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Observing northern high-latitude river systems to understand changes in a warming Arctic

Purpose of Review Streams and rivers are undergoing rapid change as the Arctic warms and thaws. We review recent observations in Arctic stream systems to identify ubiquitous changes and the most useful tools for observing change and exploring the underlying processes. Recent Findings Recent literature indicates increasingly significant trends in river hydrology and chemistry due to persistent warming in the Arctic and longer observational records for analysis. However, regional differences in the magnitude and direction of these trends persist. We also observe thresholds in ground thaw and surface–groundwater interactions that can impact river hydrology and chemistry. Summary Warming and thaw are occurring rapidly at high latitudes, resulting in increasing, yet variable responses in stream systems across regions and scales. These differences highlight the need for long-term records and an interdisciplinary approach to explain trends and predict future states. Stream systems respond to multiple landscape changes related to hydrology (changing precipitation and subsurface flow), geology (ground thaw dynamics), and ecology (vegetation change).

Current Climate Change Reports

Hydrogeology of unconsolidated and bedrock aquifers along the Salmon River, including Malone, Franklin County, New York

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, investigated the hydrogeology of the unconsolidated and bedrock aquifers along the Salmon River corridor in northern Franklin County, New York. The study area covers roughly 147 square miles and includes the village of Malone and parts of the Towns of Malone, Bellmont, Burke, Constable, Westville, Bangor, Duane, and Franklin, New York. Groundwater is the primary source for water supply within the study area. Eighty-three percent of all residents use public water supplied from two production wells that draw water from a thick, highly productive sand-and-gravel aquifer likely receiving induced infiltration from the Salmon River. Twenty-four percent of the 187 verified domestic wells in the study area outside of the production well service area boundary are screened in typically discontinuous deposits of stratified sand and sand and gravel. Seventy-six percent of the wells are completed in bedrock aquifers including the Potsdam Sandstone, metamorphic rocks, Theresa Formation, and unknown bedrock. Characterizing and understanding potential groundwater resources is critical for protecting the quality of the groundwater. The information in this report may be used to guide delineation of groundwater contributing areas, assess potential threats to aquifers from both point and nonpoint sources, respond to contamination from spills or leaks from underground storage facilities or other sources, and to support assessments for future development of municipal water supplies.

New York

New 10Be-26Al isochron burial dating informs the Pliocene and Pleistocene evolution of the lower Colorado River, southwestern United States

Four new 10 Be- 26 Al isochron burial ages ranging from 4.4 to 2 Ma on ancestral Colorado River deposits in the lower Colorado River corridor (LCRC) help constrain the river’s evolution during the Pliocene and early Pleistocene. They help fill a gap between previous work that focused on older and younger deposits: Older dated deposits include the 5 Ma Bouse Formation, which records the integration of the Colorado River through a series of preexisting basins to the Gulf of California and the ca. 4.5 - 3.5 Ma Bullhead Alluvium, a 200 to 300 m thick aggregational package that immediately followed integration. The much younger, 100 - 70 ka, Chemehuevi Formation is another major aggradation package mapped throughout the LCRC. The new burial ages on the facies of Santa Fe Railway (4.37 ± 0.71 Ma), boulder conglomerate of Bat Cave Wash (2.12 ± 0.26 and 2.05 ± 0.31 Ma), and the Palo Verde alluvium (3.03 ± 0.26 Ma) partially fill in a 3.5 M.y. gap between the deposition of the Bullhead Alluvium and the Chemeheuvi Formation and document the timescales over which the Colorado River was able to remove the Bullhead aggradational package and initiate newer and smaller aggradational pulses.

