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USGS2022

Partial observability and management of ecological systems

The actual state of ecological systems is rarely known with certainty, but management actions must often be taken regardless of imperfect measurement (partial observability). Because of the difficulties in accounting for partial observability, it is usually treated in an ad hoc fashion, or simply ignored altogether. Yet incorporating partial observability into decision processes lends a realism that has the potential to improve ecological outcomes significantly. We review frameworks for dealing with partial observability, focusing specifically on dynamic ecological systems with Markovian transitions, i.e., transitions among system states that are influenced by the current system state and management action over time. Fully observable states are represented in an observable Markov decision process (MDP), whereas obscure or hidden states are represented in a partially observable process (POMDP). POMDPs can be seen as a natural extension of observable MDPs. Management under partial observability generalizes the situation for complete observability, by recognizing uncertainty about the system's state and incorporating sequential observations associated with, but not the same as, the states themselves. Decisions that otherwise would depend on the actual state must be based instead on state probability distributions (“belief states”). Partial observability requires adaptation of the entire decision process, including the use of belief states and Bayesian updates, valuation that includes expectations over observations, and optimal strategy that identifies actions for belief states over a continuous belief space. We compare MDPs and POMDPs and highlight POMDP applications to some common ecological problems. We clarify the structure and operations, approaches for finding solutions, and analytic challenges of POMDPs for practicing ecologists. Both observable and partially observable MDPs can use an inductive approach to identify optimal strategies and values, with a considerable increase in mathematical complexity with POMDPs. Better understanding of POMDPs can help decision makers manage imperfectly measured ecological systems more effectively.

Ecology and Evolution↗

USGS1977

Current oil and gas production from North American Upper Cretaceous chalks

Production of oil and natural gas from North American chalks has increased significantly during the past five years, spurred by the prolific production from North Sea chalks, as well as by higher prices and improved production technology. Chalk reservoirs have been discovered in the Gulf Coast in the Austin Group, Saratoga and Annona Chalks, Ozan Formation, Selma Group, Monroe gas rock (an informal unit of Navarro age), and other Upper Cretaceous units. In the Western Interior, production has been obtained from the Cretaceous Niobrara and Greenhorn Formations. Significant, though subcommercial, discoveries of natural gas and gas condensate also have been made in the Upper Cretaceous Wyandot Formation on the Scotian Shelf of eastern Canada. All North American chalk units share a similar depositional and diagenetic history. The chalks consist primarily of whole and fragmented coccoliths with subordinate planktonic and benthonic Foraminifera, inoceramid prisms, oysters, and other skeletal grains. Most have between 10 and 35 percent HCl-insoluble residue, predominantly clay. Deposition was principally below wave base in tens to hundreds of meters of water. The diagenetic history of a chalk is critical in determining its reservoir potential. All chalk has a stable composition (low-Mg calcite) and very high primary porosity. With subsequent burial, mechanical and chemical (solution-transfer) compaction can reduce or completely eliminate pore space. The degree of loss of primary porosity in chalk sections is normally a direct function of the maximum depth to which it has been buried. Pore-water chemistry, pore-fluid pressures, and tectonic stresses also influence rates of cementation. Oil or gas reservoirs of North American chalk fall into three main groups: 1. Areas with thin overburden and significant primary porosity retention (for example, Niobrara Formation of Kansas and eastern Colorado). 2. Areas with thicker overburden but considerable fracturing. Here primary porosity has been largely lost but secondary (fracture) porosity provides some storage capacity and greatly improves permeability (for example, Austin Group of the Pearsall field, Texas). 3. Areas with thick overburden in which marine pore fluids have been retained, or where hydrocarbons (including biogenically generated methane) were introduced early in the diagenetic history. In these settings, primary porosity is reduced to a lesser degree than in group two, and adequate reservoir properties can be maintained to depths approaching 2,000 m (6,600 ft) (for example, Scotian Shelf of Canada). Continued small-scale oil and gas discoveries can be expected from these types of reservoirs in North America. The prolific production of oil and gas from North Sea chalk reservoirs will not be matched in North America unless deeply buried, overpressured chalks can be located. It is the early formation of overpressures and (or) early oil input into North Sea chalks that have preserved porosities as high as 40 percent at 3,000- to 3,500-m (9,800- to 11,500-ft) depths and provided the outstanding reservoir capacity of those chalks.

