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USGS2020

Numerical simulation of groundwater availability in central Moloka‘i, Hawai‘i

Since the 1990s, increased chloride concentrations of water pumped from wells (much of which is used for drinking water) and the effects of withdrawals on groundwater-dependent ecosystems have led to concerns over groundwater availability on the island of Molokaʻi, Hawaiʻi. An improved understanding of the hydrologic effects of proposed groundwater withdrawals is needed to ensure effective management of the groundwater resources of Molokaʻi, plan for possible growth, and accommodate cultural, social, and economic concerns. To address the information needs of managers and community stakeholders on Molokaʻi, the U.S. Geological Survey developed a numerical groundwater model capable of simulating salinity change and reduction in groundwater discharge in coastal areas of central and southern Molokaʻi. Estimates of groundwater recharge needed as input to the numerical groundwater model were made using a daily water budget for each decade during 1940−2012 (the period 2000−12 spanned 13 years) and the most current available data, including the distributions of monthly rainfall and potential evapotranspiration. Total island recharge during the decadal periods ranged from a low of about 189 Mgal/d during the 1970s to a high of 278 Mgal/d during the 1960s. These recharge estimates were used to develop an island-wide numerical groundwater model with simplifying assumptions (sharp interface between freshwater and saltwater; two-dimensional flow). The island-wide model provided estimates of groundwater inflows to the main area of interest simulated with a three-dimensional numerical groundwater model. Simulated withdrawal scenarios were selected in consultation with water managers and stakeholders and consisted of: (1) a baseline scenario using average recharge (1978−2007 rainfall and 2010 land cover) and average 2016−17 withdrawals; (2) a scenario using average recharge and withdrawals from existing wells at pending (as of January 2019) water-use permit rates; (3) six scenarios using average recharge and selected withdrawals from existing and proposed wells; and (4) a scenario using reduced recharge and selected withdrawals from existing and proposed wells. Results of the simulated withdrawal scenarios indicate that wells may be capable of producing groundwater with chloride concentrations below 250 mg/L at withdrawal rates exceeding average 2016−17 rates. However, the quality of water withdrawn from production wells is dependent on the rate and distribution of the withdrawals. For all nonbaseline scenarios, simulated groundwater discharge to the nearshore environment is reduced relative to the baseline scenario. Areas of discharge reduction may correspond to areas used for cultural or subsistence purposes. The three-dimensional numerical groundwater model developed for this study utilizes the latest available hydrologic and geologic information and is a useful tool for understanding the hydrologic effects of additional groundwater withdrawals in central Molokaʻi. The model has several limitations, including its nonuniqueness and inability to account for local-scale heterogeneities.

Hawaii↗

USGS2017

Genetic and grade and tonnage models for sandstone-hosted roll-type uranium deposits, Texas Coastal Plain, USA

The coincidence of a number of geologic and climatic factors combined to create conditions favorable for the development of mineable concentrations of uranium hosted by Eocene through Pliocene sandstones in the Texas Coastal Plain. Here 254 uranium occurrences, including 169 deposits, 73 prospects, 6 showings and 4 anomalies, have been identified. About 80 million pounds of U 3 O 8 have been produced and about 60 million pounds of identified producible U 3 O 8 remain in place. The development of economic roll-type uranium deposits requires a source, large-scale transport of uranium in groundwater, and deposition in reducing zones within a sedimentary sequence. The weight of the evidence supports a source from thick sequences of volcanic ash and volcaniclastic sediment derived mostly from the Trans-Pecos volcanic field and Sierra Madre Occidental that lie west of the region. The thickest accumulations of source material were deposited and preserved south and west of the San Marcos arch in the Catahoula Formation. By the early Oligocene, a formerly uniformly subtropical climate along the Gulf Coast transitioned to a zoned climate in which the southwestern portion of Texas Coastal Plain was dry, and the eastern portion humid. The more arid climate in the southwestern area supported weathering of volcanic ash source rocks during pedogenesis and early diagenesis, concentration of uranium in groundwater and movement through host sediments. During the middle Tertiary Era, abundant clastic sediments were deposited in thick sequences by bed-load dominated fluvial systems in long-lived channel complexes that provided transmissive conduits favoring transport of uranium-rich groundwater. Groundwater transported uranium through permeable sandstones that were hydrologically connected with source rocks, commonly across formation boundaries driven by isostatic loading and eustatic sea level changes. Uranium roll fronts formed as a result of the interaction of uranium-rich groundwater with either (1) organic-rich debris adjacent to large long-lived fluvial channels and barrier–bar sequences or (2) extrinsic reductants entrained in formation water or discrete gas that migrated into host units via faults and along the flanks of salt domes and shale diapirs. The southwestern portion of the region, the Rio Grande embayment, contains all the necessary factors required for roll-type uranium deposits. However, the eastern portion of the region, the Houston embayment, is challenged by a humid environment and a lack of source rock and transmissive units, which may combine to preclude the deposition of economic deposits. A grade and tonnage model for the Texas Coastal Plain shows that the Texas deposits represent a lower tonnage subset of roll-type deposits that occur around the world, and required aggregation of production centers into deposits based on geologic interpretation for the purpose of conducting a quantitative mineral resource assessment.

Texas↗

USGS2000

Cruise report RV Ocean Surveyor cruise O-1-00-GM the bathymetry and acoustic backscatter of the Pinnacles area, northern Gulf of Mexico May 23, through June 10, 2000 Venice, LA to Venice, LA

An extensive deep (~100 m) reef tract occurs on the Mississippi-Alabama outer continental shelf (OCS). The tract, known as "The Pinnacles", is apparently part of a sequence of drowned reef complexes along the "40-fathom" shelf edge of the northern Gulf of Mexico (Ludwick and Walton, 1957). It is critical to determine the accurate geomorphology of deep-reefs because of their importance as benthic habitats for fisheries. The Pinnacles were mapped by Ludwick and Walton (1957) using a single-beam echo sounder but the spatial extent and morphology were interpreted from a series of widely separated, poorly navigated bathymetric profiles. Other recent studies, supported by Minerals Management Service (MMS), used towed sidescan sonars and single-channel seismic-reflection profiling. None of the existing studies provide the quality of geomorphic data necessary for reasonable habitat studies. The fish faunas of shallow hermatypic reefs have been well studied, but those of deep ahermatypic reefs have relatively ignored. The ecology of deep ahermatypic reefs is fundamentally different from hermatipic reefs because autochthonous intracellular symbiotic zooxanthellae (the carbon source for hermatypic corals) do not form the base of the trophic web. Instead, exogenous plankton, transported to the reef by currents, serves as the primary carbon source. Deep OCS reefs also lie below the practical working depths for SCUBA; consequently, remote investigations from a ship or in situ investigations using submersibles or ROVs are required. Community structure and trophodynamics of demersal fishes of the Pinnacles are presently the focus of USGS reseach. A goal of the research is to answer questions concerning the relataive roles played by geomorphology and surficial geology in the interaction with and control of biological differentiation. OCS reefs are important because we now know that such areas are important coral reef fish havens, key spawning 2 sites, and a critical early larval and juvenile habitats for economically important sport/food fishes. Also, deep-reef ecosystems as well as the fish populations they sustain are impacted by intensive oil-field development. It is now known that deep OCS reefs function as a key source of re-population (via seasonal and ontogenetic migration) of already heavily impacted inshore reefs. A reflection of this realization is the recent closure by the Gulf States Fisheries Management Council of a 600 mi 2 area of the Florida Middle Grounds (another unmapped major "40-fathom" OCS reef complex) to commercial fishing to preserve grouper spawning aggregations. It is known that the Pinnacles reefs support a lush fauna of ahermatypic hard corals, soft corals, black corals, sessile crinoids and sponges—together forming a living habitat for a well-developed fish fauna. The fish fauna comprises typical Caribbean reef fishes and Carolinian shelf fishes, plus epipelagic fishes, and a few deep-sea fishes. The base of the megafaunal invertebrate food web is plankton, borne by essentially continuous semi-laminar currents flowing predominantly out of the SW, up, along and across the shelf edge. These currents are intercepted by pinnacles reefs, which lie roughly in two linear tracts, parallel to the coastline (see fig. 1 in report). USGS research initiated in 1997 (Sulak et al., in progress) has demonstrated that the Pinnacles reef fish fauna is dominated by planktivorous fishes. Ongoing food habits, trophic web and stable isotope analyses by the USGS are reinforcing a basic picture of deep OCS reefs as ecosystems based on exogenous current-borne plankton. Long-term current meter deployments have demonstrated that the >3 m, <16m relief of the Pinnacles reefs disrupts the prevailing currents, inducing local complexity (F. Kelly, Texas A&M Univ., pers. comm.) favorable to plankton and planktivores. Geodetically accurate bathymetry maps, coregistered with calibrated acoustic backscatter maps, are critical to delineate benthic biotopes, and are essential to correlate biological community differentiation with the physical environment. Previous mapping of the Pinnacles area using the TAMU towed single-beam sidescan system (Anonymous., 1999) employed technology with inherent deficiencies in backscatter calibration, bathymetric precision, and geo-referencing. The resulting bathymetric interpretations of TAMU data are further degraded by ship-track-parallel artifacts that obliterate geomorphology rendering them inadequate to provide high-resolution mapping of individual target reefs (typical maximum relief 15 m, diameter 200-500 m). The sidescan-sonar surveys of the area (Laswell et al., 1990) suffer many of the same deficiencies as the TAMU data so they add no quantitative and little qualitative information about the geomorphology and surficial geology.

