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Insights from fumarole gas geochemistry on the origin of hydrothermal fluids on the Yellowstone Plateau

Giovanni Chiodini·Stefano Caliro·Jacob B. Lowenstern·William C. Evans·D. Bergfeld·Franco Tassi·Dario Tedesco
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Abstract

The chemistry of Yellowstone fumarole gases shows the existence of two component waters, type MC, influenced by the addition of deep mantle fluid, and type CC, influenced by crustal interactions (CC). MC is high in 3 He/ 4 He (22 Ra) and low in 4 He/ 40 Ar (∼1), reflecting input of deep mantle components. The other water is characterized by 4 He concentrations 3–4 orders of magnitude higher than air-saturated meteoric water (ASW). These high He concentrations originate through circulation in Pleistocene volcanic rocks, as well as outgassing of Tertiary and older (including Archean) basement, some of which could be particularly rich in uranium, a major 4 He source. Consideration of CO 2 –CH 4 –CO–H 2 O–H 2 gas equilibrium reactions indicates equilibration temperatures from 170 °C to 310 °C. The estimated temperatures highly correlate with noble-gas variations, suggesting that the two waters differ in temperature. Type CC is ∼170 °C whereas the MC is hotter, at 340 °C. This result is similar to models proposed by previous studies of thermal water chemistry. However, instead of mixing the deep hot component simply with cold, meteoric waters we argue that addition of a 4 He-rich component, equilibrated at temperatures around 170 °C, is necessary to explain the range in fumarole gas chemistry.

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Geochimica et Cosmochimica ActaArticle
90° N90° S · 180° W ← longitude → 180° E
Source-reported bounding extent: 44.33° to 44.5° latitude; -111° to -110° longitude. This indicates report coverage, not an exact sampling location. View area on OpenStreetMap.

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Giovanni Chiodini, Stefano Caliro, Jacob B. Lowenstern, William C. Evans, D. Bergfeld, Franco Tassi, Dario Tedesco. 2012. Insights from fumarole gas geochemistry on the origin of hydrothermal fluids on the Yellowstone Plateau. https://doi.org/10.1016/j.gca.2012.04.051

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