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USGS2001

Effects of land use and travel time on the distribution of nitrate in the Kirkwood-Cohansey aquifer system in southern New Jersey

Residents of the southern New Jersey Coastal Plain are increasingly reliant on the unconfined Kirkwood-Cohansey aquifer system for public water supply as a result of increasing population and restrictions on withdrawals from the deeper, confined aquifers. Elevated nitrate concentrations above background levels have been found in wells in the surficial aquifer system in agricultural and urban parts of this area. A three-dimensional steady-state ground-water-flow model of a 400-square-mile study area near Glassboro, New Jersey, was used in conjunction with particle tracking to examine the effects of land use and travel time on the distribution of nitrate in ground and surface water in southern New Jersey. Contributing areas and ground-water ages, or travel times, of water at ground-water discharge points (streams and wells) in the study area were simulated. Concentrations of nitrate were computed by linking land use and age-dependent nitrate concentrations in recharge to the discharge points. Median concentrations of nitrate in water samples collected during 1996 from shallow monitoring wells in different land-use areas were used to represent the concentration of nitrate in aquifer recharge since 1990. On the basis of upward trends in the use of nitrogen fertilizer, the concentrations of nitrate in aquifer recharge in agricultural and urban areas were assumed to have increased linearly from the background value in 1940 (0.07 mg/L as N) to the 1990 (2.5-14 mg/L as N) concentrations. Model performance was evaluated by comparing the simulation results to measured nitrate concentrations and apparent ground-water ages. Apparent ground-water ages at 32 monitoring wells in the study area determined from tritium/helium-3 ratios and sulfur hexafluoride concentrations favorably matched simulated travel times to these wells. Simulated nitrate concentrations were comparable to concentrations measured in 27 water-supply wells in the study area. A time series (1987-98) of nitrate concentrations at base-flow conditions in three streams that drain basins of various sizes and with various land uses was compared to simulated concentrations in these streams. In all three of the streams, a reasonable fit to the measured concentrations was achieved by multiplying the simulated concentration by 0.6. Because nitrate appeared to move conservatively (not degraded or adsorbed) in ground water to wells, the apparent non-conservative behavior in streams indicates that about 40 percent of the nitrate in aquifer recharge is removed by denitrification in the aquifer near the streams and (or) by in-stream processes. The model was used to evaluate the effects of various nitrate management options on the concentration of nitrate in streams and water-supply wells. Nitrate concentrations were simulated under the following management alternatives: an immediate ban on nitrate input, reduction of input at a constant rate, and fixed input at the current (2000) level. The time required for water to move through the aquifer results in a time lag between the reduction of nitrate input in recharge and the reduction of nitrate concentration in streams and wells. In the gradual-reduction alternative, nitrate concentrations in streams and wells continued to increase for several years after the reduction was enacted. In both the immediate-ban and gradual-reduction alternatives, nitrate concentrations remained elevated above background concentrations long after nitrate input ceased. In the fixed-use alternative, concentrations in streams and wells continued to increase for 30 to 40 years before reaching a constant level. The spatial distributions of simulated nitrate concentrations in streams in 2000 and 2050 were examined with the assumption of no change in land use, nitrate concentration in recharge, or ground-water withdrawals. As expected, nitrate concentrations were highest in agricultural areas and lowest in largely undeveloped areas.

New Jersey↗

USGS1981

Stormwater quality processes for three land-use areas in Broward County, Florida

Systematic collection of rainfall, runoff, and water-quality samples from three small urban areas of Broward County, Florida, were obtained between 1974 and 1977. Stormwater loads for 30 or more storms were computed for the residential, highway, and commercial investigation areas. Stepwise, multiple, linear regression models were constructed for total nitrogen, total phosphorus, total carbon, chemical oxygen demand, total residue, lead, and zinc. Loadings, pounds per day per acre of hydraulically effective impervious area, were computed based on measured, modeled, and estimated loads for the three areas. Atmospheric loads were estimated from chemical analyses of bulk precipitation collected at the highway and commercial sites. The atmospheric contribution to the runoff loads were 49 percent or more for all seven constituents at the two sites.

Florida↗

USGS1994

Relations of borehole resistivity to the horizontal hydraulic conductivity and dissolved-soils concentration in water of clastic coastal plain aquifers in the southeastern United States

Aquifer bulk resistivity and grain-surface resistivity (inverse of grain-surface conductance) were tested as geoelectrical analogs to the horizontal hydraulic conductivity of clastic, freshwater aquifers in the Southeastern United States. Bulk resistivity was also tested as a geoelectrical analog for dissolved-solids concentrations in aquifer water. Bulk resistivity was defined as the average resistivity across a contributing interval measured by the long-normal (64-inch) or induction log. Grain-surface resistivity was empirically defined as the difference between aquifer bulk resistivity and aquifer water resistivity (computed from specific conductance). Sources of data were borehole geophysical logs and results of water-quality and aquifer-test analyses related to unconsolidated sands and clayey sands at more than a hundred sites in seven Southeastern States. Waterbearing units were composed of sediments ranging from the Late Cretaceous to middle Eocene. All bivariate data were related using the logarithmic regression model Y=AX B. Aquifer bulk resistivity and grain-surface resistivity were moderately correlated to horizontal hydraulic conductivity (70 and 72 percent correlation coefficients, respectively). Apparent formation factor, defined as the ratio of aquifer bulk resistivity to aquifer water resistivity, was shown to be poorly correlated with horizontal hydraulic conductivity (38 percent correlation coefficient). Aquifer bulk resistivity was shown to be highly correlated with dissolved-solids concentration and aquifer water resistivity (88 and 93 percent correlation coefficients, respectively). Regression models using bulk resistivity and aquifer water resistivity as independent variables were applied at four locations in South Carolina and Louisiana to predict dissolved-solids concentrations in aquifer water. Absolute mean error of prediction was 20 and 6 percent, respectively. A regression model using bulk resistivity to predict horizontal hydraulic conductivity was applied at 27 sites in 6 Southeastern States, resulting in an absolute error ranging from 4 to 95 percent with a corresponding mean error of 43 percent.

