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An evaluation of the effects of different deicing salt application rates on three watersheds in Essex County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Transportation, evaluated the effects of different deicing salt application rates on surface water, groundwater, and highway runoff quality near State highways in northern New York. Three reaches of State highways were tested with different deicing treatments between October 2019 and November 2022: a salt-sand mixture (Treatment A), a salt mixture applied at a lower rate (Treatment B), and a control mixture consistent with typical deicing salt amounts and application rates. Data on pavement conditions and the quality of surface water, highway runoff, and groundwater were collected. Surface electromagnetic data were also collected. Surface-water and groundwater quality downgradient from the State highways were compared with water quality at upgradient locations. The percentage of snow or ice coverage was used to evaluate the effectiveness of the salt applications. This report provides an overview of the transport of deicing salt. The Treatment B watershed had deicing mixture applied more frequently than other highway reaches, which caused it to have the highest annual total chloride application. Despite differences in chloride application, flow-weighted mean chloride concentrations in highway runoff were comparable across treatments. Chloride concentrations were elevated in surface water and groundwater downgradient from highways relative to chloride concentrations upgradient from highways. A chloride mass balance, calculated for one treatment watershed, indicated that groundwater affected by legacy deicing practices may be contributing additional chloride to surface water. Spatial patterns from electromagnetic surveys show a shallow saline plume alongside the highway in that area. Differences in winter severity and pavement-surface conditions drove deicing salt applications in the treatment areas. This study found that several factors affect chloride loads in the watersheds, including variable winter conditions, adaptive snow and ice management, legacy management practices, and area-specific aquifer and groundwater conditions.

New York

Earthquake magnitude and source parameter estimation with a distributed acoustic sensing dataset in the Gorda subduction zone

Distributed acoustic sensing (DAS) systems offer a cost‐effective way to create large‐scale strainmeter arrays for seismological applications using fiber‐optic cables. DAS‐based strain measurements are known to be influenced by various factors, bringing into question their general reliability for accurate earthquake characterization. A 15‐km‐long DAS deployment in northern California was operational within 3 days of the 2022 M w 6.4 Ferndale earthquake and ran continuously throughout the aftershock sequence. We utilize these aftershock data to validate DAS‐based strain measurements in two ways. We first test the accuracy of DAS‐based magnitude estimates from peak dynamic strains by comparing them with magnitude and attenuation scaling relations derived independently from traditional borehole strainmeter (BSM) data. We demonstrate that DAS‐based magnitudes are comparable to BSM‐based magnitudes when corrections for variations in site response along the fiber‐optic cable are properly made. Magnitude errors are spatially correlated, potentially because of factors such as finite‐fault effects (e.g., stress drop) or more complex, unmodeled path attenuation or because of wave propagation effects in heterogeneous media. We then apply more advanced source characterization methodology to the DAS data using a time‐domain empirical Green’s function (EGF) deconvolution approach to measure details of the moment rate history. The EGF approach using DAS data depends on careful treatment of distorting factors such as anthropogenic sources of noise and optical phase wrapping but successfully isolates source spectra for moderate‐magnitude earthquakes: source spectral ratios obtained from DAS data, broadband seismometer data, and BSM data in the same region show consistent results, revealing differences in directivity and spectral shape among earthquakes. Although further research is needed to refine source‐time‐function estimation techniques for DAS data, particularly for larger magnitude events, these case studies demonstrate the clear potential of DAS for earthquake source characterization.

California

Prediction of regional broadband strong ground motions using a teleseismic source model of the 18 April 2014 Mw 7.3 Papanoa, Mexico, earthquake

