculture. The review has focused on four important groups of antibiotics (tylosin, tetracycline, sulfonamides and, to a lesser extent, bacitracin) giving a background on their chemical nature, fate processes, occurrence, and effects on plants, soil organisms and bacterial community. Recognising the importance and the growing debate, the issue of antibiotic resistance due to the frequent use of antibiotics in food-producing animals is also briefly covered. The final section highlights some unresolved questions and presents a way forward on issues requiring urgent attention.

Chemosphere↗

Nonhydrostatic and surfbeat model predictions of extreme wave run-up in fringing reef environments

The accurate prediction of extreme wave run-up is important for effective coastal engineering design and coastal hazard management. While run-up processes on open sandy coasts have been reasonably well-studied, very few studies have focused on understanding and predicting wave run-up at coral reef-fronted coastlines. This paper applies the short-wave resolving, Nonhydrostatic (XB-NH) and short-wave averaged, Surfbeat (XB-SB) modes of the XBeach numerical model to validate run-up using data from two 1D (alongshore uniform) fringing-reef profiles without roughness elements, with two objectives: i) to provide insight into the physical processes governing run-up in such environments; and ii) to evaluate the performance of both modes in accurately predicting run-up over a wide range of conditions. XBeach was calibrated by optimizing the maximum wave steepness parameter (maxbrsteep) in XB-NH and the dissipation coefficient ( alpha ) in XB-SB) using the first dataset; and then applied to the second dataset for validation. XB-NH and XB-SB predictions of extreme wave run-up ( R max and R 2% ) and its components, infragravity- and sea-swell band swash ( S IG and S SS ) and shoreline setup ( <η> ), were compared to observations. XB-NH more accurately simulated wave transformation but under-predicted shoreline setup due to its exclusion of parameterized wave-roller dynamics. XB-SB under-predicted sea-swell band swash but overestimated shoreline setup due to an over-prediction of wave heights on the reef flat. Run-up (swash) spectra were dominated by infragravity motions, allowing the short-wave (but not wave group) averaged model (XB-SB) to perform comparably well to its more complete, short-wave resolving (XB-NH) counterpart. Despite their respective limitations, both modes were able to accurately predict R max and R 2% .

Coastal Engineering↗

Authigenesis of trace metals in energetic tropical shelf environments

We evaluated authigenic changes of Fe, Mn, V, U, Mo, Cd and Re in suboxic, periodically remobilized, tropical shelf sediments from the Amazon continental shelf and the Gulf of Papua. The Cd/Al, Mo/Al, and U/Al ratios in Amazon shelf sediments were 82%, 37%, and 16% less than those in Amazon River suspended sediments, respectively. Very large depletions of U previously reported in this environment were not observed. The Cd/Al ratios in Gulf of Papua sediments were 76% lower than measurements made on several Papua New Guinea rivers, whereas U/Al ratios in the shelf sediments were enriched by approximately 20%. Other metal/Al ratios in the Papua New Guinea river suspended sediments and continental shelf sediments were not distinguishably different. Comparison of metal/Al ratios to grain size distributions in Gulf of Papua samples indicates that our observations cannot be attributed to differences in grain size between the river suspended sediments and continental shelf sediments. These two shelves constitute a source of dissolved Cd to the world ocean equal to 29–100% of the dissolved Cd input from rivers, but only 3% of the dissolved Mo input and 4% of the dissolved U input. Release of Cd, Mo, and U in tropical shelf sediments is likely a result of intense Fe and Mn oxide reduction in pore waters and resuspension of the sediments. Since we do not observe depletions of particulate Fe and Mn in the shelf sediments most of these dissolved metals must reoxidize in the overlying waters and reprecipitate. As Cd exhibits the largest losses on these tropical shelves, we examined the ability of newly formed Fe and Mn oxides to adsorb dissolved Cd using a geochemical diffuse double-layer surface complexation model and found the oxide surfaces are relatively ineffective at readsorbing Cd in seawater due to surface-site competition by Mg and Ca. If the remobilization and reoxidation of Fe and Mn occurs frequently enough before sediment is buried significant amounts of Cd may be removed from the oxide surfaces. Because a much greater percentage of Mn than Fe becomes remobilized in these shelf sediments, metals closely associated with Mn oxides (like Cd) are more likely to show losses during deposition.