Circular↗

USGS2006

Multiphase, multicomponent parameter estimation for liquid and vapor fluxes in deep arid systems using hydrologic data and natural environmental tracers

Multiphase, multicomponent numerical models of long-term unsaturated-zone liquid and vapor movement were created for a thick alluvial basin at the Nevada Test Site to predict present-day liquid and vapor fluxes. The numerical models are based on recently developed conceptual models of unsaturated-zone moisture movement in thick alluvium that explain present-day water potential and tracer profiles in terms of major climate and vegetation transitions that have occurred during the past 10 000 yr or more. The numerical models were calibrated using borehole hydrologic and environmental tracer data available from a low-level radioactive waste management site located in a former nuclear weapons testing area. The environmental tracer data used in the model calibration includes tracers that migrate in both the liquid and vapor phases (δD, δ 18 O) and tracers that migrate solely as dissolved solutes (Cl), thus enabling the estimation of some gas-phase as well as liquid-phase transport parameters. Parameter uncertainties and correlations identified during model calibration were used to generate parameter combinations for a set of Monte Carlo simulations to more fully characterize the uncertainty in liquid and vapor fluxes. The calculated background liquid and vapor fluxes decrease as the estimated time since the transition to the present-day arid climate increases. However, on the whole, the estimated fluxes display relatively little variability because correlations among parameters tend to create parameter sets for which changes in some parameters offset the effects of others in the set. Independent estimates on the timing since the climate transition established from packrat midden data were essential for constraining the model calibration results. The study demonstrates the utility of environmental tracer data in developing numerical models of liquid- and gas-phase moisture movement and the importance of considering parameter correlations when using Monte Carlo analysis to characterize the uncertainty in moisture fluxes.

Vadose Zone Journal↗

USGS2015

Beyond temperature: Clumped isotope signatures in dissolved inorganic carbon species and the influence of solution chemistry on carbonate mineral composition

“Clumped-isotope” thermometry is an emerging tool to probe the temperature history of surface and subsurface environments based on measurements of the proportion of 13 C and 18 O isotopes bound to each other within carbonate minerals in 13 C 18 O 16 O 2 2- groups (heavy isotope “clumps”). Although most clumped isotope geothermometry implicitly presumes carbonate crystals have attained lattice equilibrium (i.e., thermodynamic equilibrium for a mineral, which is independent of solution chemistry), several factors other than temperature, including dissolved inorganic carbon (DIC) speciation may influence mineral isotopic signatures. Therefore we used a combination of approaches to understand the potential influence of different variables on the clumped isotope (and oxygen isotope) composition of minerals. We conducted witherite precipitation experiments at a single temperature and at varied pH to empirically determine 13 C- 18 O bond ordering (Δ 47 ) and δ 18 O of CO 3 2- and HCO 3 - molecules at a 25 °C equilibrium. Ab initio cluster models based on density functional theory were used to predict equilibrium 13 C- 18 O bond abundances and δ 18 O of different DIC species and minerals as a function of temperature. Experiments and theory indicate Δ 47 and δ 18 O compositions of CO 3 2- and HCO 3- ions are significantly different from each other. Experiments constrain the Δ 47- δ 18 O slope for a pH effect (0.011 ± 0.001; 12 ⩾ pH ⩾ 7). Rapidly-growing temperate corals exhibit disequilibrium mineral isotopic signatures with a Δ 47- δ 18 O slope of 0.011 ± 0.003, consistent with a pH effect. Our theoretical calculations for carbonate minerals indicate equilibrium lattice calcite values for Δ 47 and δ 18 O are intermediate between HCO 3 − and CO 3 2− . We analyzed synthetic calcites grown at temperatures ranging from 0.5 to 50 °C with and without the enzyme carbonic anhydrase present. This enzyme catalyzes oxygen isotopic exchange between DIC species and is present in many natural systems. The two types of experiments yielded statistically indistinguishable results, and these measurements yield a calibration that overlaps with our theoretical predictions for calcite at equilibrium. The slow-growing Devils Hole calcite exhibits Δ 47 and δ 18 O values consistent with lattice equilibrium. Factors influencing DIC speciation (pH, salinity) and the timescale for DIC equilibration, as well as reactions at the mineral–solution interface, have the potential to influence clumped-isotope signatures and the δ 18 O of carbonate minerals. In fast-growing carbonate minerals, solution chemistry may be an important factor, particularly over extremes of pH and salinity. If a crystal grows too rapidly to reach an internal equilibrium (i.e., achieve the value for the temperature-dependent mineral lattice equilibrium), it may record the clumped-isotope signature of a DIC species (e.g., the temperature-dependent equilibrium of HCO 3 − ) or a mixture of DIC species, and hence record a disequilibrium mineral composition. For extremely slow-growing crystals, and for rapidly-grown samples grown at a pH where HCO 3 - dominates the DIC pool at equilibrium, effects of solution chemistry are likely to be relatively small or negligible. In summary, growth environment, solution chemistry, surface equilibria, and precipitation rate may all play a role in dictating whether a crystal achieves equilibrium or disequilibrium clumped-isotope signatures.

