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Magmatic processes that generated the rhyolite of Glass Mountain, Medicine Lake volcano, N. California

Glass Mountain consists of a 1 km 3 , compositionally zoned rhyolite to dacite glass flow containing magmatic inclusions and xenoliths of underlying shallow crust. Mixing of magmas produced by fractional crystallization of andesite and crustal melting generated the rhyolite of Glass Mountain. Melting experiments were carried out on basaltic andesite and andesite magmatic inclusions at 100, 150 and 200 MPa, H 2 O-saturated with oxygen fugacity controlled at the nickel-nickel oxide buffer to provide evidence of the role of fractional crystallization in the origin of the rhyolite of Glass Mountain. Isotopic evidence indicates that the crustal component assimilated at Glass Mountain constitutes at least 55 to 60% of the mass of erupted rhyolite. A large volume of mafic andesite (2 to 2.5 km 3 ) periodically replenished the magma reservoir(s) beneath Glass Mountain, underwent extensive fractional crystallization and provided the heat necessary to melt the crust. The crystalline residues of fractionation as well as residual liquids expelled from the cumulate residues are preserved as magmatic inclusions and indicate that this fractionation process occurred at two distinct depths. The presence and composition of amphibole in magmatic inclusions preserve evidence for crystallization of the andesite at pressures of at least 200 MPa (6 km depth) under near H 2 O-saturated conditions. Mineralogical evidence preserved in olivine-plagioclase and olivine-plagioclase-high-Ca clinopyroxene-bearing magmatic inclusions indicates that crystallization under near H 2 O-saturated conditions also occurred at pressures of 100 MPa (3 km depth) or less. Petrologic, isotopic and geochemical evidence indicate that the andesite underwent fractional crystallization to form the differentiated melts but had no chemical interaction with the melted crustal component. Heat released by the fractionation process was responsible for heating and melting the crust.

California

Geologic and hydrologic data collected at test holes NC-4 and NC-14, Manati and Vega Baja, Puerto Rico

Test holes NC-4 and NC-14 were drilled in the municipalities of Manati and Vega Baja, respectively, in northern Puerto Rico as part of a study of the ground-water resources in the Northern Coastal Province of Puerto Rico. This study was conducted from 1986 to 1988 by the U.S. Geological Survey in cooperation with the Puerto Rico Department of Natural Resources. Test holes NC-4 and NC-14 were drilled to depths of 1,898 and 1,837 feet below land surface, respectively. Geologic and hydrologic data collected during drilling included continuous core lithology, water-quality measurements, water levels, and estimates of aquifer yields from the water-bearing zones. Detailed petrological and microfaunal analyses of the cores were used to determine the mineralogical content, ages, and paleoenvironments of deposition. Analysis of the core recovered from test hole NC-4 indicated that four geologic formations of middle Tertiary age were penetrated, these were in descending order: the Aymam6n Limestone, the Los Puertos Limestone, the Cibao Formation, and the Lares Limestone. The Tertiary formations are capped by surficial deposits of Quaternary age. Test hole NC-14 penetrated rocks of middle Tertiary age that included three geologic formations, these were in descending order: the AymamOn Limestone, the Los Puertos Limestone, and the Cibao Formation. These formations are overlain by surficial deposits of Quaternary age. In both test holes the Cibao Formation consisted of the undifferentiated Quebrada Arenas and the Rio Indio Limestone Members of the Cibao Formation and an unnamed mudstone unit. Test hole NC-4 penetrated three water-bearing units: a water-table aquifer and two artesian aquifers. The specific conductance in the water-table aquifer ranged from 500 to 38,000 microsiemens per centimeter at 25 degrees Celsius. The specific conductance ranged from 740 to 800 microsiemens per centimeter at 25 degrees Celsius in the two artesian aquifers. The relative yield ranged from 120 to 195 gallons per minute in the water-table aquifer and from 60 to 195 gallons per minute in the artesian aquifers. The water level ranged from 81 to 89 feet below land surface in the water-table aquifer. In the artesian aquifers, water levels ranged from 22 feet below land surface to 88 feet above land surface. Test hole NC-14 penetrated four water-bearing units: a water-table aquifer and three artesian aquifers. The specific conductance in the water-table aquifer ranged from 590 microsiemens per centimeter at 25 degrees Celsius at a depth of 40 feet to 49,500 microsiemens per centimeter at 25 degrees Celsius at 1,010 feet below land surface. In the artesian aquifers specific conductance was about 700 microsiemens per centimeter at 25 degrees Celsius. The relative yield ranged from 58 to 370 gallons per minute in the water-table aquifer, and from 15 to 60 gallons per minute in the artesian aquifers. The water level in the water table aquifer ranged from 20 to 32 feet below land surface. In the artesian aquifers the water levels ranged from 18 feet below land surface to 19 feet above land surface.

