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At least 181 records · Page 10Linked to original sources

Growth response of a deep-water ferromanganese crust to evolution of the Neogene Indian Ocean

A deep-water ferromanganese crust from a Central Indian Ocean seamount dated previously by 10Be and 230Th(excess) was studied for compositional and textural variations that occurred throughout its growth history. The 10Be/9Be dated interval (upper 32 mm) yields an uniform growth rate of 2.8 ?? 0.1 mm/Ma [Frank, M., O'Nions, R.K., 1998. Sources of Pb for Indian Ocean ferromanganese crusts: a record of Himalayan erosion. Earth Planet. Sci. Lett., 158, pp. 121-130.] which gives an extrapolated age of ~ 26 Ma for the base of the crust at 72 mm and is comparable to the maximum age derived from the Co-model based growth rate estimates. This study shows that Fe-Mn oxyhydroxide precipitation did not occur from the time of emplacement of the seamount during the Eocene (~ 53 Ma) until the late Oligocene (~ 26 Ma). This paucity probably was the result of a nearly overlapping palaeo-CCD and palaeo-depth of crust formation, increased early Eocene productivity, instability and reworking of the surface rocks on the flanks of the seamount, and lack of oxic deep-water in the nascent Indian Ocean. Crust accretion began (older zone) with the formation of isolated cusps of Fe-Mn oxide during a time of high detritus influx, probably due to the early-Miocene intense erosion associated with maximum exhumation of the Himalayas (op. cit.). This cuspate textured zone extends from 72 mm to 42 mm representing the early-Miocene period. Intense polar cooling and increased mixing of deep and intermediate waters at the close of the Oligocene might have led to the increased oxygenation of the bottom-water in the basin. A considerable expansion in the vertical distance between the seafloor depth and the CCD during the early Miocene in addition to the influx of oxygenated bottom-water likely initiated Fe-Mn crust formation. Pillar structure characterises the younger zone, which extends from 40 mm to the surface of the crust, i.e., ~ 15 Ma to Present. This zone is characterised by > 25% higher content of oxide-bound elements than in the older zone, possibly corresponding to further increased oxygenation of bottom-waters, increased stability of the seamount slope, and gradually reduced input of continental detritus from the erosion of the Himalayas. Middle Miocene Antarctic glaciation, which peaked ~ 12-13 Ma ago, increased the oxic bottom-water influx to the basin resulting in accretion of the crust with low detritus. Therefore, the younger crust started to accrete in response to a shift in bottom-water circulation towards the contemporary pattern, which produced a uniform growth rate and pillar structure up to the present. (C) 2000 Published by Elsevier Science B.V.

Marine Geology

Nanoscale geochemical and geomechanical characterization of dispersed organic matter in shale by infrared nanoscopy

Solid organic matter (OM) plays an essential role in the generation, migration, storage, and production of hydrocarbons from economically important shale rock formations. Electron microscopy images have documented spatial heterogeneity in the porosity of OM at nanoscale, and bulk spectroscopy measurements have documented large variation in the chemical composition of OM during petroleum generation. However, information regarding the heterogeneity of OM chemical composition at the nanoscale has been lacking. Here we demonstrate the first application of atomic force microscopy-based infrared spectroscopy (AFM-IR) to measure the chemical and mechanical heterogeneity of OM in shale at the nanoscale, orders of magnitude finer than achievable by traditional chemical imaging tools such as infrared microscopy. We present a combination of optical microscopy and AFM-IR imaging to characterize OM heterogeneity in an artificially matured series of New Albany Shales. The results document the evolution of individual organic macerals with maturation, providing a microscopic picture of the heterogeneous process of petroleum generation.

Nature Communications

Secondary hydrogeologic regions of the conterminous United States

The U.S. Geological Survey (USGS) previously identified and mapped 62 Principal Aquifers (PAs) in the U.S., with 57 located in the conterminous states. Areas outside of PAs, which account for about 40% of the conterminous U.S., were collectively identified as “other rocks.” This paper, for the first time, subdivides this large area into internally-consistent features, defined here as Secondary Hydrogeologic Regions (SHRs). SHRs are areas of other rock within which the rocks or deposits are of comparable age, lithology, geologic or physiographic setting, and relationship to the presence or absence of underling PAs or overlying glacial deposits. A total of 69 SHRs were identified. The number and size of SHRs identified in this paper are comparable to the number and size of PAs previously identified by the USGS. From a two-dimensional perspective, SHRs are complementary to PAs, mapped only where the PAs were not identified on the USGS PA map and not mapped where the PAs were identified. SHRs generally consist of low permeability rocks or deposits, but can include locally productive aquifers. The two maps, taken together, provide a comprehensive, national-scale hydrogeologic framework for assessing and understanding groundwater systems.

