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Environmental implications of element emissions from phosphate-processing operations in southeastern Idaho

In order to assess the contribution to plants and soils of certain elements emitted by phosphate processing, we sampled sagebrush, grasses, and A- and C-horizon soils along upwind and downwind transects at Pocatello and Soda Springs, Idaho. Analyses for 70 elements in plants showed that, statistically, the concentration of 7 environmentally important elements, cadmium, chromium, fluorine, selenium, uranium, vanadium, and zinc, were related to emissions from phosphate-processing operations. Two additional elements, lithium and nickel, show probable relationships. The literature on the effects of these elements on plant and animal health is briefly surveyed. Relations between element content in plants and distance from the phosphate-processing operations were stronger at Soda Springs than at Pocatello and, in general, stronger in sagebrush than in the grasses. Analyses for 58 elements in soils showed that, statistically, beryllium, fluorine, iron, lead, lithium, potassium, rubidium, thorium, and zinc were related to emissions only at Pocatello and only in the A horizon. Moreover, six additional elements, copper, mercury, nickel, titanium, uranium, and vanadium, probably are similarly related along the same transect. The approximate amounts of elements added to the soils by the emissions are estimated. In C-horizon soils, no statistically significant relations were observed between element concentrations and distance from the processing sites. At Soda Springs, the nonuniformity of soils at the sampling locations may have obscured the relationship between soil-element content and emissions from phosphate processing.

Professional Paper

The Effect of Selected Cleaning Techniques on Berkshire Lee Marble: A Scientific Study at Philadelphia City Hall

This report describes a scientific investigation of the effects of eight different cleaning techniques on the Berkshire Lee marble component of the facade of the East Center Pavilion at Philadelphia City Hall; the study was commissioned by the city of Philadelphia. The eight cleaning techniques evaluated in this study were power wash (proprietary gel detergent followed by water rinse under pressure), misting (treatment with potable, nebulized water for 24-36 hours), gommage (proprietary Thomann-Hanry low-pressure, air-driven, small-particle, dry abrasion), combination (gommage followed by misting), Armax (sodium bicarbonate delivered under pressure in a water wash), JOS (dolomite powder delivered in a low-pressure, rotary-vortex water wash), laser (thermal ablation), and dry ice (powdered-dry-ice abrasion delivered under pressure). In our study approximately 160 cores were removed from the building for laboratory analysis. We developed a computer program to analyze scanning-electron-micrograph images for the microscale surface roughness and other morphologic parameters of the stone surface, including the near-surface fracture density of the stone. An analysis of more than 1,100 samples cut from the cores provided a statistical basis for crafting the essential elements of a reduced-form, mixed-kinetics conceptual model that represents the deterioration of calcareous stone in terms of self-organized soiling and erosion patterns. This model, in turn, provided a basis for identifying the variables that are affected by the cleaning techniques and for evaluating the extent to which such variables influence the stability of the stone. The model recognizes three classes of variables that may influence the soiling load on the stone, including such exogenous environmental variables as airborne moisture, pollutant concentrations, and local aerodynamics, and such endogenous stone variables as surface chemistry and microstructure (fracturing, roughness, and so on). This study showed that morphologic variables on the mesoscale to macroscale are not generally affected by the choice of a cleaning technique. The long-term soiling pattern on the building is independent of the cleaning technique applied. This study also showed that soluble salts do not play a significant role in the deterioration of Berkshire Lee marble. Although salts were evident in cracks and fissures of the heavily soiled stone, such salts did not penetrate the surface to a depth of more than a few hundred micrometers. The criteria used to differentiate the cleaning techniques were ultimately based on the ability of each technique to remove soiling without altering the texture of the stone surface. This study identified both the gommage and JOS techniques as appropriate for cleaning ashlar surfaces and the combination technique as appropriate for cleaning highly carved surfaces at the entablatures, cornices, and column capitals.

Professional Paper

Proceedings of the U.S. Geological Survey Eighth Biennial Geographic Information Science Workshop and first The National Map Users Conference, Denver, Colorado, May 10-13, 2011

