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At least 235 records · Page 13Linked to original sources

Refining the formation and early evolution of the Eastern North American Margin: New insights from multiscale magnetic anomaly analyses

To investigate the oceanic lithosphere formation and early seafloor spreading history of the North Atlantic Ocean, we examine multiscale magnetic anomaly data from the Jurassic/Early Cretaceous age Eastern North American Margin (ENAM) between 31 and 40°N. We integrate newly acquired sea surface magnetic anomaly and seismic reflection data with publicly available aeromagnetic and composite magnetic anomaly grids, satellite-derived gravity anomaly, and satellite-derived and shipboard bathymetry data. We evaluate these data sets to (1) refine magnetic anomaly correlations throughout the ENAM and assign updated ages and chron numbers to M0–M25 and eight pre-M25 anomalies; (2) identify five correlatable magnetic anomalies between the East Coast Magnetic Anomaly (ECMA) and Blake Spur Magnetic Anomaly (BSMA), which may document the earliest Atlantic seafloor spreading or synrift magmatism; (3) suggest preexisting margin structure and rifting segmentation may have influenced the seafloor spreading regimes in the Atlantic Jurassic Quiet Zone (JQZ); (4) suggest that, if the BSMA source is oceanic crust, the BSMA may be M series magnetic anomaly M42 (~168.5 Ma); (5) examine the along and across margin variation in seafloor spreading rates and spreading center orientations from the BSMA to M25, suggesting asymmetric crustal accretion accommodated the straightening of the ridge from the bend in the ECMA to the more linear M25; and (6) observe anomalously high-amplitude magnetic anomalies near the Hudson Fan, which may be related to a short-lived propagating rift segment that could have helped accommodate the crustal alignment during the early Atlantic opening.

Journal of Geophysical Research B: Solid Earth↗

Reflections from midcrustal rocks within the Mesozoic subduction complex near the eastern Aleutian Trench

Seismic reflection data collected in 1973 by Western Geophysical Company show that highly reflective rocks make up the midcrust of the convergent margin adjacent to the eastern Aleutian Trench. These rocks form an arch that strikes obliquely across the strongly expressed northeast-southwest structural grain of exposed Mesozoic rocks. In an earlier report we proposed that the deep events mark the location of either the presently subducting plate or the top of underplated rocks. However, the short radius of curvature of this arch precludes the possibility that the deep events indicate the igneous oceanic crust. Instead, the deep reflections could be from underplated rocks that have been arched by the imbrication or underplating of strata below the reflective rocks. High-amplitude water layer and interbed multiples prevent precise connection of shallow and deep geology. For example, the Border Ranges fault, a suture between major tectonostratigraphic terranes, is not revealed on any of our seismic sections. We speculate, however, that one band of reflections that rises toward but does not reach the surface is from the Eagle River thrust fault, which separates Late Cretaceous melange from deformed turbidite sequences of the same age.

Journal of Geophysical Research Solid Earth↗

Seismic detection and analysis of icequakes at Columbia Glacier, Alaska

Contributions to sea level rise from rapidly retreating marine-terminating glaciers are large and increasing. Strong increases in iceberg calving occur during retreat, which allows mass transfer to the ocean at a much higher rate than possible through surface melt alone. To study this process, we deployed an 11-sensor passive seismic network at Columbia Glacier, Alaska, during 2004–2005. We show that calving events generate narrow-band seismic signals, allowing frequency domain detections. Detection parameters were determined using direct observations of calving and validated using three statistical methods and hypocenter locations. The 1–3 Hz detections provide a good measure of the temporal distribution and size of calving events. Possible source mechanisms for the unique waveforms are discussed, and we analyze potential forcings for the observed seismicity.