Groundwater

Sierra Nevada batholith

The Sierra Nevada batholith is localized in the axial region of a complex faulted synclinorium that coincides with a downfold in the Mohorovicic discontinuity and in P-wave velocity boundaries within the crust. Observed P-wave velocities are compatible with downward increase in the proportion of diorite, quartz diorite, and calcic granodiorite relative to quartz monzonite and granite in the upper crust, with amphibolite or gabbro-basalt in the lower crust, and with periodotite in the upper mantle. The synclinorium was formed in Paleozoic and Mesozoic strata during early and middle Mesozoic time in a geosyncline marginal to the continent. Granitic magmas are believed to have formed in the lower half of the crust at depths of 25 to 45 kilometers or more, primarily as a result of high radiogenic heat production in the thickened prism of crustal rocks. Magma was generated at different times in different places as the locus of downfolding shifted. It rose into the upper crust because it was less dense than rock of the same composition or residual refractory rocks. Refractory rocks and crystals that were not melted and early crystallized mafic minerals that settled from the rising magma thickened the lower crust. Wall and roof rocks settled around, and perhaps through, the rising magma and provided space for its continued rise. Erosion followed each magmatic episode, and 10 to 12 kilometers of rock may have been eroded away since the Jurassic and 7 to 10 kilometers since the early Late Cretaceous.

California

Progradational sequences in Miocene shoreline deposits, southeastern Caliente Range, California

An exceptionally well exposed marine-nonmarine transition in middle Miocene strata exists in the southeastern Caliente Range, California. About 50 individual progradational sequences form a succession that ranges in thickness from approximately 1000 m (where predominantly nonmarine) to more than 2500 m (where predominantly marine). Paleogreographic evidence in basalt flows near the top of the succession and in overlying fluvial deposists indicates that these middle Miocene strata were deposited across a north-northwest trending shoreline. A complete progradational sequence typically is several meters to a few tens of meters thick and includes strata that represent three intertonguing stratigraphic units. Individual sequences generally rest on a thin gravel deposit interpreted as a transgressive lag on an erosional surface. The gravel is overlain by structureless siltstone or fine-grained sandstone deposited at water depths where the rate of faunal mixing exceeded that of production of structures by physical processes. These rocks grade upward into bedded fine sandstone deposited closer to shore where physical processes exceeded bioturbation. Crossbedded lenses of coarse sand or fine gravel in the upper part of this facies suggest the presence of failry long-period surface waves. The bedded fine sandstone is sharply overlain by a crossbedded coarse sandstone facies that is interpreted as a combined offshore bar-rip channel-surf zone assemblage. Cross-strata dip dominantly offshore, suggesting substantial deposition from rip currents. A secondary, shore=parallel mode of cross-strata direction suggests longshore currents produced by surface waves from the northwest. The crossbedded coarse-grained sandstone grades upward into planar-bedded medium-grained sandstone that is interpreted as a beach foreshore. This facies grades upward through structureless medium-grained sandstone into nonmarine or lagoonal red and green mudstone of the Caliente Formation. The middle Miocene succession was deposited in a subsiding basin that was otherwise remarkably stable tectonically; the position of the strand line differed no more than a few kilometers through a period of 1 to 3 m.y. The average duration of the transgressive-regressive cycles, a few tens of thousands of years, together with their distribution in groups of three or four in the lower two-thirds of the succession, is consistent with the pattern of long-term climatic cycles produced by periodicity of the earth's solar orbit and may be related to eustatic sea level changes attendant to the development of the Antarctic ice cap. Changes in the pattern of progradation in the upper part of the succession and nearby basaltic eruptions may hav been precursors to the onset of movement along the San Andreas fault in this area 12-14 m.y. ago.

California

Sedimentary features of the Blackhawk formation (Cretaceous) at Sunnyside, Carbon County, Utah

The Blackhawk Formation at Sunnyside, Utah, was deposited along the western margin of the Western Interior Cretaceous sea during southeastward withdrawal of the sea. Sand was the dominant type of land-derived sediment deposited in the Sunnyside district during the regressive phases. Sand bodies prograded seaward in response to changing sediment supply from a source west of Sunnyside. Where conditions were favorable for the accumulation of vegetable material, peat deposits formed and were later changed to bituminous Coal by diagenesis. Studies of the coal bed show that the coals were formed from accumulation of small, low-growing plants and plant debris that was transported into the area of accumulation. Remains of large plants in the coals are rare. Trace fossils, which are tracks, trails and burrows formed by organisms and preserved in the rock, are extremely abundant in the Blackhawk rocks. These biogenic sedimentary structures are common in Cretaceous deposits throughout the western United States. Trace fossil distribution in the rocks is controlled by the depositional environment preferred by their creators. A study of the trace fossils of a. locality allows a more precise determination of the conditions during deposition of the sediments. Water depth, bottom conditions, salinity, current velocity and amount of suspended nutrients in the water are some of the environmental factors that may be reconstructed by studying trace fossils. The Blackhawk Formation at Sunnyside comprises the members, the Kenilworth Member and the Sunnyside Member. Field studies show that the formation may be further subdivided in the Sunnyside district., according to the precepts of units of mappable thickness and similar lithologic characteristics. The Blackhawk pinches out eastward and north. ward into the Mancos Shale, and names for submembers become meaningless. Names are of value in the region of interest, however, because of the prominence of the named units. Coal mining is the main industry of the Book Cliffs region. Mines of the Sunnyside district are plagued by coal mine bumps, which are sudden, catastrophic releases of stress in the coal. Bumps cause loss of life, property age, and loss of profit to mining companies. Bumps occur when shear stress built up in the coal exceeds the shear Strength of the coal. Differential overburden pressure, faulting and tectonic activity, and lithology and structure of roof rocks are factors which influence bumps. Petroleum and natural gas (methane), which occur locally in pockets in the roof rocks above coal beds, may be diagenetic products of organic-rich sediments.

