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USGS2021

The processes of preferential flow in the unsaturated zone

Preferential flow, a major influence in unsaturated soil and rock almost everywhere, occurs by multiple phenomenologically distinct hydraulic processes. For the mode known as funneled flow, concentrated in particularly conductive portions of the medium, the surface-tension/viscous-flow processes of traditional unsaturated flow theory predominate. Fingered flow, through conductive paths of higher water content than surrounding material, requires amendments to traditional theory concerning instabilities and dynamic flow-regime boundaries. Macropore flow, the most recognized preferential flow mode, poses unanswered questions and major difficulties in practice. Accumulated evidence shows that water flows preferentially mostly through macropores that are (a) only partially filled with water, and (b) surrounded by matrix material that is drier, sometimes much drier, than saturation. With partial filling, geometric characteristics such as aperture have much less influence than was previously thought, and the intra-macropore configuration of the flowing water phase, about which little is conclusively known, is then a dominant controlling influence. With unsaturated surroundings, macropore/matrix exchange interactions control, for given input and medium, the initiating circumstances, conveyed flux, and duration of macropore flow. The multiple processes in play during such interactions have different sensitivities to the matrix water state and different directions of influence. The net influence of matrix water content on macropore flow is thus highly complex and a major research need. Additional high-priority topics are: flowpath connectivity, for watersheds as well as small scales; intra-macropore processes, to discern their importance and possible means of quantification; and the identification of measurable soil and rock properties that can be utilized predictively.

Soil Science Society of America Journal↗

USGS2024

Ion exchange processes for CO2 mineralization using industrial waste streams: Pilot plant demonstration and life cycle assessment

An attractive technique for removing CO 2 from the environment is sequestration within stable carbonate solids (e. g., calcite). However, continuous addition of alkalinity is required to achieve favorable conditions for carbonate precipitation (pH>8) from aqueous streams containing dissolved CO 2 (pH<4.5) and Ca 2+ ions. In this study, a pH-swing process using ion exchange was demonstrated to process 300 L of produced water brine per day for CO 2 mineralization. Proton titration capacities were quantified for aqueous streams in equilibrium with gas streams at various concentrations of CO 2 (pCO 2 =0.03–0.20 atm) and at various flow rates (0.5–2.0 L min −1 ). Energy intensities for the process were determined to be between 30 and 65 kWh per tonne of CO 2 sequestered depending on the composition of the brine stream. A life cycle assessment was performed to analyze the net carbon emissions of the technology which indicated a net CO 2 reduction for pCO 2 ≥0.12 atm (−0.06–−0.39 kg CO 2 e per kg precipitated CaCO 3 ) utilizing calcium-rich brines. The results from this study indicate the ion exchange process can be used as a scalable method to provide alkalinity necessary for the capture and storage of CO 2 in Ca-rich waste streams.

Chemistry Select↗

USGS2008

Geology and Surface Processes on Titan

The surface of Titan has been revealed globally, if incompletely, by Cassini observations at infrared and radar wavelengths as well as locally by the instruments on the Huygens probe. Extended dune fields, lakes, mountainous terrain, dendritic erosion patterns and erosional remnants indicate dynamic surface processes. Valleys, small-scale gullies and rounded cobbles such as those observed at the Huygens landing site require erosion by energetic flow of a liquid. There is strong evidence that liquid hydrocarbons are ponded on the surface in high-latitude lakes, predominantly, but not exclusively, at high northern latitudes. A variety of features including extensive flows and caldera-like constructs are interpreted to be cryovolcanic in origin. Chains and isolated blocks of rugged terrain rising from smoother areas are best described as mountains and might be related to tectonic processes. Finally, impact craters are observed but their small numbers indicate that the crater retention age is very young overall. In general, Titan exhibits a geologically active surface indicating significant endogenic and exogenic processes, with diverse geophysical and atmospheric processes reminiscent of those on Earth.