Journal of Geophysical Research↗

The competition between thermal contraction and differentiation in the stress history of the Moon

The scarcity of both extension and compression features on the Moon strongly constrains the history of the lunar radius—to variations of less than ±1 km over the past 3.8 Gyr. This limit has traditionally been interpreted as requiring a delicate balance between thermal contraction of the near‐surface and expansion of a substantial cold interior region. Recent theories of lunar origin (e.g., giant impact), in contrast, favor a “hot” initial state. We propose that a reconciliation may be possible by taking account of the volume change Δ V / V | d due to differentiation. We calculate STP densities based on simplified normative mineralogies for a suite of estimates of the bulk lunar composition, of primary lunar basalt, and of the residuum left when the maximum amount of the latter is extracted from the former. Typically Δ V / V | d ≃ 2 to 5%—an expansion equivalent to heating by ∼10 3 K. Provided the timing of differentiation is correct, one might offset the cooling of a magma ocean as much as 630 km deep by differentiation of the remainder of the Moon (which need not start much below the solidus temperature). A large but not impossible amount of gabbroic melt production is implied: ∼100 times the volume of mare basalts known to have been extruded. We do not address the detailed genetic relationship of this melt to the basalts observed on the lunar surface but point out that it need not have reached the surface directly or even have entered the crust in order for the expansion to have occurred. To assess the timing of melt formation, we investigate a simple conductive lunar thermal model which takes account of both Δ V / V | d and thermal contraction. Our initial state is characterized by a central temperature T c and a depth Z 0 above which the material (derived from the magma ocean) is already at the solidus and is not suceptible to volume changes upon further differentiation. We find a range of models satisfying the limits on radius increase and decrease. The hottest has T c = 1210 K, Z 0 = 400 km; without Δ V / V | d , we would need a larger or colder (or both) core, e.g., T c ≲ 700 K for Z 0 = 200–400 km, in agreement with previous investigators. Our modeling thus lends credence to the idea that the Moon could have been initially ≳50% molten (with the remainder relatively close to the solidus) and yet experienced little volume change over the last 3.8 Gyr.

Journal of Geophysical Research B: Solid Earth↗

Modeling soil porewater salinity response to drought in tidal freshwater forested wetlands

There is a growing concern about the adverse effects of saltwater intrusion via tidal rivers, streams and creeks into tidal freshwater forested wetlands (TFFW) due to sea‐level rise (SLR) and intense and extended drought events. However, the magnitude and duration of porewater salinity in exceedance of plant salinity stress threshold (2 practical salinity units, psu) and the controlling factors remain unclear. In this study, we developed a TFFW soil porewater salinity model, in which the feedback mechanisms between soil salinity and evapotranspiration and hydraulic conductivity were incorporated. We selected sites (upper, middle, lower tidal freshwater forest sites and oligohaline marsh site) along the coastal floodplains of two rivers, the Waccamaw River (SC, USA) and the Savannah River (GA and SC, USA), that represent landscape salinity gradients from tidal influence of the Atlantic Ocean. The model results agreed well with field measurements and revealed that with drought‐induced saltwater intrusion, the mean annual soil porewater salinity and duration of elevated soil porewater salinity (> 2 psu) increased significantly compared to the normal (non‐drought) condition, posing a threat to the health and ecosystem services of TFFW even in the absence of SLR. Model results also showed more severe salinity stress under drought for the lower forest sites along the two rivers, where soil salinity values have already been at or in exceedance of the 2 psu threshold.

Georgia, South Carolina↗

Tree-ring derived avalanche frequency and climate associations in a high-latitude, maritime climate

Snow avalanches are a natural hazard in mountainous areas worldwide with severe impacts that include fatalities, damage to infrastructure, disruption to commerce, and landscape disturbance. Understanding long-term avalanche frequency patterns, and associated climate and weather influences, improves our understanding of how climate change may affect avalanche activity. We used dendrochronological techniques to evaluate the historical frequency of large magnitude avalanches (LMAs) in the high-latitude climate of southeast Alaska, United States. We collected 434 cross sections throughout six avalanche paths near Juneau, Alaska. This resulted in 2706 identified avalanche growth disturbances between 1720 and 2018, which allowed us to reconstruct 82 years with LMA activity across three sub-regions. By combining this tree-ring-derived avalanche data set with a suite of climate and atmospheric variables and applying a generalized linear model to fit a binomial regression, we found that February and March precipitation and the Oceanic Niño Index (ONI) were significant predictors of LMA activity in the study area. Specifically, LMA activity occurred during winters with substantial February and March precipitation and neutral or negative (cold) ONI values, while years not characterized by LMAs occur more frequently during warm winters (positive ONI values). Our examination of the climate-avalanche relationship in southeast Alaska sheds light on important climate variables and physical processes associated with LMA years. These results can be used to inform long-term infrastructure planning and avalanche mitigation operations in an urban area, such as Juneau, where critical infrastructure is subject to substantial avalanche hazard.

