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Age and composition of igneous rocks, Edna Mountain quadrangle, Humboldt County, Nevada

Six pulses of igneous activity ranging in age from Jurassic to Pliocene have been identified in the Edna Mountain quadrangle, Humboldt County, Nev. Porphyritic syenite am! quartz monzonite of Jurassic age (146-164 million years) at Buffalo Mountain are highly potassic through a wide range in SiO 2 content from olivine-bearing syenite to quartz-rich monzonite, and their composition contrasts sharply with plutons elsewhere in north-central Nevada. Granodiorite and quartz monzonite plutons of Cretaceous age (88- 106 m.y.) are chemically and mineralogically similar to other calc-alkaline plutons in north-central Nevada. Four episodes of Tertiary volcanism include rhyolite ashflow tuffs and slightly younger andesitic basalt flows and tuffs of Oligocene age, rhyolite vitrophyre of late Miocene age, and olivine basalt flows of Pliocene age. Their age and mineralogical and chemical compositions are similar to other Tertiary volcanic rocks in north-central Nevada.

Nevada↗

Ground-water conditions in southern Utah Valley and Goshen Valley, Utah

The investigation of ground-water conditions in southern Utah Valley and Goshen Valley, Utah, was made by the U. S. Geological Survey as part of a cooperative program with the Utah Department of Natural Resources, Division of Water Rights, to investigate the water resources of the State. The purposes of the investigation were to (1) determine the occurrence, recharge, discharge, movement, storage, chemical quality, and availability of ground water; (2) appraise the effects of increased withdrawal of water from wells; and (3) evaluate the effect of the Central Utah Project on the ground-water reservoir and the water supply of Utah Lake. This report presents a description of the aquifer system in the two valleys, a detailed description of the ground-water resources, and conclusions about potential development and its effect on the hydrologic conditions in the valleys. Two supplementary reports are products of the investigation. A basic-data release (Cordova, 1969) contains most of the basic data collected for the investigation, including well characteristics, drillers' logs, water levels, pumpage from wells, chemical analyses of ground and surface waters, and discharge of selected springs, drains, and streams. An interpretive report (Cordova and Mower, 1967) contains the results of a large-scale aquifer test in southern Utah Valley.

Utah↗

Radiochemical determination of very low concentrations of nickel in rocks and minerals

A radiochemical procedure has been developed for the determination of very low concentrations of nickel in rocks and minerals. Sensitivity is 0.01 μ g Ni. Accuracy and precision is estimated to be ±5 percent to levels as low as 0.1 μ g Ni a marked improvement over other analytical techniques. Samples are irradiated, combined with nickel carrier, and treated by a series of chemical procedures: (1) collection of nickel in a lead bead using a fire-assay technique, (2) refusion of the lead bead and precipitation of basic element hydroxides, (3) anion-exchange chromatography, and (4) precipitation of nickel dimethylglyoxime. The nickel precipitate is weighed to determine chemical yield and counted for β activity of Ni 65 along with a precipitate from irradiated nickel standard solution.

Journal of Research of the U.S. Geological Survey↗

Use of isotopic data to evaluate recharge and geologic controls on the movement of ground water in Las Posas Valley, Ventura County, California

Injection, storage, and recovery of imported water is planned for aquifers underlying Las Posas Valley. To evaluate sources of ground-water recharge and the age of the water (time since recharge), and to identify barriers to ground-water flow prior to the injection of imported water, samples from wells and surface sources were collected and analyzed for chemical and isotopic composition. The delta oxygen- 18 and delta deuterium composition in almost 50 samples from 32 wells ranged from -6.0 to -7.9 per mil, and -40 to -60 per mil, respectively; and in 13 samples of surface water at 6 sites the composition ranged from -6.2 to -9.4 per mil, and -42 to -71 per mil, respectively. Water from wells in the upper aquifer system near Arroyo Simi and Arroyo Las Posas (different reaches of the same stream) was isotopi cally lighter than water from other wells sampled and was similar in isotopic composition to water in the stream. Water in the stream is a mixture of local water and imported water from northern California that was discharged to the stream as treated municipal wastewater. Water from wells near the stream contained tritium and, therefore, was recharged less than 50 years ago. Water from wells in other parts of the valley was isotopically heavier, did not contain tritium, and, therefore, was recharged more than 50 years ago. Interpreted carbon-14 ages for water from wells along a flow path through the valley ranged from at least 800 to more than 8,000 years before present. There were large differences in the chemistry, isotopic composition, and interpreted age of water from wells between the eastern and western parts of Las Posas Valley. These changes are consistent with geologic and hydrologic data that suggest the presence of a barrier to ground-water flow between east and west Las Posas Valley.