Book chapter↗

USGS1996

Merged GLORIA sidescan and hydrosweep pseudo-sidescan: Processing and creation of digital mosaics

We have replaced the usual band of poor-quality data in the near-nadir region of our GLORIA long-range sidescan-sonar imagery with a shaded-relief image constructed from swath bathymetry data (collected simultaneously with GLORIA) which completely cover the nadir area. We have developed a technique to enhance these "pseudo-sidescan" images in order to mimic the neighbouring GLORIA backscatter intensities. As a result, the enhanced images greatly facilitate the geologic interpretation of the adjacent GLORIA data, and geologic features evident in the GLORIA data may be correlated with greater confidence across track. Features interpreted from the pseudo-sidescan may be extrapolated from the near-nadir region out into the GLORIA range where they may not have been recognized otherwise, and therefore the pseudo-sidescan can be used to ground-truth GLORIA interpretations. Creation of digital sidescan mosaics utilized an approach not previously used for GLORIA data. Pixels were correctly placed in cartographic space and the time required to complete a final mosaic was significantly reduced. Computer software for digital mapping and mosaic creation is incorporated into the newly-developed Woods Hole Image Processing System (WHIPS) which can process both low- and high-frequency sidescan, and can interchange data with the Mini Image Processing System (MIPS) most commonly used for GLORIA processing. These techniques are tested by creating digital mosaics of merged GLORIA sidescan and Hydrosweep pseudo-sidescan data from the vicinity of the Juan Fernandez microplate along the East Pacific Rise (EPR).

Marine Geophysical Research↗

USGS1997

Benthic boundary layer processes in the Lower Florida Keys

This special issue of Geo-Marine Letters, "Benthic Boundary Layer Processes in the Lower Florida Keys," includes 12 papers that present preliminary results from the Key West Campaign. The Dry Tortugas and Marquesas Keys test sites were selected by a group of 115 scientists and technicians to study benthic boundary layer processes in a carbonate environment controlled by bioturbation and biogeochemical processes. Major activities included remote sediment classification; high-frequency acoustic scattering experiments; sediment sampling for radiological, geotechnical, biological, biogeochemical, physical, and geoacoustic studies; and hydrodynamic studies using an instrumented tetrapod. All these data are being used to improve our understanding of the effects of environmental processes on sediment structure and behavior.

Florida↗

USGS2012

The importance of local and landscape-scale processes to the occupancy of wetlands by pond-breeding amphibians

Variation in the distribution and abundance of species across landscapes has traditionally been attributed to processes operating at fine spatial scales (i.e., environmental conditions at the scale of the sampling unit), but processes that operate across larger spatial scales such as seasonal migration or dispersal are also important. To determine the relative importance of these processes, we evaluated hypothesized relationships between the probability of occupancy in wetlands by two amphibians [wood frogs (Lithobates sylvaticus) and boreal chorus frogs (Pseudacris maculata)] and attributes of the landscape measured at three spatial scales in Rocky Mountain National Park, Colorado. We used cost-based buffers and least-cost distances to derive estimates of landscape attributes that may affect occupancy patterns from the broader spatial scales. The most highly ranked models provide strong support for a positive relationship between occupancy by breeding wood frogs and the amount of streamside habitat adjacent to a wetland. The model selection results for boreal chorus frogs are highly uncertain, though several of the most highly ranked models indicate a positive association between occupancy and the number of neighboring, occupied wetlands. We found little evidence that occupancy of either species was correlated with local-scale attributes measured at the scale of individual wetlands, suggesting that processes operating at broader scales may be more important in influencing occupancy patterns in amphibian populations.

Colorado↗

USGS2018

Water column nutrient processing rates in rivermouths of Green Bay (Lake Michigan)

Understanding the quantity and form of nutrient loads to large lakes is necessary to understand controls over primary production, phytoplankton community composition and the production of phytotoxins. Nutrient loading estimates to large lakes are primarily made at stream gages that are deliberately placed outside the direct influence of lake processes, but these estimates cannot take into account processes that occur in the biologically active river-to-lake transition zone. These transition zones (rivermouths) sometimes alter nutrient concentrations and ratios substantially, but few studies have directly measured processing rates of nutrients within rivermouths. From April through September 2016, we conducted 23 water column incubation experiments to measure nutrient loss rates in four rivermouths. First order loss rates ( K ) for inorganic nitrogen (N) and phosphorus (P) indicated greater loss in light than in dark treatments, suggesting primary production increases N and P removal. Variability in K was high across both time and space, and the measured environmental parameters did not appear to be strongly associated with this variation in K for most N and P forms. If the measured K values and water residence times are accurate, then between 0 and 99% of the inorganic P and nitrates entering the rivermouth would be lost (i.e., converted to organic or particulate P). In late summer, Fox River discharge is low and residence times are usually long, which allow for much higher proportional nutrient removal in the water column. Water column processing appears to be capable of transforming large quantities of dissolved N and P to particulate forms and thus altering its transport and presumably its bioavailability.