Geochimica et Cosmochimica Acta↗

USGS2023

U.S. Geological Survey Rocky Mountain Region 2022 science exchange, showcasing interdisciplinary and state-of-the-art USGS science

Introduction The Rocky Mountains and the Colorado River Basin in the Western United States represent complex, interconnected systems that sustain a number of species, including tens of millions of humans. These systems face several challenges, including worsening drought, altered wildfire regimes, climate change, and the spread of invasive species. These factors can exacerbate one another, further contributing to habitat loss and affecting species of conservation concern. Characterizing and managing these challenges require interdisciplinary communities of scientists to develop information and decision-support tools that can inform holistic land and water management solutions. The U.S. Geological Survey (USGS) Rocky Mountain Region 2022 Science Exchange focused on the use of interdisciplinary and state-of-the-art science being conducted by USGS scientists in the region to address these complex problems. The USGS Rocky Mountain Regional Office organized its first Science Exchange in 2017 to share scientific information between leaders and early career scientists throughout the region. Science Exchanges held in 2018 and 2020 focused on drought science relevant to the region and the Earth Monitoring, Analyses, and Prediction (EarthMAP) concept, which is designed to facilitate interdisciplinary, timely, and actionable science related to drought in the Colorado River Basin and other areas. Based on the emerging need for more holistic approaches to address increasingly complex natural resource issues that affect society, the Region hosted a virtual fourth Science Exchange for three days in April 2022. This event focused on barriers and bridges to interdisciplinary science and highlighted studies from the Region to inspire collaboration across disciplines. Presentations described recent and ongoing research that applied collaborative and state-of-the-art methods to address problems in the fields of geology, hydrology, ecology, and natural hazards. Science collaboration and outreach to all levels of stakeholders are vital elements needed for providing timely and actionable data, interpretations, analytical tools, and products. These presentations led to active online chats and panel discussions and showcased interdisciplinary science and advanced methods that may inform and lead to more effective, holistic management decisions as the Western United States adapts to ongoing and future changes.

Fact Sheet↗

USGS2025

Widespread occurrence of former anhydrite phenocrysts in Laramide-age magmas related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, USA