Water Supply Paper↗

USGS2022

Incorporating interpreter variability into estimation of the total variance of land cover area estimates under simple random sampling

Area estimates of land cover and land cover change are often based on reference class labels determined by analysts interpreting satellite imagery and aerial photography. Different interpreters may assign different reference class labels to the same sample unit. This interpreter variability is typically not accounted for in variance estimators applied to area estimates of land cover. A simple measurement model provides the basis for an estimator of the total variance ( V Total ) that takes into account both sampling variance and interpreter variance. This method requires two or more reference class interpretations (i.e., repeated measurements) obtained by analysts, working independently of each other, for the full sample or a random subsample of the full sample. Estimators of the total variance ( V ̂ Total "> V̂Total ) and the variance component attributable to interpreters ( V ̂ 1 "> V̂1 ) were obtained for the case of two reference class interpretations per repeated sample unit. To evaluate the effect of interpreter variability on variance estimation, we used land cover reference data interpreted by seven analysts who each interpreted the same 300 sample pixels from a region of the Pacific Northwest of the United States. From these data, we estimated the contribution of interpreter variance to the total variance (i.e., V ̂ 1 / V ̂ Total "> V̂1/V̂Total ) and the relative bias of the standard simple random sampling variance estimator ( V ̂ stand "> V̂stand ) as an estimator of V Total , defined as 100%*( V ̂ stand − V ̂ Total "> V̂stand−V̂Total )/ V ̂ Total "> V̂Total . For each of five land cover classes, we computed V ̂ 1 "> V̂1 , V ̂ Total "> V̂Total , and V ̂ stand "> V̂stand using the sample data from each of the 21 possible pairwise combinations of the seven interpreters, and then calculated the mean of V ̂ 1 / V ̂ Total "> V̂1/V̂Total and the mean of the estimated relative bias of V ̂ stand "> V̂stand over these 21 pairs. Based on the mean of V ̂ 1 / V ̂ Total "> V̂1/V̂Total per class, interpreter variance contributed from 25% (cropland) to 76% (grass/shrub) of the total variance, indicating that interpreter variance was a non-negligible component of the total variance. Typically, the standard variance estimator, V ̂ stand "> V̂stand , underestimated the total variance with the mean estimated relative bias ranging from −3% (cropland) to −33% (grass/shrub). Classes with greater inconsistency between pairs of interpreters had larger contributions of interpreter variance to the total variance ( V ̂ 1 / V ̂ Total "> V̂1/V̂Total ) and larger negative estimated relative bias of V ̂ stand "> V̂stand . Given that interpreter variance can contribute substantially to the total variance, the repeated measurements approach offers a practical way to incorporate this variability into an estimator of the total variance.

Washington↗

USGS2019

Integrating hydrology and biogeochemistry across frozen landscapes

Research has traditionally focused on atmospheric release of carbon from thawing permafrost, yet overlooked waterborne release pathways likely contribute significantly, especially in a warming Arctic. To address this knowledge gap and better constrain the fate of carbon in the North, we recommend inter-disciplinary efforts bridging physical, chemical and computational research.

Nature Communications↗

USGS2019

Instructions for running the analytical code PAT (Purge Analyzer Tool) for computation of in-well time of travel of groundwater under pumping conditions

Introduction Understanding the optimal time needed to purge a well while pumping to collect a representative groundwater sample requires an understanding of groundwater flow in wells (in-well flow). Parameters that affect in-well flow include the hydraulic properties of the aquifer, well construction, drawdown from pumping, and pump rate. The time of travel relative to in-well flow is affected by the pump’s intake location. The Purge Analyzer Tool (PAT) incorporates hydraulic calculations to help assess the optimal purge times required to vertically transport groundwater in the well to the pump intake (Harte, 2017). Harte (2017) includes a discussion on the rationale for determining in-well groundwater flow and time of travel and also discusses the limitations inherent in the PAT; an understanding of the limitations is important to ensure proper use. The PAT calculates flow by use of the Dupuit-Theim equation (Lohman, 1979) that assumes steady-state radial flow and a total inflow from the well opening or screen equal to the pumping rate (eq. 1). A bulk average hydraulic conductivity (K avg ) is derived from this relationship. Once K avg is calculated, the program calculates incremental (layered) horizontal radial inflow into the well over user defined increments (layers). These defined increments represent the screen or well opening as a fraction of the total inflow. The amount of inflow per layer is proportional to the user-defined layered distribution of hydraulic conductivity (K layer ) because drawdown is assumed to be uniformly distributed in the well. The water budget equation that guides the solution of the PAT (eq. 1) is specified as: Q p = Q v + Q H + Q w (1) where Q P is pumping rate, Q v is vertical flow entering the boundary of the mixing zone (M z ) from the summation of layered radial flow (∑ Q hl-n ) where l-n denotes number of layers, Q H is horizontal radial flow into the mixing zone (M z ), and Q w is flow from wellbore storage effects. The in-well flow is computed from the convergence of incremental (layered) radial inflows (Q hl-n ) summed to the total vertical flow (Q V ) entering the adjacent zone to the pump intake (called mixing zone [M z ]) as shown in figure 1. The Q v is transported as one-dimensional piston flow. Within the M z , it's assumed that flow to the pump is dominated by horizontal radial flow (Q H ) when the pump is in the open interval of the well. Flow from the wellbore storage (Q w ) is computed from the volume of water pumped from the well at the time of the drawdown (s) measurement(s). Aquifer storage effects are unaccounted for but are likely to be problematic when (1) dewatering within the well opening occurs or (2) when the water table is close to the top of the well screen or open interval where additional flow into the upper portion of the well opening may occur. For fully saturated wells tens of feet below the water table, storage effects are likely to be more uniformly distributed across the well screen or open interval (regardless of confined or unconfined conditions). Therefore, radial inflow from storage will be less prominent under pump rates commonly used in groundwater sampling either for volumetric sampling ( < 3 gallons per minute) or low-flow sampling ( < 0.5 liters per minute). A major benefit of the use of the PAT is the understanding of time-varying, vertical integration of captured pump water. The analytical model computes aquifer (formation) capture intervals relative to the open interval of the well. This information is displayed graphically (called aquifer fraction graphs) and can be used to assess the likely formation intervals contributing water to the sample at any time.

