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At least 235 records · Page 13Linked to original sources

Reservoir analysis of the Denver earthquakes: A case of induced seismicity

Injection of fluid wastes into the fractured Precambrian crystalline bedrock beneath the Rocky Mountain Arsenal near Denver triggered earthquakes in the 1960's. An analysis, based on the assumption that fluid flow in the fractured reservoir can be approximated by flow in a porous medium, is presented. The configuration and hydrologic properties of the reservoir are determined from two lines of evidence: (1) locations of earthquake hypocenters determined by seismic arrays installed at the Arsenal and (2) observed long-term decline in fluid levels in the injection well. Together these two sets of data indicate that a long, narrow reservoir, aligned in the direction N 60°W, exists. The reservoir is 3.35 km in width, extends 30.5 km to the northwest and infinitely to the southeast, and spans a depth interval from 3.7 to 7.0 km below land surface. It has a transmissivity of 1.08×10-5 m2/s and a storage coefficient of 1.0×10-5. Computed pressure buildup along the length of the reservoir is compared with the spatial distribution of earthquake epicenters. The comparison shows that earthquakes are confined to that part of the reservoir where the pressure buildup exceeds 32 bars. This critical value is interpreted as the pressure buildup above which earthquakes occur. The migration of earthquake epicenters away from the injection well, a phenomenon noted by previous investigators, can be accounted for by the outward propagation of the critical pressure buildup. The analysis is extended to examining the effects of rapid flow in fractures opened by high injection pressure. The results show that the effect is confined to a small region within 1 km of the injection well. The existence of a critical pressure buildup above which earthquakes occur is completely consistent with the theory on the role of fluid pressure in fault movement as presented by Hubbert and Rubey.

Colorado

Physical response of a back-barrier estuary to a post-tropical cyclone

This paper presents a modeling investigation of the hydrodynamic and sediment transport response of Chincoteague Bay (VA/MD, USA) to Hurricane Sandy using the Coupled Ocean-Atmosphere-Wave-Sediment-Transport (COAWST) modeling system. Several simulation scenarios with different combinations of remote and local forces were conducted to identify the dominant physical processes. While 80% of the water level increase in the bay was due to coastal sea level at the peak of the storm, a rich spatial and temporal variability in water surface slope was induced by local winds and waves. Local wind increased vertical mixing, horizontal exchanges, and flushing through the inlets. Remote waves (swell) enhanced southward flow through wave setup gradients between the inlets, and increased locally generated wave heights. Locally generated waves had a negligible effect on water level but reduced the residual flow up to 70% due to enhanced apparent roughness and breaking-induced forces. Locally generated waves dominated bed shear stress and sediment resuspension in the bay. Sediment transport patterns mirrored the interior coastline shape and generated deposition on inundated areas. The bay served as a source of fine sediment to the inner shelf, and the ocean-facing barrier island accumulated sand from landward-directed overwash. Despite the intensity of the storm forcing, the bathymetric changes in the bay were on the order of centimeters. This work demonstrates the spectrum of responses to storm forcing, and highlights the importance of local and remote processes on back-barrier estuarine function.

Chincoteague Bay

Volcanic glass signatures in spectroscopic survey of newly proposed lunar pyroclastic deposits

Moon Mineralogy Mapper spectroscopic observations are used to assess the mineralogy of five sites that have recently been proposed to include lunar dark mantle deposits (DMDs). Volcanic glasses have, for the first time, clearly been identified at the location of three of the proposed pyroclastic deposits. This is the first time that volcanic glasses have been identified at such a small scale on the lunar surface from remote sensing observations. Deposits at Birt E, Schluter, and Walther A appear to be glassy DMDs. Deposits at Birt E and Schluter show (1) morphological evidence suggesting a likely vent and (2) mineralogical evidence indicative of the presence of volcanic glasses. The Walther A deposits, although they show no morphological evidence of vents, have the spectroscopic characteristics diagnostic of volcanic glasses. The deposits of the Freundlich-Sharonov basin are separated in two areas: (1) the Buys-Ballot deposits lack mineralogical and morphological evidence and thus are found to be associated with mare volcanism not with DMDs and (2) the Anderson crater deposits, which do not exhibit glassy DMD signatures, but they appear to be associated with possible vent structures and so may be classifiable as DMDs. Finally, dark deposits near the crater Kopff are found to be associated with likely mare volcanism and not associated with DMDs. The spectral identification of volcanic glass seen in many of the potential DMDs is a strong indicator of their pyroclastic origin.