Open-File Report

Petrologic and mineral physics database for use with the U.S. Geological Survey National Crustal Model

We present a petrologic and mineral physics database as part of the U.S. Geological Survey National Crustal Model (NCM). Each of 209 geologic units, 134 of which are currently part of the geologic framework within the NCM, was assigned a mineralogical composition according to generalized classifications with some refinement for specific geologic formations. This report is concerned with the petrology and mineral physics of each geologic unit within the NCM, which control the physical behavior of the solid mineral matrix within the rock. This mineral physics database builds on the work of Abers and Hacker to include 13 minerals specific to continental rock types. We explored the effect of this database on zero-porosity anharmonic P- and S-wave rock velocities and density relative to a well-used empirical study of relations between wavespeeds and density by Brocher. We found that empirical relations between P-wave velocity and S-wave velocity or density do well on average but can differ from mineral physics calculations by up to 15 percent in S-wave velocity and almost 40 percent in density. This is consistent with Brocher’s study where he obtained similar results for in situ measurements and laboratory rock specimens. Additionally, the substantial presence of quartz in many rocks plays a major role in crustal seismic velocities and density due to quartz’s α – β phase transition, which can interfere with these empirical relationships. With increasing depth, quartz P-wave velocity can suddenly jump by 15 percent accompanied by little change in S-wave velocity and a modest decrease in density. Empirical relations based on observed P-wave velocity where P-wave velocity is positively correlated with S-wave velocity and density would then significantly overestimate both S-wave velocity and density.

Open-File Report

Layered intrusions in the Precambrian: Observations and perspectives

Layered intrusions are plutonic bodies of cumulates that form by the crystallization of mantle-derived melts. These intrusions are characterized by igneous layering distinguishable by shifts in mineralogy, texture, or composition. Layered intrusions have been fundamental to our understanding of igneous petrology; however, it is their status as important repositories of critical metals – such as platinum-group elements, chromium, and vanadium – that has predominantly driven associated research in recent decades. Many layered intrusions were emplaced during the Precambrian, predominantly at the margins of ancient cratons during intervals of supercontinent accretion and destruction. It appears that large, layered intrusions require rigid crust to ensure their preservation, and their geometry and layering is primarily controlled by the nature of melt emplacement. Layered intrusions are best investigated by integrating observations from various length-scales. At the macroscale, intrusion geometries can be discerned, and their presence understood in the context of the regional geology. At the mesoscale, the layering of an intrusion may be characterized, intrusion-host rock contact relationships studied, and the nature of stratiform mineral occurrences described. At the microscale, the mineralogy and texture of cumulate rocks and any mineralization are elucidated, particularly when novel microtextural and mineral chemical datasets are integrated. For example, here we demonstrate how mesoscale observations and microscale datasets can be combined to understand the petrogenesis of the perplexing snowball oiks outcrop located in the Upper Banded Series of the Stillwater Complex. Our data suggest that the orthopyroxene oikocrysts did not form in their present location, but rather formed in a dynamic magma chamber where crystals were transported either by convective currents or within crystal-rich slurries. Critical metals may be transported to the level of a nascent intrusion as dissolved components in the melt. Alternatively, ore minerals are entrained from elsewhere in a plumbing system, potentially facilitated by volatile-rich phases. There are many ore-forming processes propounded by researchers to occur at the level of emplacement; however, each must address the arrival of the ore mineral, its concentration of metals, and its accumulation into orebodies. In this contribution, several of these processes are described as well as our perspectives on the future of layered intrusion research.