Water-Resources Investigations Report↗

Occurrence and distribution of dissolved pesticides in the San Joaquin River basin, California

The effects of pesticide application, hydrology, and chemical and physical properties on the occurrence of pesticides in surface water in the San Joaquin River Basin, California, were examined. The study of pesticide occurrence in the highly agricultural San Joaquin?Tulare Basins is part of the National Water-Quality Assessment Program of the U.S. Geological Survey. One hundred forty-three water samples were collected throughout 1993 from sites on the San Joaquin River and three of its tributaries: Orestimba Creek, Salt Slough, and the Merced River. Of the 83 pesticides selected for analysis in this study, 49 different compounds were detected in samples from the four sites and ranged in concentration from less than the detection limit to 20 micrograms per liter. All but one sample contained at least one pesticide, and more than 50 percent of the samples contained seven or more pesticides. Six compounds were detected in more than 50 percent of the samples: four herbicides (dacthal, EPTC, metolachlor, and simazine) and two insecticides (chlorpyrifos and diazinon). None of the measured concentrations exceeded U.S. Environmental Protection Agency drinking water criteria, and many of the measured concentrations were very low. The concentrations of seven pesticides exceeded criteria for the protection of freshwater aquatic life: azinphos-methyl, carbaryl, chlorpyrifos, diazinon, diuron, malathion, and trifluralin. Overall, some criteria for protection of aquatic life were exceeded in a total of 97 samples. Factors affecting the spatial patterns of occurrence of the pesticides in the different subbasins included the pattern of application and hydrology. Seventy percent of pesticides with known application were detected. Overall, 40 different pesticides were detected in Orestimba Creek, 33 in Salt Slough, and 26 in the Merced River. Samples from the Merced River had a relatively low number of detections, despite the high number (35) of pesticides applied, owing to the generally low percentage of irrigation return flow and contribution of pesticide-free streamflow from reservoir releases. Irrigation return flows in the Orestimba Creek and Salt Slough subbasins generally contained more pesticides at higher concentrations. In addition, the distribution of seven pesticides (alachlor, cyanazine, dacthal, fonofos, molinate, napropamide, and trifluralin) in the subbasins showed a direct spatial correspondence between occurrence and application rates. Temporal patterns of occurrence also were affected by patterns of application and hydrology. Most pesticides showed a clear correspondence between the times of their application and their occurrence. Fourteen pesticides had maximum application and concentrations during the summer irrigation season. However, several pesticides exhibited maximum concentrations during winter storms, although maximum application occurred at some other time of year?the result of differences in precipitation and streamflow between seasons. In some subbasins, precipitation runoff was more effective than irrigation return flows at transporting pesticides from the site of application to the stream. Also, during autumn, when there was neither precipitation nor irrigation, the transport of pesticides to streams was limited. The effect of chemical and physical properties on the occurrence of pesticides was examined for the San Joaquin River Basin as a whole. The runoff potential of each pesticide, calculated from the solubility, water-soil organic carbon partition coefficient Koc, and hydrolysis half-life, is generally consistent with the frequency of detection of pesticides in surface water in relation to the amount applied. These three properties each were generally, and weakly, correlated with the relative load of the pesticides in surface water. Pesticide occurrence and concentrations at the mouth of the basin (the San Joaquin River near Vernalis) was compared with pesticide occurrence and concentration in the three

Water-Resources Investigations Report↗

Bibliography of selected references on the hydrogeologic and chemical properties of the Galena-Platteville bedrock unit in Illinois and Wisconsin, 1877-1997