Journal of Geophysical Research E: Planets

Chemistry and texture of the rocks at Rocknest, Gale Crater: Evidence for sedimentary origin and diagenetic alteration

A suite of eight rocks analyzed by the Curiosity Rover while it was stopped at the Rocknest sand ripple shows the greatest chemical divergence of any potentially sedimentary rocks analyzed in the early part of the mission. Relative to average Martian soil and to the stratigraphically lower units encountered as part of the Yellowknife Bay formation, these rocks are significantly depleted in MgO, with a mean of 1.3 wt %, and high in Fe, averaging over 20 wt % FeOT, with values between 15 and 26 wt % FeOT. The variable iron and low magnesium and rock texture make it unlikely that these are igneous rocks. Rock surface textures range from rough to smooth, can be pitted or grooved, and show various degrees of wind erosion. Some rocks display poorly defined layering while others seem to show possible fractures. Narrow vertical voids are present in Rocknest 3, one of the rocks showing the strongest layering. Rocks in the vicinity of Rocknest may have undergone some diagenesis similar to other rocks in the Yellowknife Bay Formation as indicated by the presence of soluble calcium phases. The most reasonable scenario is that fine-grained sediments, potentially a mixture of feldspar-rich rocks from Bradbury Rise and normal Martian soil, were lithified together by an iron-rich cement.

Journal of Geophysical Research E: Planets

Controls on mangrove forest‐atmosphere carbon dioxide exchanges in western Everglades National Park

We report on net ecosystem production (NEP) and key environmental controls on net ecosystem exchange (NEE) of carbon dioxide (CO 2 ) between a mangrove forest and the atmosphere in the coastal Florida Everglades. An eddy covariance system deployed above the canopy was used to determine NEE during January 2004 through August 2005. Maximum daytime NEE ranged from −20 to −25 μ mol (CO 2 ) m −2 s −1 between March and May. Respiration (R d ) was highly variable (2.81 ± 2.41 μ mol (CO 2 ) m −2 s −1 ), reaching peak values during the summer wet season. During the winter dry season, forest CO 2 assimilation increased with the proportion of diffuse solar irradiance in response to greater radiative transfer in the forest canopy. Surface water salinity and tidal activity were also important controls on NEE. Daily light use efficiency was reduced at high (>34 parts per thousand (ppt)) compared to low (<17 ppt) salinity by 46%. Tidal inundation lowered daytime R d by ∼0.9 μ mol (CO 2 ) m −2 s −1 and nighttime R d by ∼0.5 μ mol (CO 2 ) m −2 s −1 . The forest was a sink for atmospheric CO 2 , with an annual NEP of 1170 ± 127 g C m −2 during 2004. This unusually high NEP was attributed to year‐round productivity and low ecosystem respiration which reached a maximum of only 3 g C m −2 d −1 . Tidal export of dissolved inorganic carbon derived from belowground respiration likely lowered the estimates of mangrove forest respiration. These results suggest that carbon balance in mangrove coastal systems will change in response to variable salinity and inundation patterns, possibly resulting from secular sea level rise and climate change.

Florida

Investigating vegetation responses to underground nuclear explosions through integrated analyses

Vegetation has the potential to respond to underground nuclear explosions, yet these links have not been fully explored. Given the lack of previously described signatures, the changes in vegetation are possibly subtle. The integration of multiple different data streams is potentially a useful approach to improve signal detection. Here, we investigate whether semi-arid vegetation growth patterns responded to eight legacy underground nuclear tests at the Nevada National Security Site in southern Nevada, USA. We tested for spatial and temporal changes in vegetation cover, tree growth patterns, and tree leaf spectral properties using ground-based measurements, including those from tree-rings and hyperspectral surface vegetation reflectance, as well as space-based measurements of Normalized Difference Vegetation Index (NDVI) from Landsat. Multiple data streams suggest a localized (<1.2 km) spatial pattern whereby tree growth is enhanced closer to the source of the underground test relative to sites further away. We also observed a more regional (>1.2–9 km) pattern whereby tree growth is suppressed coincident with a drought beginning 1 year before the 1989 tests, but continuing in the 5 years following the tests, which is anomalous relative to what is expected based on the response of tree growth to previous droughts. Quantification of the relative effects of the tests on vegetation remains a challenge due to the coincident drought and the potential for other disturbances to have impacted tree growth at this time, but the integration of these data reveals a more nuanced growth response than any other one data set indicates alone.