Gulf of Mexico, the Pinnacles area↗

USGS2009

Coastal sensitivity to sea level rise— A focus on the Mid-Atlantic Region

This Synthesis and Assessment Product (SAP), developed as part of the U.S. Climate Change Science Program, examines potential effects of sea-level rise from climate change during the twenty-first century, with a focus on the mid-Atlantic coast of the United States. Using scientific literature and policy-related documents, the SAP describes the physical environments; potential changes to coastal environments, wetlands, and vulnerable species; societal impacts and implications of sea-level rise; decisions that may be sensitive to sea-level rise; opportunities for adaptation; and institutional barriers to adaptation. The SAP also outlines the policy context in the mid-Atlantic region and describes the implications of sea-level rise impacts for other regions of the United States. Finally, this SAP discusses ways natural and social science research can improve understanding and prediction of potential impacts to aid planning and decision making. Projections of sea-level rise for the twenty-first century vary widely, ranging from several centimeters to more than a meter. Rising sea level can inundate low areas and increase flooding, coastal erosion, wetland loss, and saltwater intrusion into estuaries and freshwater aquifers. Existing elevation data for the mid-Atlantic United States do not provide the degree of confidence needed for local decision making. Systematic nationwide collection of high-resolution elevation data would improve the ability to conduct detailed assessments in support of planning. The coastal zone is dynamic and the response of coastal areas to sea-level rise is more complex than simple inundation. Much of the United States consists of coastal environments and landforms such as barrier islands and wetlands that will respond to sea-level rise by changing shape, size, or position. The combined effects of sea-level rise and other climate change factors such as storms may cause rapid and irreversible coastal change. All these changes will affect coastal habitats and species. Increasing population and development in coastal areas also affects the ability of natural ecosystems to adjust to sea-level rise. Coastal communities and property owners have responded to coastal hazards by erecting shore protection structures, elevating land and buildings, or relocating inland. Accelerated sea-level rise would increase the costs and environmental impacts of these responses. Shoreline armoring can eliminate the land along the shore to which the public has access; beach nourishment projects often increase access to the shore. Preparing for sea-level rise can be justified in many cases, because the cost of preparing now is small compared to the cost of reacting later. Examples include wetland protection, flood insurance, longlived infrastructure, and coastal land-use planning. Nevertheless, preparing for sea-level rise has been the exception rather than the rule. Most coastal institutions were based on the implicit assumption that sea level and shorelines are stable. Efforts to plan for sea-level rise can be thwarted by several institutional biases, including government policies that encourage coastal development, flood insurance maps that do not consider sea-level rise, federal policies that prefer shoreline armoring over soft shore protection, and lack of plans delineating which areas would be protected or not as sea level rises. The prospect of accelerated sea-level rise and increased vulnerability in coastal regions underscores the immediate need for improving our scientific understanding of and ability to predict the effects of sea-level rise on natural systems and society. These actions, combined with development of decision support tools for taking adaptive actions and an effective public education program, can lessen the economic and environmental impacts of sea-level rise.

Report↗

USGS2010

Secular variation in economic geology

The temporal pattern of ore deposits on a constantly evolving Earth reflects the complex interplay between the evolving global tectonic regime, episodic mantle plume events, overall changes in global heat flow, atmospheric and oceanic redox states, and even singular impact and glaciation events. Within this framework, a particular ore deposit type will tend to have a time-bound nature. In other words, there are times in Earth history when particular deposit types are absent, times when these deposits are present but scarce, times when they are abundant, and still other times for which we lack sufficient data. Understanding of such secular variation provides a critical first-order tool for exploration targeting, because rocks that have formed or were deformed during a certain time slice may be very permissive for a given deposit type, whereas identification of rocks of less favorable ages would help eliminate large areas during exploration programs. Secular analysis, therefore, is potentially a powerful tool for mineral resource assessment in poorly known terranes, providing a quick filter for favorability of a given deposit type using age of host rocks. Factors bearing on the known age distribution of a particular type of deposit include the following: (1) uneven preservation, (2) data gaps, (3) contingencies of plate motions, and (4) long-term secular changes in the Earth System. The present special issue of Economic Geology is focused on the latter factor, although all of these are interrelated. The selective preservation of certain mineral deposit types and the greater susceptibility for shallowly formed ores in tectonically active environments to be lost to erosion define a pattern that is superimposed on the secular formational trends (e.g., Groves et al., 2005a , b ; Kerrich et al., 2005 ). With improved geochronological methods and the availability of information on important mineral deposits from most parts of the world, data gaps for defining broad temporal distributions of ore types are becoming smaller. It has been increasingly recognized that ore deposit formation is also correlated with plate tectonic setting. Nevertheless, a complex Earth history of supercontinent assembly and breakup has led to the fragmentation of many Paleozoic and Precambrian mineral provinces. The use of plate reconstructions in economic geology, although extremely controversial and conjectural before the late Paleozoic, is critical for defining these provinces prior to the added complications resulting from post-ore plate motions. It is now well established that the temporal patterns of many types of mineral deposits (Fig. 1 1 ) reflect the formation or break-up of supercontinents and the preservation potential of deposits formed during these periods ( Barley and Groves, 1992 ; Titley, 1993 ; Kerrich et al., 2005 ; Goldfarb et al., 2009 ). Approximate time periods for such formation and break-up, respectively, include 2800–2500 and 2450–2100 Ma for Kenorland, 2100–1800 and 1600–1300 Ma for Nuna/Columbia, 1300–1100 and 850–600 Ma for Rodinia, and 600–300 Ma and 200–60 Ma for Gondwanaland-Pangea. A new supercontinent, Amasia, has begun to form during the past 250 m.y., thus overlapping Pangea break-up. Many of the formation-preservation patterns are themselves controlled by progressive cooling of Earth, the change from a mantle-plume buoyancy style to subduction-dominated tectonics, a decreasing buoyancy of the subcontinental lithospheric mantle, and depth of ore formation. In general, orogenic Au, volcanogenic massive sulfide (VMS), epithermal Au-Ag, and porphyry Cu±Au and Mo porphyry deposits form in active margins during periods of supercontinent assembly. Numerous other ore deposit types show an association with supercontinent formation, but develop inland of the active margin. These include many of the MVT Pb-Zn deposits and unconformity-type U deposits. The Tertiary Carlin-type deposits within the deformed shelf sequences along the North American craton margin also appear to have formed during the ongoing growth of Amasia. Those ores associated with periods of supercontinent breakup or attempted breakup are more difficult to define. They probably include diamond, Bushveld-type Ni-Cu-PGE, IOCG, and clastic-dominated Pb-Zn (or SEDEX) deposits in intracontinental areas of failed rifting, and other clastic-dominated Pb-Zn deposits in areas of actual breakup. In all cases, however, these temporal/spatial distributions are ultimately controlled by the secular character of Earth history.