Arizona, California, Nevada

Determination of baseline water-quality conditions using continuous specific conductance and discrete measurements of total dissolved solids and selected major ions, Arkansas River Basin, Colorado

From 2022 through 2024, the U.S. Geological Survey (USGS) in cooperation with the Regional Resources Planning Group (Southeastern Colorado Water Conservancy District, Colorado Springs Utilities, Pueblo Water, Lower Arkansas Valley Water Conservancy District, Aurora Water, and Upper Arkansas Water Conservancy District) established a basinwide water-quality monitoring network in the Arkansas River Basin in Colorado. The study leveraged ongoing continuous measurements of streamflow and specific conductance (SC) at 13 sites along the main stem Arkansas River and Fountain Creek from the USGS 07108600 Arkansas River at Granite, Colo., (Ark Granite) site to the USGS 07137500 Arkansas River near Coolidge, Kansas, (Ark Coolidge) site. Baseline water-quality conditions were established using data from October 1989 through September 2022 to help identify changes in water quality that could result from changes in land and water use. Total dissolved solids (TDS) concentration was the main indicator of general water quality in this study because it can be accurately estimated from SC and is sensitive to changes in streamflow, water operations, and source contributions. Median TDS concentrations in Arkansas River samples (October 1989 through December 2023) ranged from 75 milligrams per liter (mg/L) at Ark Granite near the headwaters to 3,660 mg/L at Ark Coolidge near the Colorado–Kansas State line. Distinct seasonal differences in median streamflow and TDS were apparent during the winter and summer months. Seasonal Kendall tests showed no significant trends in monthly mean streamflow (October 1995 through September 2022) at Arkansas River sites upstream from Pueblo Reservoir. Upward trends in TDS concentrations and loads occurred only at Ark Granite. Downward trends in streamflow, TDS concentrations, and TDS loads occurred at Arkansas River sites from USGS 07109500 Arkansas River near Avondale, Colo., to Ark Coolidge. Downward trends in streamflow and SC (surrogate for TDS) were more prevalent during winter base flow months and may indicate changes in groundwater quantity, and possibly groundwater quality, potentially affecting the river water-quality condition.

Colorado

Spatially referenced watershed models for the binational Red–Assiniboine River Basin: Bayesian vs frequentist comparison

Excess nutrient loading remains a leading cause of declining water quality in lakes, estuaries, and coastal waters worldwide, with global economic costs of US$200 billion – US$2 trillion annually from impacts on fisheries, tourism, freshwater resources, and water treatment. Our study focuses on total phosphorus (TP) in Lake Winnipeg and its binational Red-Assiniboine River Basin, where nutrient inputs have degraded water quality and increased cyanobacterial blooms. These changes pose ecological, public health, and economic risks. We applied a spatially referenced watershed model with a hybrid statistical-mechanistic structure partitioning annual nutrient loads into land-use export, land-to-water delivery, and in-reservoir decay. Bayesian and traditional frequentist model calibrations were compared. In the frequentist model, coefficients for agricultural inputs, forests /wetlands, stream channels, precipitation, and reservoir losses were statistically significant, whereas coefficient for wastewater was not. In contrast, all variables were successfully calibrated using the Bayesian approach. Model results delineate TP-export hotspots across the basin, showing that 54–62% of TP originates from the U.S., with agricultural sources ranging 62–72%—highlighting the importance of agriculture-focused Best Management Practices. Given the global relevance of nutrient-driven water-quality challenges, our results highlight Bayesian calibration for robust risk assessment and adaptive nutrient management.

Red–Assiniboine River Basin

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ~1,900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1,500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (~1,000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

EarthArXiv

Detecting hidden sedimentary geothermal systems in the Upper Colorado River Basin