To estimate predicted ground motion from a teleseismic slip model, we use a low‐ and high‐frequency hybrid method to simulate the regional, strong ground motions observed following the 18 April 2014 moment magnitude ( ⁠M w ⁠ ) 7.3 Papanoa, Mexico, earthquake. To generate the regional ground motion at low frequencies (<1 Hz), a teleseismically derived, finite‐fault, kinematic model is used to define the earthquake source, taking into account slip‐model variations identified with a parameter sampling approach that considers possible errors in the fault geometry, the hypocenter depth, and the rupture velocity. A 3D crustal model is used to calculate the low‐frequency ground motions using a finite‐element calculation that includes topography and considers variations in the source model to estimate the uncertainty in the calculations. High frequencies (>1 Hz) are added using a 1D full‐wave propagation code that estimates uncertainties by considering multiple random distributions of slip with different spatial correlation lengths. The synthetic, broadband (0.05–10.0 Hz) ground motions are obtained by combining the low‐ and high‐frequency portions match filtered at 1 Hz. These synthetic ground motions are compared with the regional observations using velocity records, peak ground acceleration, and medians of the orientation‐independent response spectra of the horizontal components (RotD50) calculated at periods of 0.2, 0.3, 0.5, 1.0, 2.0, 3.0, 5.0, 7.5, and 10.0 s. The results indicate that ground motions estimated at these periods using our hybrid approach based primarily on a teleseismically derived source model are comparable to the values observed for the 2014 Papanoa earthquake at regional distances. The approach could be used to estimate strong‐motion spectral levels expected for regions with limited local and regional recordings and could also fill in magnitude or distance gaps in ground‐motion prediction relations utilized in the assessment of seismic hazard.

Papanoa

Environmental monitoring of groundwater, surface water, and soil at the Ammonium Perchlorate Rocket Motor Destruction Facility at the Letterkenny Army Depot, Chambersburg, Pennsylvania, 2021

Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.

Pennsylvania

The δ13C signature of dissolved organic and inorganic carbon reveals complex carbon transformations within a salt marsh

Coastal wetlands have high rates of atmospheric CO 2 uptake, which is subsequently respired back to the atmosphere, stored as organic matter within flooded, anoxic soils, or exported to the coastal ocean. Transformation of fixed carbon occurs through a variety of subsurface aerobic and anaerobic microbial processes, and results in a large inventory of dissolved carbon. Carbon source and the roles of aerobic respiration, sulfate reduction, and methane cycling were evaluated within salt marsh peat and the underlying sandy subterranean estuary. There is a large increase in dissolved inorganic carbon (DIC, 7,350 ± 3,900 μmol L −1 ), dissolved organic carbon (DOC, 1,040 ± 1,480 μmol L −1 ) and CH 4 (14.5 ± 33.3 μmol L −1 ) within the marsh porewaters compared to creek waters. Alkalinity production (5,730 ± 2,170 μeq L −1 ) and sulfate removal (1,810 ± 1,970 μmol L −1 ) indicate anaerobic respiration, however, relative contributions from the various decomposition pathways cannot be identified due to overlapping geochemical signatures. The δ 13 C of the DOC (−29.0 ± 3.7‰) and DIC (−11.2 ± 1.1‰) produced within the marsh differed from the bulk soil organic matter δ 13 C (−14.5 ± 0.2‰). We explore a variety of mechanisms that could result in co-occurring depleted δ 13 C-DOC and enriched δ 13 C-DIC compared to the bulk soil organic carbon pool and salt marsh vegetation, including selective mineralization, production of δ 13 C-depleted bacterial biomass, and methane-derived DOC. While important questions remain about carbon cycling pathways, we found evidence of a cryptic methane cycle. Alteration of the δ 13 C of carbon species complicates source attribution in solid and dissolved phases and careful consideration should be used when carbon is partitioned between in situ salt marsh production and external marine and terrestrial sources.

Massachusetts

Efficient physics‐informed ground‐motion simulations with reduced‐order models: CyberShake implications and high‐resolution site terms for southern San Andreas fault earthquakes

Recent advances in Probabilistic Seismic Hazard Analysis (PSHA) leverage physics‐based ground‐motion simulations to estimate seismic hazard, such as the CyberShake project. However, computational costs quickly escalate when performing PSHA for numerous faults or sites and can become prohibitively expensive. To reduce computational demands, CyberShake uses reciprocity and interpolates physics‐informed corrections from simulations conducted at fewer locations, but the accuracy of these interpolations remains poorly quantified. To quantify the interpolation accuracy, we derive high‐resolution, frequency‐dependent site terms for southern California and compare them with interpolated site terms using the CyberShake approach. We accomplish this by performing a set of earthquake point‐source simulations distributed along the nonplanar fault geometry for the southern San Andreas fault (SSAF) extending from Bombay Beach to Lake Hughes. Using SeisSol, we simulate three minutes of viscoelastic seismic wave propagation for these sources and store the horizontal‐component Green’s functions for 480,000 sites. We then use a scientific machine learning approach based on interpolated proper orthogonal decomposition to construct an accurate reduced‐order model of the Green’s functions to efficiently predict effective amplitude spectra (EAS) for finite‐source rupture models of SSAF earthquakes. Using minimum curvature interpolation with tension, as used in CyberShake, we compare the interpolated site terms against our high‐resolution site terms. We identify local discrepancies with EAS differing by up to a factor of approximately three. Furthermore, we identify locations where unexpectedly high or low ground motions are missed when using the interpolated dataset for these earthquakes. We estimate that our approach may be used within CyberShake to reduce the time‐to‐solution by a factor of 336 for the entire earthquake rupture forecast. Our analysis of physics‐based site terms provides more insight into the seismic hazard due to SSAF ruptures and guides future developments by combining high‐performance computing and reduced‐order modeling techniques for PSHA.