Economic Geology↗

USGS2006

Beyond the obvious limits of ore deposits: The use of mineralogical, geochemical, and biological features for the remote detection of mineralization

Far field features of ore deposits include mineralogical, geochemical, or biological attributes that can be recognized beyond the obvious limits of the deposits. They can be primary, if formed in association with mineralization or alteration processes, or secondary, if formed from the interaction of ore deposits with the hydrosphere and biosphere. This paper examines a variety of far field features of different ore deposit types and considers novel applications to exploration and discovery. Primary far field features include mineral and rock chemistry, isotopic or element halos, fluid pathways and thermal anomalies in host-rock sequences. Examples include the use of apatite chemistry to distinguish intrusive rocks permissive for iron oxide copper gold (IOCG) and porphyry deposits; resistate mineral (e.g., rutile, tourmaline) chemistry in exploration for volcanogenic massive sulfide (VMS), orogenic gold, and porphyry deposits; and pyrite chemistry to vector toward sedimentary exhalative (sedex) deposits. Distinctive whole-rock geochemical signatures also can be recognized as a far field feature of porphyry deposits. For example, unique Sr/Y ratios in whole-rock samples, used to distinguish barren versus fertile magmas for Cu mineralization, result from the differentiation of oxidized hydrous melts. Anomalous concentrations of halogen elements (Cl, Br, and I) have been found for distances of up to 200 m away from some mineralized centers. Variations in isotopic composition between ore-bearing and barren intrusions and/or systematic vertical and lateral zonation in sulfur, carbon, or oxygen isotope values have been documented for some deposit types. Owing to the thermal aureole that extends beyond the area of mineralization for some deposits, detection of paleothermal effects through methods such as conodont alteration indices, vitrinite or bitumen reflectance, illite crystallinity, and apatite or zircon thermochronology studies also can be valuable, particularly for deposits with a low-temperature thermal history. A number of newly investigated secondary far field features include the development of reduced columns by electrochemical processes in transported overburden, geochemical dispersion related to the expulsion of groundwater from tectonic and seismic compression, dispersion of vapor above ore deposits, and geochemical dispersion related to biological processes. Redox gradients have been found between underlying reduced and overlying oxidized environments associated with sulfide bodies, which result in mass transfer through electro-chemical dispersion. Recent studies have characterized the pH, oxidation-reduction potential (ORP), and self potential (SP) in overburden overlying sulfide-hosted gold and VMS deposits. Lateral migration of metals in groundwater is well understood from normal groundwater flow, but the processes responsible for vertical mass transfer of groundwater and its dissolved components have been recognized only recently. One process, termed cyclical dilatancy pumping, expels groundwater during and after earthquake events, which can cause the redistribution of metals around deposits in some environments. Soil gases are of interest owing to their high degree of mobility through the vadose zone in transported overburden. Numerous soil gas species (CO2, O2, Hg, Rn, He, sulfur compounds, and light hydrocarbons) have been measured and interpreted as diagnostic of some buried mineral deposits, and some evidence suggests a possible link between vapor dispersion and metal enrichment in soil. Geochemical enrichment in plant material and soils through successive growth-death cycles is well established, but the important role of microorganisms is now increasingly evident. Microorganisms significantly enhance the kinetics of sulfide oxidation and influence the distribution of metals around ore deposits. The presence of metal-resistant bacteria and enhanced concentrations of sulfate-reducing bacteria in exotic overburd

Economic Geology↗

USGS2008

Landsat continuity: Issues and opportunities for land cover monitoring

Initiated in 1972, the Landsat program has provided a continuous record of earth observation for 35 years. The assemblage of Landsat spatial, spectral, and temporal resolutions, over a reasonably sized image extent, results in imagery that can be processed to represent land cover over large areas with an amount of spatial detail that is absolutely unique and indispensable for monitoring, management, and scientific activities. Recent technical problems with the two existing Landsat satellites, and delays in the development and launch of a successor, increase the likelihood that a gap in Landsat continuity may occur. In this communication, we identify the key features of the Landsat program that have resulted in the extensive use of Landsat data for large area land cover mapping and monitoring. We then augment this list of key features by examining the data needs of existing large area land cover monitoring programs. Subsequently, we use this list as a basis for reviewing the current constellation of earth observation satellites to identify potential alternative data sources for large area land cover applications. Notions of a virtual constellation of satellites to meet large area land cover mapping and monitoring needs are also presented. Finally, research priorities that would facilitate the integration of these alternative data sources into existing large area land cover monitoring programs are identified. Continuity of the Landsat program and the measurements provided are critical for scientific, environmental, economic, and social purposes. It is difficult to overstate the importance of Landsat; there are no other systems in orbit, or planned for launch in the short-term, that can duplicate or approach replication, of the measurements and information conferred by Landsat. While technical and political options are being pursued, there is no satellite image data stream poised to enter the National Satellite Land Remote Sensing Data Archive should system failures occur to Landsat-5 and -7.

Remote Sensing of Environment↗

USGS2021

Satellites for long-term monitoring of inland U.S. lakes: The MERIS time series and application for chlorophyll-a

Lakes and other surface fresh waterbodies provide drinking water, recreational and economic opportunities, food, and other critical support for humans, aquatic life, and ecosystem health. Lakes are also productive ecosystems that provide habitats and influence global cycles. Chlorophyll concentration provides a common metric of water quality, and is frequently used as a proxy for lake trophic state. Here, we document the generation and distribution of the complete MEdium Resolution Imaging Spectrometer (MERIS; Appendix A provides a complete list of abbreviations) radiometric time series for over 2300 satellite resolvable inland bodies of water across the contiguous United States (CONUS) and more than 5,000 in Alaska. This contribution greatly increases the ease of use of satellite remote sensing data for inland water quality monitoring, as well as highlights new horizons in inland water remote sensing algorithm development. We evaluate the performance of satellite remote sensing Cyanobacteria Index (CI)-based chlorophyll algorithms, the retrievals for which provide surrogate estimates of phytoplankton concentrations in cyanobacteria dominated lakes. Our analysis quantifies the algorithms' abilities to assess lake trophic state across the CONUS. As a case study, we apply a bootstrapping approach to derive a new CI-to-chlorophyll relationship, ChlBS, which performs relatively well with a multiplicative bias of 1.11 (11%) and mean absolute error of 1.60 (60%). While the primary contribution of this work is the distribution of the MERIS radiometric timeseries, we provide this case study as a roadmap for future stakeholders' algorithm development activities, as well as a tool to assess the strengths and weaknesses of applying a single algorithm across CONUS.

Alaska, Minnesota↗

USGS1974

Development and evaluation of a prototype global volcanic surveillance system utilizing the ERTS-1 satellite data collection system

The ERTS Data Collection System makes it feasible for the first time to monitor the level of activity at widely separated volcanoes and to relay these data rapidly to one central office for analysis. This capability opens a new era in volcanology where the hundreds of normally quiescent but potentially dangerous volcanoes near populated regions around the world can be economically and reliably monitored daily to warn when any one volcano is becoming active again. Before ERTS was launched only a few volcanoes in the world were monitored continuously because of the high cost of building and staffing volcano observatories. Yet it is known from data collected in this century, that while visible signs of pending eruptions may occur only minutes to days in advance, invisible but measurable signs may be detected days, weeks, months and even years before a major eruption. While prediction of specific eruptions is still an elusive goal, early warning of a reawakening of activity at quiescent volcanoes is now a distinct possibility. A prototype volcano surveillance system was established during the latter part of 1972 and early 1973 on 15 volcanoes in Alaska, Hawaii, Washington, California, Iceland, Guatemala, El Salvador, and Nicaragua. Nineteen seismic detectors that count four different sizes of earthquakes and six biaxial borehole tiltmeters that measure ground tilt with a resolution of 1 microradian have been installed. Data from these instruments are relayed through the ERTS satellite and through a teletype link to the U.S. Geological Survey Office in Menlo Park for rapid analysis. Only seismic and tilt data are collected because these have been shown in the past to indicate most reliably the level of volcanic activity and also because they can be measured relatively easily with available instrumentation. Experience during this project demonstrates the feasibility of building inexpensive, low power, reliable instruments that can be installed in remote locations and can be expected to run unattended for a few years. Comparison of the data from these new earthquake counters with data from nearby standard seismometers shows that the counters do normally indicate the level of seismic activity. During periods of high seismic background noise there may be a significant number of spurious counts but the existence and duration of such noisy periods are reliably indicated by other data collected by the earthquake counters. An eruption of Volcan Fuego in Guatemala was preceded by an order of magnitude increase in the number of seismic-event counts several days before. The tiltmeters operated stably in several different environments. A twenty-microradian collapse of the summit of Kilauea Volcano in Hawaii was observed on three tiltmeters. This initial experiment shows that now with the advent of inexpensive satellite telemetry it is both technologically and economically feasible to build a global volcano surveillance system. Several details in the design and deployment of appropriate low-power, inexpensive, and reliable instruments still need to be worked out. Work continues to evaluate the scientific feasibility of this system by collecting and analyzing data that clearly demonstrate the ability of this system to detect changes in volcanic activity.

