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Differences in neonicotinoid and metabolite sorption to activated carbon are driven by alterations to the insecticidal pharmacophore

Widespread application of neonicotinoids has led to their proliferation in waters. Despite low neonicotinoid hydrophobicity, our prior studies implicated granular activated carbon (GAC) in neonicotinoid removal. Based on known receptor binding characteristics, we hypothesized that the insecticidal pharmacophore influences neonicotinoid sorption. Our objectives were to illuminate drivers of neonicotinoid sorption for parent neonicotinoids (imidacloprid, clothianidin, thiamethoxam, and thiacloprid) and pharmacophore-altered metabolites (desnitro-imidacloprid and imidacloprid urea) to GAC, powdered activated carbon, and carbon nanotubes (CNTs). Neonicotinoid sorption to GAC was extensive and largely irreversible, with significantly greater sorption of imidacloprid than desnitro-imidacloprid. Imidacloprid and imidacloprid urea (electronegative pharmacophores) sorbed most extensively to nonfunctionalized CNTs, whereas desnitro-imidacloprid (positive pharmacophore) sorbed most to COOH-CNTs, indicating the importance of charge interactions and/or hydrogen bonding between the pharmacophore and carbon surface. Water chemistry parameters (temperature, alkalinity, ionic strength, and humic acid) inhibited overall neonicotinoid sorption, suggesting that pharmacophore-driven sorption in real waters may be diminished. Analysis of a full-scale drinking water treatment plant GAC filter influent, effluent, and spent GAC attributes neonicotinoid/metabolite removal to GAC under real-world conditions for the first time. Our results demonstrate that the neonicotinoid pharmacophore not only confers insecticide selectivity but also impacts sorption behavior, leading to less effective removal of metabolites by GAC filters in water treatment.

Environmental Science and Technology↗

Subduction intraslab-interface fault interactions in the 2022 Mw 6.4 Ferndale, California earthquake sequence

The Mendocino triple junction, the intersection of the Pacific, North American, and Gorda plates, activates a collection of disparate faults that reconcile Cascadia subduction with San Andreas transform motion. The December 20, 2022, Mw 6.4 Ferndale, California earthquake occurred within this complex zone as strike-slip faulting within the subducting Gorda slab. Here, we analyze the seismic and geodetic signatures of the mainshock and aftershock sequence to illuminate its role within complex tectonic surroundings. We find aftershocks on varied fault structures within the uppermost Gorda slab, yet seismicity on the subduction interface itself was notably absent. Nevertheless, we identify small but coherent postseismic deformation that is well modeled by aseismic slip on this interface, likely triggered by stresses generated at the updip limit of coseismic rupture. This sequence demonstrates the potential for interactions between intra-slab earthquakes and slip on the subduction megathrust, highlighting the need to consider this and other subduction zones as coupled systems of interacting faults.

California↗

Editorial: Volcanic forecasting, crisis management, and risk communication

Volcanic eruptions intermittently punctuate periods of repose at volcanic centers and fields. Forecasting the timing, style, distribution, and magnitude of these eruptions is difficult, because eruptive activity varies over time, commonly in an irregular way. Furthermore, the impacts of eruptions can include loss of lives, property damage, and social and economic disturbance, where every eruption produces different impacts. Mitigation of volcanic risk is therefore complex, requiring community action that is aided by preparedness actions of emergency managers, stakeholders, community leaders, and individuals, and by timely delivery and reception of hazard information during a crisis. This Research Topic addresses efforts to understand complexities in these relations dealing with volcanic unrest, eruptions, and eruption impacts. Research Topic range from eruption forecasting (Wild et al.; Christophersen et al.; Bernard et al.) and volcanic hazard assessment (Mead et al.) to risk communication and action (Martinez-Villegas et al.; Todesco et al.; Graham et al.; Bernard et al.) prior to and during volcanic crises. The studies use various methodologies and approaches, touching on various parts of the integrated, multi-partner systems that exist to improve risk mitigation.

