USGS ScienceSearch

USGS · 70205796

Massive sulfide copper deposits of the Ergani-Maden area, Southeastern Turkey

Abstract

The copper deposits of the Ergani-Maden area, in the Taurus Mountains of southeastern Turkey, have been a major source of copper for more than 4,000 years. The area is underlain by gently dipping mudstones interlayered with mafic volcanic rocks and lenticular beds of limestone, mainly of Eocene age. The layered rocks were intruded and slightly metamorphosed by large masses of gabbro and related mafic rocks that are now largely serpentinized. The copper deposits are in an east-trending belt about 20 km long, near the center of which is the town of Maden. A broad geochemical anomaly extends north-northwest and south-southeast from this belt, its axis passing near Maden. Near the mines the main igneous mass has a gently dipping roof and steep sides. Around and south of Maden, where the mass has barely been unroofed, are many roof pendants and remnants of sedimentary and volcanic material. One of these contains the largest mine in the area--the Ana Yatak. The largest deposit, the Aria Yatak ore body, occurs in a canoe-shaped pendant of mudstone that occupies atrough about 1 km long and 1/2 km wide in the top of the intrusive. The present vertical extent is about 170 meters. In the central and western parts of the trough the mudstone is chloritized and partly replaced by ore minerals. The main ore body is about 550 X 300 X 50 m in maximum dimensions. It consists mainly of pyrite and chalcopyrite, and locally it contains abundant magnetite or pyrrhotite. The gangue consists predominantly of chlorite, smaller amounts of quartz, and very minor amounts of calcite and barite. The massive sulfide ore body is underlain by "impregnation ore" in which veinlets and irregular small masses of sulfides are embedded in chloritized mudstone. A zone rich in supergene chalcocite, corellite, and bornite lies between the sulfide mass and the well-developed gossan in many places, and this was extensively mined in ancient times. The Mihrap Dagi mine, about 1 km northwest of the Aria Yatak deposit, is also near a contact between the intrusive and the sedimentary rock. It too contains a massive sulfide ore body accompanied by chloritized rock, but it contains little "impregnation ore." In the Ergani-Maden area, ore deposition followed a long history of sedimentation, lithification, faulting, intrusion of mafic igneous rocks, serpentinization, and further faulting, and was part of a broad-scale introduction of metal into the sedimentary, extrusive, and intrusive rocks. Thus it is epigenetic. The major ore bodies are fracturecontrolled replacement masses. Adularia which occurs in veins a few hundred meters south of the main sulfide ore bodies is inferred to have formed contemporaneously with the sulfide and shows a potassium-argon age of 31.5 +/- 0.8 m.y. If this inference is correcthe deposits formed during middle Oligocene or slightly later.

Explore related subjects

90° N90° S · 180° W ← longitude → 180° E
Source-reported bounding extent: 38.09998264736481° to 38.74551518488265° latitude; 39.364013671875° to 40.36376953125° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

W. R. Griffitts, J. P. Albers, Oemer Oener. 1972-10-01. Massive sulfide copper deposits of the Ergani-Maden area, Southeastern Turkey. https://doi.org/10.2113/gsecongeo.67.6.701

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related USGS reports

Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA

The J-M reef of the Stillwater Complex is characterized by a high Pd/Pt ratio (mean ~3.8 with a standard error of 0.03) with a homogeneous geospatial distribution at the deposit scale. In this contribution, we demonstrate that the Pd/Pt ratio of the reef is the product of equilibration of an immiscible sulfide liquid with a silicate melt rich in Pd relative to Pt. Despite the high tenors of the J-M reef sulfides (avg 2,700 ppm Pt and 770 ppm Pt), numerical modeling shows that the parental melts did not have extraordinary Pd and Pt concentrations. Instead, the initial composition of a plausible parental silicate melt can have Pd and Pt contents well within the expected range of a normal, mantle-derived partial melt (i.e., ~10–20 ppb for both Pd and Pt with Pd/Pt of ~1). The relative differences in the partitioning behavior of Pt and Pd between sulfide liquid and silicate melt are unlikely to produce a consistent Pd/Pt ratio across a wide range of silicate melt to sulfide liquid mass ratios (i.e., R factors). Instead, the pre-emplacement fractionation of Pt alloy from S-undersaturated silicate magma accounts for the homogeneous and high Pd/Pt ratio of the J-M reef. We show that batch equilibration of sulfide liquid with silicate melt can produce the high Pd/Pt ratios of the reef if the partition coefficients between sulfide liquid and silicate melt for Pd and Pt are extremely high (>10 6 ). In an alternative model, Pd enrichment could be achieved by sulfide upgrading in resident footwall mush even if the partition coefficients between sulfide liquid and silicate melt are relatively small (between 10 4 and 10 6 ) because the instantaneous mass ratio of silicate melt to sulfide liquid is small (R ≈ 100–700), so the partitioning behavior of Pt and Pd has little impact on the composition of sulfide liquid.

