USGS Science⌕ Search

SEARCH · USGS Science

Results for “Nature Water”

Search indexed USGS publications on groundwater, aquifers, geologic maps, mineral resources and earthquakes. Explore source records by subject and place.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 235 records · Page 13Linked to original sources
USGS2012

Zinc isotope investigation of surface and pore waters in a mountain watershed impacted by acid rock drainage

The pollution of natural waters with metals derived from the oxidation of sulfide minerals like pyrite is a global environmental problem. However, the metal loading pathways and transport mechanisms associated with acid rock drainage reactions are often difficult to characterize using bulk chemical data alone. In this study, we evaluated the use of zinc (Zn) isotopes to complement traditional geochemical tools in the investigation of contaminated waters at the former Waldorf mining site in the Rocky Mountains, Colorado, U.S.A. Geochemical signatures and statistical analysis helped in identifying two primary metal loading pathways at the Waldorf site. The first was characterized by a circumneutral pH, high alkalinity, and high Zn/Cd ratios. The second was characterized by acidic pHs and low Zn/Cd ratios. Zinc isotope signatures in surface water samples collected across the site were remarkably similar (the δ 66 Zn, relative to JMC 3-0749-L, for most samples ranged from 0.20 to 0.30‰ ± 0.09‰ 2σ). This probably suggests that the ultimate source of Zn is consistent across the Waldorf site, regardless of the metal loading pathway. The δ 66 Zn of pore water samples collected within a nearby metal-impacted wetland area, however, were more variable, ranging from 0.20 to 0.80‰ ± 0.09‰ 2σ. Here the Zn isotopes seemed to reflect differences in groundwater flow pathways. However, a host of secondary processes might also have impacted Zn isotopes, including adsorption of Zn onto soil components, complexation of Zn with dissolved organic matter, uptake of Zn into plants, and the precipitation of Zn during the formation of reduced sulfur species. Zinc isotope analysis proved useful in this study; however, the utility of this isotopic tool would improve considerably with the addition of a comprehensive experimental foundation for interpreting the complex isotopic relationships found in soil pore waters.

Colorado↗
USGS2002

Modified zirconium-Eriochrome Cyanine R determination of fluoride

The Eriochrome Cyanine R method for determining fluoride in natural water has been modified to provide a single, stable reagent solution, eliminate interference from oxidizing agents, extend the concentration range to 3 p.p.m., and extend the phosphate tolerance. Temperature effect was minimized; sulfate error was eliminated by precipitation. The procedure is sufficiently tolerant to interferences found in natural and polluted waters to permit the elimination of prior distillation for most samples. The method has been applied to 500 samples.

Analytical Chemistry↗
USGS1981

Reconnaissance samplings and characterization of aquatic humic substances at the Yuma Desalting Test Facility, Arizona

Smectite clay minerals were found to be the principal compound on the surface of the cellulose-acetate, reverse-osmosis membranes at the Yuma Desalting Test Facility. These clay minerals were not present in the pumped ground water, but were blown into the conveyance canal from adjacent soils. Humic substances from the water and suspended sediments were associated with the clay films on the membrane, but no definitive results concerning their role in fouling were achieved. Microbial fouling is believed to be only a minor aspect of membrane fouling. Chemical and physical changes in humic substances were extensively studied at four points in the water-treatment process. Humic substances accounted for the largest component (over 25 percent) of organic constituents. Humic substances in the canal source water were similar to other aquatic humic substances present in natural waters. During the treatment process, these substances are brominated and decolorized. The effect of these halogenated humic substances on membrane fouling is unclear, but their presence in the reverse-osmosis product water and reverse-osmosis reject brine, along with volatile trihalomethanes, has led to environmental concerns. (USGS)

Arizona↗
USGS1997

Chlorofluorocarbon and tritium age determination of ground-water recharge in the Ryan Flat subbasin, Trans-Pecos Texas