Open-File Report↗

USGS2003

Topography and Sedimentation Characteristics of the Squaw Creek National Wildlife Refuge, Holt County, Missouri, 1937-2002

The Squaw Creek National Wildlife Refuge (hereafter referred to as the Refuge), located on the Missouri River floodplain in northwest Missouri, was established in 1935 to provide habitat for migratory birds and wildlife. Results of 1937 and 1964 topographic surveys indicate that sedimenta-tion, primarily from Squaw Creek and Davis Creek inflows, had substantially reduced Refuge pool volumes and depths. A study was undertaken by the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, to quantify and spatially analyze historic rates of sedimentation in the Refuge and determine the surface elevations, depths, and pool capacities for selected managed pools from a 2002 survey.The 1937 to 1964 mean total sediment depo-sition, in the area corresponding to the 2002 sur-veyed pool area (about 4,900 acres), was 1.26 ft (feet), or 0.047 ft/yr (foot per year). Mean annual rates of deposition, by pool, from 1937 to 1964 varied from 0.016 to 0.083 ft/yr. From 1964 to 2002, the mean total sediment deposition in the 2002 surveyed pools was 0.753 ft, or 0.020 ft/yr. Therefore, the mean rate of sediment-depth accu-mulation from 1964 to 2002 was about 42 percent of the mean 1937 to 1964 rate, or a 58 percent reduction. Mean annual rates of deposition by pool from 1964 to 2002 varied from 0.010 to 0.049 ft/yr. Despite a substantial reduction in the average sediment accumulation rate for the Refuge, 5 of the 15 separate pools for which annual rates were calculated for both periods showed a small increase in the deposition rates of up to 0.008 ft/yr. Sediment deposits have resulted in a sub-stantial cumulative loss of volume in the Refuge pools since 1937. The 1937 to 2002 total sediment volume deposited in the 2002 surveyed pool area was about 9,900 acre-ft (acre-feet), or 152 acre-ft/yr (acre-feet per year). The volume of sediment deposited from 1937 to 1964 for these pools was about 6,200 acre-ft, or 230 acre-ft/yr. The volume deposited from 1964 to 2002 was about 3,700 acre-ft, or 97.3 acre-ft/yr.Bulk density values were determined from sediment cores collected from 22 sites in the Ref-uge and the bulk densities, along with sediment volumes, allowed for the calculation of sediment mass contributions to the Refuge. From 1937 to 2002, about 10,300,000 tons of sediment were deposited in the 2002 surveyed area, or 32.4 tons/acre/yr (tons per acre per year). The total computed mass of sediment deposited between 1937 and 1964 was about 6,510,000 tons, or an average of 49.1 tons/acre/yr. The total mass depos-ited from 1964 to 2002 in surveyed pools was about 3,830,000 tons, or an average of 20.5 tons/acre/yr. As with sediment thickness compari-sons, the rate of sediment mass deposition between 1964 to 2002 was about 42 percent of that from 1937 to 1964, or a 58 percent reduction.The greatest amounts of sediment deposition in the Refuge for 1937 to 2002 have been near the Squaw Creek and Davis Creek inflow spillway locations. Sediment depths in some areas near former inflow locations have exceeded 8 ft. Relo-cation of an inflow spillway effectively reduced additional sediment deposition at the original loca-tion, and caused increased sedimentation at the new inflow location. This is most clearly depicted in a pool located in the north section of the Refuge that directly received Squaw Creek inflows from 1937 to 1964 and had a mean deposition rate of 0.081 ft/yr reduced to 0.012 ft/yr, from 1964 to 2002, after inflows were redirected and erosion-management plans were implemented in the con-tributing basins.