Open-File Report↗

USGS2017

Manganese

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits. From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources and about 25 percent of its reserves. South Africa, Brazil, and Ukraine together accounted for nearly 65 percent of reserves in 2013. The combination of total import reliance for manganese, the mineral commodity’s essential uses in our industrialized society, and the potential for supply disruptions because of the limited sources of the ore makes manganese among the most critical minerals for the United States. Manganese is the 12th most abundant element in Earth’s crust. Its concentration varies among common types of rocks, mostly in the range of from 0.1 to 0.2 percent. The highest quality manganese ores contain from 40 to 45 percent manganese. The formation of these ores requires specialized geologic conditions that concentrate manganese at several hundred times its average crustal abundance. The dominant processes in forming the world’s principal deposits take place in the oceans. As a result, most important manganese deposits occur in ancient marine sedimentary rocks that are now exposed on continents as a result of subsequent tectonic uplift and erosion. In many cases, other processes have further enriched these manganiferous sedimentary rocks to form some of today’s highest grade ores. Modern seabed resources of ferromanganese nodules cover vast areas of the present ocean floor and are still forming by complex interactions of marine microorganisms, manganese dissolved in seawater, and chemical processes on the seabed. Manganese is ubiquitous in soil, water, and air. It occurs most often in solid form but can become soluble under acidic conditions. Manganese mining, like any activity that disturbs large areas of Earth’s surface, has the potential to produce increases in manganese concentrations that could be harmful to humans or the environment if not properly controlled. Although manganese is an essential nutrient for humans and most other organisms, overexposure can lead to neurotoxicity in humans. Workers at manganese mining and processing facilities have the greatest potential to inhale manganese-rich dust. Without proper protective equipment, these workers may develop a permanent neurological disorder known as manganism. Each manganese mine is unique and presents its own suite of potential hazards and preventative measures. Likewise, various nations have their own sets of standards to ensure safe mining, isolation of mine waste, treatment of mine waters, and mine closure and restoration. Interest in mining trace metals contained in ferromanganese nodules and crusts on the seabed has increased rapidly in the past decade. Prime areas for future research include overcoming the technological challenges presented by mining as deep as 6,500 meters below sea level and understanding and mitigating the potential impacts of seabed mining on marine ecosystems.

Professional Paper↗

USGS1966

Stratified deposits of the oxides and carbonates of manganese

Compared with the stratified deposits of iron minerals, those of manganese minerals have received little attention until recent years. Before 1930, students of the stratified deposits of manganese minerals have generally concluded that the contained manganese was derived from the decomposition of the rocks that formed the borders of the basins. Only in a few places have geologists recognized that if these rocks were the principal source of the contained manganese the basins should contain also enormous quantities of iron minerals, whereas most of the large deposits of manganese contain little iron. Even though more than 100 years ago some geologists proposed that the iron contained in some deposits of stratified iron minerals was probably derived from hydrothermal waters related to centers of volcanism, not until about 1930 was this source of manganese in similar deposits seriously proposed. This mode of origin was given the name "volcanogene sedimentaire" by French geologists working in Morocco. Since then, other names, such as "exhalative sedimentaire," have been used by geologists working in several European districts. Because of the development of new techniques for the study of the chemical and physical features of the minerals, and because close attention to the lithologic environments of the beds is being given more and more during recent years, it has seemed advisable to review the features of stratified deposits of the manganese minerals in many parts of the world and over a wide range in age. This study indicates that at least three sources may have contributed the manganese in the large deposits of iron-free oxides and carbonates : (1) the rocks that form the borders of the basins, either marine or continental; (2) the nearby underlying sediments, largely of igneous origin, decomposed by warm waters largely derived from depth; and (3) waters of hydrothermal origin derived from great depths during epochs of volcanism from which iron minerals with little manganese are deposited in deep zones, then minerals with much iron and more manganese at intermediate depths, and, finally, manganese minerals with little iron near the surface. As the hot waters of many thermal springs contain more manganese than iron, such waters could yield the pure manganese oxides and carbonates found in stratified deposits . Several kinds of evidence indicate that most of the manganese in the large stratified deposits of the oxides and carbonates of manganese in many parts of the world has been derived from hydrothermal waters from depth related to centers of volcanism. Obviously, manganese derived from decay of the rocks on the lands adjacent to large basins-marine and continental -may have been added to that derived from centers of volcanism to form the sedimentary deposits found in the basins.

