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At least 181 records · Page 10Linked to original sources

USGS2017

The relative contribution of waves, tides, and nontidal residuals to extreme total water levels on U.S. West Coast sandy beaches

To better understand how individual processes combine to cause flooding and erosion events, we investigate the relative contribution of tides, waves, and nontidal residuals to extreme total water levels (TWLs) at the shoreline of U.S. West Coast sandy beaches. Extreme TWLs, defined as the observed annual maximum event and the simulated 100 year return level event, peak in Washington, and are on average larger in Washington and Oregon than in California. The relative contribution of wave-induced and still water levels (SWL) to the 100 year TWL event is similar to that of the annual maximum event; however, the contribution of storm surge to the SWL doubles across events. Understanding the regional variability of TWLs will lead to a better understanding of how sea level rise, changes in storminess, and possible changes in the frequency of major El Niños may impact future coastal flooding and erosion along the U.S. West Coast and elsewhere.

California, Oregon, Washington↗

USGS2017

Evidence for Regional Stream Aggradation in the Central Oregon Coast Range during the Pleistocene-Holocene Transition

Low, nearly continuous terraces of similar age are present along streams in drainage basins that range in size from Drift Creek (190 km2) to the Umpqua River (11,800 km2) in the Oregon Coast Range. Radiocarbon ages from near the bose of fluvial sediments underlying these terraces are clustered at about 9000-11,000 14C yr B.P. Beveled bedrock surfaces (straths) that underlie the fluvial sediments are 1-8 m above summer stream levels and are present along most of the nontidal reaches of the rivers that we studied. Where exposed, the bedrock straths are overlain by 2-11 m of fluvial sediment that consists of a bottom-stratum (channel) facies of sandy pebble-cobble gravel and a top-stratum (overbank) facies of sandy silt or silt. Eight radiocarbon ages from the fluvial sediments allow correlation of the lowest continuous terrace over a wide area and thus indicate that a regional aggradation episode occurred in Coast Range drainage basins during the Pleistocene-Holocene transition. The cause of such widespread aggradation is unknown but may be related to climate-induced changes in the frequency of evacuation of colluvium from hollows, which are common in all drainage basins in the region.

Quaternary Research↗

USGS2020

Climate, sea level, and people - Changing South Florida's mangrove coast

South Florida’s coast is a land of contrasts that appeals to almost everyone, whether they seek out quiet natural environments along the mangrove waterways and in the wilderness of the Everglades or vibrant international culture in Miami. Yet this paradise is threatened by a number of forces – changing climate, rising sea level, and too many people, to name a few. Florida’s past is filled with stories of dramatic change and resiliency, if we look at the geologic record. It also hints at the role of climate alone, in the absence of significant sea level change, in shaping the mangrove coast. Using our knowledge of present-day processes, such as impacts of storms on the mangroves, combined with our interpretation of the past geologic record, is the best way to anticipate future changes. The question is, have humans altered this landscape so much that the species and habitats have lost their natural resiliency, and if they have, what will happen to the people and the unique environments of south Florida?

Florida↗

USGS2026

Climate-driven waterline variability along the North American West Coast

Sandy coasts are highly dynamic environments shaped by a myriad of hydro-sedimentary processes operating across various spatio-temporal scales. From seasonal to centennial timescales, sandy beach dynamics are strongly influenced by climate variability expressed in various forms, including seasonal cycles, climate modes (e.g., El Niño Southern Oscillation (ENSO)), and global warming. Satellite-based methods enable the observation of coastlines with unprecedented spatial and temporal coverage. However, over the past decade, as these methods have matured, coastal change studies have predominantly focused on long-term trends rather than on climate-driven cycles of shoreline change. In this study, we utilize a large dataset of monthly-sampled time series of waterline positions along the Pacific Coast of the United States and Baja California, Mexico. From these time series, we derived information on long-term trends and seasonal cycles of waterline change. Our analysis reveals clear contrasts in seasonal patterns of waterline variability across the study area, with greater amplitudes observed at higher latitudes. A shift in the dominant dynamics is evident in Southern Baja California, where shoreline variability is more influenced by intertropical dynamics and sea-level anomalies than by wave energy modulation, which dominates further north. ENSO is found to induce contrasting responses of the waterline along the study area. During El Niño events, shoreline retreat is observed in subtropical regions, while La Niña winters drive waterline retreat in higher latitudes, with southern regions either remaining stable or advancing.