Nevada

Metallogeny of the Great Basin: Crustal evolution, fluid flow, and ore deposits

The Great Basin physiographic province in the Western United States contains a diverse assortment of world-class ore deposits. It currently (2006) is the world’s second leading producer of gold, contains large silver and base metal (Cu, Zn, Pb, Mo, W) deposits, a variety of other important metallic (Fe, Ni, Be, REE’s, Hg, PGE) and industrial mineral (diatomite, barite, perlite, kaolinite, gallium) resources, as well as petroleum and geothermal energy resources. Ore deposits are most numerous and largest in size in linear mineral belts with complex geology. U.S. Geological Survey (USGS) scientists are in the final year of a research project initiated in the fall of 2001 to increase understanding of relations between crustal evolution, fluid flow, and ore deposits in the Great Basin. Because of its substantial past and current mineral production, this region has been the focus of numerous investigations over the past century and is the site of ongoing research by industry, academia, and state agencies. A variety of geoinformatic tools was used to organize, reinterpret, and display, in space and time, the large amounts of geologic, geophysical, geochemical, and hydrologic information deemed pertinent to this problem. This information, in combination with concentrated research on (1) critical aspects of the geologic history, (2) an area in northern Nevada that encompasses the major mineral belts, and (3) important mining districts and deposits, is producing new insights about the interplay between key tectonic events, hydrothermal fluid flow, and ore genesis in mineral belts. The results suggest that the Archean to Holocene history of the Great Basin was punctuated by several tectonic events that caused fluids of different origins (sea water, basinal brine, meteoric water, metamorphic water, magmatic water) to move through the crust. Basement faults reactivated during these events localized deformation, sedimentation, magmatism, and hydrothermal fluid flow in overlying rocks to form mineral belts that contain ore deposits of different types and ages that are locally superimposed (demonstrating inheritance). Fluid flow in these systems also was influenced by the distribution of permeable lithologies and paleotopographic highs and lows. Hydrothermal fluids evolved from their initial chemistries towards compositions that reflect the ƒ O 2 and ƒ S 2 buffering capacity of, and the ligands and metals present in, the rocks (±older mineralization) through which they moved. In northern Nevada, where gold deposits are relatively common, carbonaceous, pyritic strata buffered fluids of diverse origins to H 2 S-rich compositions so they could transport gold repeatedly over Paleozoic-Cenozoic time (convergent evolution). Ore formed where metal-laden fluids encountered effective physicochemical traps. Maps of Neogene basin fill and erosion surfaces identify areas where preexisting ore deposits have been progressively exposed or concealed. Comparisons with analogous terrains and deposit types in other parts of the world provide global context. The initial findings and some of the databases, geologic maps, sections, reconstructions, hydrogeologic models, topical syntheses, regional overviews, short courses, field guides, and deposit comparisons produced by project staff and associated managers, contractors, and collaborators have been presented in numerous abstracts, symposia, USGS publications, and professional journals over the last 5 years (see the extensive bibliography). Notable among these was the 2005 Geological Society of Nevada symposium in Reno, Nevada, and the 2005 Geological Society of America annual meeting in Salt Lake City, Utah, where project results were presented to audiences from around the nation and world. The final results of the project will be submitted for publication in 2007 to appropriate USGS and professional journals. A special issue of GEOSPHERE, scheduled for publication in 2007, will be devoted to the results of this project and related work. This special issue will reach an international audience and be available worldwide on the internet. Much of the research for this project has concentrated on areas that will receive the focused attention of the mining industry in the future. As such, the data and interpretations generated by this project have direct use for land-use managers in Federal, State, and local agencies. Improved hydrogeologic models developed by this project will considerably enhance ongoing and future water resource investigations in the region. The increased understanding of when, where, and how hydrothermal systems produce significant economic deposits has direct uses for mineral exploration and for future USGS mineral resource assessments in the Great Basin and other parts of the world.