Economic Geology↗

USGS2007

Coastal systems and low-lying areas

Since the IPCC Third Assessment Report (TAR), our understanding of the implications of climate change for coastal systems and low-lying areas (henceforth referred to as ‘coasts’) has increased substantially and six important policy-relevant messages have emerged. Coasts are experiencing the adverse consequences of hazards related to climate and sea level (very high confidence). Coasts are highly vulnerable to extreme events, such as storms, which impose substantial costs on coastal societies [6.2.1, 6.2.2, 6.5.2]. Annually, about 120 million people are exposed to tropical cyclone hazards, which killed 250,000 people from 1980 to 2000 [6.5.2]. Through the 20th century, global rise of sea level contributed to increased coastal inundation, erosion and ecosystem losses, but with considerable local and regional variation due to other factors [6.2.5, 6.4.1]. Late 20th century effects of rising temperature include loss of sea ice, thawing of permafrost and associated coastal retreat, and more frequent coral bleaching and mortality [6.2.5]. Coasts will be exposed to increasing risks, including coastal erosion, over coming decades due to climate change and sea-level rise (very high confidence). Anticipated climate-related changes include: an accelerated rise in sea level of up to 0.6 m or more by 2100; a further rise in sea surface temperatures by up to 3°C; an intensification of tropical and extra-tropical cyclones; larger extreme waves and storm surges; altered precipitation/run-off; and ocean acidification [6.3.2]. These phenomena will vary considerably at regional and local scales, but the impacts are virtually certain to be overwhelmingly negative [6.4, 6.5.3]. Corals are vulnerable to thermal stress and have low adaptive capacity. Increases in sea surface temperature of about 1 to 3°C are projected to result in more frequent coral bleaching events and widespread mortality, unless there is thermal adaptation or acclimatisation by corals [Box 6.1, 6.4]. Coastal wetland ecosystems, such as saltmarshes and mangroves, are especially threatened where they are sediment starved or constrained on their landward margin [6.4.1]. Degradation of coastal ecosystems, especially wetlands and coral reefs, has serious implications for the well-being of societies dependent on the coastal ecosystems for goods and services [6.4.2, 6.5.3]. ncreased flooding and the degradation of freshwater, fisheries and other resources could impact hundreds of millions of people, and socio-economic costs on coasts will escalate as a result of climate change [6.4.2, 6.5.3]. The impact of climate change on coasts is exacerbated by increasing human-induced pressures (very high confidence). Utilisation of the coast increased dramatically during the 20th century and this trend is virtually certain to continue through the 21st century. Under the SRES scenarios, the coastal population could grow from 1.2 billion people (in 1990) to 1.8 to 5.2 billion people by the 2080s, depending on assumptions about migration [6.3.1]. Increasing numbers of people and assets at risk at the coast are subject to additional stresses due to land-use and hydrological changes in catchments, including dams that reduce sediment supply to the coast [6.3.2]. Populated deltas (especially Asian megadeltas), low-lying coastal urban areas and atolls are key societal hotspots of coastal vulnerability, occurring where the stresses on natural systems coincide with low human adaptive capacity and high exposure [6.4.3]. Regionally, South, South- East and East Asia, Africa and small islands are most vulnerable [6.4.2]. Climate change therefore reinforces the desirability of managing coasts in an integrated manner [6.6.1.3]. Adaptation for the coasts of developing countries will be more challenging than for coasts of developed countries, due to constraints on adaptive capacity (high confidence). While physical exposure can significantly influence vulnerability for both human populations and natural systems, a lack of adaptive capacity is often the most important factor that creates a hotspot of human vulnerability. Adaptive capacity is largely dependent upon development status. Developing nations may have the political or societal will to protect or relocate people who live in low-lying coastal zones, but without the necessary financial and other resources/capacities, their vulnerability is much greater than that of a developed nation in an identical coastal setting. Vulnerability will also vary between developing countries, while developed countries are not insulated from the adverse consequences of extreme events [6.4.3, 6.5.2]. Adaptation costs for vulnerable coasts are much less than the costs of inaction (high confidence). Adaptation costs for climate change are much lower than damage costs without adaptation for most developed coasts, even considering only property losses and human deaths [6.6.2, 6.6.3]. As post-event impacts on coastal businesses, people, housing, public and private social institutions, natural resources, and the environment generally go unrecognised in disaster cost accounting, the full benefits of adaptation are even larger [6.5.2, 6.6.2]. Without adaptation, the high-end sea-level rise scenarios, combined with other climate changes (e.g., increased storm intensity), are as likely as not to render some islands and lowlying areas unviable by 2100, so effective adaptation is urgently required [6.6.3]. The unavoidability of sea-level rise, even in the longer-term, frequently conflicts with present-day human development patterns and trends (high confidence). Sea-level rise has substantial inertia and will continue beyond 2100 for many centuries. Irreversible breakdown of the West Antarctica and/or Greenland ice sheets, if triggered by rising temperatures, would make this long-term rise significantly larger, ultimately questioning the viability of many coastal settlements across the globe. The issue is reinforced by the increasing human use of the coastal zone. Settlement patterns also have substantial inertia, and this issue presents a challenge for long-term coastal spatial planning. Stabilisation of climate could reduce the risks of ice sheet breakdown, and reduce but Chapter 6 Coastal systems and low-lying areas 317 not stop sea-level rise due to thermal expansion [Box 6.6]. Hence, it is now more apparent than it was in the TAR that the most appropriate response to sea-level rise for coastal areas is a combination of adaptation to deal with the inevitable rise, and mitigation to limit the long-term rise to a manageable level [6.6.5, 6.7].

Book chapter↗

USGS2012

USGS Environmental health science strategy: providing environmental health science for a changing world: Public review release

America has an abundance of natural resources. We have bountiful clean water, fertile soil, and unrivaled national parks, wildlife refuges, and public lands. These resources enrich our lives and preserve our health and wellbeing. These resources have been maintained because of our history of respect for their value and an enduring commitment to their vigilant protection. Awareness of the social, economic, and personal value of the health of our environment is increasing. The emergence of environmentally driven diseases caused by environmental exposure to contaminants and pathogens is a growing concern worldwide. New health threats and patterns of established threats are affected by both natural and anthropogenic changes to the environment. Human activities are key drivers of emerging (new and re-emerging) health threats. Societal demands for land and natural resources, a better quality of life, improved economic prosperity, and the environmental impacts associated with these demands will continue to increase. Natural earth processes, climate trends, and related climatic events will add to the environmental impact of human activities. These environmental drivers will influence exposure to disease agents, including viral, bacterial, prion, and fungal pathogens, parasites, natural earth materials, toxins and other biogenic compounds, and synthetic chemicals and substances. The U.S. Geological Survey (USGS) defines environmental health science broadly as the interdisciplinary study of relations among the quality of the physical environment, the health of the living environment, and human health. The interactions among these three spheres are driven by human activities, ecological processes, and natural earth processes; the interactions affect exposure to contaminants and pathogens and the severity of environmentally driven diseases in animals and people. This definition provides USGS with a framework for synthesizing natural science information from across the Bureau and providing it to environmental, natural resource, agricultural, and public-health managers. The USGS is a Federal science agency with a broad range of natural science expertise relevant to environmental health. USGS provides scientific information and tools as a scientific basis for management and policy decision making. USGS specializes in science at the environment-health interface, by characterizing the processes that affect the interaction among the physical environment, the living environment, and people, and the resulting factors that affect ecological and human exposure to disease agents. This report describes a 10-year strategy that encompasses the portfolio of USGS environmental health science. It summarizes national environmental health priorities that USGS is best suited to address, and will serve as a strategic framework for USGS environmental health science goals, actions, and outcomes for the next decade. Implementation of this strategy is intended to aid coordination of USGS environmental health activities and to provide a focal point for disseminating information to stakeholders. The "One Health" paradigm advocated by the World Health Organization (WHO, 2011), and the American Veterinary Medicine Association (AVMA, 2008), among others, is based on a general recognition that the health of humans, animals, and the environment are inextricably linked. Thus, successful efforts to protect that health will require increased interdisciplinary research and increased communication and collaboration among the broader scientific and health community. This strategy is built upon that paradigm. The vision, mission, and five cornerstone goals of the USGS Environmental Health Science Strategy were developed with significant input from a wide range of stakeholders. Vision - The USGS is a premier source of the environmental health science needed to safeguard the health of the environment, fish, wildlife, and people. Mission - The mission of USGS in environmental health science is to contribute scientific information to environmental, natural resource, agricultural, and public-health managers, who use that science to support sound decision making. USGS provides the science to: - Goal 1: Identify, prioritize, and detect contaminants and pathogens of emerging environmental concern. - Goal 2: Reduce the impact of contaminants on the environment, fish, wildlife, and people. - Goal 3: Reduce the impact of pathogens on the environment, fish, wildlife, and people. - Goal 4: Discover the complex interactions and combined effects of exposure to contaminants and pathogens. - Goal 5: Prepare for and respond to environmental impacts and related health threats of natural and anthropogenic disasters. Goals 1 through 4 are intended to provide science to address environmental health threats in a logical order, from informing prevention and preparedness, to supporting systematic management response to environmental health issues. Goal 4 addresses the interaction among contaminants and pathogens, an issue of emerging concern in environmental health science. Goal 5 acknowledges the fact that natural and anthropogenic disasters can cause immediate and prolonged adverse environmental health threats. This strategy proposes that USGS take the following strategic science actions to achieve each of the five goals of this strategy: Goal 1: Identify, prioritize, and detect contaminants and pathogens of emerging environmental concern. - Strategic Science Action 1. - Prioritize contaminants and pathogens of emerging concern to guide research, detection, and management activities. - Strategic Science Action 2. - Conduct surveillance and monitoring to provide early warning of emerging health threats. - Strategic Science Action 3. - Develop approaches and tools that identify vulnerable environmental settings, ecosystems, and species. Goal 2: Reduce the impact of contaminants on the environment, fish, wildlife, and people. - Strategic Science Action 1. - Systematically characterize the sources, occurrence, transport and fate of environmental contaminants to guide efforts to manage and mitigate contamination. - Strategic Science Action 2. - Evaluate the threats of contamination on the health of the environment, fish, wildlife, and people, and inform the associated management and protection efforts. - Strategic Science Action 3. - Characterize potential human exposure to support establishment of health-based standards or guidelines and contamination-reduction efforts. Goal 3: Reduce the impact of pathogens on the environment, fish, wildlife, and people. - Strategic Science Action 1. - Determine the biotic and abiotic factors that control the ecology of infectious diseases affecting natural populations of aquatic and terrestrial species and potential transmission to other animals and humans. - Strategic Science Action 2. - Establish how natural and anthropogenic environmental changes affect the distribution and severity of infectious diseases in natural populations of aquatic and terrestrial species and potential transmission to other animals and humans. - Strategic Science Action 3. - Develop surveillance systems to identify changing patterns of disease activity in priority geographic areas. Goal 4: Discover the complex interactions and combined effects of exposure to contaminants and pathogens. - Strategic Science Action 1. - Identify how exposure to one class of disease agents (contaminants or pathogens) can make an organism more susceptible to effects from exposure to the other class of disease agents. - Strategic Science Action 2. - Implement interdisciplinary studies that characterize the effects of combined exposure to pathogens and contaminants. Goal 5: Prepare for and respond to the environmental impacts and related health threats of natural and anthropogenic disasters. - Strategic Science Action 1. - Establish a formal interdisciplinary science capability to rapidly assess the environmental health risks associated with disasters. - Strategic Science Action 2. - Enhance methods to anticipate, prepare for, and identify environmental, ecological, and related health impacts of future disasters. This strategy is one of seven USGS science strategies developed concurrently: - Climate and Land Use Change - Core Science Systems - Ecosystems - Energy and Mineral Resources - Environmental Health - Natural Hazards - Water. This strategy describes how USGS will address the highest priority environmental health issues facing the Nation. The ultimate intended outcome of this science strategy is prevention and reduction of adverse impacts to the quality of the environment, the health of our living resources, and human health. Communication with, and receiving input from, partners and stakeholders regarding their science needs is essential for successful implementation of this strategy. It is incumbent on USGS to reach out to all stakeholders to ensure that USGS efforts are focused on the highest priority environmental health issues and that products are provided in the most timely and usable form to all those who can use them. USGS must reach out to the scientific community, internally and externally, to ensure that our efforts are integrated with and take full advantage of the activities of others.

