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The estuarine chemistry and isotope systematics of 234,238U in the Amazon and Fly Rivers

Natural concentrations of 238U and ??234U values were determined in estuarine surface waters and pore waters of the Amazon and Fly (Papua New Guinea) Rivers to investigate U transport phenomena across river-dominated land-sea margins. Discharge from large, tropical rivers is a major source of dissolved and solid materials transported to the oceans, and are important in defining not only oceanic mass budgets, but also terrestrial weathering rates. On the Amazon shelf, salinity-property plots of dissolved organic carbon, pH and total suspended matter revealed two vastly contrasting water masses that were energetically mixed. In this mixing zone, the distribution of uranium was highly non-conservative and exhibited extensive removal from the water column. Uranium removal was most pronounced within a salinity range of 0-16.6, and likely the result of scavenging and flocculation reactions with inorganic (i.e., Fe/Mn oxides) and organic colloids/particles. Removal of uranium may also be closely coupled to exchange and resuspension processes at the sediment/water interface. An inner-shelf pore water profile indicated the following diagenetic processes: extensive (???1 m) zones of Fe(III) - and, to a lesser degree, Mn(IV) - reduction in the absence of significant S(II) concentrations appeared to facilitate the formation of various authigenic minerals (e.g., siderite, rhodocrosite and uraninite). The pore water dissolved 238U profile co-varied closely with Mn(II). Isotopic variations as evidenced in ??234U pore waters values from this site revealed information on the origin and history of particulate uranium. Only after a depth of about 1 m did the ??234U value approach unity (secular equilibrium), denoting a residual lattice bound uranium complex that is likely an upper-drainage basin weathering product. This suggests that the enriched ??234U values represent a riverine surface complexation product that is actively involved in Mn-Fe diagenetic cycles and surface complexation reactions. In the Fly River estuary, 238U appears to exhibit a reasonably conservative distribution as a function of salinity. The absence of observed U removal does not necessarily imply non-reactivity, but instead may record an integration of concurrent U removal and release processes. There is not a linear correlation between ??234U vs. 1/ 238U that would imply simple two component mixing. It is likely that resuspension of bottom sediments, prolonged residence times in the lower reaches of the Fly River, and energetic particle-colloid interactions contribute to the observed estuarine U distribution. The supply of uranium discharged from humid, tropical river systems to the sea appears to be foremost influenced by particle/water interactions that are ultimately governed by the particular physiographic and hydrologic characteristics of an estuary. ?? 2004 Elsevier Ltd. All rights reserved.

Continental Shelf Research↗

Isotopic dating of Meso- and Neoproterozoic mafic magmatism in the southern Tobacco Root Mountains, Southwestern Montana

New isotopic dating of mafic dikes in the southern Tobacco Root Mountains of southwestern Montana provides evidence for two distinct episodes of subparallel Proterozoic mafic magmatism separated by about 700 m.y. Previously published geochemical data from dikes in the southern Tobacco Root Mountains had identified three geochemical groups (termed groups A, B, and C) with apparent Rb–Sr ages of 1455 Ma (group A) and 1100–1120 Ma (groups B and C). Sm–Nd dating of a geochemical group A dike yields an age of 1448 ± 49 Ma that is interpreted to represent the emplacement age of the dikes. This age is similar to published U–Pb dates from mafic sills that intrude the nearby Mesoproterozoic Belt Supergroup and Laramide basement-cored uplifts of the Archean Wyoming Province. Paleomagnetic results from groups A and B dikes are similar, suggesting that the were emplaced at about the same time. We suggest that the mafic magmatism recorded by the southern Tobacco Root Mountains group A/C dikes at about 1450 Ma probably corresponds to continental extension that accompanied development of the Mesoproterozoic Belt Basin. U–Pb dating of baddeleyite from the group B dikes provides evidence for a younger magmatic event with an age of 782.4 ± 4.9 Ma (95% confidence; ±7.1 Ma incorporating uranium decay constant errors). This date is similar to isotopic dates from Neoproterozoic mafic dikes and sills exposed elsewhere in uplifts of the Rocky Mountain foreland and that intrude the Mesoproterozoic strata of the Belt Supergroup. Geochronologic data from elsewhere in the northern Cordillera and Canadian Shield indicate that the group B dikes in the southern Tobacco Root Mountains are part of a regional 780 Ma magmatic event that extended for more than 2400 km along the western margin of Laurentia. The origin of the magmatic event is not clear, but may be related to a mantle plume and crustal extension accompanying initial breakup of the supercontinent Rodinia and development of the proto-Pacific Ocean. No evidence of ca. 1100 Ma mafic magmatism in this part of the northern Cordillera was found.

