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Simulations of flooding on Tchoutacabouffa River at State Highways 15 and 67 at D'Iberville, Mississippi

A two-dimensional finite-element surface-water model was used to simulate the effects of the proposed State Highways 15 and 67 relocation on water-surface elevations and flow distributions for the 100-year flood on the Tchoutacabouffa River at D'Iberville, Mississippi. The Mississippi Department of Transportation plans to relocate State Highways 15 and 67 by removing a portion of the existing four-lane highway and constructing a four-lane facility upstream of the existing alignment. The proposed alignment is located on the northern floodplain and will tie into the existing highway about 1,000 feet north of the dual State Highways 15 and 67 bridges. The proposed alignment will intercept flows that cross the existing highway during large floods. Seven scenarios were simulated for the 100-year flood, including four proposed alternative configurations for drainage structures. The model grid was developed by using surveyed floodplain cross sections and channel bathymetry data obtained by using an Acoustic Doppler Current Profiler, in combination with a global positioning system. The model was calibrated and verified by using surveyed flood profiles through the study reach and flood discharge measurements obtained at the State Highways 15 and 67 crossing. Model parameters were adjusted so that the computed water-surface profiles agreed closely with the surveyed flood profiles. Computed water-surface differentials across the proposed alignment near the northern edge of the floodplain for the four alternatives proposed by the Mississippi Department of Transportation ranged from 1.4 to 2.6 feet. Much lower differentials were computed in the vicinity of the main-channel bridge. The computed water-surface elevation at McCully Drive, upstream of the proposed alignment, was 17.3 feet for existing conditions. Computed water-surface elevations at McCully Drive for the proposed alternatives ranged from 17.3 to 17.8 feet.

Mississippi↗

Ground-water quality of the surficial aquifer system and the upper Floridan Aquifer, Ocala National Forest and Lake County, Florida, 1990-99

Data from 217 ground-water samples were statistically analyzed to assess the water quality of the surficial aquifer system and Upper Floridan aquifer in the Ocala National Forest and Lake County, Florida. Samples were collected from 49 wells tapping the surficial aquifer system, 141 wells tapping the Upper Floridan aquifer, and from 27 springs that discharge water from the Upper Floridan aquifer. A total of 136 samples was collected by the U.S. Geological Survey from 1995 through 1999. These data were supplemented with 81 samples collected by the St. Johns River Water Management District and Lake County Water Resources Management from 1990 through 1998. In general, the surficial aquifer system has low concentrations of total dissolved solids (median was 41 milligrams per liter) and major ions. Water quality of the surficial aquifer system, however, is not homogeneous throughout the study area. Concentrations of total dissolved solids, many major ions, and nutrients are greater in samples from Lake County outside the Ocala National Forest than in samples from within the Forest. These results indicate that the surficial aquifer system in Lake County outside the Ocala National Forest probably is being affected by agricultural and (or) urban land-use practices. High concentrations of dissolved oxygen (less than 0.1 to 8.2 milligrams per liter) in the surficial aquifer system underlying the Ocala National Forest indicate that the aquifer is readily recharged by precipitation and is susceptible to surface contamination. Concentrations of total dissolved solids were significantly greater in the Upper Floridan aquifer (median was 182 milligrams per liter) than in the surficial aquifer system. In general, water quality of the Upper Floridan aquifer was homogeneous, primarily being a calcium or calcium-magnesium- bicarbonate water type. Near the St. Johns River, the water type of the Upper Floridan aquifer is sodium-chloride, corresponding to an increase in total dissolved solids. Dissolved-oxygen concentrations in the Upper Floridan aquifer ranged from less than 0.1 to 7.3 milligrams per liter, indicating that, in parts of the aquifer, ground water is rapidly recharged by rainfall and is susceptible to surface contamination. Median concentrations of nutrients in the Upper Floridan aquifer were not significantly different between the Ocala National Forest and the area of Lake County outside the Forest. The maximum nitrate concentration in the Upper Floridan aquifer in Ocala National Forest was only 0.20 milligram per liter, whereas, 9 of 39 samples from the Upper Floridan aquifer in Lake County had elevated nitrate concentrations (greater than 1.0 milligram per liter). Hence, nitrate concentrations of the Upper Floridan aquifer appear to be affected by land use in Lake County.