A study was conducted to determine the relative influence of mountain-front infiltration in the Ryan Flat subbasin and to determine whether recent recharge (post-1940), which is of importance to water-use planning, has reached the Salt Basin aquifer, Trans-Pecos Texas. The alluvial and volcanic Salt Basin aquifer lies within a bolson, and the average depth to water in most of the subbasin is approximately 250 feet. Concentrations of the chlorofluorocarbons CFC-11, CFC-12, and CFC-113, as well as tritium, were measured in water from 10 wells in the study area. CFC-model recharge dates ranged from pre-1940 to the early 1970's. Ground water in five wells had CFC-model dates of pre-1940 or pre-1945. Ground water in two wells had dates of the mid- to late 1940's. Ground water from one well had a CFC-model recharge age of the early 1950's. Samples from the remaining two wells were most probably contaminated in some manner and are probably unreliable. CFC-model ages were calculated independently for the three chlorofluorocarbons, though the presence of volatile organic compounds affected agreement among them. Tritium activities in the nine wells for which tritium was analyzed indicated pre-1953 recharge and thus agreed approximately with the CFC-model dates. Ground water was analyzed for selected water-quality constituents. Water from all wells met U.S. Environmental Protection Agency national primary and secondary drinking water standards for all tested constituents except fluoride in samples from three wells. Silica concentrations in water from six wells exceeded a range considered typical in natural waters.

Water-Resources Investigations Report↗
USGS2009

'Natural background' soil water repellency in conifer forests of the north-western USA: Its prediction and relationship to wildfire occurrence

Soils under a wide range of vegetation types exhibit water repellency following the passage of a fire. This is viewed by many as one of the main causes for accelerated post-fire runoff and soil erosion and it has often been assumed that strong soil water repellency present after wildfire is fire-induced. However, high levels of repellency have also been reported under vegetation types not affected by fire, and the question arises to what degree the water repellency observed at burnt sites actually results from fire. This study aimed at determining 'natural background' water repellency in common coniferous forest types in the north-western USA. Mature or semi-mature coniferous forest sites (n = 81), which showed no evidence of recent fires and had at least some needle cast cover, were sampled across six states. After careful removal of litter and duff at each site, soil water repellency was examined in situ at the mineral soil surface using the Water Drop Penetration Time (WDPT) method for three sub-sites, followed by collecting near-surface mineral soil layer samples (0-3 cm depth). Following air-drying, samples were further analyzed for repellency using WDPT and contact angle (?? sl ) measurements. Amongst other variables examined were dominant tree type, ground vegetation, litter and duff layer depth, slope angle and aspect, elevation, geology, and soil texture, organic carbon content and pH. 'Natural background' water repellency (WDPT > 5 s) was detected in situ and on air-dry samples at 75% of all sites examined irrespective of dominant tree species (Pinus ponderosa, Pinus contorta, Picea engelmanii and Pseudotsuga menziesii). These findings demonstrate that the soil water repellency commonly observed in these forest types following burning is not necessarily the result of recent fire but can instead be a natural characteristic. The notion of a low background water repellency being typical for long-unburnt conifer forest soils of the north-western USA is therefore incorrect. It follows that, where pre-fire water repellency levels are not known or highly variable, post-fire soil water repellency conditions are an unreliable indicator in classifying soil burn severity. The terrain and soil variables examined showed, overall, no convincing relationship with the repellency levels observed (R 2 < 0.15) except that repellency was limited in soils (i) developed over meta-sedimentary lithology and (ii) with clay contents >4%. This suggests that water repellency levels cannot be predicted with confidence from common terrain or soil variables. ?? 2009 Elsevier B.V.

Journal of Hydrology↗
USGS2002

Indirect spectrophotometric determination of traces of bromide in water

A rapid, accurate, and sensitive indirect spectrophotometric method for the determination of bromide in natural waters is based on the catalytic effect of bromide on the oxidation of iodine to iodate by potassium permanganate in sulfuric acid solution. The method is applicable to concentrations ranging from 1 to 100 μ g. of bromide per liter, but may be modified to extend the concentration range. Most ions commonly occurring in water do not interfere. The standard deviation is 2.9 at bromide concentrations of 100 μ g. per liter and less at lower concentrations. The determination of bromide in samples containing known added amounts gave values ranging from 99 to 105% of the concentration calculated to be present.