This report presents selected references concerning the Galena-Platteville deposits in Illinois and Wisconsin published from 1877 to 1997. Sources of the bibliographic information are the Universities of Illinois and Wisconsin Library Computer Systems; Illinet Online; the Illinois and Wisconsin District Libraries of the U.S. Geological Survey; U.S. Geological Survey Selected Water Resources Abstracts; U.S. Environmental Protection Agency reports; and Federal, State, and local agencies, corporations, and consultants. The bibliography is arranged alphabetically, by county, in Illinois and Wisconsin. The references available for each county are arranged alphabetically by author. In addition, one or more selected hydrogeologic key words describing the content of the reference follow each listing. These key words are geophysical properties, hydraulic properties, inorganic geochemistry, lithology, organic geochemistry, physical properties, and water use. Included in the bibliography are 186 references obtained for 15 counties in Illinois and 21 counties in Wisconsin.

Water-Resources Investigations Report↗

Preserving ground water samples with hydrochloric acid does not result in the formation of chloroform

Water samples collected for the determination of volatile organic compounds (VOCs) are often preserved with hydrochloric acid (HCl) to inhibit the biotransformation of the analytes of interest until the chemical analyses can he performed. However, it is theoretically possible that residual free chlorine in the HCl can react with dissolved organic carbon (DOC) to form chloroform via the haloform reaction. Analyses of 1501 ground water samples preserved with HCl from the U.S. Geological Survey's National Water-Quality Assessment Program indicate that chloroform was the most commonly detected VOC among 60 VOCs monitored. The DOC concentrations were not significantly larger in samples with detectable chloroform than in those with no delectable chloroform, nor was there any correlation between the concentrations of chloroform and DOC. Furthermore, chloroform was detected more frequently in shallow ground water in urban areas (28.5% of the wells sampled) than in agricultural areas (1.6% of the wells sampled), which indicates that its detection was more related to urban land-use activities than to sample acidification. These data provide strong evidence that acidification with HCl does not lead to the production of significant amounts of chloroform in ground water samples. To verify these results, an acidification study was designed to measure the concentrations of all trihalomethanes (THMs) that can form as a result of HCl preservation in ground water samples and to determine if ascorbic acid (C 6 H 8 O 6 ) could inhibit this reaction if it did occur. This study showed that no THMs were formed as a result of HCl acidification, and that ascorbic acid had no discernible effect on the concentrations of THMs measured.

Groundwater Monitoring & Remediation↗

The physical hydrogeology of ore deposits

Hydrothermal ore deposits represent a convergence of fluid flow, thermal energy, and solute flux that is hydrogeologically unusual. From the hydrogeologic perspective, hydrothermal ore deposition represents a complex coupled-flow problem—sufficiently complex that physically rigorous description of the coupled thermal (T), hydraulic (H), mechanical (M), and chemical (C) processes (THMC modeling) continues to challenge our computational ability. Though research into these coupled behaviors has found only a limited subset to be quantitatively tractable, it has yielded valuable insights into the workings of hydrothermal systems in a wide range of geologic environments including sedimentary, metamorphic, and magmatic. Examples of these insights include the quantification of likely driving mechanisms, rates and paths of fluid flow, ore-mineral precipitation mechanisms, longevity of hydrothermal systems, mechanisms by which hydrothermal fluids acquire their temperature and composition, and the controlling influence of permeability and other rock properties on hydrothermal fluid behavior. In this communication we review some of the fundamental theory needed to characterize the physical hydrogeology of hydrothermal systems and discuss how this theory has been applied in studies of Mississippi Valley-type, tabular uranium, porphyry, epithermal, and mid-ocean ridge ore-forming systems. A key limitation in the computational state-of-the-art is the inability to describe fluid flow and transport fully in the many ore systems that show evidence of repeated shear or tensional failure with associated dynamic variations in permeability. However, we discuss global-scale compilations that suggest some numerical constraints on both mean and dynamically enhanced crustal permeability. Principles of physical hydrogeology can be powerful tools for investigating hydrothermal ore formation and are becoming increasingly accessible with ongoing advances in modeling software.