Open-File Report

Preliminary geologic map of the Simi 7.5' quadrangle, southern California: A digital database

The Simi Quadrangle covers an area of about 62 square miles in southern Ventura County. The Santa Clara River Valley occupies the northwestern corner of the quadrangle. Mountainous terrain of South Mountain and Oak Ridge characterizes the northern and central area. Elevation within the quadrangle ranges from about 250 feet along the arroyo bottoms to over 2200 feet. Steep, highly dissected slopes form much of the boundary of the area. In the southeast, Little Simi Valley, drained by Arroyo Simi/Arroyo Las Posas, separates the southern flank of Oak Ridge from the Las Posas Hills. The Las Posas upland area, a broad elevated region that slopes gently to the south, separates the South Mountain-Oak Ridge highlands from the Las Posas-Camarillo Hills between Little Simi Valley on the east and the Oxnard Plain on the west. This relatively low-lying area is also referred to as the Las Posas Valley. Numerous north-south-trending drainages cut South Mountain and Oak Ridge creating steep narrow canyons on north-facing slopes and wide flat-bottomed canyons with incised streams on south-facing slopes. A network of residential streets and ranch and oilfield roads that traverse the area from U.S. Highway 101 and State Highways 118, 23, and 126 provides access to the area. Current land use includes citrus and avocado orchards, oil well drilling and production, sand and gravel quarries, decorative-rock quarries, cattle grazing, suburban residential development, and golf courses. The oldest geologic unit mapped in the Simi Quadrangle is the upper Eocene to lower Miocene Sespe Formation. The Sespe Formation consists of alluvial fan and floodplain deposits of interbedded pebble-cobble conglomerate, massive to thick-bedded sandstone, and thin-bedded siltstone and claystone. In the northern part of the map area, Sespe Formation is overlain by and interfingers with the upper Oligocene to lower Miocene Vaqueros Formation that is composed of transitional and marine sandstone, siltstone, and claystone with local sandy coquina beds. In the Las Posas Hills, Sespe Formation is unconformably overlain by marine sandstones of the middle Miocene Topanga Group that are interlayered with and intruded by basalt flows, breccia, and diabase dikes of the Conejo Volcanics. Deep-marine strata of the upper Miocene Modelo Formation cover the Vaqueros Formation and Topanga Group along the crests and southern flanks of South Mountain and Oak Ridge. They also occur as isolated outcrops in the Las Posas Hills. Locally, Modelo Formation consists of interbedded diatomaceous shale, claystone, mudstone, and siltstone with minor sandstone, limestone, chert, and tuff beds. The most widely exposed rock units in the area are the Plio-Pleistocene marine and non-marine Pico and Saugus Formations that crop out on the southern flank of South Mountain-Oak Ridge. Locally, the Pico Formation consists of marine siltstone and silty shale with minor sandstone and pebbly sandstone. The Saugus Formation overlies and interfingers with the Pico Formation and is composed of interbedded shallow-marine to brackish water sandstone, siltstone, pebble-to-cobble conglomerate, and coquina beds that grade laterally and vertically into non-marine sandstone, siltstone, and conglomerate. A local member of the Saugus Formation is exposed in the southwest corner of the map area. It is predominantly a volcanic breccia conglomerate that resembles the Conejo Volcanics breccia, but is believed to represent remnants of landslide debris shed from the Conejo Volcanics into a local trough during Saugus time. Quaternary surficial deposits cover the floor and margins of the Little Simi Valley, Santa Clara River Valley in the north, and Arroyo Las Posas in the south, and extend up into the larger canyons that drain South Mountain and Oak Ridge. Extensive surficial deposits are also present in the Las Posas upland area in the southwest. These upper Pleistocene to Holocene sediments consist of older and younger alluvial fan and valley deposits, colluvium, active alluvial fans, and active stream deposits. Pleistocene- to Holocene-age landslide deposits are widespread throughout the Simi Quadrangle, especially in the finer grained Tertiary sedimentary units where bedding planes are dip slopes. In addition, massive slumps are present in the Sespe and Vaqueros Formations on anti-dip slopes. Seismic and well data from the San Fernando Valley (SFV) document evolution of that region from mid-Miocene rifting to north-south contraction. Formations in the western SFV subsurface (Cretaceous to Paleogene strata, and Miocene Topanga and Modelo Formations) trace southward to outcrops in the Santa Monica Mountains that constrain faulting along the valley's south basin edge. Cretaceous strata in the Simi Uplift to the west are over 2 km higher than equivalent strata beneath the western SFV across a boundary marked by the Chatsworth Reservoir fault, and Neogene thinning and offlap. The Simi fault, located at the eastern end of the Simi-Santa Rosa fault system, bounds the northern margins of the Simi and Tierra Rejada Valleys. West of Simi Valley, the Simi fault has placed Miocene Conejo Volcanics over Plio-Pleistocene Saugus Formation rocks. The 15.5 ± 0.8 m.y.a. base of the Conejo Volcanics, identified in oil well logs, is inferred to have a dip-slip separation of about 425 to 550 m, suggesting a low long-term slip rate of about 0.03 mm/yr. However, substantial late Quaternary offset is suggested by the presence of more than 150 m of Pleistocene and younger alluvium that fills the east-west trending, down-dropped bedrock trough beneath western Simi Valley. In addition, trenching within faulted colluvial deposits in Tierra Rejada Valley has revealed evidence of multiple shears within Holocene (?) deposits.