Reports of magmatic anhydrite are relatively rare, with only ~30 occurrences documented worldwide so far. However, magmatic anhydrite saturation is difficult to recognize because anhydrite decomposes rapidly in near-surface environments. In most cases, only anhydrite inclusions shielded within other phenocryst phases were able to survive. Alternatively, since anhydrite phenocrysts preserved in fresh volcanic rocks are characteristically intergrown with apatite phenocrysts, the former presence of anhydrite phenocrysts can be recognized based on the occurrence of lath-shaped cavities that show a strong spatial association with apatite phenocrysts. These cavities can be either empty or filled with low-temperature, secondary minerals such as zeolites, carbonates, or microcrystalline silica. A systematic search for the occurrence of such cavities, combined with optical and Raman-spectroscopic identification of anhydrite inclusions preserved within apatite, hornblende and quartz phenocrysts, demonstrates that most of the Laramide-age magmas associated with the Santa Rita and Hanover-Fierro porphyry-skarn Cu (Zn, Mo, Au, Pb) deposits were saturated in magmatic anhydrite. The anhydrite typically coexisted with monosulfide solid solution (MSS), suggesting oxygen fugacities of ~2.0±0.5 log units above the fayalite-magnetite-quartz buffer. The magmas range from andesitic to rhyodacitic in composition, and from shortly pre-mineralization (~61 Ma) to shortly post-mineralization (~57 Ma) in age. In three samples with particularly well-recognizable former anhydrite phenocrysts, their modal abundance could be quantified based on high-resolution scans of polished hand specimens. The observed modal anhydrite abundances of 0.63–1.8 vol% translate into minimum magma sulfur contents of 0.20–0.56 wt% S. The highest sulfur content of 0.56 wt% S is difficult to reconcile with available anhydrite solubility models, but it could be reproduced in an anhydrite solubility experiment performed at 950 °C and 1.15 GPa on a natural latite containing 13.1 wt% dissolved H2O. The sample with the second-highest sulfur content of 0.26 wt% S requires ~10 wt% H2O in the silicate melt, and, consequently, a minimum pressure of ~0.5 GPa. Taken together, the results suggest that the magmas of the Central Mining District were extremely hydrous and thus originated from great depth. Indeed, their major element compositions and reconstructed H2O and S contents agree well with experimentally observed and numerically predicted compositions of residual silicate melts after 50–70 wt% crystallization of ordinary arc basalts at high pressure and high oxygen fugacities.

New Mexico↗

USGS2015

PHT3D-UZF: A reactive transport model for variably-saturated porous media

A modified version of the MODFLOW/MT3DMS-based reactive transport model PHT3D was developed to extend current reactive transport capabilities to the variably-saturated component of the subsurface system and incorporate diffusive reactive transport of gaseous species. Referred to as PHT3D-UZF, this code incorporates flux terms calculated by MODFLOW's unsaturated-zone flow (UZF1) package. A volume-averaged approach similar to the method used in UZF-MT3DMS was adopted. The PHREEQC-based computation of chemical processes within PHT3D-UZF in combination with the analytical solution method of UZF1 allows for comprehensive reactive transport investigations (i.e., biogeochemical transformations) that jointly involve saturated and unsaturated zone processes. Intended for regional-scale applications, UZF1 simulates downward-only flux within the unsaturated zone. The model was tested by comparing simulation results with those of existing numerical models. The comparison was performed for several benchmark problems that cover a range of important hydrological and reactive transport processes. A 2D simulation scenario was defined to illustrate the geochemical evolution following dewatering in a sandy acid sulfate soil environment. Other potential applications include the simulation of biogeochemical processes in variably-saturated systems that track the transport and fate of agricultural pollutants, nutrients, natural and xenobiotic organic compounds and micropollutants such as pharmaceuticals, as well as the evolution of isotope patterns.

Ground Water↗

USGS2017

Building translational ecology communities of practice: insights from the field

Translational ecology (TE) prioritizes the understanding of social systems and decision contexts in order to address complex natural resource management issues. Although many practitioners in applied fields employ translational tactics, the body of literature addressing such approaches is limited. We present several case studies illustrating the principles of TE and the diversity of its applications. We anticipate that these examples will help others develop scientific products that decision makers can use “off the shelf” when solving critical ecological and social challenges. Our collective experience suggests that research of such immediate utility is rare. Long‐term commitment to working directly with partners to develop and reach shared goals is central to successful translation. The examples discussed here highlight the benefits of translational processes, including actionable scientific results, more informed policy making, increased investment in science‐driven solutions, and inspiration for partnerships. We aim to facilitate future TE‐based projects and build momentum for growing this community of practice.

Frontiers in Ecology and the Environment↗

USGS2002

Determining mineral weathering rates based on solid and solute weathering gradients and velocities: Application to biotite weathering in saprolites