Water-Resources Investigations Report↗

USGS1998

Peak-flow frequency for tributaries of the Colorado River downstream of Austin, Texas

A procedure to estimate the peak discharge associated with large floods is needed for tributaries of the Colorado River downstream of Austin, Texas, so that appropriate peak discharges can be used to estimate floodplain boundaries and used for the design of bridges and other structures. The U.S. Geological Survey, in cooperation with the Lower Colorado River Authority, studied flood peaks for streams in all or parts of 22 counties in that part of the Colorado River Basin extending downstream of Town Lake in Austin to the Gulf of Mexico. The study area was selected because the streams in this area either are tributaries to the Colorado River or have flood characteristics similar to those tributaries. Peak-flow frequency for 38 stations with at least 8 years of data in natural (unregulated and nonurbanized) basins was estimated on the basis of annual peak-streamflow data through water year 1995. Peak-flow frequency represents the peak discharges for recurrence intervals of 2, 5, 10, 25, 50, 100, 250, and 500 years. The peak-flow frequency and drainage basin characteristics for the stations were used to develop two sets of regression equations to estimate peak-flow frequency for tributaries of the Colorado River in the study area. One set of equations was developed for contributing drainage areas less than 32 square miles, and another set was developed for contributing drainage areas greater than 32 square miles. A procedure is presented to estimate the peak discharge at sites where both sets of equations are considered applicable. Additionally, procedures are presented to compute the 50-, 67-, and 90-percent prediction interval for any estimation from the equations.

Texas↗

USGS2005

Slicing up the San Francisco Bay Area: Block kinematics and fault slip rates from GPS-derived surface velocities

Observations of surface deformation allow us to determine the kinematics of faults in the San Francisco Bay Area. We present the Bay Area velocity unification (BA??VU??, "bay view"), a compilation of over 200 horizontal surface velocities computed from campaign-style and continuous Global Positioning System (GPS) observations from 1993 to 2003. We interpret this interseismic velocity field using a three-dimensional block model to determine the relative contributions of block motion, elastic strain accumulation, and shallow aseismic creep. The total relative motion between the Pacific plate and the rigid Sierra Nevada/Great Valley (SNGV) microplate is 37.9 ?? 0.6 mm yr-1 directed toward N30.4??W ?? 0.8?? at San Francisco (??2??). Fault slip rates from our preferred model are typically within the error bounds of geologic estimates but provide a better fit to geodetic data (notable right-lateral slip rates in mm yr-1: San Gregorio fault, 2.4 ?? 1.0; West Napa fault, 4.0 ?? 3.0; zone of faulting along the eastern margin of the Coast Range, 5.4 ?? 1.0; and Mount Diablo thrust, 3.9 ?? 1.0 of reverse slip and 4.0 ?? 0.2 of right-lateral strike slip). Slip on the northern Calaveras is partitioned between both the West Napa and Concord/ Green Valley fault systems. The total convergence across the Bay Area is negligible. Poles of rotation for Bay Area blocks progress systematically from the North America-Pacific to North America-SNGV poles. The resulting present-day relative motion cannot explain the strike of most Bay Area faults, but fault strike does loosely correlate with inferred plate motions at the time each fault initiated. Copyright 2005 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth↗

USGS1990

A Mass-balance nitrate model for predicting the effects of land use on ground-water quality in municipal wellhead-protection areas

A mass-balance accounting model can be used to guide the management of septic systems and fertilizers to control the degradation of groundwater quality in zones of an aquifer that contributes water to public supply wells. The nitrate nitrogen concentration of the mixture in the well can be predicted for steady-state conditions by calculating the concentration that results from the total weight of nitrogen and total volume of water entering the zone of contribution to the well. These calculations will allow water-quality managers to predict the nitrate concentrations that would be produced by different types and levels of development, and to plan development accordingly. Computations for different development schemes provide a technical basis for planners and managers to compare water quality effects and to select alternatives that limit nitrate concentration in wells. Appendix A contains tables of nitrate loads and water volumes from common sources for use with the accounting model. Appendix B describes the preparation of a spreadsheet for the nitrate loading calculations with a software package generally available for desktop computers. (USGS)

Open-File Report↗

USGS2002

Streamflow and erosion response to prolonged intense rainfall of November 1-2, 2000, Island of Hawaii, Hawaii

A combination of several meteorologic and topographic factors produced extreme rainfall over the eastern part of the island of Hawaii on November 1-2, 2000. Storm rainfall was concentrated in two distinct areas, the Waiakea and Kapapala areas, where maximum rainfall totals of 32.47 and 38.97 inches were recorded. Resultant flooding caused damages in excess of 70 million dollars, among the highest totals associated with flooding in the State's history. Storm rainfall had recurrence intervals that ranged from 10 years or less for maximum 1-hour totals to 100 years or more for maximum 24-hour totals As part of this study, peak flow and/or erosion data were collected at 41 sites. Analyses of these data indicated that peak discharges of record occurred at 6 of 12 sites where historic data were available. Peak flows with estimated recurrence intervals from 50 to over 100 years were recorded at 4 of 11 sites. Peak flows were poorly correlated with total storm rainfall. Critical rainfall durations associated with peak flows ranged from 1 to 12 hours and were about 3 hours at most sites. Rainfall-runoff computations and field observations indicated that infiltration-excess overland flow alone was not sufficient to have caused the observed flood peaks and therefore saturation-excess overland flow and subsurface flow probably contributed to peak flows at most sites Most hillslope erosion associated with the storm took place along or near the Kaoiki Pali in the Kapapala area. Hillslope erosion was predominately caused by overland flow.