Frontiers in Earth Science↗

Exposure to human-associated chemical markers of fecal contamination and self-reported illness among swimmers at recreational beaches

Anthropogenic chemicals have been proposed as potential markers of human fecal contamination in recreational water. However, to date, there are no published studies describing their relationships with illness risks. Using a cohort of swimmers at seven U.S. beaches, we examined potential associations between the presence of chemical markers of human fecal pollution and self-reported gastrointestinal (GI) illness, diarrhea, and respiratory illness. Swimmers were surveyed about their beach activities, water exposure, and baseline symptoms on the day of their beach visit, and about any illness experienced 10–12 days later. Risk differences were estimated using model-based standardization and adjusted for the swimmer’s age, beach site, sand contact, rainfall, and water temperature. Sixty-two chemical markers were analyzed from daily water samples at freshwater and marine beaches. Of those, 20 were found consistently. With the possible exception of bisphenol A and cholesterol, no chemicals were consistently associated with increased risks of illness. These two chemicals were suggestively associated with 2% and 1% increased risks of GI illness and diarrhea in both freshwater and marine beaches. Additional research using the more sensitive analytic methods currently available for a wider suite of analytes is needed to support the use of chemical biomarkers to quantify illness risk and identify fecal pollution sources.

Alabama, Indiana, Michigan, Mississippi, Ohio, Rho↗

Regional resource depletion and industry activity: The case of oil and gas in the Gulf of Mexico

Stable and declining oil and gas prices have changed the industry's price expectations and, along with depletion of promising exploration prospects, has resulted in reduced exploration. Even with intensive additional exploration, production in most U.S. areas is expected to decline. What does this imply for the drilling and petroleum industry suppliers in particular regions? How should planners in government and the private sector project and incorporate the consequences of these changes in their strategies? This paper answers these questions for the industry operating in the offshore Gulf of Mexico. Future oil and gas production, as well as demand for offshore drilling and production facilities, are shown to depend on the size distribution of undiscovered fields, their associated production costs, and oil and gas prices. Declining well productivity is a consequence of development of progressively smaller fields so that long-run drilling demand should not decline in proportion to the expected production decline. Calculations show a substantial payoff to the drilling industry, in terms of potential demand increases, if it can develop and implement cost reducing technologies. Implications of these results for other offshore producing areas such as the North Sea are also discussed.

Socio-Economic Planning Sciences↗

Estradiol-induced gene expression in largemouth bass (Micropterus salmoides)

Vitellogenin (Vtg) and estrogen receptor (ER) gene expression levels were measured in largemouth bass to evaluate the activation of the ER-mediated pathway by estradiol (E2). Single injections of E2 ranging from 0.0005 to 5 mg/kg up-regulated plasma Vtg in a dose-dependent manner. Vtg and ER mRNAs were measured using partial cDNA sequences corresponding to the C-terminal domain for Vtg and the ligand-binding domain of ER?? sequences. After acute E2-exposures (2 mg/kg), Vtg and ER mRNAs and plasma Vtg levels peaked after 2 days. The rate of ER mRNA accumulation peaked 36-42 h earlier than Vtg mRNA. The expression window for ER defines the primary response to E2 in largemouth bass and that for Vtg a delayed primary response. The specific effect of E2 on other estrogen-regulated genes was tested during these same time windows using differential display RT-PCR. Specific up-regulated genes that are expressed in the same time window as Vtg were ERp72 (a membrane-bound disulfide isomerase) and a gene with homology to an expressed gene identified in zebrafish. Genes that were expressed in a pattern that mimics the ER include the gene for zona radiata protein ZP2, and a gene with homology to an expressed gene found in winter flounder. One gene for fibrinogen ?? was down-regulated and an unidentified gene was transiently up-regulated after 12 h of exposure and returned to basal levels by 48 h. Taken together these studies indicate that the acute molecular response to E2 involves a complex network of responses over time. ?? 2002 Elsevier Science Ireland Ltd. All rights reserved.