Green Bay, Lake Michigan↗

USGS2011

Wildfire impacts on the processes that generate debris flows in burned watersheds

E very year, and in many countries worldwide, wildfires cause significant damage and economic losses due to both the direct effects of the fires and the subsequent accelerated runoff, erosion, and debris flow. Wildfires can have profound effects on the hydrologic response of watersheds by changing the infiltration characteristics and erodibility of the soil, which leads to decreased rainfall infiltration, significantly increased overland flow and runoff in channels, and movement of soil. Debris-flow activity is among the most destructive consequences of these changes, often causing extensive damage to human infrastructure. Data from the Mediterranean area and Western United States of America help identify the primary processes that result in debris flows in recently burned areas. Two primary processes for the initiation of fire-related debris flows have been so far identified: (1) runoff-dominated erosion by surface overland flow; and (2) infiltration-triggered failure and mobilization of a discrete landslide mass. The first process is frequently documented immediately post-fire and leads to the generation of debris flows through progressive bulking of storm runoff with sediment eroded from the hillslopes and channels. As sediment is incorporated into water, runoff can convert to debris flow. The conversion to debris flow may be observed at a position within a drainage network that appears to be controlled by threshold values of upslope contributing area and its gradient. At these locations, sufficient eroded material has been incorporated, relative to the volume of contributing surface runoff, to generate debris flows. Debris flows have also been generated from burned basins in response to increased runoff by water cascading over a steep, bedrock cliff, and incorporating material from readily erodible colluvium or channel bed. Post-fire debris flows have also been generated by infiltration-triggered landslide failures which then mobilize into debris flows. However, only 12% of documented cases exhibited this process. When they do occur, the landslide failures range in thickness from a few tens of centimeters to more than 6 m, and generally involve the soil and colluvium-mantled hillslopes. Surficial landslide failures in burned areas most frequently occur in response to prolonged periods of storm rainfall, or prolonged rainfall in combination with rapid snowmelt or rain-on-snow events.

Natural Hazards↗

USGS1973

Mariner 9-Image processing and products

The purpose of this paper is to describe the system for the display, processing, and production of image-data products created to support the Mariner 9 Television Experiment. Of necessity, the system was large in order to respond to the needs of a large team of scientists with a broad scope of experimental objectives. The desire to generate processed data products as rapidly as possible to take advantage of adaptive planning during the mission, coupled with the complexities introduced by the nature of the vidicon camera, greatly increased the scale of the ground-image processing effort. This paper describes the systems that carried out the processes and delivered the products necessary for real-time and near-real-time analyses. References are made to the computer algorithms used for the, different levels of decalibration and analysis.

Icarus↗

USGS1989

Glacimarine sedimentary processes, facies and morphology of the south-southeast Alaska shelf and fjords

High precipitation from Gulf of Alaska air masses can locally reach up to 800 cm a −1 . This precipitation on tectonically active mountains creates cool-temperate glaciation with extremely active erosion and continuously renewed resources. High basal debris loads up to 1.5 m thick of pure debris and rapid glacial flow, which can be more than 3000 m a −1 , combine to produce large volumes of siliciclastic glacimarine sediment at some of the highest sediment accumulation rates on record. At tidewater fronts of valley glaciers, sediment accumulation rates can be over 13 m a −1 and deltas commonly grow at about 10 6 m 3 a −1 . Major processes influencing glacimarine sedimentation are glacial transport and glacier-contact deposition, meltwater (subaerial and submarine) and runoff transport and deposition, iceberg rafting and gouging, sea-ice transport, wave action and storm reworking, tidal transport and deposition, alongshelf transport, sliding and slumping and gravity flows, eolian transport, and biogenic production and reworking. Processes are similar in both shelf and fjord settings; however, different intensities of some processes create different facies associations and geometries. The tectonoclimatic regime also controls morphology because bedrock structure is modified by glacial action. Major glacimarine depositional systems are all siliciclastic. They are subglacial, marginal-morainal bank and submarine outwash, and proglacial/paraglacial-fluvial/deltaic, beach, tidal flat/estuary, glacial fjord, marine outwash fjord and continental shelf. Future research should include study of long cores with extensive dating and more seismic surveys to evaluate areal and temporal extent of glacial facies and glaciation; time-series oceanographic data, sidescan sonar surveys and submersible dives to evaluate modern processes; biogenic diversity and production to evaluate paleoecological, paleobiogeographic and biofacies analysis; and detailed comparisons of exposed older rock of the Yakataga Formation to evaluate how glacial style has evolved over 6.3 Ma.

