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Calibration of a streamflow-routing model for the Delaware River and its principal tributaries in New York, New Jersey, and Pennsylvania

The flow-routing module of the Hydrologic Simulation Program-Fortran watershed model was calibrated for 31 reaches on the Delaware River and 5 of it principal tributaries. These calibrations primarily involved the development of discharge-storage volume relations for the defined reaches. Daily discharge records for stream-gaging stations located at the upstream ends of the study reaches on the respective streams provided the primary hydrographic inputs for the routing models. Streamflow records for gaging stations at upstream locations and on other tributaries were used to estimate all other inflows for the 5-year calibration period, 1979-83. Root mean square errors of streamflows that were simulated for the downstream ends of gaged reaches ranged from 0.4 to 9.4 percent for the Delaware River, Lehigh River, Schuylkill River, and Brandywine Creek. Errors of 13 and 30 percent resulted from the streamflow simulations for the Lackawaxen and Neversink Rivers, respectively. Verification simulations for a 3-month period of extreme low flows on the Delaware River in 1966 resulted in overestimation of discharges for the Trenton, NJ, gaging station by approximately 50 percent on many days. Observed (recorded) streamflows at the Trenton gaging station during this time were exceptionally low, owing to comparatively large diversions of flow for public supplies, and into the Delaware and Raritan Canal. A flow-verification simulation for 3 months of the summer and fall of 1985, during which time minimum flows in the basin were comparable to those of 1966, resulted in a root mean square error of 3.3 percent for the Trenton gaging station. There was no diversion to the Delaware and Raritan Canal at the time. Simulated flows closely matched observed flows for upstream gaging stations on the Delaware River as well, thereby confirming the routing calibration for this stream. Information contained in this report can be used, with little modification, to develop routing modules for full-scale applications of the Hydrologic Simulation Program FORTRAN model to the watersheds of the studied streams.

Water-Resources Investigations Report

Distribution and sources of nitrate, and presence of fluoride and pesticides, in parts of the Pasco Basin, Washington, 1986-88

Ground water was sampled in a 900-square-mile agricultural area in the Pasco Basin, which includes parts of eastern Benton County and western Franklin County, Washington, to determine distributions of nitrate and fluoride. Additional data were obtained to determine if fertilizers, irrigation water, septic systems, and naturally occurring nitrate are sources of nitrate in ground water. Limited sampling also was done to determine if pesticides were present in the ground water. Nitrate concentrations in ground water ranged from less than 0.1 to 100 milligrams per liter as nitrogen, and median concentrations of nitrate nitrogen in ground water were 3.2 and 6.7 milligrams per liter for Benton and Franklin Counties, respectively. In Franklin County, where a large percentage of the land is used for irrigated agriculture, nitrate nitrogen concentrations in water from 31 percent of sampled wells were equal to or greater than the maximum contaminant level for drinking water of 10 milligrams per liter. In Benton County, nitrate concentrations in water from about 10 percent of the sampled wells exceeded the maximum contaminant level. Nitrate concentrations in ground water at some locations in Franklin County have increased by as much as two orders of magnitude since the early 1950's. Historical data generally were not available to evaluate changes of nitrate concentrations in ground water in Benton County, except for the area around the town of Finley. A comparison of data collected during this study with data collected during 1976-77 indicate that nitrate concentrations in ground water of the Finley area probably have not changed over the intervening period. Applied nitrogen fertilizers are a major source of nitrate in ground water at many locations in the study area. Surface water used for irrigation does not contain sufficient nitrate to cause elevated concentrations in ground water. Instead, canal seepage, which makes up about 50 percent of the ground-water recharge in the study area, tends to dilute the nitrate present in ground water. Septic systems in the Finley area of Benton County are a source of nitrate in ground water, but analyses of data and results of a numerical model analysis of nitrate concentrations in the unconfmed ground-water system indicate that they are not the primary source of nitrate in ground water in this area. Naturally occurring nitrate may be a source of nitrate in ground water underlying Badger Coulee in Benton County. Average masses of natural nitrate per unit volume of sediment in two boreholes in Badger Coulee were equivalent to 2,590 and 964 pounds of nitrogen, respectively, in a block of sediments 50 feet thick underlying an acre of land. At most other locations in the study area, the amount of natural nitrate in ground water is probably small compared with nitrate from anthropogenic sources. Fluoride concentrations in ground water in the study area ranged from less than 0.1 to 4.7 milligrams per liter; the median concentration was 0.5 milligram per liter. The concentration of fluoride in water from only two of 143 wells equalled or exceeded 2.0 milligrams per liter, which is the secondary maximum contaminant level for drinking water. Both are deep wells open to the Saddle Mountains Basalt in Franklin County. Large concentrations of fluoride in deep ground waters of the Pasco Basin are apparently the result of natural conditions in the deeper basalt aquifers. One or more pesticide compounds were detected in 10 of 29 ground-water samples, which were analyzed for selected chlorophenoxy acid herbicides, triazine herbicides, carbamate insecticides, organophosphorus insecticides, and a few other types of pesticides. The sampling locations did not represent a random distribution, but instead, most were wells open to unconfined, shallow ground water in irrigated areas. The pesticides found include the herbicides atrazine, dicamba, metribuzin, picloram, and 2,4,5-T. Also present were aldicarb sulfone and aldicarb sulfoxide, which are degradation products of the insecticide aldicarb. Except for metribuzin, pesticide concentrations were at or near the analytical reporting limits. In all instances, the concentrations of pesticides detected were below the health advisory levels that are issued by the U.S. Environmental Protection Agency