The U.S. Geological Survey (USGS) is sponsoring the first The National Map Users Conference in conjunction with the eighth biennial Geographic Information Science (GIS) Workshop on May 10-13, 2011, in Lakewood, Colorado. The GIS Workshop will be held at the USGS National Training Center, located on the Denver Federal Center, Lakewood, Colorado, May 10-11. The National Map Users Conference will be held directly after the GIS Workshop at the Denver Marriott West, a convention hotel in the Lakewood, Colorado area, May 12-13. The National Map is designed to serve the Nation by providing geographic data and knowledge for government, industry, and public uses. The goal of The National Map Users Conference is to enhance communications and collaboration among the communities of users of and contributors to The National Map, including USGS, Department of the Interior, and other government GIS specialists and scientists, as well as the broader geospatial community. The USGS National Geospatial Program intends the conference to serve as a forum to engage users and more fully discover and meet their needs for the products and services of The National Map. The goal of the GIS Workshop is to promote advancement of GIS and related technologies and concepts as well as the sharing of GIS knowledge within the USGS GIS community. This collaborative opportunity for multi-disciplinary GIS and associated professionals will allow attendees to present and discuss a wide variety of geospatial-related topics. The Users Conference and Workshop collaboration will bring together scientists, managers, and data users who, through presentations, posters, seminars, workshops, and informal gatherings, will share accomplishments and progress on a variety of geospatial topics. During this joint event, attendees will have the opportunity to present or demonstrate their work; to develop their knowledge by attending hands-on workshops, seminars, and presentations given by professionals from USGS and other Federal Agencies, GIS related companies, and academia; and to network with other professionals to develop collaborative opportunities. Specific conference topics include scientific and modeling applications using The National Map, opportunities for partnerships, and advances in geospatial technologies. The first part of the week will be the GIS Workshop, offered as a pre-conference seminar. It will focus on hands-on GIS training and seminars concerning current topics of geospatial interest. The focus of the USGS GIS Workshop is to showcase specific techniques and concepts for using GIS in support of science. The presentations will be educational and not a marketing endeavor. To promote awareness of and interaction with selected USGS corporate and local science center data products, as well as promoting collaboration, a “GIS Olympics” event will be held Tuesday evening during the GIS Workshop. The second part of the week will feature interactive briefings and discussions on issues and opportunities of The National Map. The focus of the Users Conference will be on the role of The National Map in supporting science initiatives, emergency response, land and wildlife management, and other activities. All presentations at the Users Conference include use or innovations related to a The National Map data theme or application. On Wednesday evening, a poster session is being held as a combined event for all attendees and as a juncture between the events. On Thursday evening, the Henry Gannett Award will be presented. Additionally, poster awards will be presented. Several prominent speakers are featured at plenary sessions at The National Map Users Conference, including Deanna A. Archuleta, Deputy Assistant Secretary for Water and Science, Department of the Interior; Dr. Barbara P. Buttenfield, Professor of Geography at the University of Colorado in Boulder; best-selling author Frederick Reuss; and Dr. Joel Scheraga, Senior Advisor for Climate Adaptation, U.S. Environmental Protection Agency. Additionally, panel discussions have attracted participation from notable experts from government, academia, and the private sector. This Proceedings volume will serve as an activity reference for workshop attendees, as well as an archive of technical abstracts presented at the workshop. Author, co-author, and presenter names, affiliations, and contact information are listed with presentation titles with the abstracts. Some hands-on sessions are offered twice; in these instances, abstracts submitted for publication are presented in the proceedings on both days on which they are offered.

Scientific Investigations Report

Southern Rockies Ecoregion: Chapter 8 in Status and trends of land change in the Western United States--1973 to 2000

The Southern Rockies Ecoregion is a high-elevation mountainous ecoregion that covers approximately 138,854 km2 (53,612 mi2), including much of central Colorado and parts of southern Wyoming and northern New Mexico (fig. 1) (Omernik, 1987; U.S. Environmental Protection Agency, 1997). It abuts six other ecoregions: the Wyoming Basin and Colorado Plateaus Ecoregions on the north and west, the Arizona/New Mexico Plateau Ecoregion on the south, and the Northwestern Great Plains, Western High Plains, and Southwestern Tablelands Ecoregions on the east (fig. 1). The ecoregion receives most of its annual precipitation (25–100 cm) as snowfall, which provides a significant amount of high-elevation snowpack that is an important water source for surrounding ecoregions. The Southern Rockies Ecoregion has a steep elevation gradient from low foothills to high peaks, with several hundred summits higher than 3,660 m (12,000 ft). As a southern extension of the larger RockyMountain system, it is composed primarily of seven main north-south trending mountain ranges that are separated by four large intermontane basins. A fifth basin, the San Luis Valley, is outside the ecoregion, forming a northern finger of the Arizona/New Mexico Plateau Ecoregion that lies mostly to the south. To the east, late Tertiary sand and gravel deposits that were eroded from the relatively young Rocky Mountains were carried eastward by streams, forming the nearby Western High Plains Ecoregion and its underlying Ogallala aquifer.

Colorado;New Mexico;Wyoming

Estimated infiltration, percolation, and recharge rates at the Rillito Creek focused recharge investigation site, Pima County, Arizona

A large fraction of ground water stored in the alluvial aquifers in the Southwest is recharged by water that percolates through ephemeral stream-channel deposits. The amount of water currently recharging many of these aquifers is insufficient to meet current and future demands. Improving the understanding of streambed infiltration and the subsequent redistribution of water within the unsaturated zone is fundamental to quantifying and forming an accurate description of streambed recharge. In addition, improved estimates of recharge from ephemeral-stream channels will reduce uncertainties in water-budget components used in current ground-water models. This chapter presents a summary of findings related to a focused recharge investigation along Rillito Creek in Tucson, Arizona. A variety of approaches used to estimate infiltration, percolation, and recharge fluxes are presented that provide a wide range of temporal- and spatial-scale measurements of recharge beneath Rillito Creek. The approaches discussed include analyses of (1) cores and cuttings for hydraulic and textural properties, (2) environmental tracers from the water extracted from the cores and cuttings, (3) seepage measurements made during sustained streamflow, (4) heat as a tracer and numerical simulations of the movement of heat through the streambed sediments, (5) water-content variations, (6) water-level responses to streamflow in piezometers within the stream channel, and (7) gravity changes in response to recharge events. Hydraulic properties of the materials underlying Rillito Creek were used to estimate long-term potential recharge rates. Seepage measurements and analyses of temperature and water content were used to estimate infiltration rates, and environmental tracers were used to estimate percolation rates through the thick unsaturated zone. The presence or lack of tritium in the water was used to determine whether or not water in the unsaturated zone infiltrated within the past 40 years. Analysis of water-level and temporal-gravity data were used to estimate recharge volumes. Data presented in this chapter were collected from 1999 though 2002. Precipitation and streamflow during this period were less than the long-term average; however, two periods of significant streamflow resulted in recharge—one in the summer of 1999 and the other in the fall/winter of 2000. Flux estimates of infiltration and recharge vary from less than 0.1 to 1.0 cubic meter per second per kilometer of streamflow. Recharge-flux estimates are larger than infiltration estimates. Larger recharge fluxes than infiltration fluxes are explained by the scale of measurements. Methods used to estimate recharge rates incorporate the largest volumetric and temporal scales and are likely to have fluxes from other nearby sources, such as unmeasured tributaries, whereas the methods used to estimate infiltration incorporate the smallest scales, reflecting infiltration rates at individual measurement sites.