Economic Geology↗

Effects of urban development on stream ecosystems in nine metropolitan study areas across the United States

Urban development is an important agent of environmental change in the United States. The urban footprint on the American landscape has expanded during a century and a half of almost continuous development. Eighty percent of Americans now live in metropolitan areas, and the advantages and challenges of living in these developed areas—convenience, congestion, employment, pollution—are part of the day-to-day realities of most Americans. Nowhere are the environmental changes associated with urban development more evident than in urban streams. Contaminants, habitat destruction, and increasing streamflow flashiness resulting from urban development have been associated with the disruption of biological communities, particularly the loss of sensitive aquatic species. Every stream is connected downstream to larger water bodies, including rivers, reservoirs, and ultimately coastal waters. Inputs of chemical contaminants or sediments at any point along the stream can cause degradation downstream with adverse effects on biological communities and on economically valuable resources, such as fisheries and tourism. In response to general concerns about the degradation of urban streams, the U.S. Geological Survey (USGS) conducted a national-scale, scientific investigation of the effects of urban development on stream ecosystems. Nine metropolitan study areas of the United States were selected—Portland, Oregon; Salt Lake City, Utah; Birmingham, Alabama; Atlanta, Georgia; Raleigh, North Carolina; Boston, Massachusetts; Denver, Colorado; Dallas, Texas; and Milwaukee, Wisconsin. The studies were conducted in Salt Lake City, Birmingham, and Boston in 1999–2000; in Atlanta, Raleigh, and Denver in 2002–2003; and in Portland, Dallas, and Milwaukee in 2003–2004. The comprehensive investigation of all nine studies focused on three broad questions of interest to decision makers: What are the primary effects of urban development on stream ecosystems? How do the effects of urban development on stream ecosystems vary regionally across the country? Which urban-related stressors are most closely linked to biological community degradation, and how can multiple stressors be managed to protect stream health as a watershed becomes increasingly urbanized?

Alabama;Colorado;Georgia;Massachusetts;North Carol↗

Continuous and discrete water-quality data collected at five sites on Lake Houston near Houston, Texas, 2006-08

Lake Houston, a reservoir impounded in 1954 by the City of Houston, Texas, is a primary source of drinking water for Houston and surrounding areas. The U.S. Geological Survey, in cooperation with the City of Houston, developed a continuous water-quality monitoring network to track daily changes in water quality in the southwestern quadrant of Lake Houston beginning in 2006. Continuous water-quality data (the physiochemical properties water temperature, specific conductance, pH, dissolved oxygen concentration, and turbidity) were collected from Lake Houston to characterize the in-lake processes that affect water quality. Continuous data were collected hourly from mobile, multi-depth monitoring stations developed and constructed by the U.S. Geological Survey. Multi-depth monitoring stations were installed at five sites in three general locations in the southwestern quadrant of the lake. Discrete water-quality data (samples) were collected routinely (once or twice each month) at all sites to characterize the chemical and biological (phytoplankton and bacteria) response to changes in the continuous water-quality properties. Physiochemical properties (the five continuously monitored plus transparency) were measured in the field when samples were collected. In addition to the routine samples, discrete water-quality samples were collected synoptically (one or two times during the study period) at all sites to determine the presence and levels of selected constituents not analyzed in routine samples. Routine samples were measured or analyzed for acid neutralizing capacity; selected major ions and trace elements (calcium, silica, and manganese); nutrients (filtered and total ammonia nitrogen, filtered nitrate plus nitrite nitrogen, total nitrate nitrogen, filtered and total nitrite nitrogen, filtered and total orthophosphate phosphorus, total phosphorus, total nitrogen, total organic carbon); fecal indicator bacteria (total coliform and Escherichia coli); sediment (suspended-sediment concentration and loss-on-ignition); actinomycetes bacteria; taste-and-odor-causing compounds (2-methylisoborneol and geosmin); cyanobacterial toxins (total microcystins); and phytoplankton abundance, biovolume, and community composition (taxonomic identification to genus). Synoptic samples were analyzed for major ions, trace elements, wastewater indicators, pesticides, volatile organic compounds, and carbon. The analytical data are presented in tables by type (continuous, discrete routine, discrete synoptic) and listed by station number. Continuously monitored properties (except pH) also are displayed graphically.