Continental Shelf Research↗

Barite-forming environments along a rifted continental margin, Southern California Borderland

The Southern California Continental Borderland (SCCB) is part of the broad San Andreas transform-fault plate boundary that consists of a series of fault-bounded, petroleum-generating basins. The SCCB has high heat flow and geothermal gradients produced by thinned continental crust and Neogene volcanism. Barite deposits in the SCCB occur along faults. Barite samples from two sea-cliff sites and four offshore sites in the SCCB were analyzed for mineralogy, chemical (54 elements) and isotopic (S, Sr) compositions, and petrography. Barite from Palos Verdes (PV) Peninsula sea-cliff outcrops is hosted by the Miocene Monterey Formation and underlying basalt; carbonate rocks from those outcrops were analyzed for C, O, and Sr isotopes and the basalt for S isotopes. Cold-seep barite from Monterey Bay, California was analyzed for comparison. SCCB offshore samples occur at water depths from about 500 to 1800 m. Those barites vary significantly in texture and occurrence, from friable, highly porous actively growing seafloor mounds to dense, brecciated, vein barite. This latter type of barite contrasts with cold-seep barite in being much more coarse grained, forms thick veins in places, and completely replaced rock clasts in breccia. The barite samples range from 94 to 99 wt% BaSO4, with low trace-element contents, except for high Sr, Zr, Br, U, and Hg concentrations compared to their crustal abundances. δ34S for SCCB offshore barites range from 21.6‰ to 67.4‰, and for PV barite from 62‰ to 70‰. Pyrite from PV sea-cliff basalt and sedimentary rocks that host the barites averages 7.8‰ and 2.2‰, respectively. Two offshore barite samples have δ34S values (21.6‰, 22.1‰) close to that of modern seawater sulfate, whereas all other samples are enriched to strongly enriched in 34S. 87Sr/86Sr ratios for the barites vary over a narrow range of 0.70830–0.70856 and are much lower than that of modern seawater and also lower than the middle Miocene seawater ratio, the time of deposition of the host rocks for the PV samples. This indicates that the mineralizing fluids were not unaltered seawater. We develop a model in which the barites precipitated both below the sediment–water interface and at the seafloor from low-temperature fluids that circulated along faults. The isotopic, chemical, and textural data indicate that the barites formed by several processes. Mesozoic and Cenozoic basement rocks (crystalline and overlying sedimentary rocks), Quaternary basin fill, turbidite fans, and seawater provided various elements for the barites in different environments. The fluids had a deep-seated source and were hydrothermal in the deeper parts of the system for all the barite types, including the seafloor cold-seep deposit, based on Sr isotopes and regional geothermal gradients. These deep-seated fluids mixed with other fluids as they ascended, including seawater at and near the seafloor. The high δ34S values may have resulted from extreme Rayleigh fractionation during bacterially mediated (semi)closed-system sulfate reduction, probably driven by the flux of methane- and hydrocarbon-bearing fluids through basement rocks and basin sediments. Early diagenetic dolomite and pyrite in the host Monterey Formation in the PV Headland also formed in a zone of sulfate reduction, but within sediment buried only centimeters to a few meters and with a predominantly seawater source for the sulfur. Dolomite occurring with vein barite in the PV Headland formed at temperatures in the range of 40–90 °C. The cold-seep barites have δ34S values near that of modern seawater, although still somewhat fractionated. The barites that precipitated below the sediment–water interface have higher δ34S values, suggesting that the fluids were relatively reduced with molar dissolved barium in excess of dissolved sulfate. Those samples were exposed at the seafloor by uplift along faults and are composed predominantly of massive, brecciated, and vein barite.

California↗

Igneous rocks in the Fish Creek Mountains and environs, Battle Mountain area, north-central Nevada: A microcosm of Cenozoic igneous activity in the northern Great Basin, Basin and Range Province, USA