Arizona

Graphite

Graphite is a form of pure carbon that normally occurs as black crystal flakes and masses. It has important properties, such as chemical inertness, thermal stability, high electrical conductivity, and lubricity (slipperiness) that make it suitable for many industrial applications, including electronics, lubricants, metallurgy, and steelmaking. For some of these uses, no suitable substitutes are available. Steelmaking and refractory applications in metallurgy use the largest amount of produced graphite; however, emerging technology uses in large-scale fuel cell, battery, and lightweight high-strength composite applications could substantially increase world demand for graphite. Graphite ores are classified as “amorphous” (microcrystalline), and “crystalline” (“flake” or “lump or chip”) based on the ore’s crystallinity, grain-size, and morphology. All graphite deposits mined today formed from metamorphism of carbonaceous sedimentary rocks, and the ore type is determined by the geologic setting. Thermally metamorphosed coal is the usual source of amorphous graphite. Disseminated crystalline flake graphite is mined from carbonaceous metamorphic rocks, and lump or chip graphite is mined from veins in high-grade metamorphic regions. Because graphite is chemically inert and nontoxic, the main environmental concerns associated with graphite mining are inhalation of fine-grained dusts, including silicate and sulfide mineral particles, and hydrocarbon vapors produced during the mining and processing of ore. Synthetic graphite is manufactured from hydrocarbon sources using high-temperature heat treatment, and it is more expensive to produce than natural graphite. Production of natural graphite is dominated by China, India, and Brazil, which export graphite worldwide. China provides approximately 67 percent of worldwide output of natural graphite, and, as the dominant exporter, has the ability to set world prices. China has significant graphite reserves, and China’s graphite production is expected to increase, although rising labor costs and some mine production problems are developing. China is expected to continue to be the dominant exporter for the near future. Mexico and Canada export graphite mainly to the United States, which has not had domestic production of natural graphite since the 1950s. Most graphite deposits in the United States are too small, low-grade, or remote to be of commercial value in the near future, and the likelihood of discovering larger, higher-grade, or favorably located domestic deposits is unlikely. The United States is a major producer of synthetic graphite.

Professional Paper

Land use and land cover information and air-quality planning

The land use and land cover information developed by the U.S. Geological Survey in the Central Atlantic Regional Ecological Test Site project has been proven useful when used in an improved technique for estimating emissions, diffusion, and impact patterns of sulfur dioxide (S02) and particulate matter. Implementation of plans to control air quality requires land use and land cover information, which, until this time, has been inadequate. The land use and land cover data were used in updating information on the sources of point and area emissions of S02 and particulate matter affecting the Norfolk-Portsmouth area of Virginia for the 1971-72 winter (Dec.-Jan.-Feb.) and the annual 1972 period, and for a future annual period-1985. This emission information is used as input to the Air Quality Display Model of the Environmental Protection Agency to obtain diffusion and impact patterns for the three periods previously mentioned. The results are: (1) During the 1971-72 winter, estimated S02 amounts over an area with southwest-northeast axis in the central section of Norfolk exceeded both primary and secondary levels, (2) future annual levels of S02, estimated by anticipated residential development and point-source changes, are not expected to cause serious deterioration of the region's present air quality, and (3) for the 1971-72 winter, and annual 1972, period the diffusion results showed that both primary and secondary standards for particulate matter are regularly exceeded in central Norfolk and Portsmouth. In addition, on the basis of current control programs, the 1985 levels of particulate matter are expected to exceed the presently established secondary air-quality standards through central Norfolk and Portsmouth and in certain areas of Virginia Beach. Land use and land cover information can be used to estimate emissions for inputs to diffusion models and to interpret the implications of diffusion patterns for: (1) Implementing various control strategies, (2) selecting sites of air sampling stations, and (3) predicting the effects that proposed changes in land use and land cover might have on emission patterns and air quality.