California

Decomposing the Tea Bag Index and finding slower organic matter loss rates at higher elevations and deeper soil horizons in a minerogenic salt marsh

Environmental gradients can affect organic matter decay within and across wetlands and contribute to spatial heterogeneity in soil carbon stocks. We tested the sensitivity of decay rates to tidal flooding and soil depth in a minerogenic salt marsh using the Tea Bag Index (TBI). Tea bags were buried at 10 and 50 cm depths across an elevation gradient in a subtropical Spartina alterniflora marsh in Georgia (USA). Plant and animal communities and soil properties were characterized once, while replicate tea bags and porewaters were collected several times over 1 year. TBI decay rates were faster than prior litterbag studies in the same marsh, largely due to rapid green tea loss. Rooibos tea decay rates were more comparable to natural marsh litter, potentially suggesting that is more useful as a standardized organic matter proxy than green tea. Decay was slowest at higher marsh elevations and not consistently related to other biotic (e.g., plants, crab burrows) or abiotic factors (e.g., porewater chemistry), indicating that local hydrology strongly affected organic matter loss rates. TBI rates were 32 %–118 % faster in the 10 cm horizon than at 50 cm. Rates were fastest in the first 3 months and slowed 54 %–60 % at both depths between 3 and 6 months. Rates slowed further between 6 and 12 months, but this was more muted at 10 cm (17 %) compared to 50 cm (50 %). Slower rates at depth and with time were unlikely due to the TBI stabilization factor, which was similar across depths and decreased from 6 to 12 months. Slower decay at 50 cm demonstrates that rates were constrained by environmental conditions in the deeper horizon rather than the composition of this highly standardized litter. Overall, these patterns suggest that hydrological setting, which affects oxidant introduction and reactant removal and is often overlooked in marsh decomposition studies, may be a particularly important control on organic matter loss in the short term (3–12 months).

Georgia

Hyperspectral narrowband imaging spectroscopy: A new paradigm for Earth observation

This editorial introduces the Special Issue entitled “Hyperspectral Narrowband Imaging Spectroscopy: A New Paradigm for Earth Observation” in the August 2026 issue of Photogrammetric Engineering & Remote Sensing (PE&RS), the flagship journal of the American Society for Photogrammetry and Remote Sensing (ASPRS). This volume represents the fourth dedicated hyperspectral special issue published in PE&RS, following earlier contributions by Thenkabail et al. (2025, 2024a, 2024b), and continues ASPRS’s commitment to advancing cutting‑edge imaging spectroscopy research and its applications across Earth system science. Remote sensing is undergoing one of the most profound transformations in its history. The emergence of hyperspectral narrowband (HNB) imaging spectroscopy data, capable of acquiring hundreds of contiguous, narrow spectral bands, has shifted the discipline from observing Earth in a handful of broad spectral windows to capturing continuous spectral signatures of the Planet. This transition marks a decisive break from the multispectral paradigm that has dominated satellite remote sensing for nearly five decades, driven by the advent of new orbital imaging spectrometers such as EnMAP, PRISMA, and NASA’s EMIT, and by the forthcoming Surface Biology and Geology (SBG) mission ((Pires Silva et al., 2026; Bourriz et al., 2025; Thenkabail et al., 2025; Chabrillat et al., 2024; Aneece et al., 2024; Dave et al., 2024; Thenkabail et al., 2024a; Thenkabail et al., 2024b; Thenkabail, 2024a; Thenkabail, 2024b; Thompson et al., 2022; Kokaly et al., 2022; Aneece & Thenkabail, 2022; Cawse Nicholson et al., 2021; Guanter et al., 2021; Vangi et al., 2021; Thenkabail et al., 2021). These missions (e.g., Table 1) deliver unprecedented spectral fidelity, improved signal to noise ratios, and global coverage capabilities, enabling a new era of quantitative, spectroscopy based Earth observation. Where multispectral broadbands (MBBs) provide only a few discrete measurements along the electromagnetic spectrum, HNB systems deliver rich, diagnostic information that enables scientists to characterize Earth’s surface with unprecedented biochemical, biophysical, and structural detail (Figure 1a, 1b). The implications for environmental monitoring, agriculture, water resources, and mineral exploration are profound. Several overarching themes emerge: • Spectral fidelity matters. The ability to preserve subtle absorption features is essential for mineral mapping, vegetation trait retrieval, and biochemical modeling. • AI and deep learning are indispensable. From destriping to classification, modern analytics must be scalable, label‑efficient, and capable of exploiting the full spectral–spatial richness of HNB data. • Physics‑based and data‑driven approaches must converge. Radiative transfer models such as PROSAIL, enhanced with localized soil parameterizations, remain foundational for biophysical retrievals and model‑based inference. • Dimensionality reduction and feature extraction are critical. Techniques such as L1‑ISOMAP demonstrate that intelligent manifold learning can unlock the structure of fused, high‑dimensional datasets. • Next‑generation architectures must be interactive and multimodal. ICTNet exemplifies the future of hyperspectral classification: hybrid, synergistic, and capable of modeling both local textures and global spectral dependencies.