Hawaii↗

USGS1982

Techniques for estimating flood discharges for unregulated streams in New Mexico

Equations for estimating flood magnitudes at selected recurrence intervals from 2 to 500 years were developed using multiple-regression analyses. These equations relate flood magnitudes to basin characteristics, contributing drainage area and site altitude, and only are applicable to unregulated streams in New Mexico that are relatively unaffected by urban runoff. Estimates of floods at or near gaged sites may be computed with an equation that adjusts discharges developed with the regression equations using station-specific discharges. (USGS)

New Mexico↗

USGS1990

Mass-balance model for predicting nitrate in ground water

A mass-balance accounting model can be used to guide the management of septic systems and fertilizers to control the degradation of ground-water quality in zones of an aquifer that contribute water to public-supply wells. The nitrate concentration of the mixture in the well can be predicted for steady-state conditions by calculating the concentration that results from the total weight of nitrogen and total volume of water entering the zone of contribution to the well. These calculations will allow water-quality managers to predict the nitrate concentrations that would be produced by different types and levels of development, and to plan development accordingly. Computations for different development schemes provide a technical basis for planners and managers to compare water-quality effects and to select alternatives that limit nitrate concentration in wells.

Journal of the New England Water Works Association↗

USGS2007

Exchanges of Water between the Upper Floridan Aquifer and the Lower Suwannee and Lower Santa Fe Rivers, Florida

Exchanges of water between the Upper Floridan aquifer and the Lower Suwannee River were evaluated using historic and current hydrologic data from the Lower Suwannee River Basin and adjacent areas that contribute ground-water flow to the lowest 76 miles of the Suwannee River and the lowest 28 miles of the Santa Fe River. These and other data were also used to develop a computer model that simulated the movement of water in the aquifer and river, and surface- and ground-water exchanges between these systems over a range of hydrologic conditions and a set of hypothetical water-use scenarios. Long-term data indicate that at least 15 percent of the average annual flow in the Suwannee River near Wilcox (at river mile 36) is derived from ground-water discharge to the Lower Suwannee and Lower Santa Fe Rivers. Model simulations of ground-water flow to this reach during water years 1998 and 1999 were similar to these model-independent estimates and indicated that ground-water discharge accounted for about 12 percent of the flow in the Lower Suwannee River during this time period. The simulated average ground-water discharge to the Lower Suwannee River downstream from the mouth of the Santa Fe River was about 2,000 cubic feet per second during water years 1998 and 1999. Simulated monthly average ground-water discharge rates to this reach ranged from about 1,500 to 3,200 cubic feet per second. These temporal variations in ground-water discharge were associated with climatic phenomena, including periods of strong influence by El Ni?o-associated flooding, and La Ni?a-associated drought. These variations showed a relatively consistent pattern in which the lowest rates of ground-water inflow occurred during periods of peak flood levels (when river levels rose faster than ground-water levels) and after periods of extended droughts (when ground-water storage was depleted). Conversely, the highest rates of ground-water inflow typically occurred during periods of receding levels that followed peak river levels.

Professional Paper↗

USGS2010

Hydrology, water quality, and water-supply potential of ponds at Hunter Army Airfield, Chatham County, Georgia, November 2008-July 2009

The hydrology, water quality, and water-supply potential of four ponds constructed to capture stormwater runoff at Hunter Army Airfield, Chatham County, Georgia, were evaluated as potential sources of supplemental irrigation supply. The ponds are, Oglethorpe Lake, Halstrum Pond, Wilson Gate Pond, and golf course pond. During the dry season, when irrigation demand is highest, ponds maintain water levels primarily from groundwater seepage. The availability of water from ponds during dry periods is controlled by the permeability of surficial deposits, precipitation and evaporation, and the volume of water stored in the pond. Net groundwater seepage (Gnet) was estimated using a water-budget approach that used onsite and nearby climatic and hydrologic data collected during November-December 2008 including precipitation, evaporation, pond stage, and discharge. Gnet was estimated at three of the four sites?Oglethorpe Lake, Halstrum Pond, and Wilson Gate Pond?during November-December 2008. Pond storage volume in the three ponds ranged from 5.34 to 12.8 million gallons. During November-December 2008, cumulative Gnet ranged from -5.74 gallons per minute (gal/min), indicating a net loss in pond volume, to 19 gal/min, indicating a net gain in pond volume. During several periods of stage recovery, daily Gnet rates were higher than the 2-month cumulative amount, with the highest rates of 178 to 424 gal/min following major rainfall events during limited periods. These high rates may include some contribution from stormwater runoff; more typical recovery rates were from 23 to 223 gal/min. A conservative estimate of the volume of water available for irrigation supply from three of the ponds was provided by computing the rate of depletion of pond volume for a variety of withdrawal rates based on long-term average July precipitation and evaporation and the lowest estimated Gnet rate at each pond. Withdrawal rates of 1,000, 500, and 250 gal/min were applied during an 8-hour daily pumping period. At a withdrawal rate of 1,000 gal/min, available pond volume would be depleted in 13-29 days, at a rate of 500 gal/min in 24-60 days, and at a rate of 250 gal/min, in 44 to 130 days. In each case, Halstrum Pond had the largest amount of available pond volume. The water-supply potential at the golf course pond was assessed by measuring flow downstream from the pond during February-July 2009, and examining historic stormflow measurements collected during 1979-87. Streamflow during both of these periods exceeded average daily (2005-2007) golf course water use. Assuming an 8-hour daily irrigation period, the average discharge rate required to meet Golf Course water demand during peak demand months of March-May and July-October exceeds 200 gal/min, with the greatest rate of 531 gal/min during July. During February-July 2009, daily average streamflow downstream of the golf course pond exceeded 238 gal/min 90 percent of the time. Based on samples collected for chemical analysis during April 2009, water from all four ponds at Hunter Army Airfield is fresh and suitable for irrigation supply, with chloride concentrations below 12 milligrams per liter. With the exception of iron in Wilson Gate Pond, constituent concentrations are below U.S. Environmental Protection Agency primary and secondary drinking water maximum contaminant levels. Water in Wilson Gate Pond contained an iron concentration of 419 mg/L, which exceeds the secondary maximum contaminant level of 300 micrograms per liter. Although not a health hazard, when the iron concentration exceeds 300 micrograms per liter, iron staining of sidewalks and plumbing fixtures may occur. Levels of dissolved oxygen were below the Georgia Environmental Protection Divison standard of 4 milligrams per liter for waters supporting warm-water fishes at deeper depths in Oglethorpe Lake, Wilson Gate Pond, and Halstrum Pond, and in the composite sample at the golf course pond.