Professional Paper

Northern Rockies Ecoregion: Chapter 7 in Status and trends of land change in the Western United States--1973 to 2000

The Northern Rockies Ecoregion (Omernik, 1987; U.S. Environmental Protection Agency, 1997) covers approximately 162,746 km 2 (63,200 mi 2 ), primarily in Idaho but also including areas in western Montana and northeastern Washington (fig. 1). Canada forms the northern border of the ecoregion. To the west it is bordered by the Columbia Plateau and Blue Mountains Ecoregions, to the south by the Snake River Basin Ecoregion, and to the east by the Canadian Rockies, Middle Rockies, Northwestern Great Plains, and Northwestern Glaciated Plains Ecoregions; also to the east, the Northern Rockies Ecoregion interfingers with the Montana Valley and Foothill Prairies Ecoregion, each enclosing some isolated areas of the other (fig. 1). The ecoregion is composed of a series of high, rugged mountain ranges, mostly oriented northwest-southeast, with intermontane valleys between them (fig. 2). The entire ecoregion was glaciated during the Pleistocene (1,800,000 to 11,400 years ago), and today numerous large lakes occupy basins formed by glacial action (Omernik, 1987; Habeck and Mutch, 1973). Streams draining these mountain ranges provide a water source for many western cities and towns (fig. 3). The Continental Divide, located at the highest elevations along the northern Rocky Mountains, separates rivers that flow westward into the Columbia River watershed from those that flow eastward into the Missouri River watershed.

Idaho;Montana;Washington

Water availability and use pilot: A multiscale assessment in the U.S. Great Lakes Basin

Beginning in 2005, water availability and use were assessed for the U.S. part of the Great Lakes Basin through the Great Lakes Basin Pilot of a U.S. Geological Survey (USGS) national assessment of water availability and use. The goals of a national assessment of water availability and use are to clarify our understanding of water-availability status and trends and improve our ability to forecast the balance between water supply and demand for future economic and environmental uses. This report outlines possible approaches for full-scale implementation of such an assessment. As such, the focus of this study was on collecting, compiling, and analyzing a wide variety of data to define the storage and dynamics of water resources and quantify the human demands on water in the Great Lakes region. The study focused on multiple spatial and temporal scales to highlight not only the abundant regional availability of water but also the potential for local shortages or conflicts over water. Regional studies provided a framework for understanding water resources in the basin. Subregional studies directed attention to varied aspects of the water-resources system that would have been difficult to assess for the whole region because of either data limitations or time limitations for the project. The study of local issues and concerns was motivated by regional discussions that led to recent legislative action between the Great Lakes States and regional cooperation with the Canadian Great Lakes Provinces. The multiscale nature of the study findings challenges water-resource managers and the public to think about regional water resources in an integrated way and to understand how future changes to the system-driven by human uses, climate variability, or land-use change-may be accommodated by informed water-resources management.

Great Lakes Basin

Coast Range Ecoregion: Chapter 1 in Status and trends of land change in the Western United States--1973 to 2000

The Coast Range Ecoregion, which covers approximately 57,338 km 2 (22,138 mi 2 ), is a thin, linear ecoregion along the Pacific Coast, stretching roughly 1,300 km from the Olympic Peninsula, in northwest Washington, to an area south of San Francisco, California (fig. 1) (Omernik, 1987; U.S. Environmental Protection Agency, 1997). It is bounded on the east by the Puget Lowland, the Willamette Valley, the Klamath Mountains, and the Southern and Central California Chaparral and Oak Woodlands Ecoregions. Almost the entire Coast Range Ecoregion lies within 100 km of the coast. Topography is highly variable, with coastal mountain ranges and valleys ranging from sea level to over 1,000 m in elevation (fig. 2). A maritime climate, along with high topographic relief, results in substantial, but regionally variable, amounts of rainfall, ranging from 130 cm to more than 350 cm per year. The favorable climate of the Coast Range Ecoregion has supported forests of Sitka spruce ( Picea sitchensis ) along its northern coast and coast redwoods ( Sequoia sempervirens ) along its southern coast, as well as Douglas-fir ( Pseudotsuga menziesii ), western red cedar ( Thuja plicata ), and western hemlock ( Tsuga heterophylla ) inland (Omernik, 1987). Today, however, much of the forest is heavily managed for logging (fig. 3), although the ecoregion still supports some of the largest remaining areas of old-growth forest in the Pacific Northwest. Agriculture is a minor component of the landscape, present locally in flat lands and valleys near the coast. Urban development is minimal; Eureka, California, is the only urban center in the ecoregion, with a population of over 26,000 (U.S. Census Bureau, 2000).

California;Oregon;Washington

Streamflow, infiltration, and recharge in Arroyo Hondo, New Mexico

Infiltration events in channels that flow only sporadically produce focused recharge to the Tesuque aquifer in the Española Basin. The current study examined the quantity and timing of streamflow and associated infiltration in Arroyo Hondo, an unregulated mountain-front stream that enters the basin from the western slope of the Sangre de Cristo Mountains. Traditional methods of stream gaging were combined with environmental-tracer based methods to provide the estimates. The study was conducted during a three-year period, October 1999–October 2002. The period was characterized by generally low precipitation and runoff. Summer monsoonal rains produced four brief periods of streamflow in water year 2000, only three of which extended beyond the mountain front, and negligible runoff in subsequent years. The largest peak flow during summer monsoon events was 0.59 cubic meters per second. Snowmelt was the main contributor to annual streamflow. Snowmelt produced more cumulative flow downstream from the mountain front during the study period than summer monsoonal rains. The presence or absence of streamflow downstream of the mountain front was determined by interpretation of streambed thermographs. Infiltration rates were estimated by numerical modeling of transient vertical streambed temperature profiles. Snowmelt extended throughout the instrumented reach during the spring of 2001. Flow was recorded at a station two kilometers downstream from the mountain front for six consecutive days in March. Inverse modeling of this event indicated an average infiltration rate of 1.4 meters per day at this location. For the entire study reach, the estimated total annual volume of infiltration ranged from 17,100 to 246,000 m 3 during water years 2000 and 2001. During water year 2002, due to severe drought, streamflow and streambed infiltration in the study reach were both zero.