Washington

Methods for collection and analysis of aquatic biological and microbiological samples

Chapter A4 contains methods used by the U.S. Geological Survey to collect, preserve, and analyze waters to determine their biological and microbiological properties. Part 1 discusses biological sampling and sampling statistics. The statistical procedures are accompanied by examples. Part 2 consists of detailed descriptions of more than 45 individual methods, including those for bacteria, phytoplankton, zooplankton, seston, periphyton, macrophytes, benthic invertebrates, fish and other vertebrates, cellular contents, productivity, and bioassays. Each method is summarized, and the application, interferences, apparatus, reagents, collection, analysis, calculations, reporting of results, precision and references are given. Part 3 consists of a glossary. Part 4 is a list of taxonomic references.

Techniques of Water-Resources Investigations

Chemical analyses of surface water in Illinois, 1958–74—Volume II, Illinois River basin and Mississippi River tributaries north of Illinois River basin

Samples of surface water were collected and analyzed by the Illinois Environmental Protection Agency and its predecessor, the Stream Pollution Control Bureau of the Illinois Department of Public Health. The results for the period 1958 to 1974 are presented in tabular form and the history of sampling and analytical methods are included for all sites where samples were collected at gaging stations or near enough that reliable discharge estimates could be made. The report is contained in three volumes. This volume (Volume II) includes Illinois River basin and Mississippi River tributaries north of Illinois River basin. (See also W78-10034 and W78-10036)

Illinois

Erosion assessment at the Petroglyph National Monument area, Albuquerque, New Mexico

Areas of the Petroglyph National Monument, specifically those located along the West Mesa escarpment, are being affected by erosion and gullying. A reconnaissance along the 17-mile-long escarpment identified 50 gullies. The gullies were given a qualitative ranking of Class I, least erosion, to Class IV, highest erosion. Of the 50 gullies identified, 21 were assigned Class I, 22 to Class II, 6 to Class III, and 1 to Class IV. Although the gullies may not be a direct threat to petroglyphs, the effects of gullying may have a greater effect on the aesthetics of the monument and the residences located downgradient from a gully. Most of the gullies were found along the northern part of the escarpment. This area, which is more developed than the southern areas of the escarpment, contains many dirt roads and nonpaved foot and bicycle paths. These features channel surface runoff and increase erosion. Thirty of the 50 gullies were noted as being connected to the runoff from dirt roads. High-intensity storms during the summer of 1991 may have caused or increased gullying. Analyses of these storms indicate recurrence intervals of rainfall of no more than 2 years. Indirect measurements of peak discharge in La Boca Negra Arroyo after the August 22, 1991, storm indicate that this runoff event may have a frequency of no more than 10 years. Regional frequency reports on rainfall and data collected at the rain gages indicate that gullying and erosion that occurred during the summer of 1991 were not a result of infrequent rainfall or runoff events.