Georgia↗

USGS1989

Suspended sediment and sediment-source areas in the Fountain Creek drainage basin upstream from Widefield, southeastern Colorado

Suspended-sediment samples were collected from synoptic-sampling sites to determine suspended-sediment concentrations, loads, yields, and sediment-source areas in the Fountain Creek drainage basin upstream from Widefield, Colorado. Suspended-sediment yields ranged from 0.004 to 278 tons/sq mi/day. Twenty-four sites were sampled that represent urban and rural land use. The median suspended-sediment yield from urban drainage basins was 7.7 tons/sq mi/day and the median suspended-sediment yield from rural drainage basins was 0.46 ton/sq mi/day. Sediment-transport equations were derived for total suspended-sediment discharge and suspended-sand discharge at seven periodic-sampling sites. Annual suspended-sediment loads and yields were computed for the 1985 water year. Urbanization in the downstream parts of the Monument Creek drainage basin, the main tributary to Fountain Creek, affected sediment loads. The downstream 14% of the Monument Creek drainage basin contributed about 61% of the annual suspended-sediment load transported at the mouth of Monument Creek. About 73% of the annual suspended-sediment load for Fountain Creek at Colorado Springs was contributed by Monument Creek. Abandoned mill tailings along Fountain Creek contributed little to total suspended sediment load. Contributions of streambank erosion to basin sediment yields were not quantified. However, the measured rate of streambank erosion at a site on Fountain Creek has increased during a 37-year period. (USGS)

Water-Resources Investigations Report↗

USGS2016

Application of hydrogeology and groundwater-age estimates to assess the travel time of groundwater at the site of a landfill to the Mahomet Aquifer, near Clinton, Illinois