Great Basin

Near-fault velocity spectra from laboratory failures and their relation to natural ground motion

We compared near-fault velocity spectra recorded during laboratory experiments to that of natural earthquakes. We fractured crystalline rock samples at room temperature and intermediate confining pressure (50 MPa). Subsequent slip events were generated on the fracture surfaces under higher confinement (300 MPa). Velocity spectra from rock fracture resemble the inverse frequency (1/ f ) decay of natural earthquake velocity. This spectrum can be attributed to fault creation via seismic fracturing over a wide range of spatial scales. In contrast, subsequent slips on the rough fracture surfaces are depleted in high frequency energy and falloff approximately as 1/ f 2 . The 1/ f 2 spectrum is more consistent with a slider-block model obeying static-kinetic friction than a natural earthquake. The depleted high frequency content precludes the rough fault experiments from being directly analogous to natural sources. The suppression of high frequencies may have resulted from two possible factors: (1) the presence of a well-developed shear zone and coseismic damping of the fault motion by dissipation within it or, in our favored interpretation, (2) a smaller amount of energy dissipated by shearing relative to the total energy release at elevated confining pressure. In context of the latter explanation, a unifying concept that applies to these experiments, earthquakes, ground motion, and models of complex radiated motion is that high frequency radiated energy is relatively enhanced when total energy release is nearly balanced within the source region by dissipative processes. This near-critical energy release condition can be accessed at low normal stress in laboratory experiments.

Journal of Geophysical Research

Complex mean circulation over the inner shelf south of Martha's Vineyard revealed by observations and a high-resolution model

Inner-shelf circulation is governed by the interaction between tides, baroclinic forcing, winds, waves, and frictional losses; the mean circulation ultimately governs exchange between the coast and ocean. In some cases, oscillatory tidal currents interact with bathymetric features to generate a tidally rectified flow. Recent observational and modeling efforts in an overlapping domain centered on the Martha's Vineyard Coastal Observatory (MVCO) provided an opportunity to investigate the spatial and temporal complexity of circulation on the inner shelf. ADCP and surface radar observations revealed a mean circulation pattern that was highly variable in the alongshore and cross-shore directions. Nested modeling incrementally improved representation of the mean circulation as grid resolution increased and indicated tidal rectification as the generation mechanism of a counter-clockwise gyre near the MVCO. The loss of model skill with decreasing resolution is attributed to insufficient representation of the bathymetric gradients (Δh/h), which is important for representing nonlinear interactions between currents and bathymetry. The modeled momentum balance was characterized by large spatial variability of the pressure gradient and horizontal advection terms over short distances, suggesting that observed inner-shelf momentum balances may be confounded. Given the available observational and modeling data, this work defines the spatially variable mean circulation and its formation mechanism&mdash;tidal rectification&mdash;and illustrates the importance of model resolution for resolving circulation and constituent exchange near the coast. The results of this study have implications for future observational and modeling studies near the MVCO and other inner-shelf locations with alongshore bathymetric variability.

Massachusetts

Imaging the magmatic system of Mono Basin, California with magnetotellurics in three--dimensions

A three&ndash;dimensional (3D) electrical resistivity model of Mono Basin in eastern California unveils a complex subsurface filled with zones of partial melt, fluid&ndash;filled fracture networks, cold plutons, and regional faults. In 2013, 62 broadband magnetotelluric (MT) stations were collected in an array around southeastern Mono Basin from which a 3D electrical resistivity model was created with a resolvable depth of 35 km. Multiple robust electrical resistivity features were found that correlate with existing geophysical observations. The most robust features are two 300 &plusmn; 50 km3 near-vertical conductive bodies (3&ndash;10 Ω&middot;m) that underlie the southeast and north-eastern margin of Mono Craters below 10 km depth. These features are interpreted as magmatic crystal&ndash;melt mush zones of 15 &plusmn; 5% interstitial melt surrounded by hydrothermal fluids and are likely sources for Holocene eruptions. Two conductive east&ndash;dipping structures appear to connect each magma source region to the surface. A conductive arc&ndash;like structure (< 0.9 Ω&middot;m) links the northernmost mush column at 10 km depth to just below vents near Panum Crater, where the high conductivity suggests the presence of hydrothermal fluids. The connection from the southernmost mush column at 10 km depth to below South Coul&eacute;e is less obvious with higher resistivity (200 Ω&middot;m) suggestive of a cooled connection. A third, less constrained conductive feature (4&ndash;10 Ω&middot;m) 15 km deep extending to 35 km is located west of Mono Craters near the eastern front of the Sierra Nevada escarpment, and is coincident with a zone of sporadic, long&ndash;period earthquakes that are characteristic of a fluid-filled (magmatic or metamorphic) fracture network. A resistive feature (103&ndash;105 Ω&middot;m) located under Aeolian Buttes contains a deep root down to 25 km. The eastern edge of this resistor appears to structurally control the arcuate shape of Mono Craters. These observations have been combined to form a new conceptual model of the magmatic system beneath Mono Craters to a depth of 30 km.