New Mexico

Platinum-group elements

The platinum-group elements (PGEs)—platinum, palladium, rhodium, ruthenium, iridium, and osmium—are metals that have similar physical and chemical properties and tend to occur together in nature. PGEs are indispensable to many industrial applications but are mined in only a few places. The availability and accessibility of PGEs could be disrupted by economic, environmental, political, and social events. The United States net import reliance as a percentage of apparent consumption is about 90 percent. PGEs have many industrial applications. They are used in catalytic converters to reduce carbon monoxide, hydrocarbon, and nitrous oxide emissions in automobile exhaust. The chemical industry requires platinum or platinum-rhodium alloys to manufacture nitric oxide, which is the raw material used to manufacture explosives, fertilizers, and nitric acid. In the petrochemical industry, platinum-supported catalysts are needed to refine crude oil and to produce aromatic compounds and high-octane gasoline. Alloys of PGEs are exceptionally hard and durable, making them the best known coating for industrial crucibles used in the manufacture of chemicals and synthetic materials. PGEs are used by the glass manufacturing industry in the production of fiberglass and flat-panel and liquid crystal displays. In the electronics industry, PGEs are used in computer hard disks, hybridized integrated circuits, and multilayer ceramic capacitors. Aside from their industrial applications, PGEs are used in such other fields as health, consumer goods, and finance. Platinum, for example, is used in medical implants, such as pacemakers, and PGEs are used in cancer-fighting drugs. Platinum alloys are an ideal choice for jewelry because of their white color, strength, and resistance to tarnish. Platinum, palladium, and rhodium in the form of coins and bars are also used as investment commodities, and various financial instruments based on the value of these PGEs are traded on major exchanges. PGEs are among the rarest metals; Earth’s upper crust contains only about 0.0005 part per million (ppm) platinum. Today, the average grade of PGEs in ores that are mined primarily for their PGE concentrations varies from 5 to 15 ppm, although the concentration of PGEs in hand-picked ore specimens may range from tens to hundreds of parts per million. More than 100 different minerals have one of the PGEs as an essential component. PGE minerals occur as native metals. They also occur as compounds with other transition metals (copper, iron, mercury, nickel, and silver), post-transition metals (bismuth, lead, and tin), metalloids (antimony, arsenic, and tellurium), and nonmetals (selenium and sulfur). From 1900 to 2011, approximately 14,200 metric tons of PGEs was produced, and roughly 95 percent of that production (13,500 metric tons) took place between 1960 and 2011. The breakdown of production by country shows that, since 1900, about 90 percent of the production came from South Africa and Russia. The secondary supply of platinum, palladium, and rhodium is obtained through the recycling of catalytic converters from end-of-life vehicles, jewelry, and electronic equipment. Recycled platinum, palladium, and rhodium provide a significant proportion of the world’s total supply; these secondary sources are sufficient to close the gap between world mine production and consumption. Exploration and mining companies report resources of about 104,000 metric tons of PGEs (including minor amounts of gold) in mineral deposits around the world that could be developed. For PGEs, almost all the reported production and identified resources are associated with deposits in three geologic features—the Bushveld Complex, which is a layered mafic-to-ultramafic intrusion in South Africa; the Great Dyke, which is a layered mafic-to-ultramafic intrusion in Zimbabwe; and sill-like intrusions associated with flood basalts in the Noril’sk-Talnakh area of Russia. The metallic forms of PGEs are generally considered to be inert. PGEs pose a risk to human health only in cases where individuals are occupationally exposed to synthetic PGE compounds, especially workers in precious-metal refineries. In the natural environment, background PGE concentrations are low in water, sediment, soil, and plants. Anthropogenic sources of PGEs in the environment include catalytic converters used in modern automobiles, platinum-based chemotherapy drugs, and smelter emissions. The abundance of sulfide minerals defines the environmental and geologic characteristics of PGE-enriched magmatic sulfide deposits; those deposits with the highest amount of sulfide minerals could have the highest environmental impact. Acid rock drainage from reef-type and contact-type deposits is unlikely because the ores and their host rocks contain low proportions of sulfide minerals. For some conduit-type orebodies with massive ores, mineral-processing techniques separate and produce concentrates of copper-, iron-, and nickel-bearing sulfide minerals; those with copper and nickel are processed to extract metal, but the iron-sulfide minerals, mainly pyrrhotite, are discarded as waste. This results in waste material with a high acid-generating potential. The most significant primary source of PGEs in the United States is a deposit in the Stillwater Complex, which is a layered igneous intrusion in Montana. Approximately 305 metric tons of platinum and palladium have been mined from the Stillwater Complex deposit since 1986. Exploration and development drilling indicate that another 2,200 metric tons are present. Mining has progressed to depths of 1,800 meters below the surface, but the bottom of the ore deposit has not been reached; geologic estimates suggest that another 1,000 to 6,200 metric tons of PGEs could be present at depth. In the future, PGEs may be mined from deposits found near the base of the Duluth Complex, which is a group of igneous intrusions in Minnesota.