Alaska↗

Sr isotopic variations along the Juan de Fuca Ridge

Sr isotopic ratios of 39 glass and microcrystalline basalt samples along the Juan de Fuca Ridge and 1 glass sample from Brown Bear Seamount are at the lower end of the range for normal mid-oceanic ridge basalt (MORB); the average 87 Sr/ 86 Sr ratio is 0.70249±0.00014 (2-σ). Although subtle variations exist along strike of the ridge, the Sr isotope data do not show systematic variation relative to the proposed Cobb Hotspot. The isotopic data are inconsistent with an enriched mantle-plume origin for the Cobb-Eickelberg Seamount chain, as has been proposed for Iceland, the Azores, and the Galapagos spreading center. Sr isotopic ratios of samples collected north and south of the Cobb offset are identical, although minor element ratios indicate that these regions have chemically distinct mantle sources. These distinct mantle sources may not have been separated long enough to develop isotopic differences.

Journal of Geophysical Research Solid Earth↗

Global petrologic variations on the moon: A ternary-diagram approach.

A ternary-diagram approach for determination of global petrologic variations on the lunar surface is presented that incorporates valuable improvements in our previous method of using geochemical variation diagrams. This new approach uses a ternary diagram that is subdivided into equally spaced segments along each of its three sides and has a triangular area in its center. The segments are assigned distinct colors that cover the range of the visible spectrum. The apexes are assigned the three primary colors, and the center triangle, which represents equal proportions of the three apexes, is assigned the color gray. The apexes are assigned the average Fe and (Th/Ti) c (ratio normalized to chondrites) compositions of KREEP/Mg-suite rocks, mare basalts, and ferroan anorthosites. The composition of each picture element (pixel) within these Apollo orbital gamma ray databases is used to determine its position within the ternary diagram. The color corresponding to this ternary position is then placed on a classification map at that pixel's position within the orbital databases. Error databases produced for the Fe and (Th/Ti) c data were used to exclude pixels having high errors. The resultant classification map shows spatial transitions among petrologic units, allows direct determination of the relative proportions of each end-member composition in a pixel, and increases the geologic interpretability of these data over that of the individual elemental databases. The classification units correspond remarkably well to observed geologic units, when we consider the spatial resolution (100 km) of the gamma ray spectrometer. Our results are as follows: (1) The highlands contain large areas of relatively pure ferroan anorthosite. (2) The average composition of the upper lunar crust is represented by an “anorthositic gabbro” composition, which supports the “magma-ocean” hypothesis for lunar crustal genesis. (3) KREEP/Mg-suite rocks are a minor fraction of the upper lunar crust. (4) Within the farside highlands, areas of KREEP/Mg-suite rocks coincide mostly with areas of crustal thinning, which are probably areas of KREEP basalt extrusions or localized excavations of Mg-suite rocks or KREEP-rich rocks. (5) Portions of the east limb and farside highlands have considerable amounts of a mafic, chondritic Th/Ti component (like mare basalt) whose occurrences coincide with mapped concentrations of light plains that display dark-halo craters; the presence of this component supports the hypothesis that mare volcanism had occurred within this highland region before the end of final heavy bombardment.

Journal of Geophysical Research Solid Earth↗

New insights into Kilauea's volcano dynamics brought by large-scale relative relocation of microearthquakes

We investigated the microseismicity recorded in an active volcano to infer information concerning the volcano structure and long-term dynamics, by using relative relocations and focal mechanisms of microearthquakes. There were 32,000 earthquakes of the Mauna Loa and Kilauea volcanoes recorded by more than eight stations of the Hawaiian Volcano Observatory seismic network between 1988 and 1999. We studied 17,000 of these events and relocated more than 70%, with an accuracy ranging from 10 to 500 m. About 75% of these relocated events are located in the vicinity of subhorizontal decollement planes, at a depth of 8-11 km. However, the striking features revealed by these relocation results are steep southeast dipping fault planes working as reverse faults, clearly located below the decollement plane and which intersect it. If this decollement plane coincides with the pre-Mauna Loa seafloor, as hypothesized by numerous authors, such reverse faults rupture the pre-Mauna Loa oceanic crust. The weight of the volcano and pressure in the magma storage system are possible causes of these ruptures, fully compatible with the local stress tensor computed by Gillard et al. [1996]. Reverse faults are suspected of producing scarps revealed by kilometer-long horizontal slip-perpendicular lineations along the decollement surface and therefore large-scale roughness, asperities, and normal stress variations. These are capable of generating stick-slip, large-magnitude earthquakes, the spatial microseismic pattern observed in the south flank of Kilauea volcano, and Hilina-type instabilities. Rupture intersecting the decollement surface, causing its large-scale roughness, may be an important parameter controlling the growth of Hawaiian volcanoes.