Molecular and Cellular Endocrinology↗

Groundwater dynamics at Kīlauea Volcano and vicinity, Hawaiʻi

Kīlauea Volcano, on the Island of Hawaiʻi, is surrounded and permeated by active groundwater systems that interact dynamically with the volcanic system. A generalized conceptual model of Hawaiian hydrogeology includes high-level dike-impounded groundwater, very permeable perched and basal aquifers, and a transition (mixing) zone between freshwater and saltwater. Most high-level groundwater is associated with the low-permeability intrusive complexes that underlie volcanic rift zones and calderas and also act to compartmentalize the groundwater system. Hydrogeologic studies of Kīlauea in recent decades, accompanied by deep research drilling, have shown that high-level groundwater is more widespread than once understood, that permeability decreases dramatically at depth, particularly in rift zones, and that freshwater can occur at depths of as much as several kilometers below the local water table. Copious groundwater recharge causes near-surface conductive heat flow to be near zero over much of Kīlauea. Approximately 95 percent of groundwater discharge occurs offshore, accompanied by approximately 99 percent of the approximately 6,000 megawatts of heat supplied by magmatic intrusion. Here, we summarize current understanding of the groundwater system of Kīlauea Volcano and describe transient changes during the decade or more preceding the 2018 eruption sequence. The changes in groundwater chemistry and thermal structure beneath Kīlauea summit hold implications for volcanic-volatile transport and the potential for explosive volcanism. Between 2008 and 2018, the magma conduit beneath the lava lake likely created an adjacent zone of very hot rock that significantly delayed liquid groundwater inflow to the draining magma conduit. Sulfate concentrations in groundwater beneath Kīlauea summit, sampled at the National Science Foundation-funded drill hole 1.5 kilometers south-southwest of the lava lake, declined substantially between 2010 and present. This decline likely reflects, at least in part, the decreased effectiveness of volatile condensation and solution into groundwater (scrubbing). The vent opening in 2008 presumably focused volatile flux into the vicinity of the vent, and progressive drying of the surroundings further restricted interaction with the groundwater system. The decrease in sulfate concentrations in the drill hole between 2010 and 2018 likely reflects decreased effectiveness of scrubbing.

Hawaii↗

A millennial-scale record of Pb and Hg contamination in peatlands of the Sacramento-San Joaquin Delta of California, USA

In this paper, we provide the first record of millennial patterns of Pb and Hg concentrations on the west coast of the United States. Peat cores were collected from two micro-tidal marshes in the Sacramento-San Joaquin Delta of California. Core samples were analyzed for Pb, Hg, and Ti concentrations and dated using radiocarbon, 210Pb, and 137Cs. Pre-anthropogenic concentrations of Pb and Hg in peat ranged from 0.60 to 13.0 µg g-1and from 6.9 to 71 ng g-1, respectively. For much of the past 6000+ years, the Delta was free from anthropogenic pollution, however, beginning in ~1425 CE, Hg and Pb concentrations, Pb/Ti ratios, Pb enrichment factors (EFs), and HgEFs all increased. Pb isotope compositions of the peat suggest that this uptick was likely caused by smelting activities originating in Asia. The next increases in Pb and Hg contamination occurred during the California Gold Rush (beginning ~1850 CE), when concentrations reached their highest levels (74 µg g-1 Pb, 990 ng g-1 Hg; PbEF = 12 and HgEF = 28). Lead concentrations increased again beginning in the ~1920s with the incorporation of Pb additives in gasoline. The phase-out of lead additives in the late 1980s was reflected in Pb isotope ratios and reductions in Pb concentrations in the surface layers of the peat. The rise and fall of Hg contamination was also tracked by the peat archive, with the highest Hg concentrations occurring just before 1963 CE and then decreasing during the post-1963 period. Overall, the results show that the Delta was a pristine region for most of its ~6700-year existence; however, since ~1425 CE, it has received Pb and Hg contamination from both global and regional sources.