Chemical weathering gradients are defined by the changes in the measured elemental concentrations in solids and pore waters with depth in soils and regoliths. An increase in the mineral weathering rate increases the change in these concentrations with depth while increases in the weathering velocity decrease the change. The solid-state weathering velocity is the rate at which the weathering front propagates through the regolith and the solute weathering velocity is equivalent to the rate of pore water infiltration. These relationships provide a unifying approach to calculating both solid and solute weathering rates from the respective ratios of the weathering velocities and gradients. Contemporary weathering rates based on solute residence times can be directly compared to long-term past weathering based on changes in regolith composition. Both rates incorporate identical parameters describing mineral abundance, stoichiometry, and surface area. Weathering gradients were used to calculate biotite weathering rates in saprolitic regoliths in the Piedmont of Northern Georgia, USA and in Luquillo Mountains of Puerto Rico. Solid-state weathering gradients for Mg and K at Panola produced reaction rates of 3 to 6 x 10-17 mol m-2 s-1 for biotite. Faster weathering rates of 1.8 to 3.6 ?? 10-16 mol m-2 s-1 are calculated based on Mg and K pore water gradients in the Rio Icacos regolith. The relative rates are in agreement with a warmer and wetter tropical climate in Puerto Rico. Both natural rates are three to six orders of magnitude slower than reported experimental rates of biotite weathering. ?? 2002 Elsevier Science B.V. All rights reserved.

Chemical Geology↗

USGS2006

Usoi dam wave overtopping and flood routing in the Bartang and Panj Rivers, Tajikistan

The Usoi dam was created in the winter of 1911 after an enormous seismogenic rock slide completely blocked the valley of the Bartang River in the Pamir Mountains of southeastern Tajikistan. At present the dam impounds 17 million cubic meters of water in Lake Sarez. Flood volume and discharge estimates were made for several landslide generated floods that could overtop the dam. For landslide volumes of 200, 500, and 1,000 million cubic meters, estimated overtopping flood volumes were 2, 22, and 87 million cubic meters of water, respectively. Estimated peak discharge at the dam for these three flood scenarios were 57,000, 490,000, and 1,580,000 m3/s, based on triangular hydrographs of 70-, 90-, and 110-s durations, respectively. Flood-routing simulations were made for the three landslide-induced overtopping floods over a 530-km reach of the Bartang and Panj Rivers below the Usoi dam. A one-dimensional flow model using a Riemann numerical solution technique was selected for the analysis. For the 87 million cubic meter volume overtopping flood scenario, the peak flows were approximately 1, 100, 800, and 550 m3/s at locations 50, 100, and 150 km downstream of the dam respectively. ?? Springer 2006.

Natural Hazards↗

USGS2005

Design and analysis of a natural-gradient ground-water tracer test in a freshwater tidal wetland, West Branch Canal Creek, Aberdeen Proving Ground, Maryland

A natural-gradient ground-water tracer test was designed and conducted in a tidal freshwater wetland at West Branch Canal Creek, Aberdeen Proving Ground, Maryland. The objectives of the test were to characterize solute transport at the site, obtain data to more accurately determine the ground-water velocity in the upper wetland sediments, and to compare a conservative, ionic tracer (bromide) to a volatile tracer (sulfur hexafluoride) to ascertain whether volatilization could be an important process in attenuating volatile organic compounds in the ground water. The tracer test was conducted within the upper peat unit of a layer of wetland sediments that also includes a lower clayey unit; the combined layer overlies an aquifer. The area selected for the test was thought to have an above-average rate of ground-water discharge based on ground-water head distributions and near-surface detections of volatile organic compounds measured in previous studies. Because ground-water velocities in the wetland sediments were expected to be slow compared to the underlying aquifer, the test was designed to be conducted on a small scale. Ninety-seven ?-inch-diameter inverted-screen stainless-steel piezometers were installed in a cylindrical array within approximately 25 cubic feet (2.3 cubic meters) of wetland sediments, in an area with a vertically upward hydraulic gradient. Fluorescein dye was used to qualitatively evaluate the hydrologic integrity of the tracer array before the start of the tracer test, including verifying the absence of hydraulic short-circuiting due to nonnatural vertical conduits potentially created during piezometer installation. Bromide and sulfur hexafluoride tracers (0.139 liter of solution containing 100,000 milligrams per liter of bromide ion and 23.3 milligrams per liter of sulfur hexafluoride) were co-injected and monitored to generate a dataset that could be used to evaluate solute transport in three dimensions. Piezometers were sampled 2 to 15 times each, from July 1998 through September 1999, to assess background conditions and monitor tracer movement. During the test, 644 samples were analyzed for fluorescein, 617 samples were analyzed for bromide with an ion-selective electrode, 213 samples were analyzed for bromide with colorimetric methods, and 603 samples were analyzed for sulfur hexafluoride, including samples collected prior to tracer injection to determine background concentrations. Additional samples were analyzed for volatile organic compounds (96 samples) and methane (37 samples) to determine the distribution of these contaminants and the extent of methanogenic conditions within the tracer array; however, these data were not used for the analysis of the test. During the tracer test, the fluorescein dye, bromide, and sulfur hexafluoride were transported predominantly in the upward direction, although all three tracers also moved outward in all directions from the injection point, and it is likely that some tracer mass moved beyond the lateral edges of the array. An analysis of the tracer-test data was performed through the use of breakthrough curves and isoconcentration contour plots. Results show that movement of the fluorescein dye, a non-conservative tracer, was retarded compared to the other two tracers, likely as a result of sorption onto the wetland sediments. Suspected loss of tracer mass along the lateral edges of the array prevented a straightforward quantitative analysis of tracer transport and ground-water velocity from the bromide and sulfur-hexafluoride data. In addition, the initial density of the bromide/sulfur hexafluoride solution (calculated to be 1.097 grams per milli2 Ground-Water Tracer Test, West Branch Canal Creek, Aberdeen Proving Ground, MD liter) could have caused the solution to sink below the injection point before undergoing dilution and moving back up into the array. For these reasons, the data analysis in this report was performed largely through qualitative method