The Great Basin of the western United States, the northern component of the Basin and Range Province, is a region of Cenozoic lithospheric extension with multiple periods and types of igneous activity. The composition and volume of Cenozoic magmas reflect a complex interaction between mantle-derived magmas and highly diverse crust, where both mantle sources and magmatic processes were modulated by tectonic environment. The Fish Creek Mountains in north-central Nevada underwent multiple igneous events ranging from ca. 40 Ma to 1 Ma that span all of the complex Cenozoic tectono-magmatic episodes of the Great Basin. The Fish Creek Mountains, therefore, is an ideal location to evaluate the different sources and processes involved in magma generation. Many plutons were emplaced in the region between about 40 and 38 Ma, several of which host base and precious metal deposits. Between 36 and 33 Ma, lava fields and calderas of the 37–19 Ma Ignimbrite Flare-up were emplaced. Both these and the preceding plutons resulted from southwestward rollback of the Farallon plate beneath North America during by far the most voluminous phase of Cenozoic magmatism. The lavas range from rare basalt and basaltic andesite to andesite, dacite, and rhyolite, have continental arc-like incompatible element patterns, and high initial 87 Sr/ 86 Sr and low εNd that require a metasomatized lithospheric mantle source combined with minor crustal component. Ignimbrites of the 34.4 Ma Cove Mine (trachydacite to rhyolite) and 34.0 Ma Caetano calderas (rhyolite to high-silica rhyolite) are abundantly porphyritic, include hydrous phases, were largely derived from partial melts of crustal rocks, but likely include 20–30% of a mantle-derived component. Igneous activity ceased in the region as the rollback-arc migrated to the southwest, but at 24.9 Ma a new caldera formed in the southern Fish Creek Mountains that was filled by ignimbrites of the Fish Creek Mountains Tuff. Intracaldera rhyolite ignimbrites range from aphyric, pumice-rich deposits at the base to progressively more quartz-feldspar phyric ignimbrites at higher levels; all flow units lack hydrous phases. No contemporaneous mafic or intermediate igneous activity accompanied caldera formation, but initial 87 Sr/ 86 Sr values in the Fish Creek Mountains tuffs are lower than in the Caetano Tuff, suggesting a greater mantle contribution to the 24.9 Ma ignimbrites. After another hiatus in igneous activity, the region was intruded and overlain by basalt to rhyolite dykes and lavas of the northern Nevada rift between 16.8 and 15.1 Ma. The primarily tholeiitic igneous suite is of the same age, chemistry, and isotopic composition as the Grande Ronde Formation of the Columbia River flood basalts, and evolved members (trachydacite and rhyolite) are crustally contaminated. The youngest northern Nevada rift lava is an alkali olivine basalt with isotopic affinity to basalts of the eastern Snake River Plain. After 10 Ma of quiescence, the region was locally covered by mafic lava flows with high-alumina olivine tholeiite compositions, represented by the 5.4 Ma Pumpernickel Valley flows. Their mid-ocean ridge-like incompatible element compositions indicate a depleted mantle source for the lavas, but radiogenic isotopic compositions indicate that the lavas of this region include a significant contribution from a mafic to ultramafic, high- 87 Sr/ 86 Sr source. The final igneous event in the Fish Creek Mountains region, the 4.0 to 1.0 Ma Buffalo Valley volcanic field, includes flows and spatter cones of transitional to alkalic basalt that are divided into two geochemical groups with identical isotopic compositions. They represent variable, low percent partial melts of the asthenosphere at different depths, yielding different rare earth element characteristics. Similar to the Lunar Crater volcanic field, the Buffalo Valley rocks represent a rare case where the lithosphere in the central Great Basin is now thin enough to allow melting of the underlying asthenosphere. Cenozoic magmatism in the northern Great Basin exhibits several transitions in magma sources and tectonic setting with time. Magmatism began as pre-extension, subduction-related, primarily lithospherically-derived magmas emplaced on/in tectonically-thickened crust. The onset of extension was partially driven by impingement of the Yellowstone plume that resulted in emplacement of rift-related volcanic and intrusive rocks in the northern Nevada rift, followed by the eruption of extension-related HAOT lavas along the northwest margin of the Great Basin. Finally, lithospheric thinning allowed for partial melting of the asthenosphere and eruption of alkaline basaltic lavas.

Nevada↗

Monitoring long-term riparian vegetation trends to inform local habitat management in a mountainous environment