Analytical Chemistry↗
USGS1948

A sensitive field test for heavy metals in water

A semiquantitative colorimetric analytical method using dithizone to detect traces of heavy metals in natural water is described. Although reagents of exceptional purity are required, only simple equipment is needed and the test can be made in a few minutes in the field. A combined mixed color and mono color technique makes the test suitable for a wide range of concentrations. The test is very sensitive; as little as 0.01 part per million of either copper, lead, zinc or any combination of the three metals can be detected readily.The dithizone test permits rapid field identification of drainage elements which contain significant concentrations of heavy metals. An example is given showing how the test can be used to trace the heavy metal content of a drainage system back to its source. It is possible that, under favorable conditions, the field test may facilitate prospecting by detecting metals discharged by the weathering of hidden ore bodies. However, until the method receives further investigation, it would be premature to predict its value.

Colorado↗
USGS2000

Calcite crystal growth inhibition by humic substances with emphasis on hydrophobic acids from the Florida Everglades

The crystallization of calcium carbonate minerals plays an integral role in the water chemistry of terrestrial ecosystems. Humic substances, which are ubiquitous in natural waters, have been shown to reduce or inhibit calcite crystal growth in experiments. The purpose of this study is to quantify and understand the kinetic effects of hydrophobic organic acids isolated from the Florida Everglades and a fulvic acid from Lake Fryxell, Antarctica, on the crystal growth of calcite (CaCO 3 ). Highly reproducible calcite growth experiments were performed in a sealed reactor at constant pH, temperature, supersaturation (Ω = 4.5), P CO 2 (10 −3.5 atm), and ionic strength (0.1 M) with various concentrations of organic acids. Higher plant-derived aquatic hydrophobic acids from the Everglades were more effective growth inhibitors than microbially derived fulvic acid from Lake Fryxell. Organic acid aromaticity correlated strongly with growth inhibition. Molecular weight and heteroatom content correlated well with growth inhibition, whereas carboxyl content and aliphatic nature did not.

Florida↗
USGS2017

Ecological impacts of winter water level drawdowns on lake littoral zones: A review

Freshwater littoral zones harbor diverse ecological communities and serve numerous ecosystem functions that are controlled, in part, by natural water level fluctuations. However, human alteration of lake hydrologic regimes beyond natural fluctuations threaten littoral zone ecological integrity. One type of hydrologic alteration in lakes is winter water level drawdowns, which are frequently employed for hydropower, flood control, and macrophyte control, among other purposes. Here, we synthesize the abiotic and biotic responses to annual and novel winter water level drawdowns in littoral zones of lakes and reservoirs. The dewatering, freezing, and increased erosion of exposed lakebeds drive changes in the littoral zone. Shoreline-specific physicochemical conditions such as littoral slope and shoreline exposure further induce modifications. Loss of fine sediment decreases nutrient availability over time, but desiccation may promote a temporary nutrient pulse upon re-inundation. Annual winter drawdowns can decrease taxonomic richness of macrophytes and benthic invertebrates and shift assemblage composition to favor taxa with r-selected life history strategies and with functional traits resistant to direct and indirect drawdown effects. Fish assemblages, though less directly affected by winter drawdowns (except where there is critically low dissolved oxygen), experience negative effects via indirect pathways like decreased food resources and spawning habitat. We identify eight general research gaps to guide future research that could improve our understanding about the complex effects of winter drawdowns on littoral zone ecology.

Aquatic Sciences↗
USGS1954

The quality and character of Pacific Northwest waters

This paper is a general discussion of the quality and chemical character of surface and ground waters in the Pacific Northwest as shown by the available data. Previous quality of water studies reported in the literature are reviewed. The composition of natural waters is considered as to the source and significance of the different mineral constituents. Analytical data are presented showing mineral constituents and physical properties of selected surface and ground waters in the region.