California

Spatial heterogeneity of within-stream methane concentrations

Streams, rivers, and other freshwater features may be significant sources of CH 4 to the atmosphere. However, high spatial and temporal variabilities hinder our ability to understand the underlying processes of CH 4 production and delivery to streams and also challenge the use of scaling approaches across large areas. We studied a stream having high geomorphic variability to assess the underlying scale of CH 4 spatial variability and to examine whether the physical structure of a stream can explain the variation in surface CH 4 . A combination of high-resolution CH 4 mapping, a survey of groundwater CH 4 concentrations, quantitative analysis of methanogen DNA, and sediment CH 4 production potentials illustrates the spatial and geomorphic controls on CH 4 emissions to the atmosphere. We observed significant spatial clustering with high CH 4 concentrations in organic-rich stream reaches and lake transitions. These sites were also enriched in the methane-producing mcrA gene and had highest CH 4 production rates in the laboratory. In contrast, mineral-rich reaches had significantly lower concentrations and had lesser abundances of mcrA . Strong relationships between CH 4 and the physical structure of this aquatic system, along with high spatial variability, suggest that future investigations will benefit from viewing streams as landscapes, as opposed to ecosystems simply embedded in larger terrestrial mosaics. In light of such high spatial variability, we recommend that future workers evaluate stream networks first by using similar spatial tools in order to build effective sampling programs.

Journal of Geophysical Research G: Biogeosciences

Observation of the geology and geomorphology of the 1999 Marsokhod test site

The Marsokhod rover returned data from six stations that were used to decipher the geomorphology and geology of a region not previously visited by members of the geomorphology field team. Satellite images and simulated descent images provided information about the regional setting. The landing zone was on an alluvial apron flanking a mountain block to the west and a playa surface to the east. Rover color images, infrared spectra analysis of the mountains, and the apron surface provided insight into the rock composition of the nearby mountains. From the return data the geomorphology team interpreted the region to consist of compressionally deformed, ancient marine sediments and igneous rocks exposed by more recent extensional tectonics. Unconsolidated alluvial materials blanket the lower flanks of the mountains. An ancient shoreline cut into alluvial material marks a high stand of water during a past, wetter climate period. Playa sediments floor a present-day, seasonally, dry lake. Observations made by the rover using panoramic and close-up (hand specimens-scale) image data and color scene data confirmed the presence of boulders, cobbles, and fines of various provinces. Rover traverses to sites identified as geologically distinct, such as fan, channel, shoreline, and playa, provided useful clues to the geologic interpretations. Analysis of local rocks was given context only through comparison with distant geologic features. These results demonstrated the importance of a multifaceted approach to site interpretation through comparison of interpretations derived by differing geologic techniques.

California

Vulnerability of high-latitude soil organic carbon in North America to disturbance

This synthesis addresses the vulnerability of the North American high-latitude soil organic carbon (SOC) pool to climate change. Disturbances caused by climate warming in arctic, subarctic, and boreal environments can result in significant redistribution of C among major reservoirs with potential global impacts. We divide the current northern high-latitude SOC pools into (1) near-surface soils where SOC is affected by seasonal freeze-thaw processes and changes in moisture status, and (2) deeper permafrost and peatland strata down to several tens of meters depth where SOC is usually not affected by short-term changes. We address key factors (permafrost, vegetation, hydrology, paleoenvironmental history) and processes (C input, storage, decomposition, and output) responsible for the formation of the large high-latitude SOC pool in North America and highlight how climate-related disturbances could alter this pool's character and size. Press disturbances of relatively slow but persistent nature such as top-down thawing of permafrost, and changes in hydrology, microbiological communities, pedological processes, and vegetation types, as well as pulse disturbances of relatively rapid and local nature such as wildfires and thermokarst, could substantially impact SOC stocks. Ongoing climate warming in the North American high-latitude region could result in crossing environmental thresholds, thereby accelerating press disturbances and increasingly triggering pulse disturbances and eventually affecting the C source/sink net character of northern high-latitude soils. Finally, we assess postdisturbance feedbacks, models, and predictions for the northern high-latitude SOC pool, and discuss data and research gaps to be addressed by future research.