Florida↗

Shallow ground-water quality adjacent to burley tobacco fields in northeastern Tennessee and southwestern Virginia, spring 1997

In 1994, the U.S. Geological Survey began an assessment of the upper Tennessee River Basin as part of the National Water-Quality Assessment (NAWQA) Program. A ground-water land-use study conducted in 1996 focused on areas with burley tobacco production in northeastern Tennessee and southwestern Virginia. Land-use studies are designed to focus on specific land uses and to examine natural and human factors that affect the quality of shallow ground water underlying specific types of land use. Thirty wells were drilled in shallow regolith adjacent to and downgradient of tobacco fields in the Valley and Ridge Physiographic Province of the upper Tennessee River Basin. Ground-water samples were collected between June 4 and July 9, 1997, to coincide with the application of the majority of pesticides and fertilizers used in tobacco production. Ground-water samples were analyzed for nutrients, major ions, 79 pesticides, 7 pesticide degradation products, 86 volatile organic compounds, and dissolved organic carbon. Nutrient concentrations were lower than the levels found in similar NAWQA studies across the United States during 1993-95. Five of 30 upper Tennessee River Basin wells (16.7 percent) had nitrate levels exceeding 10 mg/L while 19 percent of agricultural land-use wells nationally and 7.9 percent in the Southeast had nitrate concentrations exceeding 10 mg/L. Median nutrient concentrations were equal to or less than national median concentrations. All pesticide concentrations in the basin were less than established drinking water standards, and pesticides were detected less frequently than average for other NAWQA study units. Atrazine was detected at 8 of 30 (27 percent) of the wells, and deethylatrazine (an atrazine degradation product) was found in 9 (30 percent) of the wells. Metalaxyl was found in 17 percent of the wells, and prometon, flumetralin, dimethomorph, 2,4,5-T, 2,4-D, dichlorprop, and silvex were detected once each (3 percent). Volatile organic compounds were detected in 27 of 30 wells. Although none of the volatile organic compound concentrations exceeded drinking water standards, the detection frequency was higher than the average for the other NAWQA study units.

Water-Resources Investigations Report↗

Influence of stream habitat and land use on benthic macroinvertebrate indicators of stream quality of selected above-tidal streams in the Houston-Galveston Area Council service area, Texas, 1997–98

During 1997–98, the U.S. Geological Survey, in cooperation with the Houston-Galveston Area Council, collected stream-habitat and benthic macroinvertebrate data for 31 reaches on abovetidal streams in the Council service area near Houston, Texas. Stream-habitat, land-use and population, and benthic aquatic insect metrics were determined for the 31 reaches. Statistical analyses were used to determine the stream-habitat, land-use and population, and aquatic insect variables that are strongly intercorrelated and that explain the greatest amount of variation between the reaches. Comparison of stream-habitat and biological integrity scores computed for each of the 31 reaches indicated (1) reaches generally had larger stream-habitat integrity scores in drainage areas that were heavily forested and had fewer people per square mile, (2) larger biological integrity scores were significantly correlated with larger stream-habitat integrity scores, and (3) urban reaches generally had more simplified streamhabitat conditions and smaller biological integrity scores. Seven reaches in the study area were selected as reference reaches on the basis of high streamhabitat integrity and high biological integrity. The reference-reaches median biological integrity score was equaled or exceeded by three reaches (one on Spring Creek and two on Cypress Creek) that are on the State of Texas 303(d) list of threatened or impaired waters with respect to aquatic life. This indicates that direct measures of biological integrity could be used to supplement surrogatebased designations of biological integrity such as the State list. A statistically significant multipleregression model was developed that uses independent variables that can be obtained without fieldintensive studies to predict the biological integrity score for a reach. The deviation from the model’s predicted score with the score based on biological sampling can be used to interpret the degree of biological impairment in a reach. Data from reaches outside the group of reaches used in this study are needed to test the validity of the multipleregression model.

Texas↗

U.S. Geological Survey Karst Interest Group: proceedings, St Petersburg, Florida February 13-16, 2001

Karst and similar landscapes are found in a wide range of biogeographic classes. In the U.S. for example, Everglades, Mammoth Cave, and Hawaii Volcanoes National Parks have little in common - except karst or pseudokarst, and a cultural past (even though these are very different). This diversity of geologic settings makes karst difficult to categorize and work with when designing a national program such as the recent NPS-USGS Geo-Indicators effort. A GIS-based approach with multiple datalayers is the only sane way to understand and convey the many relationships, in X, Y, and Z axes, between component ecosystems and cultural resources within karst and pseudokarst landscapes. Obviously, karst and cultural landscapes cross modern political as well as biogeographic boundaries. Here again, three-dimensional data are the foundation for understanding similar to that in anatomy and physiology: structure and function. In understanding where the most vulnerable 'pressure points' exist within karst landscapes, we can target landscape-scale ecosystem management to greatest effect. USGS and the National Cave and Karst research Institute could play an extremely significant role in cave and karst management on a national scale beyond NPS or other agency boundaries via cooperative management of three-dimensional karst datasets analogous to programs in several states.

