USGS Science⌕ Search
Home/Archive/USGS

USGS · ofr00182

Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group; determination of chloroacetanilide herbicide metabolites in water using high-performance liquid chromatography-diode array detection and high-performance liquid chromatography/mass spectrometry

L.R. Zimmerman·K.A. Hostetler·E.M. Thurman
View original source ↗Read source document ↗Export metadata ↓

Abstract

Analytical methods using high-performance liquid chromatography-diode array detection (HPLC-DAD) and high-performance liquid chromatography/mass spectrometry (HPLC/MS) were developed for the analysis of the following chloroacetanilide herbicide metabolites in water: acetochlor ethanesulfonic acid (ESA), acetochlor oxanilic acid (OXA), alachlor ESA, alachlor OXA, metolachlor ESA, and metolachlor OXA. Good precision and accuracy were demonstrated for both the HPLC-DAD and HPLC/MS methods in reagent water, surface water, and ground water. The mean HPLC-DAD recoveries of the chloroacetanilide herbicide metabolites from water samples spiked at 0.25, 0.50, and 2.0 mg/L (micrograms per liter) ranged from 84 to 112 percent, with relative standard deviations of 18 percent or less. The mean HPLC/MS recoveries of the metabolites from water samples spiked at 0.05, 0.20, and 2.0 mg/L ranged from 81 to 125 percent, with relative standard deviations of 20 percent or less. The limit of quantitation (LOQ) for all metabolites using the HPLC-DAD method was 0.20 mg/L, whereas the LOQ using the HPLC/MS method was 0.05 mg/L. These metabolite-determination methods are valuable for acquiring information about water quality and the fate and transport of the parent chloroacetanilide herbicides in water.

Explore related subjects

Open-File ReportReport

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

L.R. Zimmerman, K.A. Hostetler, E.M. Thurman. 2000. Methods of analysis by the U.S. Geological Survey Organic Geochemistry Research Group; determination of chloroacetanilide herbicide metabolites in water using high-performance liquid chromatography-diode array detection and high-performance liquid chromatography/mass spectrometry. https://doi.org/10.3133/ofr00182

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

ECCOE Landsat quarterly calibration and validation report—Quarter 2, 2026

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 2 (April–June), 2026. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov.

Open-File Report↗
USGS2026

ECCOE Landsat quarterly calibration and validation report—Quarter 1, 2026

Executive Summary The U.S. Geological Survey Earth Resources Observation and Science Calibration and Validation (Cal/Val) Center of Excellence (ECCOE) focuses on improving the accuracy, precision, calibration, and product quality of remote-sensing data, leveraging years of multiscale optical system geometric and radiometric calibration and characterization experience. The ECCOE Landsat Cal/Val Team continually monitors the geometric and radiometric performance of active Landsat missions and makes calibration adjustments, as needed, to maintain data quality at the highest level. This report provides observed geometric and radiometric analysis results for Landsats 8 and 9 for quarter 1 (January–March) of 2026. All data used to compile the Cal/Val analysis results presented in this report are freely available from the U.S. Geological Survey EarthExplorer website: https://earthexplorer.usgs.gov . One specific activity that the ECCOE Landsat Cal/Val Team closely monitored was a Landsat 8 Thermal Infrared Sensor encoder alerts anomaly. On March 18, 2026, the Thermal Infrared Sensor instrument’s mechanism control electronics board reset, driving several parameters to default power-on values. Subsequent telemetry and analysis determined that no persistent hardware misconfiguration was present and no radiometric or geometric degradation was observed.

Open-File Report↗
USGS2026

Floods of June 20–July 6, 2024, in the Big Sioux River, Rock River, Little Sioux River, Ocheyedan River, and Floyd River Basins, northwestern Iowa

Major flooding occurred on June 20–July 6, 2024, in northwestern Iowa affecting the Big Sioux, Rock, Little Sioux, Ocheyedan, and Floyd River Basins. Heavy rain fell in northwestern Iowa, southwestern Minnesota, and southeastern South Dakota on June 20–22, 2024. Parts of northwestern Iowa recorded 2–6 inches of rainfall and localized amounts exceeding 12 inches. A maximum peak-of-record streamflow of 175,000 cubic feet per second at the U.S. Geological Survey streamgage Big Sioux River at Akron, Iowa (06485500), was recorded on June 22, 2024, and had an annual exceedance probability range of 0.2–0.49 percent. High-water marks were measured at four locations along the Big Sioux River between U.S. Interstate 29 at Sioux City, Iowa, upstream to Iowa Highway 10 north of Hawarden, Iowa, a distance of 75.7 river miles. A maximum peak-of-record streamflow of 157,000 cubic feet per second at the U.S. Geological Survey streamgage Rock River near Rock Valley, Iowa (06483500), was recorded on June 22, 2024, and had an annual exceedance probability of less than 0.2 percent. High-water marks were measured at eight locations along the Rock River between County Road B30 east of Hudson, South Dakota, upstream to Iowa Highway 9 at Rock Rapids, Iowa, a distance of 39.3 river miles. A maximum peak-of-record streamflow of 63,000 cubic feet per second at the U.S. Geological Survey streamgage Little Sioux River at Correctionville, Iowa (06606600), was recorded on June 24, 2024, and had an annual exceedance probability range of 0.2–0.49 percent. High-water marks were measured at 11 locations along the Little Sioux River between Iowa Highway 31 west of Correctionville, Iowa, upstream to U.S. Highway 18 north of Spencer, Iowa, a distance of 134.8 river miles. A maximum streamflow of 24,500 cubic feet per second at the U.S. Geological Survey streamgage Ocheyedan River near Spencer, Iowa (06605000), was recorded on June 22, 2024, and had an annual exceedance probability range of 0.2–0.49 percent. High-water marks were measured at three locations along the Ocheyedan River between County Road M38 west of Spencer, Iowa, upstream to U.S. Highway 18 west of Everly, Iowa, a distance of 12.8 river miles. A maximum streamflow of 41,000 cubic feet per second at the U.S. Geological Survey streamgage Floyd River at Alton, Iowa (06600100), was recorded on June 22, 2024, and had an annual exceedance probability range of 1–1.99 percent. High-water marks were measured at six locations along the Floyd River between Iowa Highway 3 at Le Mars, Iowa, upstream to Iowa Highway 10 at Alton, Iowa, a distance of 27.5 river miles. The high-water marks were used to develop flood profiles for the Big Sioux, Rock, Little Sioux, Ocheyedan, and Floyd Rivers.

Iowa, Minnesota, South Dakota↗