Riparian ecosystems provide critical habitat for many species, yet assessment of vegetation condition at local scales is difficult to measure when considering large areas over long time periods. We present a framework to map and monitor two deciduous cover types, upland and riparian, occupying a small fraction of an expansive, mountainous landscape in north-central Wyoming. Initially, we developed broad-scale predictions of predominant woody vegetation types by integrating Landsat data into species distribution models and combining subsequent outputs into a synthesis map. Then, we evaluated a 35-year Landsat time series (1985–2019) using the Mann-Kendall test to identify significant trends in the condition of upland and riparian deciduous vegetation and assessed the rate and direction of change using the Theil-Sen estimator. Finally, we used plot level data to assess the utility of the framework to detect bottom-up controls (ungulate browse pressure and management actions) on vegetation condition. The synthesis map had an overall correct classification rate of 87% and field data indicated deciduous vegetation within 45 m of coniferous forest faces increased pressure of conifer expansion. The trend assessment identified consistent patterns operating at the landscape scale across both upland and riparian deciduous vegetation; a predominant greening trend was observed for 12 years followed by a 9-year browning trend, before switching back to a greening trend for the last 13 years of the study. Our results indicate trends are driven by the climate of the measurement period at the landscape scale. Although we did not find conclusive evidence to establish a strong link between browse pressure and satellite data, we highlight examples where prevailing trends can be overridden by local disturbance or management intervention. This framework is transferable to other understudied riparian environments throughout western North America to provide insight on ecohydrological processes and assess global and local stressors across broad spatiotemporal scales.

Wyoming↗

Large-scale erosion driven by intertidal eelgrass loss in an estuarine environment

Seagrasses influence local hydrodynamics by inducing drag on the flow and dampening near-bed velocities and wave energy. When seagrasses are lost, near-bed currents and wave energy can increase, which enhances bottom shear stresses, destabilizes sediment, and promotes suspension and erosion. Though seagrasses are being lost rapidly globally, the magnitude of change in sediment stabilization following ecosystem-wide eelgrass loss has rarely been measured. In this study, we explored the geomorphological changes associated with an unprecedented estuary-wide collapse of a seagrass (eelgrass, Zostera marina ) in Morro Bay, CA, USA. Morro Bay has historically suffered from accelerated sedimentation and accretion. However, following massive eelgrass loss since 2010, over 90% of locations that previously had eelgrass experienced erosion. Elevation losses (erosion) reached 0.50 m in some places (mean loss of 0.10 m) with as much as a 50% decrease (median decrease of 13.6%) in elevation (i.e., increase in depth) compared to pre-decline levels. In comparison, the mouth of the estuary, where eelgrass was largely retained, had only 27.7% of the locations with prior eelgrass experiencing erosion and underwent a mean elevation increase (accretion) of 0.32 m. Thus, the loss of eelgrass appears to have altered dynamics at the seabed and transitioned large regions of the estuary from an environment that promotes deposition and accretion to one that promotes suspension and erosion. Large-scale erosion following seagrass loss may be predictive of future shoreline and coastal habitat changes and is likely to be exacerbated by increased storm surge and sea level rise expected with climate change.

California↗

Ingredients in sustainably managing water in semi-arid environments

The lessons learned from CALFED indicate that ingredients important in the long-term resolution of water management issues may not result in short-term “solutions”. The value of this special issue lies in its identification of ingredients that stimulate re-framing of issues, adapting to new knowledge and innovative decisions. But sustainable water management also requires the political patience to sustain those processes as a means of perpetuating the long-term decision-making necessary to anticipate and/or respond to an ever-changing environment.

Environmental Science and Policy↗

Parallel Fortran-MPI software for numerical inversion of the Laplace transform and its application to oscillatory water levels in groundwater environments

A parallel Fortran-MPI (Message Passing Interface) software for numerical inversion of the Laplace transform based on a Fourier series method is developed to meet the need of solving intensive computational problems involving oscillatory water level's response to hydraulic tests in a groundwater environment. The software is a parallel version of ACM (The Association for Computing Machinery) Transactions on Mathematical Software (TOMS) Algorithm 796. Running 38 test examples indicated that implementation of MPI techniques with distributed memory architecture speedups the processing and improves the efficiency. Applications to oscillatory water levels in a well during aquifer tests are presented to illustrate how this package can be applied to solve complicated environmental problems involved in differential and integral equations. The package is free and is easy to use for people with little or no previous experience in using MPI but who wish to get off to a quick start in parallel computing. ?? 2004 Elsevier Ltd. All rights reserved.