California↗

Success of lake restoration depends on spatial aspects of nutrient loading and hydrology

Many aquatic ecosystems have deteriorated due to human activities and their restoration is often troublesome. It is proposed here that the restoration success of deteriorated lakes critically depends on hitherto largely neglected spatial heterogeneity in nutrient loading and hydrology. A modelling approach is used to study this hypothesis by considering four lake types with contrasting nutrient loading (point versus diffuse) and hydrology (seepage versus drainage). By comparing the longterm effect of common restoration measures (nutrient load reduction, lake flushing or biomanipulation) in these four lake types, we found that restoration through reduction of nutrient loading is effective in all cases. In contrast, biomanipulation only works in seepage lakes with diffuse nutrient inputs, while lake flushing will even be counterproductive in lakes with nutrient point sources. The main conclusion of the presented analysis is that a priori assessment of spatial heterogeneity caused by nutrient loading and hydrology is essential for successful restoration of lake ecosystems.

Science of the Total Environment↗

Developmental instability in Rhus copallinum L.: multiple stressors, years, and responses

Developmental instability, as assessed by leaf fluctuating asymmetry and stem internode allometry, was examined at nine sites, representing three levels of disturbance, over multiple years. Site selection was based on land‐use disturbance classes related to training of mechanized infantry and other land management activities at Fort Benning, Georgia. Developmental instability varied among sites and years, and there was a strong site‐by‐year interaction for many traits. Indeed, depending on the year, the same site could be ranked as having the greatest and least amount of leaf fluctuating asymmetry. Burning a site the year prior to collecting the leaves profoundly influenced measures of leaf fluctuating asymmetry. In the absence of recent burning, leaf fluctuating asymmetry declined with increasing disturbance, but burning the year prior to collecting the leaves reversed this trend. Total plant cover, proportion of bare ground, and amount of plant litter influenced the amount of leaf asymmetry in a site‐dependent manner. Overall, burning influenced the levels of developmental instability more than either disturbance or microhabitat variables such as total plant cover, which should reflect competition in a plant’s immediate neighborhood.

International Journal of Plant Sciences↗

Flood-inundation maps for the Peckman River in the Townships of Verona, Cedar Grove, and Little Falls, and the Borough of Woodland Park, New Jersey, 2014

Digital flood-inundation maps for an approximate 7.5-mile reach of the Peckman River in New Jersey, which extends from Verona Lake Dam in the Township of Verona downstream through the Township of Cedar Grove and the Township of Little Falls to the confluence with the Passaic River in the Borough of Woodland Park, were created by the U.S. Geological Survey (USGS) in cooperation with the New Jersey Department of Environmental Protection. The flood-inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation/ depict estimates of the probable areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage on the Peckman River at Ozone Avenue at Verona, New Jersey (station number 01389534). Near-real-time stages at this streamgage may be obtained on the Internet from the USGS National Water Information System at http://waterdata.usgs.gov/ . Flood profiles were simulated for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated using the most current stage-discharge relations at USGS streamgages on the Peckman River at Ozone Avenue at Verona, New Jersey (station number 01389534) and the Peckman River at Little Falls, New Jersey (station number 01389550). The hydraulic model was then used to compute eight water-surface profiles for flood stages at 0.5-foot (ft) intervals ranging from 3.0 ft or near bankfull to 6.5 ft, which is approximately the highest recorded water level during the period of record (1979–2014) at USGS streamgage 01389534, Peckman River at Ozone Avenue at Verona, New Jersey. The simulated water-surface profiles were then combined with a geographic information system digital elevation model derived from light detection and ranging (lidar) data to delineate the area flooded at each water level. The availability of these maps along with Internet information regarding current stage from the USGS streamgage provides emergency management personnel and residents with information, such as estimates of inundation extents, based on water stage, that is critical for flood response activities such as evacuations and road closures, as well as for post-flood recovery efforts.