Geothermal resources exist in sedimentary rock where circulation of water for efficient extraction or storage of heat is possible. Except in rare instances where hot water is expressed at the land surface, sedimentary geothermal resources are hidden, so the identification of these systems is optimally accomplished using predictive subsurface modeling. An integrated approach using detailed paleogeographic interpretations, subsurface geologic mapping, and numerical modeling has produced regional geologic and temperature models for the Upper Colorado River Basin, a large watershed in central North America that contains many sedimentary basins. These models identify areas of hidden sedimentary geothermal resource potential in low temperature (<90°C), moderate temperature (90–150°C), and high temperature (>150°C) fairways across the study area. These models incorporate maps of key horizons in outcrop and the subsurface to create a robust structural framework that can be used to target favorable geology for natural or engineered permeability. This framework is populated with lithologies derived from detailed palaeogeographical maps and over 40,000 bottom hole temperature (BHT) values were used to create a calibrated three-dimensional (3D) temperature model across the region. The resulting maps serve as a regional sedimentary geothermal play fairway screening tool for evaluating different grades of sedimentary geothermal resources and for identifying areas of interest where more detailed, prospect-scale studies can be undertaken.

Arizona, Colorado, New Mexico, Utah, Wyoming

Tracing mercury from land to river: Global sources, retention, and implications for sustainability

Mercury (Hg) pollution in river systems is a global sustainability challenge. Yet the transport, transformation, and retention of Hg within global rivers remain poorly quantified, particularly in regions with sparse observations such as Southeast Asia and Africa, hindering effective pollution mitigation and reinforcing geographic inequities in scientific knowledge and environmental governance. Here, we present the first global, high-resolution simulation of riverine Hg dynamics using a process-based model that traces Hg from land-based sources through river networks to the ocean. Under a realistic scenario, we estimate that ∼1900 megagrams per year (Mg/yr) of Hg enters global rivers, including 1500 Mg/yr from human-induced sources and 400 Mg/yr from soil erosion. Nearly half of this flux (∼1000 Mg/yr) is retained in reservoirs and dams, which act as major sinks. While such retention limits downstream delivery to the oceans, it also heightens in-reservoir Hg methylation risks. By bridging the gap between Hg releases and observed riverine exports, our framework offers a scalable tool for data-limited regions, promotes data access, and supports global freshwater and pollution-management strategies.

Environmental Science & Technology

Pesticides in surface water from three agricultural basins in south-central Georgia, 1993-97

Twenty-two of 43 pesticides analyzed were detected in 128 water samples collected from the Tucsawhatchee Creek, the Little River, and the Withlacoochee River. These streams drain agricultural basins in south-central Georgia and were sampled from March 1993 through June 1995. Herbicides were detected more frequently than insecticides. The most frequently detected herbicides were atrazine and metolachlor and the most frequently detected insecticide was carbaryl. Pesticide concentrations in the three streams were low and did not exceed U.S. Environmental Protection Agency drinking water standards. The maximum pesticide concentration was 2.6 mg/L (micrograms per liter) for propargite, a miticide detected in only one sample. The maximum concentrations of the remaining 21 pesticides were less than 0.25 mg/L. The median concentrations were equal to the method detection limit for all pesticides except atrazine (0.008 mg/L) and metolachlor (0.012 mg/L). The ratio of herbicide detections to nondetections was largest in the planting season, smaller in the harvest season and smallest in the fallow season for the three basins. The same pattern existed for the insecticide ratios in the Little River and the Withlacoochee River. Pairwise correlations between concentrations of atrazine and metolachlor, and four parameters (discharge, and concentrations of dissolved organic carbon, suspended organic carbon, and suspended sediment) were evaluated for each stream. The strongest correlations existed between metolachlor and mean daily discharge, and metolachlor and sediment in the Withlacoochee River. The only significant correlation for the Little River was between atrazine and suspended sediment.