Photogrammetric Engineering and Remote Sensing (PE

Correction to A regime shift in sediment export from a coastal watershed during a record wet winter, California: Implications for landscape response to hydroclimatic extremes

In the referenced article, the authors would like to correct text in the first paragraph on page 2571, Figure 9 and its caption. The changes reflect an error made in the processing of the rainfall intensity-duration data used to compare storms to published debris flow triggering thresholds. The correctly processed data does not change the interpretations made in the paper but does correctly indicate that the investigated storms did not exceed the rainfall intensity – duration threshold of Cannon (1988) but did significantly exceed the debris flow triggering threshold of Wieczorek (1987).

Earth Surface Processes and Landforms

What do we know without the catalog? Eliciting prior beliefs from experts for aftershock models

Fitting parametric seismological models to earthquake catalogs often comes with numerical challenges, especially when catalogs are small. An alternative way to quantify parameter values for a seismic region is by eliciting expert opinions on the seismological characteristics that each parameter corresponds to. For instance, expert beliefs on aftershock patterns can be formulated into prior distributions for aftershock parameters, for example, for the epidemic‐type aftershock sequence (ETAS) model. We illustrate such a method by not only eliciting priors for ETAS parameters for the Pacific Northwest (PNW), a subduction zone with a complex tectonic environment, but also a relatively small catalog. We compare these priors with those suggested by the ETAS literature for global subduction zones, discussing implications for aftershock forecasting for the PNW.

The Seismic Record

Inference of pattern-based geological CO2 sequestration and oil recovery potential in a commingled main pay and residual oil zone CO2-EOR flood

Several detailed studies have shown that residual oil zones (ROZs) can present significant resources for additional hydrocarbon recovery as well as subsurface carbon dioxide (CO 2 ) sequestration via enhanced oil recovery by injecting CO 2 (CO 2 -EOR). Field development strategies included new wells drilled dedicated to main pay zones (MPZ) and ROZs, or existing wells in MPZs deepened to ROZs for commingled injection-production using different well patterns. The latter presented a challenge when discerning the injection and production from each of the zones, and for subsequent quantification of CO 2 sequestration and EOR potential from different patterns and from the field. In this paper, an innovative method for analyzing commingled injections and productions from MPZs and ROZs, with application to pattern-based data from four staggered line drive patterns in Wasson Field's Denver Unit, Texas, USA, was developed. Decline curve and ratio-trend methods were used as means of history-matching and forecasting. Cumulative production-time and cumulative production-rate data for oil, gas, and water, as well as water-oil ratio (WOR) and gas-oil ratio (GOR), were analyzed along with injection data for time intervals covering major injection events in MPZ, or MPZ and ROZ combined. A combined analysis enabled inference of allocation of fluids into different zones during WAG (water alternating gas) injection and thereby estimation of CO 2 storage, utilization, and retention in different zones as a function of total injection. Results show that ROZs generally present higher CO 2 sequestration potential compared to MPZs, and a comparable incremental oil recovery factor of ∼20%, on average. Results based on ratio analysis further show that while the WOR trend of the pattern production is mostly dominated and controlled by ROZ, GOR is controlled by both intervals. Although the method relying on decline curves and the approach used in zonal fluid allocations are subject to their limitations, this study presents a practical and innovative well-pattern-based method to infer and forecast CO 2 sequestration and oil recovery quantities and fluid ratios from MPZs and ROZs in commingled operations and highlight the added potential offered by ROZs.