Journal of Geophysical Research B: Solid Earth↗

Shear velocity structure from ambient noise and teleseismic surface wave tomography in the Cascades around Mount St. Helens

Mount St. Helens (MSH) lies in the forearc of the Cascades where conditions should be too cold for volcanism. To better understand thermal conditions and magma pathways beneath MSH, data from a dense broadband array are used to produce high‐resolution tomographic images of the crust and upper mantle. Rayleigh‐wave phase‐velocity maps and three‐dimensional images of shear velocity ( Vs ), generated from ambient noise and earthquake surface waves, show that west of MSH the middle‐lower crust is anomalously fast (3.95 ± 0.1 km/s), overlying an anomalously slow uppermost mantle (4.0–4.2 km/s). This combination renders the forearc Moho weak to invisible, with crustal velocity variations being a primary cause; fast crust is necessary to explain the absent Moho. Comparison with predicted rock velocities indicates that the fast crust likely consists of gabbros and basalts of the Siletzia terrane, an accreted oceanic plateau. East of MSH where magmatism is abundant, middle‐lower crust Vs is low (3.45–3.6 km/s), consistent with hot and potentially partly molten crust of more intermediate to felsic composition. This crust overlies mantle with more typical wave speeds, producing a strong Moho. The sharp boundary in crust and mantle Vs within a few kilometers of the MSH edifice correlates with a sharp boundary from low heat flow in the forearc to high arc heat flow and demonstrates that the crustal terrane boundary here couples with thermal structure to focus lateral melt transport from the lower crust westward to arc volcanoes.

Washington↗

Gabbroic xenoliths from the northern Gorda Ridge: Implications for magma chamber processes under slow spreading centers

Abundant gabbroic xenoliths in porphyritic pillow basalt were dredged from the northern Gorda Ridge. The host lava is a moderately fractionated, normal mid-ocean ridge basalt with a heterogeneous glass rind (Mg numbers 56-60). Other lavas in the vicinity range from near primary (Mg number 69) to fractionated (Mg number 56). On the basis of textures and mineral compositions, the xenoliths are divided into five types. The xenoliths are not cognate to the host lava, but they are genetically related. Chemistry of mineral phases in conjunction with textural features suggests that the xenoliths formed in different parts of a convecting magma chamber that underwent a period of closed system fractionation. The chamber was filled with a large proportion of crystalline mush when new, more primitive, and less dense magma was injected and mixed incompletely with the contents in the chamber, forming the hybrid host lava. -from Authors

Journal of Geophysical Research Solid Earth↗

Salt marsh loss affects tides and sediment budget in shallow bays

The current paradigm is that salt marshes and their important ecosystem services are threatened by global climate change; indeed, large marsh losses have been documented worldwide. Morphological changes associated with salt marsh erosion are expected to influence the hydrodynamics and sediment dynamics of coastal systems. Here the influence of salt marsh erosion on the tidal hydrodynamics and sediment storage capability of shallow bays is investigated. Hydrodynamics, sediment transport, and vegetation dynamics are simulated using the numerical framework Coupled Ocean‐Atmosphere‐Wave‐Sediment Transport in the Barnegat Bay‐Little Egg Harbor system, USA. We show that salt marsh erosion influences the propagation of tides into back‐barrier basins, reducing the periodic inundation and sediment delivery to marsh platforms. As salt marshes erode, the sediment trapping potential of marsh platforms decreases exponentially. In this test case, up to 50% of the sediment mass trapped by vegetation is lost once a quarter of the marsh area is eroded. Similarly, without salt marshes the sediment budget of the entire bay significantly declines. Therefore, a positive feedback might be triggered such that as the salt marsh retreats the sediment storage capacity of the system declines, which could in turn further exacerbate marsh degradation.