New Jersey↗

Flood-inundation maps for the Big Blue River at Shelbyville, Indiana

Digital flood-inundation maps for a 4.1-mile reach of the Big Blue River at Shelbyville, Indiana, were created by the U.S. Geological Survey (USGS) in cooperation with the Indiana Office of Community and Rural Affairs. The floodinundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at https://water. usgs.gov/osw/flood_inundation/, depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage on the Big Blue River at Shelbyville, Ind. (station number 03361500). Near-real-time stages at this streamgage may be obtained from the USGS National Water Information System at https://waterdata. usgs.gov/ or the National Weather Service (NWS) Advanced Hydrologic Prediction Service at https://water.weather.gov/ ahps/, which also forecasts flood hydrographs at this site (SBVI3). Flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The hydraulic model was calibrated by using the most current stage-discharge relation at the Big Blue River at Shelbyville, Ind., streamgage. The calibrated hydraulic model was then used to compute 12 water-surface profiles for flood stages referenced to the streamgage datum and ranging from 9.0 feet, or near bankfull, to 19.4 feet, the highest stage of the current stage-discharge rating curve. The simulated water-surface profiles were then combined with a Geographic Information System digital elevation model (derived from light detection and ranging [lidar] data having a 0.98-foot vertical accuracy and 4.9-foot horizontal resolution) to delineate the area flooded at each water level. The availability of these maps, along with Internet information regarding current stage from the USGS streamgage at the Big Blue River at Shelbyville, Ind., and forecasted stream stages from the NWS, will provide emergency management personnel and residents with information that is critical for flood response activities such as evacuations and road closures as well as for post-flood recovery efforts.

Indiana↗

Nature's refineries — Metals and metalloids in arc volcanoes

Chemical data for fumaroles and for atmospheric gas and ash plumes from active arc volcanoes provide glimpses of the rates of release of metal and metalloids, such as Tl and Cd, from shallow and mid-crust magmas. Data from copper deposits formed in ancient volcanoes at depths of up to about 1500 m in the fractures below paleo-fumaroles, and at around 2000–4000 m in association with sub-volcanic intrusions (porphyry copper deposits) provide evidence of sub-surface deposition of Cu–Au–Ag–Mo and a range of other minor elements including Te, Se, As and Sb. These deposits, or ‘sinks’, of metals consistently record sustained histories of magmatic gas streaming through volcanic systems interspersed by continuing intrusive and eruptive activity. Here we integrate data from ancient and modern volcanic systems and show that the fluxes of metals and metalloids are controlled by a) the maintenance of fracture permeability in the stressed crust below volcanoes and b) the chemical processes that are triggered as magmatic gas, initially undersaturated with metals and metalloids, expands from lithostatic to very low pressure conditions through fracture arrays. The recognition of gas streaming may also account for the phenomenon of ‘excess degassing’, and defines an integral, but generally understated, component of active volcanic systems – a volcanic gas core – that is likely to be integral to the progression of eruptions to Plinean state. Destabilization of solvated molecular metal and metalloid species in magmatic gas mixtures and changes in their redox state are triggered, as it expands to the surface by abrupt pressure drops, or throttles' in the fracture array that guides expansion to the surface. The electronically harder, low electronegativity metals, such as copper and iron, deposit rapidly in response to expansion followed more slowly by arsenic with antimony as sulfosalts. Heavy, large radius, softer elements such as bismuth, lead, and thallium along with cadmium are strongly fractionated along the way, eventually venting their excess along with SO 2 , CO 2 , and other components of the carrier gas, into the atmosphere. These elements, many of which are toxic, may also be dispersed by mixing with groundwater in the permeable crust below volcanoes and generate potential health risks due to Hg, As, and Se contamination of drinking water resources.

Earth-Science Reviews↗

Channels and valleys on Mars: Cold climate features formed as a result of a thickening cryosphere