Montana

Depth of magma crystallization and fluid exsolution beneath the porphyry-skarn Cu deposits at Santa Rita and Hanover-Fierro, New Mexico, USA

The depth level at which porphyry Cu–forming magmas fractionated and exsolved mineralizing fluids is actively debated. In the classic model, extensive magma fractionation occurs in large, upper crustal magma chambers, and concomitant fluid exsolution leads to forceful expulsion of residual magmas in the form of porphyry dikes, stocks, and breccia pipes, which subsequently serve as pathways for the mineralizing fluids. In contrast, some recent studies highlighting the role of deep crustal magma fractionation in the production of fertile magmas essentially deny the existence of upper crustal magma chambers at the time of mineralization. To address this, we conducted a detailed thermobarometric investigation of 13 intermediate to felsic, porphyritic intrusive rocks related to porphyry-skarn Cu mineralization at Santa Rita and Hanover-Fierro, New Mexico, United States, representing two premineralization magmas (61–60 Ma), seven synmineralization magmas (60–58 Ma), and four late- to postmineralization magmas (58–57 Ma). For each sample, the pressure of last magma crystallization before final magma ascent to the current exposure level was reconstructed based on Al-in-hornblende barometry of small hornblende inclusions trapped within quartz phenocrysts and through titanium-in-quartz (TitaniQ) thermobarometry of the host quartz phenocrysts themselves. Since quartz is one of the last crystallizing magmatic minerals, and no significant phenocryst growth could have occurred in small dikes and stocks after final magma emplacement, quartz phenocrysts and their contained hornblende inclusions record the depth of last magma crystallization before final magma ascent. When present, hornblende phenocrysts and hornblende inclusions within other major phenocrysts were also analyzed. Both quartz and hornblende barometers return consistent average pressures of 3.2 ± 0.4 kbar for the entire suite of pre- to postmineralization magmas, corresponding to depths of 11 to 14 km. The synmineralization magmas return even more consistent average pressures of 3.1 ± 0.2 kbar, corresponding to a depth of 12 ± 1 km. The volume of the mineralizing porphyry dikes and stocks at the emplacement level is far too small to have provided all the fluids and metals required to form the observed ore deposits. Therefore, the majority of the ore-forming fluids must have originated from the magmas that crystallized at 12 ± 1 km depth. The ore deposits, conversely, formed at ~5-km paleodepth. This implies that most of the mineralizing fluids traveled an average vertical distance of ~7 km from their magmatic source to the eventual site of ore precipitation. The relatively unaltered nature and low veining degree of deeper parts of mineralized porphyry dikes and stocks suggest that the fluid transport through these intrusive bodies occurred mostly at near-solidus conditions by means of fluid percolation along grain boundaries. In summary, our results suggest that (1) a large, upper crustal pluton exists ~7 km beneath the Santa Rita and Hanover-Fierro deposits; (2) abundant phenocryst crystallization occurred at this depth level; and (3) this pluton was the main source for the exsolution of ore-forming fluids. However, the investigated rocks have elevated whole-rock Sr/Y ratios, indicating magma fractionation at deep crustal levels. As a result, our preferred model is a combination of the two end-member models introduced above, with most magma fractionation having occurred in the deep crust and with residual, intermediate to felsic melts having ascended and accumulated at 11 to 14 km paleodepth, where they continued to crystallize with comparatively little crystal-liquid separation, before some of these magmas ascended further to shallow levels and quenched to porphyries.

New Mexico

Assimilation of reduced carbon triggers platinum alloy saturation in mafic and ultramafic magmas

It is generally observed that magmatic sulfide ores have higher ratios of Pd/Pt than the mantle-like values of their parental magmas. This discrepancy has defied simple explanation because the partitioning behavior of both elements between sulfide and silicate liquids is very similar. Assimilation of sulfur- and carbon-rich country rocks by mafic and ultramafic magmas is considered a critical, if not essential, step in the formation of magmatic base metal sulfide deposits. Although there is general consensus that the assimilation of external sulfur and carbon promotes sulfide saturation, the effect of carbon assimilation on the solubilities of platinum-group elements in natural S-bearing silicate melt has been overlooked. In this study, we investigate the variations of platinum and palladium solubilities during assimilation of graphite and methane through thermodynamic modeling, in comparison with data from an array of highly distinctive magmatic sulfide ore systems representing ages from Archean to Paleozoic, melt compositions from komatiite to basalt, and magmatic settings including lavas, hypabyssal intrusions, plutonic continental arc roots, and plutonic layered intrusions, namely: Raglan, Norilsk-Talnakh, Lac des Iles, and the J-M Reef of the Stillwater Complex. We model assimilation-fractional crystallization processes to estimate the reduction of oxygen fugacity ( ⁠fO2⁠ ) of the melt due to incorporation of graphite and methane. The simulations show that although Pd remains highly soluble during the progressive assimilation of reduced carbon, Pt solubility decreases significantly as the silicate melt becomes increasingly reduced. With less than 8 % of sediment assimilation, Pt alloy may saturate and then deviate from sulfide-undersaturated silicate melts, concomitantly increasing the Pd/Pt value of the remaining melts of the Raglan and Norilsk-Talnakh systems. For the Lac des Iles and Stillwater systems, a higher extent of assimilation is needed to reach Pt saturation because of the relatively carbon-poor nature of the lower crustal rocks. The assimilation of methane volatiles is shown to be more effective than graphite assimilation, and it provides a pathway to Pt alloy fractionation in the absence of detectable amounts of bulk host-rock assimilation. High Pd/Pt values have been documented in many world-class magmatic sulfide deposits whose parental magmas have demonstrably experienced crustal contamination. Our model suggests that although anomalous Pd/Pt values may be explained by other mechanisms such as incongruent melting of preexisting sulfide or differences in the diffusivities of the metals within achieving equilibration, the assimilation of graphite or methane may play an important role in the global occurrence of magmatic sulfide ores with elevated Pd/Pt values.

Economic Geology