Open-File Report↗
USGS2002

Glacial geology and aquifer characteristics of the Big River area, central Rhode Island

The Rhode Island Water Resources Board (RIWRB), which is responsible for developing the State's major water resources, is concerned that continued growth in demand for water in Rhode Island will severely stress water supplies. In the early 1960s, the State proposed construction of a surface-water reservoir in the Big River Basin in central Rhode Island to meet the growing water demands, but, to date (2001) the U.S. Environmental Protection Agency has not given approval for construction of this reservoir. As an alternative, the RIWRB would like to identify sites in the Big River area stream-aquifer system where high-yield supply wells can be constructed to meet future water demands. A cooperative study was initiated during the summer of 1995 by the U.S. Geological Survey (USGS) and the RIWRB to evaluate ground water as a source of water supply in the Big River area. This report presents the initial results of a multi-year investigation of the three-dimensional characteristics of the surficial aquifer system based on geologic and geophysical field studies, and provides information needed to protect, develop, and manage the Big River area stream-aquifer system. The Big River area includes the entire Big River drainage basin and part of the Mishnock River drainage basin (fig. 1) and covers approximately 35 mi2, including parts of the towns of Coventry, Exeter, and West Greenwich. Most of the Big River area is in Kent County, with a small part in Washington County; it encompasses parts of the Coventry Center, Hope Valley, Crompton, and Slocum 7.5-minute quadrangles. This investigation includes a characterization of the geologic framework and an evaluation of the hydraulic properties of the stream-aquifer system. The Big River area stream-aquifer system is the surficial aquifer and the network of rivers, brooks, lakes, and ponds that overlie and are in hydraulic connection with the aquifer. The surficial materials units of the Big River area and the accompanying bedrock-surface contours (pl. 1) were delineated on the basis of data collected during field mapping, seismic-refraction surveys, ground-penetrating radar surveys, logs from all available wells and test holes, and results of previous investigations. Some streams in the study area lose surface water naturally to the underlying sand and gravel aquifer, whereas others lose water to the aquifer by induced infiltration of streamflow caused by ground-water withdrawals. Most large ground-water withdrawals are from public-supply wells in the sand and gravel aquifer in the Mishnock River Basin. Minimal ground-water withdrawals take place in the Big River Basin, because most of the land is designated as open space and protected from development by State law. The primary use of surface water in the study area is for recreation. Water from the Flat River Reservoir, the largest surface-water body in the study area, is used only for recreational purposes.

Rhode Island↗
USGS1986

Determining gold in water by anion-exchange batch extraction

This paper describes a batch procedure for determining gold in natural waters. It is completely adaptable to field operations. The water samples are filtered and acidified before they are equilibrated with an anion-exchange resin by shaking. The gold is then eluted with acetone-nitric acid solution, and the eluate evaporated to dryness. The residue is taken up in hydrobromic acid-bromine solution and the gold is extracted with methyl isobutyl ketone. The extract is electrothermally atomized in an atomic-absorption spectrophotometer. The limit of determination is 1 ng 1.

Talanta↗
USGS2009

The Farm Process Version 2 (FMP2) for MODFLOW-2005 - Modifications and Upgrades to FMP1