Precambrian Research

Studies of pre-Selma Cretaceous core samples from the outcrop area in western Alabama

In 1954 four core holes were drilled in the pre-Selma Cretaceous strata of the Alabama Coastal Plain in order to get unweathered samples within a few miles of the outcrops. During the next few years several specialists studied the cores, and their reports are published as consecutive parts of this bulletin. Watson H. Monroe, who spent many years studying the Coastal Plain strata in Alabama and Mississippi, conceived and supervised the drilling and planned the later studies. His earlier published report (W. H. Monroe, 1955, Cores of pre-Selma Cretaceous rocks in the outcrop area in western Alabama: Gulf Coast Geol. Societies Trans., v. 5, p. 11-37) contains a brief description of the stratigraphy, together with logs and other information regarding the core holes, and he has provided the introductory chapter to this bulletin. Richard E. Bergenback studied the petrology of the cores, which included finding the distribution of grain sizes, determining the mineralogy of the grains and the matrix of the sediments, and having X-Ray identifications made of the clay minerals. Norman F. Sohl studied the mollusks and other large fossils obtained from the cores and compared them with other faunal suites collected in Alaban1a and Texas. Esther R. Applin studied the sparse microfauna, comparing it with faunas obtained from deep wells downdip in Georgia, Alabama, and Mississippi and with outcrop samples fron1 Texas, and has described a new species of Foraminifera. Estella B. Leopold and Helen M. Pakiser obtained a large pollen and spore assemblage by digesting carbonaceous layers of some of the cores in acid; this flora includes much new material, which is not described here. The Bergenback, Sohl, and Applin reports discuss the probable environment in which the sediments accumulated. Louis C. Conant, who spent several years studying and mapping these sediments, has written a summary chapter integrating some of the surface and subsurface information. Quarter-cuts of the cores belonging to the U.S. National Museum have been deposited on indefinite loan with the Alabama Geological Survey at University, Ala., and with the Shell Oil Co. at Jackson, Miss. They are available there for inspection and study.

Bulletin

Pore-types and pore-network evolution in Upper Devonian-Lower Mississippian Woodford and Mississippian Barnett mudstones: Insights from laboratory thermal maturation and organic petrology

Pore-evolution models from immature organic-matter (OM) -rich Barnett (0.42%R o ) and Woodford (0.49%R o ) mudstones were compared with models previously developed from low-maturity OM-lean Boquillas (Eagle Ford-equivalent) mudstones to investigate whether (1) different mineralogy (siliceous vs. calcareous) exerts different catalytic and sorption effects and influences OM-pore origin and evolution; and (2) different types of macerals show different OM pore evolution history. Laboratory gold-tube pyrolysis, scanning electron microscopy (SEM) and thin-section petrography, organic petrography, and geochemical characterization were used to investigate the role of bulk mineralogy, maceral type, and thermal maturation on OM-pore evolution. Results suggest that mineralogy has little impact on OM-pore development and evolution. Macerals, identified using both SEM (platy OM, particulate OM, organic–mineral admixtures, Tasmanites ) and organic petrology (vitrinite, inertinite, amorphous organic matter [AOM]/bituminite, telalginite [ Leiosphaeridia , Tasmanites ]), do affect the origin and evolution of OM pores owing to differences in chemical compositions, generation kinetics, and activation-energy distributions between Tasmanites , matrix bituminite, and other types of macerals. Leiosphaeridia and Tasmanites in Woodford mudstone samples exhibit a delay in onset and a shorter period of petroleum generation and pore development compared to the matrix bituminite in the Barnett and Woodford mudstone samples. Pre-oil solid bitumen was observed to have migrated into initial primary mineral pore networks at the bitumen generation stage in both Barnett and Woodford samples. At higher levels of thermal maturation, the volume of primary mineral pores decreases and the pore volume composed of modified mineral pores and OM pores becomes greater. Pore evolution and pore-type heterogeneity in these mudstones is a function of the initial mineral pore network, types of kerogen and macerals, and generation kinetics of individual macerals upon thermal maturation.

Oklahoma

Petrology of unshocked crystalline rocks and shock effects in lunar rocks and minerals

On the basis of rock modes, textures, and mineralogy, unshocked crystalline rocks are classified into a dominant ilmenite-rich suite (subdivided into intersertal, ophitic, and hornfels types) and a subordinate feldspar-rich suite (subdivided into poikilitic and granular types). Weakly to moderately shocked rocks show high strain-rate deformation and solid-state transformation of minerals to glasses; intensely shocked rocks are converted to rock glasses. Data on an unknown calcium-bearing iron metasilicate are presented.