Open-File Report↗

USGS2007

Potential for shoreline changes due to sea-level rise along the U.S. mid-Atlantic region

Sea-level rise over the next century is expected to contribute significantly to physical changes along open-ocean shorelines. Predicting the form and magnitude of coastal changes is important for understanding the impacts to humans and the environment. Presently, the ability to predict coastal changes is limited by the scientific understanding of the many variables and processes involved in coastal change, and the lack of consensus regarding the validity of existing conceptual, analytical, or numerical models. In order to assess potential future coastal changes in the mid-Atlantic U.S. for the U.S. Climate Change Science Program (CCSP), a workshop was convened by the U.S. Geological Survey. Assessments of future coastal change were made by a committee of coastal scientists with extensive professional experience in the mid-Atlantic region. Thirteen scientists convened for a two-day meeting to exchange information and develop a consensus opinion on potential future coastal changes for the mid-Atlantic coast in response to sea-level rise. Using criteria defined in past work, the mid-Atlantic coast was divided into four geomorphic compartments: spits, headlands, wave-dominated barriers, and mixed-energy barriers. A range of potential coastal responses was identified for each compartment based on four sea-level rise scenarios. The four scenarios were based on the assumptions that: a) the long-term sea-level rise rate observed over the 20th century would persist over the 21st century, b) the 20th century rate would increase by 2 mm/yr, c) the 20th century rate would increase by 7 mm/yr, or d) sea-level would rise by 2 m over the next few hundred years. Potential responses to these sea-level rise scenarios depend on the landforms that occur within a region and include increased likelihood for erosion and shoreline retreat for all coastal types, increased likelihood for erosion, overwash and inlet breaching for barrier islands, as well as the possibility of a threshold state (e.g., dramatic change in barrier evolution, such as segmentation or disintegration) for some barrier island systems. The likelihood of the potential coastal responses is expressed using standard terminology employed in climate change assessments (e.g., as used by the Intergovernmental Panel on Climate Change and CCSP). This assessment was based on the coastal geomorphology in its present condition and does not consider any coastal protection that might be undertaken in the future. The committee recognized that a variety of erosion mitigation measures have been implemented along developed portions of the coast and these are very likely to be applied in the future. It was also acknowledged that economics, political will, and other factors can drive decisions to implement these measures, and that such decisions cannot be predicted with confidence. The results of this assessment are depicted graphically on maps of the study area.

Mid-Atlantic Coast↗

USGS2022

Fifty years of Landsat science and impacts

Since 1972, the Landsat program has been continually monitoring the Earth, to now provide 50 years of digital, multispectral, medium spatial resolution observations. Over this time, Landsat data were crucial for many scientific and technical advances. Prior to the Landsat program, detailed, synoptic depictions of the Earth's surface were rare, and the ability to acquire and work with large datasets was limited. The early years of the Landsat program delivered a series of technological breakthroughs, pioneering new methods, and demonstrating the ability and capacity of digital satellite imagery, creating a template for other global Earth observation missions and programs. Innovations driven by the Landsat program have paved the way for subsequent science, application, and policy support activities. The economic and scientific value of the knowledge gained through the Landsat program has been long recognized, and despite periods of funding uncertainty, has resulted in the program's 50 years of continuity, as well as substantive and ongoing improvements to payload and mission performance. Free and open access to Landsat data, enacted in 2008, was unprecedented for medium spatial resolution Earth observation data and substantially increased usage and led to a proliferation of science and application opportunities. Here, we highlight key developments over the past 50 years of the Landsat program that have influenced and changed our scientific understanding of the Earth system. Major scientific and programmatic impacts have been realized in the areas of agricultural crop mapping and water use, climate change drivers and impacts, ecosystems and land cover monitoring, and mapping the changing human footprint. The introduction of Landsat collection processing, coupled with the free and open data policy, facilitated a transition in Landsat data usage away from single images and towards time series analyses over large areas and has fostered the widespread use of science-grade data. The launch of Landsat-9 on September 27, 2021, and the advanced planning of its successor mission, Landsat-Next, underscore the sustained institutional support for the program. Such support and commitment to continuity is recognition of both the historic impact the program, and the future potential to build upon Landsat's remarkable 50-year legacy.