Professional Paper

Annual Nutrient Loadings, Primary Productivity, and Trophic State of Lake Koocanusa, Montana and British Columbia, 1972-80

Limnological data collected at Lake Koocanusa were used to investigate the relationship of nutrient loadings, primary productivity, and trophic state of the reservoir during 1972-80. The reservoir, on the Kootenai River, was impounded by Libby Dam on March 21, 1972. Manipulation of the 7.16-cubic-kilometer reservoir for flood control, its primary function, created large fluctuations in reservoir volume and produced annual lake-filling times that ranged from 0.14 to 0.66 year. Loadings of nitrogen and phosphorus prior to and following impoundment of Lake Koocanusa were found to be large enough to predict eutrophic conditions. Beginning in 1976, total phosphorus loadings, but not total nitrogen loadings, were substantially reduced following improvements in waste-water treatment at a fertilizer plant located upstream from the reservoir. The closure of Libby Dam substantially reduced loadings of nitrogen and phosphorus downstream from Lake Koocanusa. On the average, the reservoir retained 63 percent of its influent loading of total phosphorus and 25 percent of its influent loading of total nitrogen. Daily areal and volumetric primary productivity varied widely in each year at four sampled limnological stations. During the 9 years studied, daily areal primary productivity, in milligrams of carbon fixed per square meter, ranged from 0.4 to 420.0; the mean of the 313 sampled days was 128.5. Annual areal primary productivity ranged from 23.2 to 38.5 grams of carbon fixed per square meter and thereby categorized Lake Koocanusa as oligotrophic. The relationship of annual areal primary productivity and 12 selected environmental variables was determined by multiple regression analysis. One of the models that was derived used two variables-annual euphotic zone depth and annual areal phosphorus loading-and accounted for 62.0 percent of the variation in annual areal primary productivity. The distribution of chlorophyll a within the water column indicated that, on the average, more than one-half of the phytoplankton in the reservoir was beneath the euphotic zone. These results support the hypothesis that the reservoir's weak thermal structure had allowed circulation of phytoplankton out of the euphotic zone. The trophic state of Lake Koocanusa was categorized as eutrophic when based on the relationship of the nutrient loadings and the reservoir's ratio of mean depth to hydraulic-residence time. This result conflicted with the oligotrophic ranking the reservoir received based on its areal primary productivity. The discrepancy in trophic state was attributed mainly to the failure of nutrient loading models to adequately account for physical processes within reservoirs. Part of the nutrient loading that entered Lake Koocanusa was unavailable to phytoplankton because the nutrients were carried beneath the euphotic zone by large volumes of interflow and underflow. Another part of the nutrient loading was adsorbed to suspended sediment and removed from the water column. Thus, phytoplankton primary productivity was controlled not only by nutrients, but also by other limno logical processes.

Professional Paper

Data compilation, synthesis, and calculations used for organic-carbon storage and inventory estimates for mineral soils of the Mississippi River Basin

U.S. Geological Survey investigations of environmental controls on carbon cycling in soils and sediments of the Mississippi River Basin (MRB), an area of 3.3 x 106 square kilometers (km2), have produced an assessment tool for estimating the storage and inventory of soil organic carbon (SOC) by using soil-characterization data from Federal, State, academic, and literature sources. The methodology is based on the linkage of site-specific SOC data (pedon data) to the soil-association map units of the U.S. Department of Agriculture State Soil Geographic (STATSGO) and Soil Survey Geographic (SSURGO) digital soil databases in a geographic information system. The collective pedon database assembled from individual sources presently contains 7,321 pedon records representing 2,581 soil series. SOC storage, in kilograms per square meter (kg/m2), is calculated for each pedon at standard depth intervals from 0 to 10, 10 to 20, 20 to 50, and 50 to 100 centimeters. The site-specific storage estimates are then regionalized to produce national-scale (STATSGO) and county-scale (SSURGO) maps of SOC to a specified depth. Based on this methodology, the mean SOC storage for the top meter of mineral soil in the MRB is approximately 10 kg/m2, and the total inventory is approximately 32.3 Pg (1 petagram = 109 metric tons). This inventory is from 2.5 to 3 percent of the estimated global mineral SOC pool.

Professional Paper

Canadian Rockies Ecoregion: Chapter 4 in Status and trends of land change in the Western United States--1973 to 2000