Florida↗

Summary of and factors affecting pesticide concentrations in streams and shallow wells of the lower Susquehanna River basin, Pennsylvania and Maryland, 1993-95

This report presents the detection frequency of 83 analyzed pesticides, describes the concentrations of those pesticides measured in water from streams and shallow wells, and presents conceptual models of the major factors affecting seasonal and areal patterns of pesticide concentrations in water from streams and shallow wells in the Lower Susquehanna River Basin. Seasonal and areal patterns of pesticide concentrations were observed in 577 samples and nearly 40,000 pesticide analyses collected from 155 stream sites and 169 shallow wells from 1993 to 1995. For this study, shallow wells were defined as those generally less than 200 feet deep. The most commonly detected pesticides were agricultural herbicides?atrazine, metolachlor, simazine, prometon, alachlor, and cyanazine. Atrazine and metolachlor are the two most-used agricultural pesticides in the Lower Susquehanna River Basin. Atrazine was detected in 92 percent of all the samples and in 98 percent of the stream samples. Metolachlor was detected in 83 percent of all the samples and in 95 percent of the stream samples. Nearly half of all the analyzed pesticides were not detected in any sample. Of the 45 pesticides that were detected at least once, the median concentrations of 39 of the pesticides were less than the detection limit for the individual compounds, indicating that for at least 50 percent of the samples collected, those pesticides were not detected. Only 10 (less than 0.025 percent) of the measured concentrations exceeded any established drinking-water standards; 25 concentrations exceeded 2 mg/L (micrograms per liter) and 55 concentrations exceeded 1 mg/L. None of the elevated concentrations were measured in samples collected from streams that are used for public drinking-water supplies, and 8 of the 10 were measured in storm-affected samples. The timing and rate of agricultural pesticide applications affect the seasonal and areal concentration patterns of atrazine, simazine, chlorpyrifos, and diazinon observed in water from wells and streams in the Lower Susquehanna River Basin. Average annual pesticide use for agricultural purposes and nonagricultural pesticide use indicators were used to explain seasonal and areal patterns. Elevated concentrations of some pesticides in streams during base-flow and storm-affected conditions were related to the seasonality of agricultural-use applications and local climate conditions. Agricultural-use patterns affected areal concentration patterns for the high-use pesticides, but indicators of nonagricultural use were needed to explain concentration patterns of pesticides with smaller amounts used for agricultural purposes. Bedrock type influences the movement and discharge of ground water, which in turn affects concentration patterns of pesticides. The ratio of atrazine concentrations in stream base flow to concentrations in shallow wells varied among the different general rock types found in the Lower Susquehanna River Basin. Median concentrations of atrazine in well water and stream base flow tended to be similar in individual areas underlain by carbonate bedrock, indicating the connectivity of water in streams and shallow wells in these areas. In areas underlain by noncarbonate bedrock, median concentrations of atrazine tended to be significantly higher in stream base flow than in well water. This suggests a deep ground-water system that delivers water to shallow wells and a near-surficial system that supplies base-flow water to streams. In addition to the presence or absence of carbonate bedrock, pesticide leaching potential and persistence, soil infiltration capacity, and agricultural land use affected areal patterns in detection frequency and concentration differences between samples collected from streams during base-flow conditions and shallow wells.

Water-Resources Investigations Report↗

Estimates of mountain-front streamflow available for potential recharge to the Tularosa Basin, New Mexico

Streamflow in the Tularosa Basin, New Mexico, infiltrates into alluvial-basin aquifers at or near mountain fronts. Streamflow at or near mountain fronts is a substantial component of potential recharge to these aquifers. Streamflow response from precipitation differs substantially between the streams draining the Sacramento Mountains on the eastern side of the basin and those draining the San Andres Mountains on the western side. Mean annual streamflow at mountain fronts that is available for potential recharge to the Tularosa Basin was estimated using two regional regression methods. The method for estimating mean annual streamflow using basin-climatic characteristics was applied to 46 subbasins in the Tularosa Basin. Drainage areas for the subbasins ranged from 0.87 to 157 square miles, and mean annual precipitation ranged from 11.80 to 24.89 inches. Mean annual streamflow to the basin is estimated to be about 95 cubic feet per second or 68,800 acre-feet using the basin-climatic characteristics method. The method for estimating mean annual streamflow using channel-geometry characteristics was applied to 12 subbasins in the Tularosa Basin. Of the 46 basins, 31 had drainage areas less than 20.7 square miles and 3 had active-channel widths less than 15 feet, which were outside the ranges used to develop the regression equations.

Water-Resources Investigations Report↗

Analysis of borehole-radar reflection logs from selected HC boreholes at the Project Shoal area, Churchill County, Nevada