Remote Sensing of Environment↗

USGS2013

Historical methane hydrate project review

In 1995, U.S. Geological Survey made the first systematic assessment of the volume of natural gas stored in the hydrate accumulations of the United States. That study, along with numerous other studies, has shown that the amount of gas stored as methane hydrates in the world greatly exceeds the volume of known conventional gas resources. However, gas hydrates represent both a scientific and technical challenge and much remains to be learned about their characteristics and occurrence in nature. Methane hydrate research in recent years has mostly focused on: (1) documenting the geologic parameters that control the occurrence and stability of gas hydrates in nature, (2) assessing the volume of natural gas stored within various gas hydrate accumulations, (3) analyzing the production response and characteristics of methane hydrates, (4) identifying and predicting natural and induced environmental and climate impacts of natural gas hydrates, and (5) analyzing the effects of methane hydrate on drilling safety. Methane hydrates are naturally occurring crystalline substances composed of water and gas, in which a solid water-‐lattice holds gas molecules in a cage-‐like structure. The gas and water becomes a solid under specific temperature and pressure conditions within the Earth, called the hydrate stability zone. Other factors that control the presence of methane hydrate in nature include the source of the gas included within the hydrates, the physical and chemical controls on the migration of gas with a sedimentary basin containing methane hydrates, the availability of the water also included in the hydrate structure, and the presence of a suitable host sediment or “reservoir”. The geologic controls on the occurrence of gas hydrates have become collectively known as the “methane hydrate petroleum system”, which has become the focus of numerous hydrate research programs. Recognizing the importance of methane hydrate research and the need for a coordinated effort, the U.S. Congress enacted Public Law 106-‐193, the Methane Hydrate Research and Development Act of 2000. This Act called for the Secretary of Energy to begin a methane hydrate research and development program in consultation with other U.S. federal agencies. At the same time a new methane hydrate research program had been launched in Japan by the Ministry of International Trade and Industry to develop plans for a methane hydrate exploratory drilling project in the Nankai Trough. Since this early start we have seen other countries including India, China, Canada, and the Republic of Korea establish large gas hydrate research and development programs. These national led efforts have also included the investment in a long list of important scientific research drilling expeditions and production test studies that have provided a wealth of information on the occurrence of methane hydrate in nature. The most notable expeditions and projects have including the following: -‐Ocean Drilling Program Leg 164 (1995) -‐Japan Nankai Trough Project (1999-‐2000) -‐Ocean Drilling Program Leg 204 (2004) -‐Japan Tokai-‐oki to Kumano-‐nada Project (2004) -‐Gulf of Mexico JIP Leg I (2005) -‐Integrated Ocean Drilling Program Expedition 311 (2005) -‐Malaysia Gumusut-‐Kakap Project (2006) -‐India NGHP Expedition 01 (2006) -‐China GMGS Expedition 01 (2007) -‐Republic of Korea UBGH Expedition 01 (2007) -‐Gulf of Mexico JIP Leg II (2009) -‐Republic of Korea UBGH Expedition 02 (2010) -‐MH-‐21 Nankai Trough Pre-‐Production Expedition (2012-‐2013) -‐Mallik Gas Hydrate Testing Projects (1998/2002/2007-‐2008) -‐Alaska Mount Elbert Stratigraphic Test Well (2007) -‐Alaska Iġnik Sikumi Methane Hydrate Production Test Well (2011-‐2012) Research coring and seismic programs carried out by the Ocean Drilling Program (ODP) and Integrated Ocean Drilling Program (IODP), starting with the ODP Leg 164 drilling of the Blake Ridge in the Atlantic Ocean in 1995, have also contributed greatly to our understanding of the geologic controls on the formation, occurrence, and stability of gas hydrates in marine environments. For the most part methane hydrate research expeditions carried out by the ODP and IODP provided the foundation for our scientific understanding of gas hydrates. The methane hydrate research efforts under ODP-‐IODP have mostly dealt with the assessment of the geologic controls on the occurrence of gas hydrate, with a specific goal to study the role methane hydrates may play in the global carbon cycle. Over the last 10 years, national led methane hydrate research programs, along with industry interest have led to the development and execution of major methane hydrate production field test programs. Two of the most important production field testing programs have been conducted at the Mallik site in the Mackenzie River Delta of Canada and in the Eileen methane hydrate accumulation on the North Slope of Alaska. Most recently we have also seen the completion of the world’s first marine methane hydrate production test in the Nankai Trough in the offshore of Japan. Industry interest in gas hydrates has also included important projects that have dealt with the assessment of geologic hazards associated with the presence of hydrates. The scientific drilling and associated coring, logging, and borehole monitoring technologies developed in the long list of methane hydrate related field studies are one of the most important developments and contributions associated with methane hydrate research and development activities. Methane hydrate drilling has been conducted from advanced scientific drilling platforms like the JOIDES Resolution and the D/V Chikyu, which feature highly advanced integrated core laboratories and borehole logging capabilities. Hydrate research drilling has also included the use of a wide array of industry, geotechnical and multi-‐service ships. All of which have been effectively used to collect invaluable geologic and engineering data on the occurrence of methane hydrates throughout the world. Technologies designed specifically for the collection and analysis of undisturbed methane hydrate samples have included the development of a host of pressure core systems and associated specialty laboratory apparatus. The study and use of both wireline conveyed and logging-‐while-‐drilling technologies have also contributed greatly to our understanding of the in-‐situ nature of hydrate-‐bearing sediments. Recent developments in borehole instrumentation specifically designed to monitor changes associated with hydrates in nature through time or to evaluate the response of hydrate accumulations to production have also contributed greatly to our understanding of the complex nature and evolution of methane hydrate systems. Our understanding of how methane hydrates occur and behave in nature is still growing and evolving – we do not yet know if methane hydrates can be economically produced, nor do we know fully the role of hydrates as an agent of climate change or as a geologic hazard. But it is known for certain that scientific drilling has contributed greatly to our understanding of hydrates in nature and will continue to be a critical source of the information to advance our understanding of methane hydrates.