California

Microbial production of isotopically light iron(II) in a modern chemically precipitated sediment and implications for isotopic variations in ancient rocks

The inventories and Fe isotope composition of aqueous Fe(II) and solid-phase Fe compounds were quantified in neutral-pH, chemically precipitated sediments downstream of the Iron Mountain acid mine drainage site in northern California, USA. The sediments contain high concentrations of amorphous Fe(III) oxyhydroxides [Fe(III) am ] that allow dissimilatory iron reduction (DIR) to predominate over Fe–S interactions in Fe redox transformation, as indicated by the very low abundance of Cr(II)-extractable reduced inorganic sulfur compared with dilute HCl-extractable Fe. δ 56 Fe values for bulk HCl- and HF-extractable Fe were ≈ 0. These near-zero bulk δ 56 Fe values, together with the very low abundance of dissolved Fe in the overlying water column, suggest that the pyrite Fe source had near-zero δ 56 Fe values, and that complete oxidation of Fe(II) took place prior to deposition of the Fe(III) oxide-rich sediment. Sediment core analyses and incubation experiments demonstrated the production of millimolar quantities of isotopically light (δ 56 Fe ≈ -1.5 to -0.5‰) aqueous Fe(II) coupled to partial reduction of Fe(III) am by DIR. Trends in the Fe isotope composition of solid-associated Fe(II) and residual Fe(III) am are consistent with experiments with synthetic Fe(III) oxides, and collectively suggest an equilibrium Fe isotope fractionation between aqueous Fe(II) and Fe(III) am of approximately -2‰. These Fe(III) oxide-rich sediments provide a model for early diagenetic processes that are likely to have taken place in Archean and Paleoproterozoic marine sediments that served as precursors for banded iron formations. Our results suggest pathways whereby DIR could have led to the formation of large quantities of low-δ 56 Fe minerals during BIF genesis.

California

Lunar highlands volcanism implications from Luna 20 and Apollo 16

Highlands materials sampled at the Apollo 16 and Luna 20 sites represent units of distinctive morphology that are widespread on the lunar nearside. Samples from the Apollo 16 site represent hilly and furrowed materials of the Descartes highlands and Cayley Formation. Materials were collected by Luna 20 from terrain resembling the Descartes terrain. Most photogeologic interpretations of these units favored volcanic origins, but the samples fail to support this interpretation. Luna 20 soil fragments are mainly glassy microbreccia with lithic inclusions of fine-grained hornfels; less than 3 percent of the fragments have textures of volcanic rocks, and most of these are likely crystalline products of impact melting. Apollo 16 soils formed on ejecta derived from a plutonic anorthosite-norite-troctolite suite. The similarity of Luna 20 soils indicates that these too formed as regolith on ejecta of anorthosite-norite-troctolitc composition. Interpretation of the samples from the two locations now suggests that hilly and furrowed terrains, previously thought to be of volcanic origin, are impact ejecta; in view of the plutonic nature of the source rocks and their extensive fusion and metamorphism, it is likely that the ejecta were derived from multiring basins. At one point, the Apollo 16 site, the Cayley Formation is composed of basin ejecta.

