Utilizing anthropogenic compounds and geochemical tracers to identify preferential structurally controlled groundwater pathways influencing springs in Grand Canyon National Park, Arizona, USA

Kimberly R. Beisner; Nicholas V. Paretti; Jeramy Roland Jasmann; Larry B. Barber

doi:10.1016/j.ejrh.2023.101461

Home/Archive/USGS

USGS · 70246316

Utilizing anthropogenic compounds and geochemical tracers to identify preferential structurally controlled groundwater pathways influencing springs in Grand Canyon National Park, Arizona, USA

Kimberly R. Beisner·Nicholas V. Paretti·Jeramy Roland Jasmann·Larry B. Barber

View original source ↗Export metadata ↓

Abstract

Study region: This study focuses on the Colorado River watershed in the area along the South Rim of the Grand Canyon. Study focus: This study utilizes anthropogenic chemical tracers to investigate the fate of treated wastewater effluent discharged within Grand Canyon National Park. Anthropogenic chemical tracers were used to discern preferential structurally controlled pathways in a complex regional network of faults and fractures in which some are conduits and others barriers to flow. New hydrological insights for the region : Previous investigations on water resources of Grand Canyon have suggested two different discharge locations (Garden Springs versus Monument Spring) for the treated wastewater discharged on the South Rim of Grand Canyon yet the presence of wastewater at the springs remained unstudied for decades. The treated wastewater from Grand Canyon Village is released into Bright Angel Wash that flows along the surface expression of the Bright Angel Fault and past the inferred intersection with the perpendicular Monument Fault. Multiple anthropogenic compounds (pharmaceuticals, per- and polyfluoroalkyl substances (PFAS), and elevated nitrate) were found in Bright Angel Wash and Monument Spring. Stable isotopic measurements at Monument Spring show depletion over time also suggesting contribution from a depleted stable isotopic source found in the treated wastewater. The anthropogenic tracers utilized in this study provide good insight to which geologic structures are conduits versus barriers to flow and can be useful in other fracture flow and karst settings.

Explore related subjects

Journal of Hydrology: Regional Studies Article

Source-reported bounding extent: 35.57058860267266° to 36.52936308034002° latitude; -113.14926803785156° to -111.89749432574378° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Kimberly R. Beisner, Nicholas V. Paretti, Jeramy Roland Jasmann, Larry B. Barber. 2023. Utilizing anthropogenic compounds and geochemical tracers to identify preferential structurally controlled groundwater pathways influencing springs in Grand Canyon National Park, Arizona, USA. https://doi.org/10.1016/j.ejrh.2023.101461

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

USGS2026

Assessing future hydrologic extremes using an integrated hydrology and river operations model in the Russian River watershed

Study region The Russian River watershed, situated in coastal, northern California, experiences hydrologic extremes, including periodic droughts and flooding. Water managers are working to maintain sustainable water supplies and environmental flows, while mitigating flood risks. Study focus This paper introduces an integrated hydrology and river operations model for the Russian River watershed. This model is distinct from models in previous studies because it represents surface-groundwater interactions and uses climate forcings to estimate dynamic water use demands that are superimposed onto both reservoir operations and water supply constraints. The model was used to examine three historical (1990–2015) and eight future (2016–2099) water use and climate change scenarios. New hydrological insights for the region The direct connection between streams and aquifers facilitated both annual aquifer replenishment by high winter streamflows and streamflow depletion by groundwater wells (19 % of pumped groundwater in alluvial aquifers from stream leakage) during critical low flow periods. Simulated streamflow changes included 59 % longer and 54 % more severe streamflow droughts, 26 % lower seasonal low streamflows, and up to 125 % higher peak streamflows, averaged over future climate and water use scenarios, suggesting increased future flood and water availability risks. Results showed the importance of reservoir operations for mitigating the impacts of increased hydroclimatic volatility, despite a decrease in reservoir reliability at Lake Mendocino, suggesting that reservoir management may be used to decrease future risks.