Montana↗

Geomorphology, acoustic backscatter, and processes in Santa Monica Bay from multibeam mapping

Santa Monica Bay was mapped in 1996 using a high-resolution multibeam system, providing the first substantial update of the submarine geomorphology since the initial compilation by Shepard and Emery [(1941) Geol. Soc. Amer. Spec. Paper 31]. The multibeam mapping generated not only high-resolution bathymetry, but also coregistered, calibrated acoustic backscatter at 95 kHz. The geomorphology has been subdivided into six provinces; shelf, marginal plateau, submarine canyon, basin slope, apron, and basin. The dimensions, gradients, and backscatter characteristics of each province is described and related to a combination of tectonics, climate, sea level, and sediment supply. Fluctuations of eustatic sea level have had a profound effect on the area; by periodically eroding the surface of Santa Monica plateau, extending the mouth of the Los Angeles River to various locations along the shelf break, and by connecting submarine canyons to rivers. A wetter glacial climate undoubtedly generated more sediment to the rivers that then transported the increased sediment load to the low-stand coastline and canyon heads. The trends of Santa Monica Canyon and several bathymetric highs suggest a complex tectonic stress field that has controlled the various segments. There is no geomorphic evidence to suggest Redondo Canyon is fault controlled. The San Pedro fault can be extended more than 30 km to the northwest by the alignment of a series of bathymetric highs and abrupt changes in direction of channel thalwegs.

California↗

Holocene paleohydrology from alpine lake sediment, Emerald Lake, Wasatch Plateau of central Utah, USA

Holocene sediments at Emerald Lake in central Utah (3090 m asl) document the paleohydroclimatic history of the western Upper Colorado River headwater region. Multi-proxy analyses of sediment composition, mineralogy, and stable isotopes of carbonate (δ 18 O and δ 13 C) show changes in effective moisture for the past ca. 10,000 years at millennial to decadal timescales. Emerald Lake originated as a shallow, closed-basin cirque pond during the Early Holocene. By ca. 7000 cal yr BP, higher lake levels and carbonate δ 18 O values indicate rising effective moisture and higher proportions of summer precipitation continued at least until ca. 5500 cal yr BP when a landslide entered the lake margin. Between ca. 4500 and 2400 cal yr BP dry conditions at Emerald Lake envelop the timing of the ‘Late Holocene Dry Period’ identified at lower elevations. For the past ca. 2500 years, Emerald Lake δ 18 O values were relatively low, indicating wetter conditions and higher snow input (compared to rain), except for dry periods at ca. 2000 cal yr BP and during the Medieval Climate Anomaly at ca. 1000 and ca. 500 cal yr BP. Results provide a long-term perspective on precipitation extremes that influence regional water supplies from a snow-dominated catchment typical of the predominant source region for the Upper Colorado River.

Utah↗

Identifying structural priors in a hybrid differentiable model for stream water temperature modeling

Although deep learning models for stream temperature ( T s ) have recently shown exceptional accuracy, they have limited interpretability and cannot output untrained variables. With hybrid differentiable models, neural networks (NNs) can be connected to physically based equations (called structural priors) to output intermediate variables such as water source fractions (specifying what portion of water is groundwater, subsurface, and surface flow). However, it is unclear if such outputs are physically meaningful when only limited physics is imposed, and if structural priors have enough impacts to be identifiable from data. Here, we tested four alternative structural priors describing basin-scale water temperature memory and instream heat processes in a differentiable stream temperature model where NNs freely estimate the water source fractions. We evaluated models’ abilities to predict T s and baseflow ratio. The four priors exhibited noticeably different behaviors in these two metrics and their tradeoffs, with some dominating others. Therefore, the better structural priors can be identified. Moreover, testing different priors yielded valuable insights: having a separate shallow subsurface flow component better matches observations, and a recency-weighted averaging of past air temperature for calculating source water temperature resulted in better T s and baseflow prediction than traditionally employed simple averaging. However, we also highlight the limitations when insufficient physical constraints are implemented: the internal variables (water source fractions) may not be adequately constrained by a single target variable (stream temperature) alone. To ensure the physical significance of the internal fluxes, one can either employ multivariate data for model selection, or include more physical processes in the priors.