Single-hole borehole-radar reflection logs were collected and interpreted in support of a study to characterize ground-water flow and transport at the Project Shoal Area (PSA) in Churchill County, Nevada. Radar logging was conducted in six boreholes using 60-MHz omni-directional electric-dipole antennas and a 60-MHz magnetic-dipole directional receiving antenna.Radar data from five boreholes were interpreted to identify the location, orientation, estimated length, and spatial continuity of planar reflectors present in the logs. The overall quality of the radar data is marginal and ranges from very poor to good. Twenty-seven reflectors were interpreted from the directional radar reflection logs. Although the range of orientation interpreted for the reflectors is large, a significant number of reflectors strike northeast-southwest and east-west to slightly northwest-southeast. Reflectors are moderate to steeply dipping and reflector length ranged from less than 7 m to more than 133 m.Qualitative scores were assigned to each reflector to provide a sense of the spatial continuity of the reflector and the characteristics of the field data relative to an ideal planar reflector (orientation score). The overall orientation scores are low, which reflects the general data quality, but also indicates that the properties of most reflectors depart from the ideal planar case. The low scores are consistent with reflections from fracture zones that contain numerous, closely spaced, sub-parallel fractures.Interpretation of borehole-radar direct-wave velocity and amplitude logs identified several characteristics of the logged boreholes: (1) low-velocity zones correlate with decreased direct-wave amplitude, indicating the presence of fracture zones; (2) direct-wave amplitude increases with depth in three of the boreholes, suggesting an increase in electrical resistivity with depth resulting from changes in mineral assemblage or from a decrease in the specific conductance of ground water; and (3) an increase in primary or secondary porosity and an associated change in mineral assemblage, or decrease in ground water specific conductance, was characterized in two of the boreholes below 300 m.The results of the radar reflection logging indicate that even where data quality is marginal, borehole-radar reflection logging can provide useful information for ground-water characterization studies in fractured rock and insights into the nature and extent of fractures and fracture zones in and near boreholes.

Nevada↗

Hydrogeologic framework and geochemistry of the intermediate aquifer system in parts of Charlotte, De Soto, and Sarasota counties, Florida

The hydrogeologic framework underlying the 600-square-mile study area in Charlotte, De Soto, and Sarasota Counties, Florida, consists of the surficial aquifer system, the intermediate aquifer system, and the Upper Floridan aquifer. The hydrogeologic framework and the geochemical processes controlling ground-water composition were evaluated for the study area. Particular emphasis was given to the analysis of hydrogeologic and geochemical data for the intermediate aquifer system. Flow regimes are not well understood in the intermediate aquifer system; therefore, hydrogeologic and geochemical information were used to evaluate connections between permeable zones within the intermediate aquifer system and between overlying and underlying aquifer systems. Knowledge of these connections will ultimately help to protect ground-water quality in the intermediate aquifer system. The hydrogeology was interpreted from lithologic and geophysical logs, water levels, hydraulic properties, and water quality from six separate well sites. Water-quality samples were collected from wells located along six ground-water flow paths and finished at different depth intervals. The selection of flow paths was based on current potentiometric-surface maps. Ground-water samples were analyzed for major ions; field parameters (temperature, pH, specific conductance, and alkalinity); stable isotopes (deuterium, oxygen-18, and carbon-13); and radioactive isotopes (tritium and carbon-14). The surficial aquifer system is the uppermost aquifer, is unconfined, relatively thin, and consists of unconsolidated sand, shell, and limestone. The intermediate aquifer system underlies the surficial aquifer system and is composed of clastic sediments interbedded with carbonate rocks. The intermediate aquifer system is divided into three permeable zones, the Tamiami/Peace River zone (PZ1), the Upper Arcadia zone (PZ2), and the Lower Arcadia zone (PZ3). The Tamiami/Peace River zone (PZ1) is the uppermost zone and is the thinnest and generally, the least productive zone in the intermediate aquifer system. The Upper Arcadia zone (PZ2) is the middle zone and productivity is generally higher than the overlying permeable zone. The Lower Arcadia zone (PZ3) is the lowermost permeable zone and is the most productive zone in the intermediate aquifer system. The intermediate aquifer system is underlain by the Upper Floridan aquifer, which consists of a thick, stratified sequence of limestone and dolomite. The Upper Floridan aquifer is the most productive aquifer in the study area; however, its use is generally restricted because of poor water quality. Interbedded clays and fine-grained clastics separate the aquifer systems and permeable zones. The hydraulic properties of the three aquifer systems are spatially variable. Estimated trans-missivity and horizontal hydraulic conductivity varies from 752 to 32,900 feet squared per day and from 33 to 1,490 feet per day, respectively, for the surficial aquifer system; from 47 to 5,420 feet squared per day and from 2 to 102 feet per day, respectively, for the Tamiami/Peace River zone (PZ1); from 258 to 24,633 feet squared per day and from 2 to 14 feet per day, respectively, for the Upper Arcadia zone (PZ2); from 766 to 44,900 feet squared per day and from 10 to 201 feet per day, respectively, for the Lower Arcadia zone (PZ3); and from 2,350 to 7,640 feet squared per day and from 10 to 41 feet per day, respectively, for the Upper Floridan aquifer. Confining units separating the aquifer systems have leakance coefficients estimated to range from 2.3 x 10-5 to 5.6 x 10-3 feet per day per foot. Strata composing the confining unit separating the Upper Floridan aquifer from the intermediate aquifer system are substantially more permeable than confining units separating the permeable zones in the intermediate aquifer system or separating the surficial aquifer and intermediate aquifer systems. In Charlotte, Sarasota, and western De Soto Counties, hydraulic

Water-Resources Investigations Report↗

Use of thematic mapper imagery to assess water quality, trophic state, and macrophyte distributions in Massachusetts lakes