New Mexico

Geohydrology and water quality of the unconsolidated deposits in Erie County, Pennsylvania

Water in unconsolidated deposits is used for the water supplies of homes, farms, municipalities, and industries in Erie County. The unconsolidated deposits cover most of the bedrock of Erie County. Thickness of the unconsolidated deposits ranged from 60 to 400 feet at 30 sites surveyed by seismic refraction and reflection methods. Water wells, mostly in the unconsolidated deposits, provide adequate domestic supplies. Wells in fractured bedrock can generally provide small domestic supplies; however, droughts can affect some of the domestic water wells. Ground-water withdrawals accounted for 10 million gallons per day of the water used in Erie County in 1984. Mean annual precipitation ranged from 42 to 47 inches per year in Erie County from 1961 through 1990; the southeastern region of the county generally receives more precipitation than the lake shore region to the north. Overland runoff to three segments of the French Creek watershed in the upland area ranged from about 13 to 19 in. per year and base flow ranged from 14 to about 18 in. per year from 1975 to 1992. Evapotranspiration ranged from about 13 to 16 in. per year for those segments. Beach and outwash deposits generally provide the largest supplies of water to wells in Erie County. A median specific capacity of 17 (gal/min)/ft (gallons per minute per foot) of drawdown was determined from records of nondomestic wells in beach deposits and 9 (gal/min)/ft of drawdown in outwash. Mean specific capacity for wells in till deposits was 1.5 (gal/min)/ft. The range in yield and specific capacity, however, was great for the unconsolidated deposits and high yielding outwash deposits are sometimes difficult to locate beneath till and valley-fill deposits. Hydraulic conductivities from three aquifer tests of outwash deposits (sand and gravel) at separate sites ranged from 110 to 2,030 ft/d (feet per day). Hydraulic conductivities from another aquifer test of sand and silt in the water table at Presque Isle ranged from 120 to 215 ft/d. Transmissivities from a third aquifer test of beach sand and gravel ranged from 235 to 262 feet squared per day. Laboratory analyses of stream samples collected during base flows in 1987 and 1988 indicate that concentrations of arsenic, barium, cadmium, chromium, fluoride, lead, mercury, and selenium did not exceed the maximum contaminant levels (MCL's) established for drinking water by the U.S. Environmental Protection Agency (USEPA). Concentrations of two nontoxic elements, iron and manganese, exceeded USEPA secondary maximum contaminant levels (SMCL's) in samples from selected stream sites. Manganese concentrations exceeded the SMCL of 0.05 milligrams per liter at 19 of 30 stream sites sampled in the Upland Plateau Section of Erie County. Twenty-one wells were sampled for inorganic constituents and selected pesticides. Some samples from three of the wells exceeded the MCL for nitrate. Total arsenic concentrations above the MCL of 50 micrograms per liter were documented intermittently in three water wells in North East Township. Water from six of seven tile drains sampled in agricultural fields contained detectable concentrations of herbicides. These samples document the transport of the herbicides from the shallow ground-water system to local streams. Herbicide concentrations were at or more than minimum reporting levels for atrazine, cyanazine, prometone, and simazine. Atrazine concentrations in all seven samples from tile drains did not exceed the USEPA MCL of 3.0 micrograms per liter.