Georgia

Tracing metal sources and groundwater flow paths in the Upper Animas River watershed using rare earth elements and stable isotopes

Groundwater flow paths and processes that govern metal mobility and transport are difficult to characterize in mountainous bedrock watersheds. Despite the difficulty in holistic characterization, conceptual understanding of subsurface hydrologic and geochemical processes is key to developing remediation plans for locations affected by acid mine drainage, such as the Upper Animas River watershed in southwestern Colorado, USA. Stable isotopes of water and rare earth elements were utilized to evaluate groundwater flow and metal sources within this complex catchment. Stable isotope samples collected from draining mine adits and springs display systematic spatial variation wherein sample sites at higher elevations have greater seasonal variability than sites at lower elevations. The Upper Cement Creek watershed, where multiple draining mines are present, displays the lowest seasonal variation in stable isotopic signatures, potentially indicating the presence of a large, well-mixed volume of groundwater storage or interbasin groundwater flow. Rare earth elements display statistically significant variation between different alteration styles in the catchment. Overprinting of regional propylitic alteration is evident based on enrichment of middle rare earth elements in acidic springs and mines that are not spatially associated with surficial exposures of acid generating alteration styles. Europium anomaly and middle rare earth enrichment signatures from two flooded mine tunnels on opposite sides of a watershed divide indicate connections to the same subsurface flooded mine workings.

Colorado

Per- and polyfluoroalkyl substances (PFAS) mass flux and mass balance at an aqueous film-forming foam release site in semiarid eastern New Mexico, USA

Passive flux meters (PFMs) directly measure groundwater chemistry mass flux and Darcy flux, providing insight into contaminant source-zone architecture and transport properties. This study uses PFMs to characterize PFAS flux in groundwater at a semiarid site with a thick (greater than 90-m) unsaturated zone where groundwater has been contaminated with per - and polyfluoroalkyl substances (PFAS) related to the use of aqueous film-forming foam (AFFF) for fire training and fire suppression. PFAS mass discharge (PFAS mass flux integrated over a control plane) in groundwater downgradient from several PFAS release areas is calculated using PFM results. In groundwater downgradient from fire-training areas, total PFAS mass discharge (summed across 14 compounds) was estimated to be between 6.0 and 31 g per day in 2020 and between 5.9 and 23 g per day in 2021. Site-specific documentation, generic information on AFFF properties, and literature values of PFAS concentration in AFFF are used to estimate site-specific PFAS-application rates at fire-training areas. These PFAS-application rates are compared to groundwater PFAS-discharge rates. Results suggest that transformation processes (exact pathways unknown) have led to increased discharge of measured PFAS in groundwater relative to initial AFFF formulations. The mass balance approach has broad applicability as a high-level approach that can provide insight into PFAS transport at AFFF sites.

New Mexico

Three-dimensional hydrogeologic framework model of the Russian River watershed, California

The Russian River watershed is in northern Sonoma County and southern Mendocino County, California, in the northern part of the California Coast Ranges. The Russian River serves as a supply for agricultural irrigation and for municipal, domestic, and commercial uses. Through a cooperative agreement with the California State Water Resources Control Board and Sonoma County Water Agency, the U.S. Geological Survey has completed studies to better understand the hydrogeologic system and develop numerical hydrologic modeling tools to evaluate and aid in managing groundwater resources. This report focuses on the development of a digital three-dimensional hydrogeologic framework model of the Russian River watershed for use in groundwater resource assessment and numerical models. The digital three-dimensional hydrogeologic framework model of the Russian River watershed portrays the altitude, thickness, and extent of five hydrogeologic units. These five hydrogeologic units include (1) a basement unit, (2) the Sonoma Volcanics, (3) a consolidated sedimentary rock unit, (4) an unconsolidated sediment unit, and (5) channel alluvium. Model input data were compiled from published geologic maps, interpreted well data, and a model of the top of basement derived from gravity data. These data were used to construct surfaces that represent the upper and lower subsurface boundaries of each hydrogeologic unit. Top surfaces were created for the five hydrogeologic units and then stacked in three dimensions to create a solid-volume digital model. The digital three-dimensional hydrogeologic framework model described in this report and the corresponding data represent the generalized geometry of the subsurface geologic units; the model reproduces the input geologic data with reasonable accuracy and is consistent with previously published subsurface conceptualizations of the region. The model indicates the overall geometry of the basement within the watershed and the spatial extent, altitude, and thickness of the basin-filling units. The hydrogeologic framework model is at a scale and resolution appropriate for use as the foundation for a numerical hydrologic model of the study area.