During the spring and summer of 1996, 1997, and 1998, measurements of phytoplankton- chlorophyll concentration, Secchi disk transparency, and color were made at 97 Massachusetts lakes within 24 hours of Landsat Thematic Mapper imaging of the lakes in an effort to assess water quality and trophic state. Spatial distributions of floating, emergent, and submerged macrophytes were mapped in 49 of the lakes at least once during the 3-year period. The maps were digitized and used to assign pixels in the thematic mapper images to one of four vegetation cover classes-open water, 1-50 percent floating-and-emergent-vegetation cover, 51-100 percent floating-and-emergent-vegetation cover, and submerged vegetation at any density. The field data were collected by teams of U.S. Geological Survey and Massachusetts Department of Environmental Management staff and by 76 volunteers. Side-by-side sampling by U.S. Geological Survey and volunteer field teams resulted in statistically similar chlorophyll determinations, Secchi disk readings, and temperature measurements, but concurrent color determinations were not similar, possibly due to contamination of sample bottles issued to the volunteers.Attempts to develop predictive relations between phytoplankton-chlorophyll concentration, Secchi disk transparency, lake color, dissolved organic carbon, and various combinations of thematic mapper bands 1, 2, 3, and 4 digital numbers were unsuccessful, primarily because of the extremely low concentrations of chlorophyll in the lakes studied, and also because of the highly variable dissolved organic carbon concentrations.Predictive relations were developed between Secchi disk transparency and phytoplankton-chlorophyll concentration, and between color and dissolved organic carbon concentration. Phytoplankton-chlorophyll concentration was inversely correlated with Secchi disk transparency during all three sampling periods. The relations were very similar in 1996 and 1997 and indicated that 62 to 67 percent of the variability in Secchi disk transparency could be explained by the chlorophyll concentration. Analysis of color and dissolved organic carbon concentrations in water samples collected by U.S. Geological Survey field teams in 1996-98 indicated that 91 percent of the variance in color in Massachusetts lakes can be explained by variations in dissolved organic carbon.Areas of open-water, submerged vegetation, and two surface-vegetation-cover classes predicted from Thematic Mapper images acquired in the summer of 1996 closely matched the areas observed in a set of field observations. However, the same analysis applied to a set of data acquired in the summer of 1997 resulted in somewhat less reliable predictions, and an attempt to predict 1996 vegetation-cover areas using the relations developed in the 1997 analysis was unsuccessful.

Water-Resources Investigations Report↗

River and Reservoir Operations Model, Truckee River basin, California and Nevada, 1998

The demand for all uses of water in the Truckee River Basin, California and Nevada, commonly is greater than can be supplied. Storage reservoirs in the system have a maximum effective total capacity equivalent to less than two years of average river flows, so longer-term droughts can result in substantial water-supply shortages for irrigation and municipal users and may stress fish and wildlife ecosystems. Title II of Public Law (P.L.) 101-618, the Truckee?Carson?Pyramid Lake Water Rights Settlement Act of 1990, provides a foundation for negotiating and developing operating criteria, known as the Truckee River Operating Agreement (TROA), to balance interstate and interbasin allocation of water rights among the many interests competing for water from the Truckee River. In addition to TROA, the Truckee River Water Quality Settlement Agreement (WQSA), signed in 1996, provides for acquisition of water rights to resolve water-quality problems during low flows along the Truckee River in Nevada. Efficient execution of many of the planning, management, or environmental assessment requirements of TROA and WQSA will require detailed water-resources data coupled with sound analytical tools. Analytical modeling tools constructed and evaluated with such data could help assess effects of alternative operational scenarios related to reservoir and river operations, water-rights transfers, and changes in irrigation practices. The Truckee?Carson Program of the U.S. Geological Survey, to support U.S. Department of the Interior implementation of P.L. 101-618, is developing a modeling system to support efficient water-resources planning, management, and allocation. The daily operations model documented herein is a part of the modeling system that includes a database management program, a graphical user interface program, and a program with modules that simulate river/reservoir operations and a variety of hydrologic processes. The operations module is capable of simulating lake/ reservoir and river operations including diversion of Truckee River water to the Truckee Canal for transport to the Carson River Basin. In addition to the operations and streamflow-routing modules, the modeling system is structured to allow integration of other modules, such as water-quality and precipitation-runoff modules. The USGS Truckee River Basin operations model was designed to provide simulations that allow comparison of the effects of alternative management practices or allocations on streamflow or reservoir storages in the Truckee River Basin over long periods of time. Because the model was not intended to reproduce historical streamflow or reservoir storage values, a traditional calibration that includes statistical comparisons of observed and simulated values would be problematic with this model and database. This report describes a chronology and background of decrees, agreements, and laws that affect Truckee River operational practices; the construction of the Truckee River daily operations model; the simulation of Truckee River Basin operations, both current and proposed under the draft TROA and WQSA; and suggested model improvements and limitations. The daily operations model uses Hydrological Simulation Program?FORTRAN (HSPF) to simulate flow-routing and reservoir and river operations. The operations model simulates reservoir and river operations that govern streamflow in the Truckee River from Lake Tahoe to Pyramid Lake, including diversions through the Truckee Canal to Lahontan Reservoir in the Carson River Basin. A general overview is provided of daily operations and their simulation. Supplemental information that documents the extremely complex operating rules simulated by the model is available.