Baja California, California, Oregon, Washington↗

USGS1983

Temporal accumulation of organochlorine pesticides in shorebirds wintering on the south Texas coast, 1979-80

Organochlorine pesticide residues were determined in 168 shorebirds of three species collected at approximate bimonthly intervals during the fall and winter months of 1979–80 near Port Mansfield on the south Texas coast. The study was conducted to determine if shorebirds wintering on mudflats at the outlets of agricultural drains in Texas accumulated pesticides during this period. The predominant Organochlorine residues detected in shorebirds were DDE, dieldrin, and toxaphene. Ninety-five % of the skinned carcasses analyzed contained detectable levels of DDE, 13% contained dieldrin, and 22% contained toxaphene. DDE significantly increased in all species of shorebirds from October to December, with potentially dangerous levels accumulating in some long-billed dowitchers ( Limnodromus scolopaceus ) and American avocets ( Recurvirostra americana ), but DDE residues seldom exceeded 0.5 ppm in carcasses of western sandpipers ( Calidris mauri ). After about two months on the study area, no further residue increases were documented. The high levels of DDE detected in a large proportion of the dowitchers, and to a lesser extent in the avocets, are near or within the range known to inhibit reproduction in some avian species. This study demonstrates that certain aquatic areas near agricultural lands on the south Texas coast may be potential threats to waterbirds eight years after the use of DDT was banned in the United States.

Texas↗

USGS1994

Distribution and status of submerged vegetation in estuaries of the upper Texas coast

Composition and biomass of beds of submerged aquatic vegetation (SAV) in estuaries along the upper Texas coast were examined from bottom core and rake samples taken along 72 line transects during July–August 1987. Substrate composition, salinity, water depth, and water clarity were also measured at each sample station. Halodule wrightii was the dominant species of SAV meadows (69% occurrence), followed by Ruppia maritima (36%). Najas guadalupensis and Vallisneria americana were only found in the shallow (<60 cm), oligohaline (<10 ppt) waters of Trinity Bay. Halophila engelmannii and Thalassia testudinum were only found in the deeper (35–110 cm) euhaline waters (30–40 ppt) of Christmas and Matagorda Bays. H. wrightii and R. maritima occurred across the greatest depth and salinity spectra, with R. maritima more prominent in shallower (<90 cm) mixohaline waters (10–30 ppt) and H. wrightii more prominent in euhaline waters (30–40 ppt). Beds of SAV were more extensive and had greater biomass along south shorelines compared to north shorelines (P<0.045), and depth to which vegetation grew was positively correlated with water clarity (r=0.927, P<0.001). The correlations of water depth, salinity, and water clarity with variation in SAV species composition and distribution suggest that abiotic tolerances documented by previous experimental studies are major factors influencing field distributions. Comparisons with similar field data from the early 1970s corroborate the reported decrease in SAV in the Galveston Bay complex and suggest a slight increase in the Matagorda Bay complex. Decline of SAV in the Galveston Bay complex coincided with major shorefront development and a decline in numbers of wintering redhead ducks Aythya americana . Protection of shorelines of upper coast estuaries is vital to maintaining SAV resources and the dependent fauna. Where possible, barrier island preserves should be established adjacent to beds of-SAV and development restrictions implemented to reduce impacts.

Texas↗

USGS2023

Postfire hydrologic response along the central California (USA) coast: Insights for the emergency assessment of postfire debris-flow hazards

The steep, tectonically active terrain along the Central California (USA) coast is well known to produce deadly and destructive debris flows. However, the extent to which fire affects debris-flow susceptibility in this region is an open question. We documented the occurrence of postfire debris floods and flows following the landfall of a storm that delivered intense rainfall across multiple burn areas. We used this inventory to evaluate the predictive performance of the US Geological Survey M1 likelihood model, a tool that presently underlies the emergency assessment of postfire debris-flow hazards in the western USA. To test model performance, we used the threat score skill statistic and found that the rainfall thresholds estimated by the M1 model for the Central California coast performed similarly to training (Southern California) and testing (Intermountain West) data associated with the original model calibration. Model performance decreased when differentiating between “minor” and “major” postfire hydrologic response types, which weigh effects on human life and infrastructure. Our results underscore that the problem of false positives is a major challenge for developing accurate rainfall thresholds for the occurrence of postfire debris flows. As wildfire activity increases throughout the western USA, so too will the demand for the assessment of postfire debris-flow hazards. We conclude that additional collection of field-verified inventories of postfire hydrologic response will be critical to prioritize which model variables may be suitable candidates for regional calibration or replacement.