Scientific Investigations Report↗

USGS2024

When and where can coastal wetland restoration increase carbon sequestration as a natural climate solution?

Coastal wetlands are hotspots of carbon sequestration, and their conservation and restoration can help to mitigate climate change. However, there remains uncertainty on when and where coastal wetland restoration can most effectively act as a Natural Climate Solution (NCS). Here, we synthesize current understanding to illustrate the requirements for coastal wetland restoration to benefit climate, and discuss potential paths forward that address key uncertainties impeding implementation. To be effective as NCS, coastal wetland restoration projects will accrue climate cooling benefits that would not occur without management action (additionality), will be implementable (feasibility), and will persist over management-relevant timeframes (permanence). Several issues add uncertainty to understanding if these minimum requirements are met. First, coastal wetlands serve as both a landscape source and sink of carbon for other habitats, increasing uncertainty in additionality. Second, coastal wetlands can potentially migrate outside of project footprints as they respond to sea-level rise, increasing uncertainty in permanence. To address these first two issues, a system-wide approach may be necessary, rather than basing cooling benefits only on changes that occur within project boundaries. Third, the need for NCS to function over management-relevant decadal timescales means methane responses may be necessary to include in coastal wetland restoration planning and monitoring. Finally, there is uncertainty on how much data is required to justify restoration action. We summarize the minimum data required to make a decision on whether there is a net cooling benefit from a management action, noting that these data are more readily available than the data required to quantify the magnitude of cooling benefits for carbon crediting purposes. By reducing uncertainty, coastal wetland restoration can be implemented at the scale required to significantly contribute to addressing the current climate crisis.

Coastal Futures↗

USGS2011

Imaging using cross-hole seismoelectric tomography

We propose a new cross-hole imaging approach based on seismoelectric conversions associated with the transmission of seismic waves from seismic sources located in a borehole to receivers electrodes located in a second borehole. The seismoelectric seismic-to-electric problem is solved using Biot theory coupled with a generalized Ohm's law with an electrokinetic coupling term. The components of the displacement of the solid phase, the fluid pressure, and the electrical potential are solved using a finite element approach with PML boundary conditions for the seismic waves and boundary conditions mimicking an infinite material for the electrostatic problem. We have developed an inversion algorithm using the electrical disturbances recorded in the second borehole to localize the position of the heterogeneities responsible for the seismoelectric conversions. Because of the ill-posed nature of the inverse problem, regularization is used to constrain the solution at each time in the seismoelectric time window comprised between the time of the seismic shot and the time of the first arrival of the seismic waves in the second borehole. All the inverted volumetric current source densities are stacked to produce an image of the position of the heterogeneities between the two boreholes. Two simple synthetic case studies are presented to test this concept. The first case study corresponds to a vertical discontinuity between two homogeneous sub-domains. The second case study corresponds to a poroelastic inclusion embedded into an homogenous poroelastic formation. In both cases, the position of the heterogeneity is fairly well-recovered using only the electrical disturbances associated with the seismoelectric conversions. ?? 2011 Society of Exploration Geophysicists.