Environmental Modelling and Software↗

Avian community response to a novel environment: Commercial forestry in the Campos grasslands of South America

Establishing commercial tree plantations in native grassland ecosystems introduces a different structural and functional vegetation cover type, with expected implications for biodiversity. To better understand biodiversity responses to afforestation, we conducted a resource-use study with birds as a focal group, during the 2013–2014 breeding season in the Northern Campos grasslands of Uruguay. We sampled birds in native environments and plantations of loblolly pine ( Pinus taeda ) and flooded gum ( Eucalyptus grandis ) at different rotation stages. We recorded 103 species during 1,573 visits (10-min, 50-meter radius point counts) to 570 stratified sampling units. Native grasslands and forests exhibited greater diversity and had greater variability in species composition than structurally homogeneous plantations. Avian communities in plantations had distinct species combinations and relative abundances not found in native conditions. Avian communities in older plantations were more similar to native forests while those of newly-planted stands were more like grasslands. However, plantations were dominated by habitat generalists and some forest-dependent species, with negligible use by grassland specialist birds. Our results suggest the best conservation opportunities for grassland-dependent birds in afforested systems of the Campos of Uruguay may depend on diverse landscape-level measures rather than stand-level management practices. Albeit our research constituted a comprehensive assessment of bird taxonomic alpha and beta diversity, research on complementary diversity facets and multi-scale resource selection and demographic studies are needed to better understand the fitness implications for conserving and managing grassland birds in afforested landscapes.

Campos grasslands↗

Global patterns and environmental controls of perchlorate and nitrate co-occurrence in arid and semi-arid environments

Natural perchlorate (ClO 4 − ) is of increasing interest due to its wide-spread occurrence on Earth and Mars, yet little information exists on the relative abundance of ClO 4 − compared to other major anions, its stability, or long-term variations in production that may impact the observed distributions. Our objectives were to evaluate the occurrence and fate of ClO 4 − in groundwater and soils/caliche in arid and semi-arid environments (southwestern United States, southern Africa, United Arab Emirates, China, Antarctica, and Chile) and the relationship of ClO 4 − to the more well-studied atmospherically deposited anions NO 3 − and Cl − as a means to understand the prevalent processes that affect the accumulation of these species over various time scales. ClO 4 − is globally distributed in soil and groundwater in arid and semi-arid regions on Earth at concentrations ranging from 10 −1 to 10 6 μg/kg. Generally, the ClO 4 − concentration in these regions increases with aridity index, but also depends on the duration of arid conditions. In many arid and semi-arid areas, NO 3 − and ClO 4 − co-occur at molar ratios (NO 3 − /ClO 4 − ) that vary between ∼10 4 and 10 5 . We hypothesize that atmospheric deposition ratios are largely preserved in hyper-arid areas that support little or no biological activity (e.g. plants or bacteria), but can be altered in areas with more active biological processes including N 2 fixation, N mineralization, nitrification, denitrification, and microbial ClO 4 − reduction, as indicated in part by NO 3 − isotope data. In contrast, much larger ranges of Cl − /ClO 4 − and Cl − /NO 3 − ratios indicate Cl − varies independently from both ClO 4 − and NO 3 − . The general lack of correlation between Cl − and ClO 4 − or NO 3 − implies that Cl − is not a good indicator of co-deposition and should be used with care when interpreting oxyanion cycling in arid systems. The Atacama Desert appears to be unique compared to all other terrestrial locations having a NO 3 − /ClO 4 − molar ratio ∼10 3 . The relative enrichment in ClO 4 − compared to Cl − or NO 3 − and unique isotopic composition of Atacama ClO 4 − may reflect either additional in-situ production mechanism(s) or higher relative atmospheric production rates in that specific region or in the geological past. Elevated concentrations of ClO 4 − reported on the surface of Mars, and its enrichment with respect to Cl − and NO 3 − , could reveal important clues regarding the climatic, hydrologic, and potentially biologic evolution of that planet. Given the highly conserved ratio of NO 3 − /ClO 4 − in non-biologically active areas on Earth, it may be possible to use alterations of this ratio as a biomarker on Mars and for interpreting major anion cycles and processes on both Mars and Earth, particularly with respect to the less-conserved NO 3 − pool terrestrially.