Water-Resources Investigations Report

Compilation of minimum and maximum isotope ratios of selected elements in naturally occurring terrestrial materials and reagents

Documented variations in the isotopic compositions of some chemical elements are responsible for expanded uncertainties in the standard atomic weights published by the Commission on Atomic Weights and Isotopic Abundances of the International Union of Pure and Applied Chemistry. This report summarizes reported variations in the isotopic compositions of 20 elements that are due to physical and chemical fractionation processes (not due to radioactive decay) and their effects on the standard atomic weight uncertainties. For 11 of those elements (hydrogen, lithium, boron, carbon, nitrogen, oxygen, silicon, sulfur, chlorine, copper, and selenium), standard atomic weight uncertainties have been assigned values that are substantially larger than analytical uncertainties because of common isotope abundance variations in materials of natural terrestrial origin. For 2 elements (chromium and thallium), recently reported isotope abundance variations potentially are large enough to result in future expansion of their atomic weight uncertainties. For 7 elements (magnesium, calcium, iron, zinc, molybdenum, palladium, and tellurium), documented isotope-abundance variations in materials of natural terrestrial origin are too small to have a significant effect on their standard atomic weight uncertainties. This compilation indicates the extent to which the atomic weight of an element in a given material may differ from the standard atomic weight of the element. For most elements given above, data are graphically illustrated by a diagram in which the materials are specified in the ordinate and the compositional ranges are plotted along the abscissa in scales of (1) atomic weight, (2) mole fraction of a selected isotope, and (3) delta value of a selected isotope ratio. There are no internationally distributed isotopic reference materials for the elements zinc, selenium, molybdenum, palladium, and tellurium. Preparation of such materials will help to make isotope ratio measurements among laboratories comparable. The minimum and maximum concentrations of a selected isotope in naturally occurring terrestrial materials for selected chemical elements reviewed in this report are given below: Isotope Minimum mole fraction Maximum mole fraction -------------------------------------------------------------------------------- 2H 0 .000 0255 0 .000 1838 7Li 0 .9227 0 .9278 11B 0 .7961 0 .8107 13C 0 .009 629 0 .011 466 15N 0 .003 462 0 .004 210 18O 0 .001 875 0 .002 218 26Mg 0 .1099 0 .1103 30Si 0 .030 816 0 .031 023 34S 0 .0398 0 .0473 37Cl 0 .240 77 0 .243 56 44Ca 0 .020 82 0 .020 92 53Cr 0 .095 01 0 .095 53 56Fe 0 .917 42 0 .917 60 65Cu 0 .3066 0 .3102 205Tl 0 .704 72 0 .705 06 The numerical values above have uncertainties that depend upon the uncertainties of the determinations of the absolute isotope-abundance variations of reference materials of the elements. Because reference materials used for absolute isotope-abundance measurements have not been included in relative isotope abundance investigations of zinc, selenium, molybdenum, palladium, and tellurium, ranges in isotopic composition are not listed for these elements, although such ranges may be measurable with state-of-the-art mass spectrometry. This report is available at the url: http://pubs.water.usgs.gov/wri014222.

Water-Resources Investigations Report

Geomorphic response to channel modifications of Skuna River at the State Highway 9 crossing at Bruce, Calhoun County, Mississippi

Skuna River at State Highway 9 at Bruce, Calhoun County, Mississippi, has geomorphically responded to channel modifications by lowering of the channel bed through degradation, which heightened and steepened channel banks and induced widening. Skuna River Canal (Skuna River) has typically degraded about 16.5 feet and widened about 150 feet from 1925 (when constructed) to 1992. Old Skuna River has degraded and widened about 11 feet and 40 feet, respectively, from 1921 to 1991. Skuna River Canal tributary has degraded about 6 feet from 1921 to 1991. Most of the geomorphic response on the Old River and the tributary seems to be a consequence of modifications of the canal. The bankfull discharge of the canal has increased about 1,450 percent, and the channel slope has decreased about 34 percent from 1925 to 1989. The bankfull stream power has been decreasing since 1980. The bankfull channel width-depth ratio has been increasing since 1975, which indicates the canal has been widening more than degrading since 1975. As much as 1 foot of additional degradation and 40 feet of additional widening are projected through 2010 on Skuna River Canal in the vicinity of State Highway 9. About 70 feet of additional widening could occur before the canal reaches quasi-equilibrium, which will likely be reached after 2010. If Old Skuna River and Skuna River Canal tributary degrade as much as the canal, which is doubtful, then about 6 and 11 feet of additional degradation could occur by 2010 on the Old Skuna River and the tributary, respectively, at State Highway 9. Old Skuna River and the tributary could both widen an additional 30 feet in the next 10 to 20 years. The channel low-stage thalweg of Skuna River Canal is beginning to meander around sandbars inducing lateral erosion of the channel banks. The widening projections in this report do not directly account for lateral erosion and are considered to be a minimum for the typical channel reach. Lateral erosion will likely have a significant effect on future widening site.