The ability to dynamically simulate the integrated supply-and-demand components of irrigated agricultural is needed to thoroughly understand the interrelation between surface water and groundwater flow in areas where the water-use by vegetation is an important component of the water budget. To meet this need, the computer program Farm Process (FMP1) was updated and refined for use with the U.S. Geological Survey's MODFLOW-2005 groundwater-flow model, and is referred to as MF2005-FMP2. The updated program allows the simulation, analysis, and management of nearly all components of human and natural water use. MF2005-FMP2 represents a complete hydrologic model that fully links the movement and use of groundwater, surface water, and imported water for water consumption of irrigated agriculture, but also of urban use, and of natural vegetation. Supply and demand components of water use are analyzed under demand-driven and supply-constrained conditions. From large- to small-scale settings, the MF2005-FMP2 has the unique set of capabilities to simulate and analyze historical, present, and future conditions. MF2005-FMP2 facilitates the analysis of agricultural water use where little data is available for pumpage, land use, or agricultural information. The features presented in this new version of FMP2 along with the linkages to the Streamflow Routing (SFR), Multi-Node Well (MNW), and Unsaturated Zone Flow (UZF) Packages prevents mass loss to an open system and helps to account for 'all of the water everywhere and all of the time'. The first version, FMP1 for MODFLOW-2000, is limited to (a) transpiration uptake from unsaturated root zones, (b) on-farm efficiency defined solely by farm and not by crop type, (c) a simulation of water use and returnflows related only to irrigated agriculture and not also to non-irrigated vegetation, (d) a definition of consumptive use as potential crop evapotranspiration, (e) percolation being instantly recharged to the uppermost active aquifer, (f) automatic routing of returnflow from runoff either to reaches of tributary stream segments adjacent to a farm or to one reach nearest to the farm's lowest elevation, (g) farm-well pumping from cell locations regardless of whether an irrigation requirement from these cells exists or not, and (h) specified non-routed water transfers from an undefined source outside the model domain. All of these limitations are overcome in MF2005-FMP2. The new features include (a) simulation of transpiration uptake from variably saturated, fully saturated, or ponded root zones (for example, for crops like rice or riparian vegetation), (b) definition of on-farm efficiency not only by farm but also by crop, (c) simulation of water use and returnflow from non-irrigated vegetation (for example, rain-fed agriculture or native vegetation), (d) use of crop coefficients and reference evapotranspiration, (e) simulation of the delay between percolation from farms through the unsaturated zone and recharge into the uppermost active aquifer by linking FMP2 to the UZF Package, (f) an option to manually control the routing of returnflow from farm runoff to streams, (g) an option to limit pumping to wells located only in cells where an irrigation requirement exists, and (h) simulation of water transfers to farms from a series of well fields (for example, recovery well field of an aquifer-storage-and-recovery system, ASR). In addition to the output of an economic budget for each farm between irrigation demand and supply ('Farm Demand and Supply Budget' in FMP1), a new output option called 'Farm Budget' was created for FMP2, which allows the user to track all physical flows into and out of a water accounting unit at all times. Such a unit can represent individual farms, farming districts, natural areas, or urban areas. The example model demonstrates the application of MF2005-FMP2 with delayed recharge through an unsaturated zone, rejected infiltration in a riparian area, changes in de

Techniques and Methods↗
USGS1961

Occurrence of minor elements in water

Three basic studies, using spectrographic methods, have been used to establish the occurrence of minor elements in natural waters. One study, of oceanborne chemicals in principal rivers, has established a method for the quantitative analysis of many minor elements. Strontium, barium, lithium, rubidium, chromium, nickel, copper, lead, boron, titanium, molybdenum, manganese, and vanadium occur most frequently in measurable quantities. Reconnaissance of the strontium in surface waters of the United States, shows that surface waters in parts of northern and western Texas and southern New Mexico and Arizona are comparatively high in strontium. A study of minor elements in selected waters of California is continuing. Assessment of preliminary data on uranium and radium in waters is facilitated by grouping data for 10 geotectonic regions of the United States.

Circular↗
USGS1994

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-Determination of antimony by automated-hydride atomic absorption spectrophotometry

The analysis of natural-water samples for antimony by automated-hydride atomic absorption spectrophotometry is described. Samples are prepared for analysis by addition of potassium and hydrochloric acid followed by an autoclave digestion. After the digestion, potassium iodide and sodium borohydride are added automatically. Antimony hydride (stibine) gas is generated, then swept into a heated quartz cell for determination of antimony by atomic absorption spectrophotometry. Precision and accuracy data are presented. Results obtained on standard reference water samples agree with means established by interlaboratory studies. Spike recoveries for actual samples range from 90 to 114 percent. Replicate analyses of water samples of varying matrices give relative standard deviations from 3 to 10 percent.