Geochimica et Cosmochimica Acta↗

The incubation environment of nests deposited by a genetically distinct group of loggerhead sea turtles in Northwest Florida

The warming climate presents a challenge to conservation of all threatened and endangered species but particularly to those that exhibit temperature-dependent sex determination such as sea turtles. Changes in temperature may result in changes in the sex ratio of the population which can directly affect reproductive rate, abundance and population dynamics. The NW Atlantic loggerhead turtle population is listed as threatened under the U.S. Endangered Species Act, and one of the smallest subpopulations in this assemblage nests in the northern Gulf of Mexico. Here, we describe the incubation environment of northern Gulf of Mexico loggerheads nesting at several different beaches in Northwest Florida. Temperature dataloggers were placed inside and adjacent to nests on different nesting beaches across Northwest Florida. In addition, incubation durations were recorded from nests deposited on those same beaches. Internal nest temperatures were higher than those in the sand, however sand temperatures were correlated with incubation durations. Sand temperatures differed along the vertical beach profile and according to depth. Temperatures also differed along a geographic gradient across Northwest Florida and in relation to distance from the Apalachicola River. Incubation durations followed a similar pattern. Mean monthly temperatures at all sites were at or lower than 29 °C (range 23.1 °C–29.6 °C at the dunes; 23.8 °C–29.4 °C at mid-beach) which suggests nests in Northwest Florida may be producing a significant number of males, in contrast to the large number of females being produced on Florida's Atlantic coast. The temperatures and incubation durations on these nesting beaches may be regulated by differing sources of sand and beach orientations across Northwest Florida.

Northwest Florida↗

Bat activity patterns relative to temporal and weather effects in a temperate coastal environment

The northeastern and mid-Atlantic coasts of the United States are important summer maternity habitat and seasonal migratory corridors for many species of bats. Additionally, the effects of weather on bat activity are relatively unknown beyond coarse nightly scales. Using acoustic detectors, we assessed nightly and hourly activity patterns for eight species of bats over 21 consecutive months at Fire Island National Seashore, New York. The site is an important bat conservation area because it hosts one of the few confirmed northern long-eared bat ( Myotis septentrionalis ) maternity colonies in the region despite their widespread extirpation due to white-nose syndrome (WNS). There have been no reported captures of little brown bats ( M. lucifugus ), Indiana bats ( M. sodalis ), or tri-colored bats ( Perimyotis subflavus ) at the site post-WNS. Overall, we found mean hourly temperature, time since sunset, day of year, and year to be the most important predictors of bat activity levels for all examined species. Most non-hibernating, migratory species in our study demonstrated a positive relationship to mean temperature at the hourly timescale, whereas cave-hibernating bats tended to show a negative relationship to mean temperature during the time of year when they are expected to be active. Although most bat activity occurred in the late spring through early autumn, peaking in summer, some activity occurred periodically in the winter months, mostly attributable to the big brown bat ( Eptesicus fuscus ) and silver-haired bat ( Lasionycteris noctivigans ) phonic group. Unexpectedly, relationships of bat activity to wind and precipitation were largely equivocal. Initial presence (as early as March 30) and departure (between November 1–4) for northern long-eared bats at our study area occurred earlier in the spring and later in the fall than occurs for inland populations, suggesting that the species overwinters on Long Island rather than at inland karst caves or mines. A peak in spring activity characteristic of migratory behavior in the central Appalachians and Atlantic Coast was not observed at Fire Island, although Eastern red bats ( Lasiurus borealis ) and hoary bats (L. cinereus ) – both migratory species – did show a notable rise in activity in the late summer and early fall, suggesting these populations may migrate to and from Fire Island. Understanding the temporal and weather relationships to bat activity in this coastal environment may have important implications for tailoring more effective conservation and management strategies by identifying optimal timing for surveys, tracking bats during peak migratory windows, and providing insights that minimizes impacts to extant bats from activities such as wind-energy development or land management, i.e., forestry.

New York↗

Social vulnerability and geographic access barriers to earthquake early warning education in museums and other free choice learning environments

Given the earthquake risk on the West Coast of the United States, individuals and communities require a basic understanding of ShakeAlert earthquake early warning technology, which may provide crucial seconds of warning. Free choice learning environments (FCLEs), such as museums, public libraries, and national parks, are uniquely positioned to expand the reach of earthquake early warning through educational initiatives and resources. Earthquake education in these spaces creates awareness of earthquake hazards and risk in areas where people live or visit and may also increase engagement in preparedness behavior as they are trusted sources of information in their communities. However, population demographics within the ShakeAlert states has yet to be examined; audience segmentation theories require a better understanding of the demographics of the people the system seeks to serve. Here we build upon previous typology research that examined over 150 earthquake displays around the United States and found that most did not include information about earthquake preparedness or associated protective actions. This new research shifts to a hierarchical clustering analysis that identifies seven main population groups within the ShakeAlert states. We also find that the cost of admission and the geographic distance away from FCLEs, including the potential cost and time of transportation, may lead to an urban-rural divide in visitor access. Using audience segmentation theories as related to earthquakes, we can understand critical barriers to FCLEs and opportunities for ShakeAlert education. As earthquake early warning systems expand internationally, thoughtful and equitable education initiatives are beneficial to reach critical audiences.