Texas↗

Understanding Amphibian Declines Through Geographic Approaches

Growing concern over worldwide amphibian declines warrants serious examination. Amphibians are important to the proper functioning of ecosystems and provide many direct benefits to humans in the form of pest and disease control, pharmaceutical compounds, and even food. Amphibians have permeable skin and rely on both aquatic and terrestrial ecosystems during different seasons and stages of their lives. Their association with these ecosystems renders them likely to serve as sensitive indicators of environmental change. While much research on amphibian declines has centered on mysterious causes, or on causes that directly affect humans (global warming, chemical pollution, ultraviolet-B radiation), most declines are the result of habitat loss and habitat alteration. Improving our ability to characterize, model, and monitor the interactions between environmental variables and amphibian habitats is key to addressing amphibian conservation. In 2000, the U.S. Geological Survey (USGS) initiated the Amphibian Research and Monitoring Initiative (ARMI) to address issues surrounding amphibian declines.

Fact Sheet↗

Selected coal-related ground-water data, Wasatch Plateau-Book Cliffs area, Utah

The Wasatch Plateau-Book Cliffs%area as used in this report consists of about 8,000 square miles in east-central Utah. The major geographic features included in the area are the Wasatch Plateau, Book Cliffs, San Rafael Swell, Price River basin, and a small part of the Green River basin (pl. 1). The area is defined by approximate drainage-divide boundaries in the Wasatch Plateau and Book Cliffs, by an arbitrary boundary on the south, and by the Utah-Colorado State line on the east. The Wasatch Plateau-Book Cliffs area includes all the operating coal mines in Utah in 1978. Annual coal production in the area is expected to increase from the current (1978) rate of about 8 million tons to as much as 30 million tons within the next 10 years (J. W. Moffitt, U.S. Geological Survey, oral commun., 1978). Ground water is an important source of water supply in the area. As mining increases and mining-related municipalities grow, many sources of ground-water supply may be subjected to increased demands and possibly degradation of chemical quality. Waddell, Vickers, Upton, and Contratto (1978) reported some ground- water data after a reconnaissance of part of the area. The purpose of this report, which was prepared in cooperation with the U.S. Bureau of Land Management, is to present a more detailed compilation of ground-water-related data that were collected and compiled during October 1976 to March 1978. The report is designed to make the data available in an orderly and usable form for local and regional water managers and other users of water data.

Utah↗

Analytical methods of the U.S. Geological Survey's New York District Water-Analysis Laboratory

The New York District of the U.S. Geological Survey (USGS) in Troy, N.Y., operates a water-analysis laboratory for USGS watershed-research projects in the Northeast that require analyses of precipitation and of dilute surface water and soil water for major ions; it also provides analyses of certain chemical constituents in soils and soil gas samples. This report presents the methods for chemical analyses of water samples, soil-water samples, and soil-gas samples collected in wateshed-research projects. The introduction describes the general materials and technicques for each method and explains the USGS quality-assurance program and data-management procedures; it also explains the use of cross reference to the three most commonly used methods manuals for analysis of dilute waters. The body of the report describes the analytical procedures for (1) solution analysis, (2) soil analysis, and (3) soil-gas analysis. The methods are presented in alphabetical order by constituent. The method for each constituent is preceded by (1) reference codes for pertinent sections of the three manuals mentioned above, (2) a list of the method's applications, and (3) a summary of the procedure. The methods section for each constitutent contains the following categories: instrumentation and equipment, sample preservation and storage, reagents and standards, analytical procedures, quality control, maintenance, interferences, safety considerations, and references. Sufficient information is presented for each method to allow the resulting data to be appropriately used in environmental investigations.