Water-Resources Investigations Report↗

Characteristics of water, sediment, and benthic communities of the Wolf River, Menominee Indian Reservation, Wisconsin, water years 1986-98

Analyses and interpretation of water quality, sediment, and biological data from water years 1986 through 1998 indicated that land use and other human activities have had only minimal effects on water quality in the Wolf River upstream from and within the Menominee Indian Reservation in northeastern Wisconsin. Relatively high concentrations of calcium and magnesium (natural hardness), iron, manganese, and aluminum were measured in Wolf River water samples during water years 1986-98 from the three sampled sites and attributed to presence of highly mineralized geologic materials in the basin. Average calcium and magnesium concentrations varied from 22-26 milligrams per liter (mg/L) and 11-13 mg/L, respectively. Average iron concentrations ranged from 290-380 micrograms per liter ( μ g/L); average manganese concentrations ranged from 53-56 mg/L. Average aluminum concentrations ranged from 63-67 μ g/L. Mercury was present in water samples but concentrations were not at levels of concern. Levels of Kjeldahl nitrogen, ammonia, nitrite plus nitrate, total phosphorus, and orthophosphorus in water samples were often low or below detection limits (0.01- 0.10 mg/L). Trace amounts of atrazine (maximum concentration of 0.031 μ g/L), deethylatrazine (maximum 0.032 μ g/L), and alachlor (maximum of 0.002 μ g/L) were detected. Low concentrations of most trace elements were found in streambed sediment. Tissues of fish and aquatic invertebrates collected once each year from 1995 through 1998 at the Langlade and Keshena sites, near the northern and southern boundaries of the Reservation, respectively, were low in concentrations of most trace elements. Arsenic and silver in fish livers from both sites were less than or equal to 2 μ g/g arsenic and less than 1 μ g/g silver for dry weight analysis, and concentrations of antimony, beryllium, cadmium, cobalt, lead, nickel, and uranium were all below detection limits (less than 1 μ g/g dry weight). Concentrations of most other trace elements in fish were low, with the exceptions of chromium, copper, mercury, and selenium; however, these concentrations are not at levels of concern. Concentrations of all trace elements analyzed in whole caddisfly larvae also were low compared to those reported in the literature. During 1998, a total of 48 species of macroinvertebrates were identified at each of two sampled sites, with similar numbers of genera represented at both: 41 at Keshena and 44 at Langlade. The percentage EPT (Ephemeroptera, Plecoptera, and Trichoptera) was 52 at Keshena and 77 at Langlade; these relatively large percentages suggest very good to excellent water quality at these sites. A total of 52 algal taxa were identified at the Wolf River near Langlade. Diatoms made up 96 percent of the algal biomass. A total of 58 algal taxa were identified at Keshena, including 48 diatom taxa (83 percent). Although diatoms accounted for just 22 percent of the algal relative abundance, in cells per square centimeter, diatoms contributed 91 percent of the total algal biomass. The overall biological integrity of the Keshena and Langlade sites, based on diversity, siltation, and pollution indexes for diatoms is excellent.

Wisconsin↗

Hydrogeologic and water-quality reconnaissance of the artesian aquifer under the Shoalwater Bay Indian Reservation and Tokeland Peninsula, Pacific County, Washington, 1998-99

The U.S. Geological Survey (USGS) collected and compiled hydrogeologic and water quality data from September 1998 through September 1999 to describe the hydrogeologic setting and to assess the quality of the water in the artesian aquifer under the Shoalwater Bay Indian Reservation and the adjacent Tokeland Peninsula area of Pacific County, Washington. Hydrogeologic data include descriptions of 38 wells, lithologic data for 27 wells, and water-level data for 17 wells and 1 tidal station. Water-quality data include field measurements for temperature, specific conductance, pH, alkalinity, bicarbonate, carbonate, dissolved oxygen, and laboratory analyses for major inorganic ions, metals, nutrients, methylene blue-active substances, and pesticides. None of the 93 field measurements or chemicals analyzed for exceeded the U.S. Environmental Protection Agency (USEPA) primary standards for drinking water and only 2 constituents (iron and manganese) exceeded the USEPA secondary standards. Sixty-six of the constituents (including all 53 pesticides) were at or below the reporting or detection levels established by the USGS National Water Quality Laboratory.