Large flood channels, valley networks, and a variety of features attributed to the action of ground ice indicate that Mars emerged from heavy bombardment around 3.8Gyr ago, with an inventory of water at the surface equivalent to at least a few hundred meters spread over the whole planet, as compared with 3 km for the Earth. The surface water resided primarily in a porous, kilometers thick, megaregolith created by the high impact rates. At the end of heavy bombardment a rapid decline in erosion rates by a factor of 1000 suggests a major change in the global climate. It is proposed that at this time the climate became similar to today's and that this climate has been maintained throughout the rest of Mars' history. The various drainage features represent an adjustment of the distribution of water to the surface relief inherited from the period of heavy bombardment and to a thickening of the cryosphere as the heat flow declined. The valley networks formed mostly at the end of heavy bombardment when erosion rates were high and climatic conditions permitted an active water cycle. They continued to form after heavy bombardment when the cryosphere started to form by a combination of episodic flooding and mass-wasting aided by the presence of liquid water at shallow depths. As the cryosphere thickened with declining heat flow, water could no longer easily access the surface and the rate of valley formation declined. Hydrostatic pressures built below the cryosphere. Eruptions of groundwater became more catastrophic and massive floods resulted, mainly in upper Hesperian time. Flood sources were preferentially located in low-lying, low-latitude areas where the cryosphere was thin, or near volcanoes where a thinner than typical cryosphere is also expected. Floods caused a drawdown in the global water table so that few formed in the second half of Mars' history. The floodwaters pooled in low-lying areas, mostly in the northern plains. Some of the water may still be present as thick ice deposits, some has been lost to space, particularly during periods of high obliquity.

Planetary and Space Science↗

Evaluation of current techniques for isolation of chars as natural adsorbents

Chars in soils or sediments may potentially influence the soil/sediment sorption behavior. Current techniques for the isolation of black carbon including chars rely often on acid demineralization, base extraction, and chemical oxidation to remove salts and minerals, humic acid, and refractory kerogen, respectively. Little is known about the potential effects of these chemical processes on the char surface and adsorptive properties. This study examined the effects of acid demineralization, base extraction, and acidic Cr2O72- oxidation on the surface areas, surface acidity, and benzene adsorption characteristics of laboratory-produced pinewood and wheat-residue chars, pure or mixed with soils, and a commercial activated carbon. Demineralization resulted in a small reduction in the char surface area, whereas base extraction showed no obvious effect. Neither demineralization nor base extraction caused an appreciable variation in benzene adsorption and presumably the char surface properties. By contrast, the Cr2O 72- oxidation caused a >31% reduction in char surface area. The Boehm titration, supplemented by FTIR spectra, indicated that the surface acidity of oxidized chars increased by a factor between 2.3 and 12 compared to nonoxidized chars. Benzene adsorption with the oxidized chars was lower than that with the non-oxidized chars by a factor of >8.9; both the decrease in char surface area and the increase in char surface acidity contributed to the reduction in char adsorptive power. Although the Cr 2O72- oxidation effectively removes resistant kerogen, it is not well suited for the isolation of chars as contaminant adsorbents because of its destructive nature. Alternative nondestructive techniques that preserve the char surface properties and effectively remove kerogen must be sought.

Environmental Science & Technology↗

Forecasting and communicating the dispersion and fallout of ash during volcanic eruptions: lessons from the September 20, 2020 eruptive pulse at Sangay volcano, Ecuador

Volcanic ash is a hazard to human health and activities. Accurate and timely forecasts coupled with effective communication about the dispersion and fallout of volcanic ash during explosive events are essential to reduce impacts on local communities and limit economic losses. In this study, we present the first detailed description of an eruptive pulse at Sangay volcano and its eruption source parameters. The eruptive pulse on September 20, 2020, started at about 9:20 UTC and lasted between 90 and 100 min, producing an eruptive column that rapidly separated into (1) a higher (15.2 km above sea level, asl), gas-rich cloud moving east-southeast and (2) a lower (12.2 km asl), ash-rich cloud moving west and causing ash fallout up to 280 km from the volcano. Field data collected immediately after the event allow estimating the volume of bulk tephra to be between 1.5 and 5.0 × 10 6 m 3 , corresponding to a volcanic explosivity index of 2. The eruptive pulse, identified as violent Strombolian, emitted andesitic ash that was more mafic than products ejected by Sangay volcano in recent decades. Component analysis and glass chemistry of juvenile particles support the hypothesis that this event excavated deeper into the upper conduit compared to typical Strombolian activity at Sangay volcano, while grain-size analysis allows reconstruction of the total grain-size distribution of the fallout deposit. The discrepancies between the ash fallout simulations performed with the Ash3D online tool and the actual deposit are mainly the result of inaccurate pre- and syn-eruptive configurations and highlight the importance of additional processes such as aggregation. Communication products issued during the event included (1) several standard short reports, (2) volcano observatory notices for aviation, (3) social media posts, and (4) a special report providing the results of the ash fallout simulation. Although communication was effective with the authorities and the connected population, an effort must be made to reach the most vulnerable isolated communities for future events. This study shows that forecasting ash dispersion and fallout during volcanic eruptions can guide early warnings and trigger humanitarian actions, and should become a standard in volcano observatories worldwide.