Journal of Research of the U.S. Geological Survey

Gas, oil, and water production from Jonah, Pinedale, Greater Wamsutter, and Stagecoach Draw fields in the Greater Green River Basin, Wyoming

Gas, oil, and water production data were compiled from selected wells in four gas fields in rocks of Late Cretaceous age in southwestern Wyoming. This study is one of a series of reports examining fluid production from tight-gas reservoirs, which are characterized by low permeability, low porosity, and the presence of clay minerals in pore space. Production from each well is represented by two samples spaced five years apart, the first sample typically taken two years after commencement of production. For each producing interval, summary diagrams of oil versus gas and water versus gas production show fluid production rates, the change in rates during five years, the water-gas and oil-gas ratios, and the fluid type. These diagrams permit well-to-well and field-to-field comparisons. Fields producing water at low rates (water dissolved in gas in the reservoir) can be distinguished from fields producing water at moderate or high rates, and the water-gas ratios are quantified. The ranges of first-sample gas rates in Pinedale field and Jonah field are quite similar, and the average gas production rate for the second sample, taken five years later, is about one-half that of the first sample for both fields. Water rates are generally substantially higher in Pinedale than in Jonah, and water-gas ratios in Pinedale are roughly a factor of ten greater in Pinedale than in Jonah. Gas and water production rates from each field are fairly well grouped, indicating that Pinedale and Jonah fields are fairly cohesive gas-water systems. Pinedale field appears to be remarkably uniform in its flow behavior with time. Jonah field, which is internally faulted, exhibits a small spread in first-sample production rates. In the Greater Wamsutter field, gas production from the upper part of the Almond Formation is greater than from the main part of the Almond. Some wells in the main and the combined (upper and main parts) Almond show increases in water production with time, whereas increases in water production are rare in the upper part of the Almond, and a higher percentage of wells in the upper part of the Almond show water decreasing at the same rate as gas than in the main or combined parts of the Almond. In Stagecoach Draw field, the gas production rate after five years is about one-fourth that of the first sample, whereas in Pinedale, Jonah, and Greater Wamsutter fields, the production rate after five years is about one-half that of the first sample. The more rapid gas decline rate seems to be the outstanding feature distinguishing Stagecoach Draw field, which is characterized as a conventional field, from Pinedale, Jonah, and Greater Wamsutter fields, which are generally characterized as tight-gas accumulations. Oil-gas ratios are fairly consistent within Jonah, Pinedale, and Stagecoach Draw fields, suggesting similar chemical composition and pressure-temperature conditions within each field, and are less than the 20 bbl/mmcf upper limit for wet gas. However, oil-gas ratios vary considerably from one area to another in the Greater Wamsutter field, demonstrating a lack of commonality in either chemistry or pressure-temperature conditions among the six areas. In all wells in all four fields examined here, water production commences with gas production—there are no examples of wells with water-free production and no examples where water production commences after first-sample gas production. The fraction of records with water production higher in the second sample than in the first sample varies from field to field, with Pinedale field showing the lowest percentage of such cases and Jonah field showing the most. Most wells have water-gas ratios exceeding the amount that could exist dissolved in gas at reservoir pressure and temperature.

Wyoming

Metasomatic origin of large parts of the Adirondack Phacoliths

A metasomatic origin seems established for large parts of the granite phacoliths in the northwest Adirondack Mountains, New York. This conclusion is based upon the discovery and detailed mapping of a blurred but widespread stratigraphic sequence in the phacoliths . Highly complicated patterns of relict beds are defined by alternations of granitic gneiss, amphibolite, oligoclase-quartz gneiss, and a predominant alaskitic granite. Regional reconstructions indicate these relict beds comprise a major basal formation, probably of arkosic and calcareous quartzites, in the exposed Grenville metasedimentary rocks. The existing amphibolite interlayers formed early in the metasomatic epoch, probably replacing the more calcareous quartzite beds. This mafic metasomatism was overlapped and followed by pervasive granitization of the arkosic and highly quartzose members. Pink alaskitic granite is the final metasomacic product. It tends to replace all pre-existing rock types, especially in the cores of the antiforms. This mafic and granitic metasomatism occurred during the evolution of the major folds in the metasedimentary sequence. As the folds evolved, rising domes in the quartzite probed upward into successively higher horizons in the overlying marbles. At least three quartzite antiforms (California, Clark Pond, and South Edwards phacoliths ) punctured the overlying marble, invading the basal layers of the Adirondack paragneiss. The crests of the evolving folds in the basal quartzite, capped by carbonate-rich marble, acted as traps for aqueous and carbonated, alkali-bearing fluids, and perhaps some associated anatectic granitic magma generated in the deeper, hotter basement to the Grenville.