Texas

Trace elements in streambed sediment and fish liver at selected sites in the Upper Colorado River Basin, Colorado 1995-96

Trace elements were analyzed in streambed-sediment samples collected from 16 sites and in fish-liver samples collected from 14 sites in the Upper Colorado River Basin in Colorado as part of the National Water-Quality Assessment program. Sites sampled represented agricultural, mining, mixed, and urban/recreation land uses and background conditions. The results for 15 trace elements in streambed-sediment and in fish-liver samples are presented in this report. Fourteen of the selected trace elements were detected in streambed-sediment samples collected at all sites. Twelve of the selected trace elements were detected in fish liver at more than 50 percent of the sites. Cadmium, copper, selenium, and zinc were selected for a more detailed analysis. Cadmium, copper, and zinc concentrations in streambed sediment were highest at mining land-use sites in the Southern Rocky Mountains physiographic province. Selenium concentrations in streambed sediment were highest at an agricultural land-use site in the Colorado Plateau physiographic province. The concentration of trace elements in streambed sediment generally increased as particle size decreased. Concentrations of trace elements in fish liver generally did not follow the same relation to land use as concentrations in streambed sediment; however, cadmium concentrations in fish liver were highest at a mining land-use site in the Southern Rocky Mountains physiographic province, and selenium concentrations in fish liver were highest at an agricultural land-use site in the Colorado Plateau physiographic province. Copper and zinc concentrations in fish liver were highest at mixed land-use sites. Comparison of streambed-sediment and fish-liver concentrations to two other similar NAWQA studies in the Rocky Mountain region generally indicated similar patterns in relation to land use for streambed sediment, but not for fish liver. Cadmium, copper, and zinc concentrations in streambed sediment were highest at sites affected by mining in all three study units. Selenium concentrations in streambed sediment did not indicate relations among the three study units when compared to land use. Cadmium in fish liver was highest at sites affected by mining in all three study units. Copper, selenium, and zinc in fish liver did not indicate relations among the three study units when compared to land use.

Colorado

Framework for implementing damping scaling factors in U.S. Geological Survey National Seismic Hazard Models

Traditionally, probabilistic seismic hazard analysis (PSHA) has focused on calculating ground motion hazard curves for elastic, 5%-damped pseudo spectral accelerations, Sa(T,5%), which are used as the basis for engineering design parameters and targets for ground motion selection and modification. However, structures and geotechnical systems can exhibit a wide range of damping ratios both above and below the 5% level, depending on the construction material, structural system, nonstructural elements, or subsurface soil properties. When spectral parameters at such damping levels are required for certain applications, 5%-damped accelerations have traditionally been extracted from PSHA-based hazard curves and adjusted outside of the hazard integral using damping scaling factors (DSF) such as those from Newmark & Hall (1982). Recent advances in the development of more rigorous and comprehensive damping scaling models (e.g., Rezaeian et al., 2014; Rezaeian et al., 2021) have allowed for the modeling of means and standard deviations of DSFs as functions of earthquake source and path properties for crustal, intraslab, and subduction interface tectonic environments. These DSF models can be applied to ground motion model (GMM) estimates of Sa(T,5%) for a given earthquake rupture scenario to produce a corresponding mean and standard deviation Sa at a specified damping ratio β, Sa(T,β). In this study, the DSF models of Rezaeian et al. (2014) and Rezaeian et al. (2021) are implemented within the U.S. Geological Survey National Seismic Hazard Model (NSHM) PSHA framework to calculate probabilistic hazard curves for spectral accelerations at damping ratios from 0.5% to 30%. The DSF models are applied directly to the mean and standard deviation of Sa(T,5%) predictions from each GMM in the NSHM logic tree. Resulting hazard curves and uniform hazard and risk spectra for Sa(T,β) are presented for several geographic locations and compared with corresponding spectra estimated using current design practices by applying the same DSFs outside of the PSHA calculation. Key differences between the two methods for estimating Sa(T,β) are discussed, and potential strategies are presented for the implementation and usage of the hazard-consistent Sa(T,β) in building codes. Comparing the results to those from DSFs used in current design practices that are mainly based on Newmark & Hall (1982) is not explored in this study.