Journal of Geophysical Research G: Biogeosciences

Shear velocity structure from ambient noise and teleseismic surface wave tomography in the Cascades around Mount St. Helens

Mount St. Helens (MSH) lies in the forearc of the Cascades where conditions should be too cold for volcanism. To better understand thermal conditions and magma pathways beneath MSH, data from a dense broadband array are used to produce high‐resolution tomographic images of the crust and upper mantle. Rayleigh‐wave phase‐velocity maps and three‐dimensional images of shear velocity ( Vs ), generated from ambient noise and earthquake surface waves, show that west of MSH the middle‐lower crust is anomalously fast (3.95 ± 0.1 km/s), overlying an anomalously slow uppermost mantle (4.0–4.2 km/s). This combination renders the forearc Moho weak to invisible, with crustal velocity variations being a primary cause; fast crust is necessary to explain the absent Moho. Comparison with predicted rock velocities indicates that the fast crust likely consists of gabbros and basalts of the Siletzia terrane, an accreted oceanic plateau. East of MSH where magmatism is abundant, middle‐lower crust Vs is low (3.45–3.6 km/s), consistent with hot and potentially partly molten crust of more intermediate to felsic composition. This crust overlies mantle with more typical wave speeds, producing a strong Moho. The sharp boundary in crust and mantle Vs within a few kilometers of the MSH edifice correlates with a sharp boundary from low heat flow in the forearc to high arc heat flow and demonstrates that the crustal terrane boundary here couples with thermal structure to focus lateral melt transport from the lower crust westward to arc volcanoes.

Washington

Seismicity and shear strain in the southern Great Basin of Nevada and California

This study examines the relationship between the distribution of small earthquakes (M L ≤4.3) and mechanisms of strain accumulation and relaxation in an area with long repeat times between large events, the Southern Great Basin Seismic Network (SGBSN) region. The Great Basin is a unique continental extensional province characterized by normal and strike-slip faulting, high heat flow, crust of thin to normal thickness, and high elevations. The SGBSN is operated to provide data to address suitability issues pertaining to Yucca Mountain, Nevada which is being evaluated as a potential site for a national mined geologic nuclear waste repository. Suitability issues include estimation of the probability of occurrence of future damaging earthquakes, the characterization of the mechanisms that drive hydrologic flow, and the identification of fractures (faults) that might act as flow conduits or barriers. This study attempts to explain the distribution of small earthquakes in terms of spatial variations in the shear strain field; where strain concentrates there should be a greater number of small earthquakes. Strain field models are constructed under the assumption that long term fault behavior perturbs an otherwise uniform strain field. These strain field models are then interpreted with regard to the regional tectonics and site suitability issues. Modeling results provide one possible explanation of why earthquake clusters cover regions much larger than the surface projections of any of mapped major faults; clusters in a wide band along and extending northeast of the northern half of the Furnace Creek fault may correspond to elevated shear strains along the fault and a broad cluster in the Pahranagat Shear Zone may be associated with shear strain arising from a distribution of smaller localized faults. The relatively large number of small earthquakes in the southern and eastern portions of the Nevada Test Site is consistent with the strain field models. A minimum in shear strain at Yucca Mountain is predicted by all models consistent with an almost total lack of earthquakes observed there. The region to the west of the Death Valley/Furnace Creek fault system, the portion of the study area with the most active deformation but few small earthquakes, is an area of low shear strain. A possible reason for this is that the fault configuration in the area is optimal for accommodating regional deformation via large earthquakes or creep. While there is also a relative lack of earthquakes at Yucca Mountain, this may be indicative of a lack of accumulating strain energy and thus, a lower potential for a large earthquake.