New York

An aem-tem study of weathering and diagenesis, Abert Lake, Oregon: I. Weathering reactions in the volcanics

Abert Lake in south-central Oregon provides a site suitable for the study of sequential weathering and diagenetic events. In this first of two papers, transmission electron microscopy was used to characterize the igneous mineralogy, subsolidus alteration assemblage, and the structural and chemical aspects of silicate weathering reactions that occur in the volcanic rocks (basalts, basaltic andesites, and dacitic/ rhyolitic extrusive and pyroclastics) that outcrop around the lake. Olivine and pyroxene replacement occurred topotactically, whereas feldspar and glass alteration produced randomly oriented smectite in channels and cavities. The tetrahedral, octahedral, and interlayer compositions of the weathering products, largely dioctahedral smectites, varied with primary mineral composition, rock type, and as the result of addition of elements released from adjacent reaction sites. Weathering of the highly evolved, Fe-rich Jug Mountain complex at the north end of the lake produced a homogeneous smectite assemblage that contrasts with the heterogeneous smectite assemblage replacing the volcanics along the eastern margin of the lake. The variability within and between the smectite assemblages highlights the microenvironmental diversity, fluctuating redox conditions, and variable solution chemistry associated with mineral weathering reactions in the surficial environment. Late-stage exhalative and aqueous alteration of the volcanics redistributed many components and formed a variety of alkali and alkali-earth carbonate, chloride, sulfate, and fluoride minerals in vugs and cracks. Overall, substantial Mg, Si, Na, Ca, and K are released by weathering reactions that include the almost complete destruction of the Mg-smectite that initially replaced olivine. The leaching of these elements from the volcanics provides an important source of these constituents in the lake water. The nature of subsequent diagenetic reactions resulting from the interaction between the materials transported to the lake and the solution will be described in part II ( Banfield et al., 1991).

Geochimica et Cosmochimica Acta

Reconnaissance geology of the Manjamah Quadrangle, sheet 18/41 A, Kingdom of Saudi Arabia

The Manjamah quadrangle (sheet 18/41 A) lies between lat 18?30' and 19?00' N. and long 41?00' and 41?30' E. and encompasses an area of 2,932 km2, of which about half is land and the remainder covered by the Red Sea. The geologic formations exposed in the quadrangle comprise Precambrian layered and intrusive rocks,. Tertiary layered rocks and gabbro dikes, and. Quaternary basaltic lavas, pyroclastic rocks, and surficial deposits. The Precambrian rocks are layered metasedimentary and metavolcanic rocks that have been assigned to the Baish and Bahah groups. These rocks are cut by Precambrian biotite quartz monzonite and by Miocene gabbro dikes that were intruded during the initial stages of the opening of the Red Sea rift. Tuffaceous siltstone of the Baid formation was also deposited during the Miocene, followed in the Pliocene by the polymict conglomerate of the Bathan formation. The Quaternary rocks include basalt that was extruded during a continuation of the opening of the Red Sea rift, after uplift of the escarpment parallel with the Red Sea but before the Holocene erosional cycle. The greater part of the land area of the quadrangle is covered by Quaternary coastal, pediment, and alluvial deposits of various kinds associated with the deltaic mouths of Wadi Hall and Wadi Yiba and their tributaries and with the development of fringing reefs and islands. The area also contains extensive Quaternary eolian deposits. The economic potential of the quadrangle lies essentially in the agricultural value .of its flood-plain deposits, which are frequently refreshed during flooding with the products of weathering and erosion of the Precambrian rocks in the valleys of Wadi Hal i and Wadi Yiba; coral reefs could possibly provide raw material for use in a cement industry, if any such industry were ever required in this area.

Open-File Report

Geology of the Brysch uranium mine, Karnes County, Texas

Approximately 13,700 tons (12,400 tonnes) of oxidized uranium ore, averaging about 0.1 percent U 2 O 8 , was mined during 1966 and 1967 from the lower unit of the Deweesville Sandstone Member of the upper Eocene Whitsett Formation, from depths of 75 to 90 feet (23-27 m). The mine is in the Karnes County uranium area, 3 miles (5 km) east of Falls City, Tex. Meta-autunite, Ca(UO 2 ) 2 (PO 4 ) 2 2-6H 2 O, and meta-tyuyamunite, Ca(UO 2 ) 2 (PO 4 ) 2 3-5H 2 O, were identified in samples of the ore. The host rock is light-colored, medium-grained, well-sorted feldspathic sandstone that contains fossil wood and Ophiomorpha . It also contains clinoptilolite, cristobalite, and montmorillonite that probably formed as alteration products of volcanic grains in the original sediment. The host rock was deposited in a beach environment near or on a delta formed at the mouth of a stream channel oriented roughly normal to the beach. The Deweesville can be traced for many miles on the surface and represents in general the point of maximum transgression in a transgressive-regressive cycle. The upper unit of the Deweesville, which overlies the host rock, is now exposed in the mine and contains, in ascending order, storm-beach, shoreface, beach, and tidal-flat facies. The shape of the ore body suggests that it originated as an unoxidized ore roll. The ore-bearing fluids may have entered through porous fluvial rock extending updip. Plant material, abundant in the original host sediment, probably supplied reductant necessary for the roll formation.