Open-File Report↗
USGS1997

Surface-water-quality assessment of the upper Illinois River Basin in Illinois, Indiana, and Wisconsin– Results of investigations through April 1992

A water-quality assessment of the upper Illinois River Basin (10,949 square miles) was conducted during water years 1987-91. This assessment involved interpretation of available data; 4 years of intensive data collection, including monthly sample collection at eight fixed-monitoring stations in the basin; and synoptic studies of selected water-quality constituents at many sites. The number of exceedances of water-quality criteria for chromium, copper, lead, mercury, silver, and zinc in water was essentially the same at similar stations between 1978-86 and 1987-90. For water and sediment, a large signature for many trace inorganic constituents was observed from the Chicago metropolitan area, mainly from the Des Plaines River Basin and continuing down the Illinois River. Loads of trace inorganic constituents in water were 2-13 times greater from the Chicago metropolitan area than from rural areas in the upper Illinois River Basin. Concentrations of cadmium, mercury, nickel, selenium, and zinc appeared to be relatively enriched in biota in the upper Illinois River Basin compared to other river basins. Biota from some urban sites were enriched with respect to several elements. For example, relatively large concentrations of cadmium, chromium, copper, lead, and nickel were observed in biota from sites in the Chicago River in the metropolitan area and the Calumet River. Results of pesticide sampling in 1988 and 1989 identified the pesticides bromacil, diazinon, malathion, prometon, and simazine as urban related and alachlor, atrazine, cyanazine, metolachlor, and metribuzin as agricultural related. Phenol concentrations never exceeded general-use and secondary-contact water-quality standards of 100 and 300 micrograms per liter, respectively. Pentachlorophenol concentrations observed at the Illinois River at Marseilles, Ill., between 1981 and 1992 decreased beginning in 1987. A breakdown product of the organochlorine pesticide dichloro-diphenyl-trichloroethane (DDT), p,p'-DDE was the most commonly detected organic compound in biota in both 1989 and 1990. In the nine fish-fillet samples collected in 1989, exceedances of U.S. Environmental Protection Agency (USEPA) fish tissue concentrations were noted for p,p'-DDE in all nine fillets and for dieldrin in five of the nine fillets. Nutrient concentrations in water in the study area generally were larger than concentrations typically found in natural waters. The Des Plaines River Basin contributed approximately 41 percent of the total nitrogen load to the upper Illinois River Basin, whereas the Kankakee River and Iroquois River Basins contributed about 34 and 14 percent of the total load, respectively. Dissolved-oxygen concentrations measured during a 1988 synoptic sampling exceeded State water-quality standards at 76 percent of the sampled sites. Bacteria densities greater than water-quality standards were observed at all of the fixed-monitoring stations, but densities greater than water-quality criteria and standards were observed more often at stations in the Des Plaines River Basin. Results from the analysis of changes in water quality following changes in wastewater-treatment practices indicated that current monitoring programs, although sufficient for their intended purposes, are not suitable for this type of retrospective assessment in large-scale water-quality assessments. Changes were not indicated in fish-community structure and population following changes in wastewater-treatment practices. A strong relation between the quality of the fish community and overall water-quality conditions was observed, although USEPA acute criteria for the protection of freshwater aquatic life were rarely exceeded. Analyses of fish-community data clearly showed that water quality in the urbanized parts of the study area were degraded relative to those in agricultural areas. Total chromium in streambed sediments and total recoverable sodium in water were highly correlated

Illinois, Indiana, Wisconsin↗
USGS1957

Feasibility of ground-water features of the alternate plan for the Mountain Home project, Idaho