California

Streamflow, base-flow, and precipitation trends and simulated effects of groundwater withdrawals from the North Fork Red River aquifer on base flows upgradient from Lake Altus, western Oklahoma, 1980–2022

The U.S. Geological Survey, in cooperation with the Bureau of Reclamation, used five scenarios created from a previously published numerical groundwater-flow model (1980–2013) and historical streamflow records (1980–2022) to investigate the relation between groundwater withdrawals from the North Fork Red River aquifer and inflows to Lake Altus from the North Fork Red River in western Oklahoma. The five scenarios were (1) a scaled-equal-proportionate-share (EPS) groundwater-withdrawal scenario, (2) a study-area-scaled-reported groundwater-withdrawal scenario, (3) a zonal-scaled-reported groundwater-withdrawal scenario, (4) a historical drought-threshold scenario, and (5) a base-flow and evapotranspiration depletion scenario. For the scaled-EPS groundwater-withdrawal scenario, EPS groundwater withdrawals were often much higher than reported groundwater withdrawals and greatly decreased base flows for most scale factors. For the study-area-scaled-reported groundwater-withdrawal scenario, base flows were reduced more but by smaller percentages during wet periods than during dry periods when scaling simulated reported groundwater withdrawals. For the zonal-scaled-reported groundwater-withdrawal scenario, scaling simulated reported groundwater withdrawals within selected zones with more groundwater withdrawals did not always affect base flows more than scaling reported groundwater withdrawals within zones with less groundwater withdrawals. For the historical drought-threshold scenario, curtailing groundwater withdrawals at the drought thresholds increased annual base flows to Lake Altus by about 1,169 to 3,665 acre-feet. For the base-flow and evapotranspiration depletion scenario, the distance between a groundwater well and a stream was a major factor affecting base flow to the North Fork Red River when increasing groundwater withdrawals; however, spatially variable hydrologic properties and saturated-zone evapotranspiration could also affect the relation between base flows and groundwater withdrawals.

Oklahoma

Peak-discharge frequency and potential extreme peak discharge for natural streams in the Brazos River basin, Texas

The 2-, 5-, 10-, 25-, 50-, and 100-year peak discharges were estimated for 186 streamflow-gaging stations with at least 8 years of data for natural streams in and near the Brazos River Basin, Texas. Multiple regression equations were developed to estimate peak-discharge frequency for the 2-, 5-, 10-, 25-, 50-, and 100-year recurrence intervals for each of three hydrologic regions that compose the Brazos River Basin. The equations for each region are a function of significant basin characteristics (explanatory variables). The significant explanatory variables among six that were tested are the contributing drainage area and stream slope for regions 1 and 2 and the contributing drainage area for region 3. For the three sets of equations, the coefficient of determination ranges from 0.59 to 0.93, and the standard error ranges from 0.184 to 0.391 log units. A larger coefficient of determination and a lower standard error generally are associated with the equations for hydrologic regions 2 and 3. Statistics from the regression analysis allow computation of the prediction interval associated with a given significance level for a peak-discharge frequency estimate. The regression equations can be used to estimate peak discharges for sites at, near, or away from sites with streamflow-gaging stations. The potential extreme peak-discharge curves as related to contributing drainage area were estimated for each of the three hydrologic regions from measured extreme peaks of record at 186 sites with streamflow-gaging stations and from measured extreme peaks at 37 sites without streamflow-gaging stations in and near the Brazos River Basin. The potential extreme peak-discharge curves generally are similar for hydrologic regions 1 and 2, and the curve for region 3 consistently is below the curves for regions 1 and 2, which indicates smaller peak discharges.