New Jersey↗

Magnetic effects of maghemitization of oceanic crust

Both theoretical considerations and available experimental results indicate that magnetic effects of maghemitization are strongly dependent on the grain size of the originally unoxidized titanomagnetite. Maghemitization of single‐domain titanomagnetite results in a decrease in coercivity, an increase in susceptibility, and a large decrease in Q ratio. Maghemitization of multidomain titanomagnetite results in an increase in coercivity, a decrease in susceptibility, and no large changes in Q ratio. Single‐domain titanomagnetite is probably resistant to the development of a chemical remanent magnetization (CRM), whereas multidomain titanomagnetite can acquire a CRM during maghemitization. The behavior of pseudo‐single‐domain titanomagnetite, which is the main carrier of remanence in submarine extrusive rocks, is investigated by comparing the magnetic properties of the French‐American Mid‐Ocean Undersea Study (FAMOUS) (less than 0.1 m.y. old) and the Leg 37 (3.5 m.y. old) pillow basalts recovered from the Mid‐Atlantic Ridge near 37°N. Combining electron microprobe analyses, Curie temperature measurements, and cell edge determinations, we find that the FAMOUS rocks are already oxidized ( z = 0.38), possibly as a result of some high‐temperature maghemitization during cooling of the magma. Comparison with the more highly oxidized ( z = 0.7) Leg 37 pillow basalts indicates that low‐temperature maghemitization of such rocks does not result in appreciable changes of coercivity and susceptibility, although the Q ratio does decrease and CRM seems to be acquired. Such a CRM could account for the anomalously low magnetic inclinations observed at most of the Leg 37 sites.

Journal of Geophysical Research B: Solid Earth↗

Methane hydrates in nature - Current knowledge and challenges

Recognizing the importance of methane hydrate research and the need for a coordinated effort, the United States Congress enacted the Methane Hydrate Research and Development Act of 2000. At the same time, the Ministry of International Trade and Industry in Japan launched a research program to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. India, China, the Republic of Korea, and other nations also have established large methane hydrate research and development programs. Government-funded scientific research drilling expeditions and production test studies have provided a wealth of information on the occurrence of methane hydrates in nature. Numerous studies have shown that the amount of gas stored as methane hydrates in the world may exceed the volume of known organic carbon sources. However, methane hydrates represent both a scientific and technical challenge, and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of methane hydrates in nature, (2) assessing the volume of natural gas stored within various methane hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural methane hydrates, (5) analyzing the methane hydrate role as a geohazard, (6) establishing the means to detect and characterize methane hydrate accumulations using geologic and geophysical data, and (7) establishing the thermodynamic phase equilibrium properties of methane hydrates as a function of temperature, pressure, and gas composition. The U.S. Department of Energy (DOE) and the Consortium for Ocean Leadership (COL) combined their efforts in 2012 to assess the contributions that scientific drilling has made and could continue to make to advance our understanding of methane hydrates in nature. COL assembled a Methane Hydrate Project Science Team with members from academia, industry, and government. This Science Team worked with COL and DOE to develop and host the Methane Hydrate Community Workshop, which surveyed a substantial cross section of the methane hydrate research community for input on the most important research developments in our understanding of methane hydrates in nature and their potential role as an energy resource, a geohazard, and/or as an agent of global climate change. Our understanding of how methane hydrates occur in nature is still growing and evolving, and it is known with certainty that field, laboratory, and modeling studies have contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information needed to advance our understanding of methane hydrates.

Journal of Chemical and Engineering Data↗

Juan de Fuca slab geometry and its relation to Wadati-Benioff zone seismicity

A new model of the subducted Juan de Fuca plate beneath western North America allows first-order correlations between the occurrence of Wadati-Benioff zone earthquakes and slab geometry, temperature, and hydration state. The geo-referenced 3D model, constructed from weighted control points, integrates depth information from earthquake locations and regional seismic velocity studies. We use the model to separate earthquakes that occur in the Cascadia forearc from those that occur within the underlying Juan de Fuca plate and thereby reveal previously obscured details regarding the spatial distribution of earthquakes. Seismicity within the slab is most prevalent where the slab is warped beneath northwestern California and western Washington suggesting that slab flexure, in addition to expected metamorphic dehydration processes, promotes earthquake occurrence within the subducted oceanic plate. Earthquake patterns beneath western Vancouver Island are consistent with slab dehydration processes. Conversely, the lack of slab earthquakes beneath western Oregon is consistent with an anhydrous slab. Double-differenced relocated seismicity resolves a double seismic zone within the slab beneath northwestern California that strongly constrains the location of the plate interface and delineates a cluster of seismicity 10 km above the surface that includes the 1992 M7.1 Mendocino earthquake. We infer that this earthquake ruptured a surface within the Cascadia accretionary margin above the Juan de Fuca plate. We further speculate that this earthquake is associated with a detached fragment of former Farallon plate. Other subsurface tectonic elements within the forearc may have the potential to generate similar damaging earthquakes.