California↗

USGS2026

Snow simulations predict future changes in rain-on-snow events across the upper Gallatin River watershed, a Greater Yellowstone Ecosystem headwater system

Study region: The upper Gallatin River watershed, an alpine headwater system in the Greater Yellowstone Ecosystem, in Wyoming and Montana. Study focus: As global and regional air temperatures rise, mountain headwaters across the Greater Yellowstone Ecosystem (GYE) are projected to see more precipitation falling as rain. While the hydrologic effects of this snow-to-rain transition depends on a variety of factors, it can lead to an increased occurrence of rain-on-snow (RoS) events. To investigate these changes, we used high-resolution (30 m) SnowModel simulations of the upper Gallatin River watershed. Simulations were run for 2001-2013 using two scenarios: (1) historical meteorology as control and (2) pseudo global warming (PGW) where control air temperature and precipitation conditions were perturbed to represent mean end-of-century conditions under a high-emissions scenario. New hydrological insights for the region: SnowModel outputs show that changes in PGW precipitation and snow accumulation varied with elevation. Warmer air temperatures at low elevations (< 2,500 m) led to less snow accumulation and less precipitation falling as snow. Colder baseline air temperatures for elevations above 2,500 meters (m) resulted in minor reductions in winter snowfall fraction. For PGW simulations, spring (April-June) months were rainier, and elevations above 2,500 m experienced more RoS events. Snowpacks between 2,500-3,100 m generated more snowmelt during RoS events, which was reflected in the watershed average. More high-intensity melt events can affect aquatic habitat, water quality, and the accuracy of streamflow forecasts across the region.

Montana, Wyoming↗

USGS2026

VegET evapotranspiration for Africa: Continental-scale simulation, multi-product evaluation, and drought assessment

Study region Continental Africa, encompassing diverse climatic zones—tropical, arid, and temperate—and spanning major transboundary river basins such as the Nile, Niger, Congo, Volta, and Zambezi River Basins. The region exhibits pronounced hydroclimatic gradients and heterogeneous land use systems ranging from rainfed croplands and rangelands to dense tropical forests and irrigated schemes. Study focus Actual evapotranspiration (ETa) is a central component of the terrestrial water balance, governing the redistribution of water and energy between the land surface and the atmosphere. Accurate estimation of ETa at continental scale is critical for hydrological monitoring, water resource management, and climate adaptation, as well as for quantifying water, energy, and carbon fluxes that underpin sustainable development. In this study, we applied the agro-hydrologic VegET v2 model to simulate a new, high-resolution, continental-scale ETa dataset for Africa (2000–2021). The model results were benchmarked against four widely used remote sensing-based products—MODIS16 v6.1, SSEBop v6.1, WaPOR v3, and GLEAM v4.1a—across major climate zones, land use types, and River Basins, providing a comprehensive multi-product evaluation of evapotranspiration dynamics across the continent. New hydrological insights for the region Validation against eddy covariance flux tower observations at eight representative sites confirmed that VegET v2 accurately reproduces the seasonal dynamics of observed ETa, achieving a correlation (r) of 0.8 and an RMSE of 25 mm month⁻¹ —accuracy that is comparable to or higher than accuracies of satellite-based products MODIS16, SSEBop, and GLEAM. This study represents one of the first Africa-wide hydrological simulations of ETa, extending the VegET model beyond basin-scale applications. Intercomparisons reveal that VegET aligns closely with MODIS16, SSEBop, and GLEAM in humid and tropical regions (r = 0.80–0.90; RMSE < 20 mm month⁻¹), while greater discrepancies appear in arid and semi-arid zones, where WaPOR tends to overestimate ETa (RMSE ≥ 28 mm month⁻¹). Despite these differences, VegET effectively captures spatial and temporal ETa variability across rainfed croplands, forests, and savannas, supporting its utility in regional water balance assessments, water accounting, and drought monitoring. A key application of VegET v2 is the Evapotranspiration Deficit Index (ETDI), derived by integrating VegET-based ETa with potential evapotranspiration (PET) to quantify water stress. ETDI successfully captured major drought episodes across Africa, including persistent Sahelian and southern African dry spells, the 2020–2021 winter drought in the Maghreb, and the 2018–2019 austral summer drought in southern Africa, while identifying positive anomalies over central Africa indicative of recurrent wetness. These results underscore VegET’s capability as a hydrologically consistent, operational tool for continental ETa monitoring and drought assessment, offering support for basin-scale water balance studies, food security planning, and climate resilience across Africa’s diverse hydrological environments.

Journal of Hydrology: Regional Studies↗