An early plan of the U. S. Bureau of Reclamation proposed to irrigate 183,000 acres on the arid Snake River Plain south of Boise, Idaho (Mountain Home project) with Boise River water. That water would have been replaced to the Boise Valley with water imported from the Payette River. An alternate plan, proposed in 1953, would divert water from the Boise River to the plain; part of the water would be replaced by pumping ground water in the Boise valley and by importing water from the Snake River. Pumping of ground water in the Boise Valley also would help to drain waterlogged land. The present report evaluates the feasibility of the alternate plan in relation to geology and the occurrence and quality of ground water. The mean annual temperature at Boise is 50.8 ? F and there is an average of 172 days between killing frosts. The annual evaporation rate from open-water surfaces in the area is about 33 inches. Runoff in the Boise River is chiefly from precipitation on mountain slopes at altitudes above 3,000 feet, east of Boise Diversion Dam. The surface-water supply of the Boise Valley is more Than ample for the valley, owing to large upstream storage and regulatory dams and reservoirs. The valley also contains a large volume of ground water in storage, and the perennial rate of recharge is large. The computed consumptive depletion of surface water in the valley is nearly 600,000 acre-feet a year. Apparent depletion, computed from adjusted runoff at Notus, is 1,070,000 acre-feet. The difference of 470,000 acre-feet represents ground-water underflow and ungaged surface outflow from the area east of Notus. After the beginning of irrigation, around the turn of the century, the water table in the Boise Valley rose steadily; the amount of rise at some places was as much as 140 feet. Shallow perched zones of saturation were created locally. More than 100,000 acres of Boise Valley land now is waterlogged or threatened with waterlogging, despite the presence of more than 325 miles of surface drains. Successful operation of the alternate plan would depend, not only on providing adequate water to replace that exported from the Boise Valley, but also on satisfactory drainage of waterlogged land. That is, water management in the valley would have to couple economical pumping of irrigation water with effective drainage by pumping. The average of recorded yearly diversions from the Boise River is 1,280,000 acre-feet of live water (natural flow in a stream) and 201,000 acre-feet cf recycled water. Gross diversions of record in some recent single years of ample water supply reportedly exceeded 1,800,000 acre-feet. Ground water, on the other hand is used on a relatively small scale, yearly pumpage being only about 150,000 acre-feet. The feasibility of exporting 600,000 acre-feet of Boise River water would depend on the availability of replacement water in the Boise Valley and on the availability of the required surface water in the South Fork of the Boise River at the proposed point of diversion to the Mountain Home project. In 6 of the 20 years, 1931-50, recorded diversions of live and return water from th2 Boise River exceeded the live flow at the Boise Diversion Dam by 3,865 to 107,640 acre-feet. Moreover, although the average residual discharge in the river post Notus was 701,000 acre-feet, in most years some river reaches above Notus were dry at times, owing to diversion of all water from the river. Much of the flow past Notus is surface waste and effluent ground water, which averages about 422,000 acre-feet a year. The total of potential yearly ground water recharge in the Boise Valley, derived from precipitation, incoming underflow, and infiltration of irrigation water, is about 554,000 acre-feet in the feasible exchange-pumping area and areas tributary thereto. Identified and estimated consumptive depletion of ground water in the valley is about 230,000 acre-feet a year, but not all that depletion is within the exchange are

Water Supply Paper↗
USGS1996

Chemistry and potential mutagenicity of humic substances in waters from different watersheds in Britain and Ireland

Humic substances are amorphous organic macromolecules responsible for the hue of natural waters. They are also known to be precursors of mutagens formed on chlorination prior to distribution of drinking water. In this study humic substances from the waters of primary streams, from major rivers, and from reservoirs were isolated and fractionated into humic acids (HA), fulvic acids (FA) and XAD-4 acids using columns of XAD-8 and of XAD-4 resins in tandem, and the fractions from the different sources were chlorinated and assayed for mutagenicity. CPMAS 13C NMR spectroscopy showed marked differences in compositions not only between HA, FA, and XAD-4 acids from the same water samples, but also between the same fractions from water samples from different watersheds. There were found to be strong similarities between the fractions from watersheds which had closely related soil types. Aromaticity was greatest in HAs, and lowest in XAD-4 acids, and carboxyl contents and aliphatic character were greatest in the XAD-4 acids. Carbon content decreased in the order HA > FA > XAD-4 acids, and amino acids and neutral sugars contents decreased in the order HA > XAD-4 > FA. Titration data complemented aspects of the NMR data, demonstrating that carboxyl content decreased in the order XAD-4 acids > FA > HA, and indicated that phenolic character was highest in HAs and lowest in the XAD-4 acids. All samples tested gave rise to bacterial mutagens on chlorination. Although the mutagenicities were of the same order of magnitude for the chlorinated humic samples from the different sources, the samples which showed the greatest number of revertant bacterial colonies were from the Thames and Trent, large rivers with humic materials from diverse environments, and relatively high in amino acid contents.

Water Research↗