Open-File Report↗

Reconnaissance of Soil, Ground Water, and Plant Contamination at an Abandoned Oilfield-Service Site near Shawnee, Oklahoma, 2005-2006

The U.S. Geological Survey, in cooperation with the Absentee Shawnee Tribe of Oklahoma, began a reconnaissance study of a site in Pottawatomie County, Oklahoma, in 2005 by testing soil, shallow ground water, and plant material for the presence of trace elements and semivolatile organic compounds. Chemical analysis of plant material at the site was investigated as a preliminary tool to determine the extent of contamination at the site. Thirty soil samples were collected from 15 soil cores during October 2005 and analyzed for trace elements and semivolatile organic compounds. Five small-diameter, polyvinyl-chloride-cased wells were installed and ground-water samples were collected during December 2005 and May 2006 and analyzed for trace elements and semivolatile organic compounds. Thirty Johnsongrass samples and 16 Coralberry samples were collected during September 2005 and analyzed for 53 constituents, including trace elements. Results of the soil, ground-water, and plant data indicate that the areas of trace element and semivolatile organic compound contamination are located in the shallow (A-horizon) soils near the threading barn. Most of the trace-element concentrations in the soils on the study site were either similar to or less than trace-element concentrations in background soils. Several trace elements and semivolatile organic compounds exceeded the U.S. Environmental Protection Agency, Region 6, Human Health Medium-Specific Screening Levels 2007 for Tap Water, Residential Soils, Industrial Indoor Soils, and Industrial Outdoor Soils. There was little or no correlation between the plant and soil sample concentrations and the plant and ground-water concentrations based on the current sample size and study design. The lack of correlation between trace-element concentrations in plants and soils, and plants and ground water indicate that plant sampling was not useful as a preliminary tool to assess contamination at the study site.

Scientific Investigations Report↗

Groundwater quality near the Placerita Oil Field, California, 2018

Groundwater-quality data and potential fluid-migration pathways near the Placerita Oil Field in Los Angeles County, California, were examined by the U.S. Geological Survey to determine if oil-field fluids (water and gas from oil-producing and non-producing zones) have mixed with groundwater resources. Six of the 13 new groundwater samples collected for this study contained petroleum hydrocarbons, thermogenic gas, inorganic chemical signatures, and (or) isotopic values consistent with potential mixing with fluids from hydrocarbon-bearing formations. For historical groundwater samples, benzene was the most detected petroleum hydrocarbon. The historical groundwater samples with a benzene concentration greater than 0.5 micrograms per liter were from environmental monitoring wells at industrial or commercial facilities unrelated to oil and gas development that, in many cases, have identified soil or groundwater contamination and were not typically analyzed for other constituents that could provide additional lines of evidence for potential mixing with oil-field fluids. Methane was not detected in any of the 12 historical samples with a reported measurement. Reviewing historical data revealed factors that could potentially adversely affect groundwater quality in the study area. These factors include modified hydraulic gradients caused by large volumes of water extracted from the main production area and reinjected downgradient into nonproducing zones, well-barrier failures in wells constructed in the northern part of the oil field before the 1970s, well-barrier failures in produced-water disposal wells downgradient from the main production area, and naturally occurring hydrocarbons at shallow intervals. The groundwater samples most geochemically similar to samples from hydrocarbon-bearing formations were in areas where hydrocarbons are naturally occurring at shallow intervals and where oil development is at shallow depths. Additional data for hydraulic heads, water quality, and formation temperatures at multiple depths in areas with large injection volumes and well-integrity issues are needed to evaluate whether those factors have contributed to mixing between fluids from oil-producing or injection formations and groundwater resources.

California↗

Water resources data for Indiana, water year 1971

Water resources data for the 1971 water year for Indiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gaging and water-quality stations in bordering States also are included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of J. L. Cook, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Indiana.

Indiana↗

Water resources data for Indiana, water year 1972

Water resources data for the 1972 water year for Indiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gaging and water-quality stations in bordering States also are included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey under the direction of J. L. Cook, district chief. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Indiana.

Indiana↗

Water resources data for Indiana, water year 1973

Water resources data for the 1973 water year for Indiana, including records of streamflow or reservoir storage at gaging stations, partial-record stations, and miscellaneous sites, and records of water-quality data on the chemical and physical characteristics of surface water are given in this report. Records for a few pertinent gating and water-quality stations in bordering states also are included. The records were collected and computed by the Water Resources Division of the U.S. Geological Survey. These data represent that portion of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Indiana.

Indiana↗

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