Science

Late Pleistocene ages for the most recent volcanism and glacial-pluvial deposits at Big Pine volcanic field, California, USA, from cosmogenic 36 Cl dating

The Big Pine volcanic field is one of several Quaternary volcanic fields that poses a potential volcanic hazard along the tectonically active Owens Valley of east-central California, and whose lavas are interbedded with deposits from Pleistocene glaciations in the Sierra Nevada Range. Previous geochronology indicates an ∼1.2 Ma history of volcanism, but the eruption ages and distribution of volcanic products associated with the most-recent eruptions have been poorly resolved. To delimit the timing and products of the youngest volcanism, we combine field mapping and cosmogenic 36 Cl dating of basaltic lava flows in the area where lavas with youthful morphology and well-preserved flow structures are concentrated. Field mapping and petrology reveal approximately 15 vents and 6 principal flow units with variable geochemical composition and mineralogy. Cosmogenic 36 Cl exposure ages for lava flow units from the top, middle, and bottom of the volcanic stratigraphy indicate eruptions at ∼17, 27, and 40 ka, revealing several different and previously unrecognized episodes of late Pleistocene volcanism. Olivine to plagioclase-pyroxene phyric basalt erupted from several vents during the most recent episode of volcanism at ∼17 ka, and produced a lava flow field covering ∼35 km 2 . The late Pleistocene 36 Cl exposure ages indicate that moraine and pluvial shoreline deposits that overlie or modify the youngest Big Pine lavas reflect Tioga stage glaciation in the Sierra Nevada and the shore of paleo-Owens Lake during the last glacial cycle.

Geochemistry, Geophysics, Geosystems

Characterization and petrologic interpretation of olivine-rich basalts at Gusev Crater, Mars

Rocks on the floor of Gusev crater are basalts of uniform composition and mineralogy. Olivine, the only mineral to have been identified or inferred from data by all instruments on the Spirit rover, is especially abundant in these rocks. These picritic basalts are similar in many respects to certain Martian meteorites (olivine-phyric shergottites). The olivine megacrysts in both have intermediate compositions, with modal abundances ranging up to 20-30%. Associated minerals in both include low-calcium and high-calcium pyroxenes, plagioclase of intermediate composition, iron-titanium-chromium oxides, and phosphate. These rocks also share minor element trends, reflected in their nickel-magnesium and chromium-magnesium ratios. Gusev basalts and shergottites appear to have formed from primitive magmas produced by melting an undepleted mantle at depth and erupted without significant fractionation. However, apparent differences between Gusev rocks and shergottites in their ages, plagioclase abundances, and volatile contents preclude direct correlation. Orbital determinations of global olivine distribution and compositions by thermal emission spectroscopy suggest that olivine-rich rocks may be widespread. Because weathering under acidic conditions preferentially attacks olivine and disguises such rocks beneath alteration rinds, picritic basalts formed from primitive magmas may even be a common component of the Martian crust formed during ancient and recent times.

Journal of Geophysical Research E: Planets

Opaque minerals as aids in distinguishing between source and sorting effects on beach sand mineralogy in southwestern Oregon

Both source area and wave sorting affect the heavy-mineral distributions of beach sands. Although source and sorting effects are difficult to distinguish, they can be separated on four Oregon beaches by studying the magnetic fraction of the sand. Prominent headlands bound the four beaches, which are located on the southwestern Oregon coast. On three beaches the percentage of magnetite in the sand from the upper swash zone consistently increases toward the north end of each beach, apparently owing to selective sorting during littoral transport. However, the percentages of chromium and titanium in the magnetite are generally independent of the relative location of the samples along the beach and therefore independent of sorting effects. Each beach appears to be characterized by a fairly distinct range of Ti/Cr in the magnetic fraction, and the range differs from beach to beach. The magnetite percentage and the Ti/Cr range suggest that sorting and source effects can be distinguished on beaches rich in "black" sands, and that sand transport around headlands in this area is not extensive enough to mask source differences. The results of this study suggest that sorting and source effects can be distinguished wherever there are chemical or mineralogical differences in a restricted density fraction.