Water Resources Research↗

A spatiotemporal interrogation of hydrologic drought model performance for machine learning model interpretability

The predictive accuracy of regional hydrologic models often varies across both time and space. Interpreting relationships between watershed characteristics, hydrologic regimes, and model performance can reveal potential areas for model improvement. In this study, we use machine learning to assess model performance of a regional hydrologic model to forecast the occurrence of streamflow drought. We demonstrate our methodology using a regional long short-term memory (LSTM) deep learning model developed by the U.S. Geological Survey (USGS) and data from 384 streamgages across the Colorado River Basin region. Performance was assessed by clustering catchments using: (a) physical and climatological catchment attributes, and (b) streamflow drought signatures time series. We examined the association of USGS LSTM model error measures with clusters generated by both approaches to interpret meaningful spatial and temporal information about LSTM model performance. Clustering static catchment attributes identified elevation, degree of streamflow regulation, baseflow contribution, catchment aridity, and drainage area as the most influential attributes to model performance. Clustering gages by their drought signatures revealed that catchments with significant seasonal peak runoff between January and June generally exhibited better model performance. Additionally, a Random Forest classifier was trained to successfully predict LSTM model performance (F1 score of 0.72) based on physical and climatological catchment attributes. Low degree of flow regulation was identified as a key indicator of better LSTM model performance. These findings point to the opportunities for improving the USGS LSTM model performance in future hydrologic drought prediction efforts across regional and CONUS scales.

Arizona, California, Colorado, Idaho, Montana, Nev↗

Understanding the water resources of a mountain-block aquifer: Tucson Mountains, Arizona

Water resources are limited in arid locations such as Tucson Basin. Residential development in the Tucson Mountains to the west of Tucson, Arizona, is limited by groundwater resources. Groundwater samples were collected from fractured bedrock and alluvial aquifers surrounding the Tucson Mountains to assess water quality and recharge history through measurement of stable O, H, and S isotopes; tritium; and 14 C. Most groundwater is a mixture of different ages but is commonly several thousand years old. A few sampling locations indicated a component of water recharged after the above-ground nuclear testing of the mid 1950s, and these sites may represent locations near where the aquifer receives present-day recharge. The Tucson Mountains also host sulfide deposits associated with fractures and replacement zones; these locally contribute to poor-quality groundwater. Projections of future climate predict intensifying drought in southwestern North America. In the study area, a combination of strategies such as rainwater harvesting, exploitation of renewable water, and low groundwater use could be used for sustainable use of the groundwater supply.

Arizona↗

Predominant bacteria isolated from moribund Fusconaia ebena ebonyshells experiencing die-offs in Pickwick Reservoir, Tennessee River, Alabama

Mussel die-offs have been noted in recent years in Pickwick Reservoir, Tennessee River, Alabama. The primary affected species was Fusconaia ebena, but also affected to lesser degrees were Ellipsaria lineolata, Quadrula pustulosa, and Quadrula quadrula. These events were characterized by large numbers of empty shells—fresh-dead and live individuals that were presumed to be diseased because of weak and slow valve closure responses to external stimuli. Anecdotal evidence suggested the possible involvement of an etiological agent, such as a bacterial pathogen. The die-offs have occurred in Pickwick Reservoir (river miles 236–256) in sequential years during the past approximately 10 y. These timeframes have coincided with reduced basin inflows and warmer water temperatures. The majority of the moribund and freshly dead F. ebena were females possibly predisposed to infection and disease from ongoing reproductive activity. Affected and healthy-cohort mussels were collected to characterize the bacterial flora prior to, during, and after a July 2006 die-off, and during a subsequent die-off in September 2008. The numbers of total bacteria from both the 2006 and 2008 die-offs were significantly greater from the diseased specimens. For example, from the September 2008 die-off, the mean count from diseased F. ebena soft tissues was 9.75 × 10 6 cfu/g, which was more than 100 times greater (P = 0.025) than the mean from healthy cohorts (6.74 × 10 4 cfu/g). The predominant bacteria from affected F. ebena from July 2006 were Hafnia alvei and Aeromonas sobria, whereas from September 2008 the predominant bacteria were Enterobacter spp., Aeromonas schubertii, Aeromonas veronii bv. veronii, and Aeromonas veronii bv. sobria.