California↗

USGS2021

Stock composition of Atlantic sturgeon (Acipenser oxyrinchus oxyrinchus) encountered in marine and estuarine environments on the U.S. Atlantic Coast

Atlantic sturgeon ( Acipenser oxyrinchus oxyrinchus ) is a large, anadromous fish native to the Atlantic Coast of North America. Although this species once supported important fisheries, centuries of exploitation and habitat degradation have resulted in dramatic declines, presumed extirpation in some rivers, and ultimately listing under the U.S. Endangered Species Act (ESA). Under the ESA, Atlantic sturgeon are listed as five separate Distinct Population Segments (DPSs), which form the basis for federal management. Despite state and federal protections Atlantic sturgeon still face significant threats to their recovery, including fisheries bycatch mortality, marine construction, dredging, dams, and vessel strikes. However, because subadult and adult Atlantic sturgeon migrate extensively across estuarine and marine environments and frequently form mixed-stock aggregations in non-natal habitats, it can be difficult to determine how these threats impact specific populations and DPSs. To better understand ontogenetic shifts in habitat use and stock-specific exposure to anthropogenic threats, we performed a mixed-stock analysis of 1704 Atlantic sturgeon encountered across the U.S. Atlantic Coast. Collections made north of Cape Cod, MA and south of Cape Hatteras, NC were dominated by individuals from regional stocks; however, we found extensive stock mixing in the mid-Atlantic region, particularly in coastal environments where individuals from all five DPSs were commonly observed. Subadults and adults that were encountered in offshore environments had moved, on average, 277 km from their natal source; however, 23% were sampled over 500 km from their natal river suggesting long-distance movements are relatively common in these age classes. Overall, our work highlights that Atlantic sturgeon populations are vulnerable to threats over vast areas and emphasizes the need for continued genetic monitoring to track recovery progress.

Atlantic Coast↗

USGS2024

Tropical or extratropical cyclones: What drives the compound flood hazard, impact, and risk for the United States Southeast Atlantic coast?

Subtropical coastlines are impacted by both tropical and extratropical cyclones. While both may lead to substantial damage to coastal communities, it is difficult to determine the contribution of tropical cyclones to coastal flooding relative to that of extratropical cyclones. We conduct a large-scale flood hazard and impact assessment across the subtropical Southeast Atlantic Coast of the United States, from Virginia to Florida, including different flood hazards. The physics-based hydrodynamic modeling skillfully reproduces coastal water levels based on a comprehensive validation of tides, almost two hundred historical storms, and an in-depth hindcast of Hurricane Florence. We show that yearly flood impacts are two times as likely to be driven by extratropical than tropical cyclones. On the other hand, tropical cyclones are 30 times more likely to affect people during rarer 100-year events than extratropical cyclones and contribute to more than half of the regional flood risk. With increasing sea levels, more areas will be flooded, regardless of whether flooding is driven by tropical or extratropical cyclones. Most of the absolute flood risk is contained in the greater Miami metropolitan area. However, several less populous counties have the highest relative risks. The results of this study provide critical information for understanding the source and frequency of compound flooding across the Southeast Atlantic Coast of the United States.

Natural Hazards↗

USGS2021

Stormwater systems as a source of marine debris: A case study from the Mediterranean coast of Israel

Drainage (or stormwater) systems are a potential source of marine debris. Approximately 67 km (33%) of the land along the Mediterranean coast of Israel is considered urban, covered by concrete and asphalt. The purpose of the present pilot study was to determine the composition of the solid waste in a drainage system and evaluate to what extent municipal sources contribute to marine debris. We sampled the waste in Netanya, a medium-size city (245,000 residents) on the central Mediterranean coast of Israel. Samples were taken from seven street stormwater receptacles prior to the first significant rain and then on the beach near a drainage outlet, a few hours after this substantial rain. In terms of composition of the debris, paper, cigarette butts, and sanitary items made up a higher proportion of the drainage system debris than those items did on the beach. In contrast, single-use items, polystyrene pieces, bottle caps, and plastic drinking bottles composed more of the debris on the beaches compared to the debris in the drainage system. Overall, we found that municipal stormwater systems contribute significant amounts of solid waste to marine debris on Israeli beaches. Preventing the waste from reaching the streets might help reduce marine debris on the beaches, especially at the beginning of the rainy season. There are multiple solutions, but all will require creativity and resources and constant maintenance. Educating the public to prevent disposal of solid waste items in the street is also important as a way to reduce terrestrial as well as marine debris.