Water-Resources Investigations Report

Ground-water and surface-water relations along the Mojave River, southern California

The Mojave River and the associated floodplain aquifer are important water supplies in the Mojave Desert of Southern California. The river and aquifer, in many areas, are in excellent hydraulic connection, and when flow conditions change in one, the other almost always is affected. To better understand these relations, records of gaging stations were analyzed to determine the frequency and duration of historical streamflow. Annual ground-water recharge from the river during water years 1931-94 was estimated from an accounting of all streamflow accretions and losses. Annual recharge ranged from about 24,000 to 460,000 acre-feet and averaged about 96,000 acre-feet. Channel-geometry regression techniques were used to estimate runoff of ungaged ephemeral streams that are tributary to the river. Water-table and gravity changes were used to estimate specific yield of the aquifer and changes in ground-water storage following storm runoff during the winters of 1992-94. In addition, streamflow hydrographs were analyzed to estimate both ground-water discharge to the river (base flow) and historical streamflow depletion caused by ground-water pumping and evapotranspiration. Ground-water pumpage from the flood-plain aquifer was about 120,000 acre-feet during water year 1994. Annual evapotranspiration along the river probably ranges from about 10,000 to 30,000 acre-feet. Factors controlling the exchange of water are identified in this report on the basis of the historical response of the river-aquifer system to stress (stormflows and pumping). Also identified are reaches of the river that are hydraulically suitable for artificial recharge.

California

User's guide to PHREEQC, a computer program for speciation, reaction-path, advective-transport, and inverse geochemical calculations

PHREEQC is a computer program written in the C programming language that is designed to perform a wide variety of aqueous geochemical calculations. PHREEQC is based on an ion-association aqueous model and has capabilities for (1) speciation and saturation-index calculations, (2) reaction-path and advective-transport calculations involving specified irreversible reactions, mixing of solutions, mineral and gas equilibria surface-complex-ation reactions, and ion-exchange reactions, and (3) inverse modeling, which finds sets of mineral and gas mole transfers that account for composition differences between waters, within specified compositional uncertainties. PHREEQC is derived from the Fortran program PHREEQE, but it has been completely rewritten in C with the addition many new capabilities. New features include the capabilities to use redox couples to distribute redox elements among their valence states in speciation calculations; to model ion-exchange and surface-complex-ation reactions; to model reactions with a fixed-pressure, multicomponent gas phase (that is, a gas bubble); to calculate the mass of water in the aqueous phase during reaction and transport calculations; to keep track of the moles of minerals present in the solid phases and determine automatically the thermodynamically stable phase assemblage; to simulate advective transport in combination with PHREEQC's reaction-modeling capability; and to make inverse modeling calculations that allow for uncertainties in the analytical data. The user interface is improved through the use of a simplified approach to redox reactions, which includes explicit mole-balance equations for hydrogen and oxygen; the use of a revised input that is modular and completely free format; and the use of mineral names and standard chemical symbolism rather than index numbers. The use of (2) eliminates nearly all limitations on army sizes, including numbers of elements, aqueous species, solutions, phases, and lengths of character strings. A new equation solver that optimizes a set of equalities subject to both equality and inequality constraints is used to determine the thermodynamically stable set of phases in equilibrium with a solution. A more complete Newton-Raphson formulation, master-species switching, and scaling of the algebraic equations reduce the number of failures of the numerical method in PHREEQC relative to PHREEQE. This report presents the equations that are the basis for chemical equilibrium and inverse-modeling calculations in PHREEQC, describes the input for the program, and presents twelve examples that demonstrate most of the program's capabilities.