Journal of Sedimentary Petrology

Late Holocene volcanism at Medicine Lake Volcano, northern California Cascades

Late Holocene volcanism at Medicine Lake volcano in the southern Cascades arc exhibited widespread and compositionally diverse magmatism ranging from basalt to rhyolite. Nine well-characterized eruptions have taken place at this very large rear-arc volcano since 5,200 years ago, an eruptive frequency greater than nearly all other Cascade volcanoes. The lavas are widely distributed, scattered over an area of ~300 km 2 across the >2,000-km 2 volcano. The eruptions are radiocarbon dated and the ages are also constrained by paleomagnetic data that provide strong evidence that the volcanic activity occurred in three distinct episodes at ~1 ka, ~3 ka, and ~5 ka. The ~1-ka final episode produced a variety of compositions including west- and north-flank mafic flows interspersed in time with fissure rhyolites erupted tangential to the volcano’s central caldera, including the youngest and most spectacular lava flow at the volcano, the ~950-yr-old compositionally zoned Glass Mountain flow. At ~3 ka, a north-flank basalt eruption was followed by an andesite eruption 27 km farther south that contains quenched basalt inclusions. The ~5-ka episode produced two caldera-focused dacitic eruptions. Quenched magmatic inclusions record evidence of intrusions that did not independently reach the surface. The inclusions are present in five andesitic, dacitic, and rhyolitic host lavas, and were erupted in each of the three episodes. Compositional and mineralogic evidence from mafic lavas and inclusions indicate that both tholeiitic (dry) and calcalkaline (wet) parental magmas were present. Petrologic evidence records the operation of complex, multi-stage processes including fractional crystallization, crustal assimilation, and magma mixing. Experimental evidence suggests that magmas were stored at 3 to 6 km depth prior to eruption, and that both wet and dry parental magmas were involved in generating the more silicic magmas. The broad distribution of eruptive events and the relative accessibility and good exposure of lavas, combined with physical and petrologic evidence for multiple and varied mafic inputs, has created an unusual opportunity to understand the workings of this large magmatic system. A combined total of more than 25 intrusive and extrusive events are indicated for late Holocene time. Plutonic inclusions, some with ages as young as Holocene, were also brought to the surface in five of the eruptions. All eruptions took place along northwest- to northeast-trending alignments of vents, reflecting the overall east-west extensional tectonic environment. The interaction of tectonism and volcanism is a dominant influence at this subduction-related volcano, located where the west edge of the extensional Basin and Range Province impinges on the Cascades arc. Ongoing subsidence focused at the central caldera has been documented along with geophysical evidence for a small magma body. This evidence, combined with the frequency of eruptive and intrusive activity in late Holocene time, an active geothermal system, and intermittent long-period seismic events indicate that the volcano is likely to erupt again.

California

Mineralogy and composition of the oceanic mantle

The mineralogy of the oceanic basalt source region is examined by testing whether a peridotite mineralogy can yield observed whole-rock and olivine compositions from (1) the Hawaiian Islands, our type example of a mantle plume, and (2) the Siqueiros Transform, which provides primitive samples of normal mid-ocean ridge basalt. New olivine compositional data from phase 2 of the Hawaii Scientific Drilling Project (HSDP2) show that higher Ni-in-olivine at the Hawaiian Islands is due to higher temperatures ( T ) of melt generation and processing (by c . 300°C) related to the Hawaiian mantle plume. D Ni is low at high T , so parental Hawaiian basalts are enriched in NiO. When Hawaiian (picritic) parental magmas are transported to shallow depths, olivine precipitation occurs at lower temperatures, where D Ni is high, leading to high Ni-in-olivine. Similarly, variations in Mn and Fe/Mn ratios in olivines are explained by contrasts in the temperatures of magma processing. Using the most mafic rocks to delimit Siqueiros and Hawaiian Co and Ni contents in parental magmas and mantle source compositions also shows that both suites can be derived from natural peridotites, but are inconsistent with partial melting of natural pyroxenites. Whole-rock compositions at Hawaii and Siqueiros are also matched by partial melting experiments conducted on peridotite bulk compositions. Hawaiian whole-rocks have elevated FeO contents compared with Siqueiros, which can be explained if Hawaiian parental magmas are generated from peridotite at 4–5 GPa, in contrast to pressures of slightly greater than 1 GPa for melt generation at Siqueiros; these pressures are consistent with olivine thermometry, as described in an earlier paper. SiO 2 -enriched Koolau compositions are reproduced if high-Fe Hawaiian parental magmas re-equilibrate at 1–1·5 GPa. Peridotite partial melts from experimental studies also reproduce the CaO and Al 2 O 3 contents of Hawaiian (and Siqueiros) whole-rocks. Hawaiian magmas have TiO 2 contents, however, that are enriched compared with melts from natural peridotites and magmas derived from the Siqueiros depleted mantle, and consequently may require an enriched source. TiO 2 is not the only element that is enriched relative to melts of natural peridotites. Moderately incompatible elements, such as Ti, Zr, Hf, Y, and Eu, and compatible elements, such as Yb and Lu, are all enriched at the Hawaiian Islands. Such enrichments can be explained by adding 5–10% mid-ocean ridge basalt (crust) to depleted mantle; when the major element composition of such a mixture is recast into mineral components, the result is a fertile peridotite mineralogy.