Marine Geology↗

USGS1996

Fluvial process and the establishment of bottomland trees

The effects of river regulation on bottomland tree communities in western North America have generated substantial concern because of the important habitat and aesthetic values of these communities. Consideration of such effects in water management decisions has been hampered by the apparent variability of responses of bottomland tree communities to flow alteration. When the relation between streamflow and tree establishment is placed in a geomorphic context, however, much of that variability is explained, and prediction of changes in the tree community is improved. The relation between streamflow and establishment of bottomland trees is conditioned by the dominant fluvial process or processes acting along a stream. For successful establishment, cottonwoods, poplars, and willows require bare, moist surfaces protected from disturbance. Channel narrowing, channel meandering, and flood deposition promote different spatial and temporal patterns of establishment. During channel narrowing, the site requirements are met on portions of the bed abandoned by the stream, and establishment is associated with a period of low flow lasting one to several years. During channel meandering, the requirements are met on point bars following moderate or higher peak flows. Following flood deposition, the requirements are met on flood deposits ;high above the channel bed. Flood deposition can occur along most streams, but where a channel is constrained by a narrow valley, this process may be the only mechanism that can produce a bare, moist surface high enough to be safe from future disturbance. Because of differences in local bedrock, tributary influence, or geologic history, two nearby reaches of the same stream may be dominated by different fluvial processes and have different spatial and temporal patterns of trees. We illustrate this phenomenon with examples from forests of plains cottonwood ( Populus deltoides ssp. monilifera ) along meandering and constrained reaches of the Missouri River in Montana.

Geomorphology↗

USGS2011

Hydrogeochemical processes governing the origin, transport and fate of major and trace elements from mine wastes and mineralized rock to surface waters

The formation of acid mine drainage from metals extraction or natural acid rock drainage and its mixing with surface waters is a complex process that depends on petrology and mineralogy, structural geology, geomorphology, surface-water hydrology, hydrogeology, climatology, microbiology, chemistry, and mining and mineral processing history. The concentrations of metals, metalloids, acidity, alkalinity, Cl - , F - and SO 4 2- found in receiving streams, rivers, and lakes are affected by all of these factors and their interactions. Remediation of mine sites is an engineering concern but to design a remediation plan without understanding the hydrogeochemical processes of contaminant mobilization can lead to ineffective and excessively costly remediation. Furthermore, remediation needs a goal commensurate with natural background conditions rather than water-quality standards that might bear little relation to conditions of a highly mineralized terrain. This paper reviews hydrogeochemical generalizations, primarily from US Geological Survey research, that enhance our understanding of the origin, transport, and fate of contaminants released from mined and mineralized areas. Mobility of potential or actual contaminants from mining and mineral processing activities depends on (1) occurrence : is the mineral source of the contaminant actually present? (2) abundance : is the mineral present in sufficient quantity to make a difference? (3) reactivity : what are the energetics, rates, and mechanisms of sorption and mineral dissolution and precipitation relative to the flow rate of the water? and (4) hydrology : what are the main flow paths for contaminated water? Estimates of relative proportions of minerals dissolved and precipitated can be made with mass-balance calculations if minerals and water compositions along a flow path are known. Combined with discharge, these mass-balance estimates quantify the actual weathering rate of pyrite mineralization in the environment and compare reasonably well with laboratory rates of pyrite oxidation except when large quantities of soluble salts and evaporated mine waters have accumulated underground. Quantitative mineralogy with trace-element compositions can substantially improve the identification of source minerals for specific trace elements through mass balances. Post-dissolution sorption and precipitation (attenuation) reactions depend on the chemical behavior of each element, solution composition and pH, aqueous speciation, temperature, and contact-time with mineral surfaces. For example, little metal attenuation occurs in waters of low pH (<3.5) and metals tend to maintain element ratios indicative of the main mineral or group of minerals from which they dissolved, except Fe, SiO 2 , and redox-sensitive oxyanions (As, Sb, Se, Mo, Cr, V). Once dissolved, metal and metalloid concentrations are strongly affected by redox conditions and pH. Iron is the most reactive because it is rapidly oxidized by bacteria and archaea and Fe(III) hydrolyzes and precipitates at low pH (1–3) which is related directly to its first hydrolysis constant, pK 1 = 2.2. Several insoluble sulfate minerals precipitate at low pH including anglesite, barite, jarosite, alunite and basaluminite. Aluminum hydrolyzes near pH 5 (pK 1 = 5.0) and provides buffering and removal of Al by mineral precipitation from pH 4–5.5. Dissolved sulfate behaves conservatively because the amount removed from solution by precipitation is usually too small relative to the high concentrations in the water column and relative to the flow rate of the water.