Alabama↗

Chronology of late Pleistocene and Holocene volcanics, Long Valley and Mono Basin geothermal areas, eastern California

Hydration-rind ages based on hydration-rind thicknesses of obsidian and an assumed hydration rate of 5 microns /1000 yrs have been determined for the 26 exposed Mono domes and coulees. Hydration-rind thickness data give good estimates of relative age differences between the domes, but determination of absolute ages will depend upon calibration to radiometric ages. The first extrusion of highly differentiated, sparsely porphyritic rhyolite occurred an estimated 32,000 to 40,000 yrs ago and consists of a small dome at the northwest end of the contiguous chain. The next major extrusive event occurred about 24,000 yrs ago and is represented by two domes and a major tephra. About 10,000 yrs ago the frequency of eruptive activity increases and rhyolite lave was extruded at an average rate of 0.2 km3/1000 yrs; periods of dormancy ranging in length from 300 to 2000 yrs. About 2000 to 3000 yrs ago the rate of extrusion increased dramatically to 0.8 km3/1000 yrs beginning with the eruption of the South Coulee and its associated tephra. At the same time, the nature of erupted magma changed from sparsely porphyritic (3 to 10 per cent sanidine) to aphyric rhyolite. All eruptions since 2000 radiocarbon yrs BP have produced magma that is aphyric but is of the same chemical composition as the earlier porphyritic magma. Volumes of porphyritic and aphyric extrusives, each of which includes volumes of lava and volumes of pumiceous pyroclastics reduced for porosity, are nearly equal and together total about 4 km3. Projecting the recent rate of extrusion over the time since the last major eruption, 1185 radiocarbon yrs ago suggests that a future eruption in the Mono Chain could release as much as 1 km 3 of magma. The recent increase in extrusion rate and the contemporaneous change in the nature of the magma are attributed to an event in the magma chamber that allowed the release of hotter, more fluid, crystal-free magma. The young age for the beginning of rhyolite volcanism from the mono magma chamber suggests that rhyolite magma may have been emplaced in the shallow crust as recently as 32,000 to 40,000 yrs ago. Calculations by Lachenbruch et al. (1976, Jour. Geophys. Research, v. 81, p. 769-784) that a thermal disturbance at this age would have propagated upward by solid conduction only 4 km and offer an explanation for the lack of a heat-flow anomaly and surface indications of hydrothermal activity over the Mono magma chamber and its associated ring-fracture system. This report also contains new information on the age and chemistry of volcanics on the Mono Lake island, the Inyo domes, and tephras within the Long Valley Caldera. A newly discovered rhyolite tuff ring of late Quaternary age in the Toowa volcanic field of the southern Sierra Nevada is briefly described for it represents a new area that should be examined for potential as a geothermal area.

California↗

Distribution, abundance and production of Hemimysis anomala in Lake Ontario

Hemimysis anomala is one of the latest macroinvertebrates to invade the Laurentian Great Lakes. Since first reported in 2006, Hemimysis have been confirmed in several locations within the Great Lakes basin. However, little is known about the seasonal and spatial variation in demographics and dynamics of Hemimysis populations. We used a standardised pier-based methodology to describe the distribution of Hemimysis at 29 locations around the shoreline of Lake Ontario in 2009. Samples were collected in spring, summer, and fall at most locations, and bi-weekly at one site (Bronte Creek) over a 12-month period in 2009. For each site, we estimated abundance by sex and size. The more temporally intensive sampling at Bronte Creek enabled us to estimate production. Hemimysis were found at 83% of the sites visited, with densities generally highest in the northwest and lower at the other sites. Production estimates (2.67–14.09 mg dry weight·m − 2 ·d − 1 ) were higher than that of other common zooplankton species in the Great Lakes. We provide important life history parameters that will help ecologists better understand the potential impacts of Hemimysis on Great Lakes ecosystems.