Hawai'i

Thermal infrared spectroscopy of experimentally shocked anorthosite and pyroxenite: Implications for remote sensing of Mars

The feldspar and pyroxene mineralogies on Mars revealed by the Thermal Emission Spectrometer (TES) on Mars Global Surveyor likely record a variety of shock effects, as suggested by petrologic analyses of the Martian meteorites and the abundance of impact craters on the planet's surface. To study the effects of shock pressures on thermal infrared spectra of these minerals, we performed shock recovery experiments on orthopyroxenite and anorthosite samples from the Stillwater Complex (Montana) over peak pressures from 17 to 63 GPa. We acquired emissivity and hemispherical reflectance spectra (350–1400 cm −1 ; ∼7–29 μm) of both coherent chips and fine-grained powders of shocked and unshocked samples. These spectra are more directly comparable to remotely sensed data of Mars (e.g., TES) than previously acquired absorption or transmission spectra of shocked minerals. The spectra of experimentally shocked feldspar show systematic changes with increasing pressure due to depolymerization of the silica tetrahedra. For the spectra of chips, this includes the disappearance of small bands in the 500–650 cm −1 region and a strong band at 1115 cm −1 , and changes in positions of a strong band near 940 cm −1 and the Christiansen feature near 1250 cm −1 . Spectra of the shocked powders show the gradual disappearance of a transparency feature near 830 cm −1 . Fewer changes are observed in the pyroxene spectra at pressures as high as 63 GPa. Spectra of experimentally shocked minerals will help identify more precisely the mineralogy of rocks and soils not only from TES but also from Mars instruments such as miniTES and THEMIS.

Journal of Geophysical Research E: Planets

The provenance of rutile.

Most coarse detrital rutile is derived from high-grade metamorphic rocks. Contrary to a conventional assumption, independent rutile grains are particularly rare in igneous rocks except alkalic rocks. The use of rutile in the ZTR (zircon-tourmaline-rutile) index of mineralogic maturity is only partially valid, owing to its restricted provenance.

Journal of Sedimentary Petrology

Bleached chondrules: Evidence for widespread aqueous processes on the parent asteroids of ordinary chondrites

We present the first detailed study of a population of texturally distinct chondrules previously described by Kurat (1969), Christophe Michel-Lévy (1976), and Skinner et al. (1989) that are sharply depleted in alkalis and Al in their outer portions. These “bleached” chondrules, which are exclusively radial pyroxene and cryptocrystalline in texture, have porous outer zones where mesostasis has been lost. Bleached chondrules are present in all type 3 ordinary chondrites and are present in lower abundances in types 4–6. They are most abundant in the L and LL groups, apparently less common in H chondrites, and absent in enstatite chondrites. We used x-ray mapping and traditional electron microprobe techniques to characterize bleached chondrules in a cross section of ordinary chondrites. We studied bleached chondrules from Semarkona by ion microprobe for trace elements and H isotopes, and by transmission electron microscopy. Chondrule bleaching was the result of low-temperature alteration by aqueous fluids flowing through finegrained chondrite matrix prior to thermal metamorphism. During aqueous alteration, interstitial glass dissolved and was partially replaced by phyllosilicates, troilite was altered to pentlandite, but pyroxene was completely unaffected. Calcium-rich zones formed at the inner margins of the bleached zones, either as the result of the early stages of metamorphism or because of fluid-chondrule reaction. The mineralogy of bleached chondrules is extremely sensitive to thermal metamorphism in type 3 ordinary chondrites, and bleached zones provide a favorable location for the growth of metamorphic minerals in higher petrologic types. The ubiquitous presence of bleached chondrules in ordinary chondrites implies that they all experienced aqueous alteration early in their asteroidal histories, but there is no relationship between the degree of alteration and metamorphic grade. A correlation between the oxidation state of chondrite groups and their degree of aqueous alteration is consistent with the source of water being either accreted ices or water released during oxidation of organic matter. Ordinary chondrites were probably open systems after accretion, and aqueous fluids may have carried volatile elements with them during dehydration. Individual radial pyroxene and cryptocrystalline chondrules were certainly open systems in all chondrites that experienced aqueous alteration leading to bleaching.