SEG Technical Program Expanded Abstracts↗

USGS1969

Geologic Settings of Subsidence

This paper reviews the role of geologic processes that contribute to subsidence in order to aid those starting investigations of ground-surface subsidence. Subsidence occurs, or at least is discovered, only infrequently, and little organized information has been available. In order to assess our present state of knowledge, the author gathered fragmentary bits of information from many sources widely scattered in the literature of geology and other earth sciences. The author cites examples for each geologic process that is a potential contributor to ground-surface subsidence together with geologic evidence for diagnosing their causes. The geologic processes involved are: (1) solution of gypsum and salt and redistribution of transient fill materials through solution cavities in calcareous rocks; (2) underground erosion of uncemented or lightly cemented silt and sand through temporary underground passageways; (3) lateral plastic flow of salt, gypsum and anhydrite, shale, and clay under loading; (4) compaction of sediments by loading, drainage, vibration, and hydrocompaction; (5) tectonic movements including primary and secondary effects of earthquakes, folding, and warping; and (6) volcanic activity. Because the first four processes may be accelerated by various engineering activities, examples have been selected to illustrate subsidence both under natural conditions and under conditions modified by man's activities. Although this extensive search for existing information on the role of geologic factors in subsidence indicates that much detailed work remains to be done, the future prospects for advancing our geologic knowledge are excellent. Methods of measuring ground-surface displacements are improving rapidly. Also, broadly based investigations of known areas of major subsidence throughout the world are developing new methods of diagnosis and treatment and are yielding quantitative data that will aid our evaluation of the rates and magnitude of present-day geologic processes.

Book chapter↗

USGS1977

Ground-water supplies in the Murfreesboro area, Tennessee

Ground water occurs in the Murfreesboro area in solution openings in the otherwise dense paleozoic limestones that underlie most of central Tennessee. Test drilling based on conceptual models of ground-water occurrence in carbonate-rock aquifers indicate that multimillion-gallon-per-day supplies could be developed from strategically located production wells in the Shiloh and Overall Creek localities. The Shiloh locality which encompasses an elongated synclinal depression in the bedrock has the potential to supply 5 to 8 million gallons per day. The Overall Creek locality which straddles a joint-oriented lineament has the potential to supply 3 to 6 million gallons per day. Some local springs could be used as a supplemental source of potable water, but storage facilities would be needed to offset poorly sustained flows during dry periods. An exception is Fox Camp Spring which appears to be a natural well. The quality of ground water in the Murfreesboro area is typically hard, moderately mineralized and moderately to highly alkaline. Although the shallowest aquifers are subject to bacterial contamination from the land surface, aquifers beneath a depth of 100 feet are prone to yield potable water. (Woodard-USGS)

Tennessee↗

USGS1980

The heliothermic lake: a direct method of collecting and storing solar energy

Heliothermic lakes contain a sun-heated layer of warm, saline water beneath a surface layer of cooler, less saline water. The two layers are separated by a chemocline, a stratum in which salinity increases progressively with depth. The chemocline, the position of which varies from lake to lake, functions as a heat trap. Most sunlight that penetrates this stratum is transformed into heat, which cannot escape by radiation because water is opaque to infrared light, and which cannot escape by convection because the specific gravity of the dense water below the chemocline is not significantly decreased by the increasing temperature. Heat can escape only by conduction through the chemocline, and water or brine is a very poor conductor. As a result, the temperature within and commonly below the chemocline rises. Under ideal conditions of a clear solution, high isolation, and a suitable salinity distribution, the temperature of the chemocline will increase to the boiling point. The lower part of the chemocline in a shallow (0.8-m) manmade heliothermic lake at Sedom, Israel, for example, reached a temperature of 96°C (205°F) in spite of a brine with poor light transmissibility. About 30 natural heliothermic lakes have been reported. The best known, Lake Ursului, occurs in Transylvania, Romania (latitude, 46°35'N). During four consecutive summers, 1899 to 1902, this lake had temperatures of 60-70°C (140-158°F) at a depth of 1-2 m. Heliothermic conditions have persisted in this lake for at least 28 and probably for more than 77 years. The most unusual, Lake Vanda, Victoria Land, Antarctica (latitude, 77°35'S), has a temperature of 26°C near the base of the chemocline at a depth of 61 despite a mean atmospheric temperature of -20°C. Sunlight penetrates into the chemocline through 5 m of remarkably clear ice. Maintenance of the chemocline is the chief problem preventing commercial use of manmade heliothermic lakes for the collection and storage of solar energy. The most effective means of preserving this stratum from destruction by diffusion and wind mixing may be the use of salts, such as sodium sulfate and sodium borate, whose solubilities are markedly influenced by temperature. The chemoclines of ponds constructed with such salts, in theory, would persist indefinitely and could be of great size.