Journal of Geophysical Research

Experimental removal of wetland emergent vegetation leads to decreased methylmercury production in surface sediment

We performed plant removal (devegetation) experiments across a suite of ecologically diverse wetland settings (tidal salt marshes, river floodplain, rotational rice fields, and freshwater wetlands with permanent or seasonal flooding) to determine the extent to which the presence (or absence) of actively growing plants influences the activity of the Hg(II)-methylating microbial community and the availability of Hg(II) to those microbes. Vegetated control plots were paired with neighboring devegetated plots in which photosynthetic input was terminated 4–8 months prior to measurements, through clipping aboveground biomass, severing belowground connections, and shading the sediment surface to prevent regrowth. Across all wetlands, devegetation decreased the activity of the Hg(II)-methylating microbial community (k meth ) by 38%, calculated MeHg production potential (MP) rates by 36%, and pore water acetate concentration by 78%. Decreases in MP were associated with decreases in microbial sulfate reduction in salt marsh settings. In freshwater agricultural wetlands, decreases in MP were related to indices of microbial iron reduction. Sediment MeHg concentrations were also significantly lower in devegetated than in vegetated plots in most wetland settings studied. Devegetation effects were correlated with live root density (percent volume) and were most profound in vegetated sites with higher initial pore water acetate concentrations. Densely rooted wetlands had the highest rates of microbial Hg(II)-methylation activity but often the lowest concentrations of bioavailable reactive Hg(II). We conclude that the exudation of labile organic carbon (e.g., acetate) by plants leads to enhanced microbial sulfate and iron reduction activity in the rhizosphere, which results in high rates of microbial Hg(II)-methyation and high MeHg concentrations in wetland sediment.

Journal of Geophysical Research: Biogeosciences

Processes of multibathyal aragonite undersaturation in the Arctic Ocean

During 3 years of study (2010–2012), the western Arctic Ocean was found to have unique aragonite saturation profiles with up to three distinct aragonite undersaturation zones. This complexity is produced as inflow of Atlantic-derived and Pacific-derived water masses mix with Arctic-derived waters, which are further modified by physiochemical and biological processes. The shallowest aragonite undersaturation zone, from the surface to ∼30 m depth is characterized by relatively low alkalinity and other dissolved ions. Besides local influence of biological processes on aragonite undersaturation of shallow coastal waters, the nature of this zone is consistent with dilution by sea-ice melt and invasion of anthropogenic CO 2 from the atmosphere. A second undersaturated zone at ∼90–220 m depth (salinity ∼31.8–35.4) occurs within the Arctic Halocline and is characterized by elevated p CO 2 and nutrients. The nature of this horizon is consistent with remineralization of organic matter on shallow continental shelves bordering the Canada Basin and the input of the nutrients and CO 2 entrained by currents from the Pacific Inlet. Finally, the deepest aragonite undersaturation zone is at greater than 2000 m depth and is controlled by similar processes as deep aragonite saturation horizons in the Atlantic and Pacific Oceans. The comparatively shallow depth of this deepest aragonite saturation horizon in the Arctic is maintained by relatively low temperatures, and stable chemical composition. Understanding the mechanisms controlling the distribution of these aragonite undersaturation zones, and the time scales over which they operate will be crucial to refine predictive models.

Journal of Geophysical Research: Oceans

Map showing sediment isopachs in the deep-sea basins of the Pacific continental margin, Point Conception to Point Loma