Texas

Navigating uncertainty and competing objectives: Spring chinook salmon recovery in the upper Willamette river

Globally, anadromous fish populations are threatened with extinction due to multiple factors, including river impoundments that block migration, widespread alteration of physical habitat, temperature, and flow regimes, commercial and recreational harvest, changes in biological communities, and long-term climate trends. In this synthesis, we describe how physical and biological factors, policy and law, and public resource allocation affect management of spring-run Chinook Salmon ( Oncorhynchus tshawytscha ) in the Upper Willamette River (UWR), Oregon, USA. Efforts to restore salmon populations often involve trade-offs, for example, water management decisions must account for flood control, agricultural and municipal water use, and management of other species. UWR Chinook Salmon recovery efforts are also governed by multiple laws, policies, and action agencies that in some cases have incongruent objectives. Competing and conflicting objectives, combined with uncertainty regarding the outcomes of proposed management actions, create significant challenges for decision makers. Resource limitations, regulatory constraints, and incongruent objectives have created challenges for managers in the UWR, but opportunities exist for improved adaptive management and collaboration, which could build trust and engagement among stakeholders and ultimately support the successful implementation of decision tools. A suite of decision support tools that have been used in the Willamette River basin and elsewhere across the range of Pacific salmon have the potential to enhance decision processes. These tools can be effective when decision makers and stakeholders commit to long-term, collaborative utilization of the tools for decision making, and when available resources and regulatory environments are conducive to implementation and adaptive refinement of both the decision-support tools and management plans. The general biological and institutional principles discussed for UWR Chinook Salmon in this work apply more generally to populations of anadromous fishes across their range, especially to populations in highly regulated river systems.

Oregon

Water-quality characteristics of the Red River of the North and tributaries in the Fargo-Moorhead metropolitan area, North Dakota, 2019–22