Conference Paper

Current status of the community sensor model standard for the generation of planetary digital terrain models

The creation of accurate elevation models (topography) from stereo images are critical for a large variety of geospatial activities, including the production of digital orthomosaics, change detection, landing site analysis, geologic mapping, rover traverse planning, and spectral analysis. The United Stated Geological Survey, Astrogeology Science Center, continues to transition the supported planetary sensor models to the Community Sensor Model (CSM) standard. This paper describes the current state of use for this photogrammetric standard, supported sensor model types, and qualitatively compares derived topography between SOCET SET and SOCET GXP ( ® BAE Systems) using HiRISE stereo images of Mars. Our transition to the CSM standard will ensure an uninterrupted capability to make these valuable products for Mars and many other extraterrestrial planets and moons.

Remote Sensing

State shifts in the deep Critical Zone drive landscape evolution in volcanic terrains

Understanding the near-surface environment where atmospheric and solid earth processes interact, often termed the “Critical Zone,” is important for assessing resources and building resilient societies. Here, we examine a volcanic landscape in the Oregon Cascade Range, an understudied Critical Zone setting that is host to major regional water resources, pervasive silicate weathering, and significant geohazards. We leverage a bedrock age chronosequence to show that the volcanic Critical Zone undergoes a structural shift, from depth extents of >1 km to meters, over timescales of ~1 My. We map an active groundwater volume comparable to major continental lakes, stored at the Cascade Range crest. This state shift makes volcanic landscape evolution a unique probe of deep coupling between Earth systems.

PNAS

Monthly variability and possible sources of nitrate in ground water beneath mixed agricultural land use, Suwannee and Lafayette Counties, Florida

In an area of mixed agricultural land use in Suwannee and Lafayette Counties of northern Florida, water samples were collected monthly from 14 wells tapping the Upper Floridan aquifer during July 1998 through June 1999 to assess hydrologic and land-use factors affecting the variability in nitrate concentrations in ground water. Unusually high amounts of rainfall in September and October 1998 (43.5 centimeters total for both months) resulted in an increase in water levels in all wells in October 1998. This was followed by unusually low amounts of rainfall during November 1998 through May 1999, when rainfall was 40.7 centimeters below 30-year mean monthly values. The presence of karst features (sinkholes, springs, solution conduits) and the highly permeable sands that overlie the Upper Floridan aquifer provide for rapid movement of water containing elevated nitrate concentrations to the aquifer. Nitrate was the dominant form of nitrogen in ground water collected at all sites and nitrate concentrations ranged from less than 0.02 to 22 milligrams per liter (mg/L), as nitrogen. Water samples from most wells showed substantial monthly or seasonal fluctuations in nitrate concentrations. Generally, water samples from wells with nitrate concentrations higher than 10 mg/L showed the greatest amount of monthly fluctuation. For example, water samples from six of eight wells had monthly nitrate concentrations that varied by at least 5 mg/L during the study period. Water from most wells with lower nitrate concentrations (less than 6 mg/L) also showed large monthly fluctuations. For instance, nitrate concentrations in water from four sites showed monthly variations of more than 50 percent. Large fluctuations in nitrate concentrations likely result from seasonal agricultural practices (fertilizer application and animal waste spreading) at a particular site. For example, an increase in nitrate concentrations observed in water samples from seven sites in February or March 1999 most likely results from application of synthetic fertilizers during the late winter months. Lower nitrate concentrations were detected in water samples from five of eight wells sampled during high-flow conditions for the Suwannee River in March 1998 compared to low-flow conditions in November 1998. Evidence for reduction of nitrate due to denitrification reactions was observed at one site (AC-1), as indicated by elevated concentrations of nitrogen gas and a corresponding increase in nitrogen isotope (d15N-NO3) values with a decrease in nitrate concentrations. Denitrification is unlikely at other sites based on the presence of dissolved oxygen concentrations greater than 2 mg/L in ground water and no observed trend between nitrate concentrations and values d15N-NO3 values. Nitrate was the dominant nitrogen species in most monthly rainfall samples; however, ammonium concentrations were similar or greater than nitrate during November and December 1998. During February through May 1999, both nitrate and ammonium concentrations were substantially higher in monthly rainfall samples collected at the study area compared to mean monthly concentrations at the Bradford Forest site located east of the study area, which is part of the National Atmospheric Deposition Program/National Trends Network. Also, higher nitrogen deposition rates in the study area compared to those at Bradford Forest could indicate that substantial amounts of ammonia are volatilized from fertilizers and animal wastes, released to the atmosphere, and incorporated as nitrate and ammonium in rainfall deposited in the middle Suwannee River Basin. Ground-water samples from most sites had d15N-NO3 values that indicated a mixture of inorganic and organic sources of nitrogen, which corresponded to multiple land uses where both synthetic fertilizers and manure are used on fields near these sites. Distinct d15N-NO3 signatures, however, were observed at some sites. For example, water samples from areas of row-crop farming as the dominant land use had d15N-NO3 values less than 4 per mil, indicating an inorganic nitrogen source such as synthetic fertilizer. In contrast, d15N-NO3 values greater than 9 per mil were found in water samples from three sites where manure from dairy and or poultry operations is spread on fields throughout the year.