Applied Geochemistry↗

USGS2012

Hydrozincite seasonal precipitation at Naracauli (Sardinia – Italy): Hydrochemical factors and morphological features of the biomineralization process

Hydrozincite [Zn 5 (CO 3 ) 2 (OH) 6 ] precipitation from Naracauli waters (SW Sardinia) is, among other things, promoted by a microbial community made up of a filamentous cyanobacterium ( Scytonema sp.) and a microalgae ( Chlorella sp.). Hydrozincite bioprecipitation is responsible for the natural removal of harmful metals, especially Zn, from the stream waters. Thus, hydrozincite could be used to attenuate metal pollution in mining waters. Information on environmental conditions which promote the biomineralization process is fundamental for the development of remediation strategies. This paper aims to investigate the variables controlling the biomineralization process, and seasonal variation of the hydrochemical factors that affect hydrozincite precipitation. Hydrozincite morphology varies depending on the environmental conditions. Specifically, changes were observed between samples collected in late spring and samples collected in summer, and among samples precipitated under different water flow conditions. According to field observations, correlated with speciation and equilibrium calculation, the maximum intensity in hydrozincite precipitation occurs in the late spring during rainy years. In these conditions, the hydraulic regime in the stream reaches stationary conditions, and saturation index values with respect to hydrozincite reach their highest values. Concomitantly, the Zn 2+ / CO 3 2 - "> CO32- molar ratio reaches values close to 1, indicating that kinetic processes have a role on the hydrozincite biomineralization process.

Sardinia↗

USGS2006

Sorption processes affecting arsenic solubility in oxidized surface sediments from Tulare Lake Bed, California

Elevated concentrations of arsenic (As) in shallow groundwater in Tulare Basin pose an environmental risk because of the carcinogenic properties of As and the potential for its migration to deep aquifers that could serve as a future drinking water source. Adsorption and desorption are hypothesized to be the major processes controlling As solubility in oxidized surface sediments where arsenate [As(V)] is dominant. This study examined the relationship between sorption processes and arsenic solubility in shallow sediments from the dry Tulare Lake bed by determining sorption isotherms, pH effect on solubility, and desorption-readsorption behavior (hysteresis), and by using a surface complexation model to describe sorption. The sediments showed a high capacity to adsorb As(V). Estimates of the maximum adsorption capacity were 92 mg As kg- 1 at pH 7.5 and 70 mg As kg- 1 at pH 8.5 obtained using the Langmuir adsorption isotherm. Soluble arsenic [> 97% As(V)] did not increase dramatically until above pH 10. In the native pH range (7.5-8.5), soluble As concentrations were close to the lowest, indicating that As was strongly retained on the sediment. A surface complexation model, the constant capacitance model, was able to provide a simultaneous fit to both adsorption isotherms (pH 7.5 and 8.5) and the adsorption envelope (pH effect on soluble As), although the data ranges are one order of magnitude different. A hysteresis phenomenon between As adsorbed on the sediment and As in solution phase was observed in the desorption-readsorption processes and differs from conventional hysteresis observed in adsorption-desorption processes. The cause is most likely due to modification of adsorbent surfaces in sediment samples upon extensive extractions (or desorption). The significance of the hysteresis phenomenon in affecting As solubility and mobility may be better understood by further microscopic studies of As interaction mechanisms with sediments subjected to extensive leaching in natural environments. ?? 2006 Elsevier B.V. All rights reserved.

Chemical Geology↗

USGS2021

What's left before participatory modeling can fully support real-world environmental planning processes: A case study review

In environmental participatory modeling (PM), both computer and non-computer-based modeling techniques are used to aid participatory problem description, solution, and decision-making actions in environmental contexts. Although many PM case studies have been published, few efforts have sought to systematically describe and understand dominant PM processes or establish best practices for PM. As a first step, we have reviewed a random sample of environmental PM case study articles (n = 60) using a novel PM process evaluation instrument. We found that significant work likely remains for PM to fully support participatory and integrated planning processes. While PM reports systematically address knowledge integration and learning, they often neglect the facilitation of a multi-value perspective within a democratic process , and the integration across organizations within a governance system. If not reported, we suspect these aspects are also neglected in practice. We conclude with key research and practice issues for improving PM as an approach for real-world participatory planning and governance.