The Flood Risk Management Project was initiated in 2008 in the Fargo-Moorhead metropolitan area to reduce flood risk, flood damages, and flood protection costs in the Fargo-Moorhead metropolitan area. In cooperation with the U.S. Army Corps of Engineers, the U.S. Geological Survey initiated a water-quality monitoring study to describe the water-quality characteristics of the Red River of the North and its tributaries in the Fargo-Moorhead metropolitan area during the preconstruction period of the Flood Risk Management Project from October 1, 2019, to October 1, 2022. The monitoring study included the collection of discrete and continuous water-quality data and streamflow monitoring at selected sites that integrated and enhanced existing monitoring programs within the study area. Discrete samples collected at 10 sites in the Fargo-Moorhead metropolitan area were analyzed for major ions, trace elements, nutrients, suspended sediment, pesticides, and fecal indicator bacteria. In general, major ion concentrations were higher at sites on the tributaries (Wild Rice, Sheyenne, and Maple Rivers) compared to sites on the Red River of the North. In general, bicarbonate, calcium, magnesium, and sulfate represented most of the dissolved ions measured in samples collected at the 10 sites. Calcium, chloride, fluoride, potassium, silica, and sodium were also measured in samples, but they represented a smaller portion of the total dissolved ions. Sulfate was the most dominant dissolved ion that had the highest concentrations among the major ions measured in samples. A total of 18 trace elements were analyzed in discrete samples. Several of the trace elements had concentrations below the laboratory reporting level in all of the samples, including antimony, beryllium, cadmium, chromium, silver, and thallium. Sites on the Wild Rice River generally had the highest concentrations of arsenic, barium, boron, manganese, and nickel compared to the other sites. Nutrients analyzed in discrete samples included filtered and unfiltered concentrations of ammonia, nitrate plus nitrite, phosphorus, and organic carbon. The median filtered ammonia concentration at most sites was less than the laboratory reporting level of 0.03 milligram per liter as nitrogen except for the Sheyenne River at Harwood, North Dakota (U.S. Geological Survey [USGS] station 05060400), and Red River of the North near Georgetown, Minnesota (USGS station 05062130). The lowest median unfiltered nitrate plus nitrite concentration was measured at sites on the Red River of the North upstream from the Fargo-Moorhead metropolitan area and the highest median was at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to all other sites. The increase in nitrate plus nitrite concentrations could reflect the effect of the wastewater-treatment plant discharge that enters the Red River of the North upstream from the site located downstream from the Fargo-Moorhead metropolitan area and from urban runoff. Phosphorus (unfiltered) concentrations were generally higher at sites on the Maple and Sheyenne Rivers compared to the other sites and were higher at sites on the Red River of the North downstream from the Fargo-Moorhead metropolitan area compared to sites upstream on the Red River of the North. Suspended-sediment concentrations were generally highest at sites in the Sheyenne River and lowest in the upstream Red River of the North sites. Suspended-sediment concentration was highly variable in samples collected at the 10 sites, mostly influenced by the occurrence of snowmelt and rainfall-runoff events. The Sheyenne River near Kindred, N. Dak. (USGS station 05059000) had the largest range in sediment concentrations in samples collected at the 10 sites. For all sites other than the Sheyenne River near Kindred, N. Dak., 95 percent or more of the suspended sediment had particle diameter sizes less than 0.0625 millimeter in 50 percent of the samples (median). Of the 102 pesticides and pesticide degradates analyzed, 45 constituents had no detectable concentrations in any of the 17 samples collected at five sites. The remaining 57 pesticides had at least one detection in the samples collected at the five sites. The sites on the Wild Rice River (near Abercrombie, N. Dak., USGS station 05053000, and near St. Benedict, N. Dak., USGS station 05053500) and Sheyenne River near Kindred, N. Dak., had fewer pesticide detections compared to the Maple River below Mapleton, N.Dak. (USGS station 05060100) and the Red River of the North at Fargo, N. Dak (USGS station 05054000) and near Georgetown, Minn. Patterns in annual loads generally followed the same pattern as streamflow at the 10 sites for water years 2020–22. A water year is the 12-month period from October 1 to September 30 and is designated by the calendar year in which it ends. The greatest loads for all constituents were delivered at the two downstream sites on the Red River of the North; sites that also had the highest annual streamflows among the sites and the greatest loads were delivered in water year 2020 when the highest streamflows occurred at the sites. Likewise, the least loads for most constituents were at the Maple River and were least in 2021 compared to the other years because of low-streamflow conditions. Water-quality measurements continuously recorded at the Red River of the North at Hickson, N. Dak. (USGS station 05051522); Red River of the North at Fargo, N. Dak.; and Red River of the North near Georgetown, Minn. included water temperature, specific conductance, dissolved oxygen, pH, and turbidity. Specific conductance values were similar for the Red River of the North near Hickson, N. Dak., and Red River of the North at Fargo, N. Dak., when compared to the Red River of the North near Georgetown, Minn. that had higher values than the other two sites. Dissolved oxygen concentrations and pH were similar among the three sites on the Red River. The patterns in turbidity were mostly related to streamflow conditions and were similar among the three sites on the Red River of the North.

Minnesota, North Dakota

Hydrogeologic conceptual model of groundwater occurrence and brine discharge to the Dolores River in the Paradox Valley, Montrose County, Colorado