Texas

Geochemical characteristics of igneous rocks associated with epithermal mineral deposits—A review

Newly synthesized data indicate that the geochemistry of igneous rocks associated with epithermal mineral deposits varies extensively and continuously from subalkaline basaltic to rhyolitic compositions. Trace element and isotopic data for these rocks are consistent with subduction-related magmatism and suggest that the primary source magmas were generated by partial melting of the mantle-wedge above subducting oceanic slabs. Broad geochemical and petrographic diversity of individual igneous rock units associated with epithermal deposits indicate that the associated magmas evolved by open-system processes. Following migration to shallow crustal reservoirs, these magmas evolved by assimilation, recharge, and partial homogenization; these processes contribute to arc magmatism worldwide. Although epithermal deposits with the largest Au and Ag production are associated with felsic to intermediate composition igneous rocks, demonstrable relationships between magmas having any particular composition and epithermal deposit genesis are completely absent because the composition of igneous rock units associated with epithermal deposits ranges from basalt to rhyolite. Consequently, igneous rock compositions do not constitute effective exploration criteria with respect to identification of terranes prospective for epithermal deposit formation. However, the close spatial and temporal association of igneous rocks and epithermal deposits does suggest a mutual genetic relationship. Igneous systems likely contribute heat and some of the fluids and metals involved in epithermal deposit formation. Accordingly, deposit formation requires optimization of source metal contents, appropriate fluid compositions and characteristics, structural features conducive to hydrothermal fluid flow and confinement, and receptive host rocks, but not magmas with special compositional characteristics.

Ore Geology Reviews

Oligocene caldera complex and calc-alkaline tuffs and lavas of the Indian Peak volcanic field, Nevada and Utah

The Indian Peak volcanic field is representative of the more than 50,000 km 3 of ash-flow tuff and tens of calderas in the Great Basin that formed during the Oligocene-early Miocene "ignimbrite flareup" in southwestern North America. The field formed about 32 to 27 Ma in the southeastern Great Basin and consists of the centrally positioned Indian Peak caldera complex and a surrounding blanket of related ash-flow sheets distributed over an area of about 55,000 km 2 . The field has a volume on the order of 10,000 km 3 . A cluster of two obscure source areas and four calderas comprise the ∼80 x 120 km caldera complex. Only minor volumes of rhyolite and two pyroxene andesite lavas were extruded episodically throughout the lifetime of the magma system that formed the field, chiefly during its youth and old age. Six ash-flow sequences alternate between rhyolite and dacite in a volume ratio of about 1:8, and a culminating seventh is trachytic. The first, fourth, and sixth tuff units are of rhyolite that contains sparse to modest amounts of phenocrysts, chiefly plagioclase and biotite, and abundant lithic and pumice lapilli; these deposits are confined within the caldera complex and form multiple and compound cooling units that are normally zoned with respect to bulk chemical composition and crystal type, content, and size. The second, third, and fifth tuff sequences are of crystal-rich dacite that forms extensive simple cooling-unit outflow sheets and partial caldera fillings of compound cooling units. Each dacite unit contains similar amounts of plagioclase, biotite, hornblende, quartz, two pyroxenes, and Fe-Ti oxides; trace amounts of sanidine and titanite also occur in the youngest. Cognate inclusions in the dacites show only slight intra- and inter-unit differences in bulk chemical composition. The seventh eruptive sequence consists of several cooling units of trachydacite tuff containing small to modest amounts of plagioclase and two pyroxenes. These dominantly high-K calc-alkaline rocks are a record of the birth, maturation, and death of a large, open, continental magma system that was probably initiated and sustained by influx of mafic magma derived from a southward-migrating locus of magma production in the mantle. The small volumes of chemically diverse andesitic rocks were derived from separately evolving magma bodies but are modified representatives of the mantle power supply. Recurrent production of very large batches (some greater than 3,000 km 3 ) of quite uniform dacite magmas appears to have required combination of andesite magma and crustal silicic material in vigorously convecting chambers. Compositional data indicate that rhyolites are polygenetic. As the main locus of mantle magma production shifted southward, trachydacite magma could have been produced by fractionation of andesitic magma within the crust.

Nevada, Utah

Potential for formation of disinfection by-products from storage of chlorinated surface water in the Basalt aquifer near Fallon, Nevada