Lake Ontario↗

Southern Salish Sea Habitat Map Series: Admiralty Inlet

In 2010 the Environmental Protection Agency, Region 10 initiated the Puget Sound Scientific Studies and Technical Investigations Assistance Program, designed to support research in support of implementing the Puget Sound Action Agenda. The Action Agenda was created in response to Puget Sound having been designated as one of 28 estuaries of national significance under section 320 of the U.S. Clean Water Act, and its overall goal is to restore the Puget Sound Estuary's environment by 2020. The Southern Salish Sea Mapping Project was funded by the Assistance Program request for proposals process, which also supports a large number of coastal-zone- and ocean-management issues. The issues include the recommendations of the Marine Protected Areas Work Group to the Washington State Legislature (Van Cleve and others, 2009), which endorses a Puget Sound and coast-wide marine conservation needs assessment, gap analysis of existing Marine Protected Areas (MPA) and recommendations for action. This publication is the first of four U.S. Geological Survey Scientific Investigation Maps that make up the Southern Salish Sea Mapping Project. The remaining three map blocks to be published in the future, located south of Admiralty Inlet, are shown in figure 1. Puget Sound is a deep, fjord-type estuary covering an area of 2,330 km 2 in the Pacific Northwest region of the United States (fig. 1). It is connected to the ocean by the Strait of Juan de Fuca, a turbulent passage approximately 160 km in length and 22 km wide at its west end, expanding to over 40 km wide at its east end (Thomson, 1994). During the Pleistocene, the area was occupied several times by lobes of continental ice, resulting in a complex basin-fill of glacial and interglacial deposits that are locally as thick as 1100 m (Johnson and others, 2001). The last glaciation, called the Fraser glaciation, began after 28,800±740 14 C yr B.P. when ice started a slow expansion (Clague, 1981). At peak advance the westward Juan de Fuca lobe reached the edge of the continental shelf through the Juan de Fuca Strait shortly before 14,460±200 14 C yr B.P. (Herzer and Bornhold, 1982). The southward Puget lobe advanced to its terminal position in Puget Sound by around 14,150 14 C yr B.P. (Porter and Swanson, 1998). Ice retreated from its maximum to northern Whidbey Island by 13,650±350 14 C yr B.P. (Dethier and others, 1995). Retreating glaciers resulted in a thick sequence of ice-contact, glacial-marine sediment, and early post-glacial sediments (Linden and Schurrer, 1988). These deposits have experienced the effects of a marine transgression followed by regression, resulting in a sea-level several tens of meters lower than the present day (Linden and Schurrer, 1988). A second transgression brought sea level to about the present level by around 5,470±120 14 C yr B.P. (Clague and others, 1982) establishing the present oceanographic and geologic environment Puget Sound is separated into four interconnected basins; Whidbey, Central (Main), Hood Canal, and South (Thomson, 1994). The Whidbey, Central, and Hood Canal basins are the three main branches of the Puget Sound estuary and are separated from the Strait of Juan de Fuca by a double sill at Admiralty Inlet. The Admiralty Inlet map area includes the Inlet and a portion of the Whidbey Basin (fig. 1). The shallower South Basin is separated by a sill at Tacoma Narrows and is highly branched with numerous finger inlets. Flow within Puget Sound is dominated by tidal currents of as much as 1 m/s at Admiralty Inlet, reducing to approximately 0.5 m/s in the Central Basin (Lavelle and others, 1988). The lack of silt and clay-sized sediments in the Admiralty Inlet map area is likely a result of the strong currents (see Ground-Truth Studies for the Admiralty Inlet Map Area, sheet 3). The subtidal component of flow reaches approximately 0.1 m/s and is driven by density gradients arising from the contrast in salty ocean water at the entrance and freshwater inputs from stream flow (Lavelle and others, 1988). The total freshwater input to Puget Sound is approximately 3.4 x 10 6 m 3 /day, primarily from the Skagit River (Cannon, 1983). The subtidal circulation mostly consists of a two-layered flow