Salinity, or total dissolved solids (TDS), of the Colorado River is a major concern in the southwestern United States where the river provides water to about 40 million people for municipal and industrial use and is used to irrigate about 5.5 million acres of land. Much of the salinity in the Colorado River Basin is derived from natural interactions of surface water and groundwater with various geologic materials (rocks, soils, and alluvial deposits). The Dolores River in southwest Colorado is a major tributary of the Colorado River that historically accounts for about 6 percent of the salinity load to the Upper Colorado River Basin with the Paradox Valley being the primary source of salinity to the Dolores River. The Paradox Valley, one of several salt-anticline valleys in the region, is a fault-bounded topographic basin aligned with and exposing an underlying salt-anticline core. Salt deposits in the Pennsylvanian Paradox Formation of the Hermosa Group form an elongated salt diapir oriented northwest to southeast that is up to 12,000 feet (ft) thick beneath the present valley floor. Surface erosion, groundwater circulation, and weathering during Tertiary and Quaternary valley formation contributed to development of a cap rock, collapse features, breccia, and brine at the top of the exposed salt diapir. Today (2023), brine occurring in the brecciated cap rock and underlying salt deposits is in hydraulic connection with an overlying freshwater alluvial aquifer, and depending on seasonal river stage and hydrologic conditions, the brine discharges to the Dolores River causing the observed increase in salinity as the river crosses the Paradox Valley. To reduce salinity concentrations in the Dolores River, the Bureau of Reclamation (Reclamation) operates the Paradox Valley Unit (PVU). The PVU project consists of nine shallow brine pumping wells near the Dolores River and one deep disposal well where the brine is injected for disposal. When operational, the PVU pumping wells extract brine from the base of the alluvial aquifer that is piped and injected into a deep disposal well about 3 miles southwest of the PVU. The PVU became fully operational July 1, 1996, and by 2015, operation of the PVU had reduced salinity concentrations in the Dolores River by as much as 70 percent compared to pre-PVU conditions. In response to a 4.5 magnitude earthquake, injection operations, and thus PVU pumping, were ceased from March 2019 to June 2022. A trial period of PVU operation began in June 2022 with a reduced injection rate, and thus PVU pumping rate, of about two-thirds capacity to gather additional information and guide future operational decisions. In cooperation with Reclamation, the U.S. Geological Survey (USGS) developed this report to present the current (2023) understanding of groundwater and brine occurrence and discharge to the Dolores River in the Paradox Valley. Results from the compilation of spatial datasets, groundwater sampling and age dating, and aquifer tests are presented to provide improved understanding of the Paradox Valley hydrogeology, to supply datasets for a numerical groundwater-flow and brine-transport model, and to support future operations of the PVU. The hydrogeologic data provided herein, along with the most recent loading analysis for the Dolores River in the Paradox Valley, and a previous conceptual model for brine discharge to the river are used to present a conceptual understanding of groundwater occurrence in the Paradox Valley.

Colorado

Agricultural return flow dynamics on a reach of the East River, Colorado, as assessed by mass balance

The U.S. Geological Survey, in cooperation with the Upper Gunnison River Water Conservancy District, studied historical streamflow in a reach of the East River, Colorado, to gain a preliminary understanding of return flow dynamics. Return flow is agricultural irrigation water that is not consumed by evapotranspiration and instead reaches streams by surface and subsurface flow paths. The study reach had a contributing area of 50 square miles and contained 5.23 square miles of pastures irrigated with water diverted from the East River and its tributaries. By comparing upstream inflows to downstream outflows, the net water balance of the study reach from 1994 to 2023 was assessed. Two general hydrologic conditions for the study reach were identified. One hydrologic condition was characterized by a net loss or consumption of water, termed here as general deficit. This general deficit condition extended about 16 years, from 1997 to 2012. During general deficit years, there was usually a notable net loss of streamflow from April through July, and a small net gain, possibly related to return flows, occurred in August about 75 days after the minimums for losses. The second hydrologic condition was characterized by a net gain of water, termed here as general surplus. This second condition extended about 10 years, from 2014 to 2023. During general surplus years, two separate transitions from net loss to net gain commonly occurred during June through August. Losses during general surplus years were smaller than losses during general deficit years, the respective gains were larger, and times between losses and gains were about 18 and 22 days. Differences between the two hydrologic conditions could reflect interactions among irrigation water, available capacity to store additional shallow groundwater, and streamflow. However, deciphering the causes for the shifts between the two general hydrologic conditions was beyond the scope of this report.

Colorado