British Columbia;California;Oregon;Washington↗

Tektites in Cretaceous-Tertiary boundary rocks on Haiti and their bearing on the Alvarez impact extinction hypothesis

Relic tektites are associated with a Pt-group metal abundance anomaly and shocked minerals in a thin marl bed that marks the K-T boundary on Haiti. The presence of these three impact-produced materials at the precise K-T boundary enormously strengthens the Alvarez impact extinction hypothesis. The tektites occur in smectite spherules that have external shapes typical of tektites. Their chemical and physical properties are broadly similar to those of other tektite groups, except that the Haitian tektites have lower Si and higher Fe, Ca, and Na. On average, they contain more Sc, V, Cu, Zn, Ga, Sr, Sn, and Ba and less Cr, Ni, Co, B, Mn, and Hf than Other tektite groups. Amounts of rare earth elements (REE) in the tektites indicate that their progenitor materials were not melted mafic or ultramafic oceanic crust; rather they were sedimentary deposits having a bulk composition of andesite. Rare tektites contain unusually high amounts of CaO (∼20%) and S (0.4%), and these data suggest that some target materials consisted of CaSO 4 . Anhydrite beds occur in the subsurface at two candidate impact sites (Chicxulub and Manson). Sm-Nd isotopic data for the tektites indicate that the melted precursor sediments were most likely deposited less than −400 m.y. between the Late Cretaceous and Silurian periods. Major chemical changes accompanied the diagenetic change of glass to smectite. The Haitian tektites are the first datable impact products in K-T boundary rocks, and 40 Ar- 39 Ar ages of the glass show that the K-T boundary and impact event are coeval at 64.5±0.1 Ma.

Journal of Geophysical Research↗

Crustal structure of the Chugach Mountains, southern Alaska: A study of peg‐leg multiples from a low‐velocity zone

A seismic refraction profile recorded along the geologic strike of the Chugach Mountains in southern Alaska shows three upper crustal high‐velocity layers (6.9, 7.2, and 7.6 km/s) and a unique pattern of strongly focussed echelon arrivals to a distance of 225 km. The group velocity of the ensemble of echelon arrivals is 6.4 km/s. Modeling of this profile with the reflectivity method reveals that the echelon pattern is due to peg‐leg multiples generated from within a low‐velocity zone between the second and third upper crustal high‐velocity layers. The third high‐velocity layer (7.6 km/s) is underlain at 18 km depth by a pronounced low‐velocity zone that produces a seismic shadow zone wherein peg‐leg multiples are seen as echelon arrivals. The interpretation of these echelon arrivals as multiples supersedes an earlier interpretation which attributed them to successive primary reflections arising from alternating high‐ and low‐velocity layers. Synthetic seismogram modeling indicates that a low‐velocity zone with transitional upper and lower boundaries generates peg‐leg multiples as effectively as one with sharp boundaries. No PmP or Pn arrivals from the subducting oceanic Moho at 30 km depth beneath the western part of the line are observed on the long‐offset (90–225 km) data. This may be due to a lower crustal waveguide whose top is the high‐velocity (7.6 km/s) layer and whose base is the Moho. A deep (∼54 km) reflector is not affected by the waveguide and has been identified in the data. Although peg‐leg multiples have been interpreted on some long‐range refraction profiles that sound to upper mantle depths, the Chugach Mountains profile is one of the few crustal refraction profiles where peg‐leg multiples are clearly observed. This study indicates that multiple and converted phases may be more important in seismic refraction/wide‐angle reflection profiles than previously recognized.

Alaska↗

Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems

Gas hydrate is an ice-like form of water and low molecular weight gas stable at temperatures of roughly -10ºC to 25ºC and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one-sixth of Earth’s methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean-atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean-atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth’s near-surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some fields studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.

Journal of Geophysical Research-Solid Earth↗