in the basins with fresher water exiting at the surface and saltier water entering at depth (Ebbesmeyer and Cannon, 2001). In general, surface waters flow north and deeper waters flow south; variations arise from wind effects that can drive a surface current in the same direction as the wind, and a baroclinic response in the lower layer to about 100-m depth (Matsuura and Cannon, 1997). Oceanographic properties are influenced by temporal forcing parameters such as reduced stream flow during the 2000-01 drought that increased surface salinity and decreased differences between surface and bottom waters (Newton and others, 2003). On offshore seismic-reflection profiles, Pleistocene strata (excluding latest Pleistocene glacial and post-glacial deposits) form a distinct seismic unit, bounded below by pre-Tertiary or Tertiary basement and above by typically flat-lying latest Pleistocene to Holocene deposits that fill in erosional or depositional relief (Johnson and others, 2001). Cores from central Puget Sound have accumulation rates that range from 85 to 1200 mg/cm 2 /yr, or 0.12 to 2.4 cm/yr; the highest accumulation rates are near the southern end of central Puget Sound (Carpenter and others, 1985). Carpenter and others (1985) un-weighted arithmetic mean of accumulation rates for central Puget Sound deeper stations is 480±340 (± one standard deviation) mg/cm 2 /yr. Lavelle and others (1985) also found rates as high as 1200 mg/cm 2 /yr over the past approximately 70 years in cores in the Central Basin off of and north and south of Elliott Bay. Puget Sound basin rates are comparable to rates in midshelf silt deposits on the Washington coast north of the Columbia River (Nittrouer and others, 1979). The deep subtidal (in other words, below SCUBA depths) habitats of Puget Sound are relatively poorly known. A few subtidal surveys exist for several habitat types from the 1960s and 1970s (reviewed in Dethier, 1990), using grab and box core data. The Dethier (1990) review divides habitat up into Coast and Marine Ecological Classification Standard (CMECS) substrate, water column energy, and depth zones but does not attempt to map these habitats, rather it is an inventory of habitats found in the area and the flora and fauna associated with each habitat. The approach of the Southern Salish Sea Mapping project is to create highly detailed seafloor maps through collection, integration, interpretation, and visualization of swath sonar data (the undersea equivalent of satellite remote-sensing data in terrestrial mapping), acoustic backscatter, seafloor video, seafloor photography, and bottom-sediment sampling data. This approach is based in part on methods presented and data collection and product needs identified at the Washington State Seafloor Mapping Workshop (Washington State Seafloor Mapping Workshop Steering Committee, 2008), attended by coastal and marine managers and scientists. The map products display seafloor geomorphology and substrate, and identify potential marine benthic habitats. It is emphasized that the more interpretive habitat and geology maps rely on the integration of multiple, new high-resolution datasets and that mapping at small scales would not be possible without such data. Oceanographic current and wave data is not included in this analysis, however, the accompanying geographic information system (GIS) data set is designed and intended to be combined with oceanographic and biologic data sets assembled by others in the future and some of the GIS data has already been incorporated in the unpublished Nature Conservancy Benthic Habitats of Puget Sound database. This publication includes four map sheets, explanatory text, and a descriptive pamphlet. Each map sheet is published as a portable document format (PDF) file. ESRI ArcGIS compatible geotiffs (for example, bathymetry) and shapefiles (for example video observation points) will be available for download in the data catalog associated with this publication (Cochrane, 2015). An ArcGIS Project File with the symbology used to generate the map sheets is also provided. For those who do not own the full suite of ESRI GIS and mapping software, the data can be read using ESRI ArcReader, a free viewer that is available at http://www.esri.com/software/arcgis/arcreader/index.html .