Florida

Ground-water quality atlas of Oakland County, Michigan

The U.S. Geological Survey (USGS), in cooperation with Oakland County Health Division (OCHD), collected 140 water samples from 38 wells in Oakland County during 1998 to better understand ground-water quality. OCHD had observed temporal variations in concentrations of various constituents, so two additional sets of samples were collected to evaluate potential short-term variability related to sample collection procedures and long-term seasonal variability. Replicate samples from 28 wells were analyzed in the Michigan Department of Environmental Quality (MDEQ) Drinking Water Laboratory to compare MDEQ&rsquo;s analytical results to those obtained from the USGS National Water Quality Laboratory. Several additional databases describing population, land use, water supply, soils, geology, and flows of ground water and surface water are presented in the first part of the report to assist in interpreting the water-quality data. Maps created from these databases are provided in the first portion of the report as an extension of the study-area description. The U.S. Environmental Protection Agency (USEPA) has established Maximum Contaminant Levels (MCL) and Secondary Maximum Contaminant Levels (SMCL) for which samples were analyzed in this study. Water from the 38 wells sampled by the USGS did not exceed the SMCL or MCL for sulfate, fluoride, or nitrite. However, water from 26 wells exceeded the SMCL for iron, water from 12 wells exceeded the SMCL for manganese, and water from 12 wells exceeded the SMCL for dissolved solids. Water from two wells exceeded the MCL for nitrate, although nitrate concentrations in water from most wells was below the detection limit. Water from seven wells exceeded the SMCL for chloride, and water from all wells contained detectable concentrations of chloride. Water from five wells exceeded the MCL for arsenic, and most of the wells sampled contained detectable concentrations of arsenic. These five wells were identified from previous MDEQ analyses to have elevated arsenic concentrations, and were sampled to obtain additional chemistry information. Replicate samples were collected from 26 of the 38 wells for analysis at the MDEQ Drinking-Water Laboratory to compare the results with the USGS National Water Quality Laboratory. The results of the replicate analyses indicate close agreement between the laboratories, with mean differences for nitrate, chloride, and arsenic of 0.10 milligrams per liter (mg/L) as nitrogen, 6.8 mg/L, and 0.0008 mg/L, respectively between the USGS and MDEQ analyses. Potential health effects associated with ingesting nitrate, chloride, and arsenic are provided with the water-quality data, along with references for further information.

Michigan

Time varying crustal anisotropy at Whakaari/White Island volcano

Whakaari/White Island has been the most active New Zealand volcano in the 21st century, producing small phreatic and phreatomagmatic eruptions, which are hard to predict. The most recent eruption occurred in 2019, tragically claiming the lives of 22 individuals and causing numerous injuries. We employed shear-wave splitting analyses to investigate variations in anisotropy during quiescence, unrest, and an eruption between 2018 and 2020. We examined spatial and temporal variations in 7972 shear-wave splitting measurements and derived 1402 V p /IV s ratio measurements. Comparing shear-wave splitting parameters from similar earthquake paths across different times indicates that the observed temporal changes are unlikely to result from variations in earthquake paths through media with spatial variability. Instead, these changes may stem from variations in anisotropy over time, likely caused by changes in crack alignment due to stress or varying fluid content.

Whakaari/White Island volcano