Journal of Coastal Conservation↗

USGS1993

A Coast Mountains provenance for the Valdez and Orca groups, southern Alaska, based on Nd, Sr, and Pb isotopic evidence

Nd, Sr, and Pb isotopic data were obtained for fourteen fine- to coarse-grained samples of accreted flysch of the Late Cretaceous and early Tertiary Valdez and Orca Groups in southern Alaska to determine the flysch provenance. Argillites and greywackes from the Orca Group, as well as compositionally similar but higher metamorphic grade rocks from the Valdez Group, show a restricted range of correlated ε Nd ( −0.6 to −3.8) and 87 Sr/ 86 Sr (0.7060–0.7080) at the time of sediment deposition ( ∼ 50 Ma). Pb isotopic compositions also vary over a narrow range ( 206 Pb/ 204 Pb= 19.138–19.395, 207 Pb/ 204 Pb= 15.593–15.703, 208 Pb/ 204 Pb= 38.677–39.209), and in the Orca Group the samples generally become more radiogenic with decreasing ε Nd and increasing 87 Sr/ 86 Sr. All samples have similar trace element compositions characterized by moderate light rare earth element enrichments, and low ratios of high field strength elements to large ion lithophile elements. Based on petrographic, geochemical, and isotopic data the sedimentary rocks are interpreted to have been derived largely from a Phanerozoic continental margin arc complex characterized by igneous rocks with ε Nd values between 0 and −5. The latter conclusion is supported by the ε Nd values of a tonalite clast and a rhyodacite clast in the Orca Group ( ε Nd = −4.9and−0.9, respectively). However, trondjemitic clasts in the Orca Group have significantly lower ε Nd ( ∼ −10) and require a derivation of a portion of the flysch from Precambrian crustal sources. The Nd, Sr, and Pb isotopic compositions of both the Valdez and Orca Groups overlap the values determined for intrusive igneous rocks exposed within the northern portion of the Late Cretaceous to early Tertiary Coast Mountains Plutonic Complex in western British Columbia and equivalent rocks in southeastern Alaska. The isotopic data support previous conclusions based on geologic studies which suggest that the flysch was shed from this portion of the batholith, and from overlying continental margin arc-related volcanic rocks, following its rapid uplift in the Late Cretaceous and early Tertiary. The Precambrian crustal material present in the flysch may have been derived from Late Proterozoic or older metasedimentary and metaigneous rocks now exposed along the western margin of the Coast Mountains Plutonic Complex.

Earth and Planetary Science Letters↗

USGS1970

Latitudinal gradients in tertiary molluscan faunas of the Pacific coast

Tertiary molluscan faunas of the middle latitudes of the marginal eastern North Pacific are characterized by warm-water taxa whose descendants now live in more southerly latitudes. A series of profiles in which cumulative percentages of warm-water faunal elements are plotted against latitude show progressive northward decreases in the percentage of these elements in the faunas of Pacific coast Tertiary stages. Systematic changes in the relative position of these latitudinal gradients during the Middle and Late Tertiary are related to climatic change in the Pacific Basin. Widespread tropical marine climate in the middle latitudes of the eastern North Pacific during the Eocene is indicated by widespread faunal units characterized by high levels of taxonomic diversity. Succeeding Early Oligocene faunas are less diverse, suggesting cooler climatic conditions. Unusually low representations of warm-water genera characterize the molluscan faunas of the Acila shumardi Zone in central California (latitude 34°–37°N). The anomalously cool-water aspect of these faunas may record the occurrence of upwelling along a bold linear segment of the Pacific coast. During the Late Oligocene or the Early Miocene, they are replaced by faunas of unusually warm-water aspect resulting in positive anomalies in Miocene latitudinal faunal gradients in central California. The Miocene anomalies seem to result from the development of an irregular Neogene coastline with extensive, newly established shallow-water embayments.