International Journal of Disaster Risk Reduction↗

Local environment and individuals’ beliefs: The dynamics shaping public support for sustainability policy in an agricultural landscape

Agricultural landscapes are the bleeding-edge in the advancement of sustainability and climate change adaptation. Our study focuses on how individual support for sustainability policy is shaped in coupled natural and human systems. We present an agent-based model in which a cultural decision-rule quantifies the probability that a stakeholder decides to support an easement policy for a region in the Central Great Plains, USA. Our model defines a cultural threshold used to assess how culturally meaningful the policy is for each stakeholder. The individual cultural threshold is estimated using the value-belief-norm framework and is modified by perceived changes in the environment. Results demonstrated that few stakeholders support the policy in the average cultural setting (8.9%). However, enough stakeholders would support the policy under a lower cultural threshold (40.7%). Our results indicate that sustainability policies do not need to be cheap if they are culturally meaningful.

Kansas↗

Freshwater wrack along Great Lakes coasts harbors Escherichia coli: Potential for bacterial transfer between watershed environments

We investigated the occurrence, persistence, and growth potential of Escherichia coli associated with freshwater organic debris (i.e., wrack) frequently deposited along shorelines (shoreline wrack), inputs from rivers (river CPOM), and parking lot runoffs (urban litter). Samples were collected from 9 Great Lakes beaches, 3 creeks, and 4 beach parking lots. Shoreline wrack samples were mainly composed of wood chips, straw, sticks, leaf litter, seeds, feathers, and mussel shells; creek and parking lot samples included dry grass, straw, seeds, wood chips, leaf/pine needle litter; soil particles were present in parking lot samples only. E. coli concentrations (most probable number, MPN) were highly variable in all sample types: shoreline wrack frequently reached 10 5 /g dry weight (dw), river CPOM ranged from 81 to 7,916/g dw, and urban litter ranged from 0.5 to 24,952/g dw. Sequential rinsing studies showed that 61–87% of E. coli concentrations were detected in the first wash of shoreline wrack, with declining concentrations associated with 4–8 subsequent washings; viable counts were still detected even after 8 washes. E. coli grew readily in shoreline wrack and river CPOM incubated at 35 °C. At 30°C, growth was only detected in river CPOM and not in shoreline wrack or urban litter, but the bacteria persisted for at least 16 days. In summary, freshwater wrack is an understudied component of the beach ecosystem that harbors E. coli and thus likely influences estimations of water quality and the microbial community in the nearshore as a result of transfer between environments.

Illinois, Indiana, Ontario↗

Contamination of groundwater under cultivated fields in an arid environment, central Arava Valley, Israel

The purpose of this study is to obtain a better understanding of groundwater contamination processes in an arid environment (precipitation of 50 mm/year) due to cultivation. Additional aims were to study the fate of N, K, and other ions along the whole hydrological system including the soil and vadose zone, and to compare groundwater in its natural state with contaminated groundwater (through the drilling of several wells). A combination of physical, chemical, and isotopic analyses was used to describe the hydrogeological system and the recharge trends of water and salts to the aquifers. The results indicate that intensive irrigation and fertilization substantially affected the quantity and quality of groundwater recharge. Low irrigation efficiency of about 50% contributes approximately 3.5–4 million m 3 /year to the hydrological system, which corresponds to 0.65 m per year of recharge in the irrigated area, by far the most significant recharge mechanism. Two main contamination processes were identified, both linked to human activity: (1) salinization due to circulation of dissolved salts in the irrigation water itself, mainly chloride, sulfate, sodium and calcium, and (2) direct input of nitrate and potassium mainly from fertilizers. The nitrate concentrations in a local shallow groundwater lens range between 100 and 300 mg/l and in the upper sub-aquifer are over 50 mg/l. A major source of nitrate is fertilizer N in the excess irrigation water. The isotopic compositions of δ 15 N–NO 3 (range of 4.9–14.8‰) imply also possible contributions from nearby sewage ponds and/or manure. Other evidence of contamination of the local groundwater lens includes high concentrations of K (20–120 mg/l) and total organic carbon (about 10 mg/l).

Journal of Hydrology↗