Increased pumpage from a basalt aquifer near Fallon, Nevada, has caused its water levels to decline and has induced changes in the quality of water pumped from the basalt. The aquifer is the sole source of water for municipal supply to the city of Fallon, the Naval Air Station Fallon, and the Fallon Paiute-Shoshone Tribe. These changes may be mitigated by storage of surface water in the basalt for subsequent use. Because chlorination of the surface water may be required for storage, the U.S. Geological Survey, in cooperation with the Fallon Paiute-Shoshone Tribe, made laboratory tests using laboratory carbon-organic-free water, surface-water, ground-water, and basaltic-rock samples to determine the potential for formation of disinfection by-products. Experiments with water samples only (no rock and no chlorine) indicated no change in dissolved-organic-carbon (DOC) concentrations over a 20-day reaction period; whereas, all experiments using rock, water, and no chlorine indicated an increase in DOC concentrations. The greatest increase in DOC concentrations for all three water samples occurred in experiments with the rock samples from outcrops on Rattlesnake Hill. Experiments with water only and chlorine yielded a total trihalomethane (THM) concentration of 97.4 ?g/L for the ground-water sample and 347 ?g/L for the surface-water sample. Experiments with mixtures of water, rocks, and chlorine indicated that reactions with the rock consumed chlorine and released significant amounts of organic carbon from the rock, increasing the DOC concentration in the water. The organic carbon in the rocks likely is associated with the secondary clay minerals that line vesicles and fractures in the rocks. THM concentrations were greatest, from 335 to 909 ?g/L, for surface water equilibrated with rock samples from Rattlesnake Hill. However, the concentration of chlorine required to produce these high THM concentrations ranged from 18 to 84 mg/L. The results of the experiments suggest that the amount of organic carbon released from the rocks during successive cycles of recharge, storage, and recovery of chlorinated surface water may be relatively small. The chlorine demand of the rocks is so large that all of the free chlorine in the entire volume of recharged water likely would be consumed by only a very small volume of the aquifer surrounding an injection well, or beneath an infiltration bed. The majority of the volume of the aquifer filled by the stored water likely would never come in contact with free chlorine, and the increases in concentration of DOC observed in these experiments likely would occur in a very small volume of the stored water. For this reason, increases in concentration of THMs for the entire volume of water stored also likely would be considerably less than those measured in these experiments. To test this hypothesis, additional laboratory experiments using varying levels of chlorination, varying lengths of reaction periods, and repeated cycles of chlorination would be useful. A field experiment made at a small scale in an isolated part of the basalt aquifer would aid in the design of an operational system.

Scientific Investigations Report

Sulfur cycle in the Valles Caldera volcanic complex, New Mexico – Letter 1: Sulfate sources in aqueous system, and implications for S isotope record in Gale Crater on Mars

Initial in situ sulfur (S) isotope measurements of the Martian bedrock in Gale Crater have revealed an unexpectedly wide range of δ 34 S values (−47 to +28%). Generally, it is unclear what processes could have contributed to these large isotope fractionations. Therefore, we studied S sources and aqueous SO 2− 4 cycling in the Valles Caldera volcanic complex, New Mexico to better understand S isotope fractionations related to S degassing, hydrothermal activity, and low-temperature processes in aqueous environment. Overall, our study demonstrates that volcanic systems show large spatial heterogeneity in δ 34 S. Magmatic S sources are obvious in steam-dominated H 2 S degassing and precipitation of secondary minerals from hydrothermal fluids with low δ 34 S values of +0.9 ±3%. Locally, however, hydrothermal processes have resulted in more negative δ 34 S values in sulfide minerals (−18 to −4%) and more positive δ 34 S values in sulfate minerals (−1 to +3%). Major aqueous SO 2− 4 sources are oxidation of H 2 S from modern hydrothermal gas emission, and oxidation and dissolution of sulfide and sulfate minerals present in the hydrothermally altered bedrock and crater-lake sediments. The δ 34 S of aqueous SO 2− 4 in surface water and groundwater varies widely (−8 to +5%) and is similar to major S endmembers that undergo oxidation and/or dissolution by active hydrological system. Minor SO 2− 4 contributions with more positive δ 34 S values (+9 to +14%) come from deeply circulating geothermal fluids and negligible amounts from atmospheric deposition (+5 to +7% in snow). Elevated SO 2− 4 contents are mainly associated with modern and past H 2 S emissions and oxidations near the surface. On regional scale, however, most of the intracaldera bedrock is S-depleted, thus the SO 2− 4 contents are usually low in the surface aquatic system and younger sedimentary lake deposits formed at times of negligible near surface hydrothermal activity. In general, magmatic-hydrothermal processes apparently cause the largest δ 34 S variation in S-bearing minerals on volcanic terrains. Therefore, we infer that the measured wide range of δ 34 S values in the Gale sediments by the Curiosity rover on Mars can be explained by S isotope composition of magmatic-hydrothermal sulfide and sulfate minerals that were present in the initial igneous/volcanic rocks prior to crater formation. Later aqueous processes involved oxidation and dissolution of S minerals initially present in these rocks and led to subsequent formation of diagenetic fluids and alteration products enriched in SO 2− 4 with relatively large δ 34 S variation. Additionally, physical erosion, transport and deposition of detrital hydrothermal S minerals from igneous/volcanic rocks might be in part responsible for the measured wide range of δ 34 S in Gale Crater. These unique S isotope results, measured in situ on another planet for the first time, imply the importance of magmatic-hydrothermal fluids in S transport on early Mars and their subsequent alteration in low-temperature aqueous environments.

New Mexico