Meteoritics and Planetary Science

Petrologic characteristics of the 1982 and pre-1982 eruptive products of El Chichon volcano, Chiapas, Mexico

Studies on a suite of rocks from this volcano indicate that the juvenile materials of the 1982 and pre-1982 eruptions of the volcano have essentially the same mineralogy and chemistry. Data suggest that chemical composition changed little over the 0.3 m.y. sample period. Modally, plagioclase is the dominant phenocryst, followed by amphibole, clinopyroxene and minor phases including anhydrite. Plagioclase phenocrysts show complex zoning: the anorthite-rich zones are probably the result of changing volatile P on the magma and may reflect the changes in the volcano's magma reservoir in response to repetitive, explosive eruptive activity.-R.E.S.

Chiapas

Ultramafic float rocks at Jezero crater (Mars): Excavation of lower crustal rocks or mantle peridotites by impact cratering?

Based on observation and data from meteorites and in situ scientific missions, experiments as well as models, the Martian mantle is assumed to share some compositional and mineralogical affinity with the terrestrial mantle. However, there might be subtle differences like the Martian mantle being more ferroan. Yet, we do not have any direct analysis of a Martian mantle rock to confirm this assumption. NASA’s Perseverance rover found olivine-rich boulder-sized float rocks on the upper Jezero fan (Mars). These boulders have an ultramafic composition and their mineralogy is dominantly composed of Fo 73±3 olivine with high-Mg orthopyroxene, Cr-rich Ti-Fe oxides and minor plagioclase and high-Ca pyroxene. Microtextural and petrological analysis reveals that these minerals crystallized at equilibrium. In addition, these boulders are different from all the bedrocks analyzed by Perseverance along its traverse which are crustal igneous rocks and sediments. Comparing our data to Martian meteorites and available Mars bulk silicate models (BSM), we discuss that these boulders could represent primitive melts and/or lower crustal material, and we specifically hypothesize that they could be mantle peridotites. We propose that these putative mantle rocks could have been excavated by the succession of impacts from the shallow mantle or lower crust in the Isidis region where Jezero crater is located. These olivine-rich boulders could thereby constitute the first direct analysis of a Martian mantle rock.

Earth and Planetary Science Letters

Andesite sills in the Red Mountain area, Scapegoat Wilderness, Lewis and Clark County, Montana

Sills 2-200 ft (0.6-60 in) thick in the Red Mountain area of the Scapegoat Wilderness in northwest Montana consist of altered andesite, basaltic andesite, and dacite and occur over a stratigraphic range of 8,000 ft (2,400 m) in the Helena and Snowslip Formations. The approximate compositional range of the sills is 50-80 percent plagioclase, 0-25 percent orthoclase, and 5-30 percent amphibole, pyroxene, and biotite; the uppermost sill contains about 15 percent quartz in the groundmass. Accessory minerals include quartz, magnetite, ilmenite, apatite, and pyrite. The petrology and alteration of the sills distinguish them from other sills in the region. Field observations and laboratory studies consisting of chemical, isotopic and X-ray analyses, and petrographic and mineralogic investigations suggest that the sills may have been emplaced in Precambrian Y time at about the same time as the extrusion of the Purcell Lava in the vicinity of Glacier National Park. Alternatively, the sills may represent a Precambrian igneous event not previously recognized in the Belt basin.

Montana