Water-Resources Investigations Report↗

Aquifer geochemistry and effects of pumping on ground-water quality at the Green Belt Parkway Well Field, Holbrook, Long Island, New York

Geochemistry, microbiology, and water quality of the Magothy aquifer at a new supply well in Holbrook were studied to help identify factors that contribute to iron-related biofouling of public-supply wells. The organic carbon content of borehole sediments from the screen zone, and the dominant terminal electron-accepting processes (TEAPs), varied by depth. TEAP assays of core sediments indicated that iron reduction, sulfate reduction, and undetermined (possibly oxic) reactions and microbial activity are correlated with organic carbon (lignite) content. The quality of water from this well, therefore, reflects the wide range of aquifer microenvironments at this site. High concentrations of dissolved iron (3.6 to 6.4 micromoles per liter) in water samples from this well indicate that some water is derived from Fe(III)-reducing sediments within the aquifer, but traces of dissolved oxygen indicate inflow of shallow, oxygenated water from shallow units that overlie the local confining units. Water-quality monitoring before and during a 2-day pumping test indicates that continuous pumping from the Magothy aquifer at this site can induce downward flow of shallow, oxygenated water despite the locally confined conditions. Average concentrations of dissolved oxygen are high (5.2 milligrams per liter, or mg/L) in the overlying upper glacial aquifer and at the top of the Magothy aquifer (4.3 mg/L), and low ( < 0.1 mg/L) in the deeper, anaerobic part of the Magothy; average concentrations of phosphate are high (0.4 mg/L) in the upper glacial aquifer and lower (0.008 mg/L) at the top of the Magothy aquifer and in the deeper part of the Magothy (0.013 mg/L). Concentrations of both constituents increased during the 2 days of pumping. The δ 34 S of sulfate in shallow ground water from observation wells (3.8 to 6.4 per mil) was much heavier than that in the supplywell water (-0.1 per mil) and was used to help identify sources of water entering the supply well. The δ 34 S of sulfate in a deep observation well adjacent to the supply well increased from 2.4 per mil before pumping to 3.3 per mil after pumping; this confirms that the pumping induced downward migration of water. The lighter δ 34 S value in the pumped water than in the adjacent observation well probably indicates FeS 2 oxidation (which releases light δ 34 S in adjacent sediments) by the downward flow of oxygenated water.

New York↗

Historical trends and concentrations of fecal coliform bacteria in the Brandywine Creek basin, Chester County, Pennsylvania

The Brandywine Creek in Chester County is used for recreation and as an important source of drinking water. For this study, 40 sites were established for collection of water samples for analysis of fecal coliform and Escherichia coli bacteria in 1998-99. Samples were collected during base-flow conditions and during five storms in which rainfall exceeded 0.5 inch. During base- flow conditions, the median concentrations of fecal coliform bacteria exceeded 200 col/100 mL at 26 of the 40 sites (65 percent). During stormflow conditions, the median concentration of fecal coliform bacteria exceeded the Pennsylvania Department of Environmental Protection (PaDEP) criterion of 200 col/100 mL at 30 of 33 sites sampled (91 percent). Trends in fecal coliform bacteria concentrations were downward for the period 1973-99 at three long-term water-quality monitor stations, the result of upgrades in wastewater treatment plants, decreases in point-source discharges, and a decrease in agricultural land. A positive relation exists between streamflow and concentrations of fecal coliform bacteria at two of the long-term stations, but concentrations are elevated in base flow and stormflow at all three stations. Factors affecting bacteria concentrations in the Brandywine Creek Basin include nonpoint-source contaminants, reservoirs, seasonality, and stormflow. Nonpoint sources of bacterial contamination in the basin include, but are not limited to, land-surface runoff, urbanization, agricultural processes, groundwater contamination, and wildlife. Bacteria concentrations in streams that flow directly from the reservoirs are much lower than the concentrations in the streams flowing into the reservoirs. During March, April, May, October, and November, the Brandywine Creek tends to have lower water temperatures and bacteria concentrations than during June, July, August, and September. The 10-year median concentrations of bacteria at West Branch Brandywine Creek at Modena and East Branch Brandywine Creek below Downingtown exceed the criterion of 200 col/100 mL established by the PaDEP during the swimming season. The 10-year median concentrations of bacteria at Brandywine Creek at Chadds Ford exceed the criterion of 200 col/100 mL only during June. None of the stations exceed the criterion of 2,000 col/100 mL as established by the PaDEP for the remainder of the year.

Water-Resources Investigations Report↗

Relations among rainstorm runoff, streamflow, pH, and metal concentrations, Summitville Mine area, upper Alamosa River basin, southwest Colorado, 1995-97