The U.S. Geological Survey used interpretations of hydrogeologic conditions and tritium-based groundwater age estimates to assess the travel time of groundwater at a landfill site near Clinton, Illinois (the “Clinton site”) where a chemical waste unit (CWU) was proposed to be within the Clinton landfill unit #3 (CLU#3). Glacial deposits beneath the CWU consist predominantly of low-permeability silt- and clay-rich till interspersed with thin (typically less than 2 feet in thickness) layers of more permeable deposits, including the Upper and Lower Radnor Till Sands and the Organic Soil unit. These glacial deposits are about 170 feet thick and overlie the Mahomet Sand Member of the Banner Formation. The Mahomet aquifer is composed of the Mahomet Sand Member and is used for water supply in much of east-central Illinois. Eight tritium analyses of water from seven wells were used to evaluate the overall age of recharge to aquifers beneath the Clinton site. Groundwater samples were collected from six monitoring wells on or adjacent to the CLU#3 that were open to glacial deposits above the Mahomet aquifer (the upper and lower parts of the Radnor Till Member and the Organic Soil unit) and one proximal production well (approximately 0.5 miles from the CLU#3) that is screened in the Mahomet aquifer. The tritium-based age estimates were computed with a simplifying, piston-flow assumption: that groundwater moves in discrete packets to the sampled interval by advection, without hydrodynamic dispersion or mixing. Tritium concentrations indicate a recharge age of at least 59 years (pre-1953 recharge) for water sampled from deposits below the upper part of the Radnor Till Member at the CLU#3, with older water expected at progressively greater depth in the tills. The largest tritium concentration from a well sampled by this study (well G53S; 0.32 ± 0.10 tritium units) was in groundwater from a sand deposit in the upper part of the Radnor Till Member; the shallowest permeable unit sampled by this study. That result indicated that nearly all groundwater sampled from well G53S entered the aquifer as recharge before 1953. Tritium was detected in a trace concentration in one sample from a second monitoring well open to the upper part of the Radnor Till Member (well G07S; 0.11 ± 0.09 tritium units), and not detected in samples collected from two monitoring wells open to a sand deposit in the lower part of the Radnor Till Member, from two samples collected from two monitoring wells open to the Organic Soil unit, and in two samples collected from a production well screened in the middle of the Mahomet aquifer (a groundwater sample and a sequential replicate sample). The lack of tritium in five of the six groundwater samples collected from the shallow permeable units beneath CLU#3 site and the two samples from the one Mahomet aquifer well indicates an absence of post-1952 recharge. Groundwater-flow paths that could contribute post-1952 recharge to the lower part of the Radnor Till Member, the Organic Soil unit, or the Mahomet aquifer at the CLU#3 are not indicated by these data. Hypothetical two-part mixtures of tritium-dead, pre-1953 recharge water and decay-corrected tritium concentrations in post-1952 recharge were computed and compared with tritium analyses in groundwater sampled from monitoring wells at the CLU#3 site to evaluate whether tritium concentrations in groundwater could be represented by mixtures involving some post-1952 recharge. Results from the hypothetical two-part mixtures indicate that groundwater from monitoring well (G53S) was predominantly composed of pre-1953 recharge and that if present, younger, post-1955 recharge, contributed less than 2.5 percent to that sample. The hypothetical two-part mixing results also indicated that very small amounts of post-1952 recharge composing less than about 2.5 percent of the sample volume could not be distinguished in groundwater samples with tritium concentrations less than about 0.15 TU. The piston-flow based age of recharge determined from the tritium concentration in the groundwater sample from monitoring well G53S yielded an estimated maximum vertical velocity from the land surface to the upper part of the Radnor Till Member of 0.85 feet per year or less. This velocity, ifassumed to apply to the remaining glacial till deposits above the Mahomet aquifer, indicates that recharge flows through the 170 feet of glacial deposits between the base of the proposed chemical waste unit and the top of the Mahomet aquifer in a minimum of 200 years or longer. Analysis of hydraulic data from the site, constrained by a tritium-age based maximum groundwater velocity estimate, computed minimum estimates of effective porosity that range from about 0.021 to 0.024 for the predominantly till deposits above the Mahomet aquifer. Estimated rates of transport of recharge from land surface to the Mahomet aquifer for the CLU#3 site computed using the Darcy velocity equation with site-specific data were about 260 years or longer. The Darcy velocity-based estimates were computed using values that were based on tritium data, estimates of vertical velocity and effective porosity and available site-specific data. Solution of the Darcy velocity equation indicated that maximum vertical groundwater velocities through the deposits above the aquifer were 0.41 or 0.61 feet per year, depending on the site-specific values of vertical hydraulic conductivity (laboratory triaxial test values) and effective porosity used for the computation. The resulting calculated minimum travel times for groundwater to flow from the top of the Berry Clay Member (at the base of the proposed chemical waste unit) to the top of the Mahomet aquifer ranged from about 260 to 370 years, depending on the velocity value used in the calculation. In comparison, plausible travel times calculated using vertical hydraulic conductivity values from a previously published regional groundwater flow model were either slightly less than or longer than those calculated using site data and ranged from 230 to 580 years. Tritium data from 1996 to 2011 USGS regional sampling of groundwater from domestic wells in the confined part of the Mahomet aquifer—which are 2.5 to about 40 miles from the Clinton site—were compared with site-specific data from a production well at the Clinton site. Tritium-based groundwater-age estimates indicated predominantly pre- 1953 recharge dates for USGS and other prior regional samples of groundwater from domestic wells in the Mahomet aquifer. These results agreed with the tritium-based, pre-1953 recharge age estimated for a groundwater sample and a sequential replicate sample from a production well in the confined part of the Mahomet aquifer beneath the Clinton site. The regional tritium-based groundwater age estimates also were compared with pesticide detections in samples from distal domestic wells in the USGS regional network that are about 2.5 to 40 miles from the Clinton site to identify whether very small amounts of post-1952 recharge have in places reached confined parts of the Mahomet aquifer at locations other than the Clinton site in an approximately 2,000 square mile area of the Mahomet aquifer. Very small amounts of post-1952 recharge were defined in this analysis as less than about 2.5 percent of the total recharge contributing to a groundwater sample, based on results from the two-part mixing analysis of tritium data from the Clinton site. Pesticide-based groundwater-age estimates based on 22 detections of pesticides (13 of these detections were estimated concentrations), including atrazine, deethylatrazine (2-Chloro-4-isopropylamino-6-amino- s-triazine), cyanazine, diazinon, metolachlor, molinate, prometon, and trifluralin in groundwater samples from 10 domestic wells 2.5 to about 40 miles distant from the Clinton site indicate that very small amounts of post-1956 to post-1992 recharge can in places reach the confined part of the Mahomet aquifer in other parts of central Illinois. The relative lack of tritium in these samples indicate that the amounts of post-1956 to post-1992 recharge contributing to the 10 domestic wells were a very small part of the overall older groundwater sampled from those wells. The flow process by which very small amounts of pesticide-bearing groundwater reached the screened intervals of the 10 domestic wells could not be distinguished between well-integrity related infiltration and natural hydrogeologic features. Potential explanations include: (1) infiltration through man-made avenues in or along the well, (2) flow of very small amounts of post-1956 to post-1992 recharge through sparsely distributed natural permeable aspects of the glacial till and diluted by mixing with older groundwater, or (3) a combination of both processes. Presuming the domestic wells sampled by the USGS in 1996–2011 in the regional study of the confined part of the Mahomet aquifer are adequately sealed and produce groundwater that is representative of aquifer conditions, the regional tritium and pesticide-based groundwater-age results indicate substantial heterogeneity in the glacial stratigraphy above the Mahomet aquifer. The pesticide-based groundwater-age estimates from the domestic wells distant from the Clinton site also indicate that parts of the Mahomet aquifer with the pesticide detections can be susceptible to contaminant sources at the land surface. The regional pesticide and tritium results from the domestic wells further indicate that a potential exists for possible contaminants from land surface to be transported through the glacial drift deposits that confine the Mahomet aquifer in other parts of central Illinois at faster rates than those computed for recharge at the Clinton site, including CLU#3. This analysis indicates the potential value of sub-microgram-per-liter level concentrations of land-use derived indicators of modern recharge to indicate the presence of very small amounts of modern, post-1952 age recharge in overall older, pre-1953 age groundwater.