Water-Resources Investigations Report

Ground-water pumpage in the Willamette lowland regional aquifer system, Oregon and Washington, 1990

Ground-water pumpage for 1990 was estimated for an area of about 5,700 square miles in northwestern Oregon and southwestern Washington as part of the Puget-Willamette Lowland Regional Aquifer System Analysis study. The estimated total ground-water pumpage in 1990 was about 340,000 acre-feet. Ground water in the study area is pumped mainly from Quaternary sediment; lesser amounts are withdrawn from Tertiary volcanic materials. Large parts of the area are used for agriculture, and about two and one-half times as much ground water was pumped for irrigation as for either public- supply or industrial needs. Estimates of ground- water pumpage for irrigation in the central part of the Willamette Valley were generated by using image-processing techniques and Landsat Thematic Mapper data. Field data and published reports were used to estimate pumpage for irrigation in other parts of the study area. Information on public- supply and industrial pumpage was collected from Federal, State, and private organizations and individuals.

Oregon, Washington

Estimating flood hydrographs and volumes for Alabama streams

The hydraulic design of highway drainage structures involves an evaluation of the effect of the proposed highway structures on lives, property, and stream stability. Flood hydrographs and associated flood volumes are useful tools in evaluating these effects. For design purposes, the Alabama Highway Department needs information on flood hydrographs and volumes associated with flood peaks of specific recurrence intervals (design floods) at proposed or existing bridge crossings. This report will provide the engineer with a method to estimate flood hydrographs, volumes, and lagtimes for rural and urban streams in Alabama with drainage areas less than 500 sq mi. Existing computer programs and methods to estimate flood hydrographs and volumes for ungaged streams have been developed in Georgia. These computer programs and methods were applied to streams in Alabama. The report gives detailed instructions on how to estimate flood hydrographs for ungaged rural or urban streams in Alabama with drainage areas less than 500 sq mi, without significant in-channel storage or regulations. (USGS)

Water-Resources Investigations Report

Data requirements for simulation of hydrogeologic effects of liquid waste injection, Harrison and Jackson Counties, Mississippi

Available literature and data were reviewed to quantify data requirements for computer simulation of hydrogeologic effects of liquid waste injection in southeastern Mississippi. Emphasis of each review was placed on quantifying physical properties of current Class I injection zones in Harrison and Jackson Counties. Class I injection zones are zones that are used for injection of hazardous or non-hazardous liquid waste below a formation containing the lowermost underground source of drinking water located within one-quarter of a mile of the injection well. Several mathematical models have been developed to simulate injection effects. The Basic Plume Method was selected because it is commonly used in permit applications, and the Intercomp model was selected because it is generally accepted and used in injection-related research. The input data requirements of the two models were combined into a single data requirement list inclusive of physical properties of injection zones only; injected waste and well properties are not included because such information is site-specific by industry, which is beyond the scope of this report. Results of the reviews of available literature and data indicated that Class I permit applications and standard-reference chemistry and physics texts were the primary sources of information to quantify physical properties of injection zones in Harrison and Jackson Counties. With the exception of a few reports and supplementary data for one injection zone in Jackson County, very little additional information pertaining to physical properties of the injection zones was available in sources other than permit applications and standard-reference texts.