Sangay volcano↗

Discovery of an intact Quaternary paleosol, Georgia Bight, USA

A previously buried paleosol was found on the continental shelf during a study of sea floor scour, nucleated by large artificial reef structures such as vessel hulks, barges, train cars, military vehicles, etc., called “scour nuclei”. It is a relic paleo-land surface of sapling-sized tree stumps, root systems, and fossil animal bone exhumed by scour processes active adjacent to the artificial reef structure. Over the span of five research cruises to the site in 2022–2024, soil samples were taken using hand excavation, PONAR grab samplers, split spoon, hollow tube auger, and a modified Shelby-style push box. High-definition (HD) video was taken using a Remotely Operated Vehicle (ROV) and diver-held cameras. Radiocarbon dating of wood samples returned ages of 42,015–43,417 calibrated years before present (cal yrBP). Pollen studies, together with the recovered macrobotanical remains, support our interpretation of the site as a freshwater forested wetland whose keystone tree species was Taxodium distichum —bald cypress. The paleosol was identified as an Aquult, a sub-order of Ultisols where water tables are at or near the surface year-round. A deep (0.25 m+) argillic horizon comprised the bulk of the preserved soil. Comparable Ultisols found in Georgia wetlands include Typic Paleaquult (Grady and Bayboro series) soils.

Georgia↗

Flood-inundation maps for the Saddle River from Rochelle Park to Lodi, New Jersey, 2012

Digital flood-inundation maps for a 2.75-mile reach of the Saddle River from 0.2 mile upstream from the Interstate 80 bridge in Rochelle Park to 1.5 miles downstream from the U.S. Route 46 bridge in Lodi, New Jersey, were created by the U.S. Geological Survey (USGS) in cooperation with the New Jersey Department of Environmental Protection (NJDEP). The inundation maps, which can be accessed through the USGS Flood Inundation Mapping Science Web site at http://water.usgs.gov/osw/flood_inundation , depict estimates of the areal extent and depth of flooding corresponding to selected water levels (stages) at the USGS streamgage at Saddle River at Lodi, New Jersey (station 01391500). Current conditions for estimating near real-time areas of inundation using USGS streamgage information may be obtained on the Internet at http://waterdata.usgs.gov/nwis/uv?site_no=01391500 . The National Weather Service (NWS) forecasts flood hydrographs at many places that are often collocated with USGS streamgages. NWS-forecasted peak-stage information may be used in conjunction with the maps developed in this study to show predicted areas of flood inundation. In this study, flood profiles were computed for the stream reach by means of a one-dimensional step-backwater model. The model was calibrated using the most current stage-discharge relations at the Saddle River at Lodi, New Jersey streamgage and documented high-water marks from recent floods. The hydraulic model was then used to determine 11 water-surface profiles for flood stages at the Saddle River streamgage at 1-ft intervals referenced to the streamgage datum, North American Vertical Datum of 1988 (NAVD 88), and ranging from bankfull, 0.5 ft below NWS Action Stage, to the extent of the stage-discharge rating, which is approximately 1 ft higher than the highest recorded water level at the streamgage. Action Stage is the stage which when reached by a rising stream the NWS or a partner needs to take some type of mitigation action in preparation for possible significant hydrologic activity. The simulated water-surface profiles were then combined with a geographic information system 3-meter (9.84-ft) digital elevation model (derived from Light Detection and Ranging (LiDAR) data) in order to delineate the area flooded at each water level. The availability of these maps, along with Internet information regarding current stage from USGS streamgages and forecasted stream stages from the NWS, provide emergency management personnel and residents with information that is critical for flood response activities, such as evacuations and road closures, as well as for post-flood recovery efforts.

New Jersey↗

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