The U.S. Geological Survey conducted a series of cruises, EEZSCAN 84 (EEZ-SCAN 84 Scientific Staff, 1986), to collect reconnaissance data on the newly proclaimed Exclusive Economic Zone (EEZ), the area out to 200 nautical miles from the coastline of the United States. The cruises systematically surveyed the entire conterminous United States west coast EEZ using the Geological Long-Range Inclined Asdic (GLORIA) side-scan sonar, a 160-in 3 airgun seismic-reflection profiler, a 3.5-kHz high-resolution seismic-reflection profiler, a 10-kHz echo sounder, and a proton-precession magnetometer. The nominal trackline spacing throughout the survey was 30 km. Derivative maps of sediment thickness (I-2089-A, I-2090-A, I-2091-A) and depth to basement (I-2089-B, I-2090-B, I-2091-B) in the basins of the west coast EEZ were compiled from both the sonar-image dala and the deep-penetration seismic data obtained on these cruises. Only EEZ-SCAN 84 data were used for the map compilations because available data from other cruises in this region are sparsely located, have poor navigational control, or were obtained with seismic systems that were not powerful enough to resolve oceanic basement. For this map series, sediment thickness and depth to basement were determined only in the deep-ocean basin regions because the seismic system used on the EEZ-SCAN 84 cruises could not resolve oceanic basement beneath the thick sediments of the continental slope. All the data used to compile the maps are presented in the "Atlas of the Exclusive Economic Zone, Western Conterminous United States" (EEZ-SCAN 84 Scientific Staff, 1986). Basement Outcrops GLORIA imagery was used to locate areas of basement outcrop throughout the region. Where possible, sediment thickness on and immediately adjacent to basement outcrops was measured from seismic data. Where there was no bathymetric or seismic control, a seamount peak was assumed to have no sediment cover. A pattern is used on the map to indicate all basement outcrops. Data Reduction Acoustic basement in the basins, invariably oceanic Layer 2, was observed on all of the seismic records. One-way traveltime was measured from the sea floor to acoustic basement. Because the trackline spacing of about 30 km is relatively large compared to the data density along track, we chose to measure the sediment thickness every 0.5 hour or at an interval of approximately 7.5 km. Water depth was measured with a 10-kHz profiler. Depth to basement was calculated using the sea surface as the zero datum and adding the corrected water depth (Carter, 1980) to the sediment thickness. Acoustic travel times were converted to depths by first calculating a regression equation from the interval velocity versus depth data of Connard and others (1984). Their data base comprises a compilation of all available Deep Sea Drilling Project data plus wide-angle refraction data, which were collected in Cascadia Basin west of Oregon and represents the best data set available for the United States west coast EEZ. The regression equation was integrated to determine sediment thickness as a function of one-way traveltime . The resulting equation is z = 1400t + 0 .5t 2 where z is sediment thickness in meters, and t is one-way traveltime in seconds. Sediment thicknesses calculated using this equation were compared to values calculated from the general equation of Carlson and others (1986). Values for sediment thickness calculated by the two equations differed by no greater than 10 percent throughout the range of travel times. Bathymetry The bathymetry is from Chase and others (1981). The bathymetric data were compiled from a variety of sources, and data quality is inconsistent. Because of differences in navigational precision and density of coverage, the bathymetric contours of a feature may be at a different location than the corresponding isopleths derived from the EEZ-SCAN 84 data, or a feature may not be indicated on the bathymetry at all. These situations occur because either the feature is poorly located in the bathymetric data set or, especially in the outer EEZ, the bathymetric data are too sparse to have defined the existence of a feature. Acknowledgments Topographic digital data bases were corrected and verified by Christina Lief. Gerald Evenden developed the computer software system MAPGEN, used to compose this map. Reviews, suggestions, and technical contributions from Edward C. Escowitz and Florence Wong and advice about cartographic design from Will Stettner substantially improved the quality of this map. References Cited Carlson, R.L., Gangi, A.F., and Snow, K.R., 1986, Empirical reflection-traveltime/ depth and velocity/depth functions for the deep-sea sediment column: Journal of Geophysical Research, v. 91, no. B8, p. 8249-8266. Carter, D.J.T., 1980, Echo-sounding correction tables: Taunton, United Kingdom, Hydrographic Department, Ministry of Defence, 150 p. Chase, T.E., Wilde, Pat, Normark, W.R, Miller, C.P., Seekins, B.A., and Young, J.D., 1981, Offshore topography of the Western United States between 32&deg; and 49&deg; North latitudes: U.S. Geological Survey Open-File Report 81-443, scale 1:864,518 at 38&deg; latitude, 2 sheets. Connard, G., Couch, R., Keeling , K., Roy, J., and Troseth, S., 1984, Abyssal plain and continental net-objective sedimentary thicknesses, in Kulm, L.D., and others, eds., Western North America continental margin and adjacent ocean floor off Oregon and Washington, Atlas 1 of Regional Atlas Series, Ocean Margin Drilling Program: Woods Hole, Mass., Marine Science International, sheet 7. EEZ-SCAN 84 Scientific Staff, 1986, Atlas of the Exclusive Economic Zone, Western Conterminous United States: U.S. Geological Survey Miscellaneous Investigations Series I-1792, scale 1:500,000, 152 p. index map for I-2089-A See Also "U.S. Pacific West Coast Field Activities" (Paskevich and others, 2011; http://pubs.usgs.gov/of/2010/1332/htmldocs/pc/pc_overview.html). Paskevich, V.F., Wong, F.L., O?Malley, J.J., Stevenson, A.J., and Gutmacher, C.E., 2011, GLORIA sidescan-sonar imagery for parts of the U.S. Exclusive Economic Zone and adjacent areas: U.S. Geological Survey Open-File Report 2010?1332, available at http://pubs.usgs.gov/of/2010/1332/.

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