Report↗

USGS1989

Geology of the Arabian Peninsula; shield area of western Saudi Arabia

Western Arabia lies within the low-latitude desert of north Africa and the Middle East, the core being the Arabian segment of the African Shield. The core of complex basement rocks accounts for about 670,000 km 2 , or one-third of the Arabian Peninsula. Reconnaissance mapping of these crystalline rocks, together with bordering sedimentary rocks and volcanic flows, begun in 1950, resulted during the next 13 years in a series of geologic and geographic maps without extensive texts. The maps served as general guides for development of natural resources, including water supplies, ore deposits, and building materials. An intensive exploration program that began in 1963 and involved numerous geologists has vastly increased geologic information. Rainfall in Arabia is meager and episodic, and vegetation is sparse except in isolated copses on the crest of the Hejaz Range. Comparison of flora with similar species in the Sudan, where records of rainfall have long been kept, allows evaluation of mean annual precipitation. Wandering bedouin following fodder created a delicate balance between population and water supply-now disturbed by wells drilled in alluvium and lava fields. A trapezoidal region of Precambrian crystalline rocks lies along the northeast flank of the Red Sea, with two long prongs extending northwest and southeast for a total of 1,800 km. These basement rocks of the Arabian Shield are well exposed on the uplands, scarp mountains, and coastal pediments where the Phanerozoic cover rocks have been stripped as a result of Paleozoic epeirogeny and Tertiary ramping. The shield outcrops are divided into three tectonic provinces by N. 45°W.- trending shear zones of the Najd fault system of latest Proterozoic and possibly earliest Paleozoic time. The southwestern province, the 'Asir1 upland, was sharply uplifted and tilted to the northeast during the Neogene. The northwestern province, consisting of the Ash Shifa'- Hisma upland as well as Jabal Shammar farther east, similarly was uplifted and tilted. These two provinces are separated by the flat-lying median N ajd province, which is chiefly bounded by the principal Najd faults. The outcrops of the shield rocks are of the Late Proterozoic Eonupper Riphean to Vendian or Infracambrian epochs, including the Ediacarian System. The most reliable isotopic ages range from about 900 to 560 m.y., but some Middle Proterozoic rocks may be present in the easternmost shield. The rocks are divided into six lithostratigraphic sequences, two plutonic suites, and an ophiolitic suite. The mafic and ultramafic volcanic and plutonic rocks of the ophiolitic suite everywhere were emplaced tectonically and are probably of different ages in different places. Some ophiolite occurs as obducted blocks, but most is highly deformed and altered to serpentinite in fault zones that mostly define sutures between different tectonic blocks or terranes within the shield. Three of the lithostratigraphic sequences consist of mafic to silicic volcanic rocks and volcanic-derived clastic rocks which, with their subvolcanic plutonic rocks of a dioritic suite, probably formed in oceanic island arcs during convergent plate tectonism. These rocks make up the primary, or first-formed, crust of the shield. Chemical analyses show that the primary shield rocks, regardless of age, are principally calc-alkalic with some associated tholeiitic varieties. Most of the layered rocks are andesitic, but they range from basalt to dacite and in places contain intercalated pillow basalt, marble, chert, and carbonaceous or graphitic schist. Most of the plutonic rocks of the dioritic suite are dioritic, but they range from gabbro to trondhjemite and rarely contain potassium feldspar. The sequences and an associated dioritic suite become younger toward the eastern shield, that is, the primary crust of the shield youngs toward the east. Two western sequences consist of the Jiddah (Samran) and BaishBahah Groups and range in radiometric age from about 900 to 800 m.y.; the eastern sequence consists of the Halaban (Hulayfah) Group and ranges from 800 to about 700 m.y. During subsequent orogeny, most of the rocks were intensely deformed and mostly metamorphosed to upper greenschist facies, but rising in places to the almandine-amphibolite facies. Two other lithostratigraphic sequences with an associated plutonic granitic suite are the products of two mountain-building episodes during which the primary crust was greatly thickened and converted into craton. The two sequences, including largely the Ablah (Al Ays) and Murdama (Shammar) Groups, consist of abundant sedimentary rocks, commonly arkosic, that are the erosional products of the orogenic mountains. They are several thousand meters thick. Less abundant calc-alkalic to alkalic volcanic rocks, commonly dacitic and rhyolitic, are intercalated with the sedimentary rocks. The plutonic rocks of the granitic suite in association with both sequences have syntectonic and posttectonic phases, are products of the orogenies, and are the principal new ingredients making up the craton. Gneiss domes were a significant part of these cratonization orogenies. In association with orogenic crustal heating, some of the low-density, more silicic tonalitic and trondhjemitic rocks of the primary crust rose as gneiss domes. Partial melting in the middle or lower crust below the gneiss domes produced large volumes of granitic magma that intruded the gneiss domes as granodioritic batholiths. The Ablah Group and the older part of the granitic suite are about 775 to 740 Ma old and are associated with the Ablah orogeny and early cratonization in the western and earlier formed half of the shield. The Murdama (Shammar) Group and the younger part of the granitic suite are about 660 to 580 Ma old and are associated with the culminant orogeny and late cratonization that was shieldwide. The granitic suite during both orogenies consists of early, syntectonic granodiorite batholiths associated with the gneiss domes and late, posttectonic monzogranite plutons. Only during the culminant orogeny, late magmatic evolution produced syenogranite and alkali-feldspar granite commonly in circular and ring-structured plutons and with associated explosive volcanic deposits (Shammar Group); final products, some of which have economic potential, were peralkalic and peraluminous. The late plutonism of the culminant orogeny was distinctly bimodal in that subordinate gabbroic rocks are associated with the granites. Various building blocks or terranes of the andesitic and dioritic primary crust were collisionally agglomerated during the Ablah orogeny, early cratonization, whereas the entire shield as currently exposed was further collisionally accreted and compressionally consolidated during the culminant orogeny, final cratonization. Thousands of kilometers of oceanic crust had to be subducted in about 300 m.y. to form the large primary crust of the Arabian Shield. The inevitable collisional events during consumption of such a large volume of oceanic crust invariably led to numerous collisional orogenies that collectively encompass the widely known Pan African tectonic episode. The youngest lithostratigraphic sequence, the Jubaylah Group, is essentially postcratonic, although it is the end product of the collisional culminant orogeny. Final east-west compression of the entire shield from about 580 to 560 m.y. caused the craton to fracture along the large northwest-trending, left-lateral faults and elsewhere along lesser, northeast-trending, right-lateral, conjugate faults of the N ajd fault system. Erosional products of this more localized deformation were the sedimentary rocks of the Jubaylah Group, which also includes intercalated andesitic to basaltic volcanic rocks of a mafic alkalic compositional trend. The collisional edge of an old continental plate (or tectonic fragments thereof), suspected on the eastern edge of the Arabian Shield, has not been shown with certainty to be exposed. Presumably, widespread contamination from such an old continental crust affects U/Pb, Sm/Nd, Rb/Sr, and common lead ratios in the young plutonic rocks of the easternmost shield. One mass of anorthosite near Jabal Khida' on the central eastern edge of the shield may be a fragment of this old continental plate in that associated granodiorite may be as old as 1,600 to 1,800 Ma. Epeirogenic uplift, erosion, and cooling of the uppermost shield during Early and Middle Cambrian time is indicated by an average fission track age of 510±52 m.y., on sphene from diorite (hornblende K-Ar age of 615±12 m.y.) in the southwestern part of the shield. The hiatus was followed by extensive deposition of the Cambro-Ordovician Saq Sandstone in the north and northeast and the Wajid Sandstone in the southeast and south of the shield. The Cambrian Siq Sandstone had already been deposited in the northern part. During the middle and late Paleozoic, broad epeirogeny caused further erosion of the shield until marine transgression deposited the Upper Permian Khuff Formation at least in the eastern part of the shield. In the southwestern shield, the nonmarine Upper Triassic Khums Sandstone was deposited variably on Wajid or Precambrian rocks and is overlain by limestone of the middle Upper Jurassic Amran Formation. Except for shallow marine sandstone of problematic Cretaceous age deposited on the Amran Formation in the south.western shield and on Precambrian rocks in the northwestern shield, the younger beds on the shield are Paleocene and younger, with the possibility that the lowermost are upper Maestrichtian. The early Tertiary beds contain vertebrate fossils of coastal marine or estuarine environment 250 km east of the Red Sea in the central shield. Marginal marine sediments were deposited in a western tongue of the latest Tethys Sea as late as Eocene on the western shield and at least as far south as Jiddah. The great harrats of flood basalt erupted on th~ western shield during late Oligocene and early Miocene at the same time a 2,000-kmlong continental rift valley developed along the future Red Sea axis. Within this rift valley, Baid freshwater tuffaceous lakebeds were deposited between mafic and silicic volcanoes. During late early Miocene time, the Red Sea opened at a rate of 4.4 cm/yr in a firststage movement while continental dikes and swarms of oceanic tholeiitic dikes, gabbro, and granophyre plutonic rocks were intruded into the rift sedimentary and volcanic rocks at the newly formed continental margin. The continental margin was deformed and greatly extended at this time. About 14 or 15 m.y., as the first-stage spreading stopped, the Red Sea Escarpment rose; its erosion caused deposition of coarse conglomerate of the Bathan Formation. About 3,000 m of evaporite was deposited on the young Red Sea oceanic crust during the late Miocene desiccation crisis. A second stage of sea-floor spreading about 4-5 m.y. produced the Red Sea axial trough, consisting of oceanic crust, as well as renewed uplift and tilting of the three tectonic provinces in response to compression from counterclockwise rotation against the Dead Sea Rift. This late movement caused widespread major stream capture, especially along the wadis that formerly drained southwesterly or northwesterly, the channels turning westward through narrow gorges to the coastal plain and the Red Sea.

Professional Paper↗

USGS2012

Nutrient removal using biosorption activated media: preliminary biogeochemical assessment of an innovative stormwater infiltration basin

Soil beneath a stormwater infiltration basin receiving runoff from a 22.7 ha predominantly residential watershed in central Florida, USA, was amended using biosorption activated media (BAM) to study the effectiveness of this technology in reducing inputs of nitrogen and phosphorus to groundwater. The functionalized soil amendment BAM consists of a 1.0:1.9:4.1 mixture (by volume) of tire crumb (to increase sorption capacity), silt and clay (to increase soil moisture retention), and sand (to promote sufficient infiltration), which was applied to develop a prototype stormwater infiltration basin utilizing nutrient reduction and flood control sub-basins. Comparison of nitrate/chloride (NO 3 - /Cl - ) ratios for the shallow groundwater indicate that prior to using BAM, NO 3 - concentrations were substantially influenced by nitrification or variations in NO 3 - input. In contrast, for the prototype basin utilizing BAM, NO 3 - /Cl - ratios indicate minor nitrification and NO 3 - losses with the exception of one summer sample that indicated a 45% loss. Biogeochemical indicators (denitrifier activity derived from real-time polymerase chain reaction and variations in major ions, nutrients, dissolved and soil gases, and stable isotopes) suggest NO 3 - losses are primarily attributable to denitrification, whereas dissimilatory nitrate reduction to ammonium is a minor process. Denitrification was likely occurring intermittently in anoxic microsites in the unsaturated zone, which was enhanced by increased soil moisture within the BAM layer and resultant reductions in surface/subsurface oxygen exchange that produced conditions conducive to increased denitrifier activity. Concentrations of total dissolved phosphorus and orthophosphate (PO 4 3- ) were reduced by more than 70% in unsaturated zone soil water, with the largest decreases in the BAM layer where sorption was the most likely mechanism for removal. Post-BAM PO 4 3- /Cl - ratios for shallow groundwater indicate predominantly minor increases and decreases in PO 4 3- with the exception of one summer sample that indicated a 50% loss. Differences in nutrient variations between the unsaturated zone and shallow groundwater may be the result of the intensity and duration of nutrient removal processes and mixing ratios with water that had not undergone significant chemical changes. Observed nitrogen and phosphorus losses demonstrate the potential, as well as future research needs to improve performance, of the prototype stormwater infiltration basin using BAM for providing passive, economical, stormwater nutrient-treatment technology to support green infrastructure.

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