Environmental Modelling & Software↗

USGS2008

Processes of coastal bluff erosion in weakly lithified sands, Pacifica, California, USA

Coastal bluff erosion and landsliding are currently the major geomorphic processes sculpting much of the marine terrace dominated coastline of northern California. In this study, we identify the spatial and temporal processes responsible for erosion and landsliding in an area of weakly lithified sand coastal bluffs located south of San Francisco, California. Using the results of a five year observational study consisting of site visits, terrestrial lidar scanning, and development of empirical failure indices, we identify the lithologic and process controls that determine the failure mechanism and mode for coastal bluff retreat in this region and present concise descriptions of each process. Bluffs composed of weakly cemented sands (unconfined compressive strength - UCS between 5 and 30??kPa) fail principally due to oversteepening by wave action with maximum slope inclinations on the order of 65 at incipient failure. Periods of significant wave action were identified on the basis of an empirical wave run-up equation, predicting failure when wave run-up exceeds the seasonal average value and the bluff toe elevation. The empirical relationship was verified through recorded observations of failures. Bluffs composed of moderately cemented sands (UCS up to 400??kPa) fail due to precipitation-induced groundwater seepage, which leads to tensile strength reduction and fracture. An empirical rainfall threshold was also developed to predict failure on the basis of a 48-hour cumulative precipitation index but was found to be dependent on a time delay in groundwater seepage in some cases.

Geomorphology↗

USGS2014

Conservation Action Planning: Lessons learned from the St. Marys River watershed biodiversity conservation planning process

Conservation Action Planning (CAP) is an adaptive management planning process refined by The Nature Conservancy (TNC) and embraced worldwide as the Open Standards for the Practice of Conservation. The CAP process facilitates open, multi-institutional collaboration on a common conservation agenda through organized actions and quantified results. While specifically designed for conservation efforts, the framework is adaptable and flexible to multiple scales and can be used for any collaborative planning effort. The CAP framework addresses inception; design and development of goals, measures, and strategies; and plan implementation and evaluation. The specific components of the CAP include defining the project scope and conservation targets; assessing the ecological viability; ascertaining threats and surrounding situation; identifying opportunities and designing strategies for action; and implementing actions and monitoring results. In 2007, TNC and a multidisciplinary graduate student team from the University of Michigan's School of Natural Resources and Environment initiated a CAP for the St. Marys River, the connecting channel between Lake Superior and Lake Huron, and its local watershed. The students not only gained experience in conservation planning, but also learned lessons that notably benefited the CAP process and were valuable for any successful collaborative effort—a dedicated core team improved product quality, accelerated the timeline, and provided necessary support for ongoing efforts; an academic approach in preparation for engagement in the planning process brought applicable scientific research to the forefront, enhanced workshop facilitation, and improved stakeholder participation; and early and continuous interactions with regional stakeholders improved cooperation and built a supportive network for collaboration.

Michigan, Ontario↗

USGS2016

An overview of current applications, challenges, and future trends in distributed process-based models in hydrology

Process-based hydrological models have a long history dating back to the 1960s. Criticized by some as over-parameterized, overly complex, and difficult to use, a more nuanced view is that these tools are necessary in many situations and, in a certain class of problems, they are the most appropriate type of hydrological model. This is especially the case in situations where knowledge of flow paths or distributed state variables and/or preservation of physical constraints is important. Examples of this include: spatiotemporal variability of soil moisture, groundwater flow and runoff generation, sediment and contaminant transport, or when feedbacks among various Earth’s system processes or understanding the impacts of climate non-stationarity are of primary concern. These are situations where process-based models excel and other models are unverifiable. This article presents this pragmatic view in the context of existing literature to justify the approach where applicable and necessary. We review how improvements in data availability, computational resources and algorithms have made detailed hydrological simulations a reality. Avenues for the future of process-based hydrological models are presented suggesting their use as virtual laboratories, for design purposes, and with a powerful treatment of uncertainty.

Journal of Hydrology↗