Washington↗

Late Quaternary environments in Ruby Valley, Nevada

Palynological data from sediment cores from the Ruby Marshes provide a record of environmental and climatic changes over the last 40,000 yr. The modern marsh waters are fresh, but no deeper than ???3 m. A shallow saline lake occupied this basin during the middle Wisconsin, followed by fresh and perhaps deep waters by 18,000 to 15,000 yr B.P. No sediments were recovered for the period between 15,000 and 11,000 yr B.P., possibly due to lake desiccation. By 10,800 yr B.P. a fresh-water lake was again present, and deeper-than-modern conditions lasted until 6800 yr B.P. The middle Holocene was characterized by very shallow water, and perhaps complete desiccation. The marsh system deepened after 4700 yr B.P., and fresh-water conditions persisted until modern times. Vegetation changes in Ruby Valley were more gradual than those seen in the paleolimno-logical record. Sagebrush steppe was more widespread than at present through the late Pleistocene and early Holocene, giving way somewhat to expanded shadscale vegetation between 8500 and 6800 yr B.P. Shadscale steppe contracted by 4000 yr B.P., but had greater than modern coverage until 1000 to 500 yr ago. Pinyon-juniper woodland was established in the southern Ruby Mountains by 4700 yr B.P. ?? 1992.

Quaternary Research↗

Multireaction equilibrium geothermometry: A sensitivity analysis using data from the Lower Geyser Basin, Yellowstone National Park, USA

A multireaction chemical equilibria geothermometry (MEG) model applicable to high-temperature geothermal systems has been developed over the past three decades. Given sufficient data, this model provides more constraint on calculated reservoir temperatures than classical chemical geothermometers that are based on either the concentration of silica (SiO 2 ), or the ratios of cation concentrations. A set of 23 chemical analyses from Ojo Caliente Spring and 22 analyses from other thermal features in the Lower Geyser Basin of Yellowstone National Park are used to examine the sensitivity of calculated reservoir temperatures using the GeoT MEG code (Spycher et al. 2013, 2014) to quantify the effects of solute concentrations, degassing, and mineral assemblages on calculated reservoir temperatures. Results of our analysis demonstrate that the MEG model can resolve reservoir temperatures within approximately ±15°C, and that natural variation in fluid compositions represents a greater source of variance in calculated reservoir temperatures than variations caused by analytical uncertainty (assuming ~5% for major elements). The analysis also suggests that MEG calculations are particularly sensitive to variations in silica concentration, the concentrations of the redox species Fe(II) and H 2 S, and that the parameters defining steam separation and CO 2 degassing from the liquid may be adequately determined by numerical optimization. Results from this study can provide guidance for future applications of MEG models, and thus provide more reliable information on geothermal energy resources during exploration.

Idaho, Montana, Wyoming↗

Geomorphic control of landscape carbon accumulation

We use the CREEP process-response model to simulate soil organic carbon accumulation in an undisturbed prairie site in Iowa. Our primary objectives are to identify spatial patterns of carbon accumulation, and explore the effect of erosion on basin-scale C accumulation. Our results point to two general findings. First, redistribution of soil carbon by erosion results in a net increase in basin-wide carbon storage relative to a noneroding environment. Landscape-average mean residence times are increased in an eroding landscape owing to the burial/preservation of otherwise labile C. Second, field observations taken along a slope transect may overlook significant intraslope variations in carbon accumulation. Spatial patterns of modeled deep C accumulation are complex. While surface carbon with its relatively short equilibration time is predictable from surface properties, deep carbon is strongly influenced by the landscape's geomorphic and climatic history, resulting in wide spatial variability. Convergence and divergence associated with upland swales and interfluves result in bimodal carbon distributions in upper and mid slopes; variability in carbon storage within modeled mid slopes was as high as simulated differences between erosional shoulders and depositional valley bottoms. The bimodality of mid-slope C variability in the model suggests that a three-dimensional sampling strategy is preferable over the traditional two-dimensional analog or "catena" approach. Copyright 2006 by the American Geophysical Union.

Journal of Geophysical Research G: Biogeosciences↗

Cost-effective management alternatives for Snake river chinook salmon: A biological-economic synthesis

The mandate to increase endangered salmon populations in the Columbia River Basin of North America has created a complex, controversial resource-management issue. We constructed an integrated assessment model as a tool for analyzing biological-economic trade-offs in recovery of Snake River spring- and summer-run chinook salmon (Oncorhynchus tshawytscha). We merged 3 frameworks: a salmon-passage model to predict migration and survival of smolts; an age-structured matrix model to predict long-term population growth rates of salmon stocks; and a cost-effectiveness analysis to determine a set of least-cost management alternatives for achieving particular population growth rates. We assessed 6 individual salmon-management measures and 76 management alternatives composed of one or more measures. To reflect uncertainty, results were derived for different assumptions of effectiveness of smolt transport around dams. Removal of an estuarine predator, the Caspian Tern (Sterna caspia), was cost-effective and generally increased long-term population growth rates regardless of transport effectiveness. Elimination of adult salmon harvest had a similar effect over a range of its cost estimates. The specific management alternatives in the cost-effective set depended on assumptions about transport effectiveness. On the basis of recent estimates of smolt transport effectiveness, alternatives that discontinued transportation or breached dams were prevalent in the cost-effective set, whereas alternatives that maximized transportation dominated if transport effectiveness was relatively high. More generally, the analysis eliminated 80-90% of management alternatives from the cost-effective set. Application of our results to salmon management is limited by data availability and model assumptions, but these limitations can help guide research that addresses critical uncertainties and information. Our results thus demonstrate that linking biology and economics through integrated models can provide valuable tools for science-based policy and management.