Mississippi

Delineation of groundwater recharge areas, western Cape Cod, Massachusetts

The unconfined sand-and-gravel aquifer in western Cape Cod, Massachusetts, which is the sole source of water supply for the communities in the area, is recharged primarily from precipitation. The rate of recharge from precipitation is estimated to be about 26 inches per year (in/yr), or about 60 percent of the precipitation rate. This recharge rate yields a flow through the aquifer of about 180 million gallons per day (Mgal/d). Groundwater flows radially outward from the top of the water-table mound in the north-central part of the flow system toward the coast, as indicated by the water-table contours on the large map on this sheet. Recharge that reaches the water table near the top of the mound travels deeper through the aquifer than recharge that reaches the water table closer to the coast. All recharge to the aquifer ultimately discharges to pumping wells, streams, or coastal areas; however, some of this recharge may flow first through kettle ponds before eventually reaching these discharge points. Continued land development and population growth on western Cape Cod, and activities related to the operation of the Massachusetts Military Reservation (MMR), have created concerns regarding the supply of potable water in western Cape Cod and the quality and quantity of water discharging to ponds, streams, and coastal areas. Recent investigations estimated the future demand for drinking water in western Cape Cod, as well as the areas that contribute water to existing and proposed public-supply wells. Determining the source of freshwater that discharges to ponds, streams, and coastal areas is of critical importance in the protection of these natural resources for the communities of western Cape Cod. The purpose of this report is to illustrate concepts of ground-water recharge areas under average pumping and recharge conditions. This report presents results of an investigation conducted by the U.S. Geological Survey (USGS), in cooperation with the Air Force Center for Environmental Excellence (AFCEE), to delineate the areas that contribute recharge to public-supply wells, ponds, streams, and coastal areas on western Cape Cod for average annual pumping and recharge rates for the period of 1994–1996. The time period of 1994–1996 was selected for this analysis because it represents the average stress conditions prior to large-scale pumping, treatment, and reinjection of water from the MMR Installation Restoration Program's ground-water remediation systems. The pumping and reinjection of large amounts of water from these remediation systems would complicate greatly the delineation of ground-water recharge areas and therefore is beyond the scope of this analysis. The Chemical Spill-4 plume-containment system, however, is included in the simulation since it has been operating since 1993 and has been pumping, treating, and reinjecting only about 0.2 Mgal/d of water. Since 1996, however, AFCEE has constructed remediation systems for seven additional contaminant plumes that are not included in this analysis. Currently (1999), these systems are pumping, treating, and reinjecting about 9.7 Mgal/d. By 2002, when all of these systems, including those being designed, are expected to be operating, it is estimated that they will be pumping, treating, and reinjecting as much as 15.6 Mgal/d of water in the western Cape Cod aquifer. For additional information on the hydrology and geology of western Cape Cod, the reader is referred to the following reports: LeBlanc and others (1986), Barlow and Hess (1993), Masterson and others (1997a), Masterson and others (1997b), Masterson and others (1998), Ogden Environmental and Energy Services, Inc. (1998) and Jacobs Engineering Group, Inc. (1999).

Massachusetts

Water-temperature data acquisition activities in the United States

Along with the growing interest in water quality during the last decade, the need for data on all types of water-quality parameters has also increased. One parameter of particular interest, because of its many ramifications, is temperature. It influences many of the chemical and physical processes that take place in water. The solubility of gases--for example, oxygen and carbon dioxide--and the solution of mineral matter in water are functions of temperature. Such physical properties as density and viscosity vary with temperature. Oxidation of organic materials, as well as algal and bacterial growth, is promoted or retarded by favorable or unfavorable temperatures. Further, temperature bears on the utility of water: as a source of public water supplies; for industrial use, particularly if the water is used for cooling; and in the field of recreation involving contact sports, fishing, and fish culture. In recent years, temperature changes resulting from inflow of heated industrial waste, particularly effluent from power generating plants, have increased the need for temperature data to determine the degree of change, its effect on ecology, and the effect of any remedial action. Thus, because of the many extensive and intensive effects, a large amount of temperature data is collected on surface and ground waters by many agencies throughout the country. Moreover, because of its importance, there is a widespread interest in temperature even by those who are not active collectors of the data themselves. The industrialist, the manager, the public official, and others at one time or another may have need for temperature data and may well raise the questions: Who is collecting temperature data? What is the extent of the activity? Where are the data being collected? The purpose of this report is to answer these questions. The information in the report is confined to the activities of Federal and non-Federal agencies. It is based on information furnished to the Office of Water Data Coordination, U.S. Geological Survey, and published in the "Catalog of Information on Water Data, Index to Water Quality Section, Edition 1970." This is one of four indexes, each of which is a separate section of the Catalog. Three of the indexes, "Index to Water-Quality Section," "Index to Surface-Water Section," and "Index to Ground-.Water Stations," contain information on data acquired on a recurrent basis at specific locations for a period of 3 years or more. The fourth section, "Index to Areal Investigations and Miscellaneous Activities," is concerned with specific projects or shorter-term data activities that involve field or laboratory measurements or observations not included in any other section of the Catalog. The Catalog is a record of activities throughout the country (and in some places along the international border between the United States and Canada) conducted by Federal and non-Federal agencies engaged in the acquisition of water data and who furnish such information for presentation in the Catalog. The Catalog itself is an outgrowth of an assignment to the Department of the Interior and in turn to the Geological Survey, by the Office of Management and Budget, through the medium of OMB Circular A-67. This Circular states in part that one of the assigned responsibilities will be maintenance of a "central catalog of information on...water data and on Federal activities being planned or conducted to acquire such data." As an extension of this activity, non-Federal agencies are solicited to participate in the program. In this report, information is presented by means of tables and illustrations preceded by brief explanations. It includes the agencies collecting the data, the number of stations located on surface and ground waters where temperature measurements are made, the distribution of stations by States and by the 21 regions of the Water Resources Council (WRC) (a Federal agency created in accordance with the Water Resources Planning Act of 1965), and the frequency of measurements. Acquisition activities were not reported for those areas left blank on some illustrations. The report does not contain the actual temperature data. For this information, the particular agency, Federal or non-Federal, acquiring the data will have to be contacted. However, a bibliography at the end of this report lists 194 references which contain temperature data. Many of these references, especially the publications of the Geological Survey, may be available in major public and university libraries and libraries of Federal and non-Federal agencies.