Palaeogeography, Palaeoclimatology, Palaeoecology↗

USGS1979

Anomalously high uplift rates along the Ventura-Santa Barbara coast, California-tectonic implications

The NW—SE trending segments of the California coastline from Point Arena to Point Conception (500 km) and from Los Angeles to San Diego (200 km) generally parallel major right-lateral strike-slip fault systems. Minor vertical crustal movements associated with the dominant horizontal displacements along these fault systems are recorded in local sedimentary basins and slightly deformed marine terraces. Typical maximum uplift rates during Late Quaternary time are about 0.3 m/ka, based on U-series ages of corals and amino-acid age estimates of fossil mollusks from the lowest emergent terraces. In contrast, the E–W-trending segments of the California coastline between Point Conception and Los Angeles (200 km) parallel predominantly northward-dipping thrust and high-angle reverse faults of the western Transverse Ranges. Along this coast, marine terraces display significantly greater vertical deformation. Amino-acid age estimates of mollusks from elevated marine terraces along the Ventura—Santa Barbara coast imply anomalously high uplift rates of between 1 and 6 m/ka over the past 40 to 100 ka. The deduced rate of terrace uplift decreases from Ventura to Los Angeles, conforming with a similar trend observed by others in contemporary geodetic data. The more rapid rates of terrace uplift in the western Transverse Ranges reflect N—S crustal shortening that is probably a local accommodation of the dominant right-lateral shear strain along coastal California.

California↗

USGS1991

Concordant paleolatitudes from ophiolite sequences in the northern California Coast Ranges, U.S.A.

Paleomagnetic data have been obtained from two ophiolite sequences in the northern California Coast Ranges: from Mount Diablo in the San Francisco Bay area and from Potter Valley, north of Clear Lake. The ophiolite exposed at Mount Diablo is part of the late Middle to Late Jurassic Coast Range ophiolite, and that exposed near Potter Valley is Late Jurassic to perhaps Early Cretaceous in age and occurs within the Franciscan assemblage. Data from the sheeted-dike complex at Mount Diablo show these rocks to be strongly overprinted, probably following uplift and erosion of the ophiolite. Samples whose primary remanent magnetization seems to be recovered yield a mean paleomagnetic pole at 30.7°N, 159.5°E with α 95 = 5.6°. A comparison of this pole with the Jurassic apparent polar wander path for North America indicates that the ophiolite has rotated 45° ± 7° counterclockwise relative to the craton and has not been latitudinally displaced. The diabase and pillow basalt in Potter Valley have not been strongly overprinted and data from those rocks yield a paleomagnetic pole at 79.0°N, 61.5°E with α 95 = 6.4°. This result indicates that the ophiolite at Potter Valley has rotated approximately 29° ± 8° clockwise, and has undergone little or no latitudinal displacement. Because of the predominantly northeastward transport of oceanic plates converging with the western margin of North America since middle Mesozoic time, the absence of appreciable northward displacement of either ophiolite fragment indicates that both formed close to the continental margin.

California↗

USGS2015

Weathering and transport of chromium and nickel from serpentinite in the Coast Range ophiolite to the Sacramento Valley, California, USA

A soil geochemical study in northern California was done to investigate the role that weathering and transport play in the regional distribution and mobility of geogenic Cr and Ni, which are both potentially toxic and carcinogenic. These elements are enriched in ultramafic rocks (primarily serpentinite) and the soils derived from them (1700–10,000 mg Cr per kg soil and 1300–3900 mg Ni per kg soil) in the Coast Range ophiolite. Chromium and Ni have been transported eastward from the Coast Range into the western Sacramento Valley and as a result, valley soil is enriched in Cr (80–1420 mg kg −1 ) and Ni (65–224 mg kg −1 ) compared to median values of U.S. soils of 50 and 15 mg kg −1 , respectively. Nickel in ultramafic source rocks and soils is present in serpentine minerals (lizardite, antigorite, and chrysotile) and is more easily weathered compared to Cr, which primarily resides in highly refractory chromite ([Mg,Fe 2+ ][Cr 3+ ,Al,Fe 3+ ] 2 O 4 ). Although the majority of Cr and Ni in soils are in refractory chromite and serpentine minerals, the etching and dissolution of these minerals, presence of Cr- and Ni-enriched clay minerals and development of nanocrystalline Fe (hydr)oxides is evidence that a significant fractions of these elements have been transferred to potentially more labile phases.

California↗

USGS2015

Characteristics of storms driving wave-induced seafloor mobility on the U.S. East Coast continental shelf

This study investigates the relationship between spatial and temporal patterns of wave-driven sediment mobility events on the U.S. East Coast continental shelf and the characteristics of the storms responsible for them. Mobility events, defined as seafloor wave stress exceedance of the critical stress of 0.35 mm diameter sand (0.2160 Pa) for 12 or more hours, were identified from surface wave observations at National Data Buoy Center buoys in the Middle Atlantic Bight (MAB) and South Atlantic Bight (SAB) over the period of 1997-2007. In water depths ranging from 36-48 m, there were 4-9 mobility events/year of 1-2 days duration. Integrated wave stress during events (IWAVES) was used as a combined metric of wave-driven mobility intensity and duration. In the MAB, over 67% of IWAVES was caused by extratropical storms, while in the SAB, greater than 66% of IWAVES was caused by tropical storms. On average, mobility events were caused by waves generated by storms located 800+ km away. Far-field hurricanes generated swell 2-4 days before the waves caused mobility on the shelf. Throughout most of the SAB, mobility events were driven by storms to the south, east, and west. In the MAB and near Cape Hatteras, winds from more northerly storms and low-pressure extratropical systems in the mid-western U.S. also drove mobility events. Waves generated by storms off the SAB generated mobility events along the entire U.S. East Coast shelf north to Cape Cod, while Cape Hatteras shielded the SAB area from swell originating to the north offshore of the MAB.

Continental Shelf Research↗

USGS2017

Interannual to multidecadal climate forcings on groundwater resources of the U.S. West Coast

Study region The U.S. West Coast, including the Pacific Northwest and California Coastal Basins aquifer systems. Study focus Groundwater response to interannual to multidecadal climate variability has important implications for security within the water–energy–food nexus. Here we use Singular Spectrum Analysis to quantify the teleconnections between AMO, PDO, ENSO, and PNA and precipitation and groundwater level fluctuations. The computer program DAMP was used to provide insight on the influence of soil texture, depth to water, and mean and period of a surface infiltration flux on the damping of climate signals in the vadose zone. New hydrological insights for the region We find that PDO, ENSO, and PNA have significant influence on precipitation and groundwater fluctuations across a north-south gradient of the West Coast, but the lower frequency climate modes (PDO) have a greater influence on hydrologic patterns than higher frequency climate modes (ENSO and PNA). Low frequency signals tend to be preserved better in groundwater fluctuations than high frequency signals, which is a function of the degree of damping of surface variable fluxes related to soil texture, depth to water, mean and period of the infiltration flux. The teleconnection patterns that exist in surface hydrologic processes are not necessarily the same as those preserved in subsurface processes, which are affected by damping of some climate variability signals within infiltrating water.

California, Oregon, Washington↗

USGS2008

Isotope geochemistry of mercury in source rocks, mineral deposits and spring deposits of the California Coast Ranges, USA

We present here the first study of the isotopic composition of mercury in rocks, ore deposits, and active spring deposits from the California Coast Ranges, a part of Earth's crust with unusually extensive evidence of mercury mobility and enrichment. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of mercury deposits, hot-spring deposits that form at shallow depths (< 300??m) and silica-carbonate deposits that extend to depths of 1000??m. Active springs and geothermal areas continue to precipitate Hg and Au and are modern analogues to the fossil hydrothermal systems preserved in the ore deposits. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of mercury than volcanic rocks of the Clear Lake Volcanic Field. Mean mercury isotopic compositions (??202Hg) for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate mercury deposits have similar average mercury isotopic compositions that are indistinguishable from averages for the three rock units, although ??202Hg values for the mercury deposits have a greater variance than the country rocks. Precipitates from spring and geothermal waters in the area have similarly large variance and a mean ??202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate that there is little or no isotopic fractionation (< ?? 0.5???) during release of mercury from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of mercury in deposits, however, especially in their uppermost parts. Boiling of hydrothermal fluids, separation of a mercury-bearing CO2 vapor or reduction and volatilization of Hg(0) in the near-surface environment are likely the most important processes causing the observed Hg isotope fractionation. This should result in the release of mercury with low ??202Hg values into the atmosphere from the top of these hydrothermal systems. Estimates of mass balance suggest that residual Hg reservoirs are not measurably enriched in heavy Hg isotopes as a result of this process because only a small amount of Hg (< 4%) leaves actively ore-forming systems. ?? 2008 Elsevier B.V. All rights reserved.

Earth and Planetary Science Letters↗