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Improved online δ18O measurements of nitrogen‐ and sulfur‐bearing organic materials and a proposed analytical protocol

Haiping Qi·Tyler B. Coplen·Leonard I Wassenaar
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Abstract

It is well known that N 2 in the ion source of a mass spectrometer interferes with the CO background during the δ 18 O measurement of carbon monoxide. A similar problem arises with the high‐temperature conversion (HTC) analysis of nitrogenous O‐bearing samples (e.g. nitrates and keratins) to CO for δ 18 O measurement, where the sample introduces a significant N 2 peak before the CO peak, making determination of accurate oxygen isotope ratios difficult. Although using a gas chromatography (GC) column longer than that commonly provided by manufacturers (0.6 m) can improve the efficiency of separation of CO and N 2 and using a valve to divert nitrogen and prevent it from entering the ion source of a mass spectrometer improved measurement results, biased δ 18 O values could still be obtained. A careful evaluation of the performance of the GC separation column was carried out. With optimal GC columns, the δ 18 O reproducibility of human hair keratins and other keratin materials was better than ±0.15 ‰ (n = 5; for the internal analytical reproducibility), and better than ±0.10 ‰ (n = 4; for the external analytical reproducibility).

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Haiping Qi, Tyler B. Coplen, Leonard I Wassenaar. 2011-06-23. Improved online δ18O measurements of nitrogen‐ and sulfur‐bearing organic materials and a proposed analytical protocol. https://doi.org/10.1002/rcm.5088

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USGS2026

Reaffirming the consistency of the original stock of NBS 19 limestone and its byproduct with finer grain size for δ13C and δ18O calibrations—Both distributed internationally

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