Conservation Biology↗

The source, fate, and transport of arsenic in the Yellowstone hydrothermal system - An overview

The Yellowstone Plateau Volcanic Field (YPVF) contains >10,000 thermal features including hot springs, pools, geysers, mud pots, and fumaroles with diverse chemical compositions. Arsenic (As) concentrations in YPVF thermal waters typically range from 0.005 to 4 mg/L, but an As concentration of 17 mg/L has been reported. Arsenic data from thermal springs, outflow drainages, rivers, and from volcanic rocks and silica sinter were used to identify the sources, characterize geochemical and microbial processes affecting As, and quantify As fluvial transport. Arsenic in YPVF thermal waters is mainly derived from high temperature leaching of rhyolites. Arsenic concentrations in thermal waters primarily depend on water type, which is controlled by boiling, evaporation, mixing, and mineral precipitation and dissolution. Springs with low As concentrations include acid-SO 4 (0.1 ± 0.1 mg/L), NH 4 -SO 4 rich (0.003 ± 0.007 mg/L), and dilute thermal waters (0.1 ± 0.1 mg/L); travertine-forming waters have moderate As concentrations (0.4 ± 0.2 mg/L); and neutral- Cl waters (1.2 ± 0.8 mg/L) common in the western portion of the Yellowstone Caldera and Cl-rich waters (1.9 ± 1.2 mg/L) primarily from Basins near the Caldera boundary have elevated As concentrations. Reduced As species (arsenite and thiolated-As species) are most prevalent near the orifice of hot springs, and then As rapidly oxidizes to arsenate along drainages. Previously published cultivation-based studies and metagenomic data from microbial communities inhabiting a variety of hot springs indicate a widespread distribution of arsenite oxidation and arsenate reduction capabilities among the hot springs. Widespread use and transformation of As by thermophilic microorganisms promotes more soluble and toxic forms. Most of the water discharged from thermal springs eventually ends up in a nearby river where As remains soluble and exhibits little attenuation during downstream transport. Since 2010, 183 ± 10 metric tons/year of As were transported from Yellowstone National Park (YNP) via rivers. The discharge from YPVF thermal features impairs river water quality whereby As concentrations exceed 10 μg/L for many rivers reaches within and downstream from YNP.

Idaho, Montana, Wyoming↗

Structural impact of hurricane Andrew on the forested wetlands of the Atchaflaya Basin in South Louisiana

On August 26, 1992, Hurricane Andrew hit the Louisiana coast and traversed a large portion of the lower Atchafalaya Basin, bounding the largest remaining tract of cypress-tupelo and bottomland hardwood swamp in the United States. Permanent field sites were established following the hurricane to assess the extent of forest damage and to monitor the rate and process of forest recovery. Bottomland hardwood forests had significantly greater damage and mortality than did cypress-tupelo communities. Canopy trees suffered the greatest direct damage, particularly in sites within the storm's eyewall and right quadrant. The type and extent of damage (windthrow, branch loss, and defoliation) generally decreased as distance from the storm path increased. Azimuths of downed trees were strongly correlated with predicted wind vectors derived from a hurricane simulation model of Andrew. Species differences were readily apparent, indicating a high degree of tolerance to windthrow by baldcypress and water tupelo, and intolerance by many common hardwood species. Bottomland hardwood forests are particularly susceptible to catastrophic disturbance by hurricanes such as Andrew, which have significant impact on forest structure and dynamics.

Louisiana↗

Lithodiversity and its spatial association with metallic mineral sites, Great Basin of Nevada

Geographical information system (GIS) techniques were used to investigate the spatial association between metallic mineral sites and lithodiversity in Nevada. Mineral site data sets include various size and type subsets of about 5,500 metal-bearing occurrences and deposits. Lithodiversity was calculated by counting the number of unique geological map units within four sizes of square-shaped sample neighborhoods (2.5-by-2.5, 5-by-5, 10-by-10, and 20-by-20 km) on three different scales of geological maps (national, 1:2,500,000; state, 1:500,000; county, 1:250,000). The spatial association between mineral sites and lithodiversity was observed to increase with increasing lithodiversity. This relationship is consistent for (1) both basin-range and range-only regions, (2) four sizes of sample neighborhoods, (3) various mineral site subsets, (4) the three scales of geological maps, and (5) areas not covered by large-scale maps. A map scale of 1:500,000 and lithodiversity sampling neighborhood of 5-by-5 km was determined to best describe the association. Positive associations occurred for areas having >3 geological map units per neighborhood, with the strongest observed at approximately >7 units. Areas in Nevada with more than three geological map units per 5-by-5 km neighborhood contain more mineral sites than would be expected resulting from chance. High lithodiversity likely reflects the occurrence of complex structural, stratigraphic, and intrusive relationships that are thought to control, focus, localize, or expose mineralization. The application of lithodiversity measurements to areas that are not well explored may help delineate regional-scale exploration targets and provide GIS-supported mineral resource assessment and exploration activity another method that makes use of widely available geological map data.

Nevada↗

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