The Canadian Rockies Ecoregion covers approximately 18,494 km 2 (7,141 mi 2 ) in northwestern Montana (Omernik, 1987; U.S. Environmental Protection Agency, 1997). The east side of the ecoregion is bordered by the Montana Valley and Foothill Prairies Ecoregion, which also forms a large part of the western border of the ecoregion. In addition, the Northern Rockies Ecoregion wraps around the ecoregion to the northwest and south (fig. 1). As the name implies, the Canadian Rocky Mountains are located mostly in Canada, straddling the border between Alberta and British Columbia. However, this ecoregion only includes the part of the northern Rocky Mountains that is in the United States. This ecoregion is characterized by steep, high-elevation mountain ranges similar to most of the rest of the Rocky Mountains. Compared to the Northern Rockies Ecoregion, however, the Canadian Rockies Ecoregion reaches higher elevations and contains a greater proportion of perennial snow and ice (Omernik, 1987) (fig. 2). Over the years, this section of the Rocky Mountains has garnered many different names, including “Crown of the Continent” by George Bird Grinnell (Waldt, 2008) and “Backbone of the World” by the Blackfeet (Pikuni) Nation. Throughout the ecoregion, montane, subalpine, and alpine ecosystems have distinct flora and fauna elevation zones. Glaciers, permanent snowfields, and seasonal snowpack are found at the highest elevations. Spring and summer runoff fills lakes and tarns that form the headwaters of numerous streams and rivers, including the Columbia and Missouri Rivers that flow west and east, respectively, from the Continental Divide.

Montana

Niobium and tantalum

Niobium and tantalum are transition metals that are almost always found together in nature because they have very similar physical and chemical properties. Their properties of hardness, conductivity, and resistance to corrosion largely determine their primary uses today. The leading use of niobium (about 75 percent) is in the production of high-strength steel alloys used in pipelines, transportation infrastructure, and structural applications. Electronic capacitors are the leading use of tantalum for high-end applications, including cell phones, computer hard drives, and such implantable medical devices as pacemakers. Niobium and tantalum are considered critical and strategic metals based on the potential risks to their supply (because current production is restricted to only a few countries) and the significant effects that a restriction in supply would have on the defense, energy, high-tech industrial, and medical sectors. The average abundance of niobium and tantalum in bulk continental crust is relatively low—8.0 parts per million (ppm) niobium and 0.7 ppm tantalum. Their chemical characteristics, such as small ionic size and high electronic field strength, significantly reduce the potential for these elements to substitute for more common elements in rock-forming minerals and make niobium and tantalum essentially immobile in most aqueous solutions. Niobium and tantalum do not occur naturally as pure metals but are concentrated in a variety of relatively rare oxide and hydroxide minerals, as well as in a few rare silicate minerals. Niobium is primarily derived from the complex oxide minerals of the pyrochlore group ((Na,Ca,Ce) 2 (Nb,Ti,Ta) 2 (O,OH,F) 7 ), which are found in some alkaline granite-syenite complexes (that is, igneous rocks containing sodium- or potassium-rich minerals and little or no quartz) and carbonatites (that is, igneous rocks that are more than 50 percent composed of primary carbonate minerals, by volume). Tantalum is derived mostly from the mineral tantalite ((Fe,Mn)(Ta,Nb) 2 O 6 ), which is found as an accessory mineral in rare-metal granites and pegmatites that are also enriched in lithium and cesium (termed lithium-cesium-tantalum (LCT)-type pegmatites). Brazil and Canada are the leading nations that produce niobium mineral concentrates, but Brazil is by far the leading producer, accounting for about 90 percent of production, which comes mostly from weathered material derived from carbonatites. Brazil and Canada also have the largest identified niobium resources; additional resources, although they are less well reported, occur in Angola, Australia, China, Greenland, Malawi, Russia, and South Africa. Australia and Brazil have been the leading producers of tantalum mineral concentrates, although recently Ethiopia and Mozambique have also been significant suppliers of tantalum. Artisanal mining of columbite-tantalite (also called coltan) is practiced in many countries, particularly Burundi, the Democratic Republic of the Congo (Congo [Kinshasa]), Nigeria, Rwanda, and Uganda. Brazil has about 40 percent of the identified tantalum resources; other countries and regions with identified tantalum resources include, in decreasing order of resources, Australia, Asia, Russia and the Middle East, Africa, North America, and Europe. Identified niobium and tantalum resources in the United States are small, low grade, and difficult to recover and process, and are thus not commercially recoverable at current prices. Consequently, the United States meets its current and expected future needs for niobium and tantalum through imports of primary mineral concentrates and alloys and through recovery from foreign and domestic alloy scrap that contain the metals. Environmentally, the main issues related to niobium and tantalum mining are land disruptions, the volume of waste materials and their disposal, and the radioactivity of some tailings and waste materials that contain thorium and uranium. Because of the relative biological inertness of niobium and tantalum, human and ecological health concerns are generally minimal under most natural conditions. Demand for both niobium and tantalum is expected to increase as the world economy continues to recover from the downturn that began in 2008. Increased demand for niobium is linked to increased consumption of microalloyed steel, which is used in the manufacture of cars, buildings, ships, and refinery equipment. Demand for these steels will likely increase with continued economic development in such countries as Brazil, China, and India. In addition, increased global demand for cars, cell phones, computers, superconducting magnets, and other high-tech devices will likely spur increased demand for both niobium and tantalum. The estimated global reserves and resources of niobium and tantalum are large and appear more than sufficient to meet global demand for the foreseeable future, possibly the next 500 years. The sale of “conflict coltan” attributed to rebel forces waging a civil war in Congo (Kinshasa) has been of recent concern and has highlighted the need for a transparent and traceable global supply chain that can exclude illegal columbite-tantalite from the conventional market while discerning legitimate artisanal mine production in central Africa.