The upper Alamosa River Basin contains areas that are geochemically altered and have associated secondary sulfide mineralization. Occurring with this sulfide mineralization are copper, gold, and silver deposits that have been mined since the 1870's. Weathering of areas with sulfide mineralization produces runoff with anomalously low pH and high metal concentrations; mining activities exacerbate the condition. Summer rainstorms in the upper Alamosa River Basin produce a characteristic relation between streamflow and pH; streamflow suddenly increases and pH suddenly decreases (commonly by more than 1 pH unit). This report evaluates changes in pH in the upper Alamosa River Basin during July, August, and September 1995, 1996, and 1997 to examine possible adverse environmental effects due to rainstorm runoff. Ninety-three percent of the rainstorms occurring during 1995?97 produced runoff throughout the entire basin. Out of 54 storms, only 3 storms were isolated to the river reach upstream from the streamflow-gaging station Alamosa River above Wightman Fork, and only 1 storm was isolated to the river reach between the streamflow-gaging stations Alamosa River below Jasper and Alamosa River above Terrace Reservoir. Although most rainstorm runoff events occurred throughout the entire basin, pH changes were highest in parts of the basin that receive runoff from hydrothermally altered areas. The three principal altered areas within the basin are the Jasper, Stunner, and Summitville areas. Only limited mining occurred in the Stunner altered area, and yet significant decreases in pH values occur due to runoff from this area. Even after environmental restoration activities are completed at the Summitville Mine, the main stem of the Alamosa River may continue to be adversely affected by runoff from the Stunner and Jasper altered areas. A comparison of measured pH with Federal and State of Colorado water-quality standards and Toxicological Reference Values indicates pH was too low to support aquatic life in many parts of the basin for extended periods of time. Added stresses from sudden decreases in pH due to rainstorm runoff compound the adverse effects. Discharge of effluent from the Summitville Mine impoundment can significantly decrease pH in the Alamosa River downstream to Terrace Reservoir. A release of only 3 cubic feet per second from the impoundment decreased pH by at least 1 standard unit at all downstream sites. Low-flow years may pose a substantial risk to aquatic organisms within and downstream from Terrace Reservoir. During 1996, the basin had a low-flow year, and water storage and pool size of Terrace Reservoir were significantly reduced. The pH of water discharging from Terrace Reservoir was anomalously low during late August and September 1996, possibly due to geochemical interactions between sediment and the water column within the reservoir. In general, an inverse log-log relation exists between pH and the logarithm of dissolved metal concentrations, but the relations generally are not significant enough to confidently predict metal concentrations based upon measured pH values.

Water-Resources Investigations Report↗

Vertical gradients in water chemistry in the central High Plains aquifer, southwestern Kansas and Oklahoma panhandle, 1999

The central High Plains aquifer is the primary source of water for domestic, industrial, and irrigation uses in parts of Colorado, Kansas, New Mexico, Oklahoma, and Texas. Water-level declines of more than 100 feet in some areas of the aquifer have increased the demand for water deeper in the aquifer. The maximum saturated thickness of the aquifer ranged from 500 to 600 feet in 1999. As the demand for deeper water increases, it becomes increasingly important for resource managers to understand how the quality of water in the aquifer changes with depth. In 1998?99, 18 monitoring wells at nine sites in southwestern Kansas and the Oklahoma Panhandle were completed at various depths in the central High Plains aquifer, and one monitoring well was completed in sediments of Permian age underlying the aquifer. Water samples were collected once from each well in 1999 to measure vertical gradients in water chemistry in the aquifer. Tritium concentrations measured in ground water indicate that water samples collected in the upper 30 feet of the aquifer were generally recharged within the last 50 years, whereas all of the water samples collected at depths more than 30 feet below the water table were recharged more than 50 years ago. Dissolved oxygen was present throughout the aquifer, with concentrations ranging from 1.7 to 8.4 mg/L. Water in the central High Plains aquifer was predominantly a calcium-bicarbonate type that exhibited little variability in concentrations of dissolved solids with depth (290 to 642 mg/L). Exceptions occurred in some areas where there had been upward movement of mineralized water from underlying sediments of Permian age and areas where there had been downward movement of mineralized Arkansas River water to the aquifer. Calcium-sulfate and sodium-chloride waters dominated and concentrations of dissolved solids were elevated (862 to 4,030 mg/L) near the base of the aquifer in the areas of upward leakage. Dissolution of gypsum or anhydrite and halite in sediments of Permian age by ground water was the likely source of calcium, sulfate, sodium, and chloride in those waters. Calcium-sodium-sulfate waters dominated, and concentrations of dissolved solids were as large as 4,916 mg/L near the water table in the area of downward leakage. Dissolution of minerals in sedimentary deposits of marine origin in upstream areas of the Arkansas River drainage were the likely sources of calcium, sodium, and sulfate in those waters. Nitrate was detected throughout the aquifer and the background concentration was estimated to be 2.45 mg/L as N. The largest nitrate concentrations (8.28, 22, and 54.4 mg/L as N) occurred in recently recharged water collected adjacent to irrigated fields. Three pesticides (atrazine, metolachlor, simazine) and five pesticide degradation products (alachlor ethanesulfonic acid, alachlor oxanilic acid, deethylatrazine, metolachlor ethanesulfonic acid, metolachlor oxanilic acid) were detected in recently recharged water from six water-table wells. Five of the six wells were adjacent to irrigated fields. These data indicate that concentrations of nitrate and pesticides increased over time in some areas of the aquifer as a result of agricultural activities. Results from this study indicate that vertical gradients in water chemistry existed in the central High Plains aquifer. The chemical gradients resulted from chemical inputs to the aquifer from underlying sediments of Permian age, from the Arkansas River, and from agricultural activities. In areas where those chemical inputs occurred, water quality in the aquifer was impaired and may not have been suitable for some intended uses.

Water-Resources Investigations Report↗

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