Open-File Report↗

USGS2024

Unravelling spatial heterogeneity of inundation pattern domains for 2D analysis of fluvial landscapes and drainage networks

Fluvial landscape analysis is an essential part of geomorphology, hydrology, ecology, and cartography. It is traditionally focused on the transition between hillslopes and channel domain, in which the network drainage is represented by static flow lines. However, the natural fluctuations of the processes occurring in the watershed induce lateral and longitudinal expansions and contractions in the drainage patterns and variations of stream surface area. These dynamics can be better understood by introducing a two-dimensional (2D) view of catchment hydrography, in which river width and floodplain are included in the analysis. The novelty introduced in this work is the development of a hydrodynamic hierarchical framework (HHF) to analyse the transitions among geomorphic and hydrographic features of the fluvial landscape, distinguishing hillslope, unchanneled valleys, floodplains, and single/multithreads channels. HHF is based on the estimation of nested inundation pattern domains (IPDs) from digital elevation models and 2D hydrodynamic modeling. IPDs are defined by scaling laws that characterize log–log relations between watershed drainage density and unit discharge thresholds extracted from a 2D direct rainfall method (DRM) under steady state solutions. The physical significance of the IPDs is analysed within the context of both the physiographic features of the fluvial landscape and the rainfall rates employed as input for the modeling approach. Initially, the spatial heterogeneity of the IPDs is used to derive stream width metrics as a function of the rainfall rate. Then, a spatial index, representative of the IPDs' heterogeneity, is introduced as a measure of the susceptibility of the drainage network surface area to expansion and contraction. Finally, the consistency of the results is assessed in comparison to another hydrodynamic-based method for fluvial landscape analysis recently proposed in the literature. The proposed approach is analysed using challenging mountain and low-relief environments, characterized by multithread channels, meander cut-offs, oxbow lakes, and extreme landscapes that feature glacial outwash, permafrost, and peatlands.

Alaska↗

USGS2008

Characterization of calcium isotopes in natural and synthetic barite

The mineral barite (BaSO4) accommodates calcium in its crystal lattice, providing an archive of Ca-isotopes in the highly stable sulfate mineral. Holocene marine (pelagic) barite samples from the major ocean basins are isotopically indistinguishable from each other (??44/40Ca = -2.01 ?? 0.15???) but are different from hydrothermal and cold seep barite samples (??44/40Ca = -4.13 to -2.72???). Laboratory precipitated (synthetic) barite samples are more depleted in the heavy Ca-isotopes than pelagic marine barite and span a range of Ca-isotope compositions, ??44/40Ca = -3.42 to -2.40???. Temperature, saturation state, a Ba2 + / a SO42 -, and aCa2+/aBa2+ each influence the fractionation of Ca-isotopes in synthetic barite; however, the fractionation in marine barite samples is not strongly related to any measured environmental parameter. First-principles lattice dynamical modeling predicts that at equilibrium Ca-substituted barite will have much lower 44Ca/40Ca than calcite, by -9??? at 0 ??C and -8??? at 25 ??C. Based on this model, none of the measured barite samples appear to be in isotopic equilibrium with their parent solutions, although as predicted they do record lower ??44/40Ca values than seawater and calcite. Kinetic fractionation processes therefore most likely control the extent of isotopic fractionation exhibited in barite. Potential fractionation mechanisms include factors influencing Ca2+ substitution for Ba2+ in barite (e.g. ionic strength and trace element concentration of the solution, competing complexation reactions, precipitation or growth rate, temperature, pressure, and saturation state) as well as nucleation and crystal growth rates. These factors should be considered when investigating controls on isotopic fractionation of Ca2+ and other elements in inorganic and biogenic minerals. ?? 2008 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