Professional Paper

Rates, trends, causes, and consequences of urban land-use change in the United States

Over the past 200 years, changes to the Nation's urban areas have been dramatic. Changes that have occurred relate both to the location of urban centers, as well as to the spatial extent of land dedicated to urban uses. Urban areas at the beginning of the 19th century were located primarily along major rivers or bodies of water, as waterways provided the most efficient means for transporting goods and people. As railroads became prominent, urban areas were able to expand or develop away from the water's edge. Geographic features such as steep slopes, wetlands, and lack of freshwater impeded settlement. In 1902, the National Reclamation Act was passed and with it came funding for the construction of water storage and transportation systems. This encouraged urban expansion in the arid west. After World War II, the Nation's urban areas continued to expand outward away from the city center as populations migrated to the margins of urban areas, where land was less expensive and the environment was less polluted. In 1956, the Federal Highway Act and the building of Interstate highways further facilitated urban expansion across the Unite States. Rural towns, small industrial centers, and farmland were engulfed by expanding urban centers. Over the past 200 years, numerous social, cultural, economic, and political incentives have encouraged urban expansion. In the 1800s, the industrial revolution influenced where people lived and worked. Many people shifted from agricultural production in rural areas to factory work in urban centers. Advances in transportation systems, such as rail transport in the 19th and early 20th centuries, followed by the mass production of the automobile and convenient air travel, facilitated a mobile society and a national economy. Economic growth and a population boom after World War II spurred increased suburbanization-the shifting of residential areas to the outlying section of a city or to a separate municipality-on the fringe of urban areas. Other economic and political incentives that shaped the urban environment included Federally backed home loans, credit and tax mechanisms that encouraged new development, and less restrictive municipal ordinances regarding building codes, environmental laws, and zoning regulations. Throughout the past two centuries land use changes associated with increasing urbanization have had impacts that resonate at local, regional, and even national scales. Landscape changes resulting from urbanization can be mapped and studied over time. Understanding these changes requires a study of the causes of change as related to social, economic, and political influences. Understanding these changes also requires analysis of how urbanization physically spreads across the landscape. The knowledge gained from studying urban land-use change can be helpful when it flows into local, regional, and national decisionmaking that relates to land-use decisions that impact the people, the economy, and the environment. Deriving a correlation between physical change and the explanations of the causes of change can help anticipate and mitigate the impacts of future change. Throughout the past two centuries changes to the Nation's urban areas are inextricably linked to population changes. The Nation's population started growing slowly along the eastern seaboard during the 17th and 18th centuries, accelerated in the second half of the 19th century, and then continued steadily spreading westward throughout the next hundred years. Currently, nearly 80 percent of the U.S. population resides in urban areas. Land area dedicated to urban use continues to expand, although differently than it has in the past. Most newly urbanized areas are much less densely populated and less intensively developed than they were 50 to 100 years ago.

Professional Paper

Geochemistry of groundwater in the eastern Snake River Plain aquifer, Idaho National Laboratory and vicinity, eastern Idaho

Nuclear research activities at the U.S. Department of Energy (DOE) Idaho National Laboratory (INL) in eastern Idaho produced radiochemical and chemical wastes that were discharged to the subsurface, resulting in detectable concentrations of some waste constituents in the eastern Snake River Plain (ESRP) aquifer. These waste constituents may pose risks to the water quality of the aquifer. In order to understand these risks to water quality the U.S. Geological Survey, in cooperation with the DOE, conducted a study of groundwater geochemistry to improve the understanding of hydrologic and chemical processes in the ESRP aquifer at and near the INL and to understand how these processes affect waste constituents in the aquifer. Geochemistry data were used to identify sources of recharge, mixing of water, and directions of groundwater flow in the ESRP aquifer at the INL. The geochemistry data were analyzed from 167 sample sites at and near the INL. The sites included 150 groundwater, 13 surface-water, and 4 geothermal-water sites. The data were collected between 1952 and 2012, although most data collected at the INL were collected from 1989 to 1996. Water samples were analyzed for all or most of the following: field parameters, dissolved gases, major ions, dissolved metals, isotope ratios, and environmental tracers. Sources of recharge identified at the INL were regional groundwater, groundwater from the Little Lost River (LLR) and Birch Creek (BC) valleys, groundwater from the Lost River Range, geothermal water, and surface water from the Big Lost River (BLR), LLR, and BC. Recharge from the BLR that may have occurred during the last glacial epoch, or paleorecharge, may be present at several wells in the southwestern part of the INL. Mixing of water at the INL primarily included mixing of surface water with groundwater from the tributary valleys and mixing of geothermal water with regional groundwater. Additionally, a zone of mixing between tributary valley water and regional groundwater, trending southwesterly, extended from near the northeastern boundary of the INL to the southern boundary of the INL. Groundwater flow directions for regional groundwater were southwesterly, and flow directions for tributary groundwater were southeasterly upon entering the ESRP, but eventually began to flow southwesterly in a direction parallel with regional groundwater. Several discrepancies were identified from comparison of sources of recharge determined from geochemistry data and backward particle tracking with a groundwater-flow model. Some discrepancies observed in the particle tracking results included representation of recharge from BC near the north INL boundary, groundwater from the BC valley not extending far enough south, regional groundwater that extends too far west in the southern part of the INL, and no representation of recharge from geothermal water in model layer 1 or recharge from the BLR in the southwestern part of the INL.

Idaho