Water-Resources Investigations Report

Quality of wet deposition in the Grand Calumet River watershed, northwestern Indiana, June 30, 1992-August 31, 1993

Northwestern Indiana is one of the most heavily industrialized and largest steel-producing areas in the United States. High temperature processes, such as fossil-fuel combustion and steel production, release contaminants to the atmosphere that may result in wet deposition being a major contributor to major ion and trace-metal loadings in north- western Indiana and Lake Michigan. A wet-deposition collection site was established at the Gary (Indiana) Regional Airport in June 1992 to monitor the chemical quality of wet deposition. Weekly samples were collected at this site from June 30, 1992, through August 31, 1993, and were analyzed for pH, specific conductance, and selected major ions and trace metals. Forty-eight samples collected during the study were of sufficient volumes for some of the determinations to be performed. Median constituent concentrations were determined for samples collected during warm weather and cold weather (November 1 through March 31). Median concentrations were substituted for missing values from samples with insufficient volumes for analysis of all the constituents of interest. Constituent concentrations were converted to weekly loadings. Two values were calculated to provide a range for the weekly loading for samples with measured concentrations of constituents less than the method reporting limit. The minimum weekly loading was computed by substituting zero for the constituent concentration; the maximum weekly loading was computed by substituting the method reporting limit for the concentration. If all of the sample concentrations measured were greater than the method reporting limit, an annual loading value was computed. The annual loadings could be used to assist in estimating the contribution of wet deposition to the total annual constituent loadings in the Grand Calumet River in northwestern Indiana.

Indiana

Geomorphic effects of overflow dams on the lower Neosho River, Kansas

The purpose of this report is to characterize the geomorphic (channel-changing) effects of overflow dams on the lower Neosho River channel in southeastern Kansas. Specifically, the report describes the types, upstream and downstream extents, and stability of the geomorphic effects in relation to site-specific, human-caused and natural conditions that may affect the channel’s response to the overflow dams.

Water-Resources Investigations Report

Meteorological, water-temperature, and discharge data for the Mattole River basin, Humboldt County, California

To overcome a major difficulty in the testing of the validity of river-temperature models - the lack of adequate precise synoptic data for an entire river basin - synoptic meteorologic, water-temperature, and discharge data were obtained in the Mattole River Basin in northern California during the period June 10 through August 31, 1975. The variables monitored were water temperature in the main channel and major tributaries, wind velocity, wet-bulb and dry-bulb air temperature, total hemispherical incoming radiation, total incoming shortwave radiation, discharge in the main channel and major tributaries, and average velocity and axial dispersion coefficients in the main channel. This report describes the experimental design and the instrumentation and procedures followed to insure the best possible information, and it presents a detailed set of data which can be used in testing river-temperature models. (USGS)

California