Illinois↗

USGS2016

Groundwater and surface-water interaction, water quality, and processes affecting loads of dissolved solids, selenium, and uranium in Fountain Creek, near Pueblo, Colorado, 2012–2014

In 2012, the U.S. Geological Survey, in cooperation with the Arkansas River Basin Regional Resource Planning Group, initiated a study of groundwater and surface-water interaction, water quality, and loading of dissolved solids, selenium, and uranium to Fountain Creek near Pueblo, Colorado, to improve understanding of sources and processes affecting loading of these constituents to streams in the Arkansas River Basin. Fourteen monitoring wells were installed in a series of three transects across Fountain Creek near Pueblo, and temporary streamgages were established at each transect to facilitate data collection for the study. Groundwater and surface-water interaction was characterized by using hydrogeologic mapping, groundwater and stream-surface levels, groundwater and stream temperatures, vertical hydraulic-head gradients and ratios of oxygen and hydrogen isotopes in the hyporheic zone, and streamflow mass-balance measurements. Water quality was characterized by collecting periodic samples from groundwater, surface water, and the hyporheic zone for analysis of dissolved solids, selenium, uranium, and other selected constituents and by evaluating the oxidation-reduction condition for each groundwater sample under different hydrologic conditions throughout the study period. Groundwater loads to Fountain Creek and in-stream loads were computed for the study area, and processes affecting loads of dissolved solids, selenium, and uranium were evaluated on the basis of geology, geochemical conditions, land and water use, and evapoconcentration. During the study period, the groundwater-flow system generally contributed flow to Fountain Creek and its hyporheic zone (as a single system) except for the reach between the north and middle transects. However, the direction of flow between the stream, the hyporheic zone, and the near-stream aquifer was variable in response to streamflow and stage. During periods of low streamflow, Fountain Creek generally gained flow from groundwater. However, during periods of high streamflow, the hydraulic gradient between groundwater and the stream temporarily reversed, causing the stream to lose flow to groundwater. Concentrations of dissolved solids, selenium, and uranium in groundwater generally had greater spatial variability than surface water or hyporheic-zone samples, and constituent concentrations in groundwater generally were greater than in surface water. Constituent concentrations in the hyporheic zone typically were similar to or intermediate between concentrations in groundwater and surface water. Concentrations of dissolved solids, selenium, uranium, and other constituents in groundwater samples collected from wells located on the east side of the north monitoring well transect were substantially greater than for other groundwater, surface-water, and hyporheic-zone samples. With one exception, groundwater samples collected from wells on the east side of the north transect exhibited oxic to mixed (oxic-anoxic) conditions, whereas most other groundwater samples exhibited anoxic to suboxic conditions. Concentrations of dissolved solids, selenium, and uranium in surface water generally increased in a downstream direction along Fountain Creek from the north transect to the south transect and exhibited an inverse relation to streamflow with highest concentration occurring during periods of low streamflow and lowest concentrations occurring during periods of high streamflow. Groundwater loads of dissolved solids, selenium, and uranium to Fountain Creek were small because of the small amount of groundwater flowing to the stream under typical low-streamflow conditions. In-stream loads of dissolved solids, selenium, and uranium in Fountain Creek varied by date, primarily in relation to streamflow at each transect and were much larger than computed constituent loads from groundwater. In-stream loads generally decreased with decreases in streamflow and increased as streamflow increased. In-stream loads of dissolved solids and selenium increased between the north and middle transects but generally decreased between the middle and south transects. By contrast, uranium loads generally decreased between the north and middle transects but increased between the middle and south transects. In-stream load differences between transects appear primarily to be related to differences in streamflow. However, because groundwater typically flows to Fountain Creek under low-flow conditions, and groundwater has greater concentrations of dissolved solids, selenium, and uranium than surface water in Fountain Creek, increases in loads between transects likely are affected by inflow of groundwater to the stream, which can account for a substantial proportion of the in-stream load difference between transects. When loads decreased between transects, the primary cause likely was decreased streamflow as a result of losses to groundwater and flow through the hyporheic zone. However, localized groundwater inflow likely attenuated the magnitude by which the in-stream loads decreased. The combination of localized soluble geologic sources and oxic conditions likely is the primary reason for the occurrence of high concentrations of dissolved solids, selenium, and uranium in groundwater on the east side of the north monitoring well transect. To evaluate conditions potentially responsible for differences in water quality and redox conditions, physical characteristics such as depth to water, saturated thickness, screen depth below the water table, screen height above bedrock, and aquifer hydraulic conductivity were compared by using Wilcoxon rank-sum tests. Results indicated no significant difference between depth to water, screen height above bedrock, and hydraulic conductivity for groundwater samples collected from wells on the east side of the north transect and groundwater samples from all other wells. However, saturated thickness and screen depth below the water table both were significantly smaller for groundwater samples collected from wells on the east side of the north transect than for groundwater samples from other wells, indicating that these characteristics might be related to the elevated constituent concentrations found at that location. Similarly, saturated thickness and screen depth below the water table were significantly smaller for groundwater samples under oxic or mixed (oxic-anoxic) conditions than for those under anoxic to suboxic conditions. The greater constituent concentrations at wells on the east side of the north transect also could, in part, be related to groundwater discharge from an unnamed alluvial drainage located directly upgradient from that location. Although the quantity and quality of water discharging from the drainage is not known, the drainage appears to collect water from a residential area located upgradient to the east of the wells, and groundwater could become concentrated in nitrate and other dissolved constituents before flowing through the drainage. High levels of nitrate, whether from anthropogenic or natural geologic sources, could promote more soluble forms of selenium and other constituents by affecting the redox condition of groundwater. Whether oxic conditions at wells on the east side of the north transect are the result of physical characteristics or of groundwater inflow from the alluvial drainage, the oxic conditions appear to cause increased dissolution of minerals from the shallow shale bedrock at that location. Because ratios of hydrogen and oxygen isotopes indicate evaporation likely has not had a substantial effect on groundwater, constituent concentrations at that location likely are not the result of evapoconcentration.

Colorado↗