Degassing of CO2, SO2, and H2S associated with the 2009 eruption of Redoubt Volcano, Alaska

Abstract

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions. We report 35 airborne measurements of CO 2 , SO 2 , and H 2 S emission rates that span from October 2008 to August 2010. The magmatic system degassed primarily as a closed system although minor amounts of open system degassing were observed in the 6 months prior to eruption on March 15, 2009 and over 1 year following cessation of dome extrusion. Only 14% of the total CO 2 was emitted prior to eruption even though high emissions rates (between 3630 and 9020 t/d) were observed in the final 6 weeks preceding the eruption. A minor amount of the total SO 2 was observed prior to eruption (4%), which was consistent with the low emission rates at that time (up to 180 t/d). The amount of the gas emitted during the explosive and dome growth period (March 15–July 1, 2009) was 59 and 66% of the total CO 2 and SO 2 , respectively. Maximum emission rates were 33,110 t/d CO 2 , 16,650 t/d SO 2 , and 1230 t/d H 2 S. Post-eruptive passive degassing was responsible for 27 and 30% of the total CO 2 and SO 2 , respectively. SO 2 made up on average 92% of the total sulfur degassing throughout the eruption. Magmas were vapor saturated with a C- and S-rich volatile phase, and regardless of composition, the magmas appear to be buffered by a volatile composition with a molar CO 2 /SO 2 ratio of ~ 2.4. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9 to 2.1 wt.% CO 2 and 0.27–0.56 wt.% S; whole-rock normalized values are slightly lower (0.8–1.7 wt.% CO 2 and 0.22–0.47 wt.% S) and are similar to what was calculated for the 1989–90 eruption of Redoubt. Such contents argue that primary arc magmas are rich in CO 2 and S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt.% CO 2 and 0.35 wt.% S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.