USGS Science⌕ Search

USGS · wsp2266

Distribution of polychlorinated biphenyls in the Housatonic River and adjacent aquifer, Massachusetts

Abstract

Polychlorinated biphenyls (PCB's) are sorbed to the fine-grained stream-bottom sediments along the Housatonic River from Pittsfield, Massachusetts, southward to the Massachusetts-Connecticut boundary. The highest PCB concentrations, up to 140,000 micrograms per kilogram, were found in samples of bottom material from a reach of the river between Pittsfield and Woods Pond Dam in Lee, Massachusetts. Sediments in Woods Pond have been estimated to contain about 11,000 pounds of PCB's. Approximately 490 pounds per year of PCB's have also been estimated to move past the Housatonic River gaging station at Great Barrington. The distribution of hydraulic heads, water temperatures, and concentrations of dissolved oxygen, ammonia, nitrate, iron, and manganese in ground water shows that industrial water-supply wells in a sand and gravel aquifer adjacent to a stretch of the river called Woods Pond have been inducing ground-water recharge through the PCB-contaminated bottom sediments of the pond since late 1956. These data indicate that, at one location along the shore of the pond, the upper 40 feet of the aquifer contains water derived from induced infiltration. However, this induced recharge has not moved PCB's from the bottom sediments into a vertical section of the aquifer located 5 feet downgradient from the edge of Woods Pond. Samples taken at selected intervals in this section showed that no PCB's sorbed to the aquifer material or dissolved in the ground water within the detection limits of the chemical analyses.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Frederick B. Gay, Michael H. Frimpter. 1985. Distribution of polychlorinated biphenyls in the Housatonic River and adjacent aquifer, Massachusetts. https://doi.org/10.3133/wsp2266

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

Basic ground-water hydrology

Ground water is one of the Nation's most valuable natural resources. It is the source of about 40 percent of the water used for all purposes exclusive of hydropower generation and electric powerplant cooling. Surprisingly, for a resource that is so widely used and so important to the health and to the economy of the country, the occurrence of ground water is not only poorly understood but is also, in fact, the subject of many widespread misconceptions. Common misconceptions include the belief that ground water occurs in underground rivers resembling surface streams whose presence can be detected by certain individuals. These misconceptions and others have hampered the development and conservation of ground water and have adversely affected the protection of its quality. In order for the Nation to receive maximum benefit from its ground-water resource, it is essential that everyone, from the rural homeowner to managers of industrial and municipal water supplies to heads of Federal and State water-regulatory agencies, become more knowledgeable about the occurrence, development, and protection of ground water. This report has been prepared to help meet the needs of these groups, as well as the needs of hydrologists, well drillers, and others engaged in the study and development of ground-water supplies. It consists of 45 sections on the basic elements of ground-water hydrology, arranged in order from the most basic aspects of the subject through a discussion of the methods used to determine the yield of aquifers to a discussion of common problems encountered in the operation of ground-water supplies. Each section consists of a brief text and one or more drawings or maps that illustrate the main points covered in the text. Because the text is, in effect, an expanded discussion of the illustrations, most of the illustrations are not captioned. However, where more than one drawing is included in a section, each drawing is assigned a number, given in parentheses, and these numbers are inserted at places in the text where the reader should refer to the drawing. In accordance with U.S. Geological Survey policy to encourage the use of metric units, these units are used in most sections. In the sections dealing with the analysis of aquifer (pumping) test data, equations are given in both consistent units and in the inconsistent inch-pound units still in relatively common use among ground-water hydrologists and well drillers. As an aid to those who are not familiar with metric units and with the conversion of ground-water hydraulic units from inch-pound units to metric units, conversion tables are given on the inside back cover. Definitions of ground-water terms are given where the terms are first introduced. Because some of these terms will be new to many readers, abbreviated definitions are also given on the inside front cover for convenient reference by those who wish to review the definitions from time to time as they read the text. Finally, for those who need to review some of the simple mathematical operations that are used in ground-water hydrology, a section on numbers, equations, and conversions is included at the end of the text.

Water Supply Paper↗

Use of stable isotopes of carbon, nitrogen, and sulfur to identify sources of nitrogen in surface waters in the Lower Susquehanna River Basin, Pennsylvania

Samples of nitrogen-source material, soil, and water were collected from several small, primarily single-source subbasins in the Lower Susquehanna River Basin during 1988–90 to determine the feasibility of using measurements of stable isotope ratios of carbon ( 13 C), nitrogen ( 15 N), and sulfur ( 34 S) to identify sources of nitrogen (N) in stream water. Chemical and isotopic compositions were measured for six N-source types consisting of rain water, forest leaf litter, synthetic fertilizer, farm-animal manure, municipal-sewage effluent and sludge, and septictank effluent and sludge. Compositions of associated, nearby samples of topsoil, subsoil, runoff water, and stream water were measured to evaluate changes in compositions of transported N-containing materials near the N source. Animal manure, human waste (sewage plus septic), and forest-leaf litter can be distinguished on the basis of 13 C; however, most N-sources cannot be distinguished on the basis of 15 N and 34 S, owing to wide ranges and overlap of compositions among different N-source types. Although values of 15 N for soil and runoff-water samples are qualitatively similar to those of the applied N source, values of 13 C and 34 S for runoff-water and stream-water samples appear to reflect the compositions of relatively large reservoirs of the elements in soil organic matter and minerals, respectively, and not the composition of the applied N source. The ratio of organic carbon to total nitrogen (C-org:N), combined with 13 C, is useful for distinguishing agricultural soils, which have characteristically high 13 C and low C-org:N, from forested soils. The C-org:N values of suspended particulates in runoff or stream waters generally are lower than those of nearby soils, however, and indicate that chemical transformations and resultant isotopic fractionation can be important controls on the compositions of N-containing compounds in the soil and water. In aqueous samples including surface water and liquid N-sources, isotopic ratios commonly differ between coexisting dissolved fractions of NO 3- N and NH 3- N and between dissolved and particulate fractions of N or S, probably because of isotopic fractionation during transport or N-source processing. Isotopic measurements provide qualitative information about important reactions that can affect N concentrations in surface waters. However, mass-balance computations generally are not sufficiently accurate to estimate the proportions of multiple sources contributing to the N load in the streams studied because of (1) variations in source chemical and isotopic compositions and (2) nonconservative behavior and fractionation during transport over short distances (hundreds of meters). Uncertainties in mass-balance computations are complicated by the propagation of errors associated with measurements of discharge, chemical concentrations,and isotopic compositions of relatively dilute, small streams.

Pennsylvania↗

Validation of a numerical modeling method for simulating rainfall-runoff relations for headwater basins in western King and Snohomish Counties, Washington

The validity of a previously determined numerical modeling method was assessed. Numerical models for 11 drainage basins were constructed with the Hydrologic Simulation Program-FORTRAN (HSPF) with parameter values that were generalized for the physiographic region. Large and recurrent simulation errors were initially identified, but three systematic modifications of the models corrected those errors for 10 out of the 11 basins. The validity of the numerical modeling method for simulating rainfall-runoff relations in the study area, as modified during this investigation, was not rejected, but observed streamflow